JP2021070653A - Skin cleanser - Google Patents
Skin cleanser Download PDFInfo
- Publication number
- JP2021070653A JP2021070653A JP2019198937A JP2019198937A JP2021070653A JP 2021070653 A JP2021070653 A JP 2021070653A JP 2019198937 A JP2019198937 A JP 2019198937A JP 2019198937 A JP2019198937 A JP 2019198937A JP 2021070653 A JP2021070653 A JP 2021070653A
- Authority
- JP
- Japan
- Prior art keywords
- mass
- skin
- fat
- fatty acid
- points
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 48
- 229930195729 fatty acid Natural products 0.000 claims abstract description 48
- 239000000194 fatty acid Substances 0.000 claims abstract description 48
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 42
- 239000003921 oil Substances 0.000 claims abstract description 42
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 17
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- 229920002678 cellulose Polymers 0.000 claims abstract description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 8
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- 238000005187 foaming Methods 0.000 abstract description 45
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- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000011550 stock solution Substances 0.000 abstract 1
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- 238000011156 evaluation Methods 0.000 description 11
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- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 7
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- 239000012459 cleaning agent Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
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- 241000454552 Astrocaryum murumuru Species 0.000 description 4
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- 235000001014 amino acid Nutrition 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
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- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 3
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- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
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- 239000005977 Ethylene Substances 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 2
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- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
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- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
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- 238000007429 general method Methods 0.000 description 2
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- 230000037307 sensitive skin Effects 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 125000005457 triglyceride group Chemical group 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
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- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
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- KTCCLEVCNRHWQL-UHFFFAOYSA-N 3-(2-oxotridecylamino)propanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)CNCCC(O)=O KTCCLEVCNRHWQL-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
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- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
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- 239000005642 Oleic acid Substances 0.000 description 1
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- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は皮膚洗浄料に関する。 The present invention relates to a skin cleanser.
脂肪酸石鹸やアミノ酸界面活性剤等のアニオン性界面活性剤は洗浄力及び起泡力に優れることから、一般的な皮膚洗浄料の基材として汎用されている。またアニオン性界面活性剤にノニオン性界面活性剤等を組合せることで、ぬるつきのない使用感を維持しながら、泡立ちや泡質に優れる処方設計とする手法が知られている。
例えば特許文献1には、高級脂肪酸塩、カルボベタイン型両性界面活性剤、及びスルホベタイン型両性界面活性剤から選ばれる1種以上、28℃において固形状のポリオキシエチレンソルビタン脂肪酸エステル、多価アルコールを特定の比率で組み合わせることで、泡質に優れ、すすぎ時のさっぱり感を付与する液体洗浄剤組成物が開示されている。
さらに、洗浄後の肌の保湿感を高める目的でカチオン化ポリマー、シリコーン類、炭化水素類、植物性および動物性等の液状油、または半固形脂を洗浄剤組成物に配合する手法も開示されている。例えば、特許文献2には、N−アシルタウリン型陰イオン性界面活性剤、カルボベタイン型両性界面活性剤及びスルホベタイン型両性界面活性剤から選ばれる1種以上、高HLBのポリオキシエチレンソルビタン脂肪酸エステル、及び、多価アルコールを特定の比率で組合せることで、クリーミーで安定した泡が得られ、かつ洗浄後の持続的なうるおい感に優れる液体洗浄剤組成物が開示されている。また、特許文献3には、N−アシルアミノ酸塩、28℃において固形状又は半固形状油、及び、カチオン化多糖類を含有する泡立ちや泡質が良好であり、タオルドライ後のしっとり感に優れた皮膚洗浄剤組成物が開示されている。
従来の一般的な方法では、洗浄用のスポンジに液体洗浄剤を含ませ、スポンジを揉んで泡立てた後、そのスポンジで肌を擦り、水で洗い流していた。しかし近年、敏感肌志向の高まりにより、洗浄用のスポンジを使用せず、洗浄料の原液を手で肌に塗布し、肌の上で泡立てるというように、肌への摩擦を低減した方法で洗浄を行う場合もある。これまで、そのような着眼点では十分な開発がなされておらず、原液を使用した際のすすぎ時のぬるつきについては改善の余地があった。
Anionic surfactants such as fatty acid soaps and amino acid surfactants are widely used as a base material for general skin cleansers because they have excellent detergency and foaming power. Further, there is known a method of combining an anionic surfactant with a nonionic surfactant or the like to design a formulation having excellent foaming and foam quality while maintaining a feeling of use without sliminess.
For example, Patent Document 1 describes one or more selected from higher fatty acid salts, carbovetaine-type amphoteric surfactants, and sulfobetaine-type amphoteric surfactants, polyoxyethylene sorbitan fatty acid esters solid at 28 ° C., and polyhydric alcohols. Disclosed is a liquid detergent composition which is excellent in foam quality and imparts a refreshing feeling at the time of rinsing by combining the above in a specific ratio.
Further disclosed is a method of blending a cationized polymer, silicones, hydrocarbons, vegetable and animal liquid oils, or semi-solid fats into a cleansing composition for the purpose of enhancing the moisturizing feeling of the skin after washing. ing. For example, Patent Document 2 describes one or more high-HLB polyoxyethylene sorbitan fatty acids selected from N-acyltaurine-type anionic surfactants, carbobetaine-type amphoteric surfactants, and sulfobetaine-type amphoteric surfactants. A liquid cleaning agent composition is disclosed in which a creamy and stable foam is obtained by combining an ester and a polyhydric alcohol in a specific ratio, and the liquid cleaning agent composition is excellent in a long-lasting moisturizing feeling after washing. Further, Patent Document 3 has good foaming and foam quality containing N-acylamino acid salt, solid or semi-solid oil at 28 ° C., and cationized polysaccharide, and gives a moist feeling after towel drying. Excellent skin cleansing compositions are disclosed.
In the conventional general method, a cleaning sponge is impregnated with a liquid detergent, the sponge is rubbed and foamed, and then the skin is rubbed with the sponge and rinsed with water. However, in recent years, due to the growing tendency toward sensitive skin, instead of using a sponge for cleaning, the undiluted solution of the cleaning agent is applied to the skin by hand and foamed on the skin. May be done. Until now, sufficient development has not been made from such a point of view, and there is room for improvement in the sliminess during rinsing when using the undiluted solution.
本発明の目的は、使用時の泡立ち、泡質に優れ、さらに洗浄後の肌のしっとり感やなめらかさに優れるだけでなく、泡立てて皮膚に塗布し使用する際および原液を皮膚に塗布し使用する際のいずれにおいてもすすぎ時にぬるつきを感じにくい皮膚洗浄料を提供することにある。 An object of the present invention is not only excellent in foaming and foam quality during use, and also excellent in moisturizing and smoothness of the skin after washing, but also when foaming and applying to the skin and when using the undiluted solution by applying to the skin. The purpose is to provide a skin cleansing agent that does not feel slimy during rinsing.
本発明者らは、上記課題を解決するために研究を重ねたところ、下記成分を特定の比率で組み合わせることにより、目的とする皮膚洗浄料が得られることを見出し、本発明を完成させるに至った。
(A)28℃で固体の油脂のなかから選ばれる、下記2種類の油脂:
(A1)油脂中に含有されるトリグリセライドが、炭素数12又は14である脂肪酸成分を60質量%以上含有する脂肪酸組成を有している油脂;並びに、
(A2)油脂中に含有されるトリグリセライドが、炭素数16又は18である脂肪酸成分を60質量%以上含有する脂肪酸組成を有している油脂、
(B)カチオン化セルロース、
(C)エチレンオキシドの平均付加モル数が60〜100モルであるポリオキシエチレンソルビタンモノラウリン酸エステル、及び、
(D)アニオン性界面活性剤。
As a result of repeated studies to solve the above problems, the present inventors have found that a desired skin cleansing agent can be obtained by combining the following components in a specific ratio, and have completed the present invention. It was.
(A) The following two types of fats and oils selected from solid fats and oils at 28 ° C .:
(A1) A fat or oil having a fatty acid composition in which the triglyceride contained in the fat or oil contains 60% by mass or more of a fatty acid component having 12 or 14 carbon atoms;
(A2) A fat or oil having a fatty acid composition in which the triglyceride contained in the fat or oil contains 60% by mass or more of a fatty acid component having 16 or 18 carbon atoms.
(B) Cationized cellulose,
(C) Polyoxyethylene sorbitan monolauric acid ester having an average addition mole number of ethylene oxide of 60 to 100 moles, and
(D) Anionic surfactant.
すなわち、本発明の皮膚洗浄料は、28℃で固体の油脂(A)から選ばれ、油脂中に含有されるトリグリセライドが炭素数12又は14である脂肪酸成分を60質量%以上含有する脂肪酸組成を有している油脂(A1)を0.001〜1.0質量%、28℃で固体の油脂(A)から選ばれ、油脂中に含有されるトリグリセライドが炭素数16又は18である脂肪酸成分を60質量%以上含有する脂肪酸組成を有している油脂(A2)を0.001〜1.0質量%、カチオン化セルロース(B)を0.05〜1.0質量%、エチレンオキシドの平均付加モル数が60〜100モルであるポリオキシエチレンソルビタンモノラウリン酸エステル(C)を0.5〜10質量%、及び、アニオン性界面活性剤(D)を1.5〜15質量%含み、前記油脂(A2)に対する前記油脂(A1)の含有量比〔(A1)/(A2)〕が質量比で10/1〜1/5である。 That is, the skin cleaning agent of the present invention has a fatty acid composition selected from solid fats and oils (A) at 28 ° C. and containing 60% by mass or more of a fatty acid component in which triglyceride contained in the fats and oils has 12 or 14 carbon atoms. A fatty acid component in which the fat (A1) possessed is 0.001 to 1.0% by mass and is selected from the fat (A) solid at 28 ° C. and the triglyceride contained in the fat is 16 or 18 carbon atoms. 0.001 to 1.0% by mass of fat (A2) having a fatty acid composition containing 60% by mass or more, 0.05 to 1.0% by mass of cationized cellulose (B), and an average addition molar of ethylene oxide. The fat and oil containing 0.5 to 10% by mass of the polyoxyethylene sorbitan monolauric acid ester (C) and 1.5 to 15% by mass of the anionic surfactant (D) having a number of 60 to 100 mol. The content ratio [(A1) / (A2)] of the fat (A1) to A2) is 10/1 to 1/5 by mass.
本発明の皮膚洗浄料は、使用時の泡立ち、泡質に優れ、さらに洗浄後の肌のしっとり感やなめらかさに優れるだけでなく、泡立てて皮膚に塗布し使用する際および原液を皮膚に塗布し使用する際のいずれにおいてもすすぎ時にぬるつきを感じにくい。 The skin cleansing agent of the present invention is excellent in foaming and foam quality during use, and is not only excellent in moisturizing and smoothness of the skin after washing, but also when foamed and applied to the skin and when the undiluted solution is applied to the skin. It is hard to feel slimy when rinsing in any case when using it.
本発明の皮膚洗浄料は、28℃で固体の油脂であって、油脂中に含有されるトリグリセライドが炭素数12又は14である脂肪酸成分を60質量%以上含有する脂肪酸組成を有している油脂(A1)、28℃で固体の油脂であって、油脂中に含有されるトリグリセライドが炭素数16又は18である脂肪酸成分を60質量%以上含有する脂肪酸組成を有している油脂(A2)、カチオン化セルロース(B)、エチレンオキシドの平均付加モル数が60〜100モルであるポリオキシエチレンソルビタンモノラウリン酸エステル(C)、及び、アニオン性界面活性剤(D)を含み、必要に応じて、添加剤および水などの溶媒を含む。 The skin cleaning agent of the present invention is a fat or oil that is solid at 28 ° C. and has a fatty acid composition containing 60% by mass or more of a fatty acid component in which triglyceride contained in the fat or oil has 12 or 14 carbon atoms. (A1), a fat (A2) which is a solid fat at 28 ° C. and has a fatty acid composition containing 60% by mass or more of a fatty acid component in which triglyceride contained in the fat has 16 or 18 carbon atoms. Contains cationized cellulose (B), polyoxyethylene sorbitan monolauric acid ester (C) having an average addition molar number of 60 to 100 mol of ethylene oxide, and anionic surfactant (D), and is added as necessary. Contains agents and solvents such as water.
本発明は、特に以下の実施形態を含む。
28℃で固体の油脂(A)から選ばれ、油脂中に含有されるトリグリセライドが炭素数12又は14である脂肪酸成分を60質量%以上含有する脂肪酸組成を有している油脂(A1)を0.001〜1.0質量%、28℃で固体の油脂(A)から選ばれ、油脂中に含有されるトリグリセライドが炭素数16又は18である脂肪酸成分を60質量%以上含有する脂肪酸組成を有している油脂(A2)を0.001〜1.0質量%、カチオン化セルロース(B)を0.05〜1.0質量%、エチレンオキシドの平均付加モル数が60〜100モルであるポリオキシエチレンソルビタンモノラウリン酸エステル(C)を0.5〜10質量%、及び、アニオン性界面活性剤(D)を1.5〜15質量%含み、前記油脂(A2)に対する前記油脂(A1)の含有量比〔(A1)/(A2)〕が質量比で10/1〜1/5である皮膚洗浄料。
以下、皮膚洗浄料の成分について順次説明する
The present invention specifically includes the following embodiments.
Oil (A1) selected from solid fats and oils (A) at 28 ° C. and having a fatty acid composition containing 60% by mass or more of a fatty acid component in which triglyceride having 12 or 14 carbon atoms is contained in the fats and oils is 0. .001 to 1.0% by mass, selected from solid fats and oils (A) at 28 ° C., and has a fatty acid composition containing 60% by mass or more of a fatty acid component in which triglyceride contained in the fats and oils has 16 or 18 carbon atoms. Polyoxy in which the fat (A2) is 0.001 to 1.0% by mass, the cationized cellulose (B) is 0.05 to 1.0% by mass, and the average number of moles of ethylene oxide added is 60 to 100 mol. Contains 0.5 to 10% by mass of ethylene sorbitan monolauric acid ester (C) and 1.5 to 15% by mass of anionic surfactant (D), and contains the fat (A1) with respect to the fat (A2). A skin cleaning agent having a mass ratio [(A1) / (A2)] of 10/1 to 1/5 by mass.
Hereinafter, the components of the skin cleanser will be described in order.
(トリグリセライドを主成分とする28℃で固体状の油脂(A))
本発明の皮膚洗浄料に用いられる固体状の油脂(A)は、洗浄後の肌のしっとり感やなめらかさといった保湿感を向上させることができる。洗浄中および洗浄後の肌の手触り感を考慮すると、他の油剤よりもトリグリセライドを主成分とする油剤が好ましい。
28℃において固体状の油脂としては、通常化粧料に用いられるものであれば特に制限されない。例えば植物油を用いることができ、アストロカリウムムルムル種子脂、シア脂、ヤシ油等が挙げられる。化粧料グレードの植物油は、トリグリセライドを通常80質量%以上含有している。
これらの油脂を洗浄剤に配合する際、油脂中に含有されるトリグリセライドの炭素鎖の長さによって洗浄中および洗浄後の肌の手触り感が異なる。鋭意検討した結果、油脂中に含有されるトリグリセライドを構成する脂肪酸組成中の炭素数12又は炭素数14の脂肪酸成分の含有割合が60質量%以上である油脂(A1)と、油脂中に含有されるトリグリセライドを構成する脂肪酸組成中の炭素数16又は炭素数18の脂肪酸成分の含有割合が60質量%以上である油脂(A2)を組み合わせることで、本発明の効果を発揮することを見出した。
ここで、「トリグリセライドを構成する脂肪酸組成」又は「トリグリセライドの脂肪酸組成」とは、トリグリセライドの分子構造を構成する脂肪酸成分の組成を意味する。
トリグリセライドの脂肪酸組成は、溶液抽出やTLC(薄層クロマトグラフィー)等でトリグリセライドを単離し、次いでLC、LC−MS、GC−MSなどを単独または組み合わせて用いる方法や、基準油脂分析試験法2.4.2 脂肪酸組成(日本油化学会)にあるFID恒温ガスクロマトグラフ法などで分析することができる。
油脂(A1)としては、例えば、アストロカリウムムルムル種子脂、ヤシ油を用いることができ、アストロカリウムムルムル種子脂が好ましい。油脂(A2)としては、例えば、シア脂、カカオ脂を用いることができ、シア脂が好ましい。
2種類以上の油脂(A1)を組み合わせて用いても良く、2種類以上の油脂(A2)を組み合わせて用いても良い。
油脂(A1)の含有量は、皮膚洗浄料の全量中、0.001〜1.0質量%であり、好ましくは0.005〜0.5質量%であり、さらに好ましくは0.05〜0.2質量%である。油脂(A2)の含有量も同様に、皮膚洗浄料の全量中、0.001〜1.0質量%であり、好ましくは0.005〜0.5質量%であり、さらに好ましくは0.05〜0.2質量%である。
油脂(A1)または油脂(A2)の含有量が上記範囲よりも少ない場合には、洗浄後の肌のしっとり感やなめらかさおよび泡質が不十分となる場合がある。一方、油脂(A1)または油脂(A2)の含有量が上記範囲よりも多い場合には、泡立ち及び泡質が不十分となる場合がある。特に油脂(A2)の含有量が多すぎる場合には、泡立てて皮膚に塗布し使用する際および原液を皮膚に塗布し使用する際のいずれにおいても、すすぎ時にぬるつきが強くなりやすい。
油脂(A2)の含有量に対する前記油脂(A1)の含有量の比〔(A1)/(A2)〕については、原液使用時のぬるつきを防ぐ観点から質量比で10/1〜1/5の範囲であり、好ましくは5/1〜1/3であり、より好ましくは2/1〜1/2であり、特に好ましくは3/2〜2/3である。
含有量の比〔(A1)/(A2)〕が上記の範囲内であれば、泡立ちの低下やぬるつきを生じさせることなく、洗浄後の肌の優れたしっとり感やなめらかさを得ることができる。
(Fat and oil (A) solid at 28 ° C. containing triglyceride as the main component)
The solid oil (A) used in the skin cleansing agent of the present invention can improve the moisturizing feeling such as the moist feeling and smoothness of the skin after washing. Considering the feel of the skin during and after washing, an oil containing triglyceride as a main component is preferable to other oils.
The fats and oils that are solid at 28 ° C. are not particularly limited as long as they are usually used for cosmetics. For example, vegetable oil can be used, and examples thereof include astropotassium murmur seed fat, shea butter, and coconut oil. Cosmetic grade vegetable oils usually contain 80% by weight or more of triglyceride.
When these fats and oils are added to the cleansing agent, the feel of the skin during and after washing differs depending on the length of the carbon chain of triglyceride contained in the fats and oils. As a result of diligent studies, fats and oils (A1) having a fatty acid component having 12 or 14 carbon atoms in the fatty acid composition constituting triglyceride contained in the fats and oils having a content ratio of 60% by mass or more, and those contained in the fats and oils. It has been found that the effect of the present invention is exhibited by combining fats and oils (A2) in which the content ratio of the fatty acid component having 16 or 18 carbon atoms in the fatty acid composition constituting the triglyceride is 60% by mass or more.
Here, the "fatty acid composition constituting triglyceride" or the "fatty acid composition of triglyceride" means the composition of the fatty acid component constituting the molecular structure of triglyceride.
For the fatty acid composition of triglyceride, a method of isolating triglyceride by solution extraction, TLC (thin layer chromatography), etc., and then using LC, LC-MS, GC-MS, etc. alone or in combination, or a reference fat analysis test method. 4.2 It can be analyzed by the FID constant temperature gas chromatograph method in the fatty acid composition (Japan Oil Chemists' Society).
As the fat (A1), for example, astropotassium murumuru seed fat and coconut oil can be used, and astropotassium murumuru seed fat is preferable. As the fat (A2), for example, shea butter and cacao butter can be used, and shea butter is preferable.
Two or more types of fats and oils (A1) may be used in combination, and two or more types of fats and oils (A2) may be used in combination.
The content of the fat (A1) is 0.001 to 1.0% by mass, preferably 0.005 to 0.5% by mass, and more preferably 0.05 to 0% of the total amount of the skin cleansing agent. .2% by mass. Similarly, the content of the fat (A2) is 0.001 to 1.0% by mass, preferably 0.005 to 0.5% by mass, and more preferably 0.05 in the total amount of the skin cleansing agent. ~ 0.2% by mass.
When the content of the fat (A1) or the fat (A2) is less than the above range, the moist feeling, smoothness and foam quality of the skin after washing may be insufficient. On the other hand, when the content of the fat (A1) or the fat (A2) is larger than the above range, foaming and foam quality may be insufficient. In particular, when the content of fats and oils (A2) is too large, the skin tends to become slimy at the time of rinsing, both when it is foamed and applied to the skin and when the undiluted solution is applied to the skin and used.
Regarding the ratio of the content of the fat (A1) to the content of the fat (A2) [(A1) / (A2)], the mass ratio is 10/1 to 1/5 from the viewpoint of preventing sliminess when using the undiluted solution. The range is preferably 5/1 to 1/3, more preferably 2/1 to 1/2, and particularly preferably 3/2 to 2/3.
When the content ratio [(A1) / (A2)] is within the above range, it is possible to obtain an excellent moist feeling and smoothness of the skin after washing without causing a decrease in foaming or sliminess. it can.
(カチオン化セルロース(B))
本発明に用いられる(B)成分は、セルロースにカチオン性官能基が付与されたカチオン化セルロースである。(B)成分は、洗浄後の肌のしっとり感やなめらかさを向上させることができる。
(B)成分の市販品としては、例えば、ライオン株式会社製「商品名:レオガードMGP、KGP」、東邦化学工業株式会社製「商品名:カチナールHC−100、LC−100、HC−200、LC−200」などが挙げられる。
(B)成分の含有量は、皮膚洗浄料の全量中、0.05〜1.0質量%であり、好ましくは0.1〜0.8質量%、特に好ましくは0.3〜0.6質量%である。0.05質量%より少ない場合、泡質、洗浄後の肌のしっとり感やなめらかさが低下する場合がある。1.0質量%より多い場合、泡立ちが低下する場合があり、かつ、泡立てて皮膚に塗布し使用する際および原液を皮膚に塗布し使用する際のいずれにおいても、すすぎ時にぬるつきが生じるおそれがある。
(Cationized Cellulose (B))
The component (B) used in the present invention is cationized cellulose in which a cationic functional group is added to cellulose. The component (B) can improve the moist feeling and smoothness of the skin after washing.
Examples of commercially available products of the component (B) include "Product names: Leoguard MGP, KGP" manufactured by Lion Corporation and "Product names: Katinal HC-100, LC-100, HC-100, LC" manufactured by Toho Chemical Industry Co., Ltd. -200 "and the like.
The content of the component (B) is 0.05 to 1.0% by mass, preferably 0.1 to 0.8% by mass, and particularly preferably 0.3 to 0.6% of the total amount of the skin cleansing agent. It is mass%. If it is less than 0.05% by mass, the foam quality and the moist feeling and smoothness of the skin after washing may be reduced. If it is more than 1.0% by mass, foaming may decrease, and there is a risk of sliminess during rinsing both when foaming and applying to the skin and when using the undiluted solution on the skin. There is.
(エチレンオキシドの平均付加モル数が60〜100モルであるポリオキシエチレンソルビタンモノラウリン酸エステル(C))
本発明に用いられる(C)成分は、ポリオキシエチレンソルビタンモノラウリン酸エステルであり、皮膚洗浄料に起泡力や粘性を付与するために配合される。
本発明においては、エチレンオキシドの平均付加モル数(略称「E.O.」)が60〜100モルであり、好ましくは65〜95モル、特に好ましくは70〜90モルであるポリオキシエチレンソルビタンモノラウリン酸エステルを(C)成分として用いる。
かかるポリオキシエチレンソルビタンモノラウリン酸エステルの具体的な市販品としては、例えば、ポリオキシエチレンソルビタンモノラウリン酸エステル(80E.O.)(日油株式会社製の「ノニオンLT−280」)等が挙げられる。(C)成分は、1種単独または2種以上を組み合わせて用いることができる。
(C)成分の含有量は、皮膚洗浄料の全量中、0.5〜10質量%であり、好ましくは2.0〜8.5質量%、特に好ましくは3.0〜7.0質量%である。0.5質量%より少ない場合、泡立ちや泡質が低下するおそれがあり、10質量%より多い場合、すすぎ時のぬるつき、べたつきが生じたり、泡立ちの速度が低下し泡質が低下するおそれがある。
(Polyoxyethylene sorbitan monolauric acid ester (C) in which the average number of moles of ethylene oxide added is 60 to 100 moles)
The component (C) used in the present invention is a polyoxyethylene sorbitan monolauric acid ester, which is blended to impart foaming power and viscosity to a skin cleanser.
In the present invention, the average number of moles of ethylene oxide added (abbreviated as "EO") is 60 to 100 mol, preferably 65 to 95 mol, particularly preferably 70 to 90 mol, of polyoxyethylene sorbitan monolauric acid. The ester is used as the component (C).
Specific commercially available products of such polyoxyethylene sorbitan monolauric acid ester include, for example, polyoxyethylene sorbitan monolauric acid ester (80EO) (“Nonion LT-280” manufactured by Nichiyu Co., Ltd.) and the like. .. The component (C) can be used alone or in combination of two or more.
The content of the component (C) is 0.5 to 10% by mass, preferably 2.0 to 8.5% by mass, and particularly preferably 3.0 to 7.0% by mass, based on the total amount of the skin cleansing agent. Is. If it is less than 0.5% by mass, foaming and foam quality may deteriorate, and if it is more than 10% by mass, it may cause sliminess and stickiness during rinsing, and the foaming speed may decrease and foam quality may deteriorate. There is.
(アニオン性界面活性剤(D))
本発明に用いられる(D)成分は、皮膚洗浄料に起泡力や洗浄力を付与するために配合され、1種単独または2種以上を組み合わせて用いることができる。
アニオン性界面活性剤としては具体的には、アルキル硫酸塩、ポリオキシエチレンアルキルエーテル硫酸塩(例えば、ポリオキシエチレンラウリルエーテル硫酸ナトリウム)、アルキルアミドエーテル硫酸塩、ポリオキシエチレンアミドエーテル硫酸塩等の硫酸エステル塩;α−オレフィンスルホン酸塩、N−アシルイセチオン酸塩等のスルホン酸塩;N−アシルメチルタウリン塩(例えば、ココイルメチルタウリンナトリウム)、N−アシルグルタミン酸塩、N−アシルメチルアラニン塩(例えば、ラウロイルメチル−β−アラニンナトリウム)、N−アシルザルコシン塩等のN−アシルアミノ酸塩;ラウリン酸カリウム高級脂肪酸塩;ポリオキシエチレンアルキルエーテル酢酸塩等のアルキル酢酸エステル塩;アルキル燐酸塩、ポリオキシエチレンアルキルエーテルリン酸塩等のアルキルリン酸エステル塩;ヤシ油脂肪酸加水分解コラーゲンカリウム、ラウロイル加水分解シルクナトリウム等のN−アシルポリペプチド塩;ジアルキルスルホコハク酸、ポリオキシアルキレンアルキルスルホコハク酸塩等のアルキルスルホコハク酸塩が挙げられる。これらの中でも、硫酸エステル塩、スルホン酸塩、N−アシルメチルタウリン塩、N−アシルアミノ酸塩が好ましく、N−アシルメチルタウリン塩がさらに好ましい。これらのアルキル基もしくはアシル基の炭素数は、洗浄力、起泡力の観点から、好ましくは10〜18であり、さらに好ましくは12〜14である。
上記のアニオン性界面活性剤の対イオンとしては、アルカリ金属塩、アルカリ土類金属塩、アンモニウム塩、アルカノールアミン塩、アミノ酸塩等が挙げられる。
(D)成分の含有量は、皮膚洗浄料の全量中、1.5〜15質量%、好ましくは3.0〜12質量%、さらに好ましくは5.0〜10質量%である。1.5質量%未満の場合は、泡立ち、泡質が低下し、15質量%を超える場合には洗浄後の肌のしっとり感やなめらかさが低下する。
(Anionic Surfactant (D))
The component (D) used in the present invention is blended to impart foaming power and detergency to the skin cleansing agent, and can be used alone or in combination of two or more.
Specific examples of the anionic surfactant include alkyl sulfates, polyoxyethylene alkyl ether sulfates (for example, sodium polyoxyethylene lauryl ether sulfate), alkylamide ether sulfates, polyoxyethylene amide ether sulfates, and the like. Sulfate: Sulfates such as α-olefin sulfonate, N-acyl acetylionate; N-acylmethyl taurine salt (eg, cocoyl methyl taurine sodium), N-acyl glutamate, N-acyl methyl alanine ( For example, N-acylamino acid salts such as lauroylmethyl-β-alanine sodium), N-acylsulfosin salt; potassium laurate higher fatty acid salt; alkylacetate salts such as polyoxyethylene alkyl ether acetate; alkyl phosphate, polyoxy Alkyl phosphate ester salts such as ethylene alkyl ether phosphate; N-acyl polypeptide salts such as coconut oil fatty acid hydrolyzed collagen potassium and lauroyl hydrolyzed silk sodium; alkyls such as dialkyl sulfosuccinic acid and polyoxyalkylene alkyl sulfosuccinate. Examples include sulfosuccinate. Among these, sulfate ester salt, sulfonate, N-acylmethyl taurine salt and N-acylamino acid salt are preferable, and N-acylmethyl taurine salt is more preferable. The carbon number of these alkyl groups or acyl groups is preferably 10 to 18, and more preferably 12 to 14 from the viewpoint of detergency and foaming power.
Examples of the counterion of the above-mentioned anionic surfactant include alkali metal salts, alkaline earth metal salts, ammonium salts, alkanolamine salts, amino acid salts and the like.
The content of the component (D) is 1.5 to 15% by mass, preferably 3.0 to 12% by mass, and more preferably 5.0 to 10% by mass in the total amount of the skin cleansing agent. If it is less than 1.5% by mass, foaming and foam quality are lowered, and if it exceeds 15% by mass, the moist feeling and smoothness of the skin after washing are lowered.
(添加剤)
皮膚洗浄料には、本発明の効果を阻害しない範囲内で添加剤を含有させることができる。添加剤としては、例えばグリセリン、ジグリセリン、ポリエチレングリコール、ソルビトール、マルチトール、イソマルチトールなどの多価アルコール類;乳糖、果糖、ショ糖、マルトース、トレハロース、イソマルトオリゴ糖などの糖類;牛脂、豚脂などの天然油脂類;ミツロウ、カルナバロウなどのロウ類;高重合ジメチルポリシロキサン、ポリエーテル変性ジメチルポリシロキサン、アミノ変性ジメチルポリシロキサンなどのシリコーン誘導体;セラミド、コレステロール、タンパク誘導体、ラノリン、ラノリン誘導体、レシチンなどの油性基剤;アミドアミノ酸塩、アミドプロピルジメチルアミノ酢酸ベタインなどの両性界面活性剤;ポリオキシエチレンアルキルエーテル、ポリエチレングリコールの脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ポリグリセリン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、グリセリンモノ脂肪酸エステル、アルキルポリグルコシド、アルカノールアミドなどの非イオン性界面活性剤;塩化アルキルトリメチルアンモニウムなどの陽イオン界面活性剤;アルキルジメチルアミンオキシドなどの半極性界面活性剤;ピロリドンカルボン酸塩、クエン酸塩、リンゴ酸塩、食塩などの有機または無機塩類;pH調製剤としての酸およびアルカリ;殺菌剤;キレート剤;抗酸化剤;血行促進剤;紫外線吸収剤;紫外線散乱剤;動植物由来の天然エキス;アスコルビン酸およびその誘導体;アントシアニンなどのフラボノイド類およびその誘導体;ビタミン類;アミノ酸類;感光素;色素;顔料;香料などが挙げられる。
(Additive)
The skin cleanser may contain additives as long as the effects of the present invention are not impaired. Additives include polyhydric alcohols such as glycerin, diglycerin, polyethylene glycol, sorbitol, martitol, isomartitol; sugars such as lactose, fructose, sucrose, maltose, trehalose, isomaltooligosaccharide; beef fat, pig Natural fats and oils such as fats; waxes such as beeswax and carnauba wax; silicone derivatives such as highly polymerized dimethylpolysiloxane, polyether-modified dimethylpolysiloxane, amino-modified dimethylpolysiloxane; ceramide, cholesterol, protein derivatives, lanolin, lanolin derivatives, Oily bases such as lecithin; amphoteric surfactants such as amide amino acid salts and betaine amidopropyldimethylaminoacetate; polyoxyethylene alkyl ethers, polyethylene glycol fatty acid esters, polyoxyethylene hydrogenated castor oil, polyglycerin fatty acid esters, polyoxy Nonionic surfactants such as ethylene glycerin fatty acid ester, glycerin monofatty acid ester, alkylpolyglucoside, alkanolamide; cationic surfactants such as alkyltrimethylammonium chloride; semipolar surfactants such as alkyldimethylamine oxide; pyrrolidone Organic or inorganic salts such as carboxylates, citrates, malate, salt; acids and alkalis as pH adjusters; bactericides; chelating agents; antioxidants; blood circulation promoters; UV absorbers; UV scatterers Natural extracts derived from animals and plants; ascorbic acid and its derivatives; flavonoids such as anthocyanin and its derivatives; vitamins; amino acids; photosensitizers; pigments; pigments; fragrances and the like.
本発明の皮膚洗浄料は、液状皮膚洗浄料の一般的な製造方法により製造することができる。
本発明の皮膚洗浄料は、ボディーソープ、ハンドソープ、洗顔料等として用いることができる。
本発明の皮膚洗浄料は、従来の洗浄料と同様に、水を含んだ洗浄用スポンジに本発明の皮膚洗浄料を滲みこませ、スポンジを揉んで泡立て、当該スポンジで肌を擦る方法で用いても良い。
本発明の皮膚洗浄料を用いる場合には、泡立ち、泡質に優れ、洗浄後の肌のしっとり感やなめらかさといった保湿感に優れるだけでなく、泡立てた際やすすぎ時にぬるつきを感じにくい。
特に、本発明の皮膚洗浄料を原液の状態で皮膚に塗布し、手で擦る又は繊維が軟らかいウオッシュタオルで弱く擦るなど肌に対する摩擦を低減した方法で洗浄する場合には、原液を皮膚に塗布し、非常にやさしく擦るにもかかわらず、すすぎ時のぬるつきを感じないという効果がある。そのため本発明の皮膚洗浄料は、敏感肌の使用者や、美容に対する意識の高い使用者に適している。
The skin cleansing agent of the present invention can be produced by a general method for producing a liquid skin cleansing agent.
The skin cleanser of the present invention can be used as a body soap, hand soap, face wash and the like.
The skin cleansing agent of the present invention is used in a method of impregnating a cleansing sponge containing water with the skin cleansing agent of the present invention, kneading the sponge to lather, and rubbing the skin with the sponge, similarly to the conventional cleansing agent. You may.
When the skin cleansing agent of the present invention is used, it is excellent in foaming and foam quality, and not only is excellent in moisturizing feeling such as moisturizing and smoothness of the skin after washing, but also it is difficult to feel slimy when foaming and rinsing.
In particular, when the skin cleanser of the present invention is applied to the skin in the undiluted state and washed by a method that reduces friction on the skin, such as rubbing by hand or weakly with a wash towel with soft fibers, the undiluted solution is applied to the skin. However, even though it is rubbed very gently, it has the effect of not feeling slimy during rinsing. Therefore, the skin cleanser of the present invention is suitable for users with sensitive skin and users with a high awareness of beauty.
次に、実施例によって本発明をさらに詳細に説明する。
〔実施例1〜5および比較例1〜3〕
1.皮膚洗浄料の調製
A〜D成分、C’成分及びその他の成分を表1に示す配合割合で加熱しながら混合することにより、皮膚洗浄料を調製した。なお、表1中の成分の割合は質量%である。
具体的には、次の手順で皮膚洗浄料を調製した。
Next, the present invention will be described in more detail by way of examples.
[Examples 1 to 5 and Comparative Examples 1 to 3]
1. 1. Preparation of skin cleansing agent A skin cleansing agent was prepared by mixing components A to D, C'components and other components while heating at the blending ratios shown in Table 1. The ratio of the components in Table 1 is mass%.
Specifically, a skin cleanser was prepared according to the following procedure.
2.使用材料
実施例においては、以下の材料を使用した。
(A1)成分:アストロカリウムムルムル種子脂
(A2)成分:シア脂
(B)成分:ポリクオタニウム−10
(C)成分:ポリオキシエチレンソルビタンモノラウリン酸エステル(80E.O.)
(C’)成分:ポリソルベート80
(D)成分:ココイルメチルタウリンナトリウム
その他の成分(1):コカミドプロピルベタイン
その他の成分(2):オレイルアルコール
2. Materials used In the examples, the following materials were used.
(A1) Ingredient: Astropotassium Murmur Seed fat (A2) Ingredient: Shea butter (B) Ingredient: Polyquaternium-10
Component (C): Polyoxyethylene sorbitan monolauric acid ester (80EO)
(C') Ingredient: Polysorbate 80
(D) Ingredients: Sodium cocoyl methyl taurine Other ingredients (1): Cocamidopropyl betaine Other ingredients (2): Oleyl alcohol
(A1)成分として用いたアストロカリウムムルムル種子脂は、化粧料グレードであり、トリグリセライドを約80質量%〜90質量%含有するものであった。当該アストロカリウムムルムル種子脂に含まれるトリグリセライドを構成する脂肪酸組成中の炭素数12の脂肪酸成分の含有割合は約40質量%〜55質量%であり、当該トリグリセライドを構成する脂肪酸組成中の炭素数14の脂肪酸成分の含有割合は約20質量%〜30質量%であった。また、(A1)成分として用いたアストロカリウムムルムル種子脂の融点は、約35℃であった。
(A2)成分として用いたシア脂は、化粧料グレードであり、トリグリセライドを約80質量%〜90質量%含有するものであった。当該シア脂に含まれるトリグリセライドを構成する脂肪酸組成中、ステアリン酸(炭素数18)の含有割合は約40質量%〜50質量%であり、オレイン酸(炭素数18)の含有割合は約40質量%〜50質量%であった。 また、(A2)成分として用いたシア脂の融点は、約32℃であった。
(C)成分のポリオキシエチレンソルビタンモノラウリン酸エステル(80E.O.)として、商品名「ノニオンLT−280」(日油株式会社製)を使用した。
The astropotassium murumuru seed fat used as the component (A1) was of cosmetic grade and contained about 80% by mass to 90% by mass of triglyceride. The content ratio of the fatty acid component having 12 carbon atoms in the fatty acid composition constituting triglyceride contained in the astropotassium mulmul seed fat is about 40% by mass to 55% by mass, and the fatty acid number 14 in the fatty acid composition constituting the triglyceride. The content ratio of the fatty acid component of was about 20% by mass to 30% by mass. The melting point of the astropotassium murumuru seed fat used as the component (A1) was about 35 ° C.
The shea butter used as the component (A2) was cosmetic grade and contained about 80% by mass to 90% by mass of triglyceride. In the fatty acid composition constituting triglyceride contained in the shea butter, the content ratio of stearic acid (18 carbon atoms) is about 40% by mass to 50% by mass, and the content ratio of oleic acid (18 carbon atoms) is about 40% by mass. It was% to 50% by mass. The melting point of the shea butter used as the component (A2) was about 32 ° C.
As the component (C), polyoxyethylene sorbitan monolauric acid ester (80EO.), The trade name "Nonion LT-280" (manufactured by NOF CORPORATION) was used.
3.評価方法
男女20名(25〜45歳)をパネラーとし、得られた皮膚洗浄料を用いて、下記の方法(A)および方法(B)で洗浄を行い、評価した。
[方法(A)]
皮膚洗浄料をスポンジで泡立てた後、全身に塗布し、洗い流した。この方法において、(1)泡立ち、(2)泡質、(3)洗浄後のしっとり感やなめらかさ、(4)泡立てて洗浄する際のぬるつきを評価した。
[方法(B)]
皮膚洗浄料を原液のまま全身に塗布し、洗い流した。この方法において、(5)原液使用時のぬるつきを評価した。各評価項目の評価基準を以下に示す。評価結果を表1に示す。
3. 3. Evaluation Method Twenty men and women (25 to 45 years old) were used as panelists, and the obtained skin cleansing agent was used to cleanse by the following methods (A) and (B) and evaluated.
[Method (A)]
After lathering the skin cleanser with a sponge, it was applied to the whole body and rinsed off. In this method, (1) foaming, (2) foam quality, (3) moist feeling and smoothness after washing, and (4) sliminess when washing with foaming were evaluated.
[Method (B)]
The undiluted skin cleanser was applied to the whole body and rinsed off. In this method, (5) sliminess when using the undiluted solution was evaluated. The evaluation criteria for each evaluation item are shown below. The evaluation results are shown in Table 1.
(1)泡立ち
(A)個々のパネラーの採点基準
2点:泡立ちが良好であると感じた。
1点:泡立ちがまあまあであると感じた。
0点:泡立ちがやや悪いと感じた。
20名の合計点を求め、以下のように判定した。
(B)泡立ちの評価基準
◎:合計点が35点以上であり、かつ0点と評価したパネラーが0人である。泡立ちが非常に良好な皮膚洗浄料である。
○:合計点が30点以上35点未満、または合計点が35点以上かつ0点と評価したパネラーが1人以上2人以下である。泡立ちが良好な皮膚洗浄料である。
△:合計点が20点以上30点未満である。泡立ちがやや悪い皮膚洗浄料である。
×:合計点が19点未満である。泡立ちが悪い皮膚洗浄料である。
(1) Foaming (A) Scoring criteria for individual panelists 2 points: I felt that foaming was good.
1 point: I felt that the bubbling was fair.
0 points: I felt that the foaming was a little bad.
The total score of 20 people was calculated and judged as follows.
(B) Evaluation Criteria for Foaming ⊚: There are no panelists who evaluated the total score as 35 points or more and 0 points. A skin cleanser with very good foaming.
◯: The total score is 30 points or more and less than 35 points, or the total score is 35 points or more and the number of panelists evaluated as 0 points is 1 or more and 2 or less. A skin cleanser with good foaming.
Δ: The total score is 20 points or more and less than 30 points. A skin cleanser with slightly poor foaming.
X: The total score is less than 19 points. A skin cleanser with poor foaming.
(2)泡質
(A)個々のパネラーの採点基準
2点:泡質がクリーミーであると感じた。
1点:泡質がややクリーミーであると感じた。
0点:泡質が粗いと感じた。
20名の合計点を求め、以下のように判定した。
(B)泡質の評価基準
◎:合計点が35点以上であり、かつ0点と評価したパネラーが0人である。泡質が非常に良好な皮膚洗浄料である。
○:合計点が30点以上35点未満、または合計点が35点以上かつ0点と評価したパネラーが1人以上2人以下である。泡質が良好な皮膚洗浄料である。
△:合計点が20点以上30点未満である。泡質がやや悪い皮膚洗浄料である。
×:合計点が19点未満である。泡質が悪い皮膚洗浄料である。
(2) Foam quality (A) Scoring criteria for individual panelists 2 points: I felt that the foam quality was creamy.
1 point: I felt that the foam quality was a little creamy.
0 points: I felt that the foam quality was rough.
The total score of 20 people was calculated and judged as follows.
(B) Evaluation Criteria for Foam Quality ⊚: The total score was 35 points or more, and 0 panelists evaluated it as 0 points. A skin cleanser with very good foam quality.
◯: The total score is 30 points or more and less than 35 points, or the total score is 35 points or more and the number of panelists evaluated as 0 points is 1 or more and 2 or less. A skin cleanser with good foam quality.
Δ: The total score is 20 points or more and less than 30 points. A skin cleanser with slightly poor foam quality.
X: The total score is less than 19 points. A skin cleanser with poor foam quality.
(3)洗浄後のしっとり感やなめらかさ
(A)個々のパネラーの採点基準
2点:肌が潤っていると感じた。
1点:肌がやや潤っていると感じた。
0点:肌がかさつき、潤っていないと感じた。
20名の合計点を求め、以下のように判定した。
(B)洗浄後のしっとり感やなめらかさの評価基準
◎:合計点が35点以上であり、かつ0点と評価したパネラーが0人である。洗浄後の肌に潤いを付与できる皮膚洗浄料である。
○:合計点が30点以上35点未満、または合計点が35点以上かつ0点と評価したパネラーが1人以上2人以下である。洗浄後の肌に潤いをやや付与できる皮膚洗浄料である。
△:合計点が20点以上30点未満である。洗浄後の肌に潤いを付与しにくい皮膚洗浄料である。
×:合計点が19点未満である。洗浄後の肌に潤いを付与できない皮膚洗浄料である。
(3) Moist feeling and smoothness after washing (A) Scoring criteria for individual panelists 2 points: I felt that my skin was moisturized.
1 point: I felt that my skin was a little moisturized.
0 points: I felt that my skin was dry and not moisturized.
The total score of 20 people was calculated and judged as follows.
(B) Evaluation criteria for moist feeling and smoothness after washing ◎: No panelists evaluated the total score as 35 points or more and 0 points. A skin cleanser that can moisturize the skin after cleansing.
◯: The total score is 30 points or more and less than 35 points, or the total score is 35 points or more and the number of panelists evaluated as 0 points is 1 or more and 2 or less. A skin cleanser that can slightly moisturize the skin after cleansing.
Δ: The total score is 20 points or more and less than 30 points. A skin cleanser that does not easily moisturize the skin after cleansing.
X: The total score is less than 19 points. A skin cleanser that cannot moisturize the skin after cleansing.
(4)泡立てて使用する際のすすぎ時のぬるつき
(A)個々のパネラーの採点基準
2点:泡立てて使用する際、すすぎ時にぬるつきを感じなかった。
1点:泡立てて使用する際、すすぎ時にほとんどぬるつきを感じなかった。
0点:泡立てて使用する際、すすぎ時にぬるつきを感じた。
20名の合計点を求め、以下のように判定した。
(B)泡立てて使用する際のすすぎ時のぬるつきの評価基準
◎:合計点が35点以上であり、かつ0点と評価したパネラーが0人である。泡立てて使用する際、ぬるつきを感じにくい皮膚洗浄料である。
○:合計点が30点以上35点未満、または合計点が35点以上かつ0点と評価したパネラーが1人以上2人以下である。泡立てて使用する際、ややぬるつきを感じにくい皮膚洗浄料である。
△:合計点が20点以上30点未満である。泡立てて使用する際、ややぬるつきを感じやすい皮膚洗浄料である。
×:合計点が19点未満である。泡立てて使用する際、ぬるつきを感じる皮膚洗浄料である。
(4) Slimy during rinsing when using whipping (A) Scoring criteria for individual panelists 2 points: When using whipping, no slimy feeling was felt during rinsing.
1 point: When using with whipping, I felt almost no slimy feeling during rinsing.
0 points: When using with foaming, I felt slimy when rinsing.
The total score of 20 people was calculated and judged as follows.
(B) Evaluation criteria for sliminess during rinsing when whipping and using ⊚: The total score is 35 points or more, and 0 panelists evaluate it as 0 points. It is a skin cleanser that does not feel slimy when used with foaming.
◯: The total score is 30 points or more and less than 35 points, or the total score is 35 points or more and the number of panelists evaluated as 0 points is 1 or more and 2 or less. It is a skin cleanser that does not feel a little slimy when used with foaming.
Δ: The total score is 20 points or more and less than 30 points. It is a skin cleanser that makes you feel a little slimy when you use it with foam.
X: The total score is less than 19 points. A skin cleanser that feels slimy when used with foaming.
(5)原液使用時のすすぎ時のぬるつき
(A)個々のパネラーの採点基準
2点:泡立てずに原液を塗布して使用する際、すすぎ時にぬるつきを感じなかった。
1点:泡立てずに原液を塗布して使用する際、すすぎ時にほとんどぬるつきを感じなかった。
0点:泡立てずに原液を塗布して使用する際、すすぎ時にぬるつきを感じた。
20名の合計点を求め、以下のように判定した。
(B)原液使用時のすすぎ時のぬるつきの評価基準
◎:合計点が35点以上であり、かつ0点と評価したパネラーが0人である。泡立てずに原液を塗布して使用する際、ぬるつきを感じにくい皮膚洗浄料である。
○:合計点が30点以上35点未満、または合計点が35点以上かつ0点と評価したパネラーが1人以上2人以下である。泡立てずに原液を塗布して使用する際、ややぬるつきを感じにくい皮膚洗浄料である。
△:合計点が20点以上30点未満である。泡立てずに原液を塗布して使用する際、ややぬるつきを感じやすい皮膚洗浄料である。
×:合計点が19点未満である。泡立てずに原液を塗布して使用する際、ぬるつきを感じる皮膚洗浄料である。
(5) Sliminess during rinsing when using undiluted solution (A) Scoring criteria for individual panelists 2 points: When using undiluted solution applied without foaming, no sliminess was felt during rinsing.
1 point: When the undiluted solution was applied and used without foaming, almost no slimy feeling was felt during rinsing.
0 points: When using the undiluted solution without foaming, I felt slimy during rinsing.
The total score of 20 people was calculated and judged as follows.
(B) Evaluation criteria for sliminess during rinsing when using undiluted solution ⊚: No panelists evaluated the total score as 35 points or more and 0 points. It is a skin cleanser that does not feel slimy when the undiluted solution is applied and used without foaming.
◯: The total score is 30 points or more and less than 35 points, or the total score is 35 points or more and the number of panelists evaluated as 0 points is 1 or more and 2 or less. It is a skin cleanser that does not feel a little slimy when the undiluted solution is applied and used without foaming.
Δ: The total score is 20 points or more and less than 30 points. It is a skin cleanser that makes you feel a little slimy when you apply the undiluted solution without foaming.
X: The total score is less than 19 points. It is a skin cleanser that feels slimy when the undiluted solution is applied and used without foaming.
4.評価結果の説明
表1に示される結果から明らかなように、実施例1〜5の皮膚洗浄料は、使用時の泡立ち、泡質に優れ、さらに洗浄後の肌のしっとり感やなめらかさに優れながらも、泡立てた際および原液使用する際のすすぎ時にぬるつきを感じにくい皮膚洗浄料であった。
一方、比較例1〜4の皮膚洗浄料では、十分な性能は得られなかった。
比較例1では、(A1)成分を配合しなかったために、原液使用する際のすすぎ時にぬるつきを感じた。
比較例2では、(C)成分であるポリオキシエチレンソルビタンモノラウリン酸エステルの代わりに、他のノニオン性界面活性剤(C’)としてポリソルベート80を使用したために、泡質が悪く、原液使用する際のすすぎ時のぬるつき感についても不十分な結果であった。
比較例3では、(B)成分を配合しなかったために、泡立ち、泡質が悪く、洗浄後の肌のしっとり感やなめらかさについても不十分な結果であった。
比較例4では、(D)成分を配合しなかったために、しっとり感やなめらかさ以外の評価、すなわち、泡立ち、泡質、泡立てた際のすすぎ時のぬるつき感、および原液使用する際のすすぎ時のぬるつき感について悪い結果となった。
前述のように、本発明の皮膚洗浄料は、泡立ち、泡質に優れ、洗浄後の肌のしっとり感やなめらかさに優れ、原液使用の際にもぬるつきがないものである。
4. Explanation of Evaluation Results As is clear from the results shown in Table 1, the skin cleansers of Examples 1 to 5 are excellent in foaming and foam quality during use, and are also excellent in moisturizing and smoothness of the skin after washing. However, it was a skin cleanser that did not feel slimy when it was whipped and when it was rinsed when using the undiluted solution.
On the other hand, sufficient performance was not obtained with the skin cleansers of Comparative Examples 1 to 4.
In Comparative Example 1, since the component (A1) was not blended, a slimy feeling was felt during rinsing when using the undiluted solution.
In Comparative Example 2, since polysorbate 80 was used as another nonionic surfactant (C') instead of the polyoxyethylene sorbitan monolauric acid ester which is the component (C), the foam quality was poor and the undiluted solution was used. The result was also insufficient for the slimy feeling when rinsing.
In Comparative Example 3, since the component (B) was not blended, foaming and foam quality were poor, and the moist feeling and smoothness of the skin after washing were also insufficient.
In Comparative Example 4, since the component (D) was not blended, evaluations other than moist feeling and smoothness, that is, foaming, foam quality, slimy feeling when rinsing when foaming, and rinsing when using the undiluted solution The result was bad about the slimy feeling of time.
As described above, the skin cleansing agent of the present invention is excellent in foaming and foam quality, excellent in moisturizing and smoothness of the skin after washing, and is not slimy even when the undiluted solution is used.
Claims (1)
28℃で固体の油脂(A)から選ばれ、油脂中に含有されるトリグリセライドが炭素数16又は18である脂肪酸成分を60質量%以上含有する脂肪酸組成を有している油脂(A2)を0.001〜1.0質量%、
カチオン化セルロース(B)を0.05〜1.0質量%、
エチレンオキシドの平均付加モル数が60〜100モルであるポリオキシエチレンソルビタンモノラウリン酸エステル(C)を0.5〜10質量%、及び、
アニオン性界面活性剤(D)を1.5〜15質量%含み、
前記油脂(A2)に対する前記油脂(A1)の含有量比〔(A1)/(A2)〕が質量比で10/1〜1/5である皮膚洗浄料。 A fat (A1) selected from solid fats and oils (A) at 28 ° C. and having a fatty acid composition containing 60% by mass or more of a fatty acid component having triglyceride having 12 or 14 carbon atoms contained in the fats and oils is 0. .001-1.0% by mass,
A fat (A2) selected from solid fats and oils (A) at 28 ° C. and having a fatty acid composition containing 60% by mass or more of a fatty acid component having 16 or 18 carbon atoms as triglyceride contained in the fats and oils is 0. .001-1.0% by mass,
Cationized cellulose (B) in 0.05-1.0% by mass,
0.5 to 10% by mass of polyoxyethylene sorbitan monolauric acid ester (C) having an average addition mole number of ethylene oxide of 60 to 100 mol, and
Containing 1.5 to 15% by mass of the anionic surfactant (D)
A skin cleanser in which the content ratio of the fat (A1) to the fat (A2) [(A1) / (A2)] is 10/1 to 1/5 by mass ratio.
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JP2018080279A (en) * | 2016-11-17 | 2018-05-24 | 日油株式会社 | Foamy detergent composition |
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JP2005015359A (en) * | 2003-06-25 | 2005-01-20 | Lion Corp | Skin cleanser composition |
JP2011225467A (en) * | 2010-04-16 | 2011-11-10 | Kao Corp | Skin detergent composition |
JP2013087110A (en) * | 2011-10-21 | 2013-05-13 | Kao Corp | Skin detergent composition |
JP2013163658A (en) * | 2012-02-10 | 2013-08-22 | Kracie Home Products Ltd | Skin detergent composition |
JP2017193625A (en) * | 2016-04-20 | 2017-10-26 | クラシエホームプロダクツ株式会社 | Liquid detergent composition |
JP2018080279A (en) * | 2016-11-17 | 2018-05-24 | 日油株式会社 | Foamy detergent composition |
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