JP2021515084A - 熱会合性で交換可能な共重合体、およびこれを含む組成物 - Google Patents

熱会合性で交換可能な共重合体、およびこれを含む組成物 Download PDF

Info

Publication number
JP2021515084A
JP2021515084A JP2020546488A JP2020546488A JP2021515084A JP 2021515084 A JP2021515084 A JP 2021515084A JP 2020546488 A JP2020546488 A JP 2020546488A JP 2020546488 A JP2020546488 A JP 2020546488A JP 2021515084 A JP2021515084 A JP 2021515084A
Authority
JP
Japan
Prior art keywords
copolymer
monomer
group
comb
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2020546488A
Other languages
English (en)
Japanese (ja)
Other versions
JPWO2019171007A5 (enExample
Inventor
デクロワ・グレゴリー
ブリアン・ファニ
ニコライ・ルノー
ドゥルーノ・ティボー
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Physique et Chimie Industrielles de Ville de Paris ESPCI
Original Assignee
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Physique et Chimie Industrielles de Ville de Paris ESPCI
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Ecole Superieure de Physique et Chimie Industrielles de Ville de Paris ESPCI filed Critical Centre National de la Recherche Scientifique CNRS
Publication of JP2021515084A publication Critical patent/JP2021515084A/ja
Publication of JPWO2019171007A5 publication Critical patent/JPWO2019171007A5/ja
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing boron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/52—Lubricating compositions characterised by the base-material being a macromolecular compound containing boron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F30/00—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F30/04—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F30/06—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C10M2203/1025—Aliphatic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/04—Molecular weight; Molecular weight distribution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/071—Branched chain compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/74—Noack Volatility

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Lubricants (AREA)
JP2020546488A 2018-03-07 2019-03-07 熱会合性で交換可能な共重合体、およびこれを含む組成物 Pending JP2021515084A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1851970A FR3078706B1 (fr) 2018-03-07 2018-03-07 Copolymeres thermoassociatifs et echangeables, composition les comprenant
FR1851970 2018-03-07
PCT/FR2019/050510 WO2019171007A1 (fr) 2018-03-07 2019-03-07 Copolymeres thermoassociatifs et echangeables, composition les comprenant

Publications (2)

Publication Number Publication Date
JP2021515084A true JP2021515084A (ja) 2021-06-17
JPWO2019171007A5 JPWO2019171007A5 (enExample) 2022-02-22

Family

ID=62092127

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2020546488A Pending JP2021515084A (ja) 2018-03-07 2019-03-07 熱会合性で交換可能な共重合体、およびこれを含む組成物

Country Status (7)

Country Link
US (1) US11897986B2 (enExample)
EP (1) EP3762434B1 (enExample)
JP (1) JP2021515084A (enExample)
KR (1) KR20200139166A (enExample)
CN (1) CN112105658B (enExample)
FR (1) FR3078706B1 (enExample)
WO (1) WO2019171007A1 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3081464B1 (fr) * 2018-05-24 2020-09-18 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
FR3081465B1 (fr) * 2018-05-24 2020-06-12 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
FR3081466B1 (fr) * 2018-05-24 2020-06-12 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
EP4441180A1 (en) 2021-12-03 2024-10-09 TotalEnergies OneTech Lubricant compositions
WO2023099630A1 (en) 2021-12-03 2023-06-08 Evonik Operations Gmbh Boronic ester modified polyalkyl(meth)acrylate polymers
WO2023099631A1 (en) 2021-12-03 2023-06-08 Evonik Operations Gmbh Boronic ester modified polyalkyl(meth)acrylate polymers
WO2023099632A1 (en) 2021-12-03 2023-06-08 Evonik Operations Gmbh Boronic ester modified polyalkyl(meth)acrylate polymers
WO2023099635A1 (en) 2021-12-03 2023-06-08 Totalenergies Onetech Lubricant compositions
EP4441178B1 (en) 2021-12-03 2025-05-14 TotalEnergies OneTech Lubricant compositions
CN118434835A (zh) * 2021-12-24 2024-08-02 出光兴产株式会社 粘度指数改进剂组合物、润滑油用添加剂组合物和润滑油组合物

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012520358A (ja) * 2009-03-10 2012-09-06 エボニック ローマックス アディティヴス ゲゼルシャフト ミット ベシュレンクテル ハフツング スカッフィング耐荷力を改善するためのコームポリマーの使用
JP2014210844A (ja) * 2013-04-17 2014-11-13 コスモ石油ルブリカンツ株式会社 内燃機関用潤滑油組成物
WO2016043334A1 (ja) * 2014-09-19 2016-03-24 出光興産株式会社 潤滑油組成物
JP2017507228A (ja) * 2014-01-27 2017-03-16 トータル・マーケティング・サービシーズ 熱会合性で交換可能な共重合体、およびこれを含む組成物
JP2017508055A (ja) * 2014-01-27 2017-03-23 トータル・マーケティング・サービシーズ 熱会合性で交換可能な共重合体を含む潤滑剤組成物

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5159123A (en) 1991-05-02 1992-10-27 Texaco Chemical Company Synthesis of hydroxyl-terminated polybutadienes using glycol ether acetate solvents
EP1492823B1 (fr) 2002-04-11 2008-02-27 Arkema France Procede d'hydrogenation de polymeres en milieu disperse
DE102006062441A1 (de) * 2006-12-27 2008-07-03 Byk-Chemie Gmbh Modifizierte Kammcopolymere
DE102009001446A1 (de) * 2009-03-10 2010-09-23 Evonik Rohmax Additives Gmbh Verwendung von Kammpolymeren als Antifatigue-Additive
CN103804633A (zh) * 2012-11-07 2014-05-21 海洋王照明科技股份有限公司 含亚烷基芴与二噻吩并吡咯共聚物及其制备方法与应用
FR3031744B1 (fr) * 2015-01-15 2017-02-10 Total Marketing Services Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant
FR3040172B1 (fr) * 2015-08-20 2020-01-24 Ecole Superieure De Physique Et De Chimie Industrielles De La Ville De Paris Compositions de polymere comprenant des polymeres reticules comprenant des fonctions ester boronique, permettant des reactions d'echange, procede de preparation et utilisation
FR3059005B1 (fr) 2016-11-23 2018-12-07 Total Marketing Services Copolymeres thermoassociatifs et echangeables, composition les comprenant

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012520358A (ja) * 2009-03-10 2012-09-06 エボニック ローマックス アディティヴス ゲゼルシャフト ミット ベシュレンクテル ハフツング スカッフィング耐荷力を改善するためのコームポリマーの使用
JP2014210844A (ja) * 2013-04-17 2014-11-13 コスモ石油ルブリカンツ株式会社 内燃機関用潤滑油組成物
JP2017507228A (ja) * 2014-01-27 2017-03-16 トータル・マーケティング・サービシーズ 熱会合性で交換可能な共重合体、およびこれを含む組成物
JP2017508055A (ja) * 2014-01-27 2017-03-23 トータル・マーケティング・サービシーズ 熱会合性で交換可能な共重合体を含む潤滑剤組成物
WO2016043334A1 (ja) * 2014-09-19 2016-03-24 出光興産株式会社 潤滑油組成物

Also Published As

Publication number Publication date
CN112105658B (zh) 2025-02-28
US20200399412A1 (en) 2020-12-24
CN112105658A (zh) 2020-12-18
EP3762434B1 (fr) 2022-05-04
FR3078706B1 (fr) 2020-12-18
EP3762434A1 (fr) 2021-01-13
WO2019171007A1 (fr) 2019-09-12
US11897986B2 (en) 2024-02-13
KR20200139166A (ko) 2020-12-11
FR3078706A1 (fr) 2019-09-13

Similar Documents

Publication Publication Date Title
JP2021515084A (ja) 熱会合性で交換可能な共重合体、およびこれを含む組成物
JP2021517183A (ja) 熱会合性で交換可能な共重合体を含む組成物
JP7008717B2 (ja) 会合が制御された熱会合性の添加剤組成物、及び該組成物を含有する潤滑性組成物
JP6778685B2 (ja) 制御された会合性を有する熱会合性添加剤組成物、およびそれを含む潤滑剤組成物
JP7236467B2 (ja) 会合性で交換可能なオリゴマーおよびこれを含む組成物
JP7236468B2 (ja) 会合性で交換可能なオリゴマーおよびこれを含む組成物
KR102292997B1 (ko) 열결합 및 치환 공중합체를 포함하는 윤활 조성물
JP7236469B2 (ja) 会合性で交換可能なオリゴマーおよびこれを含む組成物
JP2019183176A (ja) 熱会合性で交換可能な共重合体、およびこれを含む組成物
JP2021525299A (ja) 会合性で交換可能なオリゴマーおよびこれを含む組成物
JP7085558B2 (ja) 熱会合性かつ交換可能なコポリマー、該コポリマーを含む組成物

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20220214

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20220214

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20230131

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20230131

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20230403

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20231003