JP2021172587A - Oil-in-water type emulsion cosmetic - Google Patents
Oil-in-water type emulsion cosmetic Download PDFInfo
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- JP2021172587A JP2021172587A JP2020074417A JP2020074417A JP2021172587A JP 2021172587 A JP2021172587 A JP 2021172587A JP 2020074417 A JP2020074417 A JP 2020074417A JP 2020074417 A JP2020074417 A JP 2020074417A JP 2021172587 A JP2021172587 A JP 2021172587A
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- Prior art keywords
- oil
- iob
- component
- acid
- skin
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、水中油型乳化化粧料に関し、さらに詳細には電解質を含有しつつも長期安定性に優れるとともに、浸透感、使用後の肌のやわらかさに優れた水中油型乳化化粧料に関するものである。 The present invention relates to an oil-in-water emulsified cosmetic, and more specifically, to an oil-in-water emulsified cosmetic which is excellent in long-term stability while containing an electrolyte, and has excellent penetration and softness of the skin after use. Is.
従来より、水中油型乳化化粧料は、みずみずしい使用感と油剤によるエモリエント効果を併せ持つことから、スキンケア化粧料において広く用いられている。またスキンケア化粧料には、種々の美容効果を求めて、美白剤や保湿剤等の有効成分が配合されており、これら有効成分は生理活性のある電解質であるものが多い。 Conventionally, oil-in-water emulsified cosmetics have been widely used in skin care cosmetics because they have both a fresh feeling of use and an emollient effect of oils. In addition, skin care cosmetics contain active ingredients such as whitening agents and moisturizers in order to obtain various beauty effects, and many of these active ingredients are bioactive electrolytes.
このような電解質を配合した化粧料として、例えば、アスコルビン酸−2−リン酸エステルの脂肪酸エステルの塩、炭素数が5又は6の2価アルコール、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンソルビタン脂肪酸エステル、テルペン化合物を含有する皮膚化粧料(特許文献1)や、特定のポリオキシエチレンソルビット脂肪酸エステル、特定のポリオキシエチレン硬化ヒマシ油、炭素数12〜22の高級アルコール及び/又は炭素数12〜22の脂肪酸モノグリセリル、水、電解質を含有し、乳化滴の平均粒径を50〜300nmである水中油型乳化化粧料(特許文献2)が知られている。 Examples of cosmetics containing such an electrolyte include a fatty acid ester salt of ascorbic acid-2-phosphate ester, a divalent alcohol having 5 or 6 carbon atoms, polyoxyethylene hydrogenated castor oil, and polyoxyethylene sorbitan fatty acid. Skin cosmetics containing esters and terpene compounds (Patent Document 1), specific polyoxyethylene sorbit fatty acid esters, specific polyoxyethylene hydrogenated castor oil, higher alcohols having 12 to 22 carbon atoms and / or 12 to 12 carbon atoms. An oil-in-water emulsified cosmetic containing 22 fatty acids monoglyceryl, water, and an electrolyte and having an average particle size of emulsified droplets of 50 to 300 nm (Patent Document 2) is known.
一方、これらの有効成分を含有する化粧料(医薬部外品)は、安定性試験ガイドライン(平成15年6月、医薬審発第0603001号)等の医薬品の安定性試験ガイドラインに準拠し、40℃・75%湿度環境下で6か月間の長期安定性を担保できることが求められている。 On the other hand, cosmetics (quasi-drugs) containing these active ingredients comply with the stability test guidelines for pharmaceutical products such as the stability test guidelines (June 2003, Pharmaceutical Trial No. 0603001), and 40. It is required to ensure long-term stability for 6 months in a temperature / 75% humidity environment.
しかしながら、電解質を多量に含有する化粧料は、一般的に、長期保存すると分離等の安定性不良を生じ易いという懸念があった。そこで、安定性を向上するために、耐塩性の高分子を配合すると、べたついて浸透感を損なう場合があったり、固形油を配合すると、使用後の膜感が強く、後肌のやわらかさやしっとり感の点でも満足いくものが得られない場合があった。そこで、浸透感を高めるために極性の高い油剤を配合すると、乳化安定性に寄与する界面活性剤が溶解されてしまい、長期安定性の点で問題が生じることがあった。
従って本発明は、電解質存在下において、浸透感と後肌のやわらかさに優れ、6か月に渡る長期安定性をも兼ね備える、水中油型乳化化粧料を提供することを目的とする。
However, there is a concern that cosmetics containing a large amount of electrolyte generally tend to cause poor stability such as separation when stored for a long period of time. Therefore, in order to improve stability, if a salt-resistant polymer is added, it may become sticky and impair the permeation feeling, or if a solid oil is added, the film feeling after use is strong, and the back skin is soft and moist. In some cases, I was not satisfied with the feeling. Therefore, when a highly polar oil agent is blended in order to enhance the permeation feeling, the surfactant that contributes to the emulsion stability is dissolved, which may cause a problem in terms of long-term stability.
Therefore, an object of the present invention is to provide an oil-in-water emulsified cosmetic that is excellent in permeation and softness of the back skin in the presence of an electrolyte, and also has long-term stability for 6 months.
本発明者は、上記課題を解決するために鋭意検討を重ねた結果、電解質を含有する水中油型乳化化粧料において、特定のノニオン界面活性剤を用いて、極性油とジェランガムとを組み合わせた乳化組成物とすることにより、6か月に渡る長期間の安定保存が可能であり、浸透感と後肌のやわらかさに優れる化粧料が実現できることを見出し、本発明を完成するに至った。 As a result of diligent studies to solve the above problems, the present inventor has used a specific nonionic surfactant to emulsify a combination of polar oil and gellan gum in an oil-in-water emulsified cosmetic containing an electrolyte. It has been found that the composition can be stably stored for a long period of 6 months, and a cosmetic having excellent penetration and softness of the back skin can be realized, and the present invention has been completed.
すなわち、本発明は、次の成分(A)〜(E):
(A)HLB10〜15のポリオキシエチレン硬化ヒマシ油
(B)HLB10〜15のポリオキシエチレンソルビット脂肪酸エステル
(C)25℃において液状の極性油
(D)ジェランガム
(E)電解質
を含有する水中油型乳化化粧料を提供するものである。
また、本発明の一様態としては、さらに、電気伝導率が0.01〜2S/mである水中油型乳化化粧料であってもよい。
That is, in the present invention, the following components (A) to (E):
(A) Polyoxyethylene hydrogenated castor oil of HLB10 to 15 (B) Polyoxyethylene sorbit fatty acid ester of HLB10 to 15 (C) Liquid polar oil at 25 ° C. Oil type in water containing gellan gum (E) electrolyte It provides emulsified cosmetics.
Further, as the uniform state of the present invention, an oil-in-water emulsified cosmetic having an electric conductivity of 0.01 to 2 S / m may be further used.
本発明によれば、電解質を含む場合でも、長期に渡る保存安定性に優れるものとなる。また、本発明の水中油型乳化化粧料は、浸透感に優れるため、肌なじみも良好であり、後肌のやわらかさにも優れるものである。そのため、美白化粧料、抗老化化粧料といった高機能なスキンケア化粧料として有用である。 According to the present invention, even when an electrolyte is contained, the storage stability over a long period of time is excellent. In addition, the oil-in-water emulsified cosmetic of the present invention has an excellent permeation feeling, so that it fits well on the skin and is also excellent in the softness of the back skin. Therefore, it is useful as a highly functional skin care cosmetic such as a whitening cosmetic and an anti-aging cosmetic.
以下、本発明について詳細に説明する。なお、本明細書において、「〜」はその前後の数値を含む範囲を意味するものとする。 Hereinafter, the present invention will be described in detail. In addition, in this specification, "~" means the range including the numerical values before and after it.
本発明に用いられる成分(A)HLB10〜15のポリオキシエチレン硬化ヒマシ油は、ヒマシ油に水素添加して得られる硬化ヒマシ油に、酸化エチレンを付加して得られたものであって、HLBが前記範囲内であれば、特に制限されず、何れのものも使用できる。具体的には、硬化ヒマシ油に付加される酸化エチレンのモル数が20〜80モル程度であり、これらの市販品としては、NIKKOL HCO−20、30、40、50、60、80(以上、日光ケミカルズ社製)等が挙げられ、必要に応じその1種又は2種以上を用いることができる。 The polyoxyethylene hydrogenated castor oil of the component (A) HLB10 to 15 used in the present invention is obtained by adding ethylene oxide to the cured castor oil obtained by hydrogenating the castor oil, and is HLB. Is not particularly limited as long as it is within the above range, and any of them can be used. Specifically, the number of moles of ethylene oxide added to the hardened castor oil is about 20 to 80 moles, and as these commercially available products, NIKKOL HCO-20, 30, 40, 50, 60, 80 (or more, (Manufactured by Nikko Chemicals Co., Ltd.) and the like, and one or more of them can be used as needed.
本発明における成分(A)の含有量は、特に限定されないが、浸透感と長期安定性の観点から、水中油型乳化化粧料中、0.01質量%(以下、単に%と略す)以上、さらには0.1%以上が好ましく、べたつき等の使用感の観点から、5%以下、さらには2%以下が好ましい。 The content of the component (A) in the present invention is not particularly limited, but is 0.01% by mass (hereinafter, simply abbreviated as%) or more in the oil-in-water emulsified cosmetic from the viewpoint of penetration and long-term stability. Further, 0.1% or more is preferable, and from the viewpoint of usability such as stickiness, 5% or less, further 2% or less is preferable.
本発明に用いられる成分(B)HLB10〜15のポリオキシエチレンソルビット脂肪酸エステルは、ソルビトールに酸化エチレンを付加したものを、脂肪酸でエステル化したものであって、HLBが前記範囲内であれば、特に制限されず、何れのものも使用できる。成分(B)は、成分(A)と組み合わせて配合することにより乳化滴を微細化し、浸透感と長期安定性に寄与するものである。
具体的には、例えば、モノラウリン酸ポリオキシエチレンソルビット、テトラオレイン酸ポリオキシエチレンソルビット、テトラステアリン酸ポリオキシエチレンソルビット等が挙げられ、必要に応じて1種又は2種以上を用いることができるが、中でも、浸透感と長期安定性の観点で、テトラオレイン酸ポリオキシエチレンソルビットが好ましい。これらの市販品としては、NIKKOL GO−4V、NIKKOL GO−430NV、NIKKOL GO−440V、NIKKOL GO−460V(以上、日光ケミカルズ社製)などが挙げられる。
The polyoxyethylene sorbit fatty acid ester of the component (B) HLB 10 to 15 used in the present invention is obtained by adding ethylene oxide to sorbitol and esterifying it with a fatty acid, and if the HLB is within the above range, There are no particular restrictions, and any of them can be used. The component (B) is blended in combination with the component (A) to make the emulsified droplets finer, which contributes to a feeling of penetration and long-term stability.
Specific examples thereof include polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbit tetraoleate, polyoxyethylene sorbitol tetrastearate, and the like, and one or more of them can be used as needed. Of these, polyoxyethylene sorbitol tetraoleate is preferable from the viewpoint of penetration and long-term stability. Examples of these commercially available products include NIKKOL GO-4V, NIKKOL GO-430NV, NIKKOL GO-440V, and NIKKOL GO-460V (all manufactured by Nikko Chemicals Co., Ltd.).
本発明における成分(B)の含有量は、特に限定されないが、浸透感と長期安定性の観点から、水中油型乳化化粧料中、0.01%以上、さらには0.1%以上が好ましく、べたつき等の使用感の観点から、5%以下、さらには2%以下が好ましい。 The content of the component (B) in the present invention is not particularly limited, but is preferably 0.01% or more, more preferably 0.1% or more in the oil-in-water emulsified cosmetic from the viewpoint of penetration and long-term stability. From the viewpoint of usability such as stickiness, 5% or less, more preferably 2% or less.
本発明に用いられる成分(C)25℃において液状の極性油は、主に浸透感と後肌のやわらかさに寄与するものであり、25℃において液状であれば通常化粧料に用いられるものであれば、特に限定されず、揮発性、非揮発性や、動物油、植物油、合成油等の起源を問わず、使用することができる。 The component (C) liquid at 25 ° C. used in the present invention mainly contributes to the permeation feeling and the softness of the back skin, and if it is liquid at 25 ° C., it is usually used for cosmetics. If there is, it is not particularly limited and can be used regardless of the origin of volatile, non-volatile oil, animal oil, vegetable oil, synthetic oil and the like.
成分(C)のIOBは、特に限定されないが、0.1〜0.5のものが好ましく挙げられる。IOBがこの範囲内であれば、浸透感に優れるため、好ましい。なお、IOB(Inorganic−Organicbalance)とは、下記(式1)で計算されるものである。
IOB=(Σ無機性値/Σ有機性)・・・(式1)
具体的には、2−エチルヘキサン酸セチル(IOB=0.13)、ネオペンタン酸オクチルドデシル(IOB=0.13)、ネオペンタン酸イソステアリル(IOB=0.14)、イソノナン酸イソトリデシル(IOB=0.15)、イソステアリン酸イソプロピル(IOB=0.15)、トリイソステアリン酸トリメチロールプロパン(IOB=0.16)、オリーブ油(IOB=0.16)、パルミチン酸イソプロピル(IOB=0.16)、オレイン酸エチル(IOB=0.16)、ラウリン酸ヘキシル(IOB=0.17)、ミリスチン酸イソプロピル(IOB=0.18)、イソノナン酸イソデシル(IOB=0.19)、安息香酸アルキル(C12〜15)(IOB=0.19)、イソノナン酸イソノニル(IOB=0.20)、デシルテトラデカノール(IOB=0.21)、ネオペンタン酸イソデシル(IOB=0.22)、ジカプリン酸ネオペンチルグリコール(IOB=0.25)、ジカプリン酸プロピレングリコール(IOB=0.26)、オクチルドデカノール(IOB=0.26)、リンゴ酸ジイソステアリル(IOB=0.28)、パラメトキシケイ皮酸2−エチルヘキシル(IOB値=0.28)、ジエチルヘキサン酸ネオペンチルグリコール(IOB=0.32)、コハク酸ジエチルヘキシル(IOB=0.32)、ジカプリル酸プロピレングリコール(IOB=0.32)、ジ(カプリル/カプリン酸)プロピレングリコール(IOB=0.32)、トリ2−エチルヘキサン酸グリセリル(IOB=0.35)、テトラエチルヘキサン酸ペンタエリスリチル(IOB=0.35)、ジイソステアリン酸ポリグリセリル−2(IOB=0.41)、ヒマシ油(IOB=0.42)、乳酸ミリスチル(IOB=0.47)等が挙げられ、これらの1種又は2種以上を用いることができる。
The IOB of the component (C) is not particularly limited, but those of 0.1 to 0.5 are preferably mentioned. When the IOB is within this range, it is preferable because it has an excellent permeation feeling. The IOB (Inorganic-Organic balance) is calculated by the following (Equation 1).
IOB = (Σ inorganic value / Σ organic) ... (Equation 1)
Specifically, cetyl 2-ethylhexanoate (IOB = 0.13), octyldodecyl neopentate (IOB = 0.13), isostearyl neopentate (IOB = 0.14), isotridecyl isononanoate (IOB = 0). .15), Isopropyl isostearate (IOB = 0.15), Trimethylolpropane triisostearate (IOB = 0.16), Olive oil (IOB = 0.16), Isopropyl palmitate (IOB = 0.16), Olein Ethyl acid acid (IOB = 0.16), hexyl laurate (IOB = 0.17), isopropyl myristate (IOB = 0.18), isodecyl isononanoate (IOB = 0.19), alkyl benzoate (C12-15) ) (IOB = 0.19), isononyl isononanoate (IOB = 0.20), decyltetradecanol (IOB = 0.21), isodecyl neopentanoate (IOB = 0.22), neopentyl glycol dicaprate (IOB) = 0.25), propylene glycol dicaprate (IOB = 0.26), octyldodecanol (IOB = 0.26), diisostearyl malate (IOB = 0.28), 2-ethylhexyl paramethoxysilicate crust (IOB value = 0.28), neopentyl glycol diethylhexanoate (IOB = 0.32), diethylhexyl succinate (IOB = 0.32), propylene glycol dicaprylate (IOB = 0.32), di (capril) / Capric acid) propylene glycol (IOB = 0.32), glyceryl tri2-ethylhexanoate (IOB = 0.35), pentaerythricyl tetraethylhexanoate (IOB = 0.35), polyglyceryl-2 diisostearate-2 (IOB) = 0.41), castor oil (IOB = 0.42), myristyl lactate (IOB = 0.47) and the like, and one or more of these can be used.
成分(C)の分子量は、特に限定されないが、乳化安定性に優れる点で、好ましくは400以下である。分子量が400以下である成分(C)として、具体的には、乳酸セチル、乳酸ミリスチル、ミリスチン酸イソプロピル、イソノナン酸イソトリデシル、ネオペンタン酸オクチルドデシル、ネオペンタン酸イソステアリル、パルミチン酸イソプロピル、オレイン酸エチル、ラウリン酸ヘキシル、エチルヘキサン酸ヘキシルデシル、イソノナン酸イソトリデシル、イソステアリン酸イソプロピル、イソステアリン酸エチル、パルミチン酸エチルヘキシル、ネオデカン酸オクチルドデシル、ミリスチン酸イソセチル、オクチルドデカノール、デシルテトラデカノール、ジエチルヘキサン酸ネオペンチルグリコール、アジピン酸ジイソプロピル、ジネオペンタン酸トリプロピレングリコール、イソデシルベンゾエート、ジカプリン酸プロピレングリコール、オレイン酸エチル、イソノナン酸イソノニル、イソノナン酸エチルヘキシル、セバシン酸ジエチルヘキシル、ネオペンタン酸イソデシル、エチルヘキサン酸エチルヘキシル、エチルヘキサン酸セチル、コハク酸ジエチルヘキシル等が挙げられ、これらの1種又は2種以上を用いることができる。 The molecular weight of the component (C) is not particularly limited, but is preferably 400 or less in terms of excellent emulsion stability. Specific examples of the component (C) having a molecular weight of 400 or less include cetyl lactate, myristyl lactate, isopropyl myristate, isotridecyl isononanoate, octyldodecyl neopentate, isostearyl neopentate, isopropyl palmitate, ethyl oleate, and laurin. Hexyl acid, hexyldecyl ethylhexanate, isotridecyl isononanoate, isopropyl isostearate, ethyl isostearate, ethylhexyl palmitate, octyldodecyl neodecanoate, isosetyl myristate, octyldodecanol, decyltetradecanol, neopentyl glycol diethylhexanate, Diisopropyl adipate, tripropylene glycol dineopentanoate, isodecylbenzoate, propylene glycol dicaprate, ethyl oleate, isononyl isononanoate, ethylhexyl isononanoate, diethylhexyl sebacate, isodecyl neopentate, ethylhexyl ethylhexanoate, cetyl ethylhexanate, Diethylhexyl succinate and the like can be mentioned, and one or more of these can be used.
成分(C)の化学構造は、特に限定されないが、成分(A)及び成分(B)と組み合わせた長期安定性の観点から、好ましくは分岐構造あるいは不飽和構造を有するものであり、例えばミリスチン酸イソプロピル、イソノナン酸イソトリデシル、ネオペンタン酸イソステアリル、パルミチン酸イソプロピル、オレイン酸エチル、イソノナン酸イソノニル、デシルテトラデカノール、ネオペンタン酸イソデシル、オクチルドデカノール、2−エチルヘキサン酸セチル、トリ2−エチルヘキサン酸グリセリル、コハク酸ジエチルヘキシル等が挙げられる。また、肌に浸透しやすい性質から、さらに水酸基構造を有するものが好ましく、オクチルドデカノール、デシルテトラデカノール等が挙げられ、これらの中でもオクチルドデカノールが、浸透感と後肌のやわらかさに優れる点で特に好ましい。市販品としては、EUTANOL G−JP(BASF社製)などが挙げられる。 The chemical structure of the component (C) is not particularly limited, but from the viewpoint of long-term stability in combination with the component (A) and the component (B), it preferably has a branched structure or an unsaturated structure, for example, myristic acid. Isopropyl, isotridecyl isononanoate, isostearyl neopentanoate, isopropyl palmitate, ethyl oleate, isononyl isononanoate, decyltetradecanol, isodecyl neopentanoate, octyldodecanol, cetyl 2-ethylhexanoate, glyceryl tri2-ethylhexanoate , Diethylhexyl succinate and the like. Further, since it has a property of easily penetrating into the skin, it is preferable to have a hydroxyl group structure, and examples thereof include octyldodecanol and decyltetradecanol. Among these, octyldodecanol is excellent in permeation feeling and softness of the back skin. Especially preferable in that respect. Examples of commercially available products include EUTANOL G-JP (manufactured by BASF).
本発明における成分(C)の含有量は、特に限定されないが、浸透感と後肌のやわらかさの観点から、0.01%以上、さらには0.1%以上が好ましく、長期安定性の観点から5%以下、さらには3.5%以下が好ましい。 The content of the component (C) in the present invention is not particularly limited, but is preferably 0.01% or more, more preferably 0.1% or more, from the viewpoint of penetration and the softness of the back skin, and from the viewpoint of long-term stability. 5% or less, more preferably 3.5% or less.
本発明に用いられる成分(D)ジェランガムは、Sphingomonas elodeaという微生物が菌体外に産生する多糖類であり、水で膨潤させることで弾力のあるゲルを形成し、さらにはカルシウムイオンやナトリウムイオン等の金属イオンと結合すると増粘することが期待される。ゆえに、肌に微量に存在する金属イオンと結合して素早く肌になじむことによって、成分(C)とともに浸透感を高め、成分(E)とともに保湿効果に優れる化粧膜を形成することで、後肌のやわらかさと長期安定性の向上に寄与するものである。 The component (D) gellan gum used in the present invention is a polysaccharide produced outside the cells by a microorganism called Sphingomonas elodea, which forms an elastic gel when swollen with water, and further contains calcium ions, sodium ions, etc. It is expected to thicken when combined with the metal ions of. Therefore, by binding to a small amount of metal ions present in the skin and quickly adapting to the skin, the permeation feeling is enhanced together with the component (C), and the back skin is formed with the component (E) having an excellent moisturizing effect. It contributes to the improvement of softness and long-term stability.
ジェランガムには、ネイティブ型及び、1−3結合したグルコースに存在するアセチル基とグリセリル基を除去した脱アシル型が知られているが、いずれをも用いることができる。市販品としては、脱アシル型のケルコゲル、ネイティブ型のケルコゲルLT−100(いずれもCPケルコ社製)等が挙げられ、1種又は2種以上を用いることができる。 As the gellan gum, a native type and a deacyl type in which the acetyl group and the glyceryl group present in 1-3-bonded glucose are removed are known, and any of them can be used. Examples of commercially available products include deacylated kelcogel and native kelcogel LT-100 (both manufactured by CP Kelco), and one or more of them can be used.
本発明における成分(D)の含有量は、特に限定されないが、浸透感、長期安定性の観点から、0.001%以上が好ましく、さらに0.01%以上、0.05%以上が好ましく、べたつき等の使用感の観点から、0.5%以下が好ましく、0.3%以下がさらに好ましい。 The content of the component (D) in the present invention is not particularly limited, but is preferably 0.001% or more, more preferably 0.01% or more, and more preferably 0.05% or more from the viewpoint of penetration and long-term stability. From the viewpoint of usability such as stickiness, 0.5% or less is preferable, and 0.3% or less is more preferable.
本発明に用いられる成分(E)電解質は、水、その他の溶媒に溶かした際、その溶液が電気伝導性を持つようになる物質であり、美白剤、消炎剤をはじめとする美容有効成分、保湿剤、pH調整剤、紫外線防御剤等として、化粧料に通常用いられるものであれば、有機・無機を問わず用いることができる。具体的には、アミノ酸、乳酸、クエン酸、ピロリドンカルボン酸等の有機化合物と、それらのカリウム、ナトリウム、マグネシウム、カルシウム等の金属塩、塩化ナトリウム、塩化マグネシウム等の無機塩やL−アラニン、β−アラニン、L−アルギニン、L−アルギニン塩酸塩、L−アスパラギン一水和物、L−アスパラギン酸、ポリアスパラギン酸、L−シトルリン、L−システイン、L−システイン塩酸塩一水和物、L−シスチン、L−ドーパ、L−グルタミン酸、L−グルタミン酸塩酸塩、L−グルタミン、ポリグルタミン酸、グリシン、トリメチルグリシン、L−ヒスチジン、L−ヒスチジン塩酸塩一水和物、L−ヒドロキシプロリン、L−イソロイシン、L−ロイシン、L−リジン、L−リジン塩酸塩、L−メチオニン、L−オルニチン塩酸塩、L−プロリン、L−フェニルアラニン、L−セリン、L−スレオニン、L−トリプトファン、L−チロシン、L−バリン等のアミノ酸及びその誘導体や塩類、またアスコルビン酸、アスコルビン酸リン酸エステル、アスコルビン酸硫酸エステル、アスコルビン酸グルコシド等とそれらのナトリウム、カリウム、マグネシウム、カルシウム等の金属塩等の水溶性アスコルビン酸類が挙げられる。さらに、グリチルリチン酸塩類、グリチルレチン酸塩、サリチル酸塩、トラネキサム酸塩、ニコチン酸アミド、コウジ酸、尿素、ミョウバン等が挙げられ、さらには海洋深層水、温泉水等、これら電解質を含む天然由来の水溶液も挙げられる。これらは必要に応じて、配合目的に合わせて1種又は2種以上を組み合わせて用いる事が出来る。 The component (E) electrolyte used in the present invention is a substance that makes the solution electrically conductive when dissolved in water or other solvent, and is a beauty active ingredient such as a whitening agent and an anti-inflammatory agent. As a moisturizer, a pH adjuster, an ultraviolet protective agent, etc., any organic or inorganic material usually used in cosmetics can be used. Specifically, organic compounds such as amino acids, lactic acid, citric acid and pyrrolidone carboxylic acid, metal salts such as potassium, sodium, magnesium and calcium, inorganic salts such as sodium chloride and magnesium chloride, L-alanine and β. -Alanine, L-arginine, L-arginine hydrochloride, L-aspartin monohydrate, L-aspartic acid, polyaspartic acid, L-citrulin, L-cysteine, L-cysteine hydrochloride monohydrate, L- Cistine, L-dopa, L-glutamic acid, L-glutamine acid salt, L-glutamine, polyglutamic acid, glycine, trimethylglycine, L-histidine, L-histidine hydrochloride monohydrate, L-hydroxyproline, L-isoleucine , L-leucine, L-lysine, L-lysine hydrochloride, L-methionine, L-ornithine hydrochloride, L-proline, L-phenylalanine, L-serine, L-threonine, L-tryptophane, L-tyrosine, L -Amino acids such as valine and derivatives and salts thereof, and water-soluble ascorbic acids such as ascorbic acid, ascorbic acid phosphate ester, ascorbic acid sulfate ester, ascorbic acid glucoside and their metal salts such as sodium, potassium, magnesium and calcium. Can be mentioned. Further, glycyrrhizinates, glycyrrhetinate, salicylate, tranexamate, nicotinic acid amide, kodiic acid, urea, myoban and the like can be mentioned, and further, naturally derived aqueous solutions containing these electrolytes such as deep sea water and hot spring water. Can also be mentioned. These can be used alone or in combination of two or more, depending on the purpose of blending, if necessary.
本発明における成分(E)の含有量は、特に限定されず、配合目的により、適宜調整することができる。
本発明においては、電解質の含有状態を、水中油型乳化化粧料の電気伝導率で示すことができ、後肌のやわらかさと長期安定性の観点から、25℃における電気伝導率が0.01〜2S/mであることが好ましい。なお、電気伝導率は、TOA社製 EC METER CM−60Gにて測定した。
The content of the component (E) in the present invention is not particularly limited and can be appropriately adjusted depending on the purpose of blending.
In the present invention, the content state of the electrolyte can be indicated by the electric conductivity of the oil-in-water emulsified cosmetic, and from the viewpoint of the softness of the back skin and long-term stability, the electric conductivity at 25 ° C. is 0.01 to It is preferably 2 S / m. The electrical conductivity was measured with EC METER CM-60G manufactured by TOA Corp.
本発明の水中油型乳化化粧料には、上記成分(A)〜(E)以外に、水相を構成する成分として水及び多価アルコール、低級アルコール等の水性成分、あるいは通常の水中油型乳化化粧料に使用される成分を、本発明の効果を損なわない範囲で適宜、含有することができる。例えば、成分(C)以外の油剤、成分(A)、(B)以外の界面活性剤、成分(D)以外の水溶性高分子、成分(E)以外の紫外線吸収剤、抗酸化剤、抗菌剤、防腐剤、保湿剤、pH調整剤、清涼剤、粉体、ビタミン類、美容成分、香料等を含有することができる。 In the oil-in-water emulsified cosmetic of the present invention, in addition to the above components (A) to (E), water and aqueous components such as polyhydric alcohol and lower alcohol, or ordinary oil-in-water type as components constituting the aqueous phase Ingredients used in emulsified cosmetics can be appropriately contained as long as the effects of the present invention are not impaired. For example, an oil agent other than the component (C), a surfactant other than the component (A) and (B), a water-soluble polymer other than the component (D), an ultraviolet absorber other than the component (E), an antioxidant, and an antibacterial agent. It can contain agents, preservatives, moisturizers, pH adjusters, refreshing agents, powders, vitamins, beauty ingredients, fragrances and the like.
本発明の水中油型乳化化粧料の製造方法は、特に限定されず、常法により調製される。例えば、成分(A)〜(C)と必要に応じてその他成分を加熱溶解したものを、均一に溶解混合した成分(D)、(E)に添加混合し、さらに必要に応じて上記任意成分を加え、これを混合することにより調製する方法が挙げられる。 The method for producing the oil-in-water emulsified cosmetic of the present invention is not particularly limited, and is prepared by a conventional method. For example, the components (A) to (C) and other components that have been heat-dissolved as needed are added and mixed with the components (D) and (E) that have been uniformly dissolved and mixed, and if necessary, the above optional components are added and mixed. Is added, and a method of preparing by mixing this can be mentioned.
本発明の水中油型乳化化粧料は、液状、ジェル状、乳液状、クリーム状等の種々の形態で実施することが可能であり、特に限定されるものではない。 The oil-in-water emulsified cosmetic of the present invention can be carried out in various forms such as liquid, gel, milky, cream and the like, and is not particularly limited.
また本発明の水中油型乳化化粧料は、皮膚用の化粧料として利用可能であり、例えば、化粧水、乳液、クリーム、美容液、マッサージ料、パック料、ハンドクリーム、ボディローション、ボディクリーム、日焼け止め料、ファンデーション、アイシャドウ、アイライナー、コンシーラー、頭皮用トリートメント等を例示することができる。浸透感の良さを実感できるという点では、スキンケア化粧料が好ましく、その使用方法は、手や指、コットンで使用する方法、不織布等に含浸させて使用する方法、直接噴霧して使用する方法等が挙げられる。 The oil-in-water emulsified cosmetic of the present invention can be used as a cosmetic for the skin, for example, a lotion, a milky lotion, a cream, a beauty essence, a massage agent, a pack, a hand cream, a body lotion, and a body cream. Examples include sunscreens, foundations, eye shadows, eye liners, concealers, scalp treatments and the like. Skin care cosmetics are preferable in that you can feel the good penetration, and the methods of use are methods such as using with hands, fingers, cotton, impregnating with non-woven fabric, etc., and using by spraying directly. Can be mentioned.
以下、本発明を具体的に説明するために実施例を挙げるが、本発明はこれらの実施例等に限定されるものではない。また、含有量は、特記しない限り、その成分が含有される組成物に対する質量%で示す。 Hereinafter, examples will be given to specifically explain the present invention, but the present invention is not limited to these examples and the like. Further, unless otherwise specified, the content is shown in mass% with respect to the composition containing the component.
実施例1〜14び比較例1〜8:美容液
表1に示す組成の美容液を下記の製造方法により製造し、イ:浸透感、ロ:後肌のやわらかさ、ハ:長期安定性について、以下に示す方法により評価判定した。結果を併せて表1に示す。また、実施例の電気伝導率の測定結果は、0.05〜3S/mであった。
Examples 1 to 14 and Comparative Examples 1 to 8: Beauty essence The beauty essence having the composition shown in Table 1 was produced by the following production method. , The evaluation was made by the method shown below. The results are also shown in Table 1. The measurement result of the electric conductivity of the example was 0.05 to 3 S / m.
(製造方法)
A:成分(1)〜(8)を75℃で均一に加熱溶解した。
B:成分(9)〜(17)を75℃で均一に加熱溶解した。
C:75℃にてAにBを添加し乳化した後、室温まで撹拌冷却して美容液を得た。
(Production method)
A: Ingredients (1) to (8) were uniformly heated and dissolved at 75 ° C.
B: Ingredients (9) to (17) were uniformly heated and dissolved at 75 ° C.
C: B was added to A at 75 ° C., emulsified, and then stirred and cooled to room temperature to obtain a beauty essence.
(評価方法1)
20代〜40代の女性で官能評価の訓練を受け、一定の基準で評価が可能な専門パネルを10名選定した。該専門パネルは、前腕に各試料を使用し、それぞれについて、使用時に感じる浸透感、後肌のやわらかさを、下記絶対評価にて5段階に評価し評点を付けた。各試料ごとにパネル全員の評点合計から、その平均値を算出し、下記4段階判定基準により判定した。
(Evaluation method 1)
Women in their 20s to 40s were trained in sensory evaluation, and 10 specialized panels that could be evaluated according to certain criteria were selected. The specialized panel used each sample for the forearm, and evaluated the permeation feeling and the softness of the back skin felt at the time of use on a five-point scale by the following absolute evaluation and gave a score. The average value was calculated from the total score of all the panels for each sample, and the judgment was made according to the following four-step judgment criteria.
(イ:浸透感)
<絶対評価基準>
(評点):(評価)
5点:肌への浸透感があると感じる
4点:肌への浸透感があるとやや感じる
3点:普通
2点:肌への浸透感があるとあまり感じない
1点:肌への浸透感があると感じない
<4段階判定基準>
(判定):(評点の平均点)
◎ :4.5点を超える :非常に良好
○ :3.5点を超える4.5点以下:良好
△ :1.5点を超える3.5点以下:やや不良
× :1.5点以下 :不良
(A: Penetration)
<Absolute evaluation criteria>
(Score): (Evaluation)
5 points: I feel that there is a feeling of penetration into the skin 4 points: I feel a little if there is a feeling of penetration into the skin 3 points: Normal 2 points: I do not feel much if there is a feeling of penetration into the skin 1 point: I feel that there is a feeling of penetration into the skin I don't feel it <4 grade criteria>
(Judgment): (Average score)
◎: More than 4.5 points: Very good ○: More than 3.5 points and less than 4.5 points: Good △: More than 1.5 points and less than 3.5 points: Slightly poor ×: More than 1.5 points : Bad
(ロ:後肌のやわらかさ)
<絶対評価基準>
(評点):(評価)
5点:やわらかいと感じる
4点:やややわらかいと感じる
3点:普通
2点:あまりやわらかく感じない
1点:やわらかいと感じない
<4段階判定基準>
(判定):(評点の平均点)
◎ :4.5点を超える :非常に良好
○ :3.5点を超える4.5点以下:良好
△ :1.5点を超える3.5点以下:やや不良
× :1.5点以下 :不良
(B: Softness of the back skin)
<Absolute evaluation criteria>
(Score): (Evaluation)
5 points: Feels soft 4 points: Feels soft 3 points: Normal 2 points: Does not feel very soft 1 point: Does not feel soft <4 grade criteria>
(Judgment): (Average score)
◎: More than 4.5 points: Very good ○: More than 3.5 points and less than 4.5 points: Good △: More than 1.5 points and less than 3.5 points: Slightly poor ×: More than 1.5 points : Bad
(評価方法2)
(ハ:長期安定性)
各試料を40℃の恒温槽に入れて、6ヶ月後の外観(乳化物の均一度合)を目視にて観察し、以下の判定基準にて判定した。
<判定基準>
(判定):(評価)
◎ :全くクリーミングしていない(乳化物が均一で濃淡がない)
○ :ごくわずかにクリーミングしている
△ :かなりクリーミングしている
× :著しくクリーミングしている
(Evaluation method 2)
(C: Long-term stability)
Each sample was placed in a constant temperature bath at 40 ° C., and the appearance (uniformity of emulsion) after 6 months was visually observed and judged according to the following criteria.
<Criteria>
(Judgment): (Evaluation)
◎: No creaming at all (emulsion is uniform and has no shading)
○: Very slightly creaming △: Very creaming ×: Remarkably creaming
表1の結果から明らかなように、実施例1〜14の美容液は、比較例1〜8の美容液に比べ、浸透感、後肌のやわらかさ、長期安定性において優れたものであった。
一方、成分(A)を含有しない比較例1は、浸透感および長期安定性において劣っていた。また、成分(B)を含有しない比較例2においても、比較例1と同様の結果であった。成分(C)に代えて他の油剤を配合した比較例3〜6は、化粧料が肌に浸透しにくく、浸透感および後肌のやわらかさが十分でなかった。成分(D)に代えてキサンタンガムを配合した比較例7、ヒアルロン酸ナトリウムを配合した比較例8は、化粧料が肌になじむまでに時間がかかり浸透感に劣るとともに、肌上に残る化粧膜が薄く保湿効果に乏しいために、後肌のやわらかさが十分でなかった。さらには、乳化滴の合一・分離が進み、長期安定性においても満足のいくものが得られなかった。
As is clear from the results in Table 1, the beauty essences of Examples 1 to 14 were superior to the beauty essences of Comparative Examples 1 to 8 in terms of penetration, softness of the back skin, and long-term stability. ..
On the other hand, Comparative Example 1 containing no component (A) was inferior in permeation and long-term stability. Further, in Comparative Example 2 containing no component (B), the same result as in Comparative Example 1 was obtained. In Comparative Examples 3 to 6 in which another oil agent was blended in place of the component (C), the cosmetics did not easily penetrate into the skin, and the permeation feeling and the softness of the back skin were not sufficient. In Comparative Example 7 in which xanthan gum was blended instead of component (D) and Comparative Example 8 in which sodium hyaluronate was blended, it took time for the cosmetic to blend into the skin, resulting in poor penetration and a cosmetic film remaining on the skin. Due to its thinness and poor moisturizing effect, the softness of the back skin was not sufficient. Furthermore, the coalescence and separation of the emulsified droplets proceeded, and no satisfactory long-term stability was obtained.
実施例15:ジェル状乳液
(成分) (%)
(1) ポリオキシエチレン硬化ヒマシ油 ※6 4.5
(2) テトラオレイン酸ポリオキシエチレンソルビット ※7 0.5
(3) オクチルドデカノール 1
(4) デシルテトラデカノール 1
(5) オレイン酸フィトステリル ※8 2
(6) 精製水 残量
(7) ジェランガム ※5 0.025
(8) アクリル酸・メタクリル酸アルキル共重合体 ※9 0.14
(9) アクリル酸ナトリウム・アクリロイルジメチルタウリン酸ナトリウム
共重合体混合物 ※10 0.24
(10)カルボキシビニルポリマー 0.1
(11)カルボキシメチルセルロースナトリウム ※11 0.1
(12)1,3―ブチレングリコール 15
(13)エタノール 5
(14)グリセリン 0.5
(15)ポリオキシエチレンメチルグルコシド ※12 5
(16)PEG−400 0.1
(17)トラネキサム酸 2
(18)ピロ亜硫酸ナトリウム 0.003
(19)水酸化ナトリウム 0.076
(20)リン酸一水素ナトリウム 0.1
(21)リン酸二水素ナトリウム 0.1
※6:NIKKOL HCO−40 (日光ケミカルズ社製)
※7:NIKKOL GO−460NV (日光ケミカルズ社製)
※8:プランドゥール SUN (日本精化社製)
※9:AQUPEC HV−803ERK (住友精化社製)
※10:SIMULGEL EG QD (SEPPICS.A.社製)
※11:CEKOL (CPケルコ社製)
※12:マクビオブライドMG−10E (日油社製)
Example 15: Gel-like emulsion (ingredient) (%)
(1) Polyoxyethylene hydrogenated castor oil * 6 4.5
(2) Polyoxyethylene sorbitol tetraoleate * 7 0.5
(3) Octyldodecanol 1
(4) Decyltetradecanol 1
(5) Phytosteryl oleate * 8 2
(6) Remaining amount of purified water (7) Gellan gum * 5 0.025
(8) Acrylic acid / alkyl methacrylate copolymer * 9 0.14
(9) Sodium acrylate / sodium acryloyldimethyltaurate copolymer mixture * 10 0.24
(10) Carboxyvinyl polymer 0.1
(11) Sodium Carboxymethyl Cellulose * 11 0.1
(12) 1,3-butylene glycol 15
(13) Ethanol 5
(14) Glycerin 0.5
(15) Polyoxyethylene methylglucoside * 125
(16) PEG-400 0.1
(17) Tranexamic acid 2
(18) Sodium metabisulfite 0.003
(19) Sodium hydroxide 0.076
(20) Sodium monohydrogen phosphate 0.1
(21) Sodium dihydrogen phosphate 0.1
* 6: NIKKOL HCO-40 (manufactured by Nikko Chemicals Co., Ltd.)
* 7: NIKKOL GO-460NV (manufactured by Nikko Chemicals Co., Ltd.)
* 8: Prandour SUN (manufactured by Nippon Fine Chemical Co., Ltd.)
* 9: AQUAPEC HV-803ERK (manufactured by Sumitomo Seika)
* 10: SIMULGEL EG QD (manufactured by SEPPICS.A.)
* 11: CEKOL (manufactured by CP Kelco)
* 12: McBiobride MG-10E (manufactured by NOF CORPORATION)
(製造方法)
A:成分(1)〜(5)を75℃で均一に加熱溶解した。
B:成分(6)〜(11)を75℃に加熱した。
C:成分(12)〜(21)を75℃で均一に加熱溶解した後、35℃に冷却した。
D:75℃にてAにBを添加し乳化した後に35℃まで冷却した。
E:DにCを添加し、撹拌することでジェル状乳液を得た。
以上のようにして得られたジェル状乳液の電気伝導率は0.1S/mであり、浸透感、後肌のやわらかさ、長期安定性に優れるものであった。
(Production method)
A: Ingredients (1) to (5) were uniformly heated and dissolved at 75 ° C.
B: Ingredients (6) to (11) were heated to 75 ° C.
C: Ingredients (12) to (21) were uniformly heated and dissolved at 75 ° C., and then cooled to 35 ° C.
D: B was added to A at 75 ° C., emulsified, and then cooled to 35 ° C.
E: C was added to D and stirred to obtain a gel emulsion.
The gel-like emulsion obtained as described above had an electrical conductivity of 0.1 S / m, and was excellent in permeation, softness of the back skin, and long-term stability.
実施例16:美容液
(成分) (%)
(1) ポリオキシエチレン硬化ヒマシ油 ※1 0.3
(2) ポリオキシエチレン硬化ヒマシ油 ※6 0.2
(3) テトラオレイン酸ポリオキシエチレンソルビット ※2 0.1
(4) ポリオキシエチレンコレステリルエーテル ※13 0.1
(5) オクチルドデカノール 0.5
(6) d−δ−トコフェロール 0.1
(7) シクロヘキサンジカルボン酸ビスエトキシジグリコール 0.1
(8) スクワラン 0.5
(9) 精製水 残量
(10)ジェランガム ※14 0.05
(11)キサンタンガム ※5 0.2
(12)1,3―ブチレングリコール 15
(13)グリセリン 5
(14)ジグリセリン 1
(15)エタノール 10
(16)エデト酸二ナトリウム 0.01
(17)ヒアルロン酸ナトリウム 0.01
(18)クエン酸 0.1
(19)リン酸一水素ナトリウム 0.3
(20)チオ硫酸ナトリウム 0.05
(21)コメ発酵液 ※15 30
※13:EMALEX CS−24 (日光ケミカルズ社製)
※14:KELCOGEL CG−HA (CPケルコ社製)
※15:コメエキスコーケン BG (高研社製)
Example 16: Essence (ingredient) (%)
(1) Polyoxyethylene hydrogenated castor oil * 1 0.3
(2) Polyoxyethylene hydrogenated castor oil * 6 0.2
(3) Polyoxyethylene sorbitol tetraoleate * 2 0.1
(4) Polyoxyethylene cholesteryl ether * 13 0.1
(5) Octyldodecanol 0.5
(6) d-δ-tocopherol 0.1
(7) Cyclohexanedicarboxylic acid bisethoxydiglycol 0.1
(8) Squalene 0.5
(9) Remaining amount of purified water (10) Gellan gum * 14 0.05
(11) Xanthan gum * 5 0.2
(12) 1,3-butylene glycol 15
(13) Glycerin 5
(14) Diglycerin 1
(15) Ethanol 10
(16) Disodium edetate 0.01
(17) Sodium hyaluronate 0.01
(18) Citric acid 0.1
(19) Sodium monohydrogen phosphate 0.3
(20) Sodium thiosulfate 0.05
(21) Fermented rice liquid * 15 30
* 13: EMALEX CS-24 (manufactured by Nikko Chemicals Co., Ltd.)
* 14: KELCOGEL CG-HA (manufactured by CP Kerco)
* 15: Rice extract Koken BG (manufactured by Kokensha)
(製造方法)
A:成分(1)〜(8)を75℃で均一に加熱溶解した。
B:成分(9)〜(11)を75℃に加熱した。
C:成分(12)〜(21)を75℃で均一に加熱溶解した後、35℃に冷却した。
D:75℃にてAにBを添加し乳化した後に35℃まで冷却した。
E:DにCを添加し、撹拌することでジェル状乳液を得た。
以上のようにして得られた美容液の電気伝導率は0.3S/mであり、浸透感、後肌のやわらかさ、長期安定性に優れるものであった。
(Production method)
A: Ingredients (1) to (8) were uniformly heated and dissolved at 75 ° C.
B: Ingredients (9) to (11) were heated to 75 ° C.
C: Ingredients (12) to (21) were uniformly heated and dissolved at 75 ° C., and then cooled to 35 ° C.
D: B was added to A at 75 ° C., emulsified, and then cooled to 35 ° C.
E: C was added to D and stirred to obtain a gel emulsion.
The electrical conductivity of the beauty essence obtained as described above was 0.3 S / m, and it was excellent in permeation, softness of the back skin, and long-term stability.
実施例17:ゲル状化粧水
(成分) (%)
(1) ポリオキシエチレン硬化ヒマシ油 ※16 0.05
(2) テトラオレイン酸ポリオキシエチレンソルビット ※17 0.03
(3) ポリオキシエチレンアルキル(12〜15)エーテルリン酸
(8E.O.) 0.01
(4)セトステアリルアルコール 0.001
(5)オクチルドデカノール 0.02
(6)オレイン酸エチル 0.01
(7)トリイソステアリン酸トリメチロールプロパン 0.01
(8)精製水 残量
(9)ジェランガム ※4 0.15
(10)キサンタンガム ※5 0.02
(11)1,3―ブチレングリコール 12
(12)ジプロピレングリコール 5
(13)グリセリン 1
(14)ポリオキシブチレンポリオキシエチレンポリオキシプロピレングリセリル
エーテル(3B.O.)(8E.O.)(5P.O.) 8
(15)L−アスコルビン酸2−グルコシド 2
(16)コハク酸 0.4
(17)コハク酸二ナトリウム 0.05
(18)水酸化ナトリウム 0.315
(19)エデト酸二ナトリウム 0.1
※16:NIKKOL HCO−60 (日光ケミカルズ社製)
※17:NIKKOL GO−440NV (日光ケミカルズ社製)
Example 17: Gel-like lotion (ingredient) (%)
(1) Polyoxyethylene hydrogenated castor oil * 16 0.05
(2) Polyoxyethylene sorbitol tetraoleate * 17 0.03
(3) Polyoxyethylene alkyl (12 to 15) ether phosphoric acid (8EO) 0.01
(4) Setostearyl alcohol 0.001
(5) Octyldodecanol 0.02
(6) Ethyl oleate 0.01
(7) Trimethylolpropane triisostearate 0.01
(8) Remaining amount of purified water (9) Gellan gum * 4 0.15
(10) Xanthan gum * 5 0.02
(11) 1,3-butylene glycol 12
(12) Dipropylene glycol 5
(13) Glycerin 1
(14) Polyoxybutylene polyoxyethylene polyoxypropylene glyceryl ether (3BO) (8EO) (5PO) 8
(15) L-ascorbic acid 2-glucoside 2
(16) Succinic acid 0.4
(17) Disodium succinate 0.05
(18) Sodium hydroxide 0.315
(19) Disodium edetate 0.1
* 16: NIKKOL HCO-60 (manufactured by Nikko Chemicals Co., Ltd.)
* 17: NIKKOL GO-440NV (manufactured by Nikko Chemicals Co., Ltd.)
(製造方法)
A:成分(1)〜(7)を75℃で均一に加熱溶解した。
B:成分(8)〜(10)を75℃に加熱した。
C:成分(11)〜(19)を75℃で均一に加熱溶解した後、35℃に冷却した。
D:75℃にてAにBを添加し乳化した後に35℃まで冷却した。
E:DにCを添加し、撹拌することでゲル状化粧水を得た。
以上のようにして得られたゲル状化粧水の電気伝導率は0.8S/mであり、浸透感、後肌のやわらかさ、長期安定性に優れるものであった。
(Production method)
A: Ingredients (1) to (7) were uniformly heated and dissolved at 75 ° C.
B: Ingredients (8) to (10) were heated to 75 ° C.
C: Ingredients (11) to (19) were uniformly heated and dissolved at 75 ° C., and then cooled to 35 ° C.
D: B was added to A at 75 ° C., emulsified, and then cooled to 35 ° C.
E: C was added to D and stirred to obtain a gel lotion.
The electric conductivity of the gel-like lotion obtained as described above was 0.8 S / m, and it was excellent in permeation, softness of the back skin, and long-term stability.
Claims (2)
(A)HLB10〜15のポリオキシエチレン硬化ヒマシ油
(B)HLB10〜15のポリオキシエチレンソルビット脂肪酸エステル
(C)25℃において液状の極性油
(D)ジェランガム
(E)電解質
を含有する水中油型乳化化粧料。 The following components (A) to (E):
(A) Polyoxyethylene hydrogenated castor oil of HLB10 to 15 (B) Polyoxyethylene sorbit fatty acid ester of HLB10 to 15 (C) Liquid polar oil at 25 ° C. Oil type in water containing gellan gum (E) electrolyte Esterized cosmetics.
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