JP2020518115A - レドックスフロー電池システム用の電解液をリバランスする方法及びシステム - Google Patents
レドックスフロー電池システム用の電解液をリバランスする方法及びシステム Download PDFInfo
- Publication number
- JP2020518115A JP2020518115A JP2019558678A JP2019558678A JP2020518115A JP 2020518115 A JP2020518115 A JP 2020518115A JP 2019558678 A JP2019558678 A JP 2019558678A JP 2019558678 A JP2019558678 A JP 2019558678A JP 2020518115 A JP2020518115 A JP 2020518115A
- Authority
- JP
- Japan
- Prior art keywords
- electrolyte
- rebalance
- porous layer
- reactor
- pressure drop
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003792 electrolyte Substances 0.000 title claims abstract description 221
- 238000000034 method Methods 0.000 title claims description 34
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 134
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 79
- 239000012530 fluid Substances 0.000 claims abstract description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 83
- 239000001257 hydrogen Substances 0.000 claims description 35
- 229910052739 hydrogen Inorganic materials 0.000 claims description 35
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 229910052742 iron Inorganic materials 0.000 claims description 22
- 230000004044 response Effects 0.000 claims description 13
- 238000011017 operating method Methods 0.000 claims 1
- 238000010586 diagram Methods 0.000 abstract description 6
- 239000010410 layer Substances 0.000 description 88
- 239000000446 fuel Substances 0.000 description 61
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 54
- 238000003860 storage Methods 0.000 description 37
- 239000003054 catalyst Substances 0.000 description 29
- 229910002804 graphite Inorganic materials 0.000 description 28
- 239000010439 graphite Substances 0.000 description 28
- 229910052799 carbon Inorganic materials 0.000 description 25
- 239000007789 gas Substances 0.000 description 21
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 20
- 229910001447 ferric ion Inorganic materials 0.000 description 20
- 239000007788 liquid Substances 0.000 description 18
- 239000011244 liquid electrolyte Substances 0.000 description 18
- 230000002829 reductive effect Effects 0.000 description 16
- 238000007747 plating Methods 0.000 description 14
- 238000006722 reduction reaction Methods 0.000 description 13
- 239000000126 substance Substances 0.000 description 13
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 12
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 11
- 230000009467 reduction Effects 0.000 description 11
- 238000003487 electrochemical reaction Methods 0.000 description 10
- 229910001448 ferrous ion Inorganic materials 0.000 description 10
- 230000008859 change Effects 0.000 description 9
- 238000005260 corrosion Methods 0.000 description 9
- 230000007797 corrosion Effects 0.000 description 9
- 239000011263 electroactive material Substances 0.000 description 9
- 229910052697 platinum Inorganic materials 0.000 description 9
- 229910045601 alloy Inorganic materials 0.000 description 8
- 239000000956 alloy Substances 0.000 description 8
- 229910052703 rhodium Inorganic materials 0.000 description 8
- 239000010948 rhodium Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 239000002131 composite material Substances 0.000 description 7
- 229910052763 palladium Inorganic materials 0.000 description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 7
- 229910052707 ruthenium Inorganic materials 0.000 description 7
- 229910052741 iridium Inorganic materials 0.000 description 6
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 6
- -1 iron ions Chemical class 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 229910052715 tantalum Inorganic materials 0.000 description 6
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 6
- 238000007599 discharging Methods 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 229910000510 noble metal Inorganic materials 0.000 description 5
- 238000006479 redox reaction Methods 0.000 description 5
- 238000007086 side reaction Methods 0.000 description 5
- 239000003014 ion exchange membrane Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 238000013461 design Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000036961 partial effect Effects 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000012864 cross contamination Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 229960004887 ferric hydroxide Drugs 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000016507 interphase Effects 0.000 description 2
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 description 2
- 230000008384 membrane barrier Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000012982 microporous membrane Substances 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 206010014418 Electrolyte imbalance Diseases 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000005574 cross-species transmission Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 229910021506 iron(II) hydroxide Inorganic materials 0.000 description 1
- WKPSFPXMYGFAQW-UHFFFAOYSA-N iron;hydrate Chemical compound O.[Fe] WKPSFPXMYGFAQW-UHFFFAOYSA-N 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
- H01M8/0687—Reactant purification by the use of membranes or filters
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04276—Arrangements for managing the electrolyte stream, e.g. heat exchange
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04186—Arrangements for control of reactant parameters, e.g. pressure or concentration of liquid-charged or electrolyte-charged reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2455—Grouping of fuel cells, e.g. stacking of fuel cells with liquid, solid or electrolyte-charged reactants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
Abstract
Description
本出願は、「レドックスフロー電池システム用の電解液をリバランスする方法及びシステム」と題され、2017年4月28日に出願された米国仮出願第62/491,966号に対する優先権を主張する。ここで、上記の出願の全ての内容は、あらゆる目的のために参照によって組み込まれる。
本発明は、DOE、ARPA−Eオフィスによって与えられた嘱託番号DEAR0000261の下で政府の支援を受けてなされた。政府は、本発明に所定の権利を有する。
Claims (20)
- 水素ガスが流れる第1側と、
レドックスフロー電池システムからの電解液が流れる第2側と、
前記第1側と前記第2側とを分離して流体接続する多孔質層と、を備え、
前記水素ガスと前記電解液とが、前記多孔質層の表面において流体接触しており、
前記第2側を横切る圧力降下が、前記多孔質層を横切る圧力降下よりも小さい、
レドックスフロー電池システム用のリバランス反応器。 - 前記第2側を横切る前記圧力降下が、前記第2側の入口及び出口を横切る圧力降下に対応する、請求項1に記載のリバランス反応器。
- 前記第1側を横切る圧力降下が、前記第2側を横切る前記圧力降下よりも大きい、請求項1に記載のリバランス反応器。
- さらにエジェクターを備え、前記第2側から出る前記電解液が、前記エジェクターを通って流れ、それによって、前記エジェクターを通って前記第1側から出る水素ガスを引く、請求項1に記載のリバランス反応器。
- さらにエジェクターを備え、前記第2側に入る前記電解液が、前記エジェクターを通って流れ、それによって、前記エジェクターを通って前記第1側から出る水素ガスを引く、請求項1に記載のリバランス反応器。
- 前記第1側が、前記水素ガスが流れる対向櫛形流路を含み、それによって、前記水素ガスを前記第1側から出る前に前記多孔質層を通って前記第1側に強制的に入れる、請求項1に記載のリバランス反応器。
- 前記第2側が、前記電解液が流れる対向櫛形流路を含み、それによって、前記電解液を前記第1側から出る前に前記多孔質層を通って前記第2側に強制的に入れる、請求項1に記載のリバランス反応器。
- さらに、前記多孔質層に導電接続された負極及び正極を備え、前記負極及び前記正極を横切って印加される電流が、前記水素ガスと前記電解液との間におけるリバランス反応速度を大きくする、請求項1に記載のリバランス反応器。
- リバランス反応器の第1側を通って水素を流し、
前記リバランス反応器の前記第1側に電解液を流すことなく、レドックスフロー電池から前記リバランス反応器の第2側に前記電解液を流し、
前記第1側と前記第2側との間に挿入された多孔質層の表面において前記水素ガスと前記電解液とを流体接触させる、
レドックスフロー電池システムのためのリバランス反応器操作方法。 - 前記第1側を通って水素を流すことが、前記第2側を通って水素を流すことなく、前記第1側を通って水素を流すことを包含する、請求項9に記載の方法。
- 前記レドックスフロー電池から電解液を流すことが、前記レドックスフロー電池の正極チャンバから電解液を流すことを包含する、請求項9に記載の方法。
- 前記レドックスフロー電池から電解液を流すことが、前記レドックスフロー電池の負極チャンバから電解液を流すことを包含する、請求項9に記載の方法。
- 前記水素ガスと前記電解液とを前記多孔質層の前記表面において流体接触させることが、前記多孔質層の炭素質表面において前記水素ガスによって前記電解液中の金属鉄を還元することを包含する、請求項9に記載の方法。
- さらに、前記第2側を横切る圧力降下を、前記多孔質層を横切る圧力降下よりも小さく維持することを備える、請求項9に記載の方法。
- 前記第2側を横切る圧力降下を、前記多孔質層を横切る圧力降下よりも小さく維持することが、前記第1側を横切る圧力降下を、前記多孔質層の気泡圧力よりも小さく維持することを包含する、請求項14に記載の方法。
- 前記第2側を横切る圧力降下を、前記多孔質層を横切る圧力降下よりも小さく維持することが、前記第2側を横切る圧力降下を、前記多孔質層の気泡圧力よりも小さく維持することを包含する、請求項14に記載の方法。
- 前記第2側を横切る圧力降下を、前記多孔質層を横切る圧力降下よりも小さく維持することが、前記第2側を横切る圧力降下を、閾値圧力差以上で前記多孔質層を横切る前記圧力降下よりも小さく維持することを包含する、請求項14に記載の方法。
- 複数のレドックスフロー電池セルと、
第2のリバランス反応器に流体接続された第1のリバランス反応器と、を包含し、前記第1及び2のリバランス反応器のそれぞれが、
水素ガスが流れる第1側と、
前記複数のレドックスフロー電池セルから電解液が流れる第2側と、
前記第1側と前記第2側とを分離して流体接続する多孔質層と、を包含し、
前記水素ガスと前記電解液とが、前記多孔質層の表面において流体接触し、
前記第2側を横切る圧力降下が、閾値圧力差よりも小さい前記多孔質層を横切る圧力降下より小さい、
レドックスフロー電池システム。 - さらに、実行可能な命令がメモリーに格納されたコントローラを備え、前記閾値圧力差よりも小さい前記多孔質層を横切る前記圧力降下より小さい前記第1のリバランス反応器の前記第2側を横切る圧力降下に応じて、前記第1のリバランス反応器から前記第2のリバランス反応器への前記電解液の流れの一部をリダイレクトする、請求項18に記載のレドックスフロー電池システム。
- 前記実行可能な命令が、前記閾値圧力差よりも小さい前記多孔質層を横切る前記圧力降下より小さい、前記第1のリバランス反応器の第2側を横切る圧力降下に応じて、第1のリバランス反応器の第2側への前記電解液の流れを減少させる、請求項19に記載のレドックスフロー電池システム。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201762491966P | 2017-04-28 | 2017-04-28 | |
US62/491,966 | 2017-04-28 | ||
PCT/US2018/030025 WO2018201094A1 (en) | 2017-04-28 | 2018-04-27 | Methods and systems for rebalancing electrolytes for a redox flow battery system |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2020518115A true JP2020518115A (ja) | 2020-06-18 |
JP7157078B2 JP7157078B2 (ja) | 2022-10-19 |
Family
ID=63917510
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2019558678A Active JP7157078B2 (ja) | 2017-04-28 | 2018-04-27 | レドックスフロー電池システム用の電解液をリバランスする方法及びシステム |
Country Status (6)
Country | Link |
---|---|
US (2) | US11817606B2 (ja) |
EP (1) | EP3593394A4 (ja) |
JP (1) | JP7157078B2 (ja) |
CN (1) | CN110574200B (ja) |
AU (2) | AU2018258694B2 (ja) |
WO (1) | WO2018201094A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4391125A1 (en) * | 2022-12-13 | 2024-06-26 | ESS Tech, Inc. | Rebalancing cell system for redox flow battery |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10930949B2 (en) | 2018-10-05 | 2021-02-23 | Ess Tech, Inc. | Power delivery system and method |
US11025072B2 (en) | 2018-10-17 | 2021-06-01 | Ess Tech, Inc. | System and method for operating an electrical energy storage system |
CN113169361B (zh) * | 2018-11-20 | 2024-02-27 | Ess技术有限公司 | 氧化还原液流电池的电解质健康管理 |
US20220006112A1 (en) * | 2018-12-11 | 2022-01-06 | Ekona Power Inc. | Molten carbonate direct carbon fuel cell systems and methods |
US10826102B1 (en) * | 2019-05-20 | 2020-11-03 | Creek Channel Inc. | Redox flow battery systems including a balance arrangement and methods of manufacture and operation |
CN115210919A (zh) * | 2019-11-08 | 2022-10-18 | Ess技术有限公司 | 用于氧化还原液流电池系统的多级再平衡反应器 |
US11664512B2 (en) | 2020-05-15 | 2023-05-30 | Ess Tech, Inc. | Methods and system for redox flow battery idle state |
US11990659B2 (en) | 2020-11-16 | 2024-05-21 | Cougar Creek Technologies, Llc | Fe-Cr redox flow battery systems and methods for preparation of chromium-containing electrolyte therefor |
KR20230159881A (ko) | 2021-03-24 | 2023-11-22 | 일렉트라스틸, 인크. | 철 전환 시스템에서 불순물 제거 |
AU2022310849A1 (en) * | 2021-07-13 | 2024-02-01 | Ess Tech, Inc. | Rebalancing cell for redox flow battery system |
WO2023034670A1 (en) * | 2021-08-31 | 2023-03-09 | Ess Tech, Inc. | Systems and methods for flowing, storing, and rebalancing electrolyte in redox flow battery system |
WO2023044238A1 (en) * | 2021-09-20 | 2023-03-23 | Ess Tech, Inc. | Hybrid redox fuel cell system |
WO2023044239A1 (en) * | 2021-09-20 | 2023-03-23 | Ess Tech, Inc. | Hybrid redox fuel cell system |
US11923583B2 (en) * | 2021-11-08 | 2024-03-05 | Rtx Corporation | Condensation-based redox flow battery rebalancing |
CN114824369B (zh) * | 2022-05-12 | 2024-03-26 | 北京化工大学 | 一种全铁液流电池的电解液再平衡方法 |
US20240063416A1 (en) * | 2022-08-22 | 2024-02-22 | Ess Tech, Inc. | Rebalancing cell system for redox flow battery |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130084482A1 (en) * | 2011-03-29 | 2013-04-04 | Enervault Corporation | Rebalancing electrolytes in redox flow battery systems |
US20150255824A1 (en) * | 2014-03-06 | 2015-09-10 | Energy Storage Systems, Inc. | Method and system to maintain electrolyte stability for all-iron redox flow batteries |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0741428A1 (en) * | 1995-05-04 | 1996-11-06 | FINMECCANICA S.p.A. AZIENDA ANSALDO | A supply system for fuel cells of the S.P.E. (SOLID POLYMER ELECTROLYTE) type for hybrid vehicles). |
ES2203445T3 (es) | 2000-03-31 | 2004-04-16 | Squirrel Holdings Ltd. | Bateria de flujo redox y metodo de funcionamiento de la misma. |
KR100740114B1 (ko) | 2006-05-12 | 2007-07-16 | 삼성에스디아이 주식회사 | 배터리 관리 시스템 및 그 구동방법 |
US8877365B2 (en) * | 2009-05-28 | 2014-11-04 | Deeya Energy, Inc. | Redox flow cell rebalancing |
CN102341946B (zh) * | 2010-03-12 | 2013-05-01 | 住友电气工业株式会社 | 氧化还原液流电池 |
AT510723B1 (de) * | 2010-12-21 | 2012-06-15 | Cellstrom Gmbh | Rahmen einer zelle einer redox-durchflussbatterie |
US8453097B2 (en) * | 2011-03-22 | 2013-05-28 | Ess Technology, Inc. | System and method for series and parallel combinations of electrical elements |
WO2012166997A2 (en) * | 2011-05-31 | 2012-12-06 | Clean Chemistry, Llc | Electrochemical reactor and process |
WO2013027076A1 (en) | 2011-08-23 | 2013-02-28 | Squirrel Holdings Ltd. | "in situ" production of electrolyte solution from vanadium pentoxide for use in a flow redox battery storage system |
WO2013166924A1 (zh) * | 2012-05-10 | 2013-11-14 | 北京好风光储能技术有限公司 | 无泵锂离子液流电池、电池反应器及电极悬浮液配置方法 |
US8993183B2 (en) * | 2012-12-31 | 2015-03-31 | Enervault Corporation | Operating a redox flow battery with a negative electrolyte imbalance |
US8980454B2 (en) * | 2013-03-15 | 2015-03-17 | Enervault Corporation | Systems and methods for rebalancing redox flow battery electrolytes |
US20160093925A1 (en) | 2013-05-22 | 2016-03-31 | United Techologies Corporation | In-situ electrolyte preparation in flow battery |
US10181615B2 (en) * | 2013-06-07 | 2019-01-15 | Ess Tech, Inc. | Method and system for rebalancing electrolytes in a redox flow battery system |
US9509011B2 (en) * | 2013-06-07 | 2016-11-29 | Ess Tech, Inc. | Method and system for rebalancing electrolytes in a redox flow battery system |
KR20160079049A (ko) * | 2013-11-01 | 2016-07-05 | 록히드 마틴 어드밴스드 에너지 스토리지, 엘엘씨 | 에너지 저장 장치에서 전해질 충전상태의 균형을 위한 구동식 전기화학 셀 |
FR3015122B1 (fr) * | 2013-12-16 | 2016-01-15 | Areva Np | Dispositif de stockage d'energie electrique de grande capacite |
US20160006055A1 (en) | 2014-07-07 | 2016-01-07 | Unienergy Technologies, Llc | Pump tub assembly for redox flow battery |
CN106575785B (zh) * | 2014-11-06 | 2019-06-14 | 住友电气工业株式会社 | 电池电芯和氧化还原液流电池 |
-
2018
- 2018-04-27 EP EP18791771.1A patent/EP3593394A4/en active Pending
- 2018-04-27 CN CN201880028240.9A patent/CN110574200B/zh active Active
- 2018-04-27 JP JP2019558678A patent/JP7157078B2/ja active Active
- 2018-04-27 WO PCT/US2018/030025 patent/WO2018201094A1/en active Application Filing
- 2018-04-27 US US15/965,728 patent/US11817606B2/en active Active
- 2018-04-27 AU AU2018258694A patent/AU2018258694B2/en active Active
-
2023
- 2023-10-03 US US18/480,426 patent/US20240030471A1/en active Pending
- 2023-11-09 AU AU2023263514A patent/AU2023263514A1/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130084482A1 (en) * | 2011-03-29 | 2013-04-04 | Enervault Corporation | Rebalancing electrolytes in redox flow battery systems |
US20150255824A1 (en) * | 2014-03-06 | 2015-09-10 | Energy Storage Systems, Inc. | Method and system to maintain electrolyte stability for all-iron redox flow batteries |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4391125A1 (en) * | 2022-12-13 | 2024-06-26 | ESS Tech, Inc. | Rebalancing cell system for redox flow battery |
Also Published As
Publication number | Publication date |
---|---|
US20180316033A1 (en) | 2018-11-01 |
CN110574200B (zh) | 2023-06-06 |
AU2018258694B2 (en) | 2023-11-30 |
EP3593394A4 (en) | 2021-02-17 |
EP3593394A1 (en) | 2020-01-15 |
US20240030471A1 (en) | 2024-01-25 |
US11817606B2 (en) | 2023-11-14 |
CN110574200A (zh) | 2019-12-13 |
AU2018258694A1 (en) | 2019-09-19 |
WO2018201094A1 (en) | 2018-11-01 |
JP7157078B2 (ja) | 2022-10-19 |
AU2023263514A1 (en) | 2023-11-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP7157078B2 (ja) | レドックスフロー電池システム用の電解液をリバランスする方法及びシステム | |
JP7121045B2 (ja) | 電解液の健全性とシステム性能を維持するためのフロー電池洗浄サイクル | |
AU2019203950B2 (en) | Method and system to maintain electrolyte stability for all-iron redox flow batteries | |
US11527771B2 (en) | Method and system for rebalancing electrolytes in a redox flow battery system | |
AU2018258692B2 (en) | Methods and systems for operating a redox flow battery system | |
CN113169361B (zh) | 氧化还原液流电池的电解质健康管理 | |
JP2020518951A (ja) | 加圧マルチチャンバタンクを使用した統合水素リサイクルシステム | |
CN115210919A (zh) | 用于氧化还原液流电池系统的多级再平衡反应器 | |
CN112840492A (zh) | 具有成本效益的高能量密度氧化还原液流电池 | |
CN117712436A (zh) | 用于氧化还原液流电池系统的再平衡电池单元的电解液流场 | |
US20240063416A1 (en) | Rebalancing cell system for redox flow battery |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20210422 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20211210 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20220201 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20220426 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20220913 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20221006 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 7157078 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |