JP2021161121A - Composition - Google Patents

Abstract

To provide a composition which contains a large amount of niacinamide and a compound having a hydroxy group and has excellent sense of use without stickiness and an excellent inhibitory effect on crystal deposition.SOLUTION: There is provided a composition which comprises the following components (A) to (C): (A) 1 to 10 mass% of niacinamide, (B) a compound having a hydroxy group, (C) tranexamic acid and further preferably comprises a component (D) silica and/or octenylsuccinate corn starch Al, where the content mass ratio (A)/(D) between the component (A) and the component (D) preferably is 0.5 to 10.SELECTED DRAWING: None

Description

The present invention relates to a composition that is not sticky and has an excellent feel in use and has an excellent effect of suppressing crystal precipitation.

The skin causes stains, wrinkles, sagging, pigmentation, etc. due to internal factors such as aging and stress, and external factors such as ultraviolet rays and dry air. Among them, morphological changes such as wrinkles and sagging greatly affect the impression of appearance, so many people want to improve it. Many drugs have been proposed to prevent and improve these wrinkles and sagging. Under these circumstances, niacinamide is a vitamin and is known to be highly safe, have a rough skin improving effect and a keratin improving effect, and improve the firmness and elasticity of the skin (for example, Patent Document 1, Patent Document 1, 2). Further, niacinamide is known to have a whitening effect in addition to the rough skin improving effect and the keratin improving effect (see, for example, Patent Document 3). However, it has been known that when a large amount of niacinamide is contained, there is an undesired feeling of use such as stickiness (see, for example, Patent Documents 2 and 4). Further, when a composition containing more than 1% by mass of niacinamide is used, crystals of niacinamide may precipitate on the skin surface or the side surface of the container in which the composition hangs down, and these have been improved (these have been improved). For example, see Patent Document 5).

Japanese Unexamined Patent Publication No. 10-130135 Japanese Unexamined Patent Publication No. 2012-041302 JP-A-2007-176810 Special Table 2003-502435 Special Table 2002-537241

However, in the techniques of Patent Documents 2 and 4 for suppressing stickiness due to a large amount of niacinamide, crystals may be precipitated when a large amount of niacinamide is contained. On the other hand, the technique of Patent Document 5 for suppressing crystal precipitation is a technique of using a cation-containing polymer, but the stickiness may increase and the feeling of use may be poor. In addition, when a compound having a polar group such as a hydroxy group is contained in order to impart a moisturizing function, an ultraviolet protection function, or the like, the stickiness may be further increased.

Therefore, it is an object of the present invention to provide a composition containing a large amount of niacinamide and a compound having a hydroxy group, which is not sticky and has an excellent feel in use and an excellent effect of suppressing crystal precipitation.

In view of such circumstances, the present inventor has conducted intensive studies to solve the above problems, and as a result, by combining tranexamic acid with a composition containing niacinamide and a compound having a hydroxy group, niacinamide and a hydroxy group It has been found that the stickiness of the compound having the above can be suppressed and the effect of suppressing crystal precipitation is excellent.

That is, the present invention
(A) Niacinamide 1-10% by mass
It provides a composition containing (B) a compound having a hydroxy group (C) tranexamic acid.

The composition in which the component (B) is one or more organic ultraviolet absorbers selected from hexyl diethylaminohydroxybenzoylbenzoate, bisethylhexyloxyphenol methoxyphenyltriazine, and sodium hydroxymethoxybenzophenone sulfonate. Is to provide.

It also provides the composition in which the component (B) is one or more moisturizers selected from sorbitol, maltitol, and mannitol.

Further, it provides the composition containing the component (D) silica and / or corn starch Al octenyl succinate.

Further, the composition provides the composition in which the content mass ratio (A) / (D) of the component (A) and the component (D) is 0.5 to 10.

Although the composition of the present invention contains niacinamide and a compound having a hydroxy group, it has an effect of suppressing stickiness and crystal precipitation and having an excellent effect of smooth spreading and spreading.

Details of the present invention will be described below.
The niacinamide of the component (A) used in the present invention is an amide compound of nicotinic acid (vitamin B3 / niacin). Niacinamide is a water-soluble vitamin, which is a known substance belonging to the B vitamin group, and can be extracted from a natural product (rice bran, etc.) or synthesized by a known method. Specifically, those listed in the 17th revised Japanese Pharmacopoeia can be used.

The content of the component (A) used in the present invention is 1 to 10% by mass (hereinafter, simply "mass%" is abbreviated as "%"), preferably 3 to 10%, and 4 to 9%. Especially preferable. When the content of the component (A) exceeds 10%, the stickiness at the time of application is strong and the usability is inferior.

The compound having a hydroxy group of the component (B) of the present invention refers to a compound having a hydroxy group in the structure. It is not particularly limited as long as it is a compound having a hydroxy group and is used for ordinary skin external preparations, cosmetics and the like. Examples thereof include oily components such as ester oils and fatty acids, phenols, aqueous components, water-soluble thickeners, alcohols, etc., but from the viewpoint of imparting functionality to the composition, they must be organic ultraviolet absorbers and moisturizers. As the organic ultraviolet absorber, hexyl diethylaminohydroxybenzoyl benzoate, bisethylhexyloxyphenol methoxyphenyl triazine, and sodium hydroxymethoxybenzophenone sulfonate are preferable, and sugar alcohol is preferable as the moisturizing agent, and sorbitol, martitol, and the like are particularly preferable. Mannitol is preferred.

Examples of commercially available products of the organic ultraviolet absorber include UVINUL A PLUS (manufactured by BASF), TINOSORBS (manufactured by BASF), ASL-24S (manufactured by Sankyo Kasei) and the like.

The content of the component (B) used in the present invention is not particularly limited, but from the viewpoint of imparting functionality such as an ultraviolet protection effect and a moisturizing effect to the composition, and from the viewpoint of suppressing crystal precipitation of the component (A). The content of the component (B) is preferably more than 0.1%, particularly preferably 1% or more. Further, from the viewpoint of suppressing stickiness, 10% or less is preferable, and 5% or less is particularly preferable. The component (B) may be used alone or in combination of two or more, but it is more preferable to use two or more in combination from the viewpoint of smooth expansion and spread.

Tranexamic acid, the component (C) of the present invention, is a kind of amino acid represented by the chemical name: trans-4- (aminomethyl) cyclohexane-1-carboxylic acid, and has a whitening effect and anti-hemoasis on the skin as described above. In addition to being known as a component having an inflammatory effect, it may also be used as a hemostatic agent.

The content of the component (C) used in the present invention is not particularly limited, but is preferably 0.1 to 5%, more preferably 1 to 2% from the viewpoint of suppressing stickiness.

Further, in the present invention, by further containing silica and / or corn starch Al octenyl succinate as the component (D), stickiness is suppressed and a composition having a smooth spread and spread can be obtained.

The corn starch Al octenyl succinate used in the present invention is obtained by hydrophobizing corn starch powder, and the average particle size is not particularly limited, but is preferably 1 to 100 μm, more preferably 2 to 10 μm. Further, the particle shape of the corn starch Al octenyl succinate is not particularly limited, but may be amorphous or spherical, and one or a combination of two or more may be used.

In the present invention, the average particle size is measured as a volume average particle size (D50) using a laser-type dry particle size distribution measuring device (PRO7000S manufactured by Seishin Enterprise Co., Ltd., etc.).

The silica used in the present invention is a fine powder crystal of silica which is silicon dioxide, and is not particularly limited as long as it is used for ordinary skin external preparations, cosmetics and the like. The average particle size is not particularly limited, but is preferably 1 to 100 μm, more preferably 1 to 40 μm. Further, the particle shape of silica may be any of amorphous and spherical, and is not particularly limited, but spherical is preferable. Further, the presence or absence of pores is not particularly limited, but porous is preferable. It is also possible to use one type or a combination of two or more types. As a commercial product
As amorphous silicic acid anhydride, Silicia 350, 550 (average particle size 4 μm, porous), 770 (average particle size 7 μm, porous) (all manufactured by Fuji Silysia Chemical Ltd.), as spherical silicon dioxide, Godball E -6C, E-16C, D-11C, D-25C, D11-796C (average particle size 4 μm, porous), E2-824C (average particle size 2 μm, porous), Godball E-90C (average particle size) 20-40 μm, porous) (above, manufactured by Suzuki Oil & Fat Industry Co., Ltd.), Sunsphere H-31, H-51, H-32, H-52, Sunsphere H-201 (above, manufactured by AGC SItec), Examples thereof include silica microbead P-1505 (average particle size 12 μm, porous), silica microbead P-500, and silica microbead P-4000 (all manufactured by JGC Catalysts and Chemicals Ltd.). These silicas may be used with their surfaces untreated or may be subjected to various treatments.

The content of the component (D) used in the present invention is not particularly limited, but is preferably 0.1% to 10%, more preferably 0.4% to 7%, from the viewpoint of suppressing stickiness and smooth spreading and spreading. preferable. The component (D) may be used alone or in combination of two or more, but it is more preferable to use two or more in combination from the viewpoint of smooth expansion and spread.

The content ratios (A) / (D) of the components (A) and (D) used in the present invention are not particularly limited, but are preferably 0.2 to 15, more preferably 0.5 to 10. Within this range, a composition particularly excellent in smooth spreading and spreading can be obtained.

In addition to the above components, the composition of the present invention includes optional components contained in ordinary cosmetics and external skin preparations as long as the effects of the present invention are not impaired, that is, oils other than the component (B) of the present invention. , Water-soluble polymer, film-forming agent, surfactant, ultraviolet absorber, oil-soluble gelling agent, powder other than component (D), organically modified clay mineral, resin, preservative, antibacterial agent, fragrance, antioxidant It can contain agents, pH adjusters, chelating agents and the like.

In addition, the composition of the present invention includes an aqueous mixture type, an oil-in-water emulsification type, an oil-in-oil emulsification type, a solubilization type, an oil-in-water emulsification type, a multi-layer type, and the like. An oil-in-water emulsified type emulsified composition is preferable from the viewpoint of suppressing crystal precipitation and smooth spreading and spreading of A). Further, the method for producing the composition of the present invention can be produced without particular limitation by using a known method depending on the dosage form.

The composition of the present invention can be used as a cosmetic for various purposes. For example, skin care cosmetics such as lotions, milky lotions, creams, eye creams, beauty essences, massage agents, packs, hand creams, body creams, sunscreen cosmetics, liquid foundations, makeup base cosmetics, eye shadows, etc. Makeup cosmetics can be exemplified. Examples of the method of use include a method of using it with hands and fingers, and a method of impregnating a non-woven fabric or the like in the case of skin care cosmetics.

The composition of the present invention can also be used as an external preparation for skin. For example, methods such as external liquids, external gels, creams, ointments, liniments, lotions, haptics, plasters, sprays, and aerosols can be mentioned. Moreover, the usage method can be mentioned in the same manner as the above-mentioned cosmetics.

Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.

Example 1: Products 1 to 16 of the present invention and Comparative products 1 to 10: Oil-in-water emulsified emulsion The oil-in-water emulsified emulsion having the composition shown in Tables 1 to 3 was prepared by the following production method, and "(a) Crystal precipitation". Each item of "suppressive effect", "(b) non-stickiness", and "(c) smooth elongation and spread" was evaluated and judged by the following evaluation methods and judgment criteria, and the results are also shown in Tables 1 to 3. rice field.

(Production method)
A: Ingredients (1) to (10) are uniformly mixed at room temperature.
B: Ingredients (11) to (14) are uniformly mixed at 70 ° C.
C: While stirring A at 70 ° C., B was added and emulsified, and the components (15) to (16) were uniformly mixed to obtain an oil-in-water emulsified emulsion.

(Evaluation method)
<(A) Crystal precipitation suppressing effect>
For products 1 to 16 of the present invention and products 1 to 10 of the comparative products, a sample was applied onto a glass plate with a film thickness of 800 μm using a doctor blade, air-dried at 20 ° C. for 15 minutes, and each sample was observed under a microscope. .. The crystal precipitation state was observed with a polarizing filter at a magnification of 40 times with an optical microscope.

[criterion]
[Judgment]: [Evaluation]
⊚: No crystal precipitation is observed.
◯: A slight amount of crystal precipitation is observed.
X: Crystal precipitation is clearly seen.

(Evaluation method)
<(B) Non-sticky>
After washing their faces, 20 cosmetics specialist panels picked up about 2 g of the products 1 to 16 of the present invention and products 1 to 10 of the comparative products, and applied them to both cheeks for about 60 seconds while massaging them in a circular motion. The stickiness of the cheeks after minutes was evaluated on a 5-point scale according to the following evaluation criteria (I), and the average score of all panels was further evaluated according to the following criteria (II).

[Evaluation Criteria (I)]
[Evaluation result]: [Score]
No stickiness: 5 points Almost no stickiness: 4 points Feel sticky: 3 points Feel sticky: 2 points Very sticky: 1 point [Judgment criteria (II)]
[Average score]: [Judgment]
Over 4 points: ◎
More than 3 points and less than 4 points: ○
More than 2 points and less than 3 points: △
2 points or less: ×

<(C) Smooth growth and spread>
After washing their faces, 20 cosmetics specialist panels picked up about 2 g of the products 1 to 16 of the present invention and products 1 to 10 of the comparative products, put half of them on both cheeks, and massaged them in a circular motion for about 60 seconds. The spread and spread at the time of application was evaluated in five stages according to the following evaluation standard (I), and the average score of the scores of all the panels was further determined according to the following judgment standard (II).

[Evaluation Criteria (I)]
[Evaluation result]: [Score]
Very smooth growth: 5 points Smooth growth: 4 points Slightly smooth growth: 3 points I don't feel much smooth growth: 2 points I don't feel smooth growth: 1 point [Criteria (II)]
[Average score]: [Judgment]
Over 4 points: ◎
More than 3 points and less than 4 points: ○
More than 2 points and less than 3 points: △
2 points or less: ×

As is clear from the results in Tables 1 to 3, the oil-in-water emulsified emulsions of the products 1 to 16 of the present invention have a "crystal precipitation suppressing effect" and "stickiness" as compared with the oil-in-water emulsified emulsions of the comparative products 1 to 10. It was excellent in all of "Nasa" and "Smooth expansion and spread".
On the other hand, the oil-in-water emulsified emulsions of Comparative Products 1 to 6 which did not contain the component (C) could not reduce the stickiness. Similarly, in Comparative Products 7 and 8 containing ascorbic acid glucoside instead of the component (C), the stickiness could not be reduced, and the smooth spread and spread were inferior. Further, the comparative product 9 in which the content of the component (A) exceeds 10% is inferior in the crystal precipitation suppressing effect and the non-stickiness, and the oil-in-water emulsified emulsion of the comparative product 10 containing no component (B) is inferior. It was inferior in the effect of suppressing crystal precipitation.

Example 2: Oil-in-water emulsified emulsion
(Ingredient) (%)
1.1,3-butylene glycol 12.0
2. Sorbitol 1.0
3. 3. Glycerin 5.0
4. Remaining amount of purified water
5. Niacinamide 6.0
6. Tranexamic acid 1.0
7. Polyethylene glycol monostearate (40EO) 0.5
8. Sorbitan sesquioleate 0.1
9. Hydrogenated lecithin 0.1
10. Cholesteryl hydroxystearate (Note 7) 3.0
11. Vaseline 2.0
12. α-olefin oligomer 5.0
13. Shea butter 2.0
14. Dimethylpolysiloxane (10CS) 1.0
15. Ceramide 3 0.1
16. Tocotrienols 0.1
17. Tocopherol 0.01
18. Setostearyl alcohol 2.0
19. Behenyl alcohol 1.0
20. Methyl paraoxybenzoate 0.1
21. Acrylic acid / alkyl methacrylate copolymer (Note 8) 0.1
22. Xanthan gum 0.1
23. Sodium hydroxide 0.03
24. Fragrance 0.2
25. Silica (Note 9) 0.6
Note 7) Sarakos HS (manufactured by Nisshin Oillio Co., Ltd.)
Note 8) Carbopole ULTREZ21 (manufactured by LUBRIZOL)
Note 9) Godball D11-796C (average particle size 4 μm) (manufactured by Suzuki Yushi Kogyo Co., Ltd.)

(Production method)
A: Ingredients 1 to 6 are uniformly dissolved and mixed at 70 ° C.
B: Ingredients 7 to 19 are uniformly dissolved and mixed at 80 ° C.
C: B is added to A and emulsified at 70 ° C.
After adding and mixing 10% of the component 4 and the components 20 to 25 to D: C, the mixture was cooled to 40 ° C. to obtain an oil-in-water emulsion.

The oil-in-water emulsified emulsion of Example 2 was excellent in all of "crystal precipitation suppressing effect", "non-stickiness", and "smooth spreading and spreading".

Example 3: Oil-in-water emulsified cream
(Ingredient) (%)
1. 1. Stearic acid 2.5
2. Cetanol 2.5
3. 3. Lipophilic glycerin monostearate 2.0
4. Vaseline 2.0
5. Dipentaerythrit fatty acid ester (Note 10) 2.0
6. Propylene glycol dicaprate 5.0
7. Liquid paraffin 8.0
8. Squalene 5.0
9. Bisethylhexyloxyphenol methoxyphenyl triazine 1.0
10.2-Cetyl ethylhexanoate 2.0
11. PEG-20 Phytosterol (Note 11) 1.0
12. Linoleic acid 0.1
13. Phenoxyethanol 0.1
14. Triethanolamine 1.2
15. Niacinamide 3.0
16. Tranexamic acid 1.0
17.1,3-butylene glycol 8.0
18. Glycerin 2.0
19. Polyethylene glycol 20000 (Note 12) 0.5
20. Vitamin E Glucoside 1.0
21. Remaining amount of purified water 22. Carboxyvinyl polymer (1% aqueous solution) 10.0
23. Silica (Note 5) 0.3
23. Fragrance 0.01
Note 10: Cosmall 168ARNV (manufactured by Nisshin Oillio Group)
Note 11: BPS-20 (manufactured by Nikko Chemicals Co., Ltd.)
Note 12: Polyethylene glycol 20000 (manufactured by NOF CORPORATION)

(Production method)
A. The following components (1) to (13) are heat-dissolved and kept at 70 ° C.
B. The following components (14) to (21) are dissolved by heating and kept at 70 ° C.
C. B is added to A to emulsify, and the component (22) is further added and mixed.
D. C was cooled, the component (23) was added and mixed to obtain an oil-in-water emulsified cream.

The oil-in-water emulsified cream of Example 3 was excellent in all of "crystal precipitation suppressing effect", "non-stickiness", and "smooth spreading and spreading".

Example 4: Oil-in-water emulsified beauty essence (ingredient) (%)
1. 1. Renoelaidic acid 0.1
2. Hydrogenated soybean phospholipid (PC purity 90% or more) (Note 13) 2.8
3. 3. Cholesterol 0.7
4. Isotridecyl isononanoate 2.0
5. POE (30) Cholesteryl ether (Note 14) 1.0
6. Dimethylpolysiloxane (Note 15) 2.0
7. Tocopherol oleate 0.5
8. Glycerin 3.0
9.1,3-butylene glycol 13.0
10.1,2-pentanediol 2.0
11. Xanthan gum 0.05
12. Niacinamide 3.0
13. Tranexamic acid 1.0
14. Sodium hydroxymethoxybenzophenone sulfonate 0.2
15. Phosphoric acid 0.1
16. Sodium monohydrogen phosphate 0.1
17. Theanine 0.05
18. Purified water remaining amount 19.1,3-butylene glycol 2.0
20. Silica (Note 9) 0.5
Note 13: Nikkor Resinol S-10EZ (manufactured by Nikko Chemicals Co., Ltd.)
Note 14: EMALEX CS-30 (manufactured by Nippon Emulsion Co., Ltd.)
Note 15: Silicon KF-96 (20CS) (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Ingredients (1) to (10) are heated and dissolved at 70 ° C.
B: Ingredients (11) to (18) are heated at 70 ° C. and then added to A for emulsification.
C: Cool B to room temperature.
D: C was subjected to high pressure treatment (treatment pressure 200 MPa) with a microfluidizer, and components (19) to (20) were added and mixed to obtain an oil-in-water emulsified beauty essence.

It was excellent in all of the "crystal precipitation suppressing effect", "non-stickiness", and "smooth spreading and spreading" of Example 4.

Example 5: Liquid foundation (oil-in-water emulsified cream)
(Ingredient) (%)
1.1,3 Butylene glycol 5.0
2. Hydrogenated soybean phospholipid (Note 16) 0.5
3. 3. Titanium oxide 5.0
4. Bengala 0.1
5. Yellow iron oxide 1.0
6. Black iron oxide 0.05
7. Acrylic acid / alkyl methacrylate copolymer (Note 17) 0.5
8. Triethanolamine 1.5
9. Niacinamide 1.0
10. Tranexamic acid 0.5
11. Maltitol 0.5
12. Residual amount of purified water 13. Glycerin 5.0
14. Silica (Note 5) 0.2
15. Ethyl paraoxybenzoate 0.1
16. Stearic acid 0.9
17. Glycerin monostearate 0.3
18. Setostearyl alcohol 0.4
19. Sucrose fatty acid ester (Note 18) 0.5
20. Liquid paraffin 3.0
21. Vaseline 2.0
22. POE (30) cholestanol ether (Note 19) 0.5
23. Paramethoxycinnamate 2-ethylhexyl 5.0
24. (Linoleic acid / oleic acid) Tocopherol 0.1
25. Oleic acid 0.1
26. Fragrance 0.02
Note 16: Nikkor Resinol S-10 (manufactured by Nikko Chemicals Co., Ltd.)
Note 17: Pemulen TR-2 (manufactured by NOVEON)
Note 18: DK-ester S-160 (manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.)
Note 19: Belpole DC-30 (manufactured by Nippon Fine Chemical Co., Ltd.)

(Production method)
A: Disperse components (1) to (6).
B: Add components (7) to (15) to A and mix uniformly at 70 ° C.
C: Ingredients (12) to (25) are uniformly mixed at 70 ° C.
D: Add B to C, emulsify, and cool to room temperature.
The component (26) was added to E: D to obtain an oil-in-water emulsified creamy liquid foundation.

The liquid foundation (oil-in-water emulsified cream) of Example 5 was excellent in all of "crystal precipitation suppressing effect", "non-stickiness", and "smooth spreading and spreading".

Example 6: Sunscreen cosmetic (in-oil emulsified cream)
(Ingredient) (%)
1. 1. Polyoxyethylene monolaurate (20 mol) sorbitan 0.2
2. Polyoxyethylene (60 mol) hardened castor oil (Note 20) 0.1
3. 3. Residual amount of purified water 4. Niacinamide 1.0
5. Tranexamic acid 0.5
6. Mannitol 0.5
7. Dipropylene glycol 10.0
8. Magnesium sulfate 0.5
9. Vitamin E Glucoside 1.0
10. PEG-9 Polydimethylsiloxyethyl Dimethicone (Note 21) 3.0
11. Decamethylcyclopentasiloxane 20.0
12.2-decyltetradecanol (Note 22) 5.0
13. Bisethylhexyloxyphenol methoxyphenyl triazine 1.5
14. 2-Ethylhexyl paramethoxycinnamate 8.0
15. POE (25) Phytostannole ether (Note 23) 1.0
16. Eicosapentaenoic acid 0.1
17. Dimethylstearylammonium hectorite 1.2
18. Octenyl succinate corn starch Al (Note 6) 0.5
Note 20: Nikkor HCO-60 (manufactured by Nippon Surfactant Industry Co., Ltd.)
Note 21: KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.)
Note 22: Lysonol 24SP (manufactured by Higher Alcohol Industry Co., Ltd.)
Note 23: BPSH-25 (manufactured by Nikko Chemicals Co., Ltd.)

(Production method)
A: The components (1) to (9) are uniformly dispersed.
B: The components (10) to (18) are uniformly dispersed.
C: While stirring B, A was gradually added and emulsified to obtain a water-in-oil emulsified creamy sunscreen cosmetic.

The sunscreen cosmetic (in-oil emulsified cream) of Example 6 was excellent in all of "crystal precipitation suppressing effect", "non-stickiness", and "smooth spreading and spreading".

Claims (5)

The following components (A) to (C);
(A) Niacinamide 1-10% by mass
A composition containing (B) a compound having a hydroxy group (C) tranexamic acid. The first aspect of claim 1, wherein the component (B) is one or more organic ultraviolet absorbers selected from hexyl diethylaminohydroxybenzoyl benzoate, bisethylhexyloxyphenol methoxyphenyl triazine, and sodium hydroxymethoxybenzophenone sulfonate. Composition. The composition according to claim 1, wherein the component (B) is one or more moisturizers selected from sorbitol, maltitol, and mannitol. The composition according to any one of claims 1 to 3, further containing the component (D) silica and / or corn starch Al octenyl succinate. The composition according to claim 4, wherein the component (A) and the content mass ratio (A) / (D) of the component (D) are 0.5 to 10.