JP2021066705A - Dye adhesion remover - Google Patents
Dye adhesion remover Download PDFInfo
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- JP2021066705A JP2021066705A JP2019194466A JP2019194466A JP2021066705A JP 2021066705 A JP2021066705 A JP 2021066705A JP 2019194466 A JP2019194466 A JP 2019194466A JP 2019194466 A JP2019194466 A JP 2019194466A JP 2021066705 A JP2021066705 A JP 2021066705A
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- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 9
- 239000000194 fatty acid Substances 0.000 claims abstract description 9
- 229930195729 fatty acid Natural products 0.000 claims abstract description 9
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920002678 cellulose Polymers 0.000 claims abstract description 5
- 239000001913 cellulose Substances 0.000 claims abstract description 5
- 239000000344 soap Substances 0.000 claims abstract description 5
- 238000004043 dyeing Methods 0.000 claims description 37
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 5
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 5
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 claims description 4
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 3
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 3
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 3
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 3
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 claims description 2
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 claims description 2
- 229940082004 sodium laurate Drugs 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 abstract description 3
- 230000007774 longterm Effects 0.000 abstract 1
- 239000000980 acid dye Substances 0.000 description 12
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- 239000000975 dye Substances 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 6
- -1 fatty acid salt Chemical class 0.000 description 5
- 239000000118 hair dye Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
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- 238000007796 conventional method Methods 0.000 description 3
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- 239000002453 shampoo Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
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- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000007665 sagging Methods 0.000 description 2
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- 238000012360 testing method Methods 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
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- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- OOYIOIOOWUGAHD-UHFFFAOYSA-L disodium;2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [Na+].[Na+].O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(Br)=C([O-])C(Br)=C1OC1=C(Br)C([O-])=C(Br)C=C21 OOYIOIOOWUGAHD-UHFFFAOYSA-L 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 229940009662 edetate Drugs 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JMXROTHPANUTOJ-UHFFFAOYSA-H naphthol green b Chemical compound [Na+].[Na+].[Na+].[Fe+3].C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21 JMXROTHPANUTOJ-UHFFFAOYSA-H 0.000 description 1
- CTIQLGJVGNGFEW-UHFFFAOYSA-L naphthol yellow S Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 CTIQLGJVGNGFEW-UHFFFAOYSA-L 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 229940127557 pharmaceutical product Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
- WPPDXAHGCGPUPK-UHFFFAOYSA-N red 2 Chemical compound C1=CC=CC=C1C(C1=CC=CC=C11)=C(C=2C=3C4=CC=C5C6=CC=C7C8=C(C=9C=CC=CC=9)C9=CC=CC=C9C(C=9C=CC=CC=9)=C8C8=CC=C(C6=C87)C(C=35)=CC=2)C4=C1C1=CC=CC=C1 WPPDXAHGCGPUPK-UHFFFAOYSA-N 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- LGZQSRCLLIPAEE-UHFFFAOYSA-M sodium 1-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C(S([O-])(=O)=O)C2=C1 LGZQSRCLLIPAEE-UHFFFAOYSA-M 0.000 description 1
- JAOZKJMVYIWLKU-UHFFFAOYSA-N sodium 7-hydroxy-8-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalene-1,3-disulfonic acid Chemical compound C1=CC=C2C(=C1)C(=CC=C2S(=O)(=O)O)N=NC3=C(C=CC4=CC(=CC(=C43)S(=O)(=O)O)S(=O)(=O)O)O.[Na+] JAOZKJMVYIWLKU-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、染着除去剤に関し、特に酸性染料を含有した染毛料を使用する際に、頭皮、手、肌などに付着した染料の汚れを除去するための染着除去剤に関する。 The present invention relates to a dye removing agent, and particularly to a dye removing agent for removing stains of a dye adhering to the scalp, hands, skin, etc. when using a hair dye containing an acid dye.
毛髪を染毛する手段として、酸性染料を含有したヘアマニキュアや塩基性染料を含有したカラートリートメントなどの使用があるが、中でもヘアマニキュアに含有されている酸性染料は皮膚に染着しやすい。 As a means for dyeing hair, there are uses such as a hair manicure containing an acid dye and a color treatment containing a basic dye. Among them, the acid dye contained in the hair manicure is easy to dye on the skin.
従来、皮膚に染着した染毛料の汚れを落とすためには、有機溶剤を含む染着除去剤、あるいは石鹸液やシャンプーなどが使用されてきたが、それらの多くは液状であり、使用する際にはティッシュやコットンなどに含浸させて染着部分を何度もこすり取るという方法が一般的である。しかし、皮膚に染着した染毛料の汚れをこすり取る方法は、皮膚へ摩擦による刺激を与えるという欠点がある。 Conventionally, dyeing removers containing organic solvents, soap solutions, shampoos, etc. have been used to remove stains from hair dyes that have adhered to the skin, but most of them are liquid and when used. The general method is to impregnate the dyed part with tissue or cotton and scrape off the dyed part many times. However, the method of scraping off the dirt of the hair dye that has adhered to the skin has a drawback that the skin is irritated by friction.
特許文献１の染着除去剤は液状であるため、使用する際にはティッシュやコットンなどに含浸させ、染着部分に当てて、しばらく放置する必要があり、コットンからの液垂れが懸念され含浸量は少なくなり、染着除去は弱くなってしまう。そこで、製剤の粘度を高め、染着部に十分な量を塗布し、たれ落ちを防ぐことができる染着除去剤の開発が望まれていた。 Since the dyeing remover of Patent Document 1 is a liquid, it is necessary to impregnate it with tissue or cotton when using it, apply it to the dyed part, and leave it for a while. The amount will be small and the dye removal will be weak. Therefore, it has been desired to develop a dyeing remover capable of increasing the viscosity of the preparation, applying a sufficient amount to the dyed portion, and preventing dripping.
そこで本発明は、酸性染料の染着除去、経時安定性、刺激性およびたれ落ちのなさ（以下、使用性とする）に優れる染着除去剤を提供することを課題とする。 Therefore, it is an object of the present invention to provide a dyeing remover excellent in acid dye dyeing removal, stability over time, irritation and non-dripping (hereinafter referred to as usability).
本発明者は鋭意検討した結果、脂肪酸石鹸、水溶性セルロース誘導体およびモノエタノールアミンを含有する染着除去剤が、上記の課題を解決することを見出し、本発明を完成させた。 As a result of diligent studies, the present inventor has found that a dyeing remover containing a fatty acid soap, a water-soluble cellulose derivative and monoethanolamine solves the above-mentioned problems, and has completed the present invention.
本発明により、酸性染料の染着除去、経時安定性、刺激性および使用性に優れる染着除去剤を提供する。 INDUSTRIAL APPLICABILITY The present invention provides a dyeing remover having excellent acid dye dyeing removal, stability over time, irritation and usability.
本発明は、酸性染料の染着除去の観点から、（Ａ）脂肪酸石鹸を含有する。 The present invention contains (A) fatty acid soap from the viewpoint of removing dyeing of acid dyes.
本発明で用いられる前記（Ａ）成分としては、特に限定されないが、炭素数１２以上の脂肪酸塩が好ましい。 The component (A) used in the present invention is not particularly limited, but a fatty acid salt having 12 or more carbon atoms is preferable.
本発明で用いられる炭素数１２以上の脂肪酸としては、特に限定されないが、例えば、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、オレイン酸およびヤシ油脂肪酸等が挙げられる。脂肪酸の対イオンとしては、カリウム、ナトリウム等のアルカリ金属やトリエタノールアミン等の有機アミン等が挙げられる。 The fatty acid having 12 or more carbon atoms used in the present invention is not particularly limited, and examples thereof include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, and coconut oil fatty acid. Examples of the counterion of the fatty acid include alkali metals such as potassium and sodium and organic amines such as triethanolamine.
本発明で用いられる前記（Ａ）成分のうち、酸性染料の染着除去の観点から、好ましくはラウリン酸カリウム、ラウリン酸ナトリウムおよびミリスチン酸カリウムであり、より好ましくはラウリン酸カリウムである。 Among the components (A) used in the present invention, potassium laurate, sodium laurate and potassium myristate are preferable, and potassium laurate is more preferable, from the viewpoint of removing dyeing of acid dyes.
本発明で用いられる前記（Ａ）成分の含有量は、好ましくは０．１〜０．４質量％、より好ましくは０．２〜０．３質量％がよい。前記（Ａ）成分の含有量が０．１質量％未満の場合、酸性染料の染着除去効果が得られない恐れがある。前記（Ａ）成分の含有量が０．４質量％を超える場合、経時安定性が悪くなる恐れがある。 The content of the component (A) used in the present invention is preferably 0.1 to 0.4% by mass, more preferably 0.2 to 0.3% by mass. If the content of the component (A) is less than 0.1% by mass, the effect of removing the dyeing of the acid dye may not be obtained. If the content of the component (A) exceeds 0.4% by mass, the stability over time may deteriorate.
本発明は、酸性染料の染着除去および刺激性の観点から、（Ｂ）モノエタノールアミンを含有する。 The present invention contains (B) monoethanolamine from the viewpoint of acid dye removal and irritation.
本発明で用いられる前記（Ｂ）成分の含有量は、好ましくは０．１〜１．２質量％、より好ましくは０．２〜０．８質量％、さらに好ましくは０．４〜０．６質量％がよい。前記（Ｂ）成分の含有量が０．１質量％未満の場合、酸性染料の染着除去効果が得られない恐れがある。前記（Ｂ）成分の含有量が１．２質量％を超える場合、刺激が出る恐れがある。 The content of the component (B) used in the present invention is preferably 0.1 to 1.2% by mass, more preferably 0.2 to 0.8% by mass, and further preferably 0.4 to 0.6. Mass% is good. If the content of the component (B) is less than 0.1% by mass, the effect of removing the dyeing of the acid dye may not be obtained. If the content of the component (B) exceeds 1.2% by mass, irritation may occur.
本発明は、使用性の観点から、（Ｃ）水溶性セルロース誘導体を含有する。 The present invention contains (C) a water-soluble cellulose derivative from the viewpoint of usability.
本発明で用いられる前記（Ｃ）成分としては、特に限定されないが、例えば、メチルセルロース、エチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルメチルセルロース、カルボキシメチルセルロースナトリウム等が挙げられる。 The component (C) used in the present invention is not particularly limited, and examples thereof include methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose, sodium carboxymethyl cellulose and the like.
本発明で用いられる前記（Ｃ）成分のうち、使用性の観点から、好ましくはカルボキシメチルセルロースナトリウムおよびヒドロキシプロピルメチルセルロースであり、より好ましくはカルボキシメチルセルロースナトリウムである。 Among the components (C) used in the present invention, sodium carboxymethyl cellulose and hydroxypropyl methyl cellulose are preferable, and sodium carboxymethyl cellulose is more preferable, from the viewpoint of usability.
本発明で用いられる前記（Ｃ）成分の含有量は、好ましくは２．５〜４質量％、より好ましくは３〜４質量％がよい。前記（Ｃ）成分の含有量が２．５質量％未満の場合、組成物の粘度が足りず使用性が悪くなる恐れがある。前記（Ｃ）成分の含有量が４質量％を超える場合、組成物の粘度が大きくなり伸びが悪くなる恐れがある。 The content of the component (C) used in the present invention is preferably 2.5 to 4% by mass, more preferably 3 to 4% by mass. If the content of the component (C) is less than 2.5% by mass, the viscosity of the composition may be insufficient and the usability may deteriorate. If the content of the component (C) exceeds 4% by mass, the viscosity of the composition may increase and the elongation may deteriorate.
本発明の染着除去剤は前記必須成分の他に、通常の化粧料、医薬部外品および医薬品等に用いられる各種成分、例えば、紛体、ビタミン類、キレート剤、ｐＨ調整剤、増粘剤、油性成分、保湿剤、薬効成分、蛋白誘導体、加水分解蛋白、酸化防止剤、還元剤、植物性抽出液、生薬抽出物、香料、防腐剤、色素、顔料、紫外線吸収剤、界面活性剤等から選ばれる少なくとも１種以上を含有することができる。ただし、これら例示に限定されるものではない。 In addition to the above-mentioned essential ingredients, the dyeing remover of the present invention contains various ingredients used in ordinary cosmetics, non-pharmaceutical products, pharmaceuticals, etc., such as powders, vitamins, chelating agents, pH adjusters, and thickeners. , Oily ingredients, moisturizers, medicinal ingredients, protein derivatives, hydrolyzed proteins, antioxidants, reducing agents, vegetable extracts, crude drug extracts, fragrances, preservatives, pigments, pigments, UV absorbers, surfactants, etc. It can contain at least one selected from. However, the present invention is not limited to these examples.
本発明で染着除去する酸性染料としては、特に限定されないが、例えば、黒色４０１号、赤色２号、赤色３号、赤色１０２号、赤色１０４号、赤色１０５号、赤色 １０６号、黄色４号、黄色５号、緑色３号、青色１号、青色２号、赤色２０１号、赤色２０６号、赤色２２７号、赤色２３０号、赤色２３１号、赤色２３２号、橙色２０５号、橙色２０７号、黄色２０２号、黄色２０３号、緑色２０１号、緑色２０４号、緑色２０５号、青色２０２号、青色２０３号、青色２０５号、褐色２０１号、褐色２０１号、赤色４０１号、赤色５０２号、赤色５０３号、赤色５０４号、赤色５０６号、橙色４０３号、黄色４０２号、黄色４０３号の（１）、黄色４０６号、黄色４０７号、緑色４０１号、緑色４０２号、紫色４０１号等が挙げられる。 The acidic dye to be dyed and removed in the present invention is not particularly limited, but for example, black 401, red 2, red 3, red 102, red 104, red 105, red 106, and yellow 4. , Yellow 5, Green 3, Blue 1, Blue 2, Red 201, Red 206, Red 227, Red 230, Red 231, Red 232, Orange 205, Orange 207, Yellow 202, Yellow 203, Green 201, Green 204, Green 205, Blue 202, Blue 203, Blue 205, Brown 201, Brown 201, Red 401, Red 502, Red 503 , Red No. 504, Red No. 506, Orange No. 403, Yellow No. 402, Yellow No. 403 (1), Yellow No. 406, Yellow No. 407, Green No. 401, Green No. 402, Purple No. 401 and the like.
本発明における染着除去剤の２０℃条件下によるｐＨは、特に限定されないが好ましくはｐＨ１０〜１２であり、より好ましくはｐＨ１０．５〜１１．５である。 The pH of the dyeing remover in the present invention under the condition of 20 ° C. is not particularly limited, but is preferably pH 10 to 12, and more preferably pH 10.5 to 11.5.
本発明における染着除去剤の２０℃条件下によるｐＨは、常法にて調製して得られた染着除去剤をサンプル瓶（食品１４０：第一硝子株式会社製）に１２０ｇ充填し、２０℃条件下で２４時間放置した後に、ガラス電極式水素イオン濃度指示計（Ｆ−７１、堀場製作所製）にて原液のｐＨを測定し得られるものである。 The pH of the dyeing remover in the present invention under 20 ° C. conditions is 20 by filling a sample bottle (Food 140: manufactured by Daiichi Glass Co., Ltd.) with 120 g of the dyeing remover prepared by a conventional method. It can be obtained by measuring the pH of the undiluted solution with a glass electrode type hydrogen ion concentration indicator (F-71, manufactured by Horiba Seisakusho) after being left to stand for 24 hours under the temperature condition.
本発明による染着除去剤の２０℃条件下による粘度は、特に限定されないが、使用性の観点から、好ましくは５，０００〜２００，０００ｍＰａ・ｓ、より好ましくは、１００，０００〜２００，０００ｍＰａ・ｓがよい。粘度が５，０００ｍＰａ・ｓ未満の場合、手のひらからたれ落ちやすくなる恐れがある。粘度が２００，０００ｍＰａ・ｓを超える場合、伸びが悪くなる恐れがある。 The viscosity of the dyeing remover according to the present invention under 20 ° C. conditions is not particularly limited, but from the viewpoint of usability, it is preferably 5,000 to 200,000 mPa · s, more preferably 100,000 to 200,000 mPa.・ S is good. If the viscosity is less than 5,000 mPa · s, it may easily drip from the palm. If the viscosity exceeds 200,000 mPa · s, the elongation may deteriorate.
本発明における２０℃条件下による粘度は、常法にて調製して得られた染着除去剤をサンプル瓶（食品１４０：第一硝子株式会社製）に１２０ｇ充填し、２０℃条件下で２４時間静置した後に、ヘリカルスタンド付Ｂ型粘度計（モデル：デジタル粘度計ＴＶＢ−１０Ｍ、東機産業株式会社製）により、Ｍ４号ローターを用いて２０℃条件下において３ｒｐｍで１分間、粘度が１００，０００以上２００，０００ｍＰａ・ｓ未満の場合はＭ４号ローターを用いて２０℃条件下において３ｒｐｍで２分間、回転させた後に測定したものである。 The viscosity of the present invention under 20 ° C. conditions is such that 120 g of a dyeing remover prepared by a conventional method is filled in a sample bottle (Food 140: manufactured by Daiichi Glass Co., Ltd.) and 24 ° C. After allowing to stand for a long time, the viscosity was increased by a B-type viscometer with a helical stand (model: digital viscometer TVB-10M, manufactured by Toki Sangyo Co., Ltd.) at 3 rpm for 1 minute using an M4 rotor. In the case of 100,000 or more and less than 200,000 mPa · s, it was measured after rotating at 3 rpm for 2 minutes under the condition of 20 ° C. using an M4 rotor.
本発明の染着除去剤は、液状、ジェル状、クリーム状等の形態で用いられ、チューブ容器等に充填され、使用時まで保存される。 The dyeing remover of the present invention is used in the form of liquid, gel, cream, etc., is filled in a tube container or the like, and is stored until use.
以下に実施例を挙げて本発明をさらに詳細に説明するが、これらは本発明を何ら限定するものではない。 Hereinafter, the present invention will be described in more detail with reference to examples, but these are not intended to limit the present invention in any way.
本明細書に示す評価試験において、染着除去剤に含まれる成分、およびその含有量を種々に変更しながら実施した。各成分の含有量を示す単位はすべて質量％であり、これを常法にて調製した。 In the evaluation test shown in the present specification, the components contained in the dyeing remover and the content thereof were variously changed. The unit indicating the content of each component is all mass%, and this was prepared by a conventional method.
「染着除去」
表１に記載の酸性染毛料０．２ｇをヒトの上腕部に１ｃｍ四方に塗り、５分間放置した後シャンプーで洗浄した。
"Dyeing removal"
0.2 g of the acidic hair dye shown in Table 1 was applied to a human upper arm in a 1 cm square, left for 5 minutes, and then washed with shampoo.
実施例および比較例で得られた各染着除去剤については、染着部に０．２ｇ塗布し５分間放置した後に塗布部を軽く指でなじませ、シャンプーで洗浄した。 For each dyeing remover obtained in Examples and Comparative Examples, 0.2 g was applied to the dyed portion and left for 5 minutes, and then the coated portion was lightly blended with a finger and washed with shampoo.
＜評価基準＞
○：ほぼ染着除去できた
△：やや染着除去できた
×：ほとんど染着除去できなかった
<Evaluation criteria>
◯: Almost all dyeing could be removed △: Somewhat dyeing could be removed ×: Almost no dyeing could be removed
「経時安定性」
実施例および比較例で得られた各染着除去剤を、５０℃および５℃で１ヶ月間保存したものについて目視にて評価した。
"Stability over time"
Each dyeing remover obtained in Examples and Comparative Examples was visually evaluated for those stored at 50 ° C. and 5 ° C. for 1 month.
＜評価基準＞
○：全く問題なし
△：析出が見られるが、使用上問題なし
×：析出が多く、使用できない
<Evaluation criteria>
◯: No problem at all △: Precipitation is seen, but there is no problem in use ×: There is a lot of precipitation and it cannot be used
「刺激性」
実施例および比較例で得られた各染着除去剤を、上腕部に１ｃｍ四方に０．２ｇ塗布し５分間放置後、肌に対する刺激を官能評価した。
"Irritation"
0.2 g of each dyeing remover obtained in Examples and Comparative Examples was applied to the upper arm in a 1 cm square and left for 5 minutes, and then the irritation to the skin was sensory evaluated.
＜評価基準＞
○：刺激を感じない
△：やや刺激を感じる
×：刺激を感じ、使用上問題がある
<Evaluation criteria>
○: No irritation △: Slight irritation ×: I feel irritation and have problems in use
「使用性」
実施例および比較例で得られた各染着除去剤を、上腕部に１ｃｍ四方に０．２ｇ塗布し、５分間静置しながらたれ落ちを目視にて観察した。
"Usability"
0.2 g of each dyeing remover obtained in Examples and Comparative Examples was applied to the upper arm in a 1 cm square manner, and the dripping was visually observed while allowing to stand for 5 minutes.
＜評価基準＞
○：たれ落ちがない
△：ややたれ落ちがみられる
×：たれ落ちる
<Evaluation criteria>
○: No sagging △: Slight sagging ×: Sauce
実施例１８を使用して各試験を行っても、酸性染料の染着除去、経時安定性、刺激性および使用性のいずれの評価も良好であった。 When each test was carried out using Example 18, the evaluations of acid dye removal, stability over time, irritation and usability were all good.
＜実施例１８＞
成分 含有量（質量％）
（Ａ）ラウリン酸カリウム ０．２
（Ｂ）モノエタノールアミン ０．５
（Ｃ）カルボキシメチルセルロースナトリウム ３．０
エデト酸四ナトリウム四水塩 ０．２
１，３−ブチレングリコール ３．０
グリセリン ２．０
精製水 ９１．１
合計 １００．０
<Example 18>
Ingredient content (mass%)
(A) Potassium laurate 0.2
(B) Monoethanolamine 0.5
(C) Sodium Carboxymethyl Cellulose 3.0
Tesodium edetate tetrahydrate 0.2
1,3-butylene glycol 3.0
Glycerin 2.0
Purified water 91.1
Total 100.0
本願発明によれば、酸性染料を配合した染毛料を使用する際に、頭皮、手、肌などに付着した染着性の汚れを除去するための染着除去剤に関して、染着除去、経時安定性、刺激性および使用性に優れる染着除去剤を提供できる。 According to the present invention, when a hair dye containing an acid dye is used, the dyeing remover for removing dyeing stains adhering to the scalp, hands, skin, etc. is dyed and stable over time. It is possible to provide a dye removing agent having excellent properties, irritation and usability.
Claims (6)
（Ａ）脂肪酸石鹸
（Ｂ）モノエタノールアミン
（Ｃ）水溶性セルロース誘導体
を含有する染着除去剤。 The following components (A) to (C);
A dyeing remover containing (A) fatty acid soap (B) monoethanolamine (C) water-soluble cellulose derivative.
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| JP2002226358A (en) * | 2001-02-02 | 2002-08-14 | Nonogawa Shoji Kk | Dye removing agent |
| JP2012126667A (en) * | 2010-12-14 | 2012-07-05 | Nakano Seiyaku Kk | Dyeing removing agent composition and method for removing dyeing |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2002226358A (en) * | 2001-02-02 | 2002-08-14 | Nonogawa Shoji Kk | Dye removing agent |
| JP2012126667A (en) * | 2010-12-14 | 2012-07-05 | Nakano Seiyaku Kk | Dyeing removing agent composition and method for removing dyeing |
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