JP2020158151A - Package - Google Patents

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JP2020158151A
JP2020158151A JP2019058833A JP2019058833A JP2020158151A JP 2020158151 A JP2020158151 A JP 2020158151A JP 2019058833 A JP2019058833 A JP 2019058833A JP 2019058833 A JP2019058833 A JP 2019058833A JP 2020158151 A JP2020158151 A JP 2020158151A
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Japan
Prior art keywords
storage portion
storage
opening start
opening
package
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JP2019058833A
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Japanese (ja)
Inventor
始旦 森谷
Motoaki Moriya
始旦 森谷
博文 森若
Hirobumi Moriwaka
博文 森若
藤田 実智昭
Michiaki Fujita
実智昭 藤田
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Kao Corp
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Kao Corp
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Priority to JP2019058833A priority Critical patent/JP2020158151A/en
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Abstract

To provide a package housing two types of solid contents separately in two housing parts, which is capable of ensuring opening of the two housing parts through one opening operation of tearing and preventing splashing of the contents during opening when one of the contents is a gas generating composition.SOLUTION: A package 1A in which first and second housing parts 3, 4 formed by films are continuous with a partition seal part 2A in between, a solid gas generating composition 20 is housed in the first housing part 3, and a tablet composition 21 is housed in the second housing part 4 comprises: an opening start part 5 of the first housing part 3 in a seal part 2B of the side of the first housing part 3 facing the partition seal part 2A; an opening start part 6 of the second housing part 4 in a region where the opening scheduled direction of the opening part 5 of the first housing part 3 and the partition seal part 2A intersect each other; and a degassing hole 8 in the first housing part 3.SELECTED DRAWING: Figure 1

Description

本発明は、2つに区分された収納部を有するフィルム製の包装体に関する。 The present invention relates to a film package having two compartments.

2種の内容物を別個に収納できるように2つの収納部が仕切りシール部を挟んで連続している2連式の包装体において、2つの収納部を同時に開封できるようにするため、仕切りシール部で包装体を2つ折りにした場合に、2つの収納部を同時に引き裂くことのできるノッチや穴を仕切りシール部に設けることが提案されている(特許文献1)。 In a double-layered packaging body in which two storage parts are continuous with a partition seal part in between so that two types of contents can be stored separately, a partition seal is provided so that the two storage parts can be opened at the same time. It has been proposed to provide a notch or a hole in the partition seal portion so that the two storage portions can be torn at the same time when the package is folded in half at the portion (Patent Document 1).

一方、洗浄剤には、酸素系漂白剤を含有するA剤と、pH調整機能と発泡機能を担う炭酸塩を含有するB剤とを使用時に混合する2剤式の液体洗浄剤がある(特許文献2)。 On the other hand, as a cleaning agent, there is a two-agent liquid cleaning agent in which an agent A containing an oxygen-based bleach and an agent B containing a carbonate having a pH adjusting function and a foaming function are mixed at the time of use (patented). Document 2).

特開2004−250041号公報Japanese Unexamined Patent Publication No. 2004-250041 特開2010−132758号公報JP-A-2010-132758

A剤とB剤からなる2剤式の液体洗浄剤を、取り扱い性の点から2剤式の固形洗浄剤とする場合に、例えば、酸素系漂白剤を含有する粉末状のA剤と、炭酸塩を含有する粉末状のB剤を、従来の2つの収納部を有するフィルム製包装袋に収納すると、保管中のA剤からガスが発生することがある。これに対してはA剤の収納部が著しく膨れたり破裂したりしないようにフィルム材として厚手の強固なものを使用したり、A剤の収納部に通気孔を開けたりすることが考えられる。 When a two-agent liquid cleaning agent consisting of an agent A and an agent B is used as a two-agent solid cleaning agent from the viewpoint of handleability, for example, a powdered agent A containing an oxygen-based bleach and a carbonate. When the powdered agent B containing salt is stored in a conventional film packaging bag having two storage portions, gas may be generated from the agent A during storage. For this purpose, it is conceivable to use a thick and strong film material so that the storage portion of the agent A does not swell or burst remarkably, or to open a ventilation hole in the storage portion of the agent A.

しかしながら、フィルム材として厚手の強固なものを使用し、A剤の収納部に通気孔を開け、収納部の側辺のシール部又は仕切りシール部にノッチ等の開封開始部を設けても、A剤の収納部とB剤の収納部を同時に開封しようとすると、開封片が収納部から引きちぎられるときに収納部から粉末が飛び散るおそれがある。 However, even if a thick and strong film material is used, a ventilation hole is provided in the storage portion of the A agent, and an opening start portion such as a notch is provided in the seal portion or the partition seal portion on the side of the storage portion, A If the agent storage portion and the agent B storage portion are to be opened at the same time, powder may be scattered from the storage portion when the opened piece is torn off from the storage portion.

このような従来技術の課題に対し、2種の固形の内容物を2つの収納部に別個に収納した包装体であって、内容物の一方が酸素系漂白剤のように保管中にガスを発生しやすい性質を有するガス発生性組成物であり、その収納部にガスを排出できる通気孔を設ける場合に、2つの収納部を引き裂きによる1回の開封操作で確実に開封でき、開封時の内容物の飛び散りを防止できるようにすることを課題とする。 In response to such a problem of the prior art, it is a package in which two kinds of solid contents are separately stored in two storage portions, and one of the contents is like an oxygen-based bleach and emits gas during storage. It is a gas-generating composition having a property of being easily generated, and when a vent hole capable of discharging gas is provided in the storage portion, the two storage portions can be reliably opened by a single opening operation by tearing, and at the time of opening. The challenge is to be able to prevent the contents from scattering.

本発明者は、第1収納部と第2収納部が仕切りシール部を挟んで連続した包装体であって、第1収納部にガス発生性組成物が収納され、第1収納部にガス抜き穴を設ける場合に、仕切りシール部と対向する第1収納部の側辺のシール部にノッチなどの第1収納部の開封開始部を形成すると共に、仕切りシール部の第1収納部の開封開始部に対応する位置に第2収納部の開封開始部を形成すると、第1収納部の開封開始部からの引き裂きが第2収納部の開封開始部に及び、後から開封される第2収納部も容易に開封を完了できること、この場合に、少なくとも第2収納部の内容物を粉末状ではなくタブレット状にすると、第2収納部の開封片が第2収納部から引きちぎられるときでも第2収納部の内容物が飛び散ることを防止でき、また、仮に第2収納部の開封片の第2収納部からの引きちぎりが不完全となり、開封片が第2収納部についたままになった場合でも第2収納部に収納されていた内容物の全量を確実に取り出せることを想到し、本発明を完成させた。 The present inventor is a package in which the first storage portion and the second storage portion are continuous with the partition seal portion sandwiched between them, the gas-generating composition is stored in the first storage portion, and the gas is vented in the first storage portion. When a hole is provided, an opening start portion of the first storage portion such as a notch is formed in the seal portion on the side of the first storage portion facing the partition seal portion, and the opening start of the first storage portion of the partition seal portion is started. When the opening start portion of the second storage portion is formed at a position corresponding to the portion, the tear from the opening start portion of the first storage portion extends to the opening start portion of the second storage portion, and the second storage portion to be opened later. In this case, if the contents of the second storage section are at least tablet-shaped instead of powder, the second storage section can be easily opened even when the opened piece of the second storage section is torn off from the second storage section. It is possible to prevent the contents of the part from scattering, and even if the opened piece of the second storage part is incompletely torn off from the second storage part and the opened piece remains attached to the second storage part. The present invention was completed with the idea that the entire amount of the contents stored in the second storage unit can be reliably taken out.

即ち、本発明は、フィルムで形成された第1収納部と第2収納部が仕切りシール部を挟んで連続し、第1収納部に固形のガス発生性組成物が収納され、第2収納部にタブレット状組成物が収納されている包装体であって、仕切りシール部と対向する、第1収納部の側辺のシール部に第1収納部の開封開始部を有すると共に、該第1収納部の開封開始部による開封予定方向と仕切りシール部とが交差する領域に第2収納部の開封開始部を有し、第1収納部にガス抜き穴を有する包装体を提供する。 That is, in the present invention, the first storage portion and the second storage portion formed of the film are continuous with the partition seal portion interposed therebetween, and the solid gas-generating composition is stored in the first storage portion, and the second storage portion is stored. A packaging body in which a tablet-like composition is stored, which has an opening start portion of the first storage portion at a seal portion on the side side of the first storage portion facing the partition seal portion, and the first storage portion. Provided is a package having an opening start portion of a second storage portion in a region where the planned opening direction by the opening start portion of the portion intersects with a partition seal portion, and a gas vent hole in the first storage portion.

また、本発明は、第1収納部と第2収納部が仕切りシール部を挟んで連続し、第1収納部に固形のガス発生性組成物を収納し、第2収納部にタブレット状組成物を収納するための包装袋であって、第1収納部と第2収納部がそれぞれ内容物を収納するための開口部を有し、仕切りシール部と対向する第1収納部の側辺のシール部に第1収納部の開封開始部を有すると共に、該第1収納部の開封開始部による開封予定方向と仕切りシール部とが交差する領域に第2収納部の開封開始部を有し、第1収納部にガス抜き穴を有する包装袋を提供する。 Further, in the present invention, the first storage portion and the second storage portion are continuous with the partition seal portion interposed therebetween, the solid gas-generating composition is stored in the first storage portion, and the tablet-like composition is stored in the second storage portion. A packaging bag for storing gas, in which the first storage portion and the second storage portion each have an opening for storing the contents, and a seal on the side of the first storage portion facing the partition seal portion. The opening portion of the first storage portion is provided in the portion, and the opening start portion of the second storage portion is provided in the area where the planned opening direction by the opening start portion of the first storage portion and the partition seal portion intersect. 1 Provide a packaging bag having a degassing hole in the storage portion.

本発明の包装体によれば、該包装体の保管中に第1収納部に収納されたガス発生性組成物からガスが発生してもそのガスを第1収納部のガス抜き穴から抜くことができる。 According to the package of the present invention, even if gas is generated from the gas-generating composition stored in the first storage portion during storage of the package, the gas is removed from the gas vent hole of the first storage portion. Can be done.

また、第1収納部の開封開始部による第1収納部の開封予定方向の延長上に第2収納部の開封開始部があるので、第1収納部の開封開始部から第1収納部を引き裂くと、その引き裂きが第2収納部の開封開始部に及び、第2収納部が引き裂かれるので、一回の開封操作で第1収納部と第2収納部を開封することができる。 Further, since the opening start portion of the second storage portion is located on the extension of the opening start portion of the first storage portion in the planned opening direction of the first storage portion, the first storage portion is torn from the opening start portion of the first storage portion. Then, the tear extends to the opening start portion of the second storage portion, and the second storage portion is torn, so that the first storage portion and the second storage portion can be opened with a single opening operation.

また、第1収納部の引き裂きが第2収納部の開封開始部に及び、その第2収納部の開封開始部から第2収納部が引き裂かれることで第2収納部の引き裂きがスムーズになり、第1収納部及び第2収納部から内容物が飛び散ることが防止される。 Further, the tearing of the first storage portion extends to the opening start portion of the second storage portion, and the second storage portion is torn from the opening start portion of the second storage portion, so that the tearing of the second storage portion becomes smooth. It is prevented that the contents are scattered from the first storage portion and the second storage portion.

さらに、第2収納部の内容物はタブレット状であるため、これによっても第2収納部から内容物が飛び散ることが防止されると共に、仮に第2収納部の引き裂きが不完全に行われ、第2収納部に開封片が残存しても、第2収納部の内容物の全量を容易かつ確実に取り出すことが可能となる。 Further, since the contents of the second storage portion are in the shape of a tablet, the contents are prevented from being scattered from the second storage portion, and the second storage portion is tentatively torn incompletely. 2 Even if the opened piece remains in the storage portion, the entire contents of the second storage portion can be easily and surely taken out.

特に、この包装体において、第1収納部にガス発生性組成物として粉末の酸素系漂白剤を収納し、第2収納部にタブレット状の炭酸塩含有発泡性組成物を収納した態様は、第2収納部のタブレット状の炭酸塩含有発泡性組成物が第1収納部の酸素系漂白剤の漂白効果を高めるpH調整剤としても、漂白中に発泡が持続する発泡剤としても作用するので、漂白効果が高く、かつ発泡により漂白作用が持続中であることが視覚的にわかる2剤式の洗浄剤の包装体となる。しかも、酸素系漂白剤と炭酸塩含有発泡性組成物を1回の開封操作で開封できるので、酸素系漂白剤と炭酸塩含有発泡性組成物のいずれか一方だけでなく、双方が同時に使用されるように洗浄剤のユーザーを誘導することができる。 In particular, in this package, a mode in which a powdered oxygen-based bleach is stored as a gas-generating composition in the first storage portion and a tablet-shaped carbonate-containing foaming composition is stored in the second storage portion is the first. 2 Since the tablet-like carbonate-containing foaming composition in the storage portion acts as a pH adjuster for enhancing the bleaching effect of the oxygen-based bleach in the first storage portion and as a foaming agent for which foaming is sustained during bleaching. It is a package of a two-agent cleaning agent that has a high bleaching effect and visually shows that the bleaching effect is sustained by foaming. Moreover, since the oxygen-based bleach and the carbonate-containing effervescent composition can be opened with a single opening operation, not only one of the oxygen-based bleach and the carbonate-containing effervescent composition, but both of them are used at the same time. The user of the cleaning agent can be guided so as to.

また、本発明の包装袋によれば、その第1収納部にガス発生性組成物を入れ、第2収納部にタブレット状組成物を入れ、包装袋を封じることにより本発明の包装体を容易に得ることができる。 Further, according to the packaging bag of the present invention, the packaging body of the present invention is easily facilitated by putting the gas-generating composition in the first storage portion, putting the tablet-like composition in the second storage portion, and sealing the packaging bag. Can be obtained.

図1は、実施例の包装体1Aの平面図である。FIG. 1 is a plan view of the package 1A of the embodiment. 図2は、実施例の包装体1Bの平面図である。FIG. 2 is a plan view of the package 1B of the embodiment. 図3は、実施例の包装体1Cの平面図である。FIG. 3 is a plan view of the package 1C of the embodiment. 図4は、実施例の包装体1Dの平面図である。FIG. 4 is a plan view of the package 1D of the embodiment. 図5は、実施例の包装体1Eの平面図である。FIG. 5 is a plan view of the package 1E of the embodiment. 図6は、実施例の包装体1Fの平面図である。FIG. 6 is a plan view of the packaging body 1F of the embodiment. 図7は、実施例の包装袋1dの平面図である。FIG. 7 is a plan view of the packaging bag 1d of the embodiment. 図8は、実施例の包装袋1d’の平面図である。FIG. 8 is a plan view of the packaging bag 1d'of the embodiment.

以下、図面を参照しつつ本発明を詳細に説明する。なお、各図中、同一符号は同一又は同等の構成要素を表している。 Hereinafter, the present invention will be described in detail with reference to the drawings. In each figure, the same reference numerals represent the same or equivalent components.

(全体構成)
図1は本発明の一実施例の包装体1Aの平面図である。
この包装体1Aは、4方シールのフィルム製平袋の略中央部に仕切りシール部2Aを有し、仕切りシール部2Aを挟んで第1収納部3と第2収納部4が横並びに連続しており、第1収納部3には固形のガス発生性組成物20が収納され、第2収納部4にはタブレット状組成物21が1個又は複数個収納されている。
(overall structure)
FIG. 1 is a plan view of a package 1A according to an embodiment of the present invention.
This package 1A has a partition seal portion 2A at a substantially central portion of a film flat bag having a four-way seal, and the first storage portion 3 and the second storage portion 4 are continuously arranged side by side with the partition seal portion 2A interposed therebetween. The solid gas-generating composition 20 is stored in the first storage unit 3, and one or more tablet-shaped compositions 21 are stored in the second storage unit 4.

(第1収納部の開封開始部)
仕切りシール部2Aと対向する、第1収納部3の側辺のシール部2Bには、第1収納部3の開封開始部5としてV字型ノッチが形成されている。なお、本発明において、第1収納部の開封開始部5としては、V字型ノッチに限られず、I字型ノッチ、U字型ノッチを形成してもよく、「マジックカット」(登録商標)等のように微細な穴を多数設けることで容易に開封できる部分を形成してもよい。
(Opening start part of the first storage part)
A V-shaped notch is formed as an opening start portion 5 of the first storage portion 3 in the seal portion 2B on the side side of the first storage portion 3 facing the partition seal portion 2A. In the present invention, the opening start portion 5 of the first storage portion is not limited to the V-shaped notch, and an I-shaped notch and a U-shaped notch may be formed, and "magic cut" (registered trademark) may be formed. A portion that can be easily opened may be formed by providing a large number of fine holes such as the above.

(第2収納部の開封開始部)
第1収納部3の開封開始部5により、第1収納部3は、該開封開始部5から包装体1Aの上辺又は下辺と略平行に引き裂かれることとなるが、この場合の矢印Xで示す開封予定方向と仕切りシール部2Aとが交差する領域には、第2収納部4の開封開始部6が形成されている。本実施例の包装体1Aにおいて、この第2収納部4の開封開始部6としては、開封予定方向Xと略平行に伸びたミシン目状切れ目7が複数並列した領域が形成されている。ミシン目状切れ目7としては、ミシン目のカット部分がフィルムを貫通しており、カット部分の長さL1が0.5〜2.0mm、アンカット部分の長さL2が0.5〜2.0mm、並列しているミシン目状切れ目7同士の間隔L3を0.5〜2.0mm、並列しているミシン目状切れ目7の本数を8〜50本又はミシン目状切れ目7の並列領域の幅L4を3.0〜15mmとすることが、第2収納部を容易に開封する点から好ましい。一方、第2収納部4の開封開始部6としては、図2に示す包装体1Bのように、Y字の上端を第1収納部3の開封開始部5に向けたY字型切り込みや、X字の>形部分を第1収納部3の開封開始部5に向けたX字型切り込みを設けてもよい。第1収納部3の開封開始部5から上下に多少ズレながら第1収納部3が引き裂かれていったときに、第2収納部4を引き裂く手前の仕切りシール部2Aにある第2収納部4の開封開始部6の切り込み部で、第1収納部3における引き裂き方向のズレを開封予定方向Xと略平行な方向に修正でき、かつこの開封開始部6における個々の切り込み長さを短くできることから、第2収納部4の開封開始部6としてはミシン目状切れ目が好ましい。ミシン目状切れ目とすることにより、包装体1Aの製造過程や、製造された包装体の搬送過程で開封開始部6の切り込みが不用にひっかかることを防止することもできる。
(Opening start part of the second storage part)
The opening start portion 5 of the first storage portion 3 causes the first storage portion 3 to be torn from the opening start portion 5 substantially parallel to the upper side or the lower side of the package 1A, which is indicated by an arrow X in this case. An opening start portion 6 of the second storage portion 4 is formed in a region where the planned opening direction and the partition seal portion 2A intersect. In the package 1A of the present embodiment, the opening start portion 6 of the second storage portion 4 is formed with a region in which a plurality of perforated cuts 7 extending substantially parallel to the planned opening direction X are arranged in parallel. As the perforated cut 7, the cut portion of the perforation penetrates the film, the length L1 of the cut portion is 0.5 to 2.0 mm, and the length L2 of the uncut portion is 0.5 to 2. 0 mm, the distance L3 between the perforated cuts 7 in parallel is 0.5 to 2.0 mm, the number of perforated cuts 7 in parallel is 8 to 50, or the parallel region of the perforated cuts 7 It is preferable that the width L4 is 3.0 to 15 mm from the viewpoint of easily opening the second storage portion. On the other hand, as the opening start portion 6 of the second storage portion 4, as shown in the package 1B shown in FIG. 2, a Y-shaped notch with the upper end of the Y-shape directed toward the opening start portion 5 of the first storage portion 3 or An X-shaped notch may be provided so that the X-shaped> -shaped portion faces the opening start portion 5 of the first storage portion 3. When the first storage part 3 is torn from the opening start part 5 of the first storage part 3 while being slightly displaced up and down, the second storage part 4 in the partition seal part 2A before tearing the second storage part 4 Since the deviation in the tearing direction in the first storage portion 3 can be corrected in a direction substantially parallel to the planned opening direction X at the notch portion of the opening start portion 6, and the individual notch lengths in the opening start portion 6 can be shortened. A perforated cut is preferable as the opening start portion 6 of the second storage portion 4. By making the perforated cut, it is possible to prevent the notch of the opening start portion 6 from being unnecessarily caught in the manufacturing process of the package 1A and the transporting process of the manufactured package.

第2収納部4の開封開始部6が、上述した包装体1A、1Bの開封開始部6のいずれであっても、第1収納部3の開封開始部5からこの包装体1A、1Bを引き裂くと、まず、第1収納部3が引き裂かれて開封し、その引裂が仕切りシール部2Aに設けられている第2収納部4の開封開始部6に達し、それにより、引裂力が第2収納部4の引き裂きに有効に作用し、第2収納部4も引き裂かれる。したがって、1回の引裂操作で第1収納部3と第2収納部4の双方が開封され、第1収納部3に収納されているガス発生性組成物20と第2収納部4に収納されているタブレット状組成物21の双方を収納部3、4から取り出すことが可能となる。一般に、フィルム製包装体の内容物が粉体の場合には、その包装体をノッチから引き裂き、引裂片が包装袋から引きちぎられるときには内容物が飛び散らないように注意を払うことが必要とされるが、この包装体1A、1Bでは第1収納部3の開封開始から第2収納部4の開封完了までスムーズに引き裂きが進行するので内容物の飛び散りが起こりにくく、さらに、第2収納部4の内容物がタブレット状であるため、第1収納部3から第2収納部4まで一気に引き裂いても第2収納部4から内容物が飛び散る虞がない。 Regardless of whether the opening start portion 6 of the second storage portion 4 is any of the opening start portions 6 of the packaging bodies 1A and 1B described above, the packaging bodies 1A and 1B are torn from the opening start portion 5 of the first storage portion 3. First, the first storage portion 3 is torn and opened, and the tear reaches the opening start portion 6 of the second storage portion 4 provided in the partition seal portion 2A, whereby the tearing force is second-stored. It acts effectively on the tearing of the part 4, and the second storage part 4 is also torn. Therefore, both the first storage unit 3 and the second storage unit 4 are opened by one tearing operation, and are stored in the gas-generating composition 20 and the second storage unit 4 stored in the first storage unit 3. Both of the tablet-like compositions 21 can be taken out from the storage portions 3 and 4. In general, when the content of a film package is powder, it is necessary to tear the package from the notch and take care not to scatter the content when the torn pieces are torn from the packaging bag. However, in the packages 1A and 1B, the tearing progresses smoothly from the start of opening the first storage unit 3 to the completion of opening the second storage unit 4, so that the contents are less likely to scatter, and further, the second storage unit 4 Since the contents are tablet-shaped, there is no possibility that the contents will be scattered from the second storage portion 4 even if the first storage portion 3 to the second storage portion 4 are torn at once.

(ガス抜き穴)
また、この包装体1Aには、第1収納部3に収納されたガス発生性組成物20から発生するガスのガス抜き穴8として、開封予定方向Xと略平行に伸びたミシン目状切れ目9が複数並列するように設けられている。このミシン目状切れ目9は、第1収納部3内の、第1収納部3の開封開始部5と第2収納部4の開封開始部6に挟まれた領域に設けられている。したがって、ミシン目状切れ目9は、ガス抜き穴として作用するだけでなく、第1収納部3の直線的な開封をより容易にする開封誘導線としても作用する。このようなミシン目状切れ目9としては、ミシン目のカット部分の長さL1が0.5〜2.0mm、アンカット部分の長さL2が0.5〜2.0mm、並列しているミシン目状切れ目9の間隔L3を0.5〜2.0mm、ミシン目状切れ目9の並列領域の幅L4を3.0〜15mmとすることが、ガス抜き穴と開封誘導線の双方の機能をもたせる点から好ましい。
(Gas vent hole)
Further, in the package 1A, a perforated cut 9 extending substantially parallel to the planned opening direction X is provided as a gas vent hole 8 for gas generated from the gas-generating composition 20 stored in the first storage portion 3. Are provided so as to be in parallel. The perforated cut 9 is provided in a region in the first storage portion 3 sandwiched between the opening start portion 5 of the first storage portion 3 and the opening start portion 6 of the second storage portion 4. Therefore, the perforated cut 9 not only acts as a gas vent hole, but also acts as an opening guide line that facilitates linear opening of the first storage portion 3. As such a perforated cut 9, the length L1 of the cut portion of the perforation is 0.5 to 2.0 mm, the length L2 of the uncut portion is 0.5 to 2.0 mm, and the sewing machines are arranged in parallel. Setting the spacing L3 of the perforated cuts 9 to 0.5 to 2.0 mm and the width L4 of the parallel region of the perforated cuts 9 to 3.0 to 15 mm functions as both a degassing hole and an opening guide wire. It is preferable because it can be held.

なお、本発明において、ガス抜き穴としては、第1収納部3に収納された粉末状のガス発生性組成物20が粉漏れすることなくガス抜きができればよい。したがって、ミシン目状切れ目9に代えて、例えば直径0.4〜2.0mmの小孔を格子状に設けてもよく、ランダムに設けてもよい。 In the present invention, as the degassing hole, it is sufficient that the powdery gas-generating composition 20 stored in the first accommodating portion 3 can be degassed without leaking powder. Therefore, instead of the perforated cut 9, for example, small holes having a diameter of 0.4 to 2.0 mm may be provided in a grid pattern or may be provided at random.

(フィルム材料)
本発明の包装体1A、1Bを構成するフィルム材料としては、開封予定方向Xの引裂直進性をもたない一般的なフィルムを使用することができ、このようなフィルムとしては、例えば、ポリエチレンテレフタレート等のポリエステル;ナイロン等のポリアミド;低密度ポリエチレン(LDPE)、リニア低密度ポリエチレン(L-LDPE)、延伸ポリプロピレン(OPP)、無延伸ポリプロピレン(CPP)等のオレフィン系フィルム等が挙げられる。フィルム材料は単層フィルムでも積層フィルムでもよい。一方、開封開始部5から1回の引裂操作で第1収納部3と第2収納部4の双方をより容易に開封できるようにするためには、開封予定方向Xの引裂直進性を有するフィルム材料を使用することが好ましい。このようなフィルム材料としては、延伸などにより引裂直進性を有するものが好ましく、特に、包装体を形成するフィルム材料を外側表層と内側シーラント層を備えた積層フィルムとする場合、外側表層と内側シーラント層がそれぞれ開封予定方向Xの引裂直進性を有することが好ましい。中でも、外側表層を、引裂直進性を有するPET層とし、内側シーラント層を、引裂直進性を有する3層共押出層とし、この3層共押出層を、外側から順に、接着性及び緩衝性を有するポリエチレン層と、引裂直進性を有するポリエチレンとオレフィンからなる中間層と、シール性及び耐衝撃性を有するポリエチレン層との積層構造とすることが好ましい。
(Film material)
As the film material constituting the packages 1A and 1B of the present invention, a general film having no tear straightness in the planned opening direction X can be used, and as such a film, for example, polyethylene terephthalate can be used. Such as polyester; polyamide such as nylon; olefin-based films such as low-density polyethylene (LDPE), linear low-density polyethylene (L-LDPE), stretched polypropylene (OPP), and non-stretched polypropylene (CPP). The film material may be a single-layer film or a laminated film. On the other hand, in order to make it easier to open both the first storage portion 3 and the second storage portion 4 with one tear operation from the opening start portion 5, a film having a tear straightness in the planned opening direction X. It is preferable to use the material. As such a film material, one having tear straightness by stretching or the like is preferable, and in particular, when the film material forming the package is a laminated film having an outer surface layer and an inner sealant layer, the outer surface layer and the inner sealant It is preferable that each layer has a tear straightness in the planned opening direction X. Among them, the outer surface layer is a PET layer having tear straightness, the inner sealant layer is a three-layer coextruding layer having tear straightness, and the three-layer coextrusion layer is subjected to adhesiveness and cushioning in order from the outside. It is preferable to have a laminated structure of a polyethylene layer having a polyethylene layer, an intermediate layer made of polyethylene and olefin having tear straightness, and a polyethylene layer having sealing property and impact resistance.

なお、フィルム材料は、内容物を透視できる点から透明であることが好ましいが、必要に応じて遮光性を有していてもよい。 The film material is preferably transparent from the viewpoint of being able to see through the contents, but may have a light-shielding property if necessary.

(第1収納部の内容物)
一方、第1収納部3の内容物として収納されているガス発生性組成物20としては、第2収納部4に収納されているタブレット状組成物21と併用することにより、例えば、衣類、シーツ、タオル等の繊維製品の漂白、除菌、消臭に有用な固形の酸素系漂白剤等をあげることができる。ガス発生性組成物20は、界面活性剤、漂白活性化剤、酵素等を含有していてもよい。より具体的には、酸素系漂白剤としては、例えば、特開2007−9100号公報に記載されている粉末洗浄剤組成物をあげることができる。また、pH10.5〜10.8で高い殺菌漂白力を発揮する酸素系漂白剤を使用することができる。この酸素系漂白剤は、過炭酸ナトリウム、過ホウ酸ナトリウム等の過酸化水素付加物を含有し、保管中に分解して酸素ガスを発生する。
(Contents of the first storage section)
On the other hand, the gas-generating composition 20 stored as the contents of the first storage unit 3 can be used in combination with the tablet-like composition 21 stored in the second storage unit 4, for example, clothing and sheets. , Solid oxygen-based bleaching agents useful for bleaching, sterilizing, and deodorizing textile products such as towels. The gas-generating composition 20 may contain a surfactant, a bleaching activator, an enzyme and the like. More specifically, examples of the oxygen-based bleaching agent include powder cleaning agent compositions described in JP-A-2007-9100. In addition, an oxygen-based bleaching agent that exhibits high bactericidal bleaching power at pH 10.5 to 10.8 can be used. This oxygen-based bleach contains hydrogen peroxide adducts such as sodium percarbonate and sodium perborate, and decomposes during storage to generate oxygen gas.

第1収納部3に収容されているガス発生性組成物20の形態は、ガス抜き穴8から漏れ出ることのない固形であればよく、粉末状、タブレット状等とすることができる。ガス発生性組成物20の全量を水に溶かし、その溶液に第2収納部4のタブレット状組成物21を徐々に溶解させ、殺菌漂白作用の強い有機過酸の生成効率を高める点からは、ガス発生性組成物20は粉末状とすることが好ましい。 The form of the gas-generating composition 20 housed in the first storage unit 3 may be a solid that does not leak from the gas vent hole 8, and may be in the form of powder, tablet, or the like. From the viewpoint of dissolving the entire amount of the gas-generating composition 20 in water and gradually dissolving the tablet-like composition 21 of the second storage portion 4 in the solution to increase the production efficiency of the organic peracid having a strong bactericidal bleaching action. The gas-generating composition 20 is preferably in the form of powder.

(第2収納部の内容物)
第2収納部4の内容物として収納されているタブレット状組成物21としては、例えば、特開2012―6847号公報に記載されている炭酸ナトリウム等の炭酸塩を含有する組成物、特開2002―180098号公報に記載されている錠剤型洗剤の水溶性無機塩を含有する組成物及びクエン酸、コハク酸等の水に溶けにくい有機酸をタブレット状に成形したものを挙げることができる。これらの組成物は炭酸塩及び有機酸を含有し、その水溶液はpHを酸素系漂白剤の漂白能力を高めるアルカリ性に維持するpH調整剤として機能すると共に、炭酸ガスの泡を発生し、洗浄が持続していることをユーザーに知らせる発泡剤としても機能する。
(Contents of the second storage section)
Examples of the tablet-like composition 21 stored as the contents of the second storage unit 4 include a composition containing a carbonate such as sodium carbonate described in JP-A-2012-6847, JP-A-2002. Examples thereof include a composition containing a water-soluble inorganic salt of a tablet-type detergent described in Japanese Patent Application Laid-Open No. 18098, and a tablet-shaped organic acid such as citric acid and succinic acid which is difficult to dissolve in water. These compositions contain carbonates and organic acids, the aqueous solution of which functions as a pH adjuster to maintain the pH alkaline, which enhances the bleaching ability of oxygen bleach, and produces carbon dioxide bubbles for cleaning. It also acts as a foaming agent to let the user know that it is persistent.

タブレット状組成物21の外形や大きさは、特に制限はないが、第1収納部のガス発生性組成物が酸素系漂白剤の場合、漂白中にタブレット状組成物21からの発泡を持続させて有機過酸の生成率を向上させる点からタブレット状組成物21の外形は同じ体積でも表面積を小さくすることが好ましい。したがって、小径のものを複数個使用するよりも大径のものをより少ない個数で使用することが好ましい。また、第2収納部4に収納するタブレット状組成物21の個数は、袋内でのタブレット同士の衝突による割れの点からできるだけ少ない個数とすることが好ましい。より具体的には、第2収納部4には、直径15〜50mm、厚さ5〜25mmのタブレット状組成物を1〜3個収納することが好ましく、収納個数を1個とすることがより好ましい。 The outer shape and size of the tablet-shaped composition 21 are not particularly limited, but when the gas-generating composition in the first storage portion is an oxygen-based bleach, foaming from the tablet-shaped composition 21 is sustained during bleaching. From the viewpoint of improving the production rate of organic peracid, it is preferable that the outer shape of the tablet-like composition 21 has the same volume but a smaller surface area. Therefore, it is preferable to use a smaller number of large diameter ones than to use a plurality of small diameter ones. Further, the number of tablet-shaped compositions 21 stored in the second storage unit 4 is preferably as small as possible from the viewpoint of cracking due to collision between tablets in the bag. More specifically, it is preferable that 1 to 3 tablet-like compositions having a diameter of 15 to 50 mm and a thickness of 5 to 25 mm are stored in the second storage unit 4, and the number of stored tablets is more preferably one. preferable.

なお、この炭酸塩を含有する組成物は、保管中に炭酸ガスが発生しないようにするため、第2収納部4には水分バリア性が必要とされる。したがって、第2収納部4にはガス抜き穴8は設けず、第2収納部4の開封開始部6として設けるミシン目状切れ目や切り込みは第2収納部4にかからないようにする。 The composition containing this carbonate is required to have a moisture barrier property in the second storage portion 4 in order to prevent carbon dioxide gas from being generated during storage. Therefore, the second storage portion 4 is not provided with the gas vent hole 8, and the perforated cuts and cuts provided as the opening start portion 6 of the second storage portion 4 are not provided on the second storage portion 4.

(変形態様)
本発明の包装体は、種々の態様をとることができる。例えば、図3に示した包装体1Cは、上述の図1に示した包装体1Aにおいて、第1収納部3のガス抜き穴8として設けた複数列のミシン目状切れ目9を仕切りシール部2Aに延設し、仕切りシール部2Aに延設した複数列のミシン目状切れ目9が第2収納部4の開封開始部6となるようにしたものである。このように複数列のミシン目状切れ目をガス抜き穴8としても開封開始部6としても機能させる場合、ミシン目のカット部分の長さL1を0.5〜2.0mm、アンカット部分の長さL2を0.5〜2.0mm、並列しているミシン目状切れ目9の間隔L3を0.5〜2.0mm、並列しているミシン目状切れ目9の本数を8〜70本又はミシン目状切れ目9の並列領域の幅L4を3.0〜15mmとすることが好ましい(ミシン目の長さ等の符号については図1参照)。
(Modification mode)
The package of the present invention can take various aspects. For example, in the package 1C shown in FIG. 3, in the package 1A shown in FIG. 1 described above, a plurality of rows of perforated cuts 9 provided as gas vent holes 8 in the first storage portion 3 are partitioned and sealed portions 2A. The perforated cuts 9 in a plurality of rows extending to the partition seal portion 2A serve as the opening start portion 6 of the second storage portion 4. When the perforated cuts in a plurality of rows function as both the gas vent hole 8 and the opening start portion 6, the length L1 of the cut portion of the perforation is 0.5 to 2.0 mm, and the length of the uncut portion is set. L2 is 0.5 to 2.0 mm, the interval L3 of the parallel perforated cuts 9 is 0.5 to 2.0 mm, and the number of parallel perforated cuts 9 is 8 to 70 or a sewing machine. It is preferable that the width L4 of the parallel region of the perforated cut 9 is 3.0 to 15 mm (see FIG. 1 for symbols such as the length of the perforation).

図4に示した包装体1Dは、図3においてガス抜き穴8及び第2収納部4の開封開始部6として設けたミシン目状切れ目9を、第1収納部3の側辺のシール部2Bに延設し、側辺のシール部2Bに延設したミシン目状切れ目9が、第1収納部3の開封開始部5として機能するようにしたものである。 In the package 1D shown in FIG. 4, the perforated cut 9 provided as the degassing hole 8 and the opening start portion 6 of the second storage portion 4 in FIG. 3 is provided as a seal portion 2B on the side side of the first storage portion 3. The perforated cut 9 extending to the side sealing portion 2B functions as the opening start portion 5 of the first storage portion 3.

図5に示した包装体1Eは、図4に示した包装体1Dにおいて、仕切りシール部2Aと対向する第2収納部4の側辺2Cが、フィルムを2つ折りにした折り山になるようにしたものである。したがって、この包装体1Eは、3方シールのフィルム製平袋の略中央部に仕切りシール部2Aが形成されているものとなる。この態様によれば、第2収納部4の側辺2Cがフィルムの折り山であることにより、この側辺2Cを負荷なく引き裂くことができるので、第1収納部3の開封開始部5から第2収納部4の側辺2Cまでをきれいに切ることができる。 In the package 1E shown in FIG. 5, in the package 1D shown in FIG. 4, the side 2C of the second storage portion 4 facing the partition seal portion 2A becomes a fold mountain in which the film is folded in half. It was done. Therefore, in this package 1E, the partition seal portion 2A is formed in the substantially central portion of the film flat bag having a three-way seal. According to this aspect, since the side side 2C of the second storage portion 4 is a fold of the film, the side side 2C can be torn without a load, so that the opening start portion 5 to the first storage portion 3 can be torn. 2 It is possible to cleanly cut up to the side 2C of the storage portion 4.

図6に示した包装体1Fは、図4に示した包装体1Dにおいて、第1収納部3及び第2収納部4の底辺2Dが、フィルムを2つ折りにした折り山になるようにしたものである。この態様によれば、折り山のある底辺2Dの反対側の開口部が自ずと開くようになるので、内容物の充填や取り出しが容易となる。 In the package 1F shown in FIG. 6, in the package 1D shown in FIG. 4, the bottom 2Ds of the first storage unit 3 and the second storage unit 4 are formed into folds formed by folding the film in half. Is. According to this aspect, the opening on the opposite side of the bottom 2D having the folds opens naturally, so that the contents can be easily filled and taken out.

本発明の包装体において、上述した第1収納部3の開封開始部5、第1収納部のガス抜き穴8、第2収納部4の開封開始部6の形成態様は、適宜変形したり組み合わせたりすることができる。例えば、第2収納部4の側辺のシール部に開封開始部6を、第1収納部3の開封開始部5と対向する位置に設けてもよい。 In the package of the present invention, the forms of the opening start portion 5 of the first storage portion 3, the gas vent hole 8 of the first storage portion, and the opening start portion 6 of the second storage portion 4 are appropriately deformed or combined. Can be done. For example, the opening start portion 6 may be provided on the side sealing portion of the second storage portion 4 at a position facing the opening start portion 5 of the first storage portion 3.

本発明の包装袋は、上述した包装体1A〜1Fの製造に使用するに好適な包装袋であって、上述した包装体1A〜1Fに内容物20、21が収納されておらず、内容物20、21を収納するための開口部を備えたものである。例えば、図4に示した包装体1Dに対応する包装袋としては、図7に示すように、包装袋の上辺に開口部10を有する包装袋1dや図8に示すように、包装袋の下辺に開口部10を有する包装袋1d’を挙げることができ、他の包装体1A、1B、1C、1E、1Fに対応する包装袋も同様に開口部を設けたものとすることができる。開口部10から内容物が包装袋に収納された後、開口部10はシールされ、包装体となる。 The packaging bag of the present invention is a packaging bag suitable for use in the production of the above-mentioned packages 1A to 1F, and the contents 20 and 21 are not stored in the above-mentioned packages 1A to 1F, and the contents It is provided with an opening for storing 20 and 21. For example, as the packaging bag corresponding to the packaging body 1D shown in FIG. 4, as shown in FIG. 7, the packaging bag 1d having an opening 10 on the upper side of the packaging bag and the lower side of the packaging bag as shown in FIG. The packaging bag 1d'having the opening 10 can be mentioned, and the packaging bags corresponding to the other packaging bodies 1A, 1B, 1C, 1E, and 1F can be similarly provided with the opening. After the contents are stored in the packaging bag through the opening 10, the opening 10 is sealed and becomes a package.

1A、1B、1C、1D、1E、1F 包装体
1d、1d’ 包装袋
2A 仕切りシール部
2B 側辺のシール部
2C フィルム材料の折り山となっている側辺
2D フィルム材料の折り山となっている底辺
3 第1収納部
4 第2収納部
5 第1収納部の開封開始部
6 第2収納部の開封開始部
7 ミシン目状切れ目
8 ガス抜き穴
9 ミシン目状切れ目
10 開口部
20 ガス発生性組成物
21 タブレット状組成物
X 開封予定方向
1A, 1B, 1C, 1D, 1E, 1F Packaging body 1d, 1d'Packaging bag 2A Partition seal part 2B Side seal part 2C Side side 2D film material fold Bottom 3 1st storage part 4 2nd storage part 5 Opening start part of 1st storage part 6 Opening start part of 2nd storage part 7 Perforated cut 8 Degassing hole 9 Perforated cut 10 Opening 20 Gas generation Sex composition 21 Tablet-like composition X Direction to be opened

Claims (14)

フィルムで形成された第1収納部と第2収納部が仕切りシール部を挟んで連続し、第1収納部に固形のガス発生性組成物が収納され、第2収納部にタブレット状組成物が収納されている包装体であって、仕切りシール部と対向する、第1収納部の側辺のシール部に第1収納部の開封開始部を有すると共に、該第1収納部の開封開始部による開封予定方向と仕切りシール部とが交差する領域に第2収納部の開封開始部を有し、第1収納部にガス抜き穴を有する包装体。 The first storage part and the second storage part formed of the film are continuous with the partition seal part sandwiched between them, the solid gas-generating composition is stored in the first storage part, and the tablet-like composition is stored in the second storage part. A package that is stored and has an opening start portion of the first storage portion at a seal portion on the side of the first storage portion that faces the partition seal portion, and is based on the opening start portion of the first storage portion. A packaging body having an opening start portion of a second storage portion in an area where a planned opening direction and a partition seal portion intersect, and a gas vent hole in the first storage portion. 第2収納部の開封開始部がミシン目状切れ目で形成されている請求項1記載の包装体。 The package according to claim 1, wherein the opening start portion of the second storage portion is formed by a perforated cut. 第1収納部内の、第1収納部の開封開始部と第2収納部の開封開始部に挟まれた領域にミシン目状切れ目が複数並列しており、該ミシン目状切れ目がガス抜き穴となっている請求項1又は2記載の包装宇体。 A plurality of perforated cuts are arranged in parallel in the area sandwiched between the opening start portion of the first storage portion and the opening start portion of the second storage portion in the first storage portion, and the perforation cuts are the gas vent holes. The packaging body according to claim 1 or 2. 第1収納部内の複数並列したミシン目状切れ目が仕切りシール部に延設されており、その延設されたミシン目状切れ目が第2収納部の開封開始部となっている請求項3記載の包装体。 The third aspect of claim 3, wherein a plurality of parallel perforated cuts in the first storage portion are extended to the partition seal portion, and the extended perforated cuts serve as an opening start portion of the second storage portion. Packaging body. 第1収納部内の複数並列したミシン目状切れ目が第1収納部の側辺のシール部に延設されており、その延設されたミシン目状切れ目が第1収納部の開封開始部となっている請求項3又は4記載の包装体。 A plurality of parallel perforated cuts in the first storage portion are extended to the seal portion on the side side of the first storage portion, and the extended perforated cuts serve as an opening start portion of the first storage portion. The packaging according to claim 3 or 4. 仕切りシール部と対向する第2収納部の側辺が、該第2収納部を形成するフィルムの折り山になっている請求項1〜5のいずれかに記載の包装体。 The package according to any one of claims 1 to 5, wherein the side side of the second storage portion facing the partition seal portion is a fold of a film forming the second storage portion. フィルムが引裂直進性を有する請求項1〜6のいずれかに記載の包装体。 The package according to any one of claims 1 to 6, wherein the film has tear straightness. 第1収納部に収納されているガス発生性組成物が酸素系漂白剤であり、第2収納部に収納されているタブレット状組成物が炭酸塩含有発泡性組成物である請求項1〜7のいずれかに記載の包装体。 Claims 1 to 7 where the gas-generating composition stored in the first storage portion is an oxygen-based bleach, and the tablet-like composition stored in the second storage portion is a carbonate-containing effervescent composition. The packaging described in any of. 第1収納部と第2収納部が仕切りシール部を挟んで連続し、第1収納部に固形のガス発生性組成物を収納し、第2収納部にタブレット状組成物を収納するための包装袋であって、第1収納部と第2収納部がそれぞれ内容物を収納するための開口部を有し、仕切りシール部と対向する第1収納部の側辺のシール部に第1収納部の開封開始部を有すると共に、該第1収納部の開封開始部による開封予定方向と仕切りシール部とが交差する領域に第2収納部の開封開始部を有し、第1収納部にガス抜き穴を有する包装袋。 A package for storing a solid gas-generating composition in the first storage portion and a tablet-like composition in the second storage portion, in which the first storage portion and the second storage portion are continuous with the partition seal portion in between. In the bag, the first storage portion and the second storage portion each have an opening for storing the contents, and the first storage portion is located on the side seal portion of the first storage portion facing the partition seal portion. The opening start portion of the second storage portion is provided in the area where the planned opening direction by the opening start portion of the first storage portion and the partition seal portion intersect, and the first storage portion is degassed. Packaging bag with holes. 第2収納部の開封開始部がミシン目状切れ目で形成されている請求項9記載の包装袋。 The packaging bag according to claim 9, wherein the opening start portion of the second storage portion is formed by a perforated cut. 第1収納部内の、第1収納部の開封開始部と第2収納部の開封開始部に挟まれた領域にミシン目状切れ目が複数並列しており、該ミシン目状切れ目がガス抜き穴となる請求項9又は10記載の包装袋。 A plurality of perforated cuts are arranged in parallel in the area sandwiched between the opening start portion of the first storage portion and the opening start portion of the second storage portion in the first storage portion, and the perforated cuts are the gas vent holes. The packaging bag according to claim 9 or 10. 第1収納部内の複数並列したミシン目状切れ目が仕切りシール部に延設されており、その延設されたミシン目状切れ目が第2収納部の開封開始部となる請求項11記載の包装袋。 The packaging bag according to claim 11, wherein a plurality of parallel perforated cuts in the first storage portion are extended to the partition seal portion, and the extended perforated cuts serve as an opening start portion of the second storage portion. .. 第1収納部内の複数並列したミシン目状切れ目が第1収納部の側辺のシール部に延設されており、その延設されたミシン目状切れ目が第1収納部の開封開始部となる請求項11又は12記載の包装袋。 A plurality of parallel perforated cuts in the first storage portion are extended to the seal portion on the side side of the first storage portion, and the extended perforated cuts serve as an opening start portion of the first storage portion. The packaging bag according to claim 11 or 12. 仕切りシール部と対向する第2収納部の側辺が、該第2収納部を形成するフィルムの折り山になっている請求項9〜13のいずれかに記載の包装袋。 The packaging bag according to any one of claims 9 to 13, wherein the side side of the second storage portion facing the partition seal portion is a fold of a film forming the second storage portion.
JP2019058833A 2019-03-26 2019-03-26 Package Pending JP2020158151A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6194544U (en) * 1984-11-24 1986-06-18
JPH03119174A (en) * 1989-08-23 1991-05-21 Unilever Nv Laundry treatment product
JPH061357A (en) * 1992-06-22 1994-01-11 Matsushita Electric Ind Co Ltd Packaging bag
JP2002180098A (en) * 2000-12-15 2002-06-26 Kao Corp Tablet type detergent and method for producing the same
JP2004250041A (en) * 2003-02-20 2004-09-09 Dainippon Printing Co Ltd Liquid sachet package
JP2006152179A (en) * 2004-11-30 2006-06-15 Lion Corp Method for cleaning washing machine drum
JP2011006107A (en) * 2009-06-25 2011-01-13 Toyo Seikan Kaisha Ltd Easy-opening packing bag
JP2017159913A (en) * 2016-03-07 2017-09-14 凸版印刷株式会社 Packaging bag

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6194544U (en) * 1984-11-24 1986-06-18
JPH03119174A (en) * 1989-08-23 1991-05-21 Unilever Nv Laundry treatment product
JPH061357A (en) * 1992-06-22 1994-01-11 Matsushita Electric Ind Co Ltd Packaging bag
JP2002180098A (en) * 2000-12-15 2002-06-26 Kao Corp Tablet type detergent and method for producing the same
JP2004250041A (en) * 2003-02-20 2004-09-09 Dainippon Printing Co Ltd Liquid sachet package
JP2006152179A (en) * 2004-11-30 2006-06-15 Lion Corp Method for cleaning washing machine drum
JP2011006107A (en) * 2009-06-25 2011-01-13 Toyo Seikan Kaisha Ltd Easy-opening packing bag
JP2017159913A (en) * 2016-03-07 2017-09-14 凸版印刷株式会社 Packaging bag

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