JP2021027818A - Beverage, method of producing beverage, and method of improving dispersibility and drinking pleasantness - Google Patents
Beverage, method of producing beverage, and method of improving dispersibility and drinking pleasantness Download PDFInfo
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- JP2021027818A JP2021027818A JP2019148145A JP2019148145A JP2021027818A JP 2021027818 A JP2021027818 A JP 2021027818A JP 2019148145 A JP2019148145 A JP 2019148145A JP 2019148145 A JP2019148145 A JP 2019148145A JP 2021027818 A JP2021027818 A JP 2021027818A
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- Prior art keywords
- beverage
- mpa
- mixed solution
- temperature
- insoluble solid
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- 238000000034 method Methods 0.000 title claims abstract description 34
- 230000035622 drinking Effects 0.000 title claims abstract description 32
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- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229940072056 alginate Drugs 0.000 claims abstract description 37
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Landscapes
- Non-Alcoholic Beverages (AREA)
- Jellies, Jams, And Syrups (AREA)
Abstract
Description
本発明は、飲料、飲料の製造方法、ならびに、分散性および飲用感向上方法に関する。 The present invention relates to beverages, methods for producing beverages, and methods for improving dispersibility and drinking sensation.
ダイス状にカットした果肉等の不溶性固形物を含有させた飲料は、飲用時に不溶性固形物の食感などを楽しむことができることから、一定の消費者から支持されており、これまでにも多様な商品が提供されている。
しかしながら、通常、このような飲料に含まれる不溶性固形物の比重と液の比重とは異なるため、不溶性固形物が沈下または浮上してしまい、飲料全体が不均一な状態となってしまう。
よって、この不溶性固形物を飲料中に適切に分散させる技術として、例えば、以下の特許文献1のような技術が提案されている。
Beverages containing insoluble solids such as flesh cut into dice have been supported by a certain number of consumers because they can enjoy the texture of insoluble solids when drinking, and have been diverse. The product is offered.
However, since the specific gravity of the insoluble solid contained in such a beverage is different from the specific gravity of the liquid, the insoluble solid usually sinks or floats, resulting in a non-uniform state of the entire beverage.
Therefore, as a technique for appropriately dispersing this insoluble solid substance in a beverage, for example, a technique such as the following Patent Document 1 has been proposed.
詳細には、特許文献1には、ゲル化剤として脱アシル型ジェランガムのみを0.01〜0.046質量%含むと共に、0.08〜1.28質量%の水溶性カルシウム塩と、固形分を0.1〜64質量%とを含み、10℃における粘度測定値が5〜30mPa・sであり、更にpHが3〜4であることを特徴とする固形分含有容器詰飲料が開示されている。 Specifically, Patent Document 1 contains 0.01 to 0.046% by mass of deacylated gellan gum as a gelling agent, 0.08 to 1.28% by mass of a water-soluble calcium salt, and a solid content. A solid content-containing packaged beverage containing 0.1 to 64% by mass, having a viscosity measurement value at 10 ° C. of 5 to 30 mPa · s, and having a pH of 3 to 4 is disclosed. There is.
特許文献1の実施例の記載を確認すると明らかなように、特許文献1に係る技術によると、冷蔵条件において、飲料中の不溶性固形物を適切に分散させるという効果が確認できる。 As is clear from the description of the examples in Patent Document 1, according to the technique according to Patent Document 1, the effect of appropriately dispersing the insoluble solid matter in the beverage can be confirmed under the refrigerating condition.
ここで、本発明者らは、特許文献1のような従来技術で検討されている「冷蔵条件」だけでなく「温蔵条件」であろうとも飲料中の不溶性固形物を適切に分散させる技術を創出すれば、多様化する消費者のニーズに合致した商品を提供できるのではないかと考えた。 Here, the present inventors appropriately disperse insoluble solids in a beverage not only under "refrigerating conditions" as studied in the prior art as in Patent Document 1 but also under "warming conditions". I thought that if we could create a product, we could provide products that meet the diversifying needs of consumers.
また、従来の不溶性固形物を含有する飲料の液部分はとろみを有するものが多かったが、外観および飲み口(口当たり)の良いさらっとした飲用感とすることによって、飲料として少しでも飲み易くする必要もあると考えた。 In addition, although the liquid portion of conventional beverages containing insoluble solids is often thick, it is made easier to drink as a beverage by giving it a smooth appearance and a smooth taste. I thought it was necessary.
そこで、本発明は、冷温いずれの状態(冷蔵条件および温蔵条件のいずれの状態)でも不溶性固形物の分散性が向上しており、さらっとした飲用感を奏する飲料、飲料の製造方法、ならびに、分散性および飲用感向上方法を提供することを課題とする。 Therefore, according to the present invention, the dispersibility of the insoluble solid matter is improved in any cold or hot state (either the refrigerated condition or the warmed condition), and the beverage, the method for producing the beverage, and the method for producing the beverage, which give a smooth drinking feeling, and It is an object of the present invention to provide a method for improving dispersibility and drinking sensation.
前記課題は、以下の手段により解決することができる。
(1)アルギン酸塩と、熱ゲル化性を呈するゲル化剤と、不溶性固形物と、を含有し、10℃における粘度が10mPa・s以上30mPa・s以下であり、60℃における粘度が5mPa・s以上20mPa・s以下である飲料。
(2)前記ゲル化剤はメチルセルロースである前記1に記載の飲料。
(3)前記不溶性固形物は果実片および野菜片のうちの少なくとも一種である前記1または前記2に記載の飲料。
(4)アルギン酸塩と、熱ゲル化性を呈するゲル化剤と、不溶性固形物と、を含有し、10℃における粘度が10mPa・s以上30mPa・s以下であり、60℃における粘度が5mPa・s以上20mPa・s以下である飲料の製造方法であって、前記アルギン酸塩を0〜30℃の溶媒に分散させて第1水溶液を準備するとともに、前記ゲル化剤を50〜90℃の溶媒に分散させて第2水溶液を準備する第1工程と、前記第1水溶液と前記第2水溶液とを混合して混合液の温度調整を行う第2工程と、前記混合液の温度を40℃以下としつつ攪拌した状態で前記混合液にカルシウムを加える第3工程と、を含み、前記第2工程の温度調整は、前記混合液の温度を30℃以下とする低温調整と、前記混合液の温度を70℃以上とする高温調整と、を含む飲料の製造方法。
(5)アルギン酸塩と、熱ゲル化性を呈するゲル化剤と、不溶性固形物と、を含有する飲料について、冷温いずれの状態でも不溶性固形物の分散性を向上させつつ、さらっとした飲用感とする方法であって、前記アルギン酸塩を0〜30℃の溶媒に分散させて第1水溶液を準備するとともに、前記ゲル化剤を50〜90℃の溶媒に分散させて第2水溶液を準備する第1工程と、前記第1水溶液と前記第2水溶液とを混合して混合液の温度調整を行う第2工程と、前記混合液の温度を40℃以下とし攪拌した状態で前記混合液にカルシウムを加える第3工程と、を含み、前記第2工程の温度調整は、前記混合液の温度を30℃以下とする低温調整と、前記混合液の温度を70℃以上とする高温調整と、を含み、前記飲料の10℃における粘度を10mPa・s以上30mPa・s以下とし、60℃における粘度を5mPa・s以上20mPa・s以下とする分散性および飲用感向上方法。
The problem can be solved by the following means.
(1) It contains alginate, a gelling agent exhibiting thermal gelling property, and an insoluble solid, and has a viscosity at 10 ° C. of 10 mPa · s or more and 30 mPa · s or less, and a viscosity at 60 ° C. of 5 mPa · s. Beverages of s or more and 20 mPa · s or less.
(2) The beverage according to 1 above, wherein the gelling agent is methyl cellulose.
(3) The beverage according to 1 or 2 above, wherein the insoluble solid is at least one of a fruit piece and a vegetable piece.
(4) It contains alginate, a gelling agent exhibiting thermal gelling property, and an insoluble solid, and has a viscosity at 10 ° C. of 10 mPa · s or more and 30 mPa · s or less, and a viscosity at 60 ° C. of 5 mPa · s. A method for producing a beverage having s or more and 20 mPa · s or less, wherein the alginate is dispersed in a solvent at 0 to 30 ° C. to prepare a first aqueous solution, and the gelling agent is used in a solvent at 50 to 90 ° C. The first step of dispersing and preparing the second aqueous solution, the second step of mixing the first aqueous solution and the second aqueous solution to adjust the temperature of the mixed solution, and setting the temperature of the mixed solution to 40 ° C. or lower. The temperature of the second step includes a third step of adding calcium to the mixed solution while stirring while stirring, and the temperature of the mixed solution is adjusted to a low temperature of 30 ° C. or lower and the temperature of the mixed solution is adjusted. A method for producing a beverage, which comprises adjusting the temperature to 70 ° C. or higher.
(5) With respect to a beverage containing alginate, a gelling agent exhibiting heat gelling property, and an insoluble solid substance, the dispersibility of the insoluble solid substance is improved in both cold and hot conditions, and a smooth drinking feeling is achieved. The alginate is dispersed in a solvent at 0 to 30 ° C. to prepare a first aqueous solution, and the gelling agent is dispersed in a solvent at 50 to 90 ° C. to prepare a second aqueous solution. The first step, the second step of mixing the first aqueous solution and the second aqueous solution to adjust the temperature of the mixed solution, and the mixed solution with calcium at a temperature of 40 ° C. or lower and stirring. The temperature adjustment of the second step includes a third step of adding the mixture, a low temperature adjustment of the mixed solution temperature of 30 ° C. or lower, and a high temperature adjustment of the mixed solution temperature of 70 ° C. or higher. A method for improving dispersibility and drinking sensation, which comprises, the viscosity of the beverage at 10 ° C. is 10 mPa · s or more and 30 mPa · s or less, and the viscosity at 60 ° C. is 5 mPa · s or more and 20 mPa · s or less.
本発明に係る飲料は、冷温いずれの状態(冷蔵条件および温蔵条件のいずれの状態)でも不溶性固形物の分散性が向上しており、さらっとした飲用感を奏する。
本発明に係る飲料の製造方法は、冷温いずれの状態(冷蔵条件および温蔵条件のいずれの状態)でも不溶性固形物の分散性が向上しており、さらっとした飲用感を奏する飲料を製造することができる。
本発明に係る分散性および飲用感向上方法は、飲料について、冷温いずれの状態でも不溶性固形物の分散性を向上させつつ、さらっとした飲用感とすることができる。
The beverage according to the present invention has improved dispersibility of insoluble solids in both cold and hot conditions (both refrigerated and warmed conditions), and provides a smooth drinking feeling.
The method for producing a beverage according to the present invention is to produce a beverage that has improved dispersibility of insoluble solids in any cold or hot state (either refrigerating condition or warming condition) and has a smooth drinking feeling. be able to.
The method for improving dispersibility and drinking sensation according to the present invention can improve the dispersibility of insoluble solids in both cold and hot states and give a smooth drinking sensation.
以下、本発明に係る飲料、飲料の製造方法、ならびに、分散性および飲用感向上方法を実施するための形態(実施形態)について説明する。 Hereinafter, a beverage according to the present invention, a method for producing a beverage, and an embodiment (embodiment) for carrying out a method for improving dispersibility and drinking sensation will be described.
[飲料]
本実施形態に係る飲料は、アルギン酸塩と熱ゲル化性を呈するゲル化剤と不溶性固形物とを含有し、10℃における粘度および60℃における粘度がそれぞれ所定範囲内となる飲料である。
[Beverage]
The beverage according to the present embodiment is a beverage containing alginate, a gelling agent exhibiting heat gelling property, and an insoluble solid, and the viscosity at 10 ° C. and the viscosity at 60 ° C. are within predetermined ranges, respectively.
ここで、飲料(液部分)は特に限定されず、例えば、果汁含有飲料、ジュース、野菜飲料、フレーバードウォーター、茶飲料、コーヒー飲料、紅茶飲料、ココア飲料、乳飲料等が挙げられる。 Here, the beverage (liquid portion) is not particularly limited, and examples thereof include fruit juice-containing beverages, juices, vegetable beverages, flavored waters, tea beverages, coffee beverages, tea beverages, cocoa beverages, and dairy beverages.
(アルギン酸塩)
アルギン酸塩とは、褐藻類等に含まれる多糖類であるアルギン酸の塩である。
そして、アルギン酸塩は、低温域においてゲル化能を発揮し、本実施形態に係る飲料を冷蔵した状態において、不溶性固形物の分散性を向上させることができる。
(Alginate)
Alginate is a salt of alginic acid, which is a polysaccharide contained in brown algae and the like.
Then, alginate exhibits a gelling ability in a low temperature range, and can improve the dispersibility of insoluble solids in a refrigerated state of the beverage according to the present embodiment.
使用するアルギン酸塩は、例えば、アルギン酸ナトリウム、アルギン酸アンモニウム、アルギン酸カリウム、アルギン酸カルシウム等である。そして、アルギン酸塩としては、例えば、株式会社キミカのキミカアルギン等を使用することができる。 The alginate used is, for example, sodium alginate, ammonium alginate, potassium alginate, calcium alginate and the like. As the alginate, for example, Kimika algin from Kimika Co., Ltd. can be used.
アルギン酸塩の含有量は特に限定されないが、例えば、キミカアルギンI-2Mを用いた場合、0.12w/v%以上が好ましく、0.3w/v%以下がより好ましい。 The content of alginate is not particularly limited, but for example, when Kimika algin I-2M is used, it is preferably 0.12 w / v% or more, and more preferably 0.3 w / v% or less.
(熱ゲル化性を呈するゲル化剤)
熱ゲル化性を呈するゲル化剤とは、熱が加えられることによってゲル化する性能(熱ゲル化性)を呈するゲル化剤である。また、このゲル化剤は、詳細には、前記したアルギン酸塩のゲル化能が低下する高温域においてゲル化能を発揮するゲル化剤であり、より詳細には、ゲル化温度が50℃以上(好ましくは55〜75℃)のゲル化剤である。
そして、熱ゲル化性を呈するゲル化剤は、前記のとおり、高温域においてゲル化能を発揮することから、本実施形態に係る飲料を温蔵した状態において、不溶性固形物の分散性を向上させることができる。
(Gelting agent exhibiting thermal gelling property)
The gelling agent exhibiting heat gelling property is a gelling agent exhibiting the ability to gel when heat is applied (heat gelling property). Further, the gelling agent is, in detail, a gelling agent that exerts a gelling ability in a high temperature region where the gelling ability of alginate is lowered, and more specifically, a gelling temperature of 50 ° C. or higher. It is a gelling agent (preferably 55 to 75 ° C.).
As described above, the gelling agent exhibiting thermal gelling property exhibits gelling ability in a high temperature range, so that the dispersibility of the insoluble solid matter is improved in the state where the beverage according to the present embodiment is warmed. Can be made to.
熱ゲル化性を呈するゲル化剤としては、メチルセルロース、ヒドロキシプロピルメチルセルロースが挙げられ、特にメチルセルロースが好ましい。そして、ゲル化剤(メチルセルロース)としては、例えば、ユニテックフーズ株式会社のメトセル等を使用することができる。
なお、メチルセルロースとは、セルロースの骨格にメトキシ基が付いた構造の高分子多糖類であり、ヒドロキシプロピルメチルセルロースとは、メチルセルロースのメトキシ基をヒドロキシプロピル基に置換したものである。
Examples of the gelling agent exhibiting thermal gelling property include methyl cellulose and hydroxypropyl methyl cellulose, and methyl cellulose is particularly preferable. Then, as the gelling agent (methyl cellulose), for example, Metocell of Unitech Foods Co., Ltd. can be used.
Methyl cellulose is a high molecular weight polysaccharide having a structure in which a methoxy group is attached to the skeleton of cellulose, and hydroxypropyl methyl cellulose is a substance in which the methoxy group of methyl cellulose is replaced with a hydroxypropyl group.
熱ゲル化性を呈するゲル化剤の含有量は特に限定されないが、例えば、メトセルA4Mを用いた場合、0.1w/v%以下であることが好ましい。熱ゲル化性を呈するゲル化剤の含有量が上記の上限値を超えると、ゲルが硬くなりすぎて、飲用感が低下する。
なお、熱ゲル化性を呈するゲル化剤の含有量は、2種以上の場合は合計の含有量である。
The content of the gelling agent exhibiting thermal gelling property is not particularly limited, but for example, when Metocell A4M is used, it is preferably 0.1 w / v% or less. When the content of the gelling agent exhibiting heat gelling property exceeds the above upper limit value, the gel becomes too hard and the feeling of drinking is deteriorated.
The content of the gelling agent exhibiting thermal gelling property is the total content in the case of two or more kinds.
(不溶性固形物)
不溶性固形物としては、例えば、果物類、野菜類、きのこ類、海藻類等を任意の大きさに切断したもの、柑橘類のさのう、寒天やアルギン酸ナトリウム等のゲル化剤を用いた成形物、マンナンゲル、ナタデココ、タピオカ、カプセル等が挙げられ、これらの中でも、果物類の果肉を任意の大きさに切断したもの(果実片)および野菜類の可食部を任意の大きさに切断したもの(野菜片)の少なくとも一種であることが好ましい。果物類としては、例えば、柑橘類、林檎、梨、洋梨、パインアップル、マンゴー、キウイフルーツ、パパイヤ、黄桃、白桃、あんず等を挙げることができる。野菜類としては、ジャガイモ、玉ねぎ、とうもろこし等を挙げることができる。そして、使用する不溶性固形物は1種類でも2種類以上であってもよい。また、使用する不溶性固形物は、上述の果物類や野菜類の果肉部分であってもよいし、果皮部分であってもよい。
また、不溶性固形物としては、当該不溶性固形物の内部に存在する水分と、当該不溶性固形物の外部に存在する水分とが相互に行き来できる構造を有するものが好ましい。ただし、不溶性固形物としては前述したものに限定されず、食することのできる不溶性固形物であればどのようなものでもよい。
(Insoluble solid)
Examples of insoluble solids include fruits, vegetables, mushrooms, seaweeds, etc. cut into arbitrary sizes, citrus fruits, agar, and molded products using a gelling agent such as sodium alginate. , Mannangel, nata de coco, tapioca, capsules, etc. Among these, the flesh of fruits is cut to an arbitrary size (fruit pieces) and the edible part of vegetables is cut to an arbitrary size. It is preferably at least one kind of thing (vegetable piece). Examples of fruits include citrus fruits, apples, pears, pears, pine apples, mangoes, kiwifruits, papayas, yellow peaches, white peaches, apricots and the like. Examples of vegetables include potatoes, onions, and corn. The insoluble solid material used may be one type or two or more types. Further, the insoluble solid material used may be the flesh portion of the above-mentioned fruits and vegetables, or the pericarp portion.
Further, as the insoluble solid, it is preferable that the insoluble solid has a structure in which the water existing inside the insoluble solid and the water existing outside the insoluble solid can move back and forth. However, the insoluble solid is not limited to the above-mentioned one, and any insoluble solid that can be eaten may be used.
不溶性固形物の形状は特に限定されず、例えば、立方体、直方体、球体、楕円体、不定形形状等が挙げられる。また、不溶性固形物の大きさも特に限定されず、例えば、立方体の場合、一辺の長さが2mm以上20mm以下、球体の場合、直径の長さが2mm以上20mm以下、その他の形状の場合、最大長さが2mm以上25mm以下である。 The shape of the insoluble solid is not particularly limited, and examples thereof include a cube, a rectangular parallelepiped, a sphere, an ellipsoid, and an amorphous shape. The size of the insoluble solid is also not particularly limited. For example, in the case of a cube, the length of one side is 2 mm or more and 20 mm or less, in the case of a sphere, the length of the diameter is 2 mm or more and 20 mm or less, and in the case of other shapes, the maximum is The length is 2 mm or more and 25 mm or less.
不溶性固形物の含有量は特に限定されるものではない。不溶性固形物の含有量は、例えば、3g/L以上であるのが好ましく、7g/L以上、30g/L以上、50g/L以上、70g/L以上であるのがより好ましい。不溶性固形物の含有量が所定値以上であることによって、飲料の飲みごたえを向上させることができる。
また、不溶性固形物の含有量は、例えば、200g/L以下であるのが好ましく、150g/L以下、100g/L以下であるのがより好ましい。不溶性固形物の含有量が所定値以下であることによって、不溶性固形物の分散性の向上という効果を確実に発揮させることができるとともに、飲料の飲み易さを向上させることができる。また、不溶性固形物の含有量が所定値以下であることによって、飲料の製造時において、製造適正(例えば、製造のし易さ等)も向上する。
The content of the insoluble solid matter is not particularly limited. The content of the insoluble solid is, for example, preferably 3 g / L or more, more preferably 7 g / L or more, 30 g / L or more, 50 g / L or more, and 70 g / L or more. When the content of the insoluble solid matter is at least a predetermined value, the drinkability of the beverage can be improved.
The content of the insoluble solid is, for example, preferably 200 g / L or less, more preferably 150 g / L or less, and more preferably 100 g / L or less. When the content of the insoluble solid is not more than a predetermined value, the effect of improving the dispersibility of the insoluble solid can be surely exhibited, and the ease of drinking the beverage can be improved. Further, when the content of the insoluble solid matter is not more than a predetermined value, the production suitability (for example, ease of production) is improved at the time of producing the beverage.
(10℃における粘度)
本実施形態に係る飲料(液部分)の10℃における粘度は、10mPa・s以上が好ましく、20mPa・s以上、21mPa・s以上、22mPa・s以上、23mPa・s以上がより好ましい。また、本実施形態に係る飲料の10℃における粘度は、30mPa・s以下が好ましく、28mPa・s以下、26mPa・s以下、25mPa・s以下がより好ましい。
飲料の10℃における粘度を所定範囲内(所定値以下)とすることによって、冷蔵条件における飲料の飲用感をさらっとしたものとすることができる。
なお、10℃における粘度は、アルギン酸塩や熱ゲル化性を呈するゲル化剤の含有量等によって調製することができる。
(Viscosity at 10 ° C)
The viscosity of the beverage (liquid portion) according to the present embodiment at 10 ° C. is preferably 10 mPa · s or more, more preferably 20 mPa · s or more, 21 mPa · s or more, 22 mPa · s or more, and 23 mPa · s or more. The viscosity of the beverage according to the present embodiment at 10 ° C. is preferably 30 mPa · s or less, more preferably 28 mPa · s or less, 26 mPa · s or less, and 25 mPa · s or less.
By keeping the viscosity of the beverage at 10 ° C. within a predetermined range (below a predetermined value), the drinking feeling of the beverage under the refrigerating condition can be made smooth.
The viscosity at 10 ° C. can be adjusted by the content of alginate or a gelling agent exhibiting thermal gelling property.
(60℃における粘度)
本実施形態に係る飲料(液部分)の60℃における粘度は、5mPa・s以上が好ましく、10mPa・s以上、10.5mPa・s以上、11mPa・s以上がより好ましい。また、本実施形態に係る飲料の60℃における粘度は、20mPa・s以下が好ましく、18mPa・s以下、16mPa・s以下、15mPa・s以下、13mPa・s以下がより好ましい。
飲料の60℃における粘度を所定範囲内(所定値以下)とすることによって、温蔵条件における飲料の飲用感をさらっとしたものとすることができる。
なお、60℃における粘度は、アルギン酸塩や熱ゲル化性を呈するゲル化剤の含有量等によって調製することができる。
(Viscosity at 60 ° C)
The viscosity of the beverage (liquid portion) according to the present embodiment at 60 ° C. is preferably 5 mPa · s or more, more preferably 10 mPa · s or more, 10.5 mPa · s or more, and 11 mPa · s or more. The viscosity of the beverage according to the present embodiment at 60 ° C. is preferably 20 mPa · s or less, more preferably 18 mPa · s or less, 16 mPa · s or less, 15 mPa · s or less, and 13 mPa · s or less.
By keeping the viscosity of the beverage at 60 ° C. within a predetermined range (below a predetermined value), the drinking feeling of the beverage under the warm storage condition can be made smooth.
The viscosity at 60 ° C. can be adjusted by the content of alginate or a gelling agent exhibiting thermal gelling property.
本実施形態において、飲料(液部分)の60℃における粘度A1に対する飲料(液部分)の10℃における粘度A2の比(A2/A1)は、下限値として、1.0以上が好ましく、1.5以上がより好ましく、2.0以上がさらにより好ましい。また、A2/A1は、上限値として、4.0以下が好ましく、3.0以下がより好ましい。 In the present embodiment, the ratio (A 2 / A 1 ) of the viscosity A 2 of the beverage (liquid portion) at 10 ° C. to the viscosity A 1 of the beverage (liquid portion) at 60 ° C. is 1.0 or more as the lower limit. Preferably, 1.5 or more is more preferable, and 2.0 or more is even more preferable. Further, A 2 / A 1 preferably has an upper limit value of 4.0 or less, more preferably 3.0 or less.
(pH)
本実施形態に係る飲料のpHは、特に限定されないものの、本発明は酸性飲料への適用が好ましいため、4.5以下が好ましく、3.8以下がより好ましい。
(PH)
Although the pH of the beverage according to the present embodiment is not particularly limited, the present invention is preferably applied to acidic beverages, and therefore is preferably 4.5 or less, more preferably 3.8 or less.
(不溶性固形物、液の比重)
本実施形態に係る飲料は、不溶性固形物の比重と液の比重とが異なっていようとも不溶性固形物の分散性を向上させるという効果を発揮することから、両者の比重は特に限定されない。
例えば、不溶性固形物の比重を液の比重で割った値である「不溶性固形物の比重/液の比重」について、1以上、1.01以上とし、1.05以下、1.03以下、1.02以下としてもよい。
(Specific gravity of insoluble solids and liquids)
The beverage according to the present embodiment has the effect of improving the dispersibility of the insoluble solid even if the specific gravity of the insoluble solid and the specific gravity of the liquid are different, and therefore the specific gravity of both is not particularly limited.
For example, the "specific gravity of insoluble solids / specific gravity of liquid", which is the value obtained by dividing the specific gravity of insoluble solids by the specific gravity of liquids, is set to 1 or more and 1.01 or more, and 1.05 or less, 1.03 or less, 1 It may be 0.02 or less.
液の比重は、例えば、測定された当該液のBrix(糖度)に基づいて、比重糖度換算表から算出してもよい。比重糖度換算表としては、公知のものを用いることができるが、例えば、最新・ソフトドリンクス(平成15年9月30日発行、編纂:最新・ソフトドリンクス編集委員会、出版:株式会社光琳)の1032〜1033頁に掲載されている表を用いることができる。液のBrixの測定は、例えば、屈折糖度計により行うことができる。屈折糖度計としては、例えば、ATAGO社製のデジタル屈折計rx−5000αを挙げることができる。
また、不溶性固形物の比重は、以下の方法により算出することができる。すなわち、まず、水と不溶性固形物とが混合された混合液を1000ml準備する。そして、混合液中の水と不溶性固形物とを分離して、水の重量と、不溶性固形物の重量と、を測定する。この場合、水の比重は1であることから、水の体積が算出される。また、1000mlから水の体積を減じて、不溶性固形物の体積を算出する。そして、得られた不溶性固形物の重量と、不溶性固形物の体積と、から不溶性固形物の比重を算出する。
なお、不溶性固形物が当該不溶性固形物の内部に存在する水分と、当該不溶性固形物の外部に存在する水分とが相互に行き来できる構造を有する場合、不溶性固形物の比重は、液の比重の値と、上述の算出方法により求められた不溶性固形物の比重から水の比重(具体的には、1)を減じた値と、を合算した値とする。
The specific gravity of the liquid may be calculated from the specific gravity sugar content conversion table, for example, based on the measured Brix (sugar content) of the liquid. As the specific gravity sugar content conversion table, a known one can be used. For example, the latest Soft Drinks (issued on September 30, 2003, compiled by the latest Soft Drinks Editorial Committee, published by Korin Co., Ltd.) ) 1032-1033 can be used. The measurement of Brix of the liquid can be performed by, for example, a refraction sugar content meter. Examples of the refraction sugar content meter include a digital refractometer rx-5000α manufactured by ATAGO.
The specific gravity of the insoluble solid can be calculated by the following method. That is, first, 1000 ml of a mixed solution in which water and an insoluble solid are mixed is prepared. Then, the water in the mixed solution and the insoluble solid are separated, and the weight of the water and the weight of the insoluble solid are measured. In this case, since the specific gravity of water is 1, the volume of water is calculated. Also, the volume of insoluble solids is calculated by subtracting the volume of water from 1000 ml. Then, the specific gravity of the insoluble solid is calculated from the weight of the obtained insoluble solid and the volume of the insoluble solid.
When the insoluble solid has a structure in which the water existing inside the insoluble solid and the water existing outside the insoluble solid can move back and forth, the specific gravity of the insoluble solid is the specific gravity of the liquid. The value is the sum of the value and the value obtained by subtracting the specific gravity of water (specifically, 1) from the specific gravity of the insoluble solid obtained by the above calculation method.
本実施形態に係る飲料の不溶性固形物を除いた部分を液(液部分)と説明したが、当該液は後記する製造方法で製造されることによって、マイクロゲルで構成(マイクロゲル化)されている。なお、本実施形態におけるマイクロゲルとは、アルギン酸塩と、熱ゲル化性を呈するゲル化剤と、を含んで構成される極めて微細なゲルであり、流動性は液体とほぼ変わらない。 The portion of the beverage according to the present embodiment excluding the insoluble solid matter has been described as a liquid (liquid portion), but the liquid is composed of microgels (microgels) by being produced by the production method described later. There is. The microgel in the present embodiment is an extremely fine gel containing alginate and a gelling agent exhibiting thermal gelling property, and its fluidity is almost the same as that of a liquid.
本実施形態に係る飲料は、本発明の所望の効果が阻害されない範囲で飲料として通常配合される甘味料、高甘味度甘味料、酸化防止剤、香料、酸味料、塩類、着色料、pH調整剤、強化剤、乳化剤等(以下、適宜「添加剤」という)を添加することができる。
甘味料としては、例えば、果糖ぶどう糖液糖、グルコース、ガラクトース、マンノース、フルクトース、ラクトース、スクロース、マルトース、グリコーゲンやデンプン等を用いることができる。高甘味度甘味料としては、例えば、ネオテーム、アセスルファムカリウム、スクラロース、サッカリン、サッカリンナトリウム、グリチルリチン酸二ナトリウム、チクロ、ズルチン、ステビア、グリチルリチン、ソーマチン、モネリン、アスパルテーム、アリテーム等を用いることができる。酸化防止剤としては、例えば、ビタミンC、ビタミンE、ポリフェノール等を用いることができる。酸味料としては、例えば、アジピン酸、クエン酸、クエン酸三ナトリウム、グルコノデルタラクトン、グルコン酸、グルコン酸カリウム、グルコン酸ナトリウム、コハク酸、コハク酸一ナトリウム、コハク酸二ナトリウム、酢酸ナトリウム、DL−酒石酸、L−酒石酸、DL−酒石酸ナトリウム、L−酒石酸ナトリウム、二酸化炭素、乳酸、乳酸ナトリウム、氷酢酸、フマル酸、フマル酸一ナトリウム、DL−リンゴ酸、DL−リンゴ酸ナトリウム、リン酸等を用いることができる。塩類としては、例えば、食塩、酸性りん酸カリウム、酸性りん酸カルシウム、りん酸アンモニウム、硫酸マグネシウム、硫酸カルシウム、メタ重亜硫酸カリウム、塩化カルシウム、塩化マグネシウム、硝酸カリウム、硫酸アンモニウム等を用いることができる。着色料としては、例えば、カラメル色素、アントシアニン、クチナシ色素、果汁色素、野菜色素、合成色素等を用いることができる。pH調整剤としては、例えば、重曹、フィチン酸、乳酸、クエン酸、アスコルビン酸等を用いることができる。強化剤としては、例えば、乳酸カルシウム、発酵乳酸カルシウム等を用いることができる。乳化剤としては、例えば、グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ショ糖脂肪酸エステル、サポニン、レシチン等を用いることができる。
なお、前記した添加剤は、一般に市販されているものを使用することができる。
The beverage according to the present embodiment includes sweeteners, high-sweetness sweeteners, antioxidants, flavors, acidulants, salts, colorants, and pH adjustments that are usually blended as beverages as long as the desired effects of the present invention are not impaired. Agents, strengthening agents, emulsifiers and the like (hereinafter, appropriately referred to as “additives”) can be added.
As the sweetener, for example, fructose-glucose liquid sugar, glucose, galactose, mannose, fructose, lactose, sucrose, maltose, glycogen, starch and the like can be used. As the high-sweetness sweetener, for example, neotame, acesulfame potassium, sucralose, saccharin, sodium saccharin, disodium glycyrrhizinate, cyclamate, dulcin, stevia, glycyrrhizin, somatin, monellin, aspartame, alitame and the like can be used. As the antioxidant, for example, vitamin C, vitamin E, polyphenol and the like can be used. Examples of acidulants include malic acid, citric acid, trisodium citrate, gluconodeltalactone, gluconic acid, potassium gluconate, sodium gluconate, succinic acid, monosodium succinate, disodium succinate, sodium acetate, etc. DL-tartaric acid, L-tartaric acid, DL-sodium tartrate, L-sodium tartrate, carbon dioxide, lactic acid, sodium lactate, glacial acetic acid, fumaric acid, monosodium fumarate, DL-malic acid, DL-sodium malate, phosphoric acid Etc. can be used. As the salts, for example, salt, acidic potassium phosphate, acidic calcium phosphate, ammonium phosphate, magnesium sulfate, calcium sulfate, potassium metabisulfite, calcium chloride, magnesium chloride, potassium nitrate, ammonium sulfate and the like can be used. As the colorant, for example, caramel color, anthocyanin, gardenia jasminoides pigment, fruit juice pigment, vegetable pigment, synthetic pigment and the like can be used. As the pH adjuster, for example, baking soda, phytic acid, lactic acid, citric acid, ascorbic acid and the like can be used. As the fortifier, for example, calcium lactate, fermented calcium lactate and the like can be used. As the emulsifier, for example, glycerin fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, sucrose fatty acid ester, saponin, lecithin and the like can be used.
As the above-mentioned additive, a commercially available additive can be used.
また、本実施形態に係る飲料は、本発明の所望の効果が阻害されない範囲で果汁や果汁フレーバーを含有させることもできる。そして、果汁としては、例えば、濃縮果汁、還元果汁、ストレート果汁といった各種果汁、果実ピューレ(火を通した果実あるいは生の果実をすりつぶしたり裏ごししたりした半液体状のもの)、これらの希釈液、濃縮液、混合液などを用いることができる。
そして、果汁に使用する果実(および、果汁フレーバーの果実種)は特に限定されず、従来公知の果実を挙げることができる。
In addition, the beverage according to the present embodiment may contain fruit juice or fruit juice flavor as long as the desired effect of the present invention is not impaired. The fruit juices include, for example, various fruit juices such as concentrated fruit juice, reduced fruit juice, and straight fruit juice, fruit purees (semi-liquid products obtained by grinding or straining cooked fruits or raw fruits), and diluted solutions thereof. , Concentrate, mixed solution and the like can be used.
The fruits used for the fruit juice (and the fruit species having the fruit juice flavor) are not particularly limited, and conventionally known fruits can be mentioned.
(容器詰め飲料)
本実施形態に係る飲料は、各種容器に入れて提供することができる。各種容器に飲料を詰めることにより、長期間の保管による品質の劣化を好適に防止することができる。
なお、容器は密閉できるものであればよく、金属製(アルミニウム製またはスチール製等)のいわゆる缶容器・樽容器、ガラス容器、ペットボトル容器、紙容器、パウチ容器等を適用することができる。容器の容量は特に限定されるものではなく、現在流通しているどのようなものも適用することができる。なお、気体、水分および光線を完全に遮断し、長期間常温で安定した品質を保つことが可能な点から、金属製の容器を適用することが好ましい。
(Beverage in a container)
The beverage according to the present embodiment can be provided in various containers. By filling various containers with beverages, deterioration of quality due to long-term storage can be suitably prevented.
The container may be a container that can be sealed, and a metal (aluminum, steel, etc.) so-called can container / barrel container, a glass container, a PET bottle container, a paper container, a pouch container, or the like can be applied. The capacity of the container is not particularly limited, and any container currently in circulation can be applied. It is preferable to use a metal container because it completely blocks gas, moisture and light rays and can maintain stable quality at room temperature for a long period of time.
以上説明したように、本実施形態に係る飲料によれば、アルギン酸塩と熱ゲル化性を呈するゲル化剤と不溶性固形物とを含有し、10℃における粘度と60℃における粘度とが其々所定範囲内であることから、冷温いずれの状態(冷蔵条件および温蔵条件のいずれの状態)でも不溶性固形物の分散性が向上しており、さらっとした飲用感を奏する。 As described above, the beverage according to the present embodiment contains alginate, a gelling agent exhibiting thermal gelling property, and an insoluble solid, and has a viscosity at 10 ° C. and a viscosity at 60 ° C., respectively. Since it is within a predetermined range, the dispersibility of the insoluble solid matter is improved in any cold or hot state (either the refrigerated condition or the warmed condition), and a smooth drinking feeling is obtained.
[飲料の製造方法]
次に、本実施形態に係る飲料の製造方法を説明する。
本実施形態に係る飲料の製造方法は、以下に示す第1工程と、第2工程と、第3工程と、を含む。
[Beverage manufacturing method]
Next, a method for producing a beverage according to the present embodiment will be described.
The method for producing a beverage according to the present embodiment includes the first step, the second step, and the third step shown below.
(第1工程)
第1工程では、アルギン酸塩を溶媒に分散させた第1水溶液と、熱ゲル化性を呈するゲル化剤を溶媒に分散させた第2水溶液とを準備する。
第1水溶液は、アルギン酸塩を所定温度の溶媒に分散させることによって準備する。そして、第1水溶液の準備に用いる溶媒の温度を0〜30℃(好ましくは15〜25℃)とすることによって、アルギン酸塩を好適に分散させることができる。
第2水溶液は、熱ゲル化性を呈するゲル化剤を所定温度の溶媒に分散させることによって準備する。そして、第2水溶液の準備に用いる溶媒の温度を50〜90℃(好ましくは65〜75℃)とすることによって、熱ゲル化性を呈するゲル化剤を好適に分散させることができる。
(First step)
In the first step, a first aqueous solution in which alginate is dispersed in a solvent and a second aqueous solution in which a gelling agent exhibiting thermal gelling property is dispersed in a solvent are prepared.
The first aqueous solution is prepared by dispersing alginate in a solvent at a predetermined temperature. Then, the alginate can be suitably dispersed by setting the temperature of the solvent used for preparing the first aqueous solution to 0 to 30 ° C (preferably 15 to 25 ° C).
The second aqueous solution is prepared by dispersing a gelling agent exhibiting thermal gelling property in a solvent having a predetermined temperature. Then, by setting the temperature of the solvent used for preparing the second aqueous solution to 50 to 90 ° C. (preferably 65 to 75 ° C.), the gelling agent exhibiting thermal gelling property can be preferably dispersed.
第1工程において、アルギン酸塩と熱ゲル化性を呈するゲル化剤とを各溶媒に適切に分散させておくことによって、ダマになり後記する第2工程で溶質が溶解し難くなるといった事態の発生を回避することができる。
なお、第1工程での「分散」とは、溶媒(分散媒)中に溶質を微粒子状に散在させることを示しており、溶質は溶媒に完全には溶解していない。また、第1工程で使用する溶媒は特に限定されないものの、水、熱水などが挙げられる。
In the first step, by appropriately dispersing the alginate and the gelling agent exhibiting thermal gelling property in each solvent, a situation occurs in which the solute becomes difficult to dissolve in the second step described later due to lumps. Can be avoided.
In addition, "dispersion" in the first step means that the solute is scattered in the solvent (dispersion medium) in the form of fine particles, and the solute is not completely dissolved in the solvent. The solvent used in the first step is not particularly limited, but examples thereof include water and hot water.
(第2工程)
第2工程では、第1工程で準備した第1水溶液と第2水溶液とを混合し、混合した混合液の温度調整を行う。そして、第2工程で2つの温度調整(低温調整と高温調整)を行うことによって、アルギン酸塩と熱ゲル化性を呈するゲル化剤との両方を混合液中に溶解させることができる。
(Second step)
In the second step, the first aqueous solution and the second aqueous solution prepared in the first step are mixed, and the temperature of the mixed liquid is adjusted. Then, by performing two temperature adjustments (low temperature adjustment and high temperature adjustment) in the second step, both alginate and a gelling agent exhibiting thermal gelling property can be dissolved in the mixed solution.
(第2工程:低温調整)
第2工程での低温調整とは、混合液の温度(液温)を30℃以下とする温度調整である。この低温調整によって、熱ゲル化性を呈するゲル化剤を混合液中に適切に溶解させることができる。
なお、低温調整は、混合液の温度を所定値以下にできれば、如何なる方法で混合液を冷却してもよいが、前記の添加剤を含有させた水溶液を混合液に添加することによって、混合液の液温を下げる方法によれば、製造工程数の増加を抑制することができる。
(Second step: low temperature adjustment)
The low temperature adjustment in the second step is a temperature adjustment in which the temperature (liquid temperature) of the mixed solution is 30 ° C. or lower. By this low temperature adjustment, the gelling agent exhibiting thermal gelling property can be appropriately dissolved in the mixed solution.
In the low temperature adjustment, the mixed solution may be cooled by any method as long as the temperature of the mixed solution can be kept below a predetermined value, but the mixed solution is prepared by adding the aqueous solution containing the above-mentioned additive to the mixed solution. According to the method of lowering the liquid temperature of, the increase in the number of manufacturing steps can be suppressed.
(第2工程:高温調整)
第2工程での高温調整とは、混合液の温度(液温)を70℃以上とする温度調整である。この高温調整によって、アルギン酸塩を混合液中に適切に溶解させることができる。
なお、高温調整は、混合液の温度を所定値以上にできれば、如何なる方法で混合液を加熱してもよい。
(Second step: High temperature adjustment)
The high temperature adjustment in the second step is a temperature adjustment in which the temperature (liquid temperature) of the mixed solution is 70 ° C. or higher. By this high temperature adjustment, alginate can be appropriately dissolved in the mixed solution.
In the high temperature adjustment, the mixed solution may be heated by any method as long as the temperature of the mixed solution can be set to a predetermined value or higher.
(第2工程:順番)
第2工程での低温調整と高温調整とは、低温調整→高温調整の順番でもよいし、高温調整→低温調整の順番でもよい。
ただし、後記する実施例において優れた効果の発揮を確認している低温調整→高温調整の順番の方が好ましい。
(Second step: turn)
The low temperature adjustment and the high temperature adjustment in the second step may be in the order of low temperature adjustment → high temperature adjustment, or may be the order of high temperature adjustment → low temperature adjustment.
However, the order of low temperature adjustment → high temperature adjustment, which has been confirmed to exhibit excellent effects in the examples described later, is preferable.
なお、第1水溶液の容量に対して第2水溶液の容量が非常に大きい場合、両水溶液の混合時に混合液の液温が70℃以上となる場合がある。この場合は、混合という処理によって高温調整が実現できる、つまり、混合という処理が高温調整を担うことになるため、別途、高温調整を行う必要はなく、低温調整のみ実施すればよい。
また、第2水溶液に対して第1水溶液の容量が非常に大きい場合、両水溶液の混合時に混合液の液温が30℃以下となる場合がある。この場合は、混合という処理によって低温調整が実現できる、つまり、混合という処理が低温調整を担うことになるため、別途、低温調整を行う必要はなく、高温調整のみ実施すればよい。
If the volume of the second aqueous solution is very large with respect to the volume of the first aqueous solution, the temperature of the mixed solution may be 70 ° C. or higher when both aqueous solutions are mixed. In this case, high temperature adjustment can be realized by the process of mixing, that is, since the process of mixing is responsible for the high temperature adjustment, it is not necessary to separately perform the high temperature adjustment, and only the low temperature adjustment may be performed.
Further, when the volume of the first aqueous solution is much larger than that of the second aqueous solution, the temperature of the mixed solution may be 30 ° C. or lower when both aqueous solutions are mixed. In this case, the low temperature adjustment can be realized by the process of mixing, that is, since the process of mixing is responsible for the low temperature adjustment, it is not necessary to separately perform the low temperature adjustment, and only the high temperature adjustment may be performed.
(第3工程)
第3工程では、混合液の温度を40℃以下としつつ混合液を攪拌した状態でカルシウムを加える。
具体的には、まず、混合液の温度を40℃以下(好ましくは、15〜35℃)とする。なお、第2工程で低温調整→高温調整の順番で温度調整を行った場合は、混合液の温度を所定温度以下まで冷却する必要があるが、高温調整→低温調整の順番で温度調整を行った場合は、冷却する必要はない。
そして、混合液を攪拌しつつカルシウムを加える。ここで、攪拌の条件については、混合液全体にカルシウムが混ざるように攪拌できれば特に限定されないものの、例えば、攪拌強度を1500〜4500rpmとすればよい。
また、混合液に加えるカルシウムの量についても特に限定されないものの、アルギン酸塩を適切にゲル化させるため、混合液中のカルシウムの含有量が0.1〜0.35w/v%となるように添加すればよい。また、ここでいうカルシウムを加えることは、強化剤を加えることであってもよいし、強化剤を含む水溶液を加えることであってもよい。強化剤を含む水溶液を加える場合、攪拌中の混合液に、所定のカルシウムの含有量となるまで、0.02〜0.4g/sで当該水溶液を加えればよい。
なお、混合液にカルシウムを加えた後は攪拌を停止してもよいが、混合液においてカルシウムをより一様に混ぜ合わせるために、カルシウムの添加後も攪拌を1〜15分(好ましくは、8〜12分)続けてもよい。
(Third step)
In the third step, calcium is added while the mixture is stirred while the temperature of the mixture is kept at 40 ° C. or lower.
Specifically, first, the temperature of the mixed solution is set to 40 ° C. or lower (preferably 15 to 35 ° C.). If the temperature is adjusted in the order of low temperature adjustment → high temperature adjustment in the second step, it is necessary to cool the temperature of the mixed solution to a predetermined temperature or less, but the temperature is adjusted in the order of high temperature adjustment → low temperature adjustment. If so, there is no need to cool.
Then, calcium is added while stirring the mixed solution. Here, the stirring conditions are not particularly limited as long as calcium can be mixed in the entire mixed solution, but for example, the stirring intensity may be 1500 to 4500 rpm.
Although the amount of calcium added to the mixed solution is not particularly limited, it is added so that the calcium content in the mixed solution is 0.1 to 0.35 w / v% in order to appropriately gel the alginate. do it. Further, the addition of calcium referred to here may be the addition of a strengthening agent or the addition of an aqueous solution containing a strengthening agent. When an aqueous solution containing a toughening agent is added, the aqueous solution may be added to the mixed solution during stirring at 0.02 to 0.4 g / s until the content of calcium reaches a predetermined level.
The stirring may be stopped after the calcium is added to the mixture, but in order to mix the calcium more uniformly in the mixture, the stirring is continued for 1 to 15 minutes (preferably 8) after the addition of the calcium. ~ 12 minutes) You may continue.
詳細なメカニズムは明確にはなっていないが、前記した条件(所定温度以下、攪拌状態)で前記した混合液にカルシウムを加えることで、アルギン酸塩と「熱ゲル化性を呈するゲル化剤」との混合物の周囲を、カルシウムイオンがイオン結合してゲル化した「アルギン酸塩」によって覆われるような構造の特殊なマイクロゲルが生成されているのではないかと推察する。
なお、混合液に加えるカルシウムは、如何なる状態で添加してもよいが、例えば、カルシウム水溶液の状態で添加すればよい。
Although the detailed mechanism has not been clarified, by adding calcium to the above-mentioned mixture under the above-mentioned conditions (predetermined temperature or less, in a stirred state), alginate and "a gelling agent exhibiting thermal gelling property" It is speculated that a special microgel with a structure in which calcium ions are ionic-bonded and gelled by "alginate" is formed around the mixture of.
The calcium to be added to the mixed solution may be added in any state, and for example, it may be added in the state of an aqueous calcium solution.
(その他の工程)
不溶性固形物は、第2、3工程の途中で混合液に添加してもよく、添加のタイミングは特に限定されないものの、第3工程で得られた混合液に不溶性固形物を添加する工程(第4工程)を設けてもよい。このように第3工程の後に不溶性固形物を添加することによって、不溶性固形物のまわりにゲルが固着してしまうのを抑制することができる。
そして、第3工程(または第4工程)の後に、後処理工程として、例えば、殺菌、容器への充填等の処理を必要に応じて選択的に実施する工程を設けてもよい。
なお、後処理工程の殺菌処理は、殺菌装置での不溶性固形物の詰りを防ぐ観点から、シェルアンドチューブ殺菌によって行うのが好ましいが、同様の処理を行うことができるのであればこれに限定されることなく適用可能である。また、後処理工程の充填処理は、飲料品の製造において通常行われる程度にクリーン度を保ったクリーンルームにて充填するのが好ましい。
そして、後処理工程での各処理の順序は特に限定されない。
(Other processes)
The insoluble solid may be added to the mixed solution in the middle of the second and third steps, and the timing of addition is not particularly limited, but the step of adding the insoluble solid to the mixed solution obtained in the third step (first step). 4 steps) may be provided. By adding the insoluble solid after the third step in this way, it is possible to prevent the gel from sticking around the insoluble solid.
Then, after the third step (or the fourth step), as a post-treatment step, for example, a step of selectively carrying out a treatment such as sterilization or filling into a container may be provided as necessary.
The sterilization treatment in the post-treatment step is preferably performed by shell-and-tube sterilization from the viewpoint of preventing clogging of insoluble solids in the sterilizer, but is limited to this if the same treatment can be performed. Applicable without. Further, the filling treatment in the post-treatment step is preferably filled in a clean room where the cleanliness is maintained to the extent normally performed in the production of beverages.
The order of each treatment in the post-treatment step is not particularly limited.
以上説明したように、本実施形態に係る飲料の製造方法によれば、所定の第1〜3工程を含むことから、冷温いずれの状態(冷蔵条件および温蔵条件のいずれの状態)でも不溶性固形物の分散性が向上しており、さらっとした飲用感を奏する飲料を製造することができる。 As described above, according to the method for producing a beverage according to the present embodiment, since the predetermined steps 1 to 3 are included, the insoluble solid is in any cold or hot state (either the refrigerating condition or the warming condition). The dispersibility of the product is improved, and it is possible to produce a beverage having a smooth drinking feeling.
[分散性および飲用感向上方法]
次に、本実施形態に係る分散性および飲用感向上方法について説明する。
本実施形態に係る分散性および飲用感向上方法は、アルギン酸塩と熱ゲル化性を呈するゲル化剤と不溶性固形物とを含有する飲料について、冷温いずれの状態でも不溶性固形物の分散性を向上させつつ、さらっとした飲用感とする方法である。
なお、各成分の含有量等については、前記した「飲料」において説明した内容と同じであり、各工程の条件等については、前記した「飲料の製造方法」において説明した内容と同じである。
[Method of improving dispersibility and drinking sensation]
Next, the method for improving the dispersibility and drinking sensation according to the present embodiment will be described.
The method for improving dispersibility and drinking sensation according to the present embodiment improves the dispersibility of insoluble solids in a beverage containing alginate, a gelling agent exhibiting heat gelling property, and an insoluble solid in both cold and hot conditions. It is a method to make it feel smooth and drinkable.
The content and the like of each component are the same as those described in the above-mentioned "beverage", and the conditions and the like of each step are the same as the contents described in the above-mentioned "beverage manufacturing method".
以上説明したように、本実施形態に係る分散性および飲用感向上方法によれば、所定の第1〜3工程を含むことから、飲料について、冷温いずれの状態でも不溶性固形物の分散性を向上させつつ、さらっとした飲用感とすることができる。 As described above, according to the method for improving dispersibility and drinking sensation according to the present embodiment, since the predetermined steps 1 to 3 are included, the dispersibility of the insoluble solid matter is improved in the beverage in both cold and hot states. It can be made to have a smooth drinking feeling.
なお、本実施形態に係る飲料、飲料の製造方法、ならびに、分散性および飲用感向上方法において、明示していない特性や条件については、従来公知のものであればよく、前記特性や条件によって得られる効果を奏する限りにおいて、限定されないことは言うまでもない。 In the beverage, the method for producing the beverage, and the method for improving the dispersibility and drinking sensation according to the present embodiment, the characteristics and conditions not specified may be those known in the past, and can be obtained by the above characteristics and conditions. It goes without saying that it is not limited as long as it produces the desired effect.
次に、本発明の要件を満たす実施例とそうでない比較例とを例示して、本発明について説明する。 Next, the present invention will be described by exemplifying examples that satisfy the requirements of the present invention and comparative examples that do not.
[サンプルの準備]
(サンプル1、2)
まず、アルギン酸ナトリウム(アルギン酸I−2M、株式会社キミカ製)を約20℃の水に分散させた第1溶液と、メチルセルロース(メトセル(登録商標)A4M、ユニテックスフーズ株式会社製)を約70℃の熱水に分散させた第2溶液と、を準備した。
そして、サンプル1については、第1溶液と第2溶液とを混合し、約30℃となるように低温調整を行った後、約70℃となるように高温調整を行った。その後、約35℃以下に温度調整してホモミキサーで攪拌(2800rpm、10分)しつつ、発酵乳酸カルシウムを添加した。そして、乳酸発酵カルシウムの添加後、約10分攪拌を続けた後、リンゴダイス(形状:略立方体、約2mm×約2mm×約2mm)を添加し、その後90℃以上で5分間の条件で殺菌し、各物質の含有量が表1に示す値となる「サンプル1」を製造した。
一方、サンプル2については、第1溶液を約70℃に昇温した後、35℃以下に温度調整してホモミキサーで攪拌(2800rpm、10分)しつつ、発酵乳酸カルシウムを添加した。そして、乳酸発酵カルシウムの添加後、約10分攪拌を続けた後、リンゴダイス(形状:略立方体、約2mm×約2mm×約2mm)を添加し、その後90℃以上で5分間の条件で殺菌し、各物質の含有量が表1に示す値となる「サンプル2」を製造した。
[Sample preparation]
(Samples 1 and 2)
First, a first solution in which sodium alginate (alginate I-2M, manufactured by Kimika Co., Ltd.) is dispersed in water at about 20 ° C., and methyl cellulose (Methcell (registered trademark) A4M, manufactured by Unitex Foods Co., Ltd.) at about 70 ° C. A second solution dispersed in hot water was prepared.
Then, for sample 1, the first solution and the second solution were mixed, the low temperature was adjusted to about 30 ° C., and then the high temperature was adjusted to about 70 ° C. Then, the temperature was adjusted to about 35 ° C. or lower, and fermented calcium lactate was added while stirring with a homomixer (2800 rpm, 10 minutes). Then, after the addition of lactic acid fermented calcium, stirring is continued for about 10 minutes, then apple dice (shape: approximately cube, about 2 mm × about 2 mm × about 2 mm) is added, and then sterilized at 90 ° C. or higher for 5 minutes. Then, "Sample 1" in which the content of each substance had the values shown in Table 1 was produced.
On the other hand, for sample 2, fermented calcium lactate was added while raising the temperature of the first solution to about 70 ° C., adjusting the temperature to 35 ° C. or lower, and stirring with a homomixer (2800 rpm, 10 minutes). Then, after the addition of lactic acid fermented calcium, stirring is continued for about 10 minutes, then apple dice (shape: approximately cube, about 2 mm × about 2 mm × about 2 mm) is added, and then sterilized at 90 ° C. or higher for 5 minutes. Then, "Sample 2" in which the content of each substance had the values shown in Table 1 was produced.
(サンプル3)
まず、ジェランガム(ゲルアップ、三栄源エフ・エフ・アイ株式会社製)を約20℃の水に分散させた第3溶液を準備した。
そして、サンプル3については、第3溶液を約70℃に昇温した後、35℃以下に温度調整してホモミキサーで攪拌(攪拌強度等の条件)しつつ、発酵乳酸カルシウムを添加した。そして、乳酸発酵カルシウムの添加後、約10分攪拌を続けた後、リンゴダイス(形状:略立方体、約2mm×約2mm×約2mm)を添加し、その後90℃以上で5分間の条件で殺菌し、各物質の含有量が表1に示す値となる「サンプル3」を製造した。
(Sample 3)
First, a third solution was prepared in which gellan gum (Gelup, manufactured by San-Ei Gen FFI Co., Ltd.) was dispersed in water at about 20 ° C.
Then, for sample 3, after raising the temperature of the third solution to about 70 ° C., the temperature was adjusted to 35 ° C. or lower, and fermented calcium lactate was added while stirring with a homomixer (conditions such as stirring strength). Then, after the addition of lactic acid fermented calcium, stirring is continued for about 10 minutes, then apple dice (shape: approximately cube, about 2 mm × about 2 mm × about 2 mm) are added, and then sterilized at 90 ° C. or higher for 5 minutes. Then, "Sample 3" in which the content of each substance had the values shown in Table 1 was produced.
[粘度の測定]
まず、前記の方法で製造した各サンプルから、目開き約2mmのメッシュを使用してリンゴダイスを取り除いた。
そして、各サンプルを所定温度(60℃又は10℃)とした後、東機産業社製のTVB−10Mを用いて粘度を測定した。
詳細には、ビーカーに注ぎ入れた所定温度のサンプルに対して、TVB−10MのM1ローターを上方から差し込み、回転数100rpm、測定時間30秒の粘度測定を連続して3回実施した。そして、得られた3回の測定値の平均値を算出し、算出した値を各サンプルの粘度(表1に示す粘度)とした。
[Measurement of viscosity]
First, apple dice were removed from each sample produced by the above method using a mesh having an opening of about 2 mm.
Then, after setting each sample to a predetermined temperature (60 ° C. or 10 ° C.), the viscosity was measured using TVB-10M manufactured by Toki Sangyo Co., Ltd.
Specifically, the M1 rotor of TVB-10M was inserted into the sample poured into the beaker at a predetermined temperature from above, and the viscosity was measured three times in succession at a rotation speed of 100 rpm and a measurement time of 30 seconds. Then, the average value of the obtained three measured values was calculated, and the calculated value was used as the viscosity of each sample (viscosity shown in Table 1).
[分散性の評価]
まず、サンプルを200mLのPET容器に詰め、所定温度(常温の25℃、冷蔵条件の10℃、温蔵条件の60℃)とした。そして、リンゴダイスがサンプル全体に行き渡るように天地を返すように2〜5回振って、サンプルを攪拌した。その後、攪拌直後(容器を立たせた直後)、2分後、14時間後の容器内のリンゴダイスの分散性を評価した。なお、容器に詰めたサンプルは、所定温度を維持する条件下で保管していた。
[Evaluation of dispersibility]
First, the sample was packed in a 200 mL PET container and set to a predetermined temperature (25 ° C. at room temperature, 10 ° C. under refrigeration conditions, 60 ° C. under warm storage conditions). Then, the sample was stirred by shaking it 2 to 5 times so that the apple dice were turned upside down so as to spread over the entire sample. Then, immediately after stirring (immediately after standing the container), 2 minutes and 14 hours later, the dispersibility of the apple dice in the container was evaluated. The sample packed in the container was stored under the condition of maintaining a predetermined temperature.
分散性の評価は、PET容器本体の透明部分(キャップ部分を除いた高さ12cmの透明部分)のうち上から2cmの部分において、リンゴダイスが視認できる場合を、分散状態が保たれていると判断し、リンゴダイスが視認できない場合を、分散状態が保たれていないと判断した。
そして、「分散性の評価(冷蔵条件)」は、攪拌直後、攪拌の2分後、および、攪拌の14時間後の全てのサンプルについて、分散状態が保たれていると判断できた場合を「〇」(分散性が良い)と評価し、それ以外の場合を「×」(分散性が悪い)と評価した。
また、「分散性の評価(温蔵条件)」は、攪拌直後、攪拌の2分後、および、攪拌の14時間後の全てのサンプルについて、分散状態が保たれていると判断できた場合を「〇」(分散性が良い)と評価し、それ以外の場合を「×」(分散性が悪い)と評価した。
The evaluation of dispersibility is that the dispersed state is maintained when the apple dice can be visually recognized in the transparent portion of the PET container body (transparent portion having a height of 12 cm excluding the cap portion) from the top. Judging, it was judged that the dispersed state was not maintained when the apple dice could not be visually recognized.
Then, the "evaluation of dispersibility (refrigerating condition)" is performed when it can be determined that the dispersed state is maintained for all the samples immediately after stirring, 2 minutes after stirring, and 14 hours after stirring. It was evaluated as "○" (good dispersibility), and in other cases, it was evaluated as "x" (poor dispersibility).
In addition, the "evaluation of dispersibility (warming conditions)" is based on the case where it can be determined that the dispersed state is maintained for all the samples immediately after stirring, 2 minutes after stirring, and 14 hours after stirring. It was evaluated as "○" (good dispersibility), and in other cases, it was evaluated as "x" (poor dispersibility).
[外観の評価]
訓練された識別能力のあるパネル10名が前記の方法により製造した各サンプルの外観の状態を目視で確認した。
10℃および60℃の状態における其々のサンプルの外観について、容器壁面でゲルのざらつきが確認できたり、プルプルとしたゲル状の感じを確認できたりするものでない場合を「〇」(外観が良い)と評価し、容器壁面でゲルのざらつきが確認できたり、プルプルとしたゲル状の感じを確認できたりする場合を「×」(外観が悪い)と評価した。
なお、外観の評価(〇/×)は、パネル全員の評価が一致した。
[Appearance evaluation]
Ten trained and discriminating panels visually confirmed the appearance of each sample produced by the method described above.
Regarding the appearance of each sample at 10 ° C and 60 ° C, if it is not possible to confirm the roughness of the gel on the wall surface of the container or the gel-like feeling of pulling, it is "○" (the appearance is good). ), And the case where the roughness of the gel can be confirmed on the wall surface of the container or the gel-like feeling of pulling and pulling can be confirmed is evaluated as "x" (poor appearance).
As for the evaluation of appearance (○ / ×), the evaluations of all the panels were the same.
[飲み口の評価]
訓練された識別能力のあるパネル5名が前記の方法により製造した各サンプルの飲み口を飲んで確認した。
10℃および60℃の状態における其々のサンプルの飲み口について、とろみを強く感じたり、ゲル様のざらつきを感じたり、ドロドロした舌触りを感じたりするものではない場合を「〇」(飲み口が良い)と評価し、とろみを強く感じたり、ゲル様のざらつきを感じたり、ドロドロした舌触りを感じたりする場合を「×」(飲み口が悪い)と評価した。
なお、飲み口の評価(〇/×)は、パネル全員の評価が一致した。
[Evaluation of mouthpiece]
Five trained and discriminating panels confirmed by drinking the mouth of each sample prepared by the method described above.
Regarding the mouthpiece of each sample at 10 ° C and 60 ° C, if you do not feel a strong thickening, gel-like roughness, or a muddy texture, "○" (the mouthpiece is It was evaluated as "good", and when it felt a strong thickening, a gel-like roughness, or a muddy texture, it was evaluated as "x" (bad mouthfeel).
As for the evaluation of the mouthpiece (○ / ×), the evaluations of all the panels were the same.
表1に、各サンプルの規格を示すとともに、各評価の結果を示す。
また、参考として、分散性の評価におけるサンプル(一部のサンプルを除く)の写真を図1〜3に示す。なお、14時間での分散性については、先行技術文献でも示されているので、写真を省略した。
Table 1 shows the standards of each sample and the results of each evaluation.
For reference, photographs of samples (excluding some samples) in the evaluation of dispersibility are shown in FIGS. 1 to 3. Since the dispersibility in 14 hours is also shown in the prior art document, the photograph is omitted.
(試験結果の検討)
サンプル1は、表1に示すように、アルギン酸塩とメチルセルロース(熱ゲル化性を呈するゲル化剤)とリンゴダイス(不溶性固形物)とを含有し、10℃と60℃における粘度が其々所定範囲内であったことから、冷温いずれの状態(冷蔵条件および温蔵条件のいずれの状態)でも不溶性固形物の分散性が良いとの結果となった(図2、3参照)。なお、サンプル1は、図1に示すように、常温の状態でも不溶性固形物の分散性が良いと判断できる結果となった。
また、サンプル1は、表1に示すように、10℃と60℃のいずれの飲み口の評価についても、「〇」との結果が得られるとともに、10℃と60℃のいずれの外観の評価についても、「〇」との結果が得られた。このことから、サンプル1は、さらっとした飲用感であることがわかった。
(Examination of test results)
As shown in Table 1, sample 1 contains alginate, methyl cellulose (a gelling agent exhibiting heat gelling property), and apple dice (an insoluble solid), and the viscosities at 10 ° C and 60 ° C are predetermined, respectively. Since it was within the range, the result was that the dispersibility of the insoluble solid was good in both cold and hot conditions (both refrigerating and warming conditions) (see FIGS. 2 and 3). As shown in FIG. 1, it was judged that the sample 1 had good dispersibility of the insoluble solid matter even at room temperature.
In addition, as shown in Table 1, the sample 1 gave a result of "○" in the evaluation of both the drinking spouts at 10 ° C and 60 ° C, and evaluated the appearance of both 10 ° C and 60 ° C. The result of "○" was also obtained. From this, it was found that Sample 1 had a smooth drinking feeling.
一方、サンプル2は、表1に示すように、メチルセルロース(熱ゲル化性を呈するゲル化剤)を含有していなかったことから、温蔵状態において、不溶性固形物の分散性が悪いとの結果となった(図3参照)。 On the other hand, as shown in Table 1, Sample 2 did not contain methyl cellulose (a gelling agent exhibiting thermal gelling property), and as a result, the dispersibility of the insoluble solid matter was poor in the stored state. (See Fig. 3).
なお、メチルセルロースを含有する「サンプル1」とメチルセルロースを含有していない「サンプル2」とを比較すると、サンプル2の方が60℃の粘度が高くなっているが、この理由は、アルギン酸塩の含有量がサンプル2の方が僅かに多かったためであると考える。この結果から、サンプル1はメチルセルロースを含有させることによって、60℃における粘度の上昇を抑制しつつ(つまり、60℃におけるさらっとした飲用感を実現しつつ)、分散性も向上できるということがわかった。 Comparing "Sample 1" containing methyl cellulose and "Sample 2" not containing methyl cellulose, the viscosity of Sample 2 is higher at 60 ° C. The reason for this is that it contains alginate. It is considered that this is because the amount of sample 2 was slightly larger. From this result, it was found that by containing methyl cellulose, the sample 1 can improve the dispersibility while suppressing the increase in viscosity at 60 ° C. (that is, realizing a smooth drinking feeling at 60 ° C.). It was.
また、サンプル3は、特許文献1で使用されているジェランガムを使用したものであるが、アルギン酸塩やメチルセルロース(熱ゲル化性を呈するゲル化剤)を含有していなかったことから、飲み口の評価および外観の評価において、さらっとしていないとの結果となった。 In addition, although sample 3 uses gellan gum used in Patent Document 1, it did not contain alginate or methyl cellulose (a gelling agent exhibiting heat gelling property), so that it could be used in the mouthpiece. In the evaluation and the evaluation of the appearance, the result was that it was not dry.
Claims (5)
10℃における粘度が10mPa・s以上30mPa・s以下であり、
60℃における粘度が5mPa・s以上20mPa・s以下である飲料。 Contains alginate, a gelling agent exhibiting thermal gelling properties, and an insoluble solid,
The viscosity at 10 ° C. is 10 mPa · s or more and 30 mPa · s or less.
A beverage having a viscosity at 60 ° C. of 5 mPa · s or more and 20 mPa · s or less.
前記アルギン酸塩を0〜30℃の溶媒に分散させて第1水溶液を準備するとともに、前記ゲル化剤を50〜90℃の溶媒に分散させて第2水溶液を準備する第1工程と、
前記第1水溶液と前記第2水溶液とを混合して混合液の温度調整を行う第2工程と、
前記混合液の温度を40℃以下としつつ攪拌した状態で前記混合液にカルシウムを加える第3工程と、を含み、
前記第2工程の温度調整は、前記混合液の温度を30℃以下とする低温調整と、前記混合液の温度を70℃以上とする高温調整と、を含む飲料の製造方法。 It contains alginate, a gelling agent exhibiting thermal gelability, and an insoluble solid, and has a viscosity of 20 mPa · s or more and 30 mPa · s or less at 10 ° C. and a viscosity of 10 mPa · s or more and 20 mPa at 60 ° C.・ A method for producing a beverage having a viscosity of s or less.
The first step of dispersing the alginate in a solvent at 0 to 30 ° C. to prepare a first aqueous solution, and dispersing the gelling agent in a solvent at 50 to 90 ° C. to prepare a second aqueous solution.
A second step of mixing the first aqueous solution and the second aqueous solution to adjust the temperature of the mixed solution, and
The third step of adding calcium to the mixed solution in a state of stirring while keeping the temperature of the mixed solution at 40 ° C. or lower is included.
The temperature adjustment in the second step is a method for producing a beverage, which comprises a low temperature adjustment in which the temperature of the mixed solution is 30 ° C. or lower and a high temperature adjustment in which the temperature of the mixed solution is 70 ° C. or higher.
前記アルギン酸塩を0〜30℃の溶媒に分散させて第1水溶液を準備するとともに、前記ゲル化剤を50〜90℃の溶媒に分散させて第2水溶液を準備する第1工程と、
前記第1水溶液と前記第2水溶液とを混合して混合液の温度調整を行う第2工程と、
前記混合液の温度を40℃以下とし攪拌した状態で前記混合液にカルシウムを加える第3工程と、を含み、
前記第2工程の温度調整は、前記混合液の温度を30℃以下とする低温調整と、前記混合液の温度を70℃以上とする高温調整と、を含み、
前記飲料の10℃における粘度を10mPa・s以上30mPa・s以下とし、60℃における粘度を5mPa・s以上20mPa・s以下とする分散性および飲用感向上方法。 A method for making a beverage containing alginate, a gelling agent exhibiting heat gelling property, and an insoluble solid substance a smooth drinking feeling while improving the dispersibility of the insoluble solid substance in both cold and hot conditions. And
The first step of dispersing the alginate in a solvent at 0 to 30 ° C. to prepare a first aqueous solution, and dispersing the gelling agent in a solvent at 50 to 90 ° C. to prepare a second aqueous solution.
A second step of mixing the first aqueous solution and the second aqueous solution to adjust the temperature of the mixed solution, and
The third step of adding calcium to the mixed solution in a state where the temperature of the mixed solution is set to 40 ° C. or lower and stirred is included.
The temperature adjustment in the second step includes a low temperature adjustment in which the temperature of the mixed solution is 30 ° C. or lower and a high temperature adjustment in which the temperature of the mixed solution is 70 ° C. or higher.
A method for improving dispersibility and drinking sensation, wherein the viscosity of the beverage at 10 ° C. is 10 mPa · s or more and 30 mPa · s or less, and the viscosity at 60 ° C. is 5 mPa · s or more and 20 mPa · s or less.
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS57105174A (en) * | 1980-11-19 | 1982-06-30 | Coca Cola Co | Reduction of solid separation of fruit containing product |
US4433000A (en) * | 1980-11-19 | 1984-02-21 | Coca Cola Company | Method for preventing separation in fruit juice-containing products |
US5807603A (en) * | 1996-12-19 | 1998-09-15 | The Coca Cola Company | Stabilizer system and method for lessening the separation of solids in juice-containing products |
US20100119662A1 (en) * | 2007-01-25 | 2010-05-13 | Cognis Ip Management Gmbh | Two Phase Beverage Comprising Encapsulated Fruit Pulp |
WO2014119798A1 (en) * | 2013-02-04 | 2014-08-07 | 株式会社明治 | Method for manufacturing beverage containing processed edible-plant powder having improved dispersion stability or redispersability |
JP2014171448A (en) * | 2013-03-11 | 2014-09-22 | Japan Tobacco Inc | Solid content-containing container-packaged beverage and method for manufacturing the same |
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2019
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Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57105174A (en) * | 1980-11-19 | 1982-06-30 | Coca Cola Co | Reduction of solid separation of fruit containing product |
US4433000A (en) * | 1980-11-19 | 1984-02-21 | Coca Cola Company | Method for preventing separation in fruit juice-containing products |
US5807603A (en) * | 1996-12-19 | 1998-09-15 | The Coca Cola Company | Stabilizer system and method for lessening the separation of solids in juice-containing products |
US20100119662A1 (en) * | 2007-01-25 | 2010-05-13 | Cognis Ip Management Gmbh | Two Phase Beverage Comprising Encapsulated Fruit Pulp |
WO2014119798A1 (en) * | 2013-02-04 | 2014-08-07 | 株式会社明治 | Method for manufacturing beverage containing processed edible-plant powder having improved dispersion stability or redispersability |
JP2014171448A (en) * | 2013-03-11 | 2014-09-22 | Japan Tobacco Inc | Solid content-containing container-packaged beverage and method for manufacturing the same |
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