JP6710008B2 - Cut resistant spun yarn - Google Patents

Cut resistant spun yarn Download PDF

Info

Publication number
JP6710008B2
JP6710008B2 JP2016030643A JP2016030643A JP6710008B2 JP 6710008 B2 JP6710008 B2 JP 6710008B2 JP 2016030643 A JP2016030643 A JP 2016030643A JP 2016030643 A JP2016030643 A JP 2016030643A JP 6710008 B2 JP6710008 B2 JP 6710008B2
Authority
JP
Japan
Prior art keywords
spun yarn
cut
short fibers
dtex
aramid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2016030643A
Other languages
Japanese (ja)
Other versions
JP2017150096A5 (en
JP2017150096A (en
Inventor
和義 吉田
和義 吉田
巽 薫
薫 巽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Du Pont Toray Co Ltd
Original Assignee
Du Pont Toray Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont Toray Co Ltd filed Critical Du Pont Toray Co Ltd
Priority to JP2016030643A priority Critical patent/JP6710008B2/en
Publication of JP2017150096A publication Critical patent/JP2017150096A/en
Publication of JP2017150096A5 publication Critical patent/JP2017150096A5/ja
Application granted granted Critical
Publication of JP6710008B2 publication Critical patent/JP6710008B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Description

本発明は、切創力に優れ、さらには切創力と引張強力のバランスが良好で、かつ柔軟性に優れる耐切創性紡績糸、及び該紡績糸を用いてなる防護衣料に関する。 TECHNICAL FIELD The present invention relates to a cut-resistant spun yarn having excellent cut strength, a good balance between cut strength and tensile strength, and excellent flexibility, and protective clothing using the spun yarn.

ナイロン、ポリエステル、アクリル繊維等の汎用熱可塑性合成繊維は、柔軟で快適な衣料用繊維であるが、刃物類や剪断応力によって切れ易く、摩耗して穴開きし易い。従ってこれらの汎用熱可塑性合成繊維は、身辺が危険に曝されるおそれの大きい場面で使用される衣料製品、例えば消防服、レーシングスーツ、製鉄用作業服または溶接用作業服、及び作業用手袋などの防護用の繊維素材として適しているとはいえない。 Although general-purpose thermoplastic synthetic fibers such as nylon, polyester, and acrylic fibers are flexible and comfortable fibers for clothing, they are easily cut by cutlery and shear stress, and easily worn and punctured. Therefore, these general-purpose thermoplastic synthetic fibers are clothing products used in situations where there is a great risk of personal injury, such as fire fighting clothing, racing suits, workwear for steelmaking or workwear for welding, and work gloves. It cannot be said that it is suitable as a fiber material for protection of.

一方、硬い素材から得られるガラス繊維、セラミック繊維及び金属繊維は、耐切断性に優れた素材であるが、柔軟性が低く、軽量性にも欠ける。また、フィラメントの自由端が作業者や使用者の身体を刺す危険性があり、これまた防護用の繊維素材として適しているとはいえない。 On the other hand, glass fibers, ceramic fibers and metal fibers obtained from a hard material are materials having excellent cut resistance, but have low flexibility and lack lightness. Further, the free end of the filament has a risk of piercing the body of an operator or a user, and it cannot be said that it is suitable as a fiber material for protection.

ナイロンやポリエステル繊維等の汎用熱可塑性合成繊維は、250℃前後で溶融し、限界酸素指数が約20前後で、空気中で良く燃焼するのに対して、アラミド繊維等の高機能繊維は、250℃前後では溶融せず(約400〜500℃で分解する)、限界酸素指数が29〜30で空気中では炎を近づけると燃焼するが、炎を遠ざけると燃焼を続けることができない耐熱性と難燃性に優れた素材である。それ故、アラミド繊維は、炎や高熱に曝される危険性の高い場面で使用される衣料製品、例えば消防服、レーシングスーツ、製鉄用や溶接用の作業服、手袋などの防護衣料として好んで用いられている。中でも、耐熱性、高強度特性、耐創傷性を有するパラ系アラミド繊維は、切創防止のための作業用手袋などに利用されている。 General-purpose thermoplastic synthetic fibers such as nylon and polyester fibers melt at around 250° C. and have a limiting oxygen index of about 20 and burn well in the air, whereas high-performance fibers such as aramid fibers are 250 It does not melt at around ℃ (decomposes at about 400 to 500 ℃), it has a limiting oxygen index of 29 to 30 and burns in the air when the flame is approached, but it cannot continue burning when the flame is moved away. It is a material with excellent flammability. Therefore, aramid fibers are preferred as protective clothing for clothing products used in situations where there is a high risk of exposure to flames and high heat, such as fire fighting clothing, racing suits, workwear for steelmaking and welding, gloves, etc. It is used. Among them, para-aramid fibers having heat resistance, high strength characteristics, and wound resistance are used for work gloves and the like for preventing cut wounds.

しかし、アラミド繊維紡績糸を用いて防護衣料などを製造する場合、該繊維の剛性が高いため、紡績糸の切創力と引張強力あるいは柔軟性とは互いに取り合いの関係にあり、これらの特性バランスの良い紡績糸を得ることは極めて難しいという問題がある。即ち、切創力や引張強力を高めようとすると柔軟性が劣るものとなり、柔軟性を高めようとすると切創力や引張強力が低下する。 However, in the case of manufacturing a protective garment or the like using spun yarn of aramid fiber, the cutting force of the spun yarn and tensile strength or flexibility are in mutual relationship due to the high rigidity of the fiber, and the balance of these characteristics is high. It is extremely difficult to obtain a good spun yarn. That is, if the cutting force or tensile strength is increased, the flexibility becomes poor, and if the flexibility is increased, the cutting force or tensile strength decreases.

特許文献1及び特許文献2には、繊維強化樹脂複合体において、メタ系アラミド繊維とパラ系アラミド繊維を混紡した紡績糸を用いることが提案されている。かかる提案では、紡績糸織編布と樹脂との親和性や切削加工性を向上させるべく、メタ系/パラ系アラミド繊維を所定の比率で混紡し、かつ、混紡糸の強力を向上させるために、アラミド繊維の単繊維繊度を細くして混紡糸中の単繊維本数を増やしている。しかしながら、メタ系/パラ系アラミド繊維の混紡によって混紡糸の強力向上は認められるが、加工性はメタ系アラミド繊維単独の場合と同等であり、切創力に優れる紡績糸も得られていない。 Patent Documents 1 and 2 propose the use of a spun yarn in which a meta-aramid fiber and a para-aramid fiber are mixed-spun in a fiber-reinforced resin composite. In such a proposal, in order to improve the affinity between the spun yarn woven and knitted fabric and the resin and the machinability, the meta/para aramid fibers are mixed-spun at a predetermined ratio, and in order to improve the strength of the mixed-spun yarn, The single fiber fineness of the aramid fiber is reduced to increase the number of single fibers in the mixed yarn. However, although the strength of the mixed yarn is improved by the mixed spinning of the meta/para aramid fiber, the processability is equivalent to that of the meta aramid fiber alone, and a spun yarn excellent in cut strength has not been obtained.

一方、特許文献3には、保温性に優れる衣料用編地を得るべく、単繊維繊度が異なりかつ単繊維繊度の差が0.4dtex以上である、2種類のアクリル短繊維を混紡した紡績糸を用いることが提案されている。片方の短繊維は単繊維繊度を0.7dtex以下、他方の短繊維は風合いが硬くなるのを防ぐため単繊維繊度を1.3dtex以下に設定している。しかしながら、かかる技術は高機能繊維を対象とするものではなく、切創力に関する検討もなされていない。 On the other hand, in Patent Document 3, in order to obtain a knitted fabric for clothing excellent in heat retention, a spun yarn obtained by mixing two kinds of acrylic short fibers having different single fiber fineness and a difference in single fiber fineness of 0.4 dtex or more. Is proposed to be used. One short fiber has a single fiber fineness of 0.7 dtex or less, and the other short fiber has a single fiber fineness of 1.3 dtex or less in order to prevent the texture from becoming hard. However, such a technique does not target high-performance fibers, and no consideration has been given to the cutting force.

特開2002−113788号公報JP, 2002-113788, A 特開平8−174689号公報JP-A-8-174689 特開2010−203000号公報JP, 2010-203000, A

本発明は、かかる従来技術の背景に鑑み、切創力が高くかつ柔軟性に優れる耐切創性紡績糸、及び、切創力と引張強力のバランスが良好でかつ柔軟性に優れる耐切創性紡績糸、ならびに、これら紡績糸を用いてなる防護衣料を提供せんとするものである。 In view of such background of the prior art, the present invention is a cut-resistant spun yarn having a high cutting force and excellent flexibility, and a cut-resistant spinning excellent in flexibility and having a good balance between cutting force and tensile strength. It is intended to provide a yarn and a protective garment using the spun yarn.

上記課題を解決するため、本発明者等は、紡績糸の切創力、引張強力、柔軟性の関係について鋭意検討を重ねた結果、単繊維繊度が2.8〜8.0dtexの太繊度パラ系アラミド短繊維を一定の混率で混紡した紡績糸とすることで、切創力が向上し、柔軟性が付与され、さらには引張強さが保持される耐切創性紡績糸が得られることを見出し、従来互いに取り合いの関係にあった特性を全て向上させ得る耐切創性紡績糸に到達した。 In order to solve the above problems, the inventors of the present invention have earnestly studied the relationship between the cut strength, the tensile strength, and the flexibility of the spun yarn, and as a result, the single fiber fineness is 2.8 to 8.0 dtex. By making a spun yarn in which a series of aramid short fibers are mixed-spun at a constant mixing ratio, it is possible to obtain a cut-resistant spun yarn in which the cutting force is improved, the flexibility is imparted, and the tensile strength is retained. As a result, the present invention has reached a cut-resistant spun yarn that can improve all the properties that were conventionally in mutual relation.

(1)単繊維繊度が異なる2種以上のアラミド短繊維のみを混紡してなる紡績糸であって、単繊維繊度が2.8〜8.0dtexのパラ系アラミド短繊維Aを20〜95質量%、単繊維繊度が1.0〜2.7dtexのパラ系アラミド短繊維Bを5〜80質量%含むことを特徴とする耐切創性紡績糸。
(2)短繊維Aの混率をY(質量%)、短繊維Bの混率を100−Y(質量%)としたとき、下記式(I)を満たすことを特徴とする上記(1)に記載の耐切創性紡績糸。
AF×Y≧BF×(100−Y) (I)
(AF;短繊維Aの単繊維繊度(dtex)、BF;短繊維Bの単繊維繊度(dtex))
(3)短繊維Aの混率Yが20〜80質量%、短繊維Bの混率が20〜80質量%であることを特徴とする上記(1)または(2)に記載の耐切創性紡績糸。
(4)パラ系アラミド短繊維Aの単繊維繊度が3.2〜4.8dtexであることを特徴とする上記(1)〜(3)いずれかに記載の耐切創性紡績糸。
(5)単繊維繊度が異なる2種以上のアラミド短繊維のみを混紡してなる紡績糸であって、単繊維繊度が2.8〜8.0dtexのパラ系アラミド短繊維Aを20〜95質量%、単繊維繊度が1.0〜2.7dtexのパラ系アラミド短繊維Bを5〜80質量%含み、次式で求められる撚係数K が2.5〜6.0の範囲で加撚してなる耐切創性紡績糸を用いてなることを特徴とする防護衣料。
撚係数 K =T /s 1/2 (T :撚数(回/25.4mm)、s:綿番手)

(1) 20 to 95 mass of a para-aramid short fiber A having a single fiber fineness of 2.8 to 8.0 dtex, which is a spun yarn prepared by mixing only two or more kinds of aramid short fibers having different single fiber fineness. %, and a cut-resistant spun yarn containing 5 to 80% by mass of para- aramid short fibers B having a single fiber fineness of 1.0 to 2.7 dtex.
(2) When the mixing ratio of the short fibers A is Y (mass %) and the mixing ratio of the short fibers B is 100-Y (mass %), the following formula (I) is satisfied, and the above (1) is described. Cut resistant spun yarn.
AF×Y≧BF×(100−Y) (I)
(AF: Single fiber fineness (dtex) of short fiber A, BF: Single fiber fineness (dtex) of short fiber B)
(3) The cut resistance spun yarn according to (1) or (2) above, wherein the mixing ratio Y of the short fibers A is 20 to 80% by mass and the mixing ratio of the short fibers B is 20 to 80% by mass. ..
(4) The cut-resistant spun yarn according to any one of (1) to (3) above, wherein the single fiber fineness of the para-aramid short fibers A is 3.2 to 4.8 dtex.
(5) A spun yarn obtained by mixing only two or more kinds of aramid short fibers having different single fiber fineness, and 20 to 95 mass of the para-aramid short fibers A having a single fiber fineness of 2.8 to 8.0 dtex. %, and a single fiber fineness of 5 to 80% by mass of para-aramid short fibers B having a fineness of 1.0 to 2.7 dtex, and a twist coefficient K 2 obtained by the following formula is twisted in a range of 2.5 to 6.0. A protective garment characterized by comprising a cut-resistant spun yarn obtained by .
Twist coefficient K 2 =T 1 /s 1/2 (T 1 : twist number (twists / 25.4 mm), s: cotton count)

(1)単繊維繊度が異なる2種以上のアラミド短繊維を混紡してなる紡績糸であって、
単繊維繊度が2.8〜8.0dtexのパラ系アラミド短繊維Aを20〜95質量%、単繊維繊度が1.0〜2.7dtexのアラミド短繊維Bを5〜80質量%含むことを特徴とする耐切創性紡績糸。
(2)短繊維Aの混率をY(質量%)、短繊維Bの混率を100−Y(質量%)としたとき、下記式(I)を満たすことを特徴とする上記(1)に記載の耐切創性紡績糸。
AF×Y≧BF×(100−Y) (I)
(AF;短繊維Aの単繊維繊度(dtex)、BF;短繊維Bの単繊維繊度(dtex))
(3)短繊維Aの混率Yが20〜80質量%、短繊維Bの混率が20〜80質量%であることを特徴とする上記(1)または(2)に記載の耐切創性紡績糸。
(4)短繊維Bがパラ系アラミド短繊維であることを特徴とする上記(1)〜(3)いずれかに記載の耐切創性紡績糸。
(5)上記(1)〜(4)いずれかに記載の耐切創性紡績糸で構成したことを特徴とする防護衣料。
(1) A spun yarn obtained by mixing two or more types of aramid short fibers having different single fiber fineness,
20 to 95% by mass of para-aramid short fibers A having a single fiber fineness of 2.8 to 8.0 dtex, and 5 to 80% by mass of aramid short fibers B having a single fiber fineness of 1.0 to 2.7 dtex. Cut resistant spun yarn.
(2) When the mixing ratio of the short fibers A is Y (mass %) and the mixing ratio of the short fibers B is 100-Y (mass %), the following formula (I) is satisfied, and the above (1) is described. Cut resistant spun yarn.
AF×Y≧BF×(100−Y) (I)
(AF; short fiber A single fiber fineness (dtex), BF; short fiber B single fiber fineness (dtex))
(3) The cut resistance spun yarn according to (1) or (2) above, wherein the mixing ratio Y of the short fibers A is 20 to 80% by mass and the mixing ratio of the short fibers B is 20 to 80% by mass. ..
(4) The cut-resistant spun yarn according to any of (1) to (3) above, wherein the short fiber B is a para-aramid short fiber.
(5) A protective garment characterized by comprising the cut-resistant spun yarn according to any one of (1) to (4) above.

本発明によれば、太繊度パラ系アラミド短繊維を所定の混率で混紡することにより、切創力が高くかつ柔軟性に優れる耐切創性紡績糸を得ることができる。また、太繊度パラ系アラミド短繊維を所定の混率で混紡することにより、切創力と引張強力のバランスが良好で、かつ柔軟性に優れる耐切創性アラミド紡績糸を得ることができる。これら耐切創性紡績糸は、防護衣料用として好適である。 According to the present invention, a cut-resistant spun yarn having high cut strength and excellent flexibility can be obtained by blending high-definition para-aramid short fibers at a predetermined mixing ratio. Further, by mixing the high-fineness para-aramid short fibers at a predetermined mixing ratio, it is possible to obtain a cut-resistant aramid spun yarn that has a good balance between the cut strength and the tensile strength and is excellent in flexibility. These cut-resistant spun yarns are suitable for protective clothing.

太繊度アラミド短繊維の混率と手袋の耐切創性との関係を示すグラフである。It is a graph which shows the relationship between the mixture ratio of a large fineness aramid short fiber, and the cut resistance of a glove. 太繊度アラミド短繊維の混率と、紡績糸(単糸、双糸)の引張強力×手袋の耐切創性の積との関係を示すグラフである。It is a graph showing the relationship between the mixing ratio of the fineness aramid short fibers and the product of the tensile strength of the spun yarn (single yarn, twin yarn) x the cut resistance of the glove.

以下、本発明の耐切創性紡績糸について詳細を説明する。
本発明の耐切創性紡績糸は、単繊維繊度が異なる2種以上のアラミド短繊維を混紡してなる紡績糸であって、単繊維繊度が2.8〜8.0dtexのパラ系アラミド短繊維Aを20〜95質量%、単繊維繊度が1.0〜2.7dtexのアラミド短繊維Bを5〜80質量%含むことを特徴とする。
Hereinafter, the cut resistant spun yarn of the present invention will be described in detail.
The cut resistant spun yarn of the present invention is a spun yarn obtained by mixing two or more kinds of aramid short fibers having different single fiber fineness, and a para-aramid short fiber having a single fiber fineness of 2.8 to 8.0 dtex. 20 to 95 mass% of A and 5 to 80 mass% of aramid short fibers B having a single fiber fineness of 1.0 to 2.7 dtex.

このような太繊度パラ系アラミド短繊維A(以下、短繊維Aと省略する。)を所定の混率で混紡することにより、単繊維繊度1.0〜2.7dtexのアラミド短繊維B(以下、短繊維Bと省略する。)のみからなる紡績糸に比べて、切創力が高く、かつ柔軟性を有する耐切創性紡績糸を得ることができる。 By mixing and spinning such a large fineness para-aramid short fiber A (hereinafter abbreviated as short fiber A) at a predetermined mixing ratio, an aramid short fiber B having a single fiber fineness of 1.0 to 2.7 dtex (hereinafter, It is possible to obtain a cut-resistant spun yarn having a higher cutting force and flexibility than a spun yarn composed of only short fibers B).

本発明の耐切創性紡績糸による効果は、例えば、後述する実施例の図1及び図2に示されている。即ち、図1に示す如く、短繊維Aの混率を20〜95質量%の範囲内とすることにより、短繊維Aを含まない紡績糸に比べて切創力が高く、かつ柔軟性を有する耐切創性紡績糸を得ることができる。短繊維Aの混率が20質量%未満では、耐切創性紡績糸の切創力が不十分となり、95質量%を超えると、耐切創性紡績糸の柔軟性を確保することが困難になる。短繊維Aの耐切創性紡績糸における混率は、さらに好ましくは20〜80質量%、特に好ましくは35〜70質量%である。短繊維Aの混率を前記範囲内とすることにより、図2に示す如く、耐切創性紡績糸の切創力を低下させることなく、引張強力を向上させた紡績糸が得られる。この耐切創性紡績糸は、切創力を目付で除して100倍した耐切創性と引張強力の積を縦軸、太繊度パラ系アラミド短繊維の混率(対紡績糸)を横軸にとった場合、耐切創性と引張強力の積が極大値を示し、とりわけ、短繊維Aの混率20〜80質量%の範囲においてその効果が顕著になる。 The effect of the cut-resistant spun yarn of the present invention is shown, for example, in FIGS. 1 and 2 of Examples described later. That is, as shown in FIG. 1, by setting the mixing ratio of the short fibers A within the range of 20 to 95% by mass, the cutting resistance is high and the cut resistance is high as compared with the spun yarn containing no short fibers A. An original spun yarn can be obtained. If the mixing ratio of the short fibers A is less than 20% by mass, the cutting resistance of the cut-resistant spun yarn will be insufficient, and if it exceeds 95% by mass, it will be difficult to secure the flexibility of the cut-resistant spun yarn. The mixing ratio of the staple fiber A in the cut resistant spun yarn is more preferably 20 to 80% by mass, and particularly preferably 35 to 70% by mass. By setting the mixing ratio of the short fibers A within the above range, as shown in FIG. 2, a spun yarn having improved tensile strength can be obtained without lowering the cut strength of the cut resistant spun yarn. This cut-resistant spun yarn has the product of cut resistance and tensile strength, which is 100 times the cut force divided by the basis weight, as the vertical axis, and the mixture ratio of large fineness para-aramid short fibers (to the spun yarn) as the horizontal axis. When taken, the product of cut resistance and tensile strength shows a maximum value, and the effect becomes remarkable especially in the range of 20 to 80% by mass of the short fiber A.

本発明の耐切創性紡績糸においては、短繊維Aの単繊維繊度AFは2.8〜8.0dtexの範囲であることが重要であり、単繊維繊度が2.8dtex以上、より好ましくは3.0dtex以上であれば切創力の高い耐切創性紡績糸が得られ、単繊維繊度が8.0dtex以下、より好ましくは5.0dtex以下であれば柔軟性を有する耐切創性紡績糸となり得るからである。短繊維Aの単繊維繊度が耐切創性紡績糸の各特性に及ぼす影響は比較的小さいため、上記範囲内で選択すれば良いが、引張強力の付与及び柔軟性の向上の観点より、短繊維Aの単繊維繊度AFは、さらに好ましくは3.2〜4.8dtexの範囲である。 In the cut resistant spun yarn of the present invention, it is important that the single fiber fineness AF of the short fibers A is in the range of 2.8 to 8.0 dtex, and the single fiber fineness is 2.8 dtex or more, more preferably 3 If it is 0.0 dtex or more, a cut-resistant spun yarn having a high cut strength can be obtained, and if the single fiber fineness is 8.0 dtex or less, more preferably 5.0 dtex or less, a cut-resistant spun yarn having flexibility can be obtained. Because. Since the influence of the single fiber fineness of the short fibers A on each property of the cut resistant spun yarn is relatively small, it may be selected within the above range, but from the viewpoint of imparting tensile strength and improving flexibility, the short fibers The single fiber fineness AF of A is more preferably in the range of 3.2 to 4.8 dtex.

また、本発明の耐切創性紡績糸においては、短繊維Aの混率Y(質量%)、短繊維Bの混率100−Y(質量%)としたとき、下記式(I)を満たすことが好ましい。
AF×Y≧BF×(100−Y) (I)
(AF;短繊維Aの単繊維繊度(dtex)、BF;短繊維Bの単繊維繊度(dtex))
Further, in the cut-resistant spun yarn of the present invention, it is preferable that the following formula (I) is satisfied when the mixing ratio of the short fibers A is Y (mass %) and the mixing ratio of the short fibers B is 100-Y (mass %). ..
AF×Y≧BF×(100−Y) (I)
(AF; short fiber A single fiber fineness (dtex), BF; short fiber B single fiber fineness (dtex))

即ち、AF、Y、BF、100−Yの4要素が上記式(I)を満たすことが好ましく、該式(I)により、短繊維Aにおける単繊維繊度AFと混率Yの積が、短繊維Bにおける単繊維繊度BFと混率(100−Y)の積と同等以上であれば、短繊維の本数に比例して紡績糸の引張強力と切創力が向上するため、引張強力を確保できる耐切創性紡績糸となり得る。一方、上記式(I)を満たさない場合は、切創力を確保することが困難になる。短繊維Aの好ましい比率Yは、短繊維Aの単繊維繊度にもよって若干異なるが、40〜90質量%である。 That is, it is preferable that the four elements of AF, Y, BF, and 100-Y satisfy the above formula (I), and by the formula (I), the product of the single fiber fineness AF and the mixing ratio Y in the short fiber A is short fiber. If the product of the single fiber fineness BF and the mixing ratio (100-Y) in B is equal to or more than the value, the tensile strength and cut strength of the spun yarn are improved in proportion to the number of short fibers. It can be a spun yarn. On the other hand, when the above formula (I) is not satisfied, it becomes difficult to secure the cutting force. The preferable ratio Y of the short fibers A is 40 to 90% by mass, although it varies slightly depending on the single fiber fineness of the short fibers A.

本発明の耐切創性紡績糸では、図1の例より、耐切創性は短繊維Aの混率が約65質量%以上では平衡状態となり、それ以上混率を高くしても耐切創性が直線的に向上しない。このことは、短繊維Aの単繊維繊度(太さ)AFと単繊維本数との積を一定値以上にすれば、耐切創性の確保が可能になる、との推定が成り立ち得る。従って、短繊維Aの単繊維繊度AFと混率Yの積が、短繊維Bの単繊維繊度BFと混率(1−Y)の積よりも大きければ、耐切創性紡績糸を得ることができる。 According to the cut-resistant spun yarn of the present invention, as shown in the example of FIG. 1, the cut-resistance is in an equilibrium state when the mixing ratio of the short fibers A is about 65 mass% or more, and the cutting resistance is linear even if the mixing ratio is further increased. Does not improve to This can be presumed to be able to ensure cut resistance by setting the product of the single fiber fineness (thickness) AF of the short fibers A and the number of single fibers to a certain value or more. Therefore, if the product of the single fiber fineness AF of the short fibers A and the mixing ratio Y is larger than the product of the single fiber fineness BF of the short fibers B and the mixing ratio (1-Y), a cut-resistant spun yarn can be obtained.

一方、短繊維Bの単繊維繊度BFは、1.0〜2.7dtex、より好ましくは1.2〜2.7dtexの範囲であり、混用する短繊維Aの単繊維繊度AFにより、最適な単繊維繊度BFが選択される。耐切創性の向上という観点より、さらに好ましい単繊維繊度BFは1.4〜2.6dtexの範囲である。 On the other hand, the single fiber fineness BF of the short fibers B is in the range of 1.0 to 2.7 dtex, and more preferably 1.2 to 2.7 dtex. The fiber fineness BF is selected. From the viewpoint of improving cut resistance, more preferable single fiber fineness BF is in the range of 1.4 to 2.6 dtex.

本発明の耐切創性紡績糸において、短繊維Bを構成するアラミド繊維としては、メタ系アラミド繊維、パラ系アラミド繊維が、それぞれ単独で、または、組合せて用いられる。ここで、メタ系アラミド繊維としては、例えば、ポリメタフェニレンイソフタルアミド繊維(デュポン社製、商品名「ノーメックス」)が挙げられ、パラ系アラミド繊維としては、ポリパラフェニレンテレフタールアミド繊維(東レ・デュポン社製、商品名「ケブラー」)、コポリパラフェニレン−3,4’−ジフェニルエーテルテレフタルアミド繊維(帝人テクノプロダクツ社製、商品名「テクノーラ」)等が挙げられる。これらのアラミド繊維の中でも、特に、高弾性率で、引張強さ、切創力に優れている点より、パラ系アラミド繊維が好ましい。
また、短繊維Aを構成するパラ系アラミド繊維は、上記のポリパラフェニレンテレフタールアミド繊維(東レ・デュポン社製、商品名「ケブラー」)、コポリパラフェニレン−3,4’−ジフェニルエーテルテレフタルアミド繊維(帝人テクノプロダクツ社製、商品名「テクノーラ」)等のいずれであっても良い。
In the cut resistant spun yarn of the present invention, as the aramid fiber constituting the short fiber B, a meta-aramid fiber and a para-aramid fiber may be used alone or in combination. Here, as the meta-aramid fiber, for example, polymetaphenylene isophthalamide fiber (manufactured by DuPont, trade name "Nomex") can be mentioned, and as the para-aramid fiber, polyparaphenylene terephthalamide fiber (Toray DuPont, trade name "Kevlar"), copolyparaphenylene-3,4'-diphenyl ether terephthalamide fiber (manufactured by Teijin Techno Products, trade name "Technora") and the like. Among these aramid fibers, para-aramid fibers are particularly preferable because they have a high elastic modulus and are excellent in tensile strength and cut strength.
Further, the para-aramid fiber constituting the short fiber A is a polyparaphenylene terephthalamide fiber (manufactured by Toray DuPont, trade name "Kevlar"), a copolyparaphenylene-3,4'-diphenyl ether terephthalamide fiber described above. (Manufactured by Teijin Techno Products Ltd., trade name "Technora") and the like.

短繊維A及び短繊維Bの繊維長は、耐切創性紡績糸の柔軟性及び紡績工程などにおける加工性の観点から、25〜1000mmが好ましく、さらに好ましくは30〜100mm、特に好ましくは30〜65mmである。 The fiber lengths of the short fibers A and the short fibers B are preferably 25 to 1000 mm, more preferably 30 to 100 mm, and particularly preferably 30 to 65 mm from the viewpoint of the flexibility of the cut-resistant spun yarn and the processability in the spinning process and the like. Is.

本発明の耐切創性紡績糸は、捲縮を有する連続糸条または捲縮を有しない連続糸条を短くカットした後、既存の綿紡績、スフ紡績または梳毛紡績設備で製造することができる。紡績糸の太さは、用途にもよるが、通常40s〜5s番手の範囲で好ましく使われる。5s未満では耐切創性紡績糸の加工性が劣り、40sを超えると引張強力に優れる耐切創性紡績糸を得ることが難しくなる。織編物や手袋の編み立てに用いる耐切創性紡績糸の好ましい形態は、紡績糸単糸または紡績糸単糸を2本引きそろえて紡績糸単糸と逆方向に撚糸した紡績糸双糸である。紡績糸双糸の番手は、40/2s〜5/2sが望ましく、前記範囲内であれば加工性が著しく損なわれることがない。
なお、英式綿番手は、453.6g(1ポンド)あたりの糸の長さが768.10m(840ヤード)のものを1番手といい、糸が細くなると番手数が大きくなる。
The cut-resistant spun yarn of the present invention can be produced by existing cotton spinning, soft spinning or worsted spinning equipment after short cutting of continuous yarn having crimps or continuous yarn having no crimps. Although the thickness of the spun yarn depends on the application, it is usually preferably used in the range of 40s to 5s. If it is less than 5 s, the workability of the cut-resistant spun yarn is poor, and if it exceeds 40 s, it becomes difficult to obtain a cut-resistant spun yarn having excellent tensile strength. A preferred form of the cut-resistant spun yarn used for knitting woven or knitted fabrics or gloves is a spun yarn single yarn or a spun yarn twin yarn in which two spun yarn single yarns are aligned and twisted in the opposite direction to the spun yarn single yarn. .. The yarn count of the spun yarn twin yarn is preferably 40/2s to 5/2s, and within the above range, the workability is not significantly impaired.
It should be noted that the English cotton count has a yarn length of 768.10 m (840 yards) per 453.6 g (1 lb) is called the 1st count, and the thinner the yarn, the larger the count.

本発明の耐切創性紡績糸を得るには、単糸及び双糸は、次式で求められる撚係数(K)が2.5〜6.0の範囲で加撚することが好ましい。撚係数(K)が2.5より小さいと、アラミド短繊維同士の絡みが弱くなりすぎ、該短繊維の端部が紡績糸からはみ出し、ちくちく感の多い織編物となり易い。一方、撚係数(K)が6.0より大きいと、強撚になりすぎて二重撚の発生が強くなって加工性が悪化し、耐切創性紡績糸の引張強度も低下し、また風合いが悪化する傾向がある。より好ましい撚係数(K)は2.5〜3.5の範囲である。耐切創性紡績糸単糸の撚方向は、S、Zのいずれでもよい。双糸の撚り方向は単糸の撚り方向と逆が好ましい。 In order to obtain the cut-resistant spun yarn of the present invention, it is preferable that the single yarn and the double yarn are twisted in a twist coefficient (K 2 ) calculated by the following formula in a range of 2.5 to 6.0. If the twist coefficient (K 2 ) is less than 2.5, the entanglement between the aramid short fibers becomes too weak, and the ends of the short fibers tend to stick out of the spun yarn, resulting in a woven and knitted fabric with a lot of tingling. On the other hand, when the twist coefficient (K 2 ) is more than 6.0, the strength becomes excessively strong, the double twist is strongly generated, the workability is deteriorated, and the tensile strength of the cut-resistant spun yarn is also decreased. The texture tends to deteriorate. A more preferable twist coefficient (K 2 ) is in the range of 2.5 to 3.5. The twist direction of the cut-resistant spun yarn single yarn may be either S or Z. The twisting direction of the twin yarn is preferably opposite to the twisting direction of the single yarn.

撚係数 K=T/s1/2
:撚数(回/25.4mm)
s :綿番手
Twisting coefficient K 2 =T 1 /s 1/2
T 1 : Number of twists (times/25.4 mm)
s: Cotton count

また本発明の防護衣料は、本発明の耐切創性紡績糸100%で構成することが、該紡績糸が有する高い切創力、引張強力と言った優れた特性が遺憾なく発揮される点で好ましいが、交織交編のように他の繊維や糸との併用でもよい。好ましくは、耐切創性紡績糸が織物や編物等製品全体の重量のうち、70〜100%の範囲とするのがよい。
The protective clothing of the invention, in that it consist of cut resistant yarn of 100% of the present invention, a high switching-creation of the spun yarn has a strong and said excellent properties tensile is exerted regret without Although preferred, it may be used in combination with other fibers or yarns such as interwoven or interwoven knitting. Preferably, the cut-resistant spun yarn is in the range of 70 to 100% of the weight of the entire product such as woven fabric and knitted fabric.

さらに、本発明の防護衣料は、全てを、本発明の耐切創性紡績糸で構成してもよく、またはそれらを部分的に使用することでもよい。例えば、作業用手袋では、作業内容により指先部分や手の平部分だけのように、特定の部分に本発明の耐切創性紡績糸や織編物等を使うことができる。織編物や防護材、防護衣料には、必要に応じ、樹脂コーティングを施すこともできる。
Further, the protective garment of the present invention may be composed entirely of the cut resistant spun yarn of the present invention, or may be a partial use thereof. For example, in work gloves, the cut-resistant spun yarn or woven or knitted fabric of the present invention can be used in a specific portion such as a fingertip portion or a palm portion depending on the work content. A resin coating may be applied to the woven or knitted fabric, the protective material, and the protective clothing, if necessary.

本発明の耐切創性紡績糸及び防護衣料は、厳しい使用環境条件が要求される用途に特に適している。これには、直接防護目的として使用されるものは勿論、結果的に防護機能が果たされるものも含まれ、具体的には、作業用または工業用手袋、腕カバー、前掛け、足首カバーの他、作業靴、地下足袋、溶接用作業衣;スポーツ用として、スポーツ用上着、同ズボン、同シューズ、野球やサッカー用のソックス、フェンシングユニフォーム;消防服、溶接作業用カーテン;消防用ホース、タイヤコード、椅子張布、各種補強布等が挙げられるが、これらに限定されるものではない。 The cut-resistant spun yarn and protective clothing of the present invention are particularly suitable for applications that require severe environmental conditions. This includes not only those used for direct protection purposes, but also those that eventually fulfill the protective function. Specifically, other than work or industrial gloves, arm covers, apron, ankle covers, Work shoes, basement socks, work clothes for welding; for sports, sports outerwear, pants, shoes, baseball and soccer socks, fencing uniforms; firefighting clothes, welding work curtains, fire hoses, tire cords , Chair upholstery cloth, various reinforcing cloths, etc., but not limited thereto.

以下、実施例及び比較例を用いて本発明を更に具体的に説明するが、本発明は以下の実施例のみに限定されるものではない。なお、以下の実施例及び比較例における各特性値の測定方法は次の通りである。 Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples. In addition, the measuring method of each characteristic value in the following Examples and Comparative Examples is as follows.

[紡績糸の試験方法]
JIS L 1095:2010「一般紡績糸試験方法」9.5(単糸引張強さ及び伸び率)JIS法 a)標準時、9.8(引掛強さ)に準拠し、紡績糸単糸及び紡績糸双糸の引張強力を評価した。引張試験機にて、つかみ間隔250mm、引張速度300mm/minで試料が切断したときの荷重(N)を測定した。
[Test method for spun yarn]
JIS L 1095:2010 "General spun yarn test method" 9.5 (single yarn tensile strength and elongation) JIS method a) Standard time, 9.8 (hooking strength), spun yarn single yarn and spun yarn twin The tensile strength of the yarn was evaluated. A tensile tester was used to measure the load (N) when the sample was cut at a gripping interval of 250 mm and a pulling speed of 300 mm/min.

[切創力および耐切創性(切れ難さ:Cut resistance)]
JIS T 8052:2005「防護服−機械的特性−鋭利物に対する切創抵抗性試験方法」に準拠し、手袋の手の平部の切創力(N)を測定した。切創力(N)を織編物の目付(g/m)で除して100倍し、耐切創性を求めた。耐切創性の値が大きいほど切れ難いと判定した。
[Cut resistance and cut resistance (cut resistance)]
The cutting force (N) of the palm of the glove was measured according to JIS T 8052:2005 "Protective clothing-Mechanical properties-Test method for cutting resistance to sharp objects". 100 multiplied by divided by SetsuSoryoku (N) of woven or knitted fabric basis weight (g / m 2), was determined cut resistance. The larger the cut resistance value, the more difficult it was to cut.

[柔軟性]
実施例および比較例で作成した手袋を着用した際の装着感および手指の動作性(動かし易さ、曲げ易さ)について判定し、柔らかくかつ手指の動作性が良いものを「○」、硬いものを「×」と判定した。
[Flexibility]
Judgment when wearing gloves produced in Examples and Comparative Examples and operability of fingers (ease of movement, easiness of bending) were judged, and those with softness and good operability of fingers were evaluated as "○", and those with good hardness. Was determined to be "x".

(実施例1〜3、比較例1〜2)
太繊度パラ系アラミド短繊維Aとして、東レ・デュポン社製パラ系アラミド繊維ステープル(商品名Kevlar(R)、引張強度15.7cN/dtex、限界酸素指数29、単繊維繊度3.33dtex、繊維長51mm、捲縮数8山/2.54cm)を使用した。
普通アラミド短繊維Bとして、東レ・デュポン社製パラ系アラミド繊維ステープル(商品名Kevlar(R)、引張強度17.6cN/dtex、限界酸素指数29、単繊維繊度1.67dtex、繊維長51mm、捲縮数8山/2.54cm)を使用した。
(Examples 1-3, Comparative Examples 1-2)
As the high fineness para-aramid short fiber A, a para-aramid fiber staple manufactured by Toray DuPont (trade name Kevlar (R), tensile strength 15.7 cN/dtex, limiting oxygen index 29, single fiber fineness 3.33 dtex, fiber length 51 mm, crimp number 8 peaks/2.54 cm) were used.
As ordinary aramid short fiber B, para-aramid fiber staple manufactured by Toray DuPont (trade name Kevlar (R), tensile strength 17.6 cN/dtex, limiting oxygen index 29, single fiber fineness 1.67 dtex, fiber length 51 mm, winding A reduction factor of 8 peaks/2.54 cm) was used.

太繊度パラ系アラミド短繊維Aと、普通パラ系アラミド短繊維Bを、表1に示す所定の比率(質量比)にて、常法により、打綿工程で混ぜ合わせた後、紡績工程の梳綿、練条、粗紡、リング精紡の各工程を通し、撚り数13.0(回/2.54cm)、撚り方向Zの紡績糸20s(綿番手・単糸)を作製した。撚り係数K=2.9である。 The high-fineness para-aramid short fibers A and the ordinary para-aramid short fibers B are mixed in the cotton-blowing process by a conventional method at a predetermined ratio (mass ratio) shown in Table 1, and then a card in the spinning process. A spun yarn 20s (cotton count/single yarn) having a twist number of 13.0 (twists/2.54 cm) and a twist direction Z was produced through each process of cotton, kneading, roving, and ring spinning. The twisting coefficient K is 2.9.

得られた紡績糸(単糸)を2本引き揃え、撚り数8.4(回/2.54cm)で単糸と逆方向のS方向に撚糸して、双糸20/2sを得た。撚り係数K=2.7である。撚数比率(双糸撚数/単糸撚数)は65%とした。 Two spun yarns (single yarns) thus obtained were aligned and twisted in the S direction opposite to the single yarn at a twist number of 8.4 (twists/2.54 cm) to obtain a double yarn 20/2s. The twisting coefficient K is 2.7. The twist number ratio (twisted yarn twist number/single yarn twist number) was set to 65%.

次に、得られた紡績糸(20/2s)を5本、7ゲージタイプの手袋編み機(株式会社島精機製作所)に供給して、手の平部の目付520〜570g/mの手袋を編みあげた。 Next, 5 spun yarns (20/2s) obtained were supplied to a 7-gauge type glove knitting machine (Shima Seiki Seisakusho Co., Ltd.) to knit a glove having a palm weight of 520 to 570 g/m 2. It was

(実施例4)
太繊度パラ系アラミド短繊維Aとして、実施例1で用いたものと同じ単繊維繊度3.33dtexのパラ系アラミド繊維ステープルを使用した。
アラミド短繊維Bとして、東レ・デュポン社製パラ系アラミド繊維ステープル(商品名Kevlar(R)、引張強度18.1cN/dtex、限界酸素指数29、単繊維繊度1.2dtex、繊維長51mm、捲縮数8山/2.54cm)を使用した。
実施例1と同様の方法で紡績糸20s(綿番手・単糸)を作製し、それを本引き揃え、実施例1と同様の条件で撚糸して、双糸20/2sを得た。得られた紡績糸(20/2s)を5本、7ゲージタイプの手袋編み機(株式会社島精機製作所)に供給して、表1に示す目付の手袋を編みあげた。
(Example 4)
As the high-fineness para-aramid short fiber A, the same para-aramid fiber staple having a single-fiber fineness of 3.33 dtex as used in Example 1 was used.
As the aramid short fiber B, a para-aramid fiber staple manufactured by Toray DuPont (trade name Kevlar (R), tensile strength 18.1 cN/dtex, limiting oxygen index 29, single fiber fineness 1.2 dtex, fiber length 51 mm, crimped) Several 8 peaks/2.54 cm) were used.
20s of spun yarns (cotton count/single yarn) were produced in the same manner as in Example 1, and the yarns were aligned and twisted under the same conditions as in Example 1 to obtain 20/2s double yarns. Five spun yarns (20/2s) thus obtained were supplied to a 7-gauge type glove knitting machine (Shima Seiki Seisakusho Co., Ltd.) to knit gloves with a weight shown in Table 1.

(実施例5)
アラミド短繊維Bとして、東レ・デュポン社製パラ系アラミド繊維ステープル(商品名Kevlar(R)、引張強度16.8cN/dtex、限界酸素指数29、単繊維繊度2.5dtex、繊維長51mm、捲縮数8山/2.54cm)を使用した以外は、実施例4と同様にして紡績糸を作製し、得られた紡績糸(20/2s)を5本、7ゲージタイプの手袋編み機(株式会社島精機製作所)に供給して、表1に示す目付の手袋を編みあげた。
(Example 5)
As the aramid short fiber B, a para-aramid fiber staple manufactured by Toray DuPont (trade name Kevlar (R), tensile strength 16.8 cN/dtex, limiting oxygen index 29, single fiber fineness 2.5 dtex, fiber length 51 mm, crimped) A spun yarn was produced in the same manner as in Example 4 except that several ridges/2.54 cm) were used, and 5 spun yarns (20/2s) obtained were used for a 7 gauge type glove knitting machine (K.K. Shima Seiki Seisakusho) and knitted the gloves with the fabric weight shown in Table 1.

実施例および比較例で得られた紡績糸、およびそれを用いて編み上げた手袋を、前記試験法により評価した結果を表1に示す。
また、実施例1〜3および比較例1〜2において、太繊度短繊維Aの混率と耐切創性との関係を図1に、太繊度短繊維Aの混率と紡績糸(単糸、双糸)の引張強力×手袋の耐切創性との関係を図2に示す。
Table 1 shows the results of evaluation of the spun yarns obtained in Examples and Comparative Examples and the gloves knitted with the spun yarns by the above-described test method.
In addition, in Examples 1 to 3 and Comparative Examples 1 and 2, the relationship between the mixing ratio of the large fineness short fibers A and the cut resistance is shown in FIG. 1, and the mixing ratio of the large fineness short fibers A and the spun yarn (single yarn, twin yarn). Fig. 2 shows the relationship between (1) tensile strength x glove cut resistance.


Figure 0006710008
Figure 0006710008

表1及び図1の結果より、実施例1〜3で作製した手袋は、ソフトでボリューム感豊かな風合いを有していて、短繊維Aの混率80質量%までは、混率が高くなるにしたがい手袋の耐切創性が向上した。短繊維Aの混率が80質量%を超えても、手袋の耐切創性は維持されていた。一方、紡績糸の引張強力は、短繊維Aの混率が増加するにしたがいほぼ直線的に低下する傾向が認められた。 From the results of Table 1 and FIG. 1, the gloves produced in Examples 1 to 3 have a soft and rich texture, and the mixing ratio becomes higher up to the mixing ratio of the short fibers A of 80% by mass. Cut resistance of gloves is improved. Even if the mixing ratio of the short fibers A exceeds 80% by mass, the cut resistance of the gloves was maintained. On the other hand, it was recognized that the tensile strength of the spun yarn decreased almost linearly as the mixing ratio of the short fibers A increased.

また、太繊度パラ系アラミド短繊維Aと混綿する短繊維Bの単繊維繊度を変えた場合(実施例4、5)も、ソフトでボリューム感豊かな風合いを有する手袋が得られ、手袋の耐切創性が向上した。短繊維Aと混綿する短繊維Bの単繊維繊度が大きくなるほど、手袋の耐切創性はやや高くなる傾向があり、反対に紡績糸の引張強力は低下する傾向が認められた。 Also, when the single fiber fineness of the short fiber B mixed with the thick fineness para-aramid short fiber A is changed (Examples 4 and 5), a glove having a soft and rich texture is obtained, and the cut resistance of the glove is improved. Creativity improved. The larger the monofilament fineness of the short fibers B mixed with the short fibers A, the higher the cut resistance of the glove tends to be, whereas the tensile strength of the spun yarn tends to be decreased.

さらに、図2より、耐切創性と紡績糸双糸の引張強力の積は、短繊維Aの混率50〜80質量%にピークが認められ、とりわけ、短繊維Aの混率50〜70質量%の範囲では、切創力、引張強力及び柔軟性を兼備する紡績糸が得られていることが分かる。 Further, from FIG. 2, the product of the cut resistance and the tensile strength of the spun yarn twin yarn shows a peak at a mixing ratio of the short fibers A of 50 to 80% by mass, and in particular, a mixing ratio of the short fibers A of 50 to 70% by mass. In the range, it can be seen that a spun yarn having cut strength, tensile strength and flexibility is obtained.

本発明の耐切創性紡績糸及びそれで構成した織編物は、消防服、レーシングスーツ、製鉄・溶接用作業服、手袋などの防護衣料として好適に用いられる。
The cut-resistant spun yarn of the present invention and the woven/knitted fabric formed thereof are preferably used as protective clothing such as fire fighting clothes, racing suits, iron/welding work clothes, and gloves.

Claims (5)

単繊維繊度が異なる2種以上のアラミド短繊維のみを混紡してなる紡績糸であって、単繊維繊度が2.8〜8.0dtexのパラ系アラミド短繊維Aを20〜95質量%、単繊維繊度が1.0〜2.7dtexのパラ系アラミド短繊維Bを5〜80質量%含むことを特徴とする耐切創性紡績糸。 A spun yarn obtained by mixing only two or more kinds of aramid short fibers having different single fiber fineness, and a single fiber fineness of ara-aramid short fibers A having a single fiber fineness of 2.8 to 8.0 dtex is 20 to 95% by mass. A cut-resistant spun yarn comprising 5 to 80% by mass of a para- aramid short fiber B having a fiber fineness of 1.0 to 2.7 dtex. 短繊維Aの混率をY(質量%)、短繊維Bの混率を100−Y(質量%)としたとき、下記式(I)を満たすことを特徴とする請求項1に記載の耐切創性紡績糸。
AF×Y≧BF×(100−Y) (I)
(AF;短繊維Aの単繊維繊度(dtex)、BF;短繊維Bの単繊維繊度(dtex))
The cut resistance according to claim 1, wherein when the mixing ratio of the short fibers A is Y (mass %) and the mixing ratio of the short fibers B is 100-Y (mass %), the following formula (I) is satisfied. Spun yarn.
AF×Y≧BF×(100−Y) (I)
(AF: Single fiber fineness (dtex) of short fiber A, BF: Single fiber fineness (dtex) of short fiber B)
短繊維Aの混率Yが20〜80質量%、短繊維Bの混率が20〜80質量%であることを特徴とする請求項1または2に記載の耐切創性紡績糸。 The cut resistant spun yarn according to claim 1 or 2, wherein the mixing ratio Y of the short fibers A is 20 to 80% by mass and the mixing ratio of the short fibers B is 20 to 80% by mass. パラ系アラミド短繊維Aの単繊維繊度が3.2〜4.8dtexであることを特徴とする請求項1〜3いずれかに記載の耐切創性紡績糸。 The cut-resistant spun yarn according to any one of claims 1 to 3, wherein the single fiber fineness of the para-aramid short fibers A is 3.2 to 4.8 dtex. 単繊維繊度が異なる2種以上のアラミド短繊維のみを混紡してなる紡績糸であって、単繊維繊度が2.8〜8.0dtexのパラ系アラミド短繊維Aを20〜95質量%、単繊維繊度が1.0〜2.7dtexのパラ系アラミド短繊維Bを5〜80質量%含み、次式で求められる撚係数K が2.5〜6.0の範囲で加撚してなる耐切創性紡績糸を用いてなることを特徴とする防護衣料。
撚係数 K =T /s 1/2 (T :撚数(回/25.4mm)、s:綿番手)
A spun yarn obtained by mixing and spinning only two or more aramid short fibers having different single fiber fineness, and a single fiber fineness of ara-aramid short fibers A having a single fiber fineness of 2.8 to 8.0 dtex is 20 to 95% by mass. 5 to 80% by mass of para-aramid short fibers B having a fiber fineness of 1.0 to 2.7 dtex, and twisted in a twist coefficient K 2 of 2.5 to 6.0 calculated by the following formula. Protective clothing characterized by using cut-resistant spun yarn .
Twist coefficient K 2 =T 1 /s 1/2 (T 1 : twist number (twists / 25.4 mm), s: cotton count)
JP2016030643A 2016-02-22 2016-02-22 Cut resistant spun yarn Active JP6710008B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2016030643A JP6710008B2 (en) 2016-02-22 2016-02-22 Cut resistant spun yarn

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2016030643A JP6710008B2 (en) 2016-02-22 2016-02-22 Cut resistant spun yarn

Publications (3)

Publication Number Publication Date
JP2017150096A JP2017150096A (en) 2017-08-31
JP2017150096A5 JP2017150096A5 (en) 2019-03-07
JP6710008B2 true JP6710008B2 (en) 2020-06-17

Family

ID=59740407

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2016030643A Active JP6710008B2 (en) 2016-02-22 2016-02-22 Cut resistant spun yarn

Country Status (1)

Country Link
JP (1) JP6710008B2 (en)

Also Published As

Publication number Publication date
JP2017150096A (en) 2017-08-31

Similar Documents

Publication Publication Date Title
US9121115B2 (en) Yarn, a process for making the yarn, and products containing the yarn
JP2021143453A (en) Cut resistant, tear resistant and/or abrasion resistant fabric and lightweight protective clothing made therefrom
US5248548A (en) Stainless steel yarn and protective garments
KR100655831B1 (en) Comfortable Cut-Abrasion Resistant Fiber Composition
CA2663184C (en) Multidenier fiber cut resistant fabrics and articles and processes for making same
JP2016132841A (en) Blended yarn
JP3437887B2 (en) Spun yarn, fiber structure and protective material with excellent flexibility and cut resistance
JP2005256212A (en) Heat resistant compound yarn and fabric using the same
US20040064865A1 (en) Cut resistant fabric and glove
JP6744687B2 (en) Mixed knit and mixed gloves
US20080085646A1 (en) Multidenier fiber cut resistant fabrics and articles and processes for making same
JP6710008B2 (en) Cut resistant spun yarn
JP2003147651A (en) Heat-resistant composite spun yarn and fabric using the same
JP6465480B2 (en) Spun yarn, fiber structures and protective materials
JP6351169B2 (en) Long / short composite spun yarn and woven / knitted fabric / protective material using the same
JP4256039B2 (en) Composite yarn, fiber structure and manufacturing method thereof
JP2005248345A (en) Knitted fabric having excellent cutting resistance, and utilization thereof
JP6685071B2 (en) Crimped aramid staple fiber, high-strength spun yarn made of the same, fiber structure and protective material
JP7489749B2 (en) Fabric for protective products and textile products using same
JP2004060112A (en) Spun yarn having excellent wound-proofness
JPH08109530A (en) Spun yarn excellent in cutting resistance, heat resistance and abrasion resistance and knitted or woven fabric using the same
JP2017082351A (en) Spun yarn, and woven or knitter fabric
JP2023047523A (en) Composite yarn and fabric formed of the same
PL217696B1 (en) Barrier fabric with biophysical properties protecting against toxic allergenic dusts

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20190124

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20190124

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20191011

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20191029

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20191224

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20200525

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20200525

R150 Certificate of patent or registration of utility model

Ref document number: 6710008

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250