JP2021161567A - Fabric for protective products and textile product using the same - Google Patents

Fabric for protective products and textile product using the same Download PDF

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JP2021161567A
JP2021161567A JP2020064797A JP2020064797A JP2021161567A JP 2021161567 A JP2021161567 A JP 2021161567A JP 2020064797 A JP2020064797 A JP 2020064797A JP 2020064797 A JP2020064797 A JP 2020064797A JP 2021161567 A JP2021161567 A JP 2021161567A
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spun yarn
glove
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JP7489749B2 (en
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薫 巽
Kaoru Tatsumi
和義 吉田
Kazuyoshi Yoshida
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Du Pont Toray Co Ltd
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Abstract

To provide a fabric for a protective product which is excellent in cut resistance, lightweightness, ease of attachment, and washing resistance and is suitable as an inner protective material such as an inner glove, and to provide a textile product using the same.SOLUTION: There are provided a fabric for protective products made by using a spun yarn containing aramid fibers, which has a thickness of 1.0 mm or less measured according to JIS L 1096 8.4 method, and has a thickness change rate of ±5% or less after 5 times of washing treatment by flat drying according to JIS L 0217-103 method, and whose dimensional change rate in the vertical direction and the horizontal direction after 5 times of washing treatment is ±5% or less as well as textile products using the fabric for protective products such as an inner glove, an inner wear, a wrist guard, an arm cover, and a sock.SELECTED DRAWING: None

Description

本発明は、防護製品用布帛及びそれを用いた繊維製品に関する。 The present invention relates to a fabric for a protective product and a textile product using the same.

アラミド繊維等の耐切創性繊維で製造される手袋、アームカバー、前掛け等の防護製品は、当該繊維が刃物で切断されにくいので、綿やウーリーナイロン等の繊維で製造される防護製品に比べて耐切創性が画期的に高い。そのため、バリの出た板金加工品を扱う作業、割れ易いガラス製品を扱う作業、あるいは金属片やガラス片が混入している可能性のある一般塵芥を扱うゴミ収集作業等、切創事故を起こし易い作業において作業者の手や体を保護するために広く使用されてきた。しかし、当該作業者等から、より一層安全な防護製品が強く要望されている。例えば防護手袋を着用する場合は、一般的に該手袋を1枚装着して作業する場合が多く、作業内容によってさらなる耐切創性が必要となり、かつ汚れ等による手袋交換が必要になることから、軍手タイプの手袋の上に、同タイプの手袋、革製の縫製手袋あるいはゴム製手袋等を重ね履きすることが多い。そのため、軽量かつ装着性(重ね履きし易いこと)及び着用感(作業し易いこと)の良いものが望まれている。 Protective products such as gloves, arm covers, and apron made of cut-resistant fibers such as aramid fibers are less likely to be cut by blades, so they are compared to protective products made of fibers such as cotton and woolly nylon. Remarkably high cut resistance. As a result, cut accidents occur, such as work with processed sheet metal products with burrs, work with fragile glass products, or work with garbage collection that handles general dust that may contain metal pieces or glass pieces. It has been widely used to protect the hands and body of workers in easy work. However, there is a strong demand for safer protective products from the workers and the like. For example, when wearing protective gloves, in general, one piece of the gloves is often worn for work, and further cut resistance is required depending on the work content, and gloves need to be replaced due to dirt or the like. Often, gloves of the same type, leather sewn gloves, rubber gloves, etc. are layered on top of work gloves. Therefore, those that are lightweight, easy to wear (easy to wear in layers), and comfortable to wear (easy to work) are desired.

一方、農作業、園芸、軽作業、調理作業等では、綿糸やウーリーナイロン等の繊維で製造される手袋等の繊維製品は、装着性が良いことに加えて通気性もよく、装着しての作業における蒸れ感等も軽減できるため、重ね履きの際のインナー手袋として適している。しかし、洗濯後の寸法変化が非常に大きいため、再使用した際の装着性及び着用感が著しく悪化する。また、耐切創性及び耐熱性等の機能がアラミド繊維に比べて著しく劣る。 On the other hand, in agricultural work, horticulture, light work, cooking work, etc., textile products such as gloves made of fibers such as cotton thread and woolly nylon are not only easy to wear but also have good breathability, so they are worn. It is suitable as an inner glove when wearing layers because it can reduce the feeling of stuffiness. However, since the dimensional change after washing is very large, the wearability and the wearing feeling when reused are remarkably deteriorated. In addition, functions such as cut resistance and heat resistance are significantly inferior to those of aramid fibers.

ところが、一般に、アラミド繊維等の高強力繊維は、耐切創性に優れている一方で剛性が高いためにごわごわ感があり、切創性と装着性は相互に取り合いの関係にある。 However, in general, high-strength fibers such as aramid fibers have excellent cut resistance but are stiff due to their high rigidity, and cutability and wearability are in a mutually competing relationship.

また、作業用手袋や作業衣等においては、着用者に作業の妨げとなる疲労感や不快感を与えることは好ましくなく、止むを得ない場合でもこれらは許される最小程度でなければならない。耐切創性が優れていても、手袋等の防護製品では、硬い繊維端の刺激はチクチク感のような不快感を着用者に与えるため、チクチク感が少なく、耐切創性、装着性に優れる防護製品を工業的に生産することは極めて重要なことである。 Further, in work gloves, work clothes, etc., it is not preferable to give the wearer a feeling of fatigue or discomfort that hinders the work, and even if it is unavoidable, these must be the minimum allowed. Even if it has excellent cut resistance, in protective products such as gloves, irritation of hard fiber ends gives the wearer a discomfort such as a tingling sensation, so there is less tingling sensation, and protection with excellent cut resistance and wearability. Industrial production of products is extremely important.

アラミド繊維は一般に、単糸繊度が大きくなるにつれ切断されにくくなるため、防護布帛の耐切創性向上には単糸繊度を大きくすることが有効と考えられてきた。特許文献1には、単糸繊度3.9〜4.4dtexのアラミド短繊維からなる綿番手20番の紡績糸双糸を用いることで、単糸繊度1.7dtexの従来品よりも耐切創性が改善されることが示されている。しかし、綿番手20番のアラミド紡績糸を7ゲージの手袋編み機に供給して編み上げた手袋は、重量60g/双、甲部掌部あわせて厚さ4.0mmであるため、軽量性、重ね履きの際の装着性の点で課題があり、インナー手袋には不向きである。 Since aramid fibers are generally less likely to be cut as the single yarn fineness increases, it has been considered effective to increase the single yarn fineness in order to improve the cut resistance of the protective fabric. In Patent Document 1, by using a spun yarn twin yarn having a cotton count of 20 made of aramid short fibers having a single yarn fineness of 3.9 to 4.4 dtex, the cut resistance is higher than that of a conventional product having a single yarn fineness of 1.7 dtex. Has been shown to improve. However, the gloves knitted by supplying aramid spun yarn with a cotton count of 20 to a 7-gauge glove knitting machine weighs 60 g / pair and the total thickness of the instep palm is 4.0 mm, so it is lightweight and can be worn in layers. There is a problem in terms of wearability at the time, and it is not suitable for inner gloves.

特許文献2には、繰り返しの使用や洗濯による毛羽の発生、脱落がない手袋として、ゴム手袋の内面に伸縮性のあるストレッチ素材からなる超薄繊維シートを接合させたゴム手袋が提案されているが、ゴム手袋は、装着している使用者に蒸れ感等による不快感を与えるため、インナー手袋には不向きである。また、特許文献3には、メタ系アラミド繊維紡績糸とウール紡績糸を72/28の比率で用いた糸を10ゲージ手袋編機で編成した薄手インナー手袋が開示されているが、重さが30g/双あるため、軽量性、装着性の点で課題がある。さらに、特許文献4には、作業性、フィット感の良い薄手の編み手袋を得るために、細いデニール(10〜100デニール)の糸を使用して、ゲージ数が20〜32ゲージの経編機で編成した編み手袋に、エラストマーや樹脂の滑り止めを施した手袋が開示されているが、コーティングが施されているため、洗濯して繰り返し使用される手袋ではない。 Patent Document 2 proposes a rubber glove in which an ultra-thin fiber sheet made of an elastic stretch material is bonded to the inner surface of the rubber glove as a glove that does not generate fluff or fall off due to repeated use or washing. However, rubber gloves are not suitable for inner gloves because they give the wearing user a feeling of discomfort due to stuffiness and the like. Further, Patent Document 3 discloses a thin inner glove in which a yarn using a meta-aramid fiber spun yarn and a wool spun yarn at a ratio of 72/28 is knitted by a 10 gauge glove knitting machine, but the weight is heavy. Since it weighs 30 g / pair, there are problems in terms of lightness and wearability. Further, Patent Document 4 describes a warp knitting machine having a gauge number of 20 to 32 gauge using a fine denier (10 to 100 denier) yarn in order to obtain a thin knitted glove with good workability and fit. Although a glove with an elastomer or resin anti-slip is disclosed for the knitted glove knitted in, it is not a glove that is washed and used repeatedly because it is coated.

したがって、耐切創性、軽量性、装着性及び耐洗濯性を兼ね備えた防護製品用布帛は現状得られていない。 Therefore, a cloth for a protective product having cut resistance, light weight, wearability and washing resistance has not been obtained at present.

特開平9−157981号公報Japanese Unexamined Patent Publication No. 9-157981 特開2011−127265号公報Japanese Unexamined Patent Publication No. 2011-127265 特開2010−203012号公報JP-A-2010-203012 再公表2016−208694号公報Republished 2016-208694

本発明は、かかる従来技術の背景に鑑み、耐切創性、軽量性、装着性及び耐洗濯性に優れる、インナー手袋等のインナー防護材として好適である防護製品用布帛、及びそれを用いた繊維製品を提供せんとするものである。 In view of the background of the prior art, the present invention is a cloth for a protective product which is excellent in cut resistance, light weight, wearability and washing resistance and is suitable as an inner protective material such as an inner glove, and a fiber using the same. It is intended to provide products.

本発明は、かかる課題を解決するために、次の手段を採用するものである。すなわち、本発明は、以下の通りである。 The present invention employs the following means in order to solve such a problem. That is, the present invention is as follows.

(1)アラミド繊維を含む紡績糸を用いてなる布帛であって、
JIS L 1096 8.4法に準じて測定される厚みが1.0mm以下であり、
JIS L 0217−103法平干し乾燥 による洗濯処理5回後の厚み変化率が±5%以下であり、かつ、前記洗濯処理5回後のたて方向及びよこ方向における寸法変化率が±5%以下であることを特徴とする防護製品用布帛。
(2)前記紡績糸が、単繊維数100本以下/単糸で構成される前記(1)に記載の防護製品用布帛。
(3)前記紡績糸が、英国式綿番手40番ないし70番の単糸又は双糸である前記(1)又は(2)に記載の防護製品用布帛。
(4)前記布帛が編物であり、該編物を編成するよこ編機のゲージ数が15ゲージ〜21ゲージである前記(1)〜(3)いずれかに記載の防護製品用布帛。
(5)前記(1)〜(4)いずれかに記載の防護製品用布帛を用いてなる、インナー手袋、インナーウエア、リストガード、アームカバー及び靴下からなる群から選択されるいずれかの繊維製品。
(6)繊維製品がインナー手袋であり、断熱性あるいは低発塵性のアウター手袋、又は、革製、天然繊維製あるいはアラミド繊維製のアウター手袋に対する、インナー手袋として用いられる前記(5)に記載の繊維製品。
(1) A fabric made of spun yarn containing aramid fibers.
The thickness measured according to the JIS L 1096 8.4 method is 1.0 mm or less.
JIS L 0217-103 method The rate of change in thickness after 5 washing treatments by flat-drying is ± 5% or less, and the rate of dimensional change in the vertical and horizontal directions after 5 times of washing treatment is ± 5%. A cloth for a protective product, which is characterized by the following.
(2) The cloth for protective products according to (1) above, wherein the spun yarn is composed of 100 or less single fibers / single yarn.
(3) The cloth for protective products according to (1) or (2) above, wherein the spun yarn is a single yarn or a twin yarn having an English cotton count of 40 to 70.
(4) The cloth for a protective product according to any one of (1) to (3) above, wherein the cloth is a knit, and the number of gauges of the weft knitting machine for knitting the knit is 15 gauge to 21 gauge.
(5) Any textile product selected from the group consisting of inner gloves, inner wear, wrist guards, arm covers and socks, which are made of the cloth for protective products according to any one of (1) to (4) above. ..
(6) The above-mentioned (5), wherein the textile product is an inner glove, which is used as an inner glove for an outer glove having heat insulation or low dust generation, or an outer glove made of leather, natural fiber or aramid fiber. Textile products.

本発明によれば、単繊維本数が少ない(綿番手が大きい)アラミド繊維紡績糸を用いることにより、薄型でありながら、綿やナイロンとは異なり、複数回洗濯しても布帛の厚み及び寸法の変化率が非常に小さい防護製品用布帛を提供できる。該布帛は、軽量性、装着性(手袋の重ね履き性)、耐切創性に優れているため、インナー手袋等の繊維製品として好適である。紡績糸の繊度が小さいため、よこ編機のゲージ数が15ゲージ以上のハイゲージ手袋を提供できる。 According to the present invention, by using the aramid fiber spun yarn having a small number of single fibers (large cotton count), although it is thin, unlike cotton and nylon, the thickness and dimensions of the fabric can be increased even if it is washed multiple times. It is possible to provide a fabric for a protective product having a very small rate of change. The fabric is suitable as a textile product such as inner gloves because it is excellent in light weight, wearability (glove layering property), and cut resistance. Due to the low fineness of the spun yarn, it is possible to provide high gauge gloves having a weft knitting machine having a gauge of 15 gauge or more.

本発明の防護製品用布帛は、耐熱性に優れているため、アウター手袋が断熱手袋や低発塵手袋である場合に、耐切創性インナー手袋として効果的に使用できる。
また、本発明の防護製品用布帛は、耐切創性に優れているため、アウター手袋が革製手袋や綿・麻・絹等の天然繊維製手袋である場合にインナー手袋として重ね履きすることにより、アウター手袋の欠点を補填することができる。
また、本発明の防護製品用布帛は、耐洗濯性に優れている(洗濯後の寸法変化が小さい)ため、アラミド繊維手袋等の耐切創性手袋のインナー手袋として重ね履きすることにより、汚れたアウター手袋の交換を効率的に行うことができる。
Since the cloth for a protective product of the present invention has excellent heat resistance, it can be effectively used as a cut-resistant inner glove when the outer glove is a heat insulating glove or a low dust generation glove.
Further, since the cloth for protective products of the present invention has excellent cut resistance, when the outer gloves are leather gloves or natural fiber gloves such as cotton, linen, and silk, they can be worn repeatedly as inner gloves. , The shortcomings of outer gloves can be compensated.
Further, since the cloth for protective products of the present invention has excellent washing resistance (small dimensional change after washing), it becomes dirty by being repeatedly worn as inner gloves of cut-resistant gloves such as aramid fiber gloves. Outer gloves can be replaced efficiently.

実施例で作製した繊維製品(手袋)の長さ方向及び幅方向の寸法説明図。Dimensional explanatory view in the length direction and the width direction of the textile product (glove) produced in the examples.

以下、本発明の防護布帛について詳細を説明する。 Hereinafter, the protective fabric of the present invention will be described in detail.

アラミド繊維は一般に単糸繊度が太くなるにつれ切断されにくくなるため、布帛の耐切創性を向上させるためには、単糸繊度を大きくすることが有効と考えられてきたが、それを用いて編織された布帛は軽量性及び装着性が劣る傾向にある。本発明では、布帛の耐切創性を著しく低下させることなく、アラミド繊維布帛の軽量性と装着性の向上を図ることに注力し、従来、綿番手20番〜40番の糸を用いて来た糸構成について大幅な見直しを行った。その結果、精紡時の単繊維構成本数が少ないため紡績糸としての入手が困難である細番手の紡績糸を用いることで、薄手のアラミド繊維布帛を得ることに成功し、それにより、アラミド繊維本来の特性を保持しながら、軽量性と装着性の課題を一挙に解決したものである。 Since aramid fibers generally become more difficult to cut as the single yarn fineness increases, it has been considered effective to increase the single yarn fineness in order to improve the cut resistance of the fabric. The fabric is light and tends to be inferior in wearability. In the present invention, efforts have been made to improve the lightness and wearability of the aramid fiber fabric without significantly reducing the cut resistance of the fabric, and conventionally, yarns having cotton counts of 20 to 40 have been used. A major review was made on the thread composition. As a result, we succeeded in obtaining a thin aramid fiber fabric by using a fine count spun yarn, which is difficult to obtain as a spun yarn because the number of single fiber constituents at the time of spinning is small. It solves the problems of lightness and wearability at once while maintaining the original characteristics.

本発明において、紡績糸に用いられるアラミド繊維としては、メタ系アラミド繊維、パラ系アラミド繊維が挙げられる。紡績糸は、メタ系又はパラ系アラミド繊維を任意の混紡率で混紡した混紡品、あるいは、パラ系アラミド繊維100%品でもよく、要求される防護製品用布帛の特性により選定することができる。中でも、耐切創性及び耐熱性に優れる点より、パラ系アラミド繊維を含む紡績糸が好適である。かかるパラ系アラミド繊維の市販品としては、ポリパラフェニレンテレフタルアミド繊維(東レ・デュポン(株)製、商品名「ケブラー」(登録商標))、コポリパラフェニレン−3,4'−ジフェニルエーテルテレフタルアミド繊維(帝人(株)製、商品名「テクノーラ」(登録商標))等がある。これらの繊維の中でも、特に耐切創性に優れているポリパラフェニレンテレフタルアミド繊維が好ましい。 In the present invention, examples of the aramid fiber used for the spun yarn include meta-type aramid fiber and para-type aramid fiber. The spun yarn may be a blended product obtained by blending meta- or para-aramid fibers at an arbitrary blending ratio, or a 100% para-aramid fiber product, and can be selected according to the required characteristics of the protective product fabric. Among them, a spun yarn containing a para-aramid fiber is preferable from the viewpoint of excellent cut resistance and heat resistance. Commercially available products of such para-aramid fibers include polyparaphenylene terephthalamide fiber (manufactured by Toray DuPont Co., Ltd., trade name "Kevlar" (registered trademark)), copolyparaphenylene-3,4'-diphenyl ether terephthalamide fiber. (Made by Teijin Limited, trade name "Technora" (registered trademark)), etc. Among these fibers, polyparaphenylene terephthalamide fiber having excellent cut resistance is particularly preferable.

従来有機繊維のみを使用した軍手タイプの耐切創性手袋では、一般的に7ゲージや10ゲージを代表とする手袋編み機で作製したものが多く、この中で高い特性を示す7ゲージの手袋の切創力は、特許文献1に開示されているように、凡そ1.15〜1.30kgである。この切創力が約0.25kg以上であれば、インナー手袋としては耐切創性が充分高いと言える。ところが、単繊維繊度が10.0dtexを超えてしまうと、綿番手の大きい紡績糸において単繊維本数が減少するため紡績糸の製造が困難になる、織編物等の布帛が硬くなるため装着性(手袋の重ね履き性)や作業性が低下してしまい、チクチク感を解消することも困難になる。 Most of the conventional work gloves type cut-resistant gloves that use only organic fibers are generally made with a glove knitting machine typified by 7 gauge or 10 gauge, and among these, 7 gauge glove cutting that shows high characteristics. The creativity is approximately 1.15 to 1.30 kg, as disclosed in Patent Document 1. If the incision force is about 0.25 kg or more, it can be said that the incision resistance is sufficiently high as an inner glove. However, if the single fiber fineness exceeds 10.0 dtex, the number of single fibers in the spun yarn having a large cotton count decreases, which makes it difficult to manufacture the spun yarn. The layered wearability of gloves) and workability are reduced, and it becomes difficult to eliminate the tingling sensation.

本発明の紡績糸では、アラミド繊維の単繊維繊度が、好ましくは0.8〜10.0dtexの範囲、より好ましくは1.0〜6.5dtex、特に好ましくは1.2〜4.5dtexの範囲にある短繊維を用いるのが良い。このような単繊維繊度としたのは、単繊維繊度が0.8dtex未満では、JIS T 8052:2005「防護服−機械的特性−鋭利物に対する切創抵抗性試験方法」に規定された試験方法に基づいて測定した耐切創性が不充分となるからである。 In the spun yarn of the present invention, the single fiber fineness of the aramid fiber is preferably in the range of 0.8 to 10.0 dtex, more preferably 1.0 to 6.5 dtex, and particularly preferably 1.2 to 4.5 dtex. It is better to use the short fibers in. Such a single fiber fineness is defined as a test method specified in JIS T 8052: 2005 "Protective clothing-Mechanical properties-Cut resistance test method for sharp objects" when the single fiber fineness is less than 0.8 dtex. This is because the cut resistance measured based on the above is insufficient.

短繊維の繊維長は、紡績糸の撚り係数を適正化する際の加工性を容易にし、同時にチクチク感を解消し、作業性や装着性を高めることのできる、最適な繊維長を選択するのが良い。平均繊維長として35〜160mmの範囲が好ましく、より好ましくは45〜130mmの範囲である。また、良好な紡績性を得るために、短繊維の捲縮数は、約3〜約12山/inchが望ましい。 The fiber length of the short fiber facilitates workability when optimizing the twist coefficient of the spun yarn, and at the same time eliminates the tingling sensation and selects the optimum fiber length that can improve workability and wearability. Is good. The average fiber length is preferably in the range of 35 to 160 mm, more preferably in the range of 45 to 130 mm. Further, in order to obtain good spinnability, the number of crimps of the short fibers is preferably about 3 to about 12 ridges / inch.

紡績糸(単糸)の単繊維数としては、100本以下/単糸が好ましく、より好ましくは95本以下、さらに好ましくは90〜25本である。 The number of single fibers of the spun yarn (single yarn) is preferably 100 or less / single yarn, more preferably 95 or less, and further preferably 90 to 25.

本発明の紡績糸は、アラミド繊維を常法により綿紡績、スフ紡績又は梳毛紡績設備で製造したものであって良い。その際、紡績糸の繊度(番手)は、薄手布帛が得られ易い点より、英国式綿番手40〜70番が好ましく使用される。ここで、紡績糸が細くなると番手数が大きくなる。綿番手70番以下であれば、インナー防護材に好適な軽量の防護製品用布帛を得ることが可能であり、綿番手40番よりも低番手になると、防護製品用布帛の耐洗濯性が低下する(寸法変化や厚み変化が大きくなる)虞がある。 The spun yarn of the present invention may be made by producing aramid fibers by a conventional method in cotton spinning, rayon spinning or worsted spinning equipment. At that time, as the fineness (count) of the spun yarn, an English cotton count of 40 to 70 is preferably used from the viewpoint that a thin cloth can be easily obtained. Here, as the spun yarn becomes thinner, the number of counts increases. If the cotton count is 70 or less, it is possible to obtain a lightweight protective product cloth suitable for the inner protective material, and if the cotton count is lower than 40, the washing resistance of the protective product cloth is lowered. (Dimensional change and thickness change become large).

防護製品用布帛の製造に用いる好ましい紡績糸の形態は、紡績糸単糸、又は、紡績糸単糸を2本引き揃えて紡績糸単糸と逆方向に撚糸した紡績糸双糸である。その他、紡績糸単糸を3本引き揃えて撚り合わせた三子糸であっても良い。これらの紡績糸の中でも製編時の張力に耐えうる引張強さと、布帛の耐切創性に優れる観点より、双糸が好ましい。紡績糸双糸の番手は、綿番手40番/2s〜70番/2sが好ましく、前記範囲内であれば加工性が著しく損なわれることがない。より好ましくは、40番/2s〜60番/2s、さらに好ましくは50番/2s〜60番/2sである。 A preferable form of the spun yarn used for producing the cloth for a protective product is a spun yarn single yarn or a spun yarn twin yarn in which two spun yarn single yarns are aligned and twisted in the opposite direction to the spun yarn single yarn. In addition, a triple yarn obtained by pulling and twisting three single spun yarns may be used. Among these spun yarns, twin yarns are preferable from the viewpoints of tensile strength that can withstand the tension during knitting and excellent cut resistance of the fabric. The count of the spun yarn twin yarn is preferably cotton count 40 / 2s to 70 / 2s, and if it is within the above range, the workability is not significantly impaired. More preferably, it is No. 40 / 2s to No. 60 / 2s, and even more preferably No. 50 / 2s to No. 60 / 2s.

本発明の紡績糸では、単糸撚係数(K)と、単糸及びそれを引き揃えた双糸の撚数(T、T)を適正化することが好ましい。紡績糸単糸を加撚する場合は、次式で求められる単糸撚係数(K)を、2.0〜4.0の範囲とすることが好ましい。単糸撚係数(K)が2.0より小さいと、短繊維同士の絡みが弱くなりすぎ、短繊維の端部が紡績糸からはみ出し、チクチク感の多い布帛(手袋)となる。また、単糸撚係数(K)が4.0より大きいと、強撚になりすぎて二重撚の発生が強くなって加工性が悪化し、紡績糸の引張強さも低下し、また風合いも劣る。より好ましい単糸撚係数(K)は2.5〜3.8の範囲である。また、単糸撚数(T)は15〜30t/inchが好ましく、より好ましくは18〜25t/inchである。紡績糸単糸の撚方向は、S、Zのいずれでも良い。 In the spun yarn of the present invention, it is preferable to optimize the single yarn twist coefficient (K 1 ) and the number of twists (T 1 , T 2 ) of the single yarn and the twin yarns in which the single yarns are aligned. When twisting a single yarn of a spun yarn, it is preferable that the single yarn twist coefficient (K 1 ) obtained by the following equation is in the range of 2.0 to 4.0. When the single yarn twist coefficient (K 1 ) is smaller than 2.0, the entanglement between the short fibers becomes too weak, and the ends of the short fibers protrude from the spun yarn, resulting in a fabric (glove) with a lot of tingling sensation. Further, when the single yarn twist coefficient (K 1 ) is larger than 4.0, the twist becomes too strong, the occurrence of double twist becomes strong, the workability deteriorates, the tensile strength of the spun yarn also decreases, and the texture Is also inferior. A more preferred single yarn twist coefficient (K 1 ) is in the range of 2.5 to 3.8. The number of single yarn twists (T 1 ) is preferably 15 to 30 t / inch, more preferably 18 to 25 t / inch. The twisting direction of the spun yarn single yarn may be either S or Z.

撚係数 K=T/s1/2
T;撚数(t/inch)
s;綿番手
Twist coefficient K = T / s 1/2
T; number of twists (t / inch)
s; cotton count

上記の所定の撚り(撚数T)を加えた紡績糸単糸を2本引き揃え、ダブルツイスターで所定の逆撚り(撚数T)を加えて、紡績糸双糸に加工する。双糸上撚数(T)は300〜700t/mが好ましく、より好ましくは400〜600t/mである。
上記の式で求められる双糸の上撚り撚係数(K)は、2.0〜4.0の範囲とすることが好ましい。双糸撚係数(K)が2.0より小さいと、短繊維の端部が紡績糸からはみ出し、チクチク感の多い手袋となる。また、双糸撚係数(K)が4.0より大きいと、強撚になりすぎて二重撚の発生が強くなって加工性が悪化し、紡績糸の引張強さも低下し、また風合いも劣る。より好ましい双糸撚係数(K)は2.0〜3.3の範囲である。このとき、紡績糸の単糸下撚り数(T)と双糸上撚り撚数(T)の比率(T/T)(%)が30〜95%、より好ましくは50〜90%の範囲になるように加撚することが望ましい。
Two single spun yarns to which the above-mentioned predetermined twist (twist number T 1 ) has been added are aligned, and a predetermined reverse twist (twist number T 2 ) is added with a double twister to process the spun yarn twin yarn. The number of twists on the twin yarn (T 2 ) is preferably 300 to 700 t / m, more preferably 400 to 600 t / m.
The upper twist twist coefficient (K 2 ) of the twin yarns obtained by the above formula is preferably in the range of 2.0 to 4.0. When the twin yarn twist coefficient (K 2 ) is smaller than 2.0, the ends of the short fibers protrude from the spun yarn, resulting in a glove with a lot of tingling sensation. Further, when the twin yarn twist coefficient (K 2 ) is larger than 4.0, the twist becomes too strong, the occurrence of double twist becomes strong, the workability deteriorates, the tensile strength of the spun yarn also decreases, and the texture. Is also inferior. A more preferred twin yarn twist coefficient (K 2 ) is in the range of 2.0 to 3.3. At this time, the ratio (T 2 / T 1 ) (%) of the number of single yarn lower twists (T 1 ) and the number of twin yarn upper twists (T 2 ) of the spun yarn is 30 to 95%, more preferably 50 to 90. It is desirable to twist so that it is in the range of%.

本発明の紡績糸は、単糸繊度が0.8〜10.0dtexのアラミド長繊維を切断し、ステープル化したものを用いて、従来公知の紡績手段で製造することができる。ステープルをスライバーとし、それをリング撚糸機等にて所定の撚係数の撚りを加え、さらにダブルツイスター等にて、所定の撚数比率とする。こうして得られる、本発明の紡績糸の引張強さは、綿番手50/sの単糸で少なくとも0.4kg、綿番手50/2sの双糸で少なくとも1.4kgある。このことから、本発明の紡績糸を用いてなる布帛は、引張強さの点でも優れているので、インナー手袋をはじめとする各種のインナー防護製品用布帛として好適である。 The spun yarn of the present invention can be produced by a conventionally known spinning means by cutting aramid filaments having a single yarn fineness of 0.8 to 10.0 dtex and converting them into staples. A staple is used as a sliver, and a ring twisting machine or the like is used to twist the staples with a predetermined twist coefficient, and then a double twister or the like is used to obtain a predetermined twist number ratio. The tensile strength of the spun yarn of the present invention thus obtained is at least 0.4 kg for a single yarn having a cotton count of 50 / s and at least 1.4 kg for a twin yarn having a cotton count of 50 / 2s. From this, the fabric made of the spun yarn of the present invention is also excellent in terms of tensile strength, and is therefore suitable as a fabric for various inner protective products such as inner gloves.

また、本発明の紡績糸を製造する場合、本発明の効果を妨げない範囲で、約30質量%以下で他の短繊維(例えば、綿、レーヨン、ポリエステル、ナイロン等)を混用することができる。好ましくはアラミド繊維(特に好ましくはパラ系アラミド繊維)を紡績糸全体の質量のうち、70〜100%の範囲とするのが良い。 Further, in the case of producing the spun yarn of the present invention, other short fibers (for example, cotton, rayon, polyester, nylon, etc.) can be mixed in an amount of about 30% by mass or less within a range that does not interfere with the effect of the present invention. .. Aramid fibers (particularly preferably para-aramid fibers) are preferably in the range of 70 to 100% of the total mass of the spun yarn.

さらに、本発明の繊維製品は、全てを、本発明の防護製品用布帛で構成してもよく、又はそれらを部分的に使用することでも良い。例えば、作業用手袋では、作業内容により指先部分や手の平部分だけのように、特定の部分に防護製品用布帛を使うことができる。防護製品用布帛には、必要に応じ、樹脂コーティングを施すこともできる。手袋を編成する場合は、手の平部の目付が70〜220g/mの範囲になるように編みあげることが好ましく、目付70g/m以上にすることで、耐切創性、耐洗濯性に優れるインナー手袋を得ることができ、また目付220g/m以下にすることで、軽量で重ね履き性が良い手袋となる。手の平部の目付が220g/mを超える手袋の場合は、手袋の厚みが大きいためインナー手袋としては不向きとなる。さらに好ましくは、手の平部の目付が85〜200g/mの範囲にするのが良い。この場合の構成する紡績糸の本数は、紡績糸の太さ(番手)と防護製品用布帛の目付が関係するが、それぞれの範囲内であれば、1〜複数本で使用できる。 Furthermore, the textile products of the present invention may be composed entirely of the fabrics for protective products of the present invention, or they may be partially used. For example, in work gloves, a protective product cloth can be used for a specific part such as a fingertip part or a palm part depending on the work content. If necessary, the fabric for protective products may be coated with a resin. When organizing glove is preferably the basis weight of palm portion'll knitting to be in the range of 70~220g / m 2, by the basis weight 70 g / m 2 or more, excellent cut resistance, the resistance to washing Inner gloves can be obtained, and by reducing the basis weight to 220 g / m 2 or less, the gloves are lightweight and have good layerability. Gloves with a basis weight of more than 220 g / m 2 on the palm are not suitable as inner gloves because the gloves are thick. More preferably, the basis weight of the palm portion is in the range of 85 to 200 g / m 2. The number of spun yarns constituting in this case is related to the thickness (count) of the spun yarn and the basis weight of the cloth for the protective product, but if it is within each range, one or a plurality of spun yarns can be used.

本発明の防護製品用布帛は、JIS L 1096:2010 8.4 による厚み測定方法に基づいて測定した厚みが1.0mm以下である。好ましくは0.9mm以下である。そのため、手袋に編成した際に、従来にない薄手かつ重ね履き性に優れる手袋が得られる。また、手袋の重さ(1双あたり)は、番手が大きい紡績糸を用いるため、ウーリーナイロン製手袋並みの軽量性を有している。また、アラミド繊維を含む紡績糸を用いるため、耐洗濯性に優れる手袋が得られ、手袋の洗濯5回後の厚み変化率(%)並びに手袋のたて(長さ)方向及びよこ(幅)方向の寸法変化率は、±5%以下を達成できる。繊維製品の洗濯はJIS L 0217−103記載の方法に基づき、厚み変化率及び寸法変化率はJIS L 1096 8.39.8記載の方法に基づく。前記の厚み変化率及び寸法変化率は、好ましくは±2%以下、さらに好ましくは±1%以下であるのが良い。 The cloth for protective products of the present invention has a thickness of 1.0 mm or less measured based on the thickness measuring method according to JIS L 1096: 2010 8.4. It is preferably 0.9 mm or less. Therefore, when knitted into gloves, it is possible to obtain gloves that are thin and have excellent layerability, which has never been seen before. In addition, the weight of the gloves (per pair) is as light as that of woolly nylon gloves because the spun yarn having a large count is used. Further, since the spun yarn containing the aramid fiber is used, gloves having excellent washing resistance can be obtained, and the thickness change rate (%) of the gloves after washing 5 times, the vertical (length) direction and the horizontal (width) of the gloves. The dimensional change rate in the direction can be achieved to be ± 5% or less. The washing of textile products is based on the method described in JIS L 0217-103, and the thickness change rate and the dimensional change rate are based on the method described in JIS L 1096 8.39.8. The thickness change rate and the dimensional change rate are preferably ± 2% or less, more preferably ± 1% or less.

また、防護製品用布帛として編物を編成する場合、使用するよこ編み機のゲージ数は、15ゲージ以上に設定することが好ましく、より好ましくは15〜21ゲージであり、手袋の耐洗濯性を確保するという観点からは15〜18ゲージとするのが良い。 Further, when knitting a knitted fabric as a cloth for a protective product, the number of gauges of the weft knitting machine to be used is preferably set to 15 gauge or more, more preferably 15 to 21 gauge, and the washing resistance of gloves is ensured. From this point of view, it is better to use 15 to 18 gauge.

本発明の防護製品用布帛は、手袋、アームカバー、靴下等の重ね履きが必要な程度の耐切創性が要求される用途に特に適しているため、これらの布帛を、インナー手袋あるいは防護材等、各種繊維製品に用いることができる。これには、直接防護目的として使用されるものはもちろん、結果的に防護機能が果たされるものも含まれる。具体的には、作業用又は工業用のインナー手袋、インナーウエア、リストガード、アームカバー、靴下等が挙げられる。その他、溶接用作業衣、レーシングスーツ、スポーツウエア、スキーウエア、スケートウエア等のアンダーウエア等の用途が挙げられるが、これらに限定されるものではない。 Since the cloth for protective products of the present invention is particularly suitable for applications that require cut resistance to the extent that it is necessary to wear gloves, arm covers, socks, etc., these cloths are used as inner gloves, protective materials, etc. , Can be used for various textile products. This includes those used for direct protection purposes as well as those that eventually fulfill the protective function. Specific examples thereof include work or industrial inner gloves, inner wear, wrist guards, arm covers, socks and the like. Other uses include, but are not limited to, work clothes for welding, racing suits, sportswear, ski wear, underwear such as skate wear, and the like.

以下、実施例及び比較例を用いて本発明を更に具体的に説明するが、本発明は以下の実施例のみに限定されるものではない。なお、以下の実施例及び比較例における各物性値の測定方法は次の通りである。 Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples. The method for measuring each physical property value in the following Examples and Comparative Examples is as follows.

[単繊維繊度]
JIS L 1013:2010 化学繊維フィラメント糸試験方法8.3 B法(簡便法)により測定した。
[Single fiber fineness]
JIS L 1013: 2010 Chemical fiber filament yarn test method 8.3 Measured by the B method (simple method).

[紡績糸の引張強さ、伸び]
JIS L 1095:2010「一般紡績糸試験方法」9.5に準じて紡績糸の引張強さ(N)を測定した。
[Tensile strength and elongation of spun yarn]
The tensile strength (N) of the spun yarn was measured according to JIS L 1095: 2010 "General spun yarn test method" 9.5.

[手袋の切創力]
JIS T 8052:2005「防護服−機械的特性−鋭利物に対する切創抵抗性試験方法」に準拠し、手袋1枚における手の平部の切創力(N)を測定した。切創力(N)を織編物の目付で除して、耐切創性を求めた。切創力の値が大きいほど切れ難いと判定した。
[Glove cutting power]
The cut force (N) of the palm of one glove was measured in accordance with JIS T 8052: 2005 "Protective clothing-Mechanical properties-Cut resistance test method for sharp objects". The cut resistance (N) was divided by the basis weight of the woven or knitted fabric to obtain the cut resistance. It was judged that the larger the value of the incision force, the more difficult it was to cut.

[手袋の耐洗濯性]
JIS L 0217 103の試験方法に準じて洗濯処理を行い、平干し乾燥した。ドライアイロンによる仕上げ無しとした。前記洗濯処理を5回行った後に、JIS L 1096 8.2.2 長さ、に準じて手袋の全長(長さ方向)及び4本胴(幅方向)の寸法を測定し(図1参照)、JIS L 1096 8.4 厚さ、に準じて手の平部の厚みを測定し、JIS L 1096 8.39.8 計算、に準じて寸法変化率及び厚み変化率を算出した。
[Wash resistance of gloves]
It was washed according to the test method of JIS L 0217 103, and then laid flat and dried. No finishing with a dry iron. After performing the washing treatment 5 times, the total length (length direction) and the four body (width direction) dimensions of the gloves were measured according to the JIS L 1096 8.2.2 length (see FIG. 1). , JIS L 1096 8.4 thickness, the thickness of the palm was measured, and the dimensional change rate and the thickness change rate were calculated according to JIS L 1096 8.39.8 calculation.

ΔL=[(L−L)/L]×100
(ここで、ΔL:寸法変化率(%)、L:洗濯処理前の長さ(mm)、L:洗濯処理後の長さ(mm))
ΔL = [(L 2- L 1 ) / L 1 ] × 100
(Here, ΔL: dimensional change rate (%), L 1 : length before washing treatment (mm), L 2 : length after washing treatment (mm))

ΔD=[(D−D)/D]×100
(ここで、ΔD:厚み変化率(%)、D:洗濯処理前の厚み(mm)、D:洗濯処理後の厚み(mm))
ΔD = [(D 2- D 1 ) / D 1 ] × 100
(Here, ΔD: thickness change rate (%), D 1 : thickness before washing treatment (mm), D 2 : thickness after washing treatment (mm))

(実施例1)
アラミド短繊維糸条として、繊度1.67dtexのパラ系アラミド繊維(東レ・デュポン(株)製“Kevlar(R)29”、引張強さ20.3cN/dtex)にステープル加工を施した、繊維長51mm、捲縮数約8山/inchのパラ系アラミド短繊維100%を用いた。
これを、開綿機、カード、練条の順で通しスライバーとした。次に、これをリング精紡機に仕掛け、撚数(T)20.3t/inch、撚係数2.87、撚り方向がZ撚りの撚りを加えて、糸番手50(綿番手)、引張強さ910gの紡績糸の単糸を得た。この紡績糸を2本引き揃え、ダブルツイスターで撚数(T)519t/mの逆(S)撚りを加えて、糸番手が50/2(綿番手)、引張強さ2050gの双糸を得た。
さらに、双糸を2本引き揃えて、15ゲージタイプの手袋編み機((株)島精機製作所)に供給して手袋を編みあげた。
(Example 1)
As aramid short fiber threads, para-aramid fibers with a fineness of 1.67 dtex (“Kevlar (R) 29” manufactured by Toray DuPont Co., Ltd., tensile strength 20.3 cN / dtex) are stapled and have a fiber length. 100% para-aramid short fibers of 51 mm and about 8 crimps / inch were used.
This was made into a sliver by passing it through a cotton-opening machine, a card, and a kneading strip in that order. Next, this is set in a ring spinning machine, and the number of twists (T 1 ) is 20.3 t / inch, the twist coefficient is 2.87, and the twist direction is Z twist. A single yarn of 910 g of spun yarn was obtained. Two of these spun yarns are aligned, and a reverse (S) twist with a twist number (T 2 ) of 519 t / m is added with a double twister to obtain a twin yarn with a yarn count of 50/2 (cotton count) and a tensile strength of 2050 g. Obtained.
Furthermore, two twin yarns were pulled together and supplied to a 15 gauge type glove knitting machine (Shima Seiki Seisakusho Co., Ltd.) to knit the gloves.

(実施例2)
アラミド短繊維糸条として、繊度2.5dtexのパラ系アラミド繊維(東レ・デュポン(株)製)にステープル加工を施した、繊維長51mm、捲縮数約8山/inchのパラ系アラミド短繊維100%を用いた。
これを、開綿機、カード、練条の順で通しスライバーとした。次に、これをリング精紡機に仕掛け、撚数(T)20.5t/inch、撚係数2.90、撚り方向がZ撚りの撚りを加えて、糸番手50(綿番手)、引張強さ450gの紡績糸の単糸を得た。この紡績糸を2本引き揃え、ダブルツイスターで撚数(T)525t/mの逆(S)撚りを加えて、糸番手が50/2(綿番手)、引張強さ1430gの双糸を得た。
さらに、双糸を2本引き揃えて、15ゲージタイプの手袋編み機((株)島精機製作所)に供給して手袋を編みあげた。
(Example 2)
As aramid short fiber threads, para-aramid fibers with a fineness of 2.5 dtex (manufactured by Toray DuPont Co., Ltd.) are stapled, and the fiber length is 51 mm, and the number of crimps is about 8 threads / inch para-aramid short fibers. 100% was used.
This was made into a sliver by passing it through a cotton-opening machine, a card, and a kneading strip in that order. Next, this is set in a ring spinning machine, and the number of twists (T 1 ) is 20.5 t / inch, the twist coefficient is 2.90, and the twist direction is Z twist. A single yarn of 450 g of spun yarn was obtained. Two of these spun yarns are aligned and a reverse (S) twist with a twist number (T 2 ) of 525 t / m is added with a double twister to produce a twin yarn with a yarn count of 50/2 (cotton count) and a tensile strength of 1430 g. Obtained.
Furthermore, two twin yarns were pulled together and supplied to a 15 gauge type glove knitting machine (Shima Seiki Seisakusho Co., Ltd.) to knit the gloves.

(実施例3)
アラミド短繊維糸条として、繊度3.3dtexのパラ系アラミド繊維(東レ・デュポン(株)製)にステープル加工を施した、繊維長51mm、捲縮数約8山/inchのパラ系アラミド短繊維100%を用いた。
これを、開綿機、カード、練条の順で通しスライバーとした。次に、これをリング精紡機に仕掛け、撚数(T)24.8t/inch、撚係数3.50、撚り方向がZ撚りの撚りを加えて、糸番手50(綿番手)、引張強さ510gの紡績糸の単糸を得た。この紡績糸を2本引き揃え、ダブルツイスターで撚数(T)556t/mの逆(S)撚りを加えて、糸番手が50/2(綿番手)、引張強さ1460gの双糸を得た。
さらに、双糸を2本引き揃えて、15ゲージタイプの手袋編み機((株)島精機製作所)に供給して手袋を編みあげた。
(Example 3)
As aramid short fiber threads, para-aramid fibers with a fineness of 3.3 dtex (manufactured by Toray DuPont Co., Ltd.) are stapled, and the fiber length is 51 mm, and the number of crimps is about 8 threads / inch para-aramid short fibers. 100% was used.
This was made into a sliver by passing it through a cotton-opening machine, a card, and a kneading strip in that order. Next, this was set in a ring spinning machine, and the number of twists (T 1 ) was 24.8 t / inch, the twist coefficient was 3.50, and the twist direction was Z twist. A single yarn of 510 g of spun yarn was obtained. Two of these spun yarns are aligned and a reverse (S) twist with a twist number (T 2 ) of 556 t / m is added with a double twister to produce a twin yarn with a yarn count of 50/2 (cotton count) and a tensile strength of 1460 g. Obtained.
Furthermore, two twin yarns were pulled together and supplied to a 15 gauge type glove knitting machine (Shima Seiki Seisakusho Co., Ltd.) to knit the gloves.

(実施例4)
アラミド短繊維糸条として、繊度1.67dtexのパラ系アラミド繊維(東レ・デュポン(株)製“Kevlar(R)29”、引張強さ20.3cN/dtex)にステープル加工を施した、繊維長51mm、捲縮数約8山/inchのパラ系アラミド短繊維100%を用いた。
これを、開綿機、カード、練条の順で通しスライバーとした。次に、これをリング精紡機に仕掛け、撚数(T)22.5t/inch、撚係数2.90、撚り方向がZ撚りの撚りを加えて、糸番手60(綿番手)、引張強さ670gの紡績糸の単糸を得た。この紡績糸を2本引き揃え、ダブルツイスターで撚数(T)505t/mの逆(S)撚りを加えて、糸番手が60/2(綿番手)、引張強さ1620gの双糸を得た。
さらに、双糸を2本引き揃えて、15ゲージタイプの手袋編み機((株)島精機製作所)に供給して手袋を編みあげた。
(Example 4)
As aramid short fiber threads, para-aramid fibers with a fineness of 1.67 dtex (“Kevlar (R) 29” manufactured by Toray DuPont Co., Ltd., tensile strength 20.3 cN / dtex) are stapled and have a fiber length. 100% para-aramid short fibers of 51 mm and about 8 crimps / inch were used.
This was made into a sliver by passing it through a cotton-opening machine, a card, and a kneading strip in that order. Next, this is set in a ring spinning machine, and the number of twists (T 1 ) is 22.5 t / inch, the twist coefficient is 2.90, and the twist direction is Z twist. A single yarn of 670 g of spun yarn was obtained. Two of these spun yarns are aligned and a reverse (S) twist with a twist number (T 2 ) of 505 t / m is added with a double twister to produce a twin yarn with a yarn count of 60/2 (cotton count) and a tensile strength of 1620 g. Obtained.
Furthermore, two twin yarns were pulled together and supplied to a 15 gauge type glove knitting machine (Shima Seiki Seisakusho Co., Ltd.) to knit the gloves.

(実施例5)
実施例1で得た紡績糸の双糸を1本用い、18ゲージタイプの手袋編み機((株)島精機製作所)に供給して手袋を編み上げた。
(Example 5)
Using one twin yarn of the spun yarn obtained in Example 1, the glove was knitted by supplying it to an 18 gauge type glove knitting machine (Shima Seiki Seisakusho Co., Ltd.).

(実施例6)
実施例2で得た紡績糸の双糸を1本用い、18ゲージタイプの手袋編み機((株)島精機製作所)に供給して手袋を編み上げた。
(Example 6)
Using one twin yarn of the spun yarn obtained in Example 2, the glove was knitted by supplying it to an 18 gauge type glove knitting machine (Shima Seiki Seisakusho Co., Ltd.).

(実施例7)
実施例4で得た紡績糸の双糸を1本用い、21ゲージタイプの手袋編み機((株)島精機製作所)に供給して手袋を編み上げた。
(Example 7)
Using one twin yarn of the spun yarn obtained in Example 4, the glove was knitted by supplying it to a 21 gauge type glove knitting machine (Shima Seiki Seisakusho Co., Ltd.).

(比較例1)
アラミド短繊維糸条として、繊度1.67dtexのパラ系アラミド繊維(東レ・デュポン(株)製“Kevlar(R)29”、引張強さ20.3cN/dtex)にステープル加工を施した、繊維長51mm、捲縮数約8山/inchのパラ系アラミド短繊維100%を用いた。これを、開綿機、カード、練条の順で通しスライバーとした。次に、これをリング精紡機に仕掛け、撚数(T)13.0t/inch、撚係数2.90、撚り方向がZ撚りの撚りを加えて、糸番手20(綿番手)、引張強さ2173gの紡績糸の単糸を得た。この紡績糸を2本引き揃え、ダブルツイスターで撚数(T)331t/mの逆(S)撚りを加えて、糸番手が20/2(綿番手)、引張強さ4724gの双糸を得た。
さらに、双糸を5本引き揃えて、7ゲージタイプの手袋編み機((株)島精機製作所)に供給して手袋を編みあげた。
(Comparative Example 1)
As aramid short fiber threads, para-aramid fibers with a fineness of 1.67 dtex (“Kevlar (R) 29” manufactured by Toray DuPont Co., Ltd., tensile strength 20.3 cN / dtex) are stapled and have a fiber length. 100% para-aramid short fibers of 51 mm and about 8 crimps / inch were used. This was made into a sliver by passing it through a cotton-opening machine, a card, and a kneading strip in that order. Next, this is set in a ring spinning machine, and the number of twists (T 1 ) is 13.0 t / inch, the twist coefficient is 2.90, and the twist direction is Z twist. A single yarn of 2173 g of spun yarn was obtained. Two of these spun yarns are aligned and a reverse (S) twist with a twist number (T 2 ) of 331 t / m is added with a double twister to produce a twin yarn with a yarn count of 20/2 (cotton count) and a tensile strength of 4724 g. Obtained.
Furthermore, five twin yarns were pulled together and supplied to a 7-gauge type glove knitting machine (Shima Seiki Seisakusho Co., Ltd.) to knit the gloves.

(比較例2)
繊度78dtexのウーリーナイロン繊維を2本引き揃えて、18ゲージタイプの手袋編み機((株)島精機製作所)に供給して、手袋を編みあげた。
(Comparative Example 2)
Two woolly nylon fibers with a fineness of 78 dtex were pulled together and supplied to an 18 gauge type glove knitting machine (Shima Seiki Seisakusho Co., Ltd.) to knit the gloves.

実施例1〜7、比較例1〜2で得た紡績糸の特性を表1、手袋の特性を表2にまとめた。 The characteristics of the spun yarns obtained in Examples 1 to 7 and Comparative Examples 1 and 2 are summarized in Table 1, and the characteristics of gloves are summarized in Table 2.

表1及び表2より、本発明の紡績糸は、単繊維の構成本数が少なく繊度が小さいが、引張強さ及び伸びの点で、耐切創性手袋を編成するのに充分な特性を有していた。また、編成した手袋は、重さが10g以下で厚みが1.0mm以下と非常に薄いにも拘わらず、ウーリーナイロン(双糸)手袋の2倍以上の切創力を有していた。さらに、洗濯後の厚み変化率及び寸法変化率が非常に小さいものであった。 From Tables 1 and 2, the spun yarn of the present invention has a small number of single fibers and a small fineness, but has sufficient properties for knitting cut-resistant gloves in terms of tensile strength and elongation. Was there. Further, although the knitted gloves weigh 10 g or less and have a thickness of 1.0 mm or less, which are very thin, they have more than twice the cut force of the woolly nylon (double thread) gloves. Further, the thickness change rate and the dimensional change rate after washing were very small.

Figure 2021161567
Figure 2021161567

Figure 2021161567
Figure 2021161567

本発明の紡績糸を用いてなる防護製品用布帛は、作業用又は工業用のインナー手袋等として好適に用いられる他、レーシングスーツ、スポーツウエア等の各種衣服を着用する際のインナー繊維製品として幅広く用いることができる。 The cloth for protective products using the spun yarn of the present invention is suitably used as inner gloves for work or industry, and is also widely used as an inner textile product when wearing various clothes such as racing suits and sportswear. Can be used.

Claims (6)

アラミド繊維を含む紡績糸を用いてなる布帛であって、
JIS L 1096 8.4法に準じて測定される厚みが1.0mm以下であり、
JIS L 0217−103法平干し乾燥 による洗濯処理5回後の厚み変化率が±5%以下であり、かつ、前記洗濯処理5回後のたて方向及びよこ方向における寸法変化率が±5%以下であることを特徴とする防護製品用布帛。
A fabric made of spun yarn containing aramid fibers.
The thickness measured according to the JIS L 1096 8.4 method is 1.0 mm or less.
JIS L 0217-103 method The rate of change in thickness after 5 washing treatments by flat-drying is ± 5% or less, and the rate of dimensional change in the vertical and horizontal directions after 5 times of washing treatment is ± 5%. A cloth for a protective product, which is characterized by the following.
前記紡績糸が、単繊維数100本以下/単糸で構成される請求項1に記載の防護製品用布帛。 The cloth for a protective product according to claim 1, wherein the spun yarn is composed of 100 or less single fibers / single yarn. 前記紡績糸が、英国式綿番手40番ないし70番の単糸又は双糸である請求項1又は2に記載の防護製品用布帛。 The fabric for a protective product according to claim 1 or 2, wherein the spun yarn is a single yarn or a twin yarn having an English cotton count of 40 to 70. 前記布帛が編物であり、該編物を編成するよこ編機のゲージ数が15ゲージ〜21ゲージである請求項1〜3いずれかに記載の防護製品用布帛。 The cloth for a protective product according to any one of claims 1 to 3, wherein the cloth is a knit, and the number of gauges of the weft knitting machine for knitting the knit is 15 gauge to 21 gauge. 請求項1〜4いずれかに記載の防護製品用布帛を用いてなる、インナー手袋、インナーウエア、リストガード、アームカバー及び靴下からなる群から選択されるいずれかの繊維製品。 Any textile product selected from the group consisting of inner gloves, inner wear, wrist guards, arm covers and socks, which uses the cloth for protective products according to any one of claims 1 to 4. 繊維製品がインナー手袋であり、断熱性あるいは低発塵性のアウター手袋、又は、革製、天然繊維製あるいはアラミド繊維製のアウター手袋に対する、インナー手袋として用いられる請求項5に記載の繊維製品。 The textile product according to claim 5, wherein the textile product is an inner glove, which is used as an inner glove for an outer glove having heat insulation or low dust generation, or an outer glove made of leather, natural fiber or aramid fiber.
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