JP2020100812A5 - - Google Patents
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- Publication number
- JP2020100812A5 JP2020100812A5 JP2019212419A JP2019212419A JP2020100812A5 JP 2020100812 A5 JP2020100812 A5 JP 2020100812A5 JP 2019212419 A JP2019212419 A JP 2019212419A JP 2019212419 A JP2019212419 A JP 2019212419A JP 2020100812 A5 JP2020100812 A5 JP 2020100812A5
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- airgel
- polymer airgel
- less
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229920000642 polymer Polymers 0.000 claims 32
- 239000000178 monomer Substances 0.000 claims 10
- 239000012986 chain transfer agent Substances 0.000 claims 6
- 239000003795 chemical substances by application Substances 0.000 claims 6
- 239000004971 Cross linker Substances 0.000 claims 5
- 239000003431 cross linking reagent Substances 0.000 claims 5
- 239000002243 precursor Substances 0.000 claims 5
- 239000002904 solvent Substances 0.000 claims 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 claims 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims 2
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical compound C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 claims 2
- 239000003999 initiator Substances 0.000 claims 2
- 239000010702 perfluoropolyether Substances 0.000 claims 2
- 239000011148 porous material Substances 0.000 claims 2
- BWTMTZBMAGYMOD-UHFFFAOYSA-N (2,2,3,3,4,4,5,5-octafluoro-6-prop-2-enoyloxyhexyl) prop-2-enoate Chemical group C=CC(=O)OCC(F)(F)C(F)(F)C(F)(F)C(F)(F)COC(=O)C=C BWTMTZBMAGYMOD-UHFFFAOYSA-N 0.000 claims 1
- FMQPBWHSNCRVQJ-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-yl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C(F)(F)F)C(F)(F)F FMQPBWHSNCRVQJ-UHFFFAOYSA-N 0.000 claims 1
- OGBWMWKMTUSNKE-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CCCCCC(OC(=O)C(C)=C)OC(=O)C(C)=C OGBWMWKMTUSNKE-UHFFFAOYSA-N 0.000 claims 1
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 claims 1
- MLBWTXHUVGBPNL-UHFFFAOYSA-N 1-pyridin-4-ylheptan-1-one Chemical compound CCCCCCC(=O)C1=CC=NC=C1 MLBWTXHUVGBPNL-UHFFFAOYSA-N 0.000 claims 1
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 claims 1
- VBHXIMACZBQHPX-UHFFFAOYSA-N 2,2,2-trifluoroethyl prop-2-enoate Chemical compound FC(F)(F)COC(=O)C=C VBHXIMACZBQHPX-UHFFFAOYSA-N 0.000 claims 1
- HCZMHWVFVZAHCR-UHFFFAOYSA-N 2-[2-(2-sulfanylethoxy)ethoxy]ethanethiol Chemical compound SCCOCCOCCS HCZMHWVFVZAHCR-UHFFFAOYSA-N 0.000 claims 1
- FDSUVTROAWLVJA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)COCC(CO)(CO)CO FDSUVTROAWLVJA-UHFFFAOYSA-N 0.000 claims 1
- GVEUEBXMTMZVSD-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,6-nonafluorohex-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C=C GVEUEBXMTMZVSD-UHFFFAOYSA-N 0.000 claims 1
- UZFMOKQJFYMBGY-UHFFFAOYSA-N 4-hydroxy-TEMPO Chemical compound CC1(C)CC(O)CC(C)(C)N1[O] UZFMOKQJFYMBGY-UHFFFAOYSA-N 0.000 claims 1
- 101710141544 Allatotropin-related peptide Proteins 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 1
- QYTDEUPAUMOIOP-UHFFFAOYSA-N TEMPO Chemical group CC1(C)CCCC(C)(C)N1[O] QYTDEUPAUMOIOP-UHFFFAOYSA-N 0.000 claims 1
- 239000004964 aerogel Substances 0.000 claims 1
- 125000005262 alkoxyamine group Chemical group 0.000 claims 1
- 238000010560 atom transfer radical polymerization reaction Methods 0.000 claims 1
- ZGRWZUDBZZBJQB-UHFFFAOYSA-N benzenecarbodithioic acid Chemical group SC(=S)C1=CC=CC=C1 ZGRWZUDBZZBJQB-UHFFFAOYSA-N 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 238000000354 decomposition reaction Methods 0.000 claims 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical group CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 claims 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 238000012712 reversible addition−fragmentation chain-transfer polymerization Methods 0.000 claims 1
- 150000003573 thiols Chemical group 0.000 claims 1
- 229910001428 transition metal ion Inorganic materials 0.000 claims 1
- HIZCIEIDIFGZSS-UHFFFAOYSA-L trithiocarbonate Chemical group [S-]C([S-])=S HIZCIEIDIFGZSS-UHFFFAOYSA-L 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16/228,472 | 2018-12-20 | ||
| US16/228,472 US10995191B2 (en) | 2018-12-20 | 2018-12-20 | High optical transparency polymer aerogels using low refractive index monomers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2020100812A JP2020100812A (ja) | 2020-07-02 |
| JP2020100812A5 true JP2020100812A5 (enExample) | 2022-12-01 |
| JP7285200B2 JP7285200B2 (ja) | 2023-06-01 |
Family
ID=68944352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019212419A Active JP7285200B2 (ja) | 2018-12-20 | 2019-11-25 | 低屈折率モノマーを使用する高光透過性ポリマーエアロゲル |
Country Status (3)
| Country | Link |
|---|---|
| US (2) | US10995191B2 (enExample) |
| EP (1) | EP3671291A1 (enExample) |
| JP (1) | JP7285200B2 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2970672A4 (en) * | 2013-03-15 | 2016-08-24 | California Inst Of Techn | Associative polymers and related compositions, methods and systems |
| WO2016044803A1 (en) | 2014-09-18 | 2016-03-24 | California Institute Of Technology | Associative polymers and related compositions, methods and systems |
| US10995191B2 (en) | 2018-12-20 | 2021-05-04 | Palo Alto Research Center Incoporated | High optical transparency polymer aerogels using low refractive index monomers |
| EP4363061A4 (en) * | 2021-07-01 | 2025-05-14 | Chalkless, Inc. | PARTICULATED AEROGEL MATERIAL KIT FOR GRIP IMPROVEMENT |
| US20230286810A1 (en) | 2022-03-09 | 2023-09-14 | Cardinal Cg Company | Silica wet gel and aerogel |
| CN115449036B (zh) * | 2022-09-07 | 2025-07-01 | 亚士创能科技(石家庄)有限公司 | 氟改性的二氧化硅气凝胶及其制备方法、应用、隔热涂料及其制备方法、应用 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2736342B1 (fr) | 1995-07-07 | 1999-01-29 | Univ Claude Bernard Lyon | Procede pour la fabrication d'aerogels de silice monolithiques et aerogels de silice ainsi obtenus |
| JP3296153B2 (ja) | 1995-09-06 | 2002-06-24 | 住友化学工業株式会社 | スチレン系重合体の製造方法、スチレン系樹脂組成物及びその成形品 |
| EP1062248B1 (en) | 1998-03-12 | 2004-07-21 | Lucite International UK Limited | Polymer composition |
| US7732496B1 (en) | 2004-11-03 | 2010-06-08 | Ohio Aerospace Institute | Highly porous and mechanically strong ceramic oxide aerogels |
| US8110258B2 (en) | 2005-11-25 | 2012-02-07 | Advanced Glazing Technologies Limited (Agtl) | Glazing unit with transparent filler |
| US8663742B2 (en) | 2008-06-30 | 2014-03-04 | Stc.Unm | Durable polymer-aerogel based superhydrophobic coatings, a composite material |
| WO2010080238A2 (en) | 2008-12-18 | 2010-07-15 | 3M Innovative Properties Company | Telechelic hybrid aerogels |
| US8691883B2 (en) | 2009-02-11 | 2014-04-08 | Samsung Electronics Co., Ltd. | Aerogel-foam composites |
| WO2012154602A1 (en) | 2011-05-06 | 2012-11-15 | Showers Robert James | Aerogel window film system |
| WO2013055432A1 (en) * | 2011-10-10 | 2013-04-18 | 3M Innovative Properties Company | Aerogels, calcined and crystalline articles and methods of making the same |
| JP2017043708A (ja) * | 2015-08-27 | 2017-03-02 | 日立化成株式会社 | エアロゲル |
| JP2019131622A (ja) * | 2016-05-09 | 2019-08-08 | 国立大学法人 東京大学 | アルコキシシラン類及びポリロタキサンを有してなるゾル及びゲル |
| US10421253B2 (en) | 2016-10-05 | 2019-09-24 | Palo Alto Research Center Incorporated | Polymer aerogel for window glazings |
| US11180627B2 (en) * | 2017-01-11 | 2021-11-23 | The Regents Of The University Of Colorado, A Body Corporate | Cellulose enabled orientationally ordered flexible gels |
| US10626224B2 (en) * | 2017-10-09 | 2020-04-21 | Palo Alto Research Center Incorporated | Method to produce transparent polymer aerogels using chain transfer agents |
| WO2019210094A2 (en) * | 2018-04-26 | 2019-10-31 | Blueshift Materials, Inc. | Polymer aerogels fabricated without solvent exchange |
| US10995191B2 (en) | 2018-12-20 | 2021-05-04 | Palo Alto Research Center Incoporated | High optical transparency polymer aerogels using low refractive index monomers |
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2018
- 2018-12-20 US US16/228,472 patent/US10995191B2/en active Active
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2019
- 2019-11-25 JP JP2019212419A patent/JP7285200B2/ja active Active
- 2019-12-17 EP EP19217213.8A patent/EP3671291A1/en active Pending
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2021
- 2021-04-30 US US17/245,418 patent/US11851543B2/en active Active