JP5156977B2 - Formulation and production method of carbon dioxide containing soft jelly beverage in sealed container - Google Patents

Formulation and production method of carbon dioxide containing soft jelly beverage in sealed container Download PDF

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JP5156977B2
JP5156977B2 JP2007288140A JP2007288140A JP5156977B2 JP 5156977 B2 JP5156977 B2 JP 5156977B2 JP 2007288140 A JP2007288140 A JP 2007288140A JP 2007288140 A JP2007288140 A JP 2007288140A JP 5156977 B2 JP5156977 B2 JP 5156977B2
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container
gelling agent
carbon dioxide
beverage
jelly
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JP2009112236A (en
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英史 中田
幸美 山川
正張 佐橋
昭則 細江
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Coca Cola Co
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Priority to TW097141790A priority patent/TW200934397A/en
Priority to BRPI0819181-6A2A priority patent/BRPI0819181A2/en
Priority to PCT/IB2008/003781 priority patent/WO2009060314A2/en
Priority to KR1020107010985A priority patent/KR20100093052A/en
Priority to MX2010004799A priority patent/MX2010004799A/en
Priority to CN200880114330A priority patent/CN101848654A/en
Priority to EP08848236A priority patent/EP2230947A2/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/02Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation containing fruit or vegetable juices
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/54Mixing with gases
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L21/00Marmalades, jams, jellies or the like; Products from apiculture; Preparation or treatment thereof
    • A23L21/10Marmalades; Jams; Jellies; Other similar fruit or vegetable compositions; Simulated fruit products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/256Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from seaweeds, e.g. alginates, agar or carrageenan
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/269Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of microbial origin, e.g. xanthan or dextran
    • A23L29/27Xanthan not combined with other microbial gums
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

Description

本発明は、特定のゲル化剤と飲料原料液とから構成される柔らかなゲル状飲料(以下「ソフトゼリー状飲料」という)に炭酸ガスを吸収させてなる密閉容器入り炭酸ガス含有ソフトゼリー状飲料の製造方法に関し、特に密閉容器を軽く数回振ってゼリーを破砕した後容器から排出させて飲用するかまたはストローを容器内に差し込んでゼリーを吸引して飲用するタイプの密閉容器入り炭酸ガス含有ソフトゼリー状飲料の配合と製造方法に関する。   The present invention relates to a soft jelly-form containing soft carbon in a sealed container in which a soft gel beverage (hereinafter referred to as “soft jelly beverage”) composed of a specific gelling agent and a beverage raw material liquid is absorbed with carbon dioxide. Regarding the beverage production method, in particular, the sealed container is a type of carbon dioxide gas in which the sealed container is shaken lightly several times and then the jelly is crushed and then discharged from the container for drinking, or a straw is inserted into the container to suck and drink the jelly. It is related with the mixing | blending and manufacturing method of a containing soft jelly-form drink.

炭酸ガス含有飲料あるいは炭酸ガス含有飲料中に細片状(チップ状)のゼリーを加えた飲料は市場において周知の飲料である。   Beverages containing carbon dioxide gas or beverages obtained by adding strip-like (chip-like) jelly to carbon dioxide gas-containing beverages are well-known beverages on the market.

近年食品に対する嗜好が多様化するにつれ、従来から存在する飲食物にあきたらず新規な形態の飲食物を求める傾向が特に若年層に強まっており、缶、カップ等の密閉容器入り飲料においてもこの傾向にあわせて新規な形態のものが現れている。   In recent years, as food preferences have diversified, the tendency to seek new forms of food and drinks, which are not related to existing foods and drinks, has become particularly strong, and even in beverages in cans, cups and other closed containers New forms appear in line with trends.

特願2001−021300号公報には、密閉容器入り炭酸ガス含有飲料の分野において、このような傾向に合致し従来の炭酸ガス含有飲料と差別化し得る新規で美味なソフトゼリー状飲料を提供することを目的として、易溶性寒天、キサンタンガム、ローカストビーンガム、糖類および有機酸を組合せてゼリーを作り、このゼリーを細片状に裁断し、この細片状ゼリーと、糖類および酸味料を含むシロップ液に炭酸ガスを吸収させた炭酸ガス含有シロップ液とを容器に充填し密封した後加熱処理を施してゼリーを溶融させ、溶融したゼリーとシロップ液とを混合均一化した後冷却することを特徴とする密閉容器入り炭酸ガス含有ソフトゼリー状飲料の製造方法を開示されている。   In Japanese Patent Application No. 2001-021300, to provide a new and delicious soft jelly-like beverage that matches such a trend and can be differentiated from conventional carbon dioxide-containing beverages in the field of carbon dioxide-containing beverages in sealed containers. For the purpose of making a jelly by combining easily soluble agar, xanthan gum, locust bean gum, sugar and organic acid, this jelly is cut into pieces, this jelly and a syrup solution containing sugar and acidulant The container is filled with a carbon dioxide gas-containing syrup solution that has absorbed carbon dioxide gas, sealed and then heat-treated to melt the jelly, and the molten jelly and syrup solution are mixed and homogenized and then cooled. A method for producing a carbon dioxide containing soft jelly beverage in a closed container is disclosed.

この方法によって製造された炭酸ガス含有ソフトゼリー状飲料は、缶等密閉容器の内容物である飲料全体が柔らかなゼリーの塊となっており、容器にストローを差込んでゼリーを吸引するか、あるいは容器を開封する前に軽く容器を振って容器内のゼリーを破砕した後容器を開封してゼリーを飲用することができる飲料であるが、炭酸ガス含有飲料を容器に充填、密封した後の寒天等のゲル化剤の溶融温度が85℃〜90℃の高温であり、このような高温で炭酸含有飲料を密封した容器を加熱すると内圧が高まりバックリングを起こす危険があるので、外部に加圧を施し内圧との均衡を保たせる熱水加圧レトルトを必要とし、工業的生産において、加熱装置としてパストライザーを使用する従来既設の炭酸飲料を製造するためのラインをそのまま使用することができず、既設の炭酸飲料製造ラインに加えて熱水加圧レトルト装置を設けなければならず、製造コストが増大するという問題点を有していた。   The soft jelly-like beverage containing carbon dioxide gas produced by this method is a soft jelly lump that is the contents of a sealed container such as a can, and sucks the jelly by inserting a straw into the container, Alternatively, it is a beverage that can be shaken lightly before crushing the container to crush the jelly in the container and then open the container to drink the jelly, but after filling and sealing the carbon dioxide containing beverage in the container Since the melting temperature of gelling agents such as agar is as high as 85 ° C. to 90 ° C., heating a container sealed with a carbonated beverage at such a high temperature may increase the internal pressure and cause buckling. A hot water pressurizing retort that applies pressure to maintain balance with the internal pressure is required, and in industrial production, a line for producing a conventional carbonated beverage that uses a pastoriser as a heating device is used. Or it can not be used, it is necessary to provide a hot water pressure retort apparatus in addition to the existing carbonated beverage production line, has a problem that manufacturing cost is increased.

また、上記の方法では、ゲル化剤のゼリーを裁断して5mm角程度のキューブ状に均一形状化しなければならず、このための工程を必要としていた。また、シロップと水を混合したものにカーボネーターで炭酸を含有せしめた後キューブ状のゲル化剤ゼリーを充填するという別個の工程を必要としていた。したがって製造工程が複雑となり、この点でも製造コストが増大するという問題点を有していた。   In the above method, the gelling agent jelly must be cut into a uniform shape of about 5 mm square cube, which requires a process for this purpose. In addition, a separate process is required in which a mixture of syrup and water is made to contain carbonic acid with a carbonator and then filled with a cube-shaped gelling agent jelly. Therefore, the manufacturing process becomes complicated, and this also has a problem that the manufacturing cost increases.

また、特許第2658008号公報には、冷水不溶性のカッパーカラギナンおよび/またはアイオータカラギナンを水溶液中に均一分散したものに炭酸ガスを封入した後容器に充填密封し加熱殺菌した後冷却する炭酸ガス含有ゼリー飲料の製造方法が開示されている。しかし、この方法によれば、ゲル化剤を水溶液に分散し炭酸ガスを封入した後耐圧ガラスびんに充填し、温水中で85℃、20分(実施例1)または温水シャワーで90℃、15分間(実施例2)加熱することにより殺菌しており、この加熱殺菌温度条件では、耐圧ガラスびんならばよいが、食缶では上記のとおりバックリングを起こす危険があるので、熱水加圧レトルトを必要とし、パストライザーを使用する従来既設の炭酸飲料製造ラインをそのまま使用することはできない。さらに、この方法によれば、ゲル化剤としてカッパーカラギナンおよび/またはアイオータカラギナンを0.3〜2.0重量%使用することを必要とし(請求項2および表1、表2)、したがってその他のゲル化剤を含むゲル化剤の総量も0.3%以上とすることが必要であるが、この方法で作成されたゼリー状飲料はセット状態が極めて固く、スプーンで喫食することはできるが、容器として食缶や紙カップを使用し、開封前に容器を軽く振って容器内のゼリーを破砕した後容器を開封してゼリーを飲用しようとしても振ることによってゼリーが容器壁から分離はするが、小さく破砕されることはない。同様に容器にストローを差し込んでゼリーを吸引することより飲用することも不可能である。   Japanese Patent No. 2658008 discloses a carbon dioxide gas containing cold water-insoluble copper carrageenan and / or iota carrageenan uniformly dispersed in an aqueous solution, filled with carbon dioxide gas, filled in a container, sealed, heated and sterilized, and then cooled. A method for producing a jelly beverage is disclosed. However, according to this method, the gelling agent is dispersed in an aqueous solution and carbon dioxide gas is enclosed, and then the pressure-resistant glass bottle is filled, and 85 ° C. for 20 minutes in warm water (Example 1) or 90 ° C. in a warm water shower, 15 Sterilized by heating for a minute (Example 2). Under this heat sterilization temperature condition, a pressure-resistant glass bottle is sufficient, but in food cans there is a risk of buckling as described above, so hot water pressure retort Therefore, the existing carbonated beverage production line that uses the paste riser cannot be used as it is. Furthermore, this method requires the use of 0.3-2.0% by weight of copper carrageenan and / or iota carrageenan as the gelling agent (Claim 2 and Tables 1 and 2), thus other The total amount of the gelling agent including the gelling agent must be 0.3% or more, but the jelly-like beverage prepared by this method is very hard to set and can be eaten with a spoon. Using a food can or paper cup as a container, shaking the container lightly before opening it, crushing the jelly in the container, then opening the container and shaking it to drink the jelly will separate the jelly from the container wall It will not be crushed small. Similarly, it is impossible to drink by inserting a straw into the container and sucking the jelly.

したがって、この方法は、密閉容器を軽く数回振ってゼリーを破砕した後容器から排出させて飲用するかまたはストローを容器内に差し込んでゼリーを吸引して飲用するタイプの密閉容器入り炭酸ガス含有ソフトゼリー状飲料の製造方法としては不適である。   Therefore, this method shakes the sealed container several times and crushes the jelly, then drains it from the container and drinks it, or inserts a straw into the container and sucks the jelly for drinking. It is unsuitable as a method for producing a soft jelly beverage.

また、特開2007−236299号公報には、飲料総量の0.05〜0.15質量%のカッパーカラギナンと飲料総量の0.08〜0.20質量%の溶融温度70℃〜80℃のローカストビーンガムを主成分とするゲル化剤を飲料原料液に混合し、この混合液に炭酸を含有させた炭酸ガス含有混合液を容器に充填し密封した後70℃〜80℃で10分〜20分間加熱処理を施してゲル化剤を溶融させ、ゲル化剤が溶融した混合液を混合均一化した後冷却する炭酸ガス含有ソフトゼリー状飲料の製造方法が開示されている。この方法によれば、ゲル化剤は、溶融温度が70℃〜80℃のカッパーカラギナンとこの温度範囲で溶融するローカストビーンガムを主成分とするので、炭酸ガス含有混合液を容器に充填・密封後70℃〜80℃の加熱処理を施すことによってゲル化剤が飲料中に溶融し、これによってレトルト装置を設ける必要がなくなり、加熱装置としてパストライザーを使用する従来既設の炭酸飲料製造ラインを使用することができ、製造方法を簡素化することができるので、製造コストを低減することができる。   Japanese Patent Application Laid-Open No. 2007-236299 discloses a copper carrageenan of 0.05 to 0.15% by mass of the total amount of beverage and a locust having a melting temperature of 70 ° C. to 80 ° C. of 0.08 to 0.20% by mass of the total amount of beverage. A gelling agent mainly composed of bean gum is mixed with a beverage raw material liquid, and a carbon dioxide-containing mixed liquid containing carbonic acid in this mixed liquid is filled in a container and sealed, and then at 70 to 80 ° C for 10 minutes to 20 minutes. A method for producing a soft jelly-containing beverage containing carbon dioxide gas is disclosed in which a gelling agent is melted by performing a heat treatment for a minute, and a mixed solution in which the gelling agent is melted is mixed and then cooled. According to this method, the gelling agent is mainly composed of copper carrageenan having a melting temperature of 70 ° C. to 80 ° C. and locust bean gum that melts in this temperature range. After that, the gelling agent melts in the beverage by performing a heat treatment at 70 ° C. to 80 ° C., thereby eliminating the need to provide a retort device, and using a conventional carbonated beverage production line that uses a pastoriser as the heating device. Since the manufacturing method can be simplified, the manufacturing cost can be reduced.

しかし、この方法によっても、容器にストローを差し込んでゼリーを吸引して飲用することはできるが、容器として食缶や紙カップを使用し、開封前に容器を軽く振って容器内のゼリーを破砕した後容器を開封してゼリーを飲用しようとしても、数回振るだけでは容器からの排出に手間取るか、数回振った上で容器を押すことによりゼリーを排出さなければならない。したがって、この方法は、密閉容器を軽く数回振ってゼリーを破砕した後容器から排出させて飲用するタイプの密閉容器入り炭酸ガス含有ソフトゼリー状飲料の製造方法としては不充分である。
特願2001−021300号公報 特許第2658008号公報 特開2007−236299号公報
However, this method can also be used by inserting a straw into the container and sucking and drinking the jelly, but using a food can or paper cup as the container, the container was crushed gently by shaking the container before opening. Even if you try to drink the jelly after opening the container afterwards, if you shake it only a few times, you will have to expel the discharge from the container, or you will have to discharge the jelly by pushing the container after shaking it several times. Therefore, this method is insufficient as a method for producing a soft jelly-like beverage containing a carbon dioxide gas in a sealed container in which the sealed container is shaken lightly several times to crush the jelly and then discharge the container from the container.
Japanese Patent Application No. 2001-021300 Japanese Patent No. 2658008 JP 2007-236299 A

本発明は、上記の製造法における従来技術の問題点を解決することを目的としてなされたものであって、炭酸ガス含有ソフトゼリー状飲料として充分な味覚、食感を保ちながら、レトルト装置を設ける必要がなく従来既設の炭酸飲料製造ラインをそのまま使用することができ、またル化剤をキューブ状に裁断する工程を必要としない簡素化された製造工程を使用することができる上に、密閉容器を軽く数回振ってゼリーを破砕した後容器から排出させて飲用するかまたはストローを容器内に差し込んでゼリーを吸引して飲用するタイプの密閉容器入り炭酸ガス含有ソフトゼリー状飲料の製造に好適な配合と製造方法を提供しようとするものである。 The present invention has been made for the purpose of solving the problems of the prior art in the above production method, and is provided with a retort device while maintaining sufficient taste and texture as a carbon dioxide-containing soft jelly beverage. it can be used as is conventional existing carbonated beverage manufacturing line is not necessary, also on the gel agent can be used step manufacturing process is simplified without requiring to be cut into cubes, sealed For the production of soft jelly-like beverages containing carbon dioxide gas in sealed containers of the type in which the container is shaken lightly several times and then drained from the container for drinking, or a straw is inserted into the container to suck and drink the jelly. It is intended to provide a suitable formulation and manufacturing method.

上記目的を達成するため、本発明者は、鋭意研究と実験を重ねた結果、カッパーカラギナンの使用量が0.001%(w/v)以上0.035%(w/v)未満で、ゲル化剤の総使用量が0.3%(w/v)未満という極めて少量のゲル化剤を使用し、炭酸ガス含有飲料を容器に充填・密封後70℃〜80℃で加熱処理を施してゲル化剤を溶融させることにより、密閉容器を軽く数回振ってゼリーを破砕した後容器から排出させて飲用するかまたはストローを容器内に差し込んでゼリーを吸引して飲用するタイプの密閉容器入り炭酸ガス含有ソフトゼリー状飲料の製造に好適な配合および製造方法を提供することができることを見出し、本発明に到達した。   In order to achieve the above object, the present inventor has conducted extensive studies and experiments, and as a result, the amount of copper carrageenan used is 0.001% (w / v) or more and less than 0.035% (w / v), Using a very small amount of gelling agent with a total amount of the agent used of less than 0.3% (w / v), filling the container with a carbon dioxide-containing beverage and sealing, heat-treat at 70-80 ° C. By melting the gelling agent, shake the sealed container several times and crush the jelly, then drain it from the container and drink it, or insert a straw into the container and suck the jelly for drinking The present inventors have found that a composition and production method suitable for producing a carbon dioxide-containing soft jelly beverage can be provided, and the present invention has been achieved.

すなわち、上記目的を達成する本発明の第1の構成は、カッパーカラギナンの使用量が、0.001%w/v以上0.035%w/v未満で、ゲル化剤の総使用量が0.3%w/v未満であり、ミネラルとして、カリウム塩及びカルシウム塩を含み、ゲル化剤としてカッパーカラギナン以外に、ペクチン、ローカストビーンガム、キサンタンガム、グアーガム、コンニャクマンナン、タマリンドガム、CMCのうち1種、または、2種類以上を組み合わせてなり、前記の配合となるような原材料液を容器に充填する前または充填後該原材料液に炭酸ガスを含有させ、次いで容器に充填した後、70℃〜80℃で10〜20分間加熱処理を施してゲル化剤を溶融させ、ゲル化剤が溶融した混合液を混合均一化した後冷却することによって得られる密閉容器入り炭酸ガス含有ソフトゼリー飲料である。 That is, in the first configuration of the present invention that achieves the above object, the amount of copper carrageenan used is 0.001% w / v or more and less than 0.035% w / v, and the total amount of gelling agent used is 0. Less than 3% w / v , including potassium salt and calcium salt as minerals, in addition to copper carrageenan as gelling agent, 1 of pectin, locust bean gum, xanthan gum, guar gum, konjac mannan, tamarind gum, CMC Before or after filling the container with the raw material liquid that is a seed or a combination of two or more, and filling the raw material liquid into the container, and then filling the container with the carbon dioxide gas, and then filling the container, It is obtained by heating at 80 ° C. for 10 to 20 minutes to melt the gelling agent, mixing and homogenizing the mixed solution in which the gelling agent has melted, and then cooling. A closed container containing a carbon dioxide-containing soft jelly beverage.

本発明の第2の構成は、請求項1記載の配合となるような原材料液を容器に充填する前または充填後該原材料液に炭酸ガスを含有させ、次いで容器に充填した後、70℃〜80℃で10〜20分間加熱処理を施してゲル化剤を溶融させ、ゲル化剤が溶融した混合液を混合均一化した後冷却することによって得られる密閉容器入り炭酸ガス含有ソフトゼリー飲料の製造方法である。 The second configuration of the present invention is that before or after filling the raw material liquid as described in claim 1 into the container, the raw material liquid contains carbon dioxide gas, and then filled into the container, Production of carbon dioxide-containing soft jelly beverage in a sealed container obtained by heating at 80 ° C. for 10 to 20 minutes to melt the gelling agent, mixing and homogenizing the mixed solution in which the gelling agent has melted, and cooling Is the method .

本発明によれば、カッパーカラギナンの使用量が0.001%(w/v)以上0.035%(w/v)未満で、ゲル化剤の総使用量が0.3%(w/v)未満のゲル化剤を使用し、炭酸ガス含有飲料を容器に充填・密封後70℃〜80℃で加熱処理を施してゲル化剤を溶融させることにより、密閉容器を軽く数回振ってゼリーを破砕した後容器から排出させて飲用するタイプ(以下シェイクタイプという)またはストローを容器内に差し込んでゼリーを吸引して飲用するタイプ(以下ストロータイプという)の密閉容器入り炭酸ガス含有ソフトゼリー状飲料を製造することができる。   According to the present invention, the amount of copper carrageenan used is 0.001% (w / v) or more and less than 0.035% (w / v), and the total amount of gelling agent used is 0.3% (w / v). ) Using less gelling agent, filling the container with carbon dioxide gas-containing beverage and sealing, heat treatment at 70 ° C to 80 ° C to melt the gelling agent, shake the sealed container lightly several times, and jelly A type of soft jelly containing carbon dioxide in a sealed container that is crushed after being crushed and discharged from a container (hereinafter referred to as shake type) or a type in which a straw is inserted into the container to suck and drink jelly (hereinafter referred to as straw type) Beverages can be produced.

また、ゲル化剤は、溶融温度が70℃〜80℃のカッパーカラギナンを主成分とするので、炭酸ガス含有混合液を容器に充填・密封後70℃〜80℃の加熱処理を施すことによってゲル化剤が飲料中に溶融し、これによってレトルト装置を設ける必要がなくなり、加熱装置としてパストライザーを使用する従来既設の炭酸飲料製造ラインを使用することができ、製造方法を簡素化することができるので、製造コストを低減することができる。   Moreover, since the gelling agent is mainly composed of copper carrageenan having a melting temperature of 70 ° C. to 80 ° C., the gelling agent is subjected to a heat treatment of 70 ° C. to 80 ° C. after filling and sealing the carbon dioxide containing liquid mixture. The melting agent is melted in the beverage, so that it is not necessary to provide a retort device, a conventional carbonated beverage production line using a pastoriser as a heating device can be used, and the production method can be simplified. Therefore, the manufacturing cost can be reduced.

また、ゲル化剤はゲル化した後キューブ状に裁断することなく、ゲル化剤の粉末の形で飲料原料液に混合するので、従来技術のようにゲル化したゲル化剤をキューブ状に裁断する工程を別工程として必要とせず、この点でも製造方法を簡素化することができ、製造コストを一層低減することができる。   In addition, the gelling agent is mixed into the beverage raw material liquid in the form of a gelling agent powder without being cut into cubes after gelling, so the gelling agent gelled as in the prior art is cut into cubes In this respect, the manufacturing method can be simplified and the manufacturing cost can be further reduced.

1.ゲル化剤
本発明の一つの特徴は、カッパーカラギナン0.001%w/v以上0.035%w/v未満を主成分とするゲル化剤を使用することである。
カラギナンにはカッパータイプのほかラムダータイプとアイオータタイプがあるが、ラムダータイプでは70℃〜80℃の加熱処理では溶融せず、またアイオータタイプではゲル化した後のゲル状態が弱すぎて適当でなく、本発明の目的上使用するカラギナンとしては、70℃〜80℃の加熱処理で溶融し、ゲル化後のゲル状態も好適なカッパータイプに限定されることが判った。
1. Gelling agent One feature of the present invention is the use of a gelling agent whose main component is copper carrageenan 0.001% w / v or more and less than 0.035% w / v.
Carrageenan has a lambda type and an iota type in addition to a copper type, but the lambda type does not melt by heat treatment at 70 ° C to 80 ° C, and the gel state after gelation is too weak in the iota type. It was found that the carrageenan used for the purpose of the present invention is melted by heat treatment at 70 ° C. to 80 ° C., and the gel state after gelation is limited to a suitable copper type.

カッパーカラギナンの使用量については、臨界性があり、飲料総量の0.001%w/v以上0.035%w/v未満という極めて少量かつ狭い範囲の使用量に限定されることがわかった。カッパーカラギナンの使用量が0.001%w/v未満ではゲル化が充分でなく、また0.035%w/v以上であると、ストロータイプのソフトゼリー状飲料の場合はストローを差し込んで飲用することができるが、シェイクタイプのソフトゼリー状飲料の場合は、容器を5回以上振ってもゼリーが充分に破砕されず容器からの排出に手間取り、容器を押して排出する必要がある場合が生じるので、シェイクタイプとしては好ましくない。より好ましい範囲は0.005〜0.035%w/v、もっとも好ましい範囲は0.01〜0.03%w/vである。   It has been found that the amount of copper carrageenan used is critical and is limited to a very small amount in a narrow range of 0.001% w / v to less than 0.035% w / v of the total beverage. If the amount of copper carrageenan used is less than 0.001% w / v, gelation is not sufficient, and if it is 0.035% w / v or more, in the case of a straw-type soft jelly beverage, a straw is inserted for drinking. However, in the case of shake type soft jelly beverages, even if the container is shaken 5 times or more, the jelly is not sufficiently crushed, it takes time to discharge from the container, and it may be necessary to push and discharge the container. Therefore, it is not preferable as a shake type. A more preferable range is 0.005 to 0.035% w / v, and a most preferable range is 0.01 to 0.03% w / v.

本発明の製造方法においては、カッパーカラギナン以外のゲル化剤として、精製ローカストビーンガム、キサンタンガム、ペクチン、グアーガム、コンニャクマンナン、タマリンドガム、CMCのうち1種、または、2種類以上を組み合わせて使用することができる。   In the production method of the present invention, as a gelling agent other than copper carrageenan, one of purified locust bean gum, xanthan gum, pectin, guar gum, konjac mannan, tamarind gum, or CMC is used, or a combination of two or more types is used. be able to.

ローカストビーンガムも多くの種類があるが、70℃〜80℃で溶融するタイプのものが発明の目的上必要である。このタイプのローカストビーンガムとしては、高精製度タイプとして市販されているものが容易に入手できるので好適である。   There are many types of locust bean gum, but a type that melts at 70 ° C. to 80 ° C. is necessary for the purpose of the invention. As this type of locust bean gum, a commercially available high-purity type is preferable because it can be easily obtained.

またキサンタンガムは飲料の食感を向上させる効果があり、また70〜80℃で溶融するので、添加することが好ましい。   Further, xanthan gum has an effect of improving the texture of the beverage and melts at 70 to 80 ° C., so it is preferably added.

カッパーカラギナン以外のゲル化剤の使用量については、ローカストビーンガムの使用量は、飲料総量の0.04〜0.08%w/vの範囲、キサンタンガムは飲料総量の0.04〜0.08%w/vの範囲で使用することが好ましい。ゲル化剤の使用量が上記下限値未満では目的とするゲル化が不十分となる一方使用量が上記上限値を超えると、ゼリー状態において硬度が高まるため、シェイクタイプでは飲用する際に容器から出難くなるおそれが生じ、また食感が悪くなる。   Regarding the amount of gelling agent other than copper carrageenan, the amount of locust bean gum used is in the range of 0.04 to 0.08% w / v of the total beverage amount, and xanthan gum is 0.04 to 0.08 of the total beverage amount. It is preferable to use in the range of% w / v. If the amount of gelling agent used is less than the above lower limit, the intended gelation will be insufficient, while if the amount used exceeds the above upper limit, the hardness will increase in the jelly state, so in the shake type from the container when drinking There is a risk that it may be difficult to get out, and the texture becomes worse.

本発明のもう一つの特徴は、ゲル化剤の総使用量の上限値には限界性があり、ゲル化剤の総使用量を飲料総量の0.3%w/v未満に押えることにより良好なシェイクタイプ、ストロータイプのソフトゼリー状炭酸ガス含有飲料を製造することができることである。ゲル化剤の総使用量が0.3%w/v以上であると、シェイクタイプの場合数回容器を振ることでゼリーは容器壁から分離はするもののゼリーが小さく崩壊することはない。またストロータイプでもストローで吸引してもゼリーがスムースに出てこない。したがって、ゲル化剤の総使用量が0.3%w/v以上のものはシェイクタイプおよびストロータイプのいずれにも不適である。   Another feature of the present invention is that there is a limit on the upper limit of the total amount of gelling agent used, and it is better to keep the total amount of gelling agent used below 0.3% w / v of the total amount of beverage. A soft jelly-like carbon dioxide-containing beverage can be produced. When the total amount of the gelling agent is 0.3% w / v or more, in the shake type, the jelly is separated from the container wall by shaking the container several times, but the jelly does not collapse. Also, the jelly does not come out smoothly even if it is sucked with a straw type. Accordingly, a gelling agent having a total amount of 0.3% w / v or more is unsuitable for both shake type and straw type.

このようにゲル化剤の組み合わせ、総使用量、キーとなるカッパーカラギナンの配合量に注目して検討を重ねた結果、見出された「配合」そのものも、本発明を実施するための重要な要素となっている。   As a result of repeated investigations focusing on the combination of gelling agents, the total amount used, and the amount of key kappa carrageenan, the found “formulation” itself is also important for carrying out the present invention. It is an element.

2.飲料原料液
本発明の製造方法においては、飲料の容器への充填・密封後の加熱処理が70℃〜80℃で10分〜20分であるので、本発明の炭酸ガス含有ソフトゼリー状飲料に使用する飲料原料液は、この温度範囲の温度で殺菌が完了する種類の飲料でなければならない。
したがって、この条件を満たす飲料原料液としては製品のpHが3.3〜3.8の比較的に低酸性に飲料が好適である。本発明を適用するのに好適な飲料の中で果汁飲料としては、ブルーベリー、レモン、グレープフルーツ、うめ、ピーチ、パイナップル、グレープ、ビルベリー、洋ナシ、マンゴー、アセロラ、カルカム、バナナ、オレンジ、ライチ等がある。また、非果汁飲料としては、コーラ、コーヒー、紅茶、蜂蜜(ハチミツレモン)、乳酸菌飲料、発酵豆乳、緑茶飲料等が挙げられる。
2. Beverage raw material liquid In the production method of the present invention, since the heat treatment after filling and sealing the beverage container is 70 to 80 ° C. for 10 to 20 minutes, the carbon dioxide-containing soft jelly beverage of the present invention is used. The beverage raw material liquid to be used must be a type of beverage that can be sterilized at a temperature in this temperature range.
Therefore, as a beverage raw material liquid satisfying this condition, a beverage having a relatively low acidity with a product pH of 3.3 to 3.8 is suitable. Among the beverages suitable for applying the present invention, juice drinks include blueberries, lemons, grapefruits, plums, peaches, pineapples, grapes, bilberries, pears, mangoes, acerola, calcum, bananas, oranges, litchis, etc. is there. Examples of non-fruit juice beverages include cola, coffee, tea, honey (honey lemon), lactic acid bacteria beverages, fermented soy milk, and green tea beverages.

3.カリウム塩
本発明の製造方法においては、ゲル化剤および該飲料原料液の少なくとも一方にカリウム塩を含有させることが好ましい。
加熱により溶融したカッパーカラギナンをゲル状に硬化させるには1値の陽イオンが必要であり、このため商業的に入手しやすく、味覚や安全の点で問題がなく、使いやすいカリウム塩を使用することが好適である。カリウム塩としては、食品添加物表示許可品が対象となり、具体的には、塩化カリウム、リン酸第一カリウム、リン酸第二カリウム、リン酸第三カリウム、炭酸カリウム、酒石酸水素カリウム、ピロリン酸カリウム、ポリリン酸カリウムが好適であるが、これに限定されるものではない。
3. Potassium salt In the production method of the present invention, it is preferable to contain a potassium salt in at least one of the gelling agent and the beverage raw material liquid.
In order to harden the kappa carrageenan melted by heating into a gel, one value of cation is required. For this reason, a potassium salt that is easy to obtain commercially, has no problem in taste and safety, and is easy to use is used. Is preferred. Potassium salts are subject to food additive labeling approval, specifically potassium chloride, monopotassium phosphate, dipotassium phosphate, tripotassium phosphate, potassium carbonate, potassium hydrogen tartrate, pyrophosphate Although potassium and potassium polyphosphate are suitable, it is not limited to this.

カリウム塩の使用量は、飲料総量の10−12mmol/lの範囲とすることが好ましい。カリウム塩の使用量が上記下限値未満ではカッパーカラギナンのゲル化が充分でない場合が生じ、また使用量が上記上限値を超えるとゼリー状態において硬度が高まるため、シェイクタイプの場合飲用する際に容器から出難くなるおそれが生じ、また塩味が強まったりミネラル臭が強くなったりして食感が悪くなる。   The amount of potassium salt used is preferably in the range of 10-12 mmol / l of the total amount of beverage. When the amount of potassium salt used is less than the above lower limit value, there is a case where the kappa carrageenan is not sufficiently gelled, and when the amount used exceeds the above upper limit value, the hardness increases in a jelly state. This may cause difficulty in getting out of the food, and the salty taste or mineral odor may become strong, resulting in poor texture.

4.カルシウム塩
同様の理由により、加熱によりキサンタンガムをゲル状に硬化させるためにカルシウム塩を使用することが好適である。食品添加物表示許可品として使用可能なカルシウム塩としては、乳酸カルシウム等を挙げることができる。
カルシウム塩の使用量は、飲料総量の3−10mmol/lの範囲とすることが好ましい。カルシウム塩の使用量が上記下限値未満ではキサンタンガムのゲル化が充分でない場合が生じ、また使用量が上記上限値を超えるとゼリー状態において硬度が高まるため、シェイクタイプの場合飲用する際に容器から出難くなるおそれが生じ、またミネラル臭が強くなったりして食感が悪くなる。
4). Calcium salt For the same reason, it is preferable to use a calcium salt to cure xanthan gum in a gel state by heating. Examples of calcium salts that can be used as food additive labeling permission products include calcium lactate.
The amount of calcium salt used is preferably in the range of 3-10 mmol / l of the total beverage. If the amount of calcium salt used is less than the above lower limit value, gelation of xanthan gum may not be sufficient, and if the amount used exceeds the above upper limit value, the hardness will increase in the jelly state. There is a risk that it may become difficult to come out, and the mineral odor will become strong, resulting in a poor texture.

5.その他の原材料
飲料原料液が果汁飲料の場合は、原料となる果汁に、炭酸ガス含有飲料として美味なものを提供するため、甘味料としての糖類および酸味料としての有機酸を加えることが好ましい。糖類としては果糖ブドウ糖液糖が特に好ましく、有機酸としてはクエン酸が特に好ましい。
また、pH調整のためにクエン酸ナトリウムを加えてもよく、その他飲料の味覚、食感等を調整するために香料等を適宜加えることができる。
また飲料原料液が紅茶、コーヒー等非果汁飲料の場合も、飲料の種類に応じて、pH調整剤、乳化剤、ビタミン剤等を適宜加えることができる。
これらゲル化剤以外の飲料原料液添加用原材料の添加量は飲料の種類やpH調整等の必要に応じて異なるものである。
5. Other raw materials When the beverage raw material liquid is a fruit juice beverage, it is preferable to add a sugar as a sweetener and an organic acid as an acidulant to provide a delicious beverage as a carbon dioxide-containing beverage to the fruit juice as a raw material. As the sugar, fructose-glucose liquid sugar is particularly preferable, and as the organic acid, citric acid is particularly preferable.
Moreover, sodium citrate may be added for pH adjustment, and a fragrance | flavor etc. can be suitably added in order to adjust the taste, food texture, etc. of other drinks.
Moreover, also when a drink raw material liquid is non-fruit juice drinks, such as tea and coffee, a pH adjuster, an emulsifier, a vitamin agent, etc. can be added suitably according to the kind of drink.
The addition amount of the raw material for adding beverage raw material liquid other than these gelling agents varies depending on the type of beverage and pH adjustment.

6.炭酸ガス含有混合液の調製
果汁等の飲料原料に必要に応じ糖類、酸味料等の添加物を添加した飲料原料液を調製する。一方純水をデアレーターで処理して純水中に含まれる余分なガス成分を排出した後、飲料原料液と純水を任意の配合比率で混合する。ゲル化剤は飲料原料液と純水の混合前に飲料原料液に粉末状で添加してもよく、混合後に混合液中に粉末状で添加してもよい。添加されたゲル化剤は水膨潤した状態で混合液中に散在している。既設の炭酸飲料製造ラインを使用する場合はライン上に設けられたカーボネーターによりこの混合液に炭酸を含有せしめ、炭酸ガス含有混合液を調製する。また、炭酸飲料製造ラインを使用する以外の方法としては、上記の方法で調製した純水にカーボネーター等で炭酸ガスを含有せしめて炭酸水とし、この炭酸水と飲料原料液を任意の配合比率で混合することにより炭酸ガス含有混合液としてもよい。カーボネーター等で液に炭酸ガスを含有せしめる場合は、炭酸の溶解時にホーミングの発生や、低混合率化することを避けるため、液を4℃以下に冷却しておくことが好ましい。また、炭酸ガスは原材料液を容器に充填後原材料液に含有させても良い。
6). Preparation of Carbon Dioxide-Containing Mixed Liquid A beverage raw material liquid is prepared by adding additives such as sugars and acidulants to beverage raw materials such as fruit juice as necessary. On the other hand, after treating pure water with a dearator to discharge excess gas components contained in pure water, the beverage raw material liquid and pure water are mixed at an arbitrary blending ratio. The gelling agent may be added in powder form to the beverage raw material liquid before mixing the beverage raw material liquid and pure water, or may be added in powder form to the mixed liquid after mixing. The added gelling agent is scattered in the mixed solution in a swollen state with water. When using an existing carbonated beverage production line, carbon dioxide is contained in this mixed solution by a carbonator provided on the line to prepare a carbon dioxide-containing mixed solution. Moreover, as a method other than using the carbonated beverage production line, carbonated gas is contained in the pure water prepared by the above method with a carbonator or the like to obtain carbonated water, and this carbonated water and beverage raw material liquid are mixed at any ratio. It is good also as a carbon dioxide gas containing liquid mixture by mixing by. When carbon dioxide is added to the liquid with a carbonator or the like, the liquid is preferably cooled to 4 ° C. or lower in order to avoid generation of homing or lowering of the mixing ratio when carbonic acid is dissolved. Carbon dioxide gas may be contained in the raw material liquid after the raw material liquid is filled in the container.

7.加熱処理および混合均一化処理
次に、こうして調製した炭酸ガス含有混合液を缶、カップ、食缶等の容器に充填し密封した後パストライザーによって70℃〜80℃で10分〜20分間加熱処理を施すことによってゲル化剤を混合液中に溶融させるとともに必要な殺菌を行う。
次いで、液ムラが出ることを防止するため、容器をライン上で1〜5回スクリュー状に回転させる等の方法で容器内の溶融したゲル化剤と飲料原料液を混合して均一化する。次いで容器を水冷却等の方法で冷却し、品温を20℃以下にしてソフトゼリー状飲料製品とする。
7). Heat treatment and mixing and homogenizing treatment Next, the carbon dioxide-containing mixed solution prepared in this way is filled in a container such as a can, cup, or food can and sealed, and then heat-treated at 70 to 80 ° C. for 10 to 20 minutes by a path riser. To melt the gelling agent in the mixed solution and perform necessary sterilization.
Next, in order to prevent liquid unevenness from appearing, the melted gelling agent in the container and the beverage raw material liquid are mixed and homogenized by a method such as rotating the container 1 to 5 times on the line in a screw shape. Next, the container is cooled by a method such as water cooling, and the product temperature is set to 20 ° C. or lower to obtain a soft jelly beverage product.

8.炭酸飲料製造ラインによるソフトゼリー状飲料製造方法の実施形態
以下添付図面を参照して、本発明の好ましい1実施形態として、既設の炭酸飲料製造ラインを利用して果汁飲料を飲料原料液とするソフトゼリー状飲料を製造する方法について説明する。
図1のフロー図において、原料となる果汁と糖類、酸味料等の添加物からなる原材料に粉末状のゲル化剤を加えて混合し混合シロップを調合する。この時の温度は20℃である。この混合シロップをたとえば60#のろ過機でろ過する。一方純水をデアレーターにて余分なガス成分を除去し、計量装置付きのシンクロミキサーにより混合シロップと純水を所定の混合比率で混合する。
この混合液を4℃に冷却した後カーボネーターに送り炭酸ガスを混合液中に含有せしめる(製品ガスボリューム2.0相当)。
次いで、炭酸ガス含有混合液を缶に充填・巻締めた後炭酸ガスをゲル化剤に分散させるため、ライン上で缶をスクリュー状に1〜3回回転させる。
次いで混合液をパストライザーに送り75℃で10分間加熱することによりゲル化剤を溶融させるとともに混合液を殺菌する。
次いで、缶内での液ムラが生じないよう、ライン上で缶をスクリュー状に1〜5回回転させた後20℃以下に冷却して製品とする。
8). Embodiment of Soft Jelly-like Beverage Production Method Using Carbonated Beverage Production Line With reference to the accompanying drawings, as a preferred embodiment of the present invention, soft drink juice is used as a beverage raw material liquid using an existing carbonated beverage production line. A method for producing a jelly-like beverage will be described.
In the flow chart of FIG. 1, a powdered gelling agent is added to a raw material consisting of raw materials such as fruit juice, saccharides, and acidulant and mixed to prepare a mixed syrup. The temperature at this time is 20 ° C. The mixed syrup is filtered, for example, with a 60 # filter. On the other hand, excess gas components are removed from the pure water with a dearator, and the mixed syrup and pure water are mixed at a predetermined mixing ratio by a synchro mixer with a metering device.
After cooling this mixed solution to 4 ° C., it is sent to a carbonator to contain carbon dioxide gas in the mixed solution (equivalent to product gas volume 2.0).
Next, after filling and tightening the carbon dioxide-containing mixed solution in the can, the can is rotated in a screw shape 1 to 3 times on the line in order to disperse the carbon dioxide in the gelling agent.
Next, the mixed solution is sent to a pasterizer and heated at 75 ° C. for 10 minutes to melt the gelling agent and sterilize the mixed solution.
Next, in order to prevent liquid unevenness in the can, the can is rotated in a screw shape 1 to 5 times on the line and then cooled to 20 ° C. or lower to obtain a product.

以下本発明の実施例と比較例について説明する。
1.処方内容
本発明の方法において使用するゲル化剤の主成分であるカッパーカラギナンの使用量の適正範囲およびゲル化剤の総使用量の適正範囲を調べるために種々の実験を行った結果判明した好適な実施例と比較例の処方内容を下表1に示す。
Examples of the present invention and comparative examples will be described below.
1. Prescription contents The results of various experiments conducted in order to investigate the appropriate range of the amount of kappa carrageenan used as the main component of the gelling agent used in the method of the present invention and the appropriate range of the total amount of gelling agent were determined. Table 1 below shows the formulation contents of various examples and comparative examples.

Figure 0005156977
Figure 0005156977

2.処置
(1)ゲル化剤すべてを純水に分散した。
(2)その他の原料をそれぞれ分散溶解した。
(3)分散したゲル化剤と原料を合わせて混合した。
(4)(3)の混合液に炭酸ガスを含有させ、アルミ缶に充填した。
(5)缶を巻き締め、密封した。
(6)缶を70〜80℃で10分〜20分間加熱した。
(7)混合液を均一化するために回転した 。
(8)終了後缶を水冷した。
(9)水冷終了後室温にて28時間放置し、試飲2時間前より20℃近辺まで冷却して開缶し、パネルテストを行った。
2. Treatment (1) All gelling agents were dispersed in pure water.
(2) Other raw materials were dispersed and dissolved.
(3) The dispersed gelling agent and the raw material were mixed and mixed.
(4) Carbon dioxide gas was contained in the mixed solution of (3) and filled into an aluminum can.
(5) The can was tightened and sealed.
(6) The can was heated at 70-80 ° C. for 10-20 minutes.
(7) Rotated to homogenize the mixture.
(8) After completion, the can was cooled with water.
(9) After completion of water cooling, the sample was allowed to stand at room temperature for 28 hours, cooled to around 20 ° C. and opened from 2 hours before tasting, and a panel test was conducted.

3.結果
上記試験の結果は次のとおりである。
実施例1(カッパーカラギナン0.03%(w/v))
pH 3.55 Brix 15.9
缶を5回ほど縦方向に振るだけでゼリー状内容液はストレスなしに排出された。またゼリー飲料としての食感もしっかりあり、炭酸感も充分にあった。
実施例2(カッパーカラギナン0.03%(w/v))
pH 3.55 Brix 16.7
缶を5回ほど縦方向に振るだけでゼリー状内容液はストレスなしに排出された。またゼリー飲料としての食感もしっかりあり、炭酸感も充分にあった。
比較例1(カッパーカラギナン0.05%(w/v))
pH 3.52 Brix 16.7
缶を5回以上振ってなお缶からの排出に手間どった。数回缶を軽く押すことにより排出できた。食感はゼリー飲料としてさほど問題はない。ストローによる飲用が望ましい。
比較例2(カッパーカラギナン0.1%(w/v))
pH 3.52 Briz 16.8
5回以上振っても排出は困難であった。10回振ってさらに外圧をかけて排出させた。食感はさくい感じが出て、やや劣る・ストローでの飲用でしか商品価値はないと思われる。
比較例3(ゲル化剤総量0.3%(w/v))
pH3.52 Brix 17.0
缶を振ることで内容物は缶壁から分離はするが、内容物が小さく崩壊することはなかった。食感もソフトゼリー状飲料というよりもスプーンで食したい食感であった。ストローで吸引することも困難と思われる。
3. Results The results of the above test are as follows.
Example 1 (copper carrageenan 0.03% (w / v))
pH 3.55 Brix 15.9
The jelly-like liquid was discharged without stress by simply shaking the can about 5 times in the vertical direction. Moreover, the texture as a jelly drink was firm, and there was also a sufficient carbonated feeling.
Example 2 (Copper carrageenan 0.03% (w / v))
pH 3.55 Brix 16.7
The jelly-like liquid was discharged without stress by simply shaking the can about 5 times in the vertical direction. Moreover, the texture as a jelly drink was firm, and there was also a sufficient carbonated feeling.
Comparative Example 1 (Copper carrageenan 0.05% (w / v))
pH 3.52 Brix 16.7
The can was shaken 5 times or more, and it took time to discharge the can. The can was discharged by lightly pushing the can several times. The texture is not a problem as a jelly drink. Drinking with a straw is desirable.
Comparative Example 2 (copper carrageenan 0.1% (w / v))
pH 3.52 Briz 16.8
Even if it was shaken 5 times or more, it was difficult to discharge. It was shaken 10 times and discharged by applying external pressure. The texture is a little bit inferior, and it is a little inferior.
Comparative Example 3 (Total amount of gelling agent 0.3% (w / v))
pH 3.52 Brix 17.0
The contents were separated from the can wall by shaking the can, but the contents were small and did not collapse. The texture was also a texture that I wanted to eat with a spoon rather than a soft jelly beverage. It may be difficult to suck with a straw.

4.パネルテスト
上記実施例1〜2および比較例1〜3の炭酸ガス含有ソフトゼリー飲料について6〜11人のパネルにより4回にわたって試飲を実施し、缶からの出具合、食感を含め、総合評価を、良好、良、普通、好まない、不良の5段階で評価した。その結果は次のとおりである。
4). Panel test The carbon dioxide-containing soft jelly beverages of Examples 1-2 and Comparative Examples 1-3 above were tasted four times by a panel of 6 to 11 people, and the overall evaluation including the condition of the can and the texture. Was evaluated in five grades: good, good, normal, unfavorable, and poor. The results are as follows.

試飲人員
男性 女性 計
第1回 2 4 6
第2回 5 6 11
第3回 4 0 4
第4回 2 6 8
平均 3.25 4 7.25
(数値単位は人)
Tasting personnel
Male Female Total 1st 2 4 6
2nd 5 6 11
3rd 4 0 4
4th 2 6 8
Average 3.25 4 7.25
(The numerical unit is people)

評価 良好 良 普通 好まない 不良
第1回 実施例1 5 1 0 0 0
実施例2 5 1 0 0 0
比較例1 1 1 3 1 0
比較例2 0 1 1 3 1
比較例3 0 0 0 3 3
第2回 実施例1 8 2 1 0 0
実施例2 7 3 1 0 0
比較例1 2 3 4 1 1
比較例2 0 0 3 7 1
比較例3 0 0 1 4 6
第3回 実施例1 3 1 0 0 0
実施例2 2 2 0 0 0
比較例1 1 1 2 1 0
比較例2 0 0 1 3 0
比較例3 0 0 0 1 3
第4回 実施例1 6 2 0 0 0
実施例2 6 2 0 0 0
比較例1 2 3 1 2 0
比較例2 0 1 4 2 1
比較例3 0 0 1 3 4
(数値単位は人)
Evaluation Good Good Normal Unfavorable Defect 1st Example 1 5 1 0 0 0
Example 2 5 1 0 0 0
Comparative Example 1 1 1 3 1 0
Comparative Example 2 0 1 1 3 1
Comparative Example 3 0 0 0 3 3
2nd Example 1 8 2 1 0 0
Example 2 7 3 1 0 0
Comparative Example 1 2 3 4 1 1
Comparative Example 2 0 0 3 7 1
Comparative Example 3 0 0 1 4 6
3rd Example 1 3 1 0 0 0
Example 2 2 2 0 0 0
Comparative Example 1 1 1 2 1 0
Comparative Example 2 0 0 1 3 0
Comparative Example 3 0 0 0 1 3
4th Example 1 6 2 0 0 0
Example 2 6 2 0 0 0
Comparative Example 1 2 3 1 2 0
Comparative Example 2 0 1 4 2 1
Comparative Example 3 0 0 1 3 4
(The numerical unit is people)

平均(人)実施例1 5.5 1.5 0.25 0 0
実施例2 5.0 2.0 0.25 0 0
比較例1 1.25 2.0 2.5 1.25 0.25
比較例2 0 0.5 2.25 3.75 0.75
比較例3 0 0 0.5 2.75 4.0
Average (person) Example 1 5.5 1.5 0.25 0 0
Example 2 5.0 2.0 0.25 0 0
Comparative Example 1 1.25 2.0 2.5 1.25 0.25
Comparative Example 2 0 0.5 2.25 3.75 0.75
Comparative Example 3 0 0 0.5 2.75 4.0

平均(%)実施例1 76% 21% 3% 0% 0%
実施例2 69% 28% 3% 0% 0%
比較例1 17% 28% 34% 17% 3%
比較例2 0% 7% 31% 52% 10%
比較例3 0% 0% 7% 38% 55%
Average (%) Example 1 76% 21% 3% 0% 0%
Example 2 69% 28% 3% 0% 0%
Comparative Example 1 17% 28% 34% 17% 3%
Comparative Example 2 0% 7% 31% 52% 10%
Comparative Example 3 0% 0% 7% 38% 55%

良好=5、良=4、普通=3、好まない=2、不良=1としてそれぞれ人数に割り当て、数値が大きいほど好評かであるとした場合

良好 良 普通 好まない 不良 合計
実施例1 28 6 1 0 0 34
実施例2 25 8 1 0 0 34
比較例1 6 8 8 3 0 25
比較例2 0 2 7 8 1 17
比較例3 0 0 2 6 4 11
When good = 5, good = 4, normal = 3, unfavorable = 2, bad = 1, assigned to the number of people, the larger the value, the better

Good Good Normal Unfavorable Bad Total Example 1 28 6 1 0 0 34
Example 2 25 8 1 0 0 34
Comparative Example 1 6 8 8 3 0 25
Comparative Example 2 0 2 7 8 1 17
Comparative Example 3 0 0 2 6 4 11

上記の結果から、本発明実施例についての評価が非常に高いことがわかる。すなわち、カッパーカラギナンについての使用量は0.035%(w/v)未満にあって良好であると考えられる。特にシェイクタイプのものにあっては、0.035%(w/v)が限界とあると考えられる。ストロータイプのものについても0.035%(w/v)未満である方が飲用しやすいと考えられる。
ゲル化剤の総量については、0.3%未満でければシェイクタイプ、ストロータイプいずれの場合にも不適であると考えられる。
From the above results, it can be seen that the evaluation of the embodiment of the present invention is very high. That is, the amount used for copper carrageenan is considered to be good, being less than 0.035% (w / v). In particular, in the shake type, the limit is considered to be 0.035% (w / v). It is considered that the straw type is easier to drink if it is less than 0.035% (w / v).
If the total amount of the gelling agent is less than 0.3%, it is considered unsuitable for both the shake type and the straw type.

本発明の1実施態様を示すフロー図である。It is a flowchart which shows one embodiment of this invention.

Claims (2)

カッパーカラギナンの使用量が、0.001%w/v以上0.035%w/v未満で、ゲル化剤の総使用量が0.3%w/v未満であり、ミネラルとして、カリウム塩及びカルシウム塩を含み、ゲル化剤としてカッパーカラギナン以外に、ペクチン、ローカストビーンガム、キサンタンガム、グアーガム、コンニャクマンナン、タマリンドガム、CMCのうち1種、または、2種類以上を組み合わせてなり、前記の配合となるような原材料液を容器に充填する前または充填後該原材料液に炭酸ガスを含有させ、次いで容器に充填した後、70℃〜80℃で10〜20分間加熱処理を施してゲル化剤を溶融させ、ゲル化剤が溶融した混合液を混合均一化した後冷却することによって得られる密閉容器入り炭酸ガス含有ソフトゼリー飲料。The amount of copper carrageenan used is 0.001% w / v or more and less than 0.035% w / v, the total amount of gelling agent used is less than 0.3% w / v, and minerals include potassium salt and A calcium salt is included, and in addition to copper carrageenan as a gelling agent, pectin, locust bean gum, xanthan gum, guar gum, konjac mannan, tamarind gum, CMC, or a combination of two or more thereof, Before or after filling the container with such raw material liquid, the raw material liquid is made to contain carbon dioxide gas, and then filled into the container, and then subjected to heat treatment at 70 to 80 ° C. for 10 to 20 minutes to obtain a gelling agent. A carbon dioxide-containing soft jelly beverage in an airtight container obtained by melting, mixing and homogenizing a mixed solution in which a gelling agent is melted, and then cooling. 請求項1記載の配合となるような原材料液を容器に充填する前または充填後該原材料液に炭酸ガスを含有させ、次いで容器に充填した後、70℃〜80℃で10〜20分間加熱処理を施してゲル化剤を溶融させ、ゲル化剤が溶融した混合液を混合均一化した後冷却することによって得られる密閉容器入り炭酸ガス含有ソフトゼリー飲料の製造方法。Before or after filling the container with the raw material liquid as described in claim 1, the raw material liquid is made to contain carbon dioxide gas, and then filled into the container, followed by heat treatment at 70 to 80 ° C for 10 to 20 minutes. The method for producing a soft jelly drink containing carbon dioxide in an airtight container is obtained by melting the gelling agent, mixing and homogenizing the mixed solution in which the gelling agent is melted, and then cooling.
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KR101194399B1 (en) * 2009-12-22 2012-10-25 롯데칠성음료주식회사 Jelly-containing carbonated beverage, a production process thereof and a suitable container thereof
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WO2012009273A1 (en) * 2010-07-13 2012-01-19 Pepsico, Inc. Carbonated jelly beverage with inclusions
JP6042609B2 (en) * 2011-12-27 2016-12-14 三栄源エフ・エフ・アイ株式会社 Gelling agent for food and drink
JP5468168B1 (en) * 2013-09-03 2014-04-09 アサヒ飲料株式会社 soda drink
CN103815214A (en) * 2014-01-16 2014-05-28 李长桃 Method for forming bubbles in jelly and pudding
KR101596230B1 (en) 2014-05-22 2016-02-25 (주)건영제과 Jelly Beverage Producing Method
JP6236698B2 (en) * 2014-05-29 2017-11-29 三菱重工機械システム株式会社 Liquid processing equipment
JP6242922B2 (en) * 2016-01-12 2017-12-06 三栄源エフ・エフ・アイ株式会社 Gelling agent for food and drink
EP3560347B1 (en) * 2016-12-20 2024-02-28 Daiwa Can Company Method for manufacturing thickened carbonated beverage packed in a container
CN109480134A (en) * 2018-11-30 2019-03-19 杭州娃哈哈科技有限公司 A kind of carbonated juice fruit syrup and preparation method thereof suitable for PET bottle dress production
TWI730770B (en) * 2020-05-19 2021-06-11 統一企業股份有限公司 Manufacturing method for a jelly beverage

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2658008B2 (en) * 1991-01-24 1997-09-30 明治製菓株式会社 Method for producing carbon dioxide-containing jelly beverage
JPH053773A (en) * 1991-06-27 1993-01-14 Morinaga & Co Ltd Production of granular food-containing beverage
JPH0767593A (en) * 1993-08-31 1995-03-14 Sanei Gen F F I Inc Beverage containing fine pieces of heat-resistant jelly
JP2898932B2 (en) * 1996-11-05 1999-06-02 大東乳業株式会社 Gelated carbonated drink in sealed container
JP2004105031A (en) * 2002-09-13 2004-04-08 Lotte Co Ltd Jellylike food and drink
JP2004248521A (en) * 2003-02-18 2004-09-09 Kanebo Ltd Carbon dioxide-containing jelly food
JP4323974B2 (en) * 2004-02-06 2009-09-02 キヤノン株式会社 Imaging apparatus, control method thereof, and program
GB2425451A (en) * 2005-04-27 2006-11-01 I Lan Foods Ind Co Ltd Production of a jelly-containing carbonated beverage
JP2006304655A (en) * 2005-04-27 2006-11-09 I Ran Foods Industrial Co Ltd Method for producing jelly-containing carbonated beverage
JP4234723B2 (en) * 2006-03-09 2009-03-04 大東乳業株式会社 Method for producing carbon dioxide containing soft jelly beverage in sealed container

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