JP2020095287A5 - - Google Patents

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JP2020095287A5
JP2020095287A5 JP2020039592A JP2020039592A JP2020095287A5 JP 2020095287 A5 JP2020095287 A5 JP 2020095287A5 JP 2020039592 A JP2020039592 A JP 2020039592A JP 2020039592 A JP2020039592 A JP 2020039592A JP 2020095287 A5 JP2020095287 A5 JP 2020095287A5
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film
strain
polarizing plate
resin
measuring
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JP2020039592A
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JP2020095287A (en
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Claims (7)

偏光板の一方の面に、可塑性樹脂フィルムとその上に積層される粘着剤層とを含む表面保護フィルムが剥離可能に積層され、
前記偏光板のもう一方の面に厚み3〜25μmである粘着剤層を介して、離型処理された熱可塑性樹脂フィルムで構成された剥離フィルムが剥離可能に積層され、
前記偏光板は、偏光子を含み、該偏光子の一方の面に接着剤層を介して保護フィルムが積層され、もう一方の面に粘着剤層を介して輝度向上フィルムが積層された層構成であり、
前記表面保護フィルムを測定フィルムとして、以下の測定方法により測定される最大の力(F(N))をF3とし、歪み(S(mm))をS3としたときに最大の力F3(N)と歪みS3(mm)との積(F3(N)×S3(mm))として表される剛性K3が0.14N・mm以上0.75N・mm以下である積層体であって、
前記偏光板と前記表面保護フィルムとからなる層を測定用フィルムとして、以下の測定方法により測定される最大の力(F(N))をF1とし、歪み(S(mm))をS1としたときに、最大の力F1(N)と歪みS1(mm)との積(F1(N)×S1(mm))として表される剛性K1が3.8N・mm以上9.1N・mm以下であり、
前記偏光板を測定フィルムとして前記測定方法により測定される最大の力(F(N))をF2(N)とし、歪み(S(mm))をS2としたときに最大の力F2(N)と歪みS2(mm)との積として表される剛性K2が0.10N・mm以上1.00N・mm以下であり、
前記熱可塑性樹脂フィルムは、ポリオレフィン系樹脂、環状ポリオレフィン系樹脂、ポリエステル系樹脂ポリカーボネート系樹脂または(メタ)アクリル系樹脂から構成され、厚みが30〜80μmであり、
前記剥離フィルムは、ポリエチレン系樹脂、ポリプロピレン系樹脂、ポリエステル系樹脂から構成され、厚みが10〜50μmであり、
前記偏光板と前記剥離フィルムとの間の密着力は0.02〜0.05N/25mmであり、前記偏光板と前記表面保護フィルムとの間の密着力よりも小さい積層体。
測定方法:
上面から見て中央に円形の貫通孔を有し、上面における貫通孔の直径が30mmであり、側面から見た貫通孔の形状が柱状の下部と半球状の上部とによって構成される形状である測定台に、
25mm×43mmの矩形の測定用フィルムを載置し、
該測定用フィルムの上方から、先端が球形であり先端径が1mmφであり曲率半径が0.5mmであるニードルを、該ニードルが測定台の貫通孔の中心を通るように、1.0cm/秒の速度で垂直に降下させ、
ニードルの先端が測定用フィルムに接してから、該フィルムがたわんだ状態を保持する最大の荷重を最大の力F(N)として測定し、そのときのフィルムの歪みS(mm)を測定する。
A surface protective film containing a plastic resin film and an adhesive layer laminated on the plastic resin film is detachably laminated on one surface of the polarizing plate.
A release film composed of a release-treated thermoplastic resin film is laminated on the other surface of the polarizing plate via a pressure-sensitive adhesive layer having a thickness of 3 to 25 μm so as to be removable.
The polarizing plate includes a polarizing element, and a protective film is laminated on one surface of the polarizing element via an adhesive layer, and a brightness improving film is laminated on the other surface via an adhesive layer. And
When the surface protective film is used as a measuring film, the maximum force (F (N)) measured by the following measuring method is F3, and the strain (S (mm)) is S3, the maximum force F3 (N). A laminated body having a rigidity K3 expressed as the product of the strain S3 (mm) and the strain S3 (mm) (F3 (N) × S3 (mm)) of 0.14 N · mm or more and 0.75 N · mm or less.
The layer composed of the polarizing plate and the surface protective film was used as a measuring film, the maximum force (F (N)) measured by the following measuring method was F1, and the strain (S (mm)) was S1. Sometimes, the rigidity K1 expressed as the product (F1 (N) × S1 (mm)) of the maximum force F1 (N) and the strain S1 (mm) is 3.8 N ・ mm or more and 9.1 N ・ mm or less. Oh it is,
When the maximum force (F (N)) measured by the measurement method is F2 (N) and the strain (S (mm)) is S2 using the polarizing plate as a measurement film, the maximum force F2 (N) The rigidity K2 expressed as the product of the strain S2 (mm) is 0.10 N ・ mm or more and 1.00 N ・ mm or less.
The thermoplastic resin film is composed of a polyolefin resin, a cyclic polyolefin resin, a polyester resin, a polycarbonate resin, or a (meth) acrylic resin, and has a thickness of 30 to 80 μm.
The release film is composed of a polyethylene-based resin, a polypropylene-based resin, and a polyester-based resin, and has a thickness of 10 to 50 μm.
A laminate having an adhesion between the polarizing plate and the release film of 0.02 to 0.05 N / 25 mm, which is smaller than the adhesion between the polarizing plate and the surface protective film .
Measuring method:
It has a circular through hole in the center when viewed from the upper surface, the diameter of the through hole on the upper surface is 30 mm, and the shape of the through hole when viewed from the side surface is a shape composed of a columnar lower portion and a hemispherical upper portion. On the measuring table
A 25 mm x 43 mm rectangular measuring film is placed on it.
From above the measuring film, a needle having a spherical tip, a tip diameter of 1 mmφ, and a radius of curvature of 0.5 mm is passed through the center of the through hole of the measuring table at 1.0 cm / sec. Descent vertically at the speed of
After the tip of the needle comes into contact with the measuring film, the maximum load that keeps the film in a bent state is measured as the maximum force F (N), and the strain S (mm) of the film at that time is measured.
前記輝度向上フィルムが一方の振動方向の直線偏光を透過し、他方の振動方向の直線偏光を反射する異方性多重薄膜である請求項1に記載の積層体。The laminate according to claim 1, wherein the brightness improving film is an anisotropic multilayer thin film that transmits linearly polarized light in one vibration direction and reflects linearly polarized light in the other vibration direction. 前記剛性K3が0.20N・mm以下である請求項1または請求項2に記載の積層体。The laminate according to claim 1 or 2, wherein the rigidity K3 is 0.20 N · mm or less. 前記熱可塑性樹脂フィルムがポリエステル系樹脂からなるフィルムである請求項1〜請求項3のいずれかに記載の積層体。The laminate according to any one of claims 1 to 3, wherein the thermoplastic resin film is a film made of a polyester resin. 前記熱可塑性樹脂フィルムの厚みが30μm〜60μmである請求項1〜請求項4のいずれかに記載の積層体。The laminate according to any one of claims 1 to 4, wherein the thickness of the thermoplastic resin film is 30 μm to 60 μm. 前記偏光子が、ポリビニルアルコール系樹脂フィルムに二色性色素を吸着配向させた偏光The polarized light is obtained by adsorbing and orienting a dichroic dye on a polyvinyl alcohol-based resin film.
子である請求項1〜請求項5のいずれかに記載の積層体。The laminate according to any one of claims 1 to 5, which is a child.
請求項1〜請求項6のいずれかに記載の積層体における表面保護フィルムを、0.1〜0.3N/60mmの密着力で保持台上に固定する工程と、
当該積層体から剥離フィルムを剥離する工程を含む表面保護フィルム付き偏光板の製造方法。
A step of fixing the surface protective film in the laminate according to any one of claims 1 to 6 on a holding table with an adhesion force of 0.1 to 0.3 N / 60 mm.
A method for manufacturing a polarizing plate with a surface protective film, which comprises a step of peeling a release film from the laminate.
JP2020039592A 2017-10-31 2020-03-09 Laminate body Pending JP2020095287A (en)

Applications Claiming Priority (4)

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JP2017210092 2017-10-31
JP2017210092 2017-10-31
JP2018082808 2018-04-24
JP2018082808 2018-04-24

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JP2020095287A5 true JP2020095287A5 (en) 2021-10-14

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JP7469889B2 (en) * 2020-01-28 2024-04-17 住友化学株式会社 Optical laminate and method for manufacturing display device
CN115151967B (en) * 2020-02-28 2024-05-10 住友化学株式会社 Optical laminate and flexible image display device
JP7469087B2 (en) * 2020-03-18 2024-04-16 住友化学株式会社 Optical film and flexible display device
WO2021205727A1 (en) 2020-04-09 2021-10-14 住友化学株式会社 Optical laminate and peeling method
JP2023076153A (en) * 2021-11-22 2023-06-01 住友化学株式会社 optical laminate

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JP3311032B2 (en) 1992-07-28 2002-08-05 株式会社東芝 Film peeling method and apparatus
CN105717569A (en) * 2014-12-18 2016-06-29 住友化学株式会社 Polarizing plate with protection film and laminated body comprising same
JP2016118771A (en) * 2014-12-18 2016-06-30 住友化学株式会社 Polarizing plate with protective film and laminate including the same
KR102641791B1 (en) * 2015-08-24 2024-03-04 닛토덴코 가부시키가이샤 Optical member with surface protection film
JP7154733B2 (en) * 2015-08-24 2022-10-18 日東電工株式会社 Optical components with surface protection film
JP7334024B2 (en) * 2016-02-08 2023-08-28 日東電工株式会社 Optical film and optical display panel
JP2017181597A (en) * 2016-03-28 2017-10-05 住友化学株式会社 Optical film and polarizing plate
JP6905312B2 (en) * 2016-03-30 2021-07-21 日東電工株式会社 Optical film, peeling method and manufacturing method of optical display panel

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