JP2020036584A - Modifier for protein containing sol-like food product - Google Patents

Modifier for protein containing sol-like food product Download PDF

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JP2020036584A
JP2020036584A JP2019149835A JP2019149835A JP2020036584A JP 2020036584 A JP2020036584 A JP 2020036584A JP 2019149835 A JP2019149835 A JP 2019149835A JP 2019149835 A JP2019149835 A JP 2019149835A JP 2020036584 A JP2020036584 A JP 2020036584A
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protein
product
texture
flavor
mouthfeel
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圭五 新美
Keigo Niimi
圭五 新美
泰志 一見
Yasushi Hitomi
泰志 一見
直哉 森
Naoya Mori
直哉 森
宮本 圭一
Keiichi Miyamoto
圭一 宮本
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Taiyo Kagaku KK
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Abstract

To provide a modifier for protein containing sol-like food product which can maintain shape retention due to modified protein, reduce mucus-like texture and improve flavor and melting-in-mouth feeling, while keeping a blended ratio of protein to an equal ratio, in a discomfort phenomenon in eating which occurs due to modification of protein, such as increase of mucus-like texture unique to modified protein, or reduction of melting-in-mouth feeling and flavor.SOLUTION: There is provided a modifier for protein containing sol-like food product which comprises fine gels which are prepared by a gelator and whose median size is 500 μm or smaller, for solving the above-mentioned problems.SELECTED DRAWING: Figure 1

Description

本発明は、蛋白質含有ゾル状食品に関し、保形性の向上に用いる蛋白質特有の粘質様食感の増加、口どけの悪化、風味の低下等の、蛋白質が変性することによって生じる喫食時の不快な現象を改質する、ゲル化剤によって調製された微細なゲルを含有した改質剤に関するものである。   The present invention relates to a protein-containing sol food product, such as an increase in the sticky texture of the protein used for improving the shape retention, deterioration of mouthfeel, decrease in flavor, etc., during eating caused by denaturation of the protein. The present invention relates to a modifier containing a fine gel prepared by a gelling agent, which modifies an unpleasant phenomenon.

蛋白質含有ゾル状食品として、卵を加熱して固めた焼プリンや、牛乳を乳酸発酵して固めたヨーグルト、豆乳ににがり等の凝固剤を添加し加熱して固めた豆腐、ゼラチンを加熱して溶かし冷し固めたゼリーや煮こごり類、畜肉のミンチや魚肉のすり身等を捏ねて加熱して固めたハンバーグやつくね類等が挙げられる。
これらの蛋白質含有ゾル状食品は、スプーンや箸などで食べ易くするために、加熱や発酵などの加工調理により蛋白質を変性させて保形性を高めた食品であるが、この変性した蛋白質特有の粘質様食感が増加して、口どけが悪く、風味が弱い等の問題があった。また、近年では、消費者の嗜好性の多様化や、製造会社の新製品開発競争の激化による従来品との差別化、高齢者社会化による硬い食物を噛めない・飲み込めない患者(嚥下・咀嚼困難者)向けの需要が高まり、滑らかで口どけの良い食感が求められてきている。
例えば、卵を加熱して固める加工品として、焼プリンや茶碗蒸し等では半熟卵様のソフトで滑らかな食感が、オムレツや卵焼き等ではふんわり柔らかく口どけの良い食感が好まれているが、加熱変性した卵蛋白質特有の粘質様食感が増加して、口どけが悪く、風味が弱い等の問題があった。
牛乳を発酵して固めるヨーグルトやクリームチーズのおいしさの指標として、滑らかさや濃厚感及び口どけの良さが挙げられ、豆乳に凝固剤を加え加熱して固める豆腐類では、つるりとして口どけの良い絹ごし豆腐の様な食感が近年好まれているが、変性した蛋白質特有の粘質様食感が増加して、口どけが悪く、風味が弱い等の問題があった。
ゼラチンはゼリーやムースのゲル化剤として使用されるほか、コンビニエンスストアで販売している電子レンジ加熱する麺類のスープやつゆ類に保形性の向上や麺類への染み込み抑制として使用され、電子レンジ加熱した後のゼラチン特有の粘質様食感が増加し、口どけや風味の低下等の問題があった。
また、畜肉のミンチや魚肉のすり身を使ったハンバーグやつくね類等においても、同様な問題があった。
As a protein-containing sol-like food, baked pudding hardened by heating eggs, yogurt hardened by lactic acid fermentation of milk, soy milk and a coagulant such as bittern are added and heated to harden tofu and gelatin. Examples thereof include melted and solidified jellies and boiled garnishes, hamburgers and meatballs which are made by kneading minced livestock meat or fish meat surimi and then heating and hardening them.
These protein-containing sol foods are foods that have been modified by heating, fermentation, or other processing to improve their shape retention so that they can be easily eaten with a spoon or chopsticks. There were problems such as an increase in the sticky texture, poor palatability and weak flavor. In recent years, diversification of consumer tastes, differentiation from conventional products due to intensifying competition for new product development by manufacturing companies, and patients who cannot chew or swallow hard food due to the aging society (swallowing / chewing) Demand for those who have difficulty is increasing, and smooth and mouthfeel texture is required.
For example, as a processed product that heats and solidifies eggs, soft and smooth texture like soft-boiled eggs is preferred for grilled pudding or chawanmushi, etc., and soft and mouthfeel texture is preferred for omelets and fried eggs etc. There were problems such as an increase in the sticky texture unique to the heat-denatured egg protein, poor palatability and weak flavor.
Indicators of the taste of yogurt and cream cheese that ferment and harden milk include smoothness, richness, and good mouthfeel.For tofu that is hardened by adding a coagulant to soymilk and heating it, it can be used as a slipper. A good silky tofu-like texture is recently preferred, but there are problems such as an increase in the viscous texture unique to the denatured protein, poor mouthfeel, and weak flavor.
Gelatin is used as a gelling agent for jelly and mousse, and is also used in soups and soups of noodles heated in microwave ovens sold at convenience stores to improve shape retention and to prevent penetration into noodles. The viscosity-like texture characteristic of gelatin after heating increased, and there were problems such as mouthfeel and a decrease in flavor.
There are also similar problems with hamburgers and meatballs using minced meat or minced fish meat.

そこで、蛋白質を変性又は添加して生じる、特有の粘質様食感が弱く、口どけや風味が良好な、蛋白質含有ゾル状食品がかねてより望まれていた。
これらの改善策として、卵の加工品に関しては、酸性可溶の大豆蛋白質を添加することにより、プリンや茶碗蒸しにあっては、ソフトで口溶けの良い食感、カスタードクリームやカルボナーラソースにおいては、離水及びザラツキが無く滑らかな食感、オムレツシートやクレープにおいては、ふっくら軟らかく口溶けの良い食感を得ることが報告されている(例えば、特許文献1参照。)。
また、乳製品に関しては、乳製品に、ネイティブ型ジェランガムおよび化工澱粉、好ましくはワキシーコーン由来のヒドロキシプロピル化リン酸架橋澱粉、タピオカ由来のヒドロキシプロピル化リン酸架橋澱粉、ワキシーコーン由来の水流動度10〜40のヒドロキシプロピル化澱粉、及びタピオカ由来の水流動度10〜40のヒドロキシプロピル化澱粉よりなる群から選ばれる少なくとも1種以上の二成分を配合することにより、濃厚感や口どけ感に代表される食感及び/又は保形性や保水性等の安定性に優れた乳製品、当該乳製品の製造方法、および当該乳製品の調製に有用な食品添加組成物を提供することが報告されている(例えば、特許文献2参照。)。
Therefore, a protein-containing sol food which has a weak sticky-like texture produced by denaturation or addition of protein, and has a good taste and flavor has been desired.
As a remedy, for processed egg products, acid-soluble soy protein is added, so that pudding and chawanmushi have a soft and mouth-melting texture, and custard cream and carbonara sauce have water separation. In addition, it has been reported that a smooth, texture-free omelet sheet or crepe without graininess gives a plump soft and mouth-melting texture (for example, see Patent Document 1).
As for dairy products, dairy products include native gellan gum and chemically modified starch, preferably hydroxypropylated phosphate-crosslinked starch derived from waxy corn, hydroxypropylated phosphate-crosslinked starch derived from tapioca, and water fluidity derived from waxy corn. By adding at least one or more two components selected from the group consisting of 10-40 hydroxypropylated starch and tapioca-derived water-fluidized hydroxypropylated starch having a fluidity of 10-40, richness and mouthfeel are obtained. It is reported that a dairy product having excellent stability such as typical texture and / or shape retention and water retention, a method for producing the dairy product, and a food additive composition useful for preparing the dairy product are reported. (For example, see Patent Document 2).

豆腐に関しては、豆乳に豆腐用凝固剤を添加する直前もしくは添加した後、通気し気泡を含有させ、更に静止型混合器(インラインミキサー)を通過させた後、豆腐用容器に充填する工程を含み、かつ凝固剤添加豆乳の粘度が200〜700cpで、凝固剤添加後充填直前までの時間が90秒以内とすることによって、増粘剤を使用しないで絹ごし豆腐様のつるんとした口どけの食感を保ちつつ、気泡を含有し新たな食感を付与した気泡入り豆腐を得ることが報告されている(例えば、特許文献3参照。)。
ゼラチンを使用したゾル状食品に関しては、酵素分解澱粉を、増粘多糖類及び/又はゼラチンの代替又は増粘多糖類及び/又はゼラチンと併用することにより、加工食品に優れた保形性や口どけ性を備えることができ、更には加工食品がゲル状食品であれば、優れた離水防止効果をも備えさせ得ることが報告されている(例えば、特許文献4参照。)
畜肉又は魚肉食品に関しては、固形分中のカルシウム含量が2質量%未満である乳清ミネラルを有効成分として含有することにより、畜肉又は魚肉食品の食感を柔らかくて口溶けの良い食感とすることができることが報告されている(例えば、特許文献5参照。)。
With respect to tofu, the method includes aeration and air bubbles immediately before or after the addition of a coagulant for tofu to soy milk, a step of passing through a static mixer (in-line mixer), and then filling the tofu container. The viscosity of the soymilk with the coagulant added is 200 to 700 cp, and the time immediately before the filling after the addition of the coagulant is 90 seconds or less, so that a silky tofu-like smooth mouth food without using a thickener is used. It has been reported that a bubble-containing tofu containing air bubbles and imparting a new texture while maintaining a feeling is obtained (for example, see Patent Document 3).
For sol foods using gelatin, the enzyme-degraded starch is substituted for the thickening polysaccharide and / or gelatin or used in combination with the thickening polysaccharide and / or gelatin to provide excellent shape retention and mouthfeel for processed foods. It has been reported that if the processed food is a gel food, it can also have an excellent water separation preventing effect (for example, see Patent Document 4).
Livestock meat or fish meat foods should contain whey minerals having a calcium content of less than 2% by mass of solid content as an active ingredient, so that the meat meat or fish meat food has a soft, mouth-melting texture. (See, for example, Patent Document 5).

しかしながら、これらの先行発明は、蛋白質含有ゾル状食品を柔らかい食感にして口どけを良くする技術、空気を含ませて軽い食感にして口どけを良くする技術、又は酵素分解澱粉をゼラチンと代替又は併用して口どけを良くする技術であり、蛋白質の配合割合はそのままで、保形性を維持しながら、変性した蛋白質特有の粘質様食感の増加に対する口どけや風味の低下の改善としては、まだ十分とは言えないものである。   However, these prior inventions are directed to a technique for improving the mouthfeel of a protein-containing sol food by giving it a soft texture, a technique of improving the mouthfeel by including air to provide a light mouthfeel, or a method of enzymatically degrading starch with gelatin. It is a technique to improve mouth-feeling by using alternative or combined use, while maintaining the shape-retaining property while maintaining the protein blending ratio, reducing mouth-feeling and flavor reduction with respect to the increase in the viscous texture unique to denatured protein. Improvements are still not enough.

WO2006/038413号公報WO2006 / 038413 特開2004−267160号公報JP-A-2004-267160 特開2004−201634号公報JP-A-2004-201634 特開2016−103992号公報JP-A-2006-103992 特開2011−55776号公報JP 2011-55776 A

本発明は、蛋白質含有ゾル状食品において、その蛋白質の配合割合のままで、変性した蛋白質による保形性を維持して、変性した蛋白質特有の粘質様食感を低減させ、口どけや風味の向上等の品質を改質する改質剤を提供することを目的とする。   The present invention provides a protein-containing sol food, which maintains the shape retention of the denatured protein while reducing the protein blending ratio, reduces the sticky-like texture peculiar to the denatured protein, and has a mouthfeel and flavor. It is an object of the present invention to provide a modifier for improving the quality such as improvement of the quality.

本発明者らは上記課題を解決するために鋭意努力した結果、メジアン径が500μm以下である、ゲル化剤によって調製された微細なゲルを含有する改質剤を、蛋白質含有ゾル状食品に添加することで、変性した蛋白質による保形性を維持したまま、口どけや風味の向上等の品質を改質することを見出し、本発明の完成に至った。
すなわち本発明は、蛋白質含有ゾル状食品用改質剤、及びその改質剤を含有するゾル状食品に関する。
The present inventors have made intensive efforts to solve the above problems, and as a result, added a modifier containing a fine gel prepared by a gelling agent and having a median diameter of 500 μm or less to a protein-containing sol food. By doing so, it was found that quality such as improvement in mouthfeel and flavor was improved while maintaining the shape-retaining property of the denatured protein, and the present invention was completed.
That is, the present invention relates to a protein-containing sol food modifier and a sol food containing the modifier.

上記構成からなる本発明の改質剤を、蛋白質含有ゾル状食品に添加することで、その蛋白質の配合割合のままで、変性した蛋白質による保形性を維持し、変性した蛋白質特有の粘質様食感を低減させ、口どけや風味の向上等の品質を改質することができる。   By adding the modifying agent of the present invention having the above-described structure to a protein-containing sol food, the shape retention of the modified protein is maintained while maintaining the blending ratio of the protein, and the viscosity characteristic of the modified protein is maintained. The texture can be reduced, and the quality such as mouthfeel and flavor can be improved.

図1は本発明品1〜3の蛋白質含有ゾル状食品用改質剤及び比較品1の調製操作の図である。FIG. 1 is a diagram showing a preparation operation of a protein-containing sol-like food modifier of products 1 to 3 of the present invention and a comparative product 1. 図2は本発明品4の蛋白質含有ゾル状食品用改質剤の調製操作の図である。FIG. 2 is a diagram showing an operation for preparing a protein-containing sol-like food modifier of product 4 of the present invention. 図3は本発明品5の蛋白質含有ゾル状食品用改質剤の調製操作の図である。FIG. 3 is a diagram showing an operation for preparing a protein-containing sol-like food modifier of the product 5 of the present invention. 図4は本発明品6の蛋白質含有ゾル状食品用改質剤の調製操作の図である。FIG. 4 is a diagram showing a procedure for preparing a protein-containing sol-based food modifier of the product 6 of the present invention. 図5は本発明品7の蛋白質含有ゾル状食品用改質剤の調製操作の図である。FIG. 5 is a diagram of the preparation operation of the protein-containing sol-like food modifier of the product 7 of the present invention. 図6は本発明品8の蛋白質含有ゾル状食品用改質剤の調製操作の図である。FIG. 6 is a diagram showing the procedure for preparing the protein-containing sol-based food modifier of the product 8 of the present invention. 図7は本発明品9の蛋白質含有ゾル状食品用改質剤の調製操作の図である。FIG. 7 is a diagram showing a procedure for preparing a protein-containing sol food modifier of the product 9 of the present invention. 図8は本発明品10及び11の蛋白質含有ゾル状食品用改質剤の調製操作の図である。FIG. 8 is a diagram showing the procedure for preparing the protein-containing sol-based food modifiers of the products 10 and 11 of the present invention. 図9は試験品1〜12及び対照品1の焼プリンの調製操作の図である。FIG. 9 is a diagram of the preparation operation of the baked pudding of the test products 1 to 12 and the control product 1. 図10は対照品2の焼プリンの調製操作の図である。FIG. 10 is a diagram illustrating a preparation operation of the baked pudding of the control product 2. 図11は試験品19〜30及び対照品3のプレーンヨーグルトの調製操作の図である。FIG. 11 is a diagram showing a preparation operation of plain yogurt of test products 19 to 30 and control product 3. 図12は対照品4のプレーンヨーグルトの調製操作の図である。FIG. 12 is a diagram showing a preparation operation of the plain yogurt of the control product 4. 図13は試験品37〜48及び対照品5の充填豆腐の調製操作の図である。FIG. 13 is a diagram showing an operation for preparing packed tofu of test products 37 to 48 and control product 5. 図14は対照品6の充填豆腐の調製操作の図である。FIG. 14 is a diagram showing an operation of preparing a filled tofu of the control product 6. 図15は試験品55〜66及び対照品7のゼラチンで固めた麺つゆの調製操作の図である。FIG. 15 is a diagram showing a preparation operation of noodle soup hardened with gelatin of test products 55 to 66 and control product 7. 図16は対照品8のゼラチンで固めた麺つゆの調製操作の図である。FIG. 16 is a diagram illustrating the operation of preparing a noodle soup hardened with gelatin as a control product 8. 図17は試験品73〜84及び対照品9の鶏つくねの調製操作の図である。FIG. 17 is a diagram showing a preparation operation of chicken tsukune of test products 73 to 84 and control product 9. 図18は対照品10の鶏つくねの調製操作の図である。FIG. 18 is a diagram showing a preparation operation of a chicken meatball of the control product 10. 図19は試験品91〜102及び対照品11のアジのつみれの調製操作の図である。FIG. 19 is a diagram illustrating the operation of preparing the horse mackerel fins of the test articles 91 to 102 and the control article 11. 図20は対照品12のアジのつみれの調製操作の図である。FIG. 20 is a diagram showing a preparation operation of a horse mackerel fin of the control product 12. 図21は本発明品12の蛋白質含有ゾル状食品用改質剤の調製操作の図である。FIG. 21 is a diagram showing an operation for preparing a protein-containing sol-like food modifier of the product 12 of the present invention.

以下、本発明を詳細に説明する。
本発明における微細なゲルの調製に用いられるゲル化剤は、通常のゲル状食品に使用されるものであって特に限定するものではないが、例えば、寒天、カラギナン、ジェランガム、キサンタンガム、ローカストビーンガム、タラガム、グルコマンナン、こんにゃく粉(芋)、ペクチン、アルギン酸、アルギン酸塩類、カードラン等が挙げられ、蛋白質含有ゾル状食品への本発明品添加後の食品製造工程における微細なゲルの安定性の面より、好ましくは、寒天、ジェランガム、グルコマンナン、こんにゃく粉(芋)、ペクチン、アルギン酸、アルギン酸塩類、カードラン等からなる群より選ばれる少なくとも1種以上が挙げられる。
上記ゲル化剤の種類により、ゲルの形成や強度の調整、溶解性の向上、又は耐熱性の向上などのために、カリウムや、カルシウム、ナトリウム等の金属塩類を併用してもよい。
Hereinafter, the present invention will be described in detail.
The gelling agent used in the preparation of the fine gel in the present invention is used for ordinary gel foods and is not particularly limited.For example, agar, carrageenan, gellan gum, xanthan gum, locust bean gum , Cod gum, glucomannan, konjac powder (potato), pectin, alginic acid, alginates, curdlan, etc., and the stability of the fine gel in the food production process after the addition of the product of the present invention to a protein-containing sol food From the viewpoint, preferably, at least one or more selected from the group consisting of agar, gellan gum, glucomannan, konjac powder (potato), pectin, alginic acid, alginates, curdlan and the like are used.
Depending on the type of the gelling agent, metal salts such as potassium, calcium, and sodium may be used in combination to form a gel, adjust strength, improve solubility, or improve heat resistance.

本発明における微細なゲルの調製方法は、特に限定するものではないが、例えば、通常のゲル状食品の様に、ゲル化剤を水にそのまま溶解、又は加熱して溶解、pHを調整して溶解して液状とし、冷却、又は加熱、塩類を添加、pHを調整して一旦ゲル状とした塊を、機械的に破砕・粉砕処理をして微細化させることにより得ることができる。また、液状としたものを高速で攪拌しながら、連続的に冷却、又は加熱、塩類を添加、pHを調整して、微細なゲルを得ることもできる。他に、塩類溶液に塩類と反応してゲル化するゲル化剤溶液を微細な粒状で滴下させることにより得る方法や、又は大きな粒状で滴下して得られたゲルを機械的に破砕・粉砕処理して微細化させることにより得る方法、冷却又は加熱してゲル化するゲル化剤溶液を霧状に噴霧して冷却又は加熱させることにより得る方法等が挙げられる。
また、必要により、ゲルの融解温度以下で微細なゲルを加熱殺菌することもできる。
The method for preparing a fine gel in the present invention is not particularly limited, but, for example, like a normal gel food, dissolve the gelling agent as it is in water, or dissolve it by heating and adjust the pH. It can be obtained by mechanically crushing and pulverizing a gel-like mass which is dissolved into a liquid state, cooled or heated, salt is added, and the pH is adjusted, and then finely divided. Further, a fine gel can be obtained by continuously cooling or heating, adding salts, and adjusting the pH while stirring the liquid at high speed. In addition, a method of obtaining a gelling agent solution that reacts with salts to form a gel by reacting with salts in fine particles, or mechanically crushing / crushing a gel obtained by dropping in large particles And a method obtained by spraying a gelling agent solution which gels upon cooling or heating to form a mist and cooling or heating the solution.
If necessary, the fine gel can be sterilized by heating at a temperature lower than the melting temperature of the gel.

本発明における微細なゲルに用いるゲル化剤の配合割合は、ゲル化剤の種類や、微細なゲルの調製方法、各々の工程における機械適性等によって、適宜調整することができる。
本発明における微細なゲルの大きさは、メジアン径で500μm以下であればよく、特に限定するものではないが、使用するゲル化剤において、より好ましくはメジアン径で300μm以下であり、更に好ましくはメジアン径で200μm以下である。
The mixing ratio of the gelling agent used for the fine gel in the present invention can be appropriately adjusted depending on the type of the gelling agent, the method for preparing the fine gel, the mechanical aptitude in each step, and the like.
The size of the fine gel in the present invention is not particularly limited as long as it is 500 μm or less in median diameter, but in the gelling agent used, it is more preferably 300 μm or less in median diameter, further preferably The median diameter is 200 μm or less.

本発明における微細なゲルのメジアン径は、湿式粒度分布測定装置(レーザ回折散乱法、Beckman coulter社製、機種名:LS 13 320)で測定した、体積基準の累積分布の50%に対応する粒子径(微細ゲルをある粒子径から同じ体積になるよう2つに分けたとき、大きい側と小さい側が等量となる径)のことである。湿式粒度分布測定装置の測定条件は、分散媒:水、ポンプ速度:31%循環、微細なゲルの相対濃度:8〜12%、超音波分散レベル:8で30秒間処理、測定時間:90秒、であり、粒度の算出条件は、分散媒屈折率の実数部:1.333、サンプル屈折率の実数部:1.6、 虚数部:0、とし、自動的にメジアン径を算出した。   The median diameter of the fine gel in the present invention is a particle corresponding to 50% of the volume-based cumulative distribution measured by a wet particle size distribution analyzer (laser diffraction scattering method, manufactured by Beckman coulter, model name: LS13320). The diameter (the diameter at which the larger side and the smaller side have the same volume when the fine gel is divided into two parts so as to have the same volume from a certain particle diameter). The measurement conditions of the wet type particle size distribution measuring device are as follows: dispersion medium: water, pump speed: 31% circulation, relative concentration of fine gel: 8 to 12%, ultrasonic dispersion level: 8 for 30 seconds, measurement time: 90 seconds The calculation conditions of the particle size were as follows: the real part of the refractive index of the dispersion medium: 1.333, the real part of the sample refractive index: 1.6, and the imaginary part: 0, and the median diameter was automatically calculated.

本発明における蛋白質含有ゾル状食品用改質剤に対する微細なゲルの配合割合は、特に限定するものではないが、例えば、好ましくは20重量%以上、より好ましくは50重量%以上、更に好ましくは65重量%以上、最も好ましくは80重量%以上である。
本発明の効果に悪影響を与えない限度において、本発明における微細なゲル、又は本発明における微細なゲルを含有する蛋白質含有ゾル状食品用改質剤に各種原料や添加剤を使用してもよく、特に限定するものではないが、例えば、砂糖などの糖類や、醤油、塩、香辛料、抹茶やココアなどの粉末類、チョコレートやゴマ油などの油脂類、牛乳や脱脂粉乳などの乳製品、食酢、果汁、酸味料、pH調整剤、グァーガムなどの増粘剤、乳化剤、アミノ酸などの調味料、高甘味度甘味料、香料、着色料、アルコール類、保存料、日持ち向上剤、酸化防止剤等が挙げられる。
The mixing ratio of the fine gel to the protein-containing sol food modifier in the present invention is not particularly limited, but is, for example, preferably 20% by weight or more, more preferably 50% by weight or more, and further preferably 65% by weight or more. % By weight, most preferably 80% by weight or more.
To the extent that the effects of the present invention are not adversely affected, various raw materials and additives may be used for the fine gel of the present invention, or the protein-containing sol-based food modifier containing the fine gel of the present invention. Although not particularly limited, for example, sugars such as sugar, soy sauce, salt, spices, powders such as matcha and cocoa, oils and fats such as chocolate and sesame oil, dairy products such as milk and skim milk powder, vinegar, Fruit juices, acidulants, pH adjusters, thickeners such as guar gum, emulsifiers, seasonings such as amino acids, high-intensity sweeteners, flavors, coloring agents, alcohols, preservatives, shelf life improvers, antioxidants, etc. No.

本発明における蛋白質含有ゾル状食品に使用される蛋白質は、通常のゾル状食品に使用されるものであって特に限定するものではないが、例えば、ゼラチン、卵由来、乳由来、豆由来、畜肉由来及び魚肉由来の蛋白質等からなる群より選ばれる少なくとも1種以上の蛋白質が挙げられる。
本発明における蛋白質含有ゾル状食品に使用される卵由来の蛋白質含有原料は、鶏卵が代表的であるが、特に限定するものではないが、例えば、鶉(ウズラ)、アヒル、鴨等の家禽、野禽その他食用になるいかなる卵であってよい。また、卵原料は、卵殻内にある或いは卵殻から分離された状態のいわゆる全卵は勿論、これを分割した卵黄や卵白であってもよい。また、これらの卵原料は、液状に限らず、それから得られる粉末状及び凍結状であってもよく、これら卵原料を殺菌或いは酵素反応などの処理等を施した加工卵、これらの混合物であってもよい。
The protein used in the protein-containing sol food according to the present invention is used in ordinary sol foods, and is not particularly limited. Examples thereof include gelatin, eggs, milk, beans, and meat. And at least one protein selected from the group consisting of proteins derived from fish meat and fish meat.
The egg-containing protein-containing raw material used for the protein-containing sol food according to the present invention is typically a chicken egg, but is not particularly limited. For example, poultry such as quail (quail), duck, duck, etc. It can be wild fowl or any other edible egg. In addition, the egg raw material may be not only so-called whole eggs in the eggshell or separated from the eggshell, but also egg yolk and egg white obtained by dividing the eggs. In addition, these egg raw materials are not limited to liquids, but may be powdered or frozen forms obtained therefrom. These egg raw materials are processed eggs obtained by subjecting the egg raw materials to treatment such as sterilization or enzymatic reaction, and mixtures thereof. You may.

本発明における蛋白質含有ゾル状食品に使用される乳由来の蛋白質含有原料は、牛乳が代表的であるが、特に限定するものではないが、例えば、山羊乳、羊乳等の獣乳であってよい。また、これらの乳原料は、液状に限らず、それから得られる全脂粉乳や脱脂粉乳等の粉末状であってもよく、これら乳原料より分離したカゼイン蛋白やホエー蛋白、更には、それらの乳原料に糖類を加え濃縮した全脂加糖練乳や脱脂加糖練乳等、各種乳製品であってもよい。   The milk-containing protein-containing raw material used in the protein-containing sol food according to the present invention is typically milk, but is not particularly limited, but includes, for example, goat milk and animal milk such as sheep milk. Good. In addition, these milk ingredients are not limited to liquids, and may be in the form of powder such as whole milk powder or skim milk powder obtained therefrom, and casein proteins and whey proteins separated from these milk ingredients, and further, those milk ingredients. Various dairy products such as condensed whole fat and defatted condensed milk obtained by adding saccharides to raw materials may be used.

本発明における蛋白質含有ゾル状食品に使用される豆由来の蛋白質含有原料は、大豆が代表的であるが、特に限定するものではないが、例えば、インゲン豆、緑豆、そら豆、えんどう豆、落花生等のマメ科植物の種子であってよい。また、これらの豆原料は、大豆から絞った液状の豆乳であってもよく、それから得られる全脂大豆粉や脱脂大豆粉等の粉末状であってもよく、これら大豆原料より分離した大豆蛋白等、各種豆製品であってもよい。   The protein-containing raw material derived from beans used in the protein-containing sol food of the present invention is typically soybean, but is not particularly limited. For example, kidney beans, mung beans, broad beans, peas, peanuts, peanuts And the like. Further, these soy materials may be liquid soymilk squeezed from soybeans, or may be in the form of powder such as full fat soybean powder or defatted soybean powder obtained therefrom, and soybean protein separated from these soybean materials. And various bean products.

本発明における蛋白質含有ゾル状食品に使用されるゼラチン原料は、牛や豚の骨や皮より抽出したものが代表的であるが、特に限定するものではないが、例えば、魚の鱗、ロバの皮等動物の皮膚や骨等より抽出したものであってよい。また、これらのゼラチン原料は、前駆体であるコラーゲンであってもよい。
本発明における蛋白質含有ゾル状食品に使用される畜肉由来の蛋白質含有原料は、牛肉、豚肉、鶏肉が代表的であるが、特に限定するものではないが、例えば、羊、馬、鹿、兎、猪、羊、熊等の動物の肉類であってよい。
The gelatin raw material used in the protein-containing sol food according to the present invention is typically extracted from bovine or pork bones or skin, but is not particularly limited, but includes, for example, fish scales and donkey skin. It may be extracted from the skin or bones of an animal. These gelatin raw materials may be collagen, which is a precursor.
The protein-containing raw material derived from animal meat used in the protein-containing sol food according to the present invention is typically beef, pork, or chicken, but is not particularly limited, for example, sheep, horse, deer, rabbit, It may be animal meat such as boars, sheep, and bears.

本発明における蛋白質含有ゾル状食品に使用される蛋白質の魚肉由来の蛋白質含有原料は、タラが代表的であるが、特に限定するものではないが、例えば、ホキ、タイ、イワシ、サケ、アジ、サバ、サンマ、秋刀魚等の魚類の肉類であってよい。また、タコ、イカ、貝類等の軟体動物類や、エビ、カニ等の甲殻類の肉類であってもよい。
これらの蛋白質含有原料及びゼラチン原料には、その特性(凝固性、起泡性、乳化性など)を失わない範囲で、糖類、食塩、調味料、pH調整剤等の混合物であってもよい。
The protein-containing raw material derived from the fish meat of the protein used in the protein-containing sol food according to the present invention is typically cod, but is not particularly limited, for example, hoki, tai, sardine, salmon, horse mackerel, It may be fish meat such as mackerel, saury, and swordfish. Also, it may be mollusks such as octopus, squid and shellfish, and crustacean meat such as shrimp and crab.
These protein-containing raw materials and gelatin raw materials may be a mixture of saccharides, salt, seasonings, pH adjusters, etc. as long as their properties (coagulability, foamability, emulsifying properties, etc.) are not lost.

本発明における蛋白質含有ゾル状食品は、特に限定するものではないが、例えば、焼プリンや、卵豆腐、茶碗蒸し、卵焼き、オムレツシート、カスタードソースなどの卵加工品類、ヨーグルトや、クリームチーズ、プロセスチーズ、ナチュラルチーズ、乳酸菌飲料などの乳製品類、豆腐や、高野豆腐、油揚げ、がんもどき、味噌などの大豆加工品類、ゼリー、プリン、ムース、ババロア、グミキャンディ、煮こごりなどのゼラチンで固めるデザートや惣菜類、ハンバーグ、ミートボール、肉団子、ミートパテ、チキンナゲット、ミートコロッケ、メンチカツ、焼売の具、餃子の具、肉まんの具、つくね、つみれ、ソーセージなどの畜肉加工品、はんぺん、つみれ、さつま揚げ、ちくわ、かまぼこなどの魚肉加工品が挙げられる。また、コンビニエンスストアで販売している、ラーメンやうどんなどのスープやつゆ類、キムチ鍋や豆乳鍋などの汁類、カレーや牛丼などの丼物の具材類、パスタソース類等、電子レンジで加熱して喫食する、ゼラチンで固めたメニュー類、更に、プリンシェイクドリンクや、ヨーグルトとバナナやアボガドなどの果物や野菜類を混ぜて砕いたシェイクドリンクなどの、上記の蛋白質含有ゾル状食品を原料として調理加工した、飲食品類も本発明の蛋白質含有ゾル状食品の例として挙げられる。   Although the protein-containing sol food of the present invention is not particularly limited, for example, baked pudding, egg tofu, chawanmushi, fried egg, omelet sheet, processed egg products such as custard sauce, yogurt, cream cheese, process cheese Dairy products such as natural cheese, lactobacillus drinks, tofu, soybean products such as Takano tofu, fried fish, ganmoji, miso, etc. And side dishes, hamburgers, meatballs, meatballs, meat pate, chicken nuggets, meat croquettes, menchikatsu, shredders, dumplings, meatballs, processed meat products such as tsukuni, tsumire, sausage, hanpen, tsumire, satsumaage, Fish processed products, such as chikuwa and kamaboko. Also, microwaves such as ramen and udon soups and soups sold at convenience stores, soups such as kimchi pots and soy milk pots, ingredients for bowls such as curry and beef bowl, pasta sauces, etc. The above protein-containing sol foods, such as menus hardened with gelatin, eaten by heating in, and shake shake drinks crushed by mixing fruits and vegetables such as pudding shake drink and yogurt with bananas and avocados Foods and beverages cooked and processed as a raw material are also examples of the protein-containing sol food of the present invention.

本発明品における蛋白質含有ゾル状食品用改質剤の蛋白質含有ゾル状食品への配合割合は、含有する微細なゲルの大きさ、微細なゲルに用いるゲル化剤の種類や含量、ゾル状食品に用いる蛋白質の種類や含量、対象とする蛋白質含有ゾル状食品の種類や水分量などに応じて適時調整することができるが、その上限値は、好ましくは蛋白質含有ゾル状食品100重量%に対して25.0重量%以下であり、より好ましくは15.0重量%以下、更に好ましくは10.0重量%以下、最も好ましくは5.0重量%以下である。また、その下限値は、好ましくは0.1重量%以上であり、更に好ましくは0.2重量%以上である。
以下、実施例及び比較例を挙げて本発明を具体的に説明するが、本発明はこれらに限定されるものではない。
The mixing ratio of the protein-containing sol-based food modifier to the protein-containing sol-based food in the product of the present invention is determined by the size of the fine gel to be contained, the type and content of the gelling agent used for the fine gel, and the sol-based food. It can be adjusted as appropriate according to the type and content of the protein used, the type and water content of the target protein-containing sol food, etc., but the upper limit is preferably based on 100% by weight of the protein-containing sol food. By weight is 25.0% by weight or less, more preferably 15.0% by weight or less, further preferably 10.0% by weight or less, and most preferably 5.0% by weight or less. The lower limit is preferably at least 0.1% by weight, more preferably at least 0.2% by weight.
Hereinafter, the present invention will be described specifically with reference to Examples and Comparative Examples, but the present invention is not limited thereto.

実施例1〜3、比較例1
表1に記載の配合割合で、ゲル化剤としてジェランガムを使用して、図1に記載の操作に従って、メジアン径の異なる微細なゲルを含有する本発明品1〜3及び比較品1を調製した。尚、クエン酸液は、クエン酸500gを水で溶解して全量が1Lとなるように調製した。
Examples 1 to 3, Comparative Example 1
Using gellan gum as a gelling agent at the compounding ratio shown in Table 1, in accordance with the operation shown in FIG. 1, inventive products 1 to 3 containing fine gels having different median diameters and comparative product 1 were prepared. . The citric acid solution was prepared by dissolving 500 g of citric acid in water so that the total amount was 1 L.

Figure 2020036584
Figure 2020036584

実施例4
表2に記載の配合割合で、ゲル化剤としてペクチンを使用して、図2に記載の操作に従って、本発明品4の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤を調製した。尚、乳酸液は、ムサシノ乳酸50(50%乳酸溶液)(株式会社武蔵野化学研究所製)を用いた。
Example 4
Using pectin as a gelling agent at the mixing ratio shown in Table 2, a protein-containing sol-like food modifier containing a fine gel of the product 4 of the present invention was prepared according to the operation shown in FIG. . The lactic acid solution used was Musashino lactic acid 50 (50% lactic acid solution) (manufactured by Musashino Chemical Laboratory Co., Ltd.).

Figure 2020036584
Figure 2020036584

実施例5
表3に記載の配合割合で、ゲル化剤としてペクチンを使用して、図3に記載の操作に従って、本発明品5の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤を調製した。尚、乳酸液は、ムサシノ乳酸50(50%乳酸溶液)(株式会社武蔵野化学研究所製)を用いた。
Example 5
Using pectin as a gelling agent in the mixing ratio shown in Table 3, a protein-containing sol-like food modifier containing a fine gel of product 5 of the present invention was prepared according to the operation shown in FIG. . The lactic acid solution used was Musashino lactic acid 50 (50% lactic acid solution) (manufactured by Musashino Chemical Laboratory Co., Ltd.).

Figure 2020036584
Figure 2020036584

実施例6
表4に記載の配合割合で、ゲル化剤として寒天を使用して、図4に記載の操作に従って、本発明品6の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤を調製した。
Example 6
A protein-containing sol-like food modifier containing a fine gel of product 6 of the present invention was prepared according to the operation shown in FIG. 4 using agar as a gelling agent at the compounding ratio shown in Table 4. .

Figure 2020036584
Figure 2020036584

実施例7
表5に記載の配合割合で、ゲル化剤としてアルギン酸ナトリウムを使用して、図5に記載の操作に従って、本発明品7の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤を調製した。
Example 7
Using sodium alginate as a gelling agent in the mixing ratio shown in Table 5, according to the operation shown in FIG. 5, a protein-containing sol-like food modifier containing a fine gel of product 7 of the present invention was prepared. did.

Figure 2020036584
Figure 2020036584

実施例8
表6に記載の配合割合で、ゲル化剤としてアルギン酸を使用して、図6に記載の操作に従って、本発明品8の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤を調製した。尚、クエン酸液は、クエン酸500gを水で溶解して全量が1Lとなるように調製した。
Example 8
Using alginic acid as a gelling agent at the mixing ratio shown in Table 6, a protein-containing sol food modifier containing a fine gel of product 8 of the present invention was prepared according to the operation shown in FIG. . The citric acid solution was prepared by dissolving 500 g of citric acid in water so that the total amount was 1 L.

Figure 2020036584
Figure 2020036584

実施例9
表7に記載の配合割合で、ゲル化剤としてこんにゃく粉を使用して、図7に記載の操作に従って、本発明品9の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤を調製した。
Example 9
Using konjac powder as a gelling agent in the mixing ratio shown in Table 7, according to the operation shown in FIG. 7, a protein-containing sol food modifier containing a fine gel of product 9 of the present invention was prepared. did.

Figure 2020036584
Figure 2020036584

実施例10、11
表8に記載の配合割合で、ゲル化剤としてカラギナンと他のゲル化剤類を混合したゲル化剤製剤を使用して、図8に記載の操作に従って、本発明品10及び11の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤を調製した。尚、クエン酸液は、クエン酸500gを水で溶解して全量が1Lとなるように調製した。
Examples 10 and 11
Using a gelling agent mixture of carrageenan and other gelling agents as the gelling agent in the mixing ratio shown in Table 8, the fine particles of the products 10 and 11 of the present invention were prepared according to the operation shown in FIG. A gel-containing protein-containing sol-based food modifier was prepared. The citric acid solution was prepared by dissolving 500 g of citric acid in water so that the total amount was 1 L.

Figure 2020036584
Figure 2020036584

実施例1〜11及び比較例1で調製した本発明品1〜11及び比較品1について、粒度分布測定装置(Beckman coulter社製、機種名:LS 13 320)にて測定したメジアン径の測定結果と、図1〜8に記載の破砕工程前のゲルに対して(それぞれ図中の(*)の工程で得られるゲル)、ゲルの50重量%の水を加え、ゲルの融解温度を測定した結果を、表9に記載する。
尚、実施例8で調製した本発明品8のゲルの融解温度は、実施例7で調製した本発明品7のゲルの融解温度と同様に、アルギン酸溶液にグルコノデルタラクトン溶液を投入し混合後、30分以上静置しゲル化したもので測定した。
Measurement results of the median diameter of the products 1 to 11 of the present invention and the comparative product 1 prepared in Examples 1 to 11 and Comparative Example 1 as measured by a particle size distribution measuring device (manufactured by Beckman coulter, model name: LS 13 320). To the gel before the crushing step described in FIGS. 1 to 8 (each obtained in the step of (*) in the figure), 50% by weight of water of the gel was added, and the melting temperature of the gel was measured. The results are shown in Table 9.
The melting temperature of the gel of the product 8 of the present invention prepared in Example 8 was the same as the melting temperature of the gel of the product 7 of the present invention prepared in Example 7, and the glucono delta lactone solution was added to the alginic acid solution and mixed. Thereafter, measurement was carried out on a gel that was allowed to stand for 30 minutes or more.

Figure 2020036584
Figure 2020036584

試験例1
実施例1〜11及び比較例1で調製した本発明品1〜11及び比較品1について、表10に記載の配合割合で、図9に記載の操作に従って、試験品1〜12の卵蛋白質を加熱変性させた焼プリンを調製した。また対照として、表10に記載の配合割合で、本発明品及び比較品が無添加の対照品1の焼プリンを、図9に記載の操作に従って調製した。
Test example 1
For the inventive products 1 to 11 and the comparative product 1 prepared in Examples 1 to 11 and Comparative Example 1, the egg proteins of the test products 1 to 12 were prepared according to the operations shown in FIG. A heat-denatured baked pudding was prepared. As a control, a baked pudding of Control product 1 in which the product of the present invention and the comparative product were not added was prepared according to the operation shown in FIG.

Figure 2020036584
Figure 2020036584

試験例1で調製した焼プリンについて、以下の評価を行った。
<ゲル強度>
冷蔵庫で1日保存した焼プリンのゲル強度について、レオメーター(レオテック社製)を使用して、下記の測定条件で、プランジャーがプリン表面から1.6mm押下げた時の荷重を測定した。
プランジャー:直径20mmの円板状
上昇速度:6.0cm/分
The following evaluation was performed on the baked pudding prepared in Test Example 1.
<Gel strength>
The gel strength of the baked pudding stored in the refrigerator for one day was measured using a rheometer (manufactured by Leotech) under the following measurement conditions when the plunger pressed down 1.6 mm from the pudding surface.
Plunger: Disc shape with a diameter of 20 mm Ascending speed: 6.0 cm / min

<保形性>
冷蔵庫で1日保存した焼プリンの保形性について、焼プリンのカップを逆さまにして、プリンを皿に取り出して、冷蔵庫で2時間保存し、プリン形状の沈み程度をノギスで測定し、以下の基準で評価を行った。
◎:プリン形状の沈みが2mm未満で、保形性が非常に良好。
○:プリン形状の沈みが2〜5mm未満で、保形性が良好。
△:プリン形状の沈みが5〜10mm未満で、保形性がやや悪い。
▲:プリン形状の沈みが10mm以上で、保形性が悪い。
×:プリン形状が無く、保形性が無い。
<Shape retention>
For the shape retention of the baked pudding stored for 1 day in the refrigerator, turn the baked pudding cup upside down, take out the pudding to a dish, store in the refrigerator for 2 hours, measure the degree of sinking of the pudding shape with a vernier caliper, The evaluation was performed based on criteria.
:: Sink of pudding shape was less than 2 mm, and shape retention was very good.
:: The swelling of the pudding is less than 2 to 5 mm, and the shape retention is good.
Δ: The swelling of the pudding shape was less than 5 to 10 mm, and the shape retention was somewhat poor.
▲: The swelling of the pudding shape was 10 mm or more, and the shape retention was poor.
×: No pudding shape and no shape retention.

<粘質様食感と口どけ>
冷蔵庫で1日保存した焼プリンの粘質様食感と口どけについて、熟練したパネラー5名による官能評価を行った。対照品1の粘質様食感と口どけを基準(評点:0)として、以下に示す7段階の点数評価を行い、その平均値を算出した。
+3点…粘質様食感が全く無く、口どけが非常に良好。
+2点…粘質様食感が殆ど無く、口どけが良好。
+1点…粘質様食感が弱く、口どけがやや良好。
0点…粘質様食感と口どけとも、対照品1と変わらない。
−1点…粘質様食感がやや強く、口どけがやや悪い。
−2点…粘質様食感が強く、口どけが悪い。
−3点…粘質様食感が非常に強く、口どけが非常に悪い。
<Viscous texture and mouthfeel>
The sensory evaluation was performed by five skilled panelists on the sticky texture and mouthfeel of the baked pudding stored in the refrigerator for one day. Based on the sticky-like texture and mouthfeel of the control product 1 as a reference (score: 0), the following seven-point evaluation was performed, and the average value was calculated.
+3 points: There is no sticky-like texture at all, and the taste is very good.
+2 points: Almost no sticky texture and good mouthfeel.
+1 point: The sticky texture is weak, and the mouthfeel is slightly good.
0 point: No difference from control product 1 in terms of the sticky texture and mouthfeel.
-1 point: Sticky-like texture is slightly strong, and mouthfeel is somewhat poor.
-2 points: Strong sticky texture and poor mouthfeel.
-3 points: Mouth-like texture is very strong, and mouthfeel is very poor.

<風味>
冷蔵庫で1日保存した焼プリンの風味について、熟練したパネラー5名による官能評価を行った。対照品1のカスタード風味を基準(評点:0)として、以下に示す7段階の点数評価を行い、その平均値を算出した。
+3点…カスタード風味が非常に強い。
+2点…カスタード風味が強い。
+1点…カスタード風味がやや強い。
0点…カスタード風味が対照品1と変わらない。
−1点…カスタード風味がやや弱い。
−2点…カスタード風味が弱い。
−3点…カスタード風味が非常に弱く、全く味が無い。
試験例1の評価結果を、表11に示した。
<Flavor>
The sensory evaluation was performed by five skilled panelists on the flavor of the baked pudding stored in the refrigerator for one day. Using the custard flavor of Control 1 as a reference (score: 0), the following seven-point score evaluation was performed, and the average value was calculated.
+3 points: Very strong custard flavor.
+2 points: Strong custard flavor.
+1 point: Custard flavor is slightly strong.
0 point: Custard flavor is not different from control product 1.
-1 point: Custard flavor is slightly weak.
-2 points ... The custard flavor is weak.
-3 points: The custard flavor is very weak and has no taste.
Table 11 shows the evaluation results of Test Example 1.

Figure 2020036584
Figure 2020036584

表11の結果より、メジアン径が500μm以下の微細なゲルを含有する本発明品1〜11を添加した試験品1〜11は、ゲル強度が対照品1とほぼ同様で、保形性も良好であり、粘質様食感が弱く口どけは良好であり、風味も強い焼プリンであるのに対し、メジアン径が500μm以上の微細なゲルを含有する比較品1を添加した試験品12は、対照品1と同様のゲル強度で保形性も良好であるが、粘質様食感と口どけ及び風味とも、対照品1と殆ど変わらない焼プリンであった。   From the results in Table 11, the test articles 1 to 11 to which the inventive articles 1 to 11 containing the fine gel having a median diameter of 500 µm or less were added, the gel strength was almost the same as the control article 1, and the shape retention was good. The test product 12 to which the comparative product 1 containing a fine gel having a median diameter of 500 μm or more was added to a baked pudding having a weak sticky-like texture and a good mouthfeel and a strong flavor. The baked pudding had a gel strength similar to that of the control product 1 and good shape retention, but was almost the same as the control product 1 in terms of the sticky texture, mouth feel and flavor.

以上のことから、メジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤は、卵蛋白質を変性させた焼プリンにおいて、卵蛋白質の配合割合はそのままで、変性した卵蛋白質による保形性を維持したまま、変性した卵蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   From the above, the protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less is a modified egg in a baked pudding obtained by denaturing an egg protein, while keeping the mixing ratio of the egg protein unchanged. While maintaining the shape-retaining property of the protein, the mucous-like texture peculiar to the denatured egg protein was reduced, and the mouthfeel and flavor were improved.

試験例2
表12に記載の配合割合で、実施例1で調製した本発明品1の添加量を変えて、図9に記載の操作に従って試験品1と同様の方法で、試験品13〜18の焼プリンを調製した。また対照として、表12に記載の配合割合で、図10に記載の操作に従って、本発明品1のゲル化剤として使用したジェランガム及び塩化カルシウムをプリン液に溶解し冷却後に粉砕処理して加熱した対照品2の焼プリンを調製した。
また、試験例2で調製した焼プリンについて、試験例1と同様の評価を行った。
試験例2の評価結果を、表13に示した。
Test example 2
By changing the addition amount of the product 1 of the present invention prepared in Example 1 at the compounding ratios shown in Table 12, according to the operation shown in FIG. Was prepared. As a control, gellan gum and calcium chloride used as the gelling agent of the product 1 of the present invention were dissolved in a purine solution, cooled, pulverized, heated and heated according to the operation shown in FIG. 10 in the mixing ratio shown in Table 12. A baked pudding of Control 2 was prepared.
The same evaluation as in Test Example 1 was performed on the baked pudding prepared in Test Example 2.
Table 13 shows the evaluation results of Test Example 2.

Figure 2020036584
Figure 2020036584

Figure 2020036584
Figure 2020036584

表13の結果より、本発明品1を0.1%添加した試験品13は、粘質様食感が弱く口どけも良好になり、風味も強くなった。本発明品1の添加量が増加するに従い、粘質様食感は更に弱くなり口どけも更に良好となり、添加量が3.0%と5.0%の試験品17と試験品18が最も粘質様食感が弱くなった。風味については、添加量が2.0%の試験品16が最も強く、添加量が3.0%以上になると逆に微細なゲルの風味の影響により、次第に弱くなった。ゲル強度及び保形性は、本発明品を5.0%まで添加しても、試験例1の対照品1と同様な結果であった。   From the results shown in Table 13, the test product 13 containing 0.1% of the product 1 of the present invention had a weak sticky-like texture, a good mouthfeel, and a strong flavor. As the addition amount of the product 1 of the present invention increases, the sticky texture becomes weaker and the mouthfeel becomes better, and the test products 17 and 18 with the addition amounts of 3.0% and 5.0% are the most. The sticky texture became weak. As for the flavor, the test article 16 with the added amount of 2.0% was the strongest, and when the added amount became 3.0% or more, the flavor gradually became weaker due to the influence of the fine gel flavor. The gel strength and shape retention were the same as those of the control product 1 of Test Example 1 even when the product of the present invention was added up to 5.0%.

一方、ゲル化剤であるジェランガムをプリン液に添加後、微細なゲル状(ゾル状)として加熱変性させた対照品2は、粘質様食感の低減や口どけ及び風味の改善効果は殆ど無かった。尚、対照品2と試験品18のジェランガム含量は同じであることから、予め調製されたメジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤をプリン液に添加し加熱することで、卵蛋白質の配合割合はそのままで、変性した卵蛋白質による保形性を維持したまま、変性した卵蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   On the other hand, the control product 2 in which gellan gum, which is a gelling agent, was added to the pudding solution and then denatured by heating as a fine gel (sol), showed almost no effect of reducing the mucous-like texture and improving the mouthfeel and flavor. There was no. Since the gellan gum content of the control product 2 and the test product 18 were the same, a protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less prepared in advance was added to the pudding solution. By heating, the mixture ratio of the egg protein was kept as it was, the shape-retaining property of the denatured egg protein was maintained, the sticky-like texture peculiar to the denatured egg protein was reduced, and the mouthfeel and flavor were improved.

試験例3
実施例1〜11及び比較例1で調製した本発明品1〜11及び比較品1について、表14に記載の配合割合で、図11に記載の操作に従って、試験品19〜30の乳蛋白質を発酵変性させたプレーンヨーグルトを調製した。また対照として、表14に記載の配合割合で、本発明品及び比較品が無添加の対照品3のプレーンヨーグルトを、図11に記載の操作に従って、調製した。
Test example 3
With respect to the inventive products 1 to 11 and the comparative product 1 prepared in the examples 1 to 11 and the comparative example 1, the milk proteins of the test products 19 to 30 were prepared according to the operation shown in FIG. Fermented and denatured plain yogurt was prepared. In addition, as a control, plain yogurt of control product 3 in which the product of the present invention and the comparative product were not added was prepared according to the operation shown in FIG.

Figure 2020036584
Figure 2020036584

試験例3で調製したプレーンヨーグルトについて、以下の評価を行った。
<ゲル強度>
冷蔵庫で1日保存したプレーンヨーグルトのゲル強度について、レオメーター(レオテック社製)を使用して、下記の測定条件で、プランジャーがヨーグルト表面から1.6mm押下げた時の荷重を測定した。
プランジャー:直径20mmの円板状
上昇速度:6.0cm/分
The following evaluation was performed on the plain yogurt prepared in Test Example 3.
<Gel strength>
The gel strength of plain yogurt stored in a refrigerator for one day was measured using a rheometer (manufactured by Leotech) under the following measurement conditions when the plunger was pushed down 1.6 mm from the yogurt surface.
Plunger: Disc shape with a diameter of 20 mm Ascending speed: 6.0 cm / min

<保形性>
冷蔵庫で1日保存したプレーンヨーグルトの保形性について、ヨーグルトのカップを逆さまにして、ヨーグルトを皿に取り出して、冷蔵庫で2時間保存し、ヨーグルト形状の沈み程度をノギスで測定し、以下の基準で評価を行った。
◎:ヨーグルト形状の沈みが2mm未満で、保形性が非常に良好。
○:ヨーグルト形状の沈みが2〜5mm未満で、保形性が良好。
△:ヨーグルト形状の沈みが5〜10mm未満で、保形性がやや悪い。
▲:ヨーグルト形状の沈みが10mm以上で、保形性が悪い。
×:ヨーグルト形状が無く、保形性が無い。
<Shape retention>
For the shape retention of plain yogurt stored in the refrigerator for one day, turn the yogurt cup upside down, remove the yogurt into a dish, store in the refrigerator for 2 hours, measure the degree of sinking of the yogurt shape with a caliper, and Was evaluated.
A: Yogurt-shaped settling is less than 2 mm, and shape retention is very good.
:: Yogurt-shaped settling is less than 2 to 5 mm, and shape retention is good.
Δ: Yogurt-shaped settling was less than 5 to 10 mm, and shape retention was somewhat poor.
:: Yogurt-shaped sinkage of 10 mm or more, poor shape retention.
×: No yogurt shape, no shape retention.

<pH>
冷蔵庫で1日保存したプレーンヨーグルトのpHについて、pHメーター(堀場製作所社製)を使用して測定し、発酵の進行程度の評価を行った。
<粘質様食感と口どけ>
冷蔵庫で1日保存したプレーンヨーグルトの粘質様食感と口どけについて、熟練したパネラー5名による官能評価を行った。対照品3の粘質様食感と口どけを基準(評点:0)として、以下に示す7段階の点数評価を行い、その平均値を算出した。
+3点…粘質様食感が全く無く、口どけが非常に良好。
+2点…粘質様食感が殆ど無く、口どけが良好。
+1点…粘質様食感が弱く、口どけがやや良好。
0点…粘質様食感と口どけとも、対照品3と変わらない。
−1点…粘質様食感がやや強く、口どけがやや悪い。
−2点…粘質様食感が強く、口どけが悪い。
−3点…粘質様食感が非常に強く、口どけが非常に悪い。
<PH>
The pH of plain yogurt stored in a refrigerator for one day was measured using a pH meter (manufactured by Horiba, Ltd.) to evaluate the degree of progress of fermentation.
<Viscous texture and mouthfeel>
Sensory evaluation was performed by five skilled panelists on the sticky texture and mouthfeel of the plain yogurt stored in the refrigerator for one day. Using the sticky-like texture and mouthfeel of the control product 3 as criteria (rating: 0), the following seven levels of score evaluation were performed, and the average value was calculated.
+3 points: There is no sticky-like texture at all, and the taste is very good.
+2 points: Almost no sticky texture and good mouthfeel.
+1 point: The sticky texture is weak, and the mouthfeel is slightly good.
0 point: No difference from control product 3 with respect to the sticky texture and mouthfeel.
-1 point: Sticky-like texture is slightly strong, and mouthfeel is somewhat poor.
-2 points: Strong sticky texture and poor mouthfeel.
-3 points: Mouth-like texture is very strong, and mouthfeel is very poor.

<風味>
冷蔵庫で1日保存したプレーンヨーグルトの風味について、熟練したパネラー5名による官能評価を行った。対照品3のヨーグルト風味を基準(評点:0)として、以下に示す7段階の点数評価を行い、その平均値を算出した。
+3点…ヨーグルト風味が非常に強い。
+2点…ヨーグルト風味が強い。
+1点…ヨーグルト風味がやや強い。
0点…ヨーグルト風味が対照品3と変わらない。
−1点…ヨーグルト風味がやや弱い。
−2点…ヨーグルト風味が弱い。
−3点…ヨーグルト風味が非常に弱く、全く味が無い。
試験例3の評価結果を、表15に示した。
<Flavor>
The sensory evaluation of the flavor of plain yogurt stored in the refrigerator for one day was performed by five skilled panelists. Using the yogurt flavor of Control 3 as a reference (score: 0), the following seven levels of score evaluation were performed, and the average value was calculated.
+3 points: Very strong yogurt flavor.
+2 points: Strong yogurt flavor.
+1 point: Yogurt flavor is slightly strong.
0 point: Yogurt flavor is not different from control product 3.
-1 point: Yogurt flavor is slightly weak.
-2 points ... The yogurt flavor is weak.
-3 points: The yogurt flavor is very weak and has no taste.
Table 15 shows the evaluation results of Test Example 3.

Figure 2020036584
Figure 2020036584

表15の結果より、メジアン径が500μm以下の微細なゲルを含有する本発明品1〜11を添加した試験品19〜29は、ゲル強度が対照品3とほぼ同様で、保形性も良好であり、pHも対照品3と同様で発酵阻害は無く、粘質様食感が弱く口どけは良好であり、風味も強いプレーンヨーグルトであるのに対し、メジアン径が500μm以上の微細なゲルを含有する比較品1を添加した試験品30は、対照品3と同様のゲル強度で保形性も良好で発酵阻害も無いが、粘質様食感と口どけ及び風味とも、対照品3と殆ど変わらないプレーンヨーグルトであった。   From the results in Table 15, the test products 19 to 29 to which the products 1 to 11 of the present invention containing a fine gel having a median diameter of 500 µm or less were added, the gel strength was almost the same as the control product 3, and the shape retention was good. The pH is the same as that of the control product 3, and there is no fermentation inhibition, the mucous-like texture is weak, the mouthfeel is good, and the taste is plain yogurt, whereas the fine gel having a median diameter of 500 μm or more is obtained. The test product 30 to which the comparative product 1 containing was added had the same gel strength and good shape retention and no fermentation inhibition as the control product 3, but had a viscous-like texture, mouthfeel and flavor, and the control product 3 It was plain yogurt that was almost the same.

以上のことから、メジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤は、乳蛋白質を変性させたプレーンヨーグルトにおいて、乳蛋白質の配合割合はそのままで、変性した乳蛋白質による保形性を維持したまま、変性した乳蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   From the above, the protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less is a modified yolk in plain yogurt in which milk protein has been denatured, the milk protein proportion remains unchanged, While maintaining the shape-retaining property of the protein, the mucous-like texture peculiar to the denatured milk protein was reduced, and the mouthfeel and flavor were improved.

試験例4
表16に記載の配合割合で、実施例1で調製した本発明品1の添加量を変えて、図11に記載の操作に従って試験品19と同様の方法で、試験品31〜36のプレーンヨーグルトを調製した。また対照として、表16に記載の配合割合で、図12に記載の操作に従って、本発明品1のゲル化剤として使用したジェランガム及び塩化カルシウムをヨーグルト液に溶解し冷却後に粉砕処理して発酵した対照品4のプレーンヨーグルトを調製した。
また、試験例4で調製したプレーンヨーグルトについて、試験例3と同様の評価を行った。
試験例4の評価結果を、表17に示した。
Test example 4
Plain yogurt of test products 31 to 36 was prepared in the same manner as test product 19 according to the operation shown in FIG. 11 by changing the addition amount of product 1 of the present invention prepared in Example 1 at the mixing ratio shown in Table 16. Was prepared. As a control, gellan gum and calcium chloride used as the gelling agent of the product 1 of the present invention were dissolved in a yogurt solution, cooled, pulverized, and fermented according to the operation shown in FIG. A control product 4 plain yogurt was prepared.
The same evaluation as in Test Example 3 was performed on the plain yogurt prepared in Test Example 4.
Table 17 shows the evaluation results of Test Example 4.

Figure 2020036584
Figure 2020036584

Figure 2020036584
Figure 2020036584

表17の結果より、本発明品1を0.1%添加した試験品31は、粘質様食感が弱く口どけも良好になり、風味も強くなった。本発明品1の添加量が増加するに従い、粘質様食感は更に弱くなり口どけも更に良好となり、添加量が3.0%と5.0%の試験品35と試験品36が最も粘質様食感が弱くなった。風味についても、添加量が3.0%と5.0%の試験品35と試験品36が最も強く、粘質様食感と同様の結果であった。ゲル強度及び保形性とpHは、本発明品を5.0%まで添加しても、試験例3の対照品3と同様な結果であった。   From the results shown in Table 17, the test product 31 to which the product 1 of the present invention was added at 0.1% had a weak sticky-like texture, a good mouthfeel, and a strong flavor. As the addition amount of the product 1 of the present invention increases, the sticky texture becomes weaker and the mouthfeel becomes better, and the test products 35 and 36 with the addition amounts of 3.0% and 5.0% are the most. The sticky texture became weak. As for the flavor, the test products 35 and 36 with the added amounts of 3.0% and 5.0% were the strongest, and the results were similar to the viscous texture. The gel strength, shape retention and pH were the same as those of the control product 3 of Test Example 3 even when the product of the present invention was added to 5.0%.

一方、ゲル化剤であるジェランガムをヨーグルト液に添加後、微細なゲル状(ゾル状)として発酵した対照品4は、粘質様食感の低減や口どけ及び風味の改善効果は殆ど無かった。尚、対照品4と試験品36のジェランガム含量は同じであることから、予め調製されたメジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤をヨーグルト液に添加し発酵することで、乳蛋白質の添加量はそのままで、変性した乳蛋白質による保形性を維持したまま、変性した乳蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   On the other hand, after adding gellan gum, which is a gelling agent, to the yogurt solution, the control product 4, which was fermented as a fine gel (sol), had almost no effect of reducing the mucous-like texture, improving mouthfeel and flavor. . Since the gellan gum content of the control product 4 and the test product 36 is the same, a protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less prepared in advance was added to the yogurt solution. The fermentation reduced the sticky-like texture peculiar to the denatured milk protein while maintaining the shape retention property of the denatured milk protein while maintaining the added amount of milk protein, and improved the mouthfeel and flavor.

試験例5
実施例1〜11及び比較例1で調製した本発明品1〜11及び比較品1について、表18に記載の配合割合で、図13に記載の操作に従って、試験品37〜48の充填豆腐を調製した。また対照として、表18に記載の配合割合で、本発明品及び比較品が無添加の対照品5の充填豆腐を、図13に記載の操作に従って、調製した。
Test example 5
For the inventive products 1 to 11 and the comparative product 1 prepared in the examples 1 to 11 and the comparative example 1, the filling tofu of the test products 37 to 48 was prepared according to the operation shown in FIG. Prepared. As a control, filled tofu of the control product 5 in which the product of the present invention and the comparative product were not added was prepared according to the operation shown in FIG.

Figure 2020036584
Figure 2020036584

試験例5で調製した充填豆腐について、以下の評価を行った。
<ゲル強度>
冷蔵庫で1日保存した充填豆腐のゲル強度について、レオメーター(レオテック社製)を使用して、下記の測定条件で、プランジャーが豆腐表面から2.4mm押下げた時の荷重を測定した。
プランジャー:直径20mmの円板状
上昇速度:6.0cm/分
The following evaluation was performed on the packed tofu prepared in Test Example 5.
<Gel strength>
Regarding the gel strength of the packed tofu stored in the refrigerator for one day, the load when the plunger was pushed down 2.4 mm from the tofu surface was measured using a rheometer (manufactured by Leotech) under the following measurement conditions.
Plunger: Disc shape with a diameter of 20 mm Ascending speed: 6.0 cm / min

<保形性>
冷蔵庫で1日保存した充填豆腐の保形性について、豆腐のカップを逆さまにして、豆腐を皿に取り出して、冷蔵庫で2時間保存し、豆腐形状の沈み程度をノギスで測定し、以下の基準で評価を行った。
◎:豆腐形状の沈みが2mm未満で、保形性が非常に良好。
○:豆腐形状の沈みが2〜5mm未満で、保形性が良好。
△:豆腐形状の沈みが5〜10mm未満で、保形性がやや悪い。
▲:豆腐形状の沈みが10mm以上で、保形性が悪い。
×:豆腐形状が無く、保形性が無い。
<Shape retention>
Regarding the shape retention of the filled tofu stored in the refrigerator for 1 day, turn the tofu cup upside down, take out the tofu in a dish, store it in the refrigerator for 2 hours, measure the degree of sinking of the tofu shape with a vernier caliper, Was evaluated.
A: Tofu-shaped settling is less than 2 mm, and shape retention is very good.
:: Tofu-shaped settling is less than 2 to 5 mm, and shape retention is good.
Δ: Tofu-shaped settling was less than 5 to 10 mm, and shape retention was somewhat poor.
:: Tofu-shaped sink of 10 mm or more, poor shape retention.
×: No tofu shape and no shape retention.

<粘質様食感と口どけ>
冷蔵庫で1日保存した充填豆腐の粘質様食感と口どけについて、熟練したパネラー5名による官能評価を行った。対照品5の粘質様食感と口どけを基準(評点:0)として、以下に示す7段階の点数評価を行い、その平均値を算出した。
+3点…粘質様食感が全く無く、口どけが非常に良好。
+2点…粘質様食感が殆ど無く、口どけが良好。
+1点…粘質様食感が弱く、口どけがやや良好。
0点…粘質様食感と口どけとも、対照品5と変わらない。
−1点…粘質様食感がやや強く、口どけがやや悪い。
−2点…粘質様食感が強く、口どけが悪い。
−3点…粘質様食感が非常に強く、口どけが非常に悪い。
<Viscous texture and mouthfeel>
Sensory evaluation was performed by five skilled panelists on the sticky texture and mouthfeel of the packed tofu stored in the refrigerator for one day. Based on the sticky-like texture and mouthfeel of the control product 5 as a reference (score: 0), the following seven-point scoring was performed, and the average value was calculated.
+3 points: There is no sticky-like texture at all, and the taste is very good.
+2 points: Almost no sticky texture and good mouthfeel.
+1 point: The sticky texture is weak, and the mouthfeel is slightly good.
0 point: No difference from control product 5 in terms of the sticky texture and mouthfeel.
-1 point: Sticky-like texture is slightly strong, and mouthfeel is somewhat poor.
-2 points: Strong sticky texture and poor mouthfeel.
-3 points: Mouth-like texture is very strong, and mouthfeel is very poor.

<風味>
冷蔵庫で1日保存した充填豆腐の風味について、熟練したパネラー5名による官能評価を行った。対照品5の豆腐風味を基準(評点:0)として、以下に示す7段階の点数評価を行い、その平均値を算出した。
+3点…豆腐風味が非常に強い。
+2点…豆腐風味が強い。
+1点…豆腐風味がやや強い。
0点…豆腐風味が対照品5と変わらない。
−1点…豆腐風味がやや弱い。
−2点…豆腐風味が弱い。
−3点…豆腐風味が非常に弱く、全く味が無い。
試験例5の評価結果を、表19に示した。
<Flavor>
The flavor of the packed tofu stored in the refrigerator for one day was subjected to a sensory evaluation by five skilled panelists. Based on the tofu flavor of the control product 5 as a reference (score: 0), the following seven-point score evaluation was performed, and the average value was calculated.
+3 points: Very strong tofu flavor.
+2 points: Strong tofu flavor.
+1 point: Tofu flavor is slightly strong.
0 point: Tofu flavor is not different from control product 5.
-1 point: Tofu flavor is slightly weak.
-2 points: Tofu flavor is weak.
-3 points: The tofu flavor is very weak and has no taste.
Table 19 shows the evaluation results of Test Example 5.

Figure 2020036584
Figure 2020036584

表19の結果より、メジアン径が500μm以下の微細なゲルを含有する本発明品1〜11を添加した試験品37〜47は、ゲル強度が対照品5とほぼ同様で、保形性も良好であり、粘質様食感が弱く口どけは良好であり、風味も強い充填豆腐であるのに対し、メジアン径が500μm以上の微細なゲルを含有する比較品1を添加した試験品48は、対照品5よりゲル強度はやや弱く、保形性もやや悪くなり、粘質様食感と口どけ及び風味とも、対照品5と殆ど変わらない充填豆腐であった。   From the results in Table 19, the test articles 37 to 47 to which the inventive articles 1 to 11 containing the fine gel having a median diameter of 500 µm or less were added, the gel strength was almost the same as the control article 5, and the shape retention was good. The test product 48 to which the comparative product 1 containing a fine gel having a median diameter of 500 μm or more was added to the packed tofu having a weak sticky-like texture, a good mouthfeel, and a strong flavor. The gel strength was slightly weaker than that of the control product 5, and the shape retention was slightly inferior, and the filled tofu was almost the same as the control product 5 in terms of the sticky texture, mouthfeel and flavor.

以上のことから、メジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤は、大豆蛋白質を変性させた充填豆腐において、大豆蛋白質の配合割合はそのままで、変性した大豆蛋白質による保形性を維持したまま、変性した大豆蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   From the above, the protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less is the modified soybean in the packed soybean protein-modified tofu with the soybean protein proportion unchanged. While maintaining the shape-retaining property of the protein, the sticky texture unique to the denatured soybean protein was reduced, and the mouthfeel and flavor were improved.

試験例6
表20に記載の配合割合で、実施例1で調製した本発明品1の添加量を変えて、図13に記載の操作に従って試験品37と同様の方法で、試験品49〜54の充填豆腐を調製した。また対照として、表20に記載の配合割合で、図14に記載の操作に従って、本発明品1のゲル化剤として使用したジェランガム及び塩化カルシウムを豆乳に溶解し冷却後に粉砕処理してにがりを加え加熱した対照品6の充填豆腐を調製した。
また、試験例6で調製した充填豆腐について、試験例5と同様の評価を行った。
試験例6の評価結果を、表21に示した。
Test example 6
The amount of the product 1 of the present invention prepared in Example 1 was changed at the mixing ratio shown in Table 20, and the filled tofu of the test products 49 to 54 was prepared in the same manner as the test product 37 according to the operation shown in FIG. Was prepared. As a control, gellan gum and calcium chloride used as the gelling agent of the product 1 of the present invention were dissolved in soymilk, cooled, pulverized, and added with bittern according to the operation shown in FIG. 14 in the mixing ratio shown in Table 20. A packed tofu of the heated control product 6 was prepared.
The same evaluation as in Test Example 5 was performed on the packed tofu prepared in Test Example 6.
Table 21 shows the evaluation results of Test Example 6.

Figure 2020036584
Figure 2020036584

Figure 2020036584
Figure 2020036584

表21の結果より、本発明品1を0.1%添加した試験品49は、粘質様食感が弱く口どけも良好になり、風味も強くなった。本発明品1の添加量が増加するに従い、粘質様食感は更に弱くなり口どけも更に良好となり、添加量が2.0%の試験品52が最も粘質様食感が弱く、添加量が3.0%以上になると、逆に粘質様食感はやや強く、口どけはやや悪くなった。風味についても、添加量が2.0%の試験品52が最も強く、添加量が3.0%以上になると逆に微細なゲルの風味の影響により、次第に弱くなり、粘質様食感と同様の結果であった。ゲル強度及び保形性は、本発明品を5.0%まで添加しても、試験例5の対照品5と同様な結果であった。   From the results shown in Table 21, the test product 49 containing 0.1% of the product 1 of the present invention had a weak sticky-like texture, a good mouthfeel, and a strong flavor. As the addition amount of the product 1 of the present invention increases, the sticky texture is further weakened and the mouthfeel is further improved, and the test product 52 having an addition amount of 2.0% has the weakest sticky texture. Conversely, when the amount was 3.0% or more, the sticky texture was rather strong and the mouthfeel was slightly worse. As for the flavor, the test product 52 with the added amount of 2.0% is the strongest, and when the added amount is 3.0% or more, on the contrary, it gradually becomes weaker due to the influence of the fine gel flavor, and has a sticky texture. Similar results were obtained. The gel strength and the shape retention were the same as those of the control product 5 of Test Example 5 even when the product of the present invention was added up to 5.0%.

一方、ゲル化剤であるジェランガムを豆乳に添加後、微細なゲル状(ゾル状)としにがりを加え加熱した対照品6は、粘質様食感の低減や口どけ及び風味の改善効果は殆ど無かった。尚、対照品6と試験品54のジェランガム含量は同じであることから、予め調製されたメジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤を豆乳に添加しにがりを加え加熱することで、大豆蛋白質の添加量はそのままで、変性した大豆蛋白質による保形性を維持したまま、変性した大豆蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   On the other hand, after adding gellan gum, which is a gelling agent, to soymilk, and then heating it with a fine gel (sol-like) bittern, the control product 6 has almost no effect of reducing the sticky-like texture and improving the mouthfeel and flavor. There was no. Since the gellan gum content of the control product 6 and the test product 54 is the same, a protein-containing sol-based food modifier containing a fine gel having a median diameter of 500 μm or less prepared in advance is added to soymilk. By adding and heating, the amount of soy protein added remains unchanged, while maintaining the shape retention of the denatured soy protein, reducing the sticky texture of the denatured soy protein, improving mouthfeel and flavor did.

試験例7
実施例1〜11及び比較例1で調製した本発明品1〜11及び比較品1について、表22に記載の配合割合で、図15に記載の操作に従って、試験品55〜66のゼラチンで固めた麺つゆを調製した。また対照として、表22に記載の配合割合で、本発明品及び比較品が無添加の対照品7のゼラチンで固めた麺つゆを、図15に記載の操作に従って、調製した。
Test example 7
Inventive products 1 to 11 and comparative product 1 prepared in Examples 1 to 11 and Comparative Example 1 were hardened with gelatin of test products 55 to 66 in accordance with the operation shown in FIG. A noodle soup was prepared. As a control, a noodle soup solidified with gelatin of a control product 7 containing no product of the present invention and a comparative product in the mixing ratio shown in Table 22 was prepared according to the operation shown in FIG.

Figure 2020036584
Figure 2020036584

試験例7で調製したゼラチンで固めた麺つゆについて、以下の評価を行った。
<ゲル強度>
冷蔵庫で1晩保存後、10℃の恒温槽に約2時間静置したゼラチンで固めた麺つゆについて、樹脂製円筒型カップ(上面直径:70mm、底面直径:42mm、高さ:57mm)に満量充填したゼラチンで固めた麺つゆを、レオメーター(レオテック社製)を使用して、下記の測定条件で、プランジャーがゼラチンで固めた麺つゆ表面から4mm押下げた時の荷重を測定した。
プランジャー:直径20mmの円板状
上昇速度:6.0cm/分
The following evaluation was performed on the noodle soup solidified with gelatin prepared in Test Example 7.
<Gel strength>
After storing overnight in a refrigerator, the noodle soup solidified with gelatin, which was allowed to stand in a thermostat at 10 ° C. for about 2 hours, was filled in a cylindrical cup made of resin (top diameter: 70 mm, bottom diameter: 42 mm, height: 57 mm). Using a rheometer (manufactured by Leotech Co.), the load when the plunger pressed down 4 mm from the surface of the noodle soup solidified with gelatin was measured using a rheometer (manufactured by Leotech) under the following conditions. .
Plunger: Disc shape with a diameter of 20 mm Ascending speed: 6.0 cm / min

<保形性と沈み込み>
冷蔵庫で1晩保存したゼラチンで固めた麺つゆを約1cm角前後にスプーンでクラッシュし、専用容器に400g充填した上に、茹で蕎麦160gを均等に載せて冷蔵庫で保存し、24時間後のゼラチンで固めた麺つゆへの蕎麦の沈み込み程度をノギスで測定し、以下の基準で評価を行った。
◎:蕎麦の麺つゆへの沈み込みが5mm未満で、保形性が非常に良好。
○:蕎麦の麺つゆへの沈み込みが5〜10mm未満で、保形性が良好。
△:蕎麦の麺つゆへの沈み込みが10〜15mm未満で、保形性がやや悪い。
▲:蕎麦の麺つゆへの沈み込みが15〜20mm未満で、保形性が悪い。
×:蕎麦が麺つゆに全て沈み(20mm以上)、保形性が無い。
<Shape retention and subduction>
Noodle soup hardened with gelatin stored overnight in a refrigerator is crashed with a spoon about 1 cm square, 400 g is filled in a special container, and 160 g of boiled buckwheat noodles are evenly placed and stored in the refrigerator. Gelatin after 24 hours The degree of sinking of the buckwheat into the noodle soup hardened in step was measured with calipers and evaluated according to the following criteria.
:: Sink sink into noodle soup is less than 5 mm, and shape retention is very good.
:: Sink sink into noodle soup is less than 5 to 10 mm, and shape retention is good.
Δ: Sink sink into noodle soup is less than 10 to 15 mm, and shape retention is slightly poor.
▲: Sink sink into noodle soup is less than 15 to 20 mm, and shape retention is poor.
×: All the buckwheat sinks into the noodle soup (20 mm or more) and has no shape retention.

<粘質様食感と口どけ>
冷蔵庫で1晩保存後、37℃の恒温槽に約2時間静置したゼラチンで固めて融解した麺つゆの粘質様食感と口どけについて、熟練したパネラー5名による官能評価を行った。対照品7の粘質様食感と口どけを基準(評点:0)として、以下に示す7段階の点数評価を行い、その平均値を算出した。
+3点…粘質様食感が全く無く、口どけが非常に良好。
+2点…粘質様食感が殆ど無く、口どけが良好。
+1点…粘質様食感が弱く、口どけがやや良好。
0点…粘質様食感と口どけとも、対照品7と変わらない。
−1点…粘質様食感がやや強く、口どけがやや悪い。
−2点…粘質様食感が強く、口どけが悪い。
−3点…粘質様食感が非常に強く、口どけが非常に悪い。
<Viscous texture and mouthfeel>
After storage in a refrigerator overnight, sensory evaluation was performed by five skilled panelists on the sticky texture and mouthfeel of the noodle soup solidified and melted with gelatin that had been allowed to stand in a thermostat at 37 ° C. for about 2 hours. Using the sticky-like texture and mouthfeel of the control product 7 as criteria (rating: 0), the following seven-point scoring was performed, and the average value was calculated.
+3 points: There is no sticky-like texture at all, and the taste is very good.
+2 points: Almost no sticky texture and good mouthfeel.
+1 point: The sticky texture is weak, and the mouthfeel is slightly good.
0 point: No difference from control product 7 with respect to the sticky texture and mouthfeel.
-1 point: Sticky-like texture is slightly strong, and mouthfeel is somewhat poor.
-2 points: Strong sticky texture and poor mouthfeel.
-3 points: Mouth-like texture is very strong, and mouthfeel is very poor.

<風味>
冷蔵庫で1晩保存後、37℃の恒温槽に約2時間静置したゼラチンで固めて融解した麺つゆの風味について、熟練したパネラー5名による官能評価を行った。対照品7のつゆ風味を基準(評点:0)として、以下に示す7段階の点数評価を行い、その平均値を算出した。
+3点…つゆ風味が非常に強い。
+2点…つゆ風味が強い。
+1点…つゆ風味がやや強い。
0点…つゆ風味が対照品7と変わらない。
−1点…つゆ風味がやや弱い。
−2点…つゆ風味が弱い。
−3点…つゆ風味が非常に弱く、全く味が無い。
試験例7の評価結果を、表23に示した。
<Flavor>
After storage in a refrigerator overnight, five skilled panelists conducted a sensory evaluation on the flavor of the noodle soup solidified and melted with gelatin which was allowed to stand in a thermostat at 37 ° C. for about 2 hours. Using the soup flavor of the control product 7 as a reference (score: 0), the following seven-point score evaluation was performed, and the average value was calculated.
+3 points: Very strong soup flavor.
+2 points: Strong soup flavor.
+1 point: The soup flavor is rather strong.
0 point: The soup flavor is the same as the control product 7.
-1 point: The soup flavor is slightly weak.
-2 points ... The soup flavor is weak.
-3 points: The soup flavor is very weak and has no taste.
Table 23 shows the evaluation results of Test Example 7.

Figure 2020036584
Figure 2020036584

表23の結果より、メジアン径が500μm以下の微細なゲルを含有する本発明品1〜11を添加した試験品55〜65は、ゲル強度が対照品7とほぼ同様で、保形性も良好であり、蕎麦のゼラチンで固めた麺つゆへの沈み込みも少なく、粘質様食感が弱く口どけは良好であり、風味も強いゼラチンで固めた麺つゆであるのに対し、メジアン径が500μm以上の微細なゲルを含有する比較品1を添加した試験品66は、対照品7と同様のゲル強度で保形性も良好で蕎麦のゼラチンで固めた麺つゆへの沈み込みが少ないが、粘質様食感と口どけ及び風味とも、対照品7と殆ど変わらないゼラチンで固めた麺つゆであった。   From the results in Table 23, the test products 55 to 65 to which the present invention products 1 to 11 containing a fine gel having a median diameter of 500 μm or less were added, the gel strength was almost the same as the control product 7, and the shape retention was good. The noodle soup hardened with buckwheat gelatin hardly sinks into the noodle soup.The noodle soup has a weak sticky-like texture and good mouthfeel. The test product 66 to which the comparative product 1 containing a fine gel of 500 μm or more was added had the same gel strength and good shape retention as the control product 7, and had little sinking into noodle soup hardened with buckwheat gelatin. The noodle soup was hardened with gelatin which was almost the same as the control product 7 in terms of the sticky texture, mouthfeel and flavor.

以上のことから、メジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤は、ゼラチンで固めた麺つゆにおいて、ゼラチンの配合割合はそのままで、ゲル化したゼラチンによる保形性を維持したまま、融解したゼラチン特有の粘質様食感を低減させ、口どけや風味を向上した。   From the above, the protein-containing sol food modifier containing a fine gel having a median diameter of 500 μm or less can be preserved in gelled gelatin without changing the mixing ratio of gelatin in noodle soup hardened with gelatin. While maintaining the formability, the viscous-like texture peculiar to the melted gelatin was reduced, and the mouthfeel and flavor were improved.

試験例8
表24に記載の配合割合で、実施例1で調製した本発明品1の添加量を変えて、図15に記載の操作に従って試験品55と同様の方法で、試験品67〜72のゼラチンで固めた麺つゆを調製した。また対照として、表24に記載の配合割合で、図16に記載の操作に従って、本発明品1のゲル化剤として使用したジェランガム及び塩化カルシウムを麺つゆ液に溶解し冷却後に粉砕処理した対照品8のゼラチンで固めた麺つゆを調製した。
また、試験例8で調製したゼラチンで固めた麺つゆについて、試験例7と同様の評価を行った。
試験例8の評価結果を、表25に示した。
Test Example 8
The amount of the product 1 of the present invention prepared in Example 1 was changed at the compounding ratio shown in Table 24, and the gelatin of the test products 67 to 72 was obtained in the same manner as the test product 55 according to the operation shown in FIG. A hardened noodle soup was prepared. As a control, gellan gum and calcium chloride used as the gelling agent of the product 1 of the present invention were dissolved in noodle soup in a mixing ratio shown in Table 24 according to the operation shown in FIG. Noodle soup hardened with gelatin of No. 8 was prepared.
The same evaluation as in Test Example 7 was performed on the noodle soup hardened with gelatin prepared in Test Example 8.
Table 25 shows the evaluation results of Test Example 8.

Figure 2020036584
Figure 2020036584

Figure 2020036584
Figure 2020036584

表25の結果より、本発明品1を0.1%添加した試験品67は、粘質様食感が弱く口どけも良好になり、風味も強くなった。本発明品1の添加量が増加するに従い、粘質様食感は更に弱くなり口どけも更に良好となり、添加量が3.0%と5.0%の試験品71と試験品72が最も粘質様食感が弱くなった。風味については、添加量が2.0%の試験品70が最も強く、添加量が3.0%以上になると逆に微細なゲルの風味の影響により、次第に弱くなった。ゲル強度及び保形性と沈み込みは、本発明品を5.0%まで添加しても、試験例7の対照品7と同様な結果であった。   From the results shown in Table 25, the test product 67 containing 0.1% of the product 1 of the present invention had a weak sticky-like texture, a good mouthfeel, and a strong flavor. As the addition amount of the product 1 of the present invention increases, the sticky-like texture becomes weaker and the mouthfeel becomes better, and the test products 71 and 72 with the addition amounts of 3.0% and 5.0% are the most. The sticky texture became weak. As for the flavor, the test product 70 with the added amount of 2.0% was the strongest, and when the added amount was 3.0% or more, it gradually weakened due to the influence of the fine gel flavor. The gel strength, shape retention and sinking were the same as those of the control product 7 of Test Example 7 even when the product of the present invention was added up to 5.0%.

一方、ゲル化剤であるジェランガムを麺つゆ液に添加後、微細なゲル状(ゾル状)とした対照品8は、粘質様食感の低減や口どけ及び風味の改善効果は殆ど無かった。尚、対照品8と試験品72のジェランガム含量は同じであることから、予め調製されたメジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤をゼラチンで固めた麺つゆに添加することで、ゼラチンの配合割合はそのままで、ゲル化したゼラチンの保形性を維持したまま、融解したゼラチン特有の粘質様食感を低減させ、口どけや風味を向上した。   On the other hand, after adding gellan gum which is a gelling agent to the noodle soup liquid, the control product 8 in the form of a fine gel (sol) had almost no effect of reducing the mucous-like texture and improving the mouthfeel and flavor. . Since the gellan gum content of the control product 8 and the test product 72 is the same, the protein-containing sol food modifier containing a fine gel prepared in advance containing a fine gel having a median diameter of 500 μm or less is hardened with gelatin. By adding the soup to the soup, the gelatin mixture ratio was kept as it was, the shape-retaining texture of the gelatinized gelatin was maintained, the viscosity-like texture peculiar to the melted gelatin was reduced, and the mouthfeel and flavor were improved.

試験例9
実施例1〜11及び比較例1で調製した本発明品1〜11及び比較品1について、表26に記載の配合割合で、図17に記載の操作に従って、試験品73〜84の鶏つくねを調製した。また対照として、表26に記載の配合割合で、本発明品及び比較品が無添加の対照品9の鶏つくねを、図17に記載の操作に従って、調製した。
Test example 9
For the products 1 to 11 and the comparative product 1 of the present invention prepared in Examples 1 to 11 and Comparative Example 1, chicken mixes of the test products 73 to 84 were prepared according to the operation shown in FIG. Prepared. In addition, as a control, a chicken tsukuni of Control product 9 in which the product of the present invention and the comparative product were not added was prepared according to the operation shown in FIG.

Figure 2020036584
Figure 2020036584

試験例9で調製した鶏つくねについて、以下の評価を行った。
<ゲル強度>
冷蔵庫で1日保存した鶏つくねのゲル強度について、鶏つくねの高さを20mmに切断し、直径:37mmの円筒状金属製型でくり抜いたものを、レオメーター(レオテック社製)を使用して、下記の測定条件で、プランジャーが鶏つくね表面から2.4mm押下げた時の荷重を測定した。
プランジャー:直径10mmの円板状
上昇速度:2.0cm/分
The following evaluation was performed on the chicken tsukune prepared in Test Example 9.
<Gel strength>
For the gel strength of chicken tsukutsu stored for 1 day in a refrigerator, the height of chicken tsukutsu was cut to 20 mm and cut out with a cylindrical metal mold having a diameter of 37 mm using a rheometer (manufactured by Leotech). Under the following measurement conditions, the load when the plunger was pushed down 2.4 mm from the chicken meat surface was measured.
Plunger: Disc shape with a diameter of 10 mm Ascending speed: 2.0 cm / min

<保形性>
焼成して冷却後の鶏つくねの保形性について、焼成前(成型後)との変形程度をノギスで測定し、以下の基準で評価を行った。
◎:鶏つくねの高さの低下が2mm未満で、保形性が非常に良好。
○:鶏つくねの高さの低下が2〜5mm未満で、保形性が良好。
△:鶏つくねの高さの低下が5〜10mm未満で、保形性がやや悪い。
▲:鶏つくねの高さの低下が10〜15mm未満で、保形性が悪い。
×:鶏つくねの高さの低下が15mm以上で、保形性が無い。
<Shape retention>
With respect to the shape retention of chicken tsukune after firing and cooling, the degree of deformation before firing (after molding) was measured with a vernier caliper, and evaluated based on the following criteria.
:: Chicken meat drop in height was less than 2 mm and shape retention was very good.
:: Chicken meat drop in height is less than 2 to 5 mm, and shape retention is good.
Δ: The height of the chicken meat drop was less than 5 to 10 mm, and the shape retention was somewhat poor.
:: Chicken meat drop in height less than 10 to 15 mm, poor shape retention.
×: The height of the chicken meat drop was 15 mm or more, and there was no shape retention.

<粘質様食感と口どけ>
冷蔵庫で1日保存した鶏つくねの粘質様食感と口どけについて、熟練したパネラー5名による官能評価を行った。対照品9の粘質様食感と口どけを基準(評点:0)として、以下に示す7段階の点数評価を行い、その平均値を算出した。
+3点…粘質様食感が全く無く、口どけが非常に良好。
+2点…粘質様食感が殆ど無く、口どけが良好。
+1点…粘質様食感が弱く、口どけがやや良好。
0点…粘質様食感と口どけとも、対照品9と変わらない。
−1点…粘質様食感がやや強く、口どけがやや悪い。
−2点…粘質様食感が強く、口どけが悪い。
−3点…粘質様食感が非常に強く、口どけが非常に悪い。
<Viscous texture and mouthfeel>
A sensory evaluation was conducted by five skilled panelists on the sticky texture and mouthfeel of the chicken tsukune stored in the refrigerator for one day. Based on the sticky-like texture and mouthfeel of the control product 9 as a reference (score: 0), the following seven-point scoring was performed, and the average value was calculated.
+3 points: There is no sticky-like texture at all, and the taste is very good.
+2 points: Almost no sticky texture and good mouthfeel.
+1 point: The sticky texture is weak, and the mouthfeel is slightly good.
0 point: No difference from control product 9 in both the sticky texture and mouthfeel.
-1 point: Sticky-like texture is slightly strong, and mouthfeel is somewhat poor.
-2 points: Strong sticky texture and poor mouthfeel.
-3 points: Mouth-like texture is very strong, and mouthfeel is very poor.

<風味>
冷蔵庫で1日保存した鶏つくねの風味について、熟練したパネラー5名による官能評価を行った。対照品9のつくね風味(鶏旨味としょうが味等)を基準(評点:0)として、以下に示す7段階の点数評価を行い、その平均値を算出した。
+3点…つくね風味が非常に強い。
+2点…つくね風味が強い。
+1点…つくね風味がやや強い。
0点…つくね風味が対照品9と変わらない。
−1点…つくね風味がやや弱い。
−2点…つくね風味が弱い。
−3点…つくね風味が非常に弱く、全く味が無い。
試験例9の評価結果を、表27に示した。
<Flavor>
The sensory evaluation was performed by five skilled panelists on the flavor of chicken tsukune stored in the refrigerator for one day. The following seven-point score evaluation was performed based on the tsukune flavor (chicken umami and ginger taste) of the control product 9 as a reference (score: 0), and the average value was calculated.
+3 points: Tsukune flavor is very strong.
+2 points ... Tsukune flavor is strong.
+1 point: Tsukune flavor is rather strong.
0 point: Tsukune flavor is not different from control product 9.
-1 point: Tsukune flavor is slightly weak.
-2 points ... Tsukune flavor is weak.
-3 points: Tsukune flavor is very weak and has no taste.
Table 27 shows the evaluation results of Test Example 9.

Figure 2020036584
Figure 2020036584

表27の結果より、メジアン径が500μm以下の微細なゲルを含有する本発明品1〜11を添加した試験品73〜83は、ゲル強度が対照品9とほぼ同様で、保形性も良好であり、粘質様食感が弱く口どけは良好であり、風味も強い鶏つくねであるのに対し、メジアン径が500μm以上の微細なゲルを含有する比較品1を添加した試験品84は、対照品9と同様のゲル強度で保形性も良好であるが、粘質様食感と口どけ及び風味とも、対照品9と殆ど変わらない鶏つくねであった。   From the results in Table 27, the test articles 73 to 83 to which the present invention articles 1 to 11 containing the fine gel having a median diameter of 500 μm or less were added, the gel strength was almost the same as the control article 9, and the shape retention was good. The test product 84 to which the comparative product 1 containing a fine gel having a median diameter of 500 μm or more was added, whereas the chicken meat meat having a weak sticky-like texture, a good mouthfeel, and a strong flavor was obtained. Although the gel strength was similar to the control product 9 and the shape retention was good, the chicken meat was almost the same as the control product 9 in terms of the sticky texture, mouthfeel and flavor.

以上のことから、メジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤は、畜肉蛋白質を変性させた鶏つくねにおいて、畜肉蛋白質の配合割合はそのままで、変性した畜肉蛋白質による保形性を維持したまま、変性した畜肉蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   From the above, the protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less is a chicken meat meat modified meat meat protein, the mixture ratio of meat meat protein, denatured meat meat While maintaining the shape-retaining property of the protein, the mucous-like texture peculiar to the denatured meat protein was reduced, and the mouthfeel and flavor were improved.

試験例10
表28に記載の配合割合で、実施例1で調製した本発明品1の添加量を変えて、図17に記載の操作に従って試験品73と同様の方法で、試験品85〜90の鶏つくねを調製した。また対照として、表28に記載の配合割合で、図18に記載の操作に従って、本発明品1のゲル化剤として使用したジェランガム及び塩化カルシウムの溶液を冷却後に鶏つくね生地に加え加熱した対照品10の鶏つくねを調製した。
また、試験例10で調製した鶏つくねについて、試験例9と同様の評価を行った。
試験例10の評価結果を、表29に示した。
Test example 10
The amount of the product 1 of the present invention prepared in Example 1 was changed at the compounding ratio shown in Table 28, and the chicken Tsukune of the test products 85 to 90 were produced in the same manner as the test product 73 in accordance with the operation shown in FIG. Was prepared. As a control, a control product was prepared by cooling the solution of gellan gum and calcium chloride used as the gelling agent of the product 1 of the present invention in a mixing ratio shown in Table 28 according to the operation shown in FIG. Ten chicken meatballs were prepared.
In addition, the same evaluation as in Test Example 9 was performed on the chicken tsukuni prepared in Test Example 10.
Table 29 shows the evaluation results of Test Example 10.

Figure 2020036584
Figure 2020036584

Figure 2020036584
Figure 2020036584

表29の結果より、本発明品1を0.1%添加した試験品85は、粘質様食感が弱く口どけも良好になり、風味も強くなった。本発明品1の添加量が増加するに従い、粘質様食感は更に弱くなり口どけも更に良好となり、添加量が2.0%と3.0%及び5.0%の試験品88と試験品89及び試験品90が最も粘質様食感が弱くなった。風味については、添加量が2.0%の試験品88が最も強く、添加量が3.0%以上になると逆に微細なゲルの風味の影響により、次第に弱くなった。ゲル強度及び保形性は、本発明品を5.0%まで添加しても、試験例9の対照品9と同様な結果であった。   From the results shown in Table 29, the test product 85 containing 0.1% of the product 1 of the present invention had a weak sticky-like texture, a good mouthfeel, and a strong flavor. As the amount of addition of the product 1 of the present invention increased, the sticky texture became weaker and the mouthfeel became even better. Test product 89 and test product 90 had the weakest sticky texture. As for the flavor, the test product 88 with the added amount of 2.0% was the strongest, and when the added amount was 3.0% or more, it gradually weakened due to the influence of the fine gel flavor. The gel strength and shape retention were the same as those of the control product 9 of Test Example 9 even when the product of the present invention was added up to 5.0%.

一方、ゲル化剤であるジェランガムの溶液を冷却後につくね生地に加えて加熱した対照品10は、粘質様食感の低減や口どけ及び風味の改善効果は殆ど無かった。尚、対照品10と試験品90のジェランガム含量は同じであることから、予め調製されたメジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤を鶏つくね生地に添加し加熱することで、畜肉蛋白質の配合割合はそのままで、変性した畜肉蛋白質の保形性を維持したまま、変性した畜肉蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   On the other hand, the control product 10 in which the gellan gum solution as the gelling agent was cooled and then added to the tsukuni dough and heated, had almost no effect of reducing the sticky-like texture and improving the mouthfeel and flavor. In addition, since the gellan gum content of the control product 10 and the test product 90 is the same, a protein-containing sol-form food modifier containing a fine gel having a median diameter of 500 μm or less prepared in advance is added to chicken meatball. By heating and heating, the mixture ratio of the meat protein remains unchanged, while maintaining the shape-retaining property of the denatured meat protein, the viscous-like texture peculiar to the denatured meat protein is reduced, and the mouthfeel and flavor are improved. .

試験例11
実施例1〜11及び比較例1で調製した本発明品1〜11及び比較品1について、表30に記載の配合割合で、図19に記載の操作に従って、試験品91〜102のアジのつみれを調製した。また対照として、表30に記載の配合割合で、本発明品及び比較品が無添加の対照品11のアジのつみれを、図19に記載の操作に従って、調製した。
Test Example 11
For the products 1 to 11 of the present invention and the comparative product 1 prepared in Examples 1 to 11 and Comparative Example 1, at the compounding ratios shown in Table 30, according to the operation shown in FIG. Was prepared. In addition, as a control, a horse mackerel clam of a control product 11 in which the product of the present invention and the comparative product were not added was prepared according to the operation shown in FIG.

Figure 2020036584
Figure 2020036584

試験例11で調製したアジのつみれについて、以下の評価を行った。
<ゲル強度>
冷蔵庫で1日保存したアジのつみれのゲル強度について、つみれの高さを20mmに切断し、直径:37mmの円筒状金属製型でくり抜いたものを、レオメーター(レオテック社製)を使用して、下記の測定条件で、プランジャーがアジのつみれ表面から2.4mm押下げた時の荷重を測定した。
プランジャー:直径10mmの円板状
上昇速度:2.0cm/分
The following evaluation was performed on the horse mackerel fins prepared in Test Example 11.
<Gel strength>
As for the gel strength of horse mackerel fins stored in a refrigerator for one day, the height of the fins was cut into 20 mm and cut out with a cylindrical metal mold having a diameter of 37 mm using a rheometer (manufactured by Leotech). Under the following measurement conditions, the load when the plunger was pushed down 2.4 mm from the fin surface of the horse mackerel was measured.
Plunger: Disc shape with a diameter of 10 mm Ascending speed: 2.0 cm / min

<保形性>
加熱して冷却後のアジのつみれの保形性について、加熱前(成型後)との変形程度をノギスで測定し、以下の基準で評価を行った。
◎:つみれの高さの低下が2mm未満で、保形性が非常に良好。
○:つみれの高さの低下が2〜5mm未満で、保形性が良好。
△:つみれの高さの低下が5〜10mm未満で、保形性がやや悪い。
▲:つみれの高さの低下が10〜15mm未満で、保形性が悪い。
×:つみれの高さの低下が15mm以上で、保形性が無い。
<Shape retention>
As for the shape retention of horse mackerel fins after heating and cooling, the degree of deformation before heating (after molding) was measured with a vernier caliper, and evaluated according to the following criteria.
:: The reduction of the height of the fin is less than 2 mm, and the shape retention is very good.
:: The reduction in fin height is less than 2 to 5 mm, and the shape retention is good.
C: The decrease in the height of the fin is less than 5 to 10 mm, and the shape retention is slightly poor.
:: The decrease in the height of the fin is less than 10 to 15 mm, and the shape retention is poor.
X: The decrease in the height of the fin is 15 mm or more, and there is no shape retention.

<粘質様食感と口どけ>
冷蔵庫で1日保存したアジのつみれの粘質様食感と口どけについて、熟練したパネラー5名による官能評価を行った。対照品11の粘質様食感と口どけを基準(評点:0)として、以下に示す7段階の点数評価を行い、その平均値を算出した。
+3点…粘質様食感が全く無く、口どけが非常に良好。
+2点…粘質様食感が殆ど無く、口どけが良好。
+1点…粘質様食感が弱く、口どけがやや良好。
0点…粘質様食感と口どけとも、対照品11と変わらない。
−1点…粘質様食感がやや強く、口どけがやや悪い。
−2点…粘質様食感が強く、口どけが悪い。
−3点…粘質様食感が非常に強く、口どけが非常に悪い。
<Viscous texture and mouthfeel>
Sensory evaluation was conducted by five skilled panelists on the sticky texture and mouthfeel of horse mackerel fins stored for one day in a refrigerator. Based on the sticky-like texture and mouthfeel of the control product 11 as a reference (rating: 0), the following seven levels of score evaluation were performed, and the average value was calculated.
+3 points: There is no sticky-like texture at all, and the taste is very good.
+2 points: Almost no sticky texture and good mouthfeel.
+1 point: The sticky texture is weak, and the mouthfeel is slightly good.
0 point: No difference from control product 11 in both the sticky texture and mouthfeel.
-1 point: Sticky-like texture is slightly strong, and mouthfeel is somewhat poor.
-2 points: Strong sticky texture and poor mouthfeel.
-3 points: Mouth-like texture is very strong, and mouthfeel is very poor.

<風味>
冷蔵庫で1日保存したアジのつみれの風味について、熟練したパネラー5名による官能評価を行った。対照品11のつみれ風味(魚旨味としょうが味等)を基準(評点:0)として、以下に示す7段階の点数評価を行い、その平均値を算出した。
+3点…つみれ風味が非常に強い。
+2点…つみれ風味が強い。
+1点…つみれ風味がやや強い。
0点…つみれ風味が対照品11と変わらない。
−1点…つみれ風味がやや弱い。
−2点…つみれ風味が弱い。
−3点…つみれ風味が非常に弱く、全く味が無い。
試験例11の評価結果を、表31に示した。
<Flavor>
The sensory evaluation was carried out by five skilled panelists on the flavor of horse mackerel caught in the refrigerator for one day. The following seven-point scoring was performed based on the savory flavor (fish umami and ginger taste) of the control product 11 as a reference (rating: 0), and the average value was calculated.
+3 points ... Tsumire flavor is very strong.
+2 points ... Tsumire flavor is strong.
+1 point ... Tsumire flavor is rather strong.
0 point: Tummy flavor is not different from control product 11.
-1 point: Tsumire flavor is slightly weak.
-2 points: Tsumire flavor is weak.
-3 points ... Tsumire flavor is very weak and has no taste.
Table 31 shows the evaluation results of Test Example 11.

Figure 2020036584
Figure 2020036584

表31の結果より、メジアン径が500μm以下の微細なゲルを含有する本発明品1〜11を添加した試験品91〜101は、ゲル強度が対照品11とほぼ同様で、保形性も良好であり、粘質様食感が弱く口どけは良好であり、風味も強いアジのつみれであるのに対し、メジアン径が500μm以上の微細なゲルを含有する比較品1を添加した試験品102は、対照品11と同様のゲル強度で保形性も良好であるが、粘質様食感と口どけ及び風味とも、対照品11と殆ど変わらないアジのつみれであった。   From the results in Table 31, the test articles 91 to 101 to which the present invention articles 1 to 11 containing a fine gel having a median diameter of 500 μm or less were added, the gel strength was almost the same as the control article 11, and the shape retention was good. The test product 102 was prepared by adding a comparative product 1 containing a fine gel having a median diameter of 500 μm or more, while having a weak sticky-like texture, a good mouthfeel, and a strong flavor. The gel had the same gel strength and good shape retention as the control product 11, but had a sticky fin that was almost the same as the control product 11 in both the sticky texture and the mouthfeel and flavor.

以上のことから、メジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤は、魚肉蛋白質を変性させたアジのつみれにおいて、魚肉蛋白質の配合割合はそのままで、変性した魚肉蛋白質による保形性を維持したまま、変性した魚肉蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   From the above, the protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less was modified in fish mackerel tuna caught in a modified fish mackerel with the proportion of the fish protein unchanged. While maintaining the shape retention property of the fish meat protein, the sticky-like texture peculiar to the denatured fish meat protein was reduced, and the mouthfeel and flavor were improved.

試験例12
表32に記載の配合割合で、実施例1で調製した本発明品1の添加量を変えて、図19に記載の操作に従って試験品91と同様の方法で、試験品103〜108のアジのつみれを調製した。また対照として、表32に記載の配合割合で、図20に記載の操作に従って、本発明品1のゲル化剤として使用したジェランガム及び塩化カルシウムの溶液を冷却後にアジのつみれ生地に加え加熱した対照品12のアジのつみれを調製した。
また、試験例12で調製したアジのつみれについて、試験例11と同様の評価を行った。
試験例12の評価結果を、表33に示した。
Test Example 12
The amount of the product 1 of the present invention prepared in Example 1 was changed at the compounding ratio shown in Table 32, and according to the operation shown in FIG. Tsumire was prepared. As a control, a solution in which gellan gum and calcium chloride used as gelling agents of the product 1 of the present invention were cooled and added to a horse mackerel fin dough according to the operation shown in FIG. Article 12 horse mackerel fins were prepared.
The same evaluation as in Test Example 11 was performed on the horse mackerel fins prepared in Test Example 12.
Table 33 shows the evaluation results of Test Example 12.

Figure 2020036584
Figure 2020036584

Figure 2020036584
Figure 2020036584

表33の結果より、本発明品1を0.1%添加した試験品103は、粘質様食感が弱く口どけも良好になり、風味も強くなった。本発明品1の添加量が増加するに従い、粘質様食感は更に弱くなり口どけも更に良好となり、添加量が3.0%と5.0%の試験品107と試験品108が最も粘質様食感が弱くなった。風味については、添加量が2.0%の試験品106が最も強く、添加量が3.0%以上になると逆に微細なゲルの風味の影響により、次第に弱くなった。ゲル強度及び保形性は、本発明品を5.0%まで添加しても、試験例11の対照品11と同様な結果であった。   From the results in Table 33, it was found that the test product 103 containing 0.1% of the product 1 of the present invention had a weak sticky-like texture, good mouthfeel, and a strong flavor. As the addition amount of the product 1 of the present invention increases, the sticky texture becomes weaker and the mouthfeel becomes better, and the test products 107 and 108 with the addition amounts of 3.0% and 5.0% are the most. The sticky texture became weak. With respect to the flavor, the test product 106 with the added amount of 2.0% was the strongest, and when the added amount was 3.0% or more, it gradually weakened due to the influence of the fine gel flavor. The gel strength and shape retention were the same as those of the control product 11 of Test Example 11 even when the product of the present invention was added to 5.0%.

一方、ゲル化剤であるジェランガムの溶液を冷却後にアジのつみれ生地に加えて加熱した対照品12は、粘質様食感の低減や口どけ及び風味の改善効果は殆ど無かった。尚、対照品12と試験品108のジェランガム含量は同じであることから、予め調製されたメジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤をアジのつみれ生地に添加し加熱することで、魚肉蛋白質の配合割合はそのままで、変性した魚肉蛋白質の保形性を維持したまま、変性した魚肉蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   On the other hand, the control product 12 in which the gellan gum solution as the gelling agent was cooled and then added to the horse mackerel fin dough and heated, had almost no effect of reducing the mucous-like texture, improving mouthfeel and flavor. In addition, since the gellan gum content of the control product 12 and the test product 108 is the same, the protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less prepared in advance is used as a mackerel clam dough. By adding and heating, the mixture ratio of the fish protein remains unchanged, while maintaining the shape-retaining property of the denatured fish protein, reducing the sticky-like texture unique to the denatured fish protein, improving mouthfeel and flavor did.

実施例12
表34に記載の配合割合で、ゲル化剤としてカードランを使用して、図21に記載の操作に従って、本発明品12の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤を調製した。尚、クエン酸液は、クエン酸500gを水で溶解して全量が1Lとなるように調製した。
Example 12
Using curdlan as a gelling agent at the blending ratio shown in Table 34 and preparing the protein-containing sol food modifier containing a fine gel of the product 12 of the present invention, according to the operation shown in FIG. did. The citric acid solution was prepared by dissolving 500 g of citric acid in water so that the total amount was 1 L.

Figure 2020036584
Figure 2020036584

実施例12で調製した本発明品12について、粒度分布測定装置(Beckman coulter社製、機種名:LS 13 320)にて測定したメジアン径の測定結果と、図21に記載のカードラン分散液(図中の(*)の工程で得られる液)を静置状態で90℃まで加熱して得られたゲルに対し、ゲルの50重量%の水を加え、ゲルの融解温度を測定した結果を表35に記載した。   With respect to the product 12 of the present invention prepared in Example 12, a measurement result of a median diameter measured by a particle size distribution measuring device (manufactured by Beckman coulter, model name: LS 13320) and a curdlan dispersion shown in FIG. The solution obtained by heating the liquid obtained in the step (*) in the figure to 90 ° C. in a stationary state was added with 50% by weight of water of the gel, and the melting temperature of the gel was measured. It is described in Table 35.

Figure 2020036584
Figure 2020036584

試験例13
実施例12で調製した本発明品12について、表10に記載の試験品1〜12と同様の配合割合で、図9に記載の試験品1〜12と同様の操作に従って、試験品109の焼プリンを調製した。
また、試験例13で調製した焼プリンについて、試験例1と同様の評価を行った。
試験例13の評価結果を、表36に示した。
Test Example 13
With respect to the product 12 of the present invention prepared in Example 12, the firing ratio of the test product 109 was determined in the same mixing ratio as that of the test products 1 to 12 shown in Table 10 according to the same operation as the test products 1 to 12 shown in FIG. Pudding was prepared.
The same evaluation as in Test Example 1 was performed on the baked pudding prepared in Test Example 13.
Table 36 shows the evaluation results of Test Example 13.

Figure 2020036584
Figure 2020036584

表36の結果より、メジアン径が500μm以下の微細なゲルを含有する本発明品12を添加した試験品109は、ゲル強度が対照品1とほぼ同様で、保形性も良好であり、粘質様食感が弱く口どけは良好であり、風味も強い焼プリンであった。   From the results shown in Table 36, the test article 109 to which the product 12 of the present invention containing a fine gel having a median diameter of 500 μm or less was added, the gel strength was almost the same as the control article 1, the shape retention was good, and the viscosity was good. It was a baked pudding with a weak texture, good mouthfeel, and a strong flavor.

以上のことから、メジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤は、卵蛋白質を変性させた焼プリンにおいて、卵蛋白質の配合割合はそのままで、変性した卵蛋白質による保形性を維持したまま、変性した卵蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   From the above, the protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less is a modified egg in a baked pudding obtained by denaturing an egg protein, while keeping the mixing ratio of the egg protein unchanged. While maintaining the shape-retaining property of the protein, the mucous-like texture peculiar to the denatured egg protein was reduced, and the mouthfeel and flavor were improved.

試験例14
実施例12で調製した本発明品12について、表14に記載の試験品19〜30と同様の配合割合で、図11に記載の試験品19〜30と同様の操作に従って、試験品110のプレーンヨーグルトを調製した。
また、試験例14で調製したプレーンヨーグルトについて、試験例3と同様の評価を行った。
試験例14の評価結果を、表37に示した。
Test Example 14
With respect to the product 12 of the present invention prepared in Example 12, at the same blending ratio as that of the test products 19 to 30 shown in Table 14, according to the same operation as the test products 19 to 30 shown in FIG. Yogurt was prepared.
The same evaluation as in Test Example 3 was performed on the plain yogurt prepared in Test Example 14.
Table 37 shows the evaluation results of Test Example 14.

Figure 2020036584
Figure 2020036584

表37の結果より、メジアン径が500μm以下の微細なゲルを含有する本発明品12を添加した試験品110は、ゲル強度が対照品3とほぼ同様で、保形性も良好であり、pHも対照品3と同様で発酵阻害は無く、粘質様食感が弱く口どけは良好であり、風味も強いプレーンヨーグルトであった。   From the results in Table 37, it is found that the test product 110 to which the product 12 of the present invention containing a fine gel having a median diameter of 500 μm or less was added had almost the same gel strength as the control product 3, good shape retention, and pH. This was plain yogurt having no fermentation inhibition similarly to control product 3, having a weak sticky-like texture, good mouthfeel, and a strong flavor.

以上のことから、メジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤は、乳蛋白質を変性させたプレーンヨーグルトにおいて、乳蛋白質の配合割合はそのままで、変性した乳蛋白質による保形性を維持したまま、変性した乳蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   From the above, the protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less is a modified yolk in plain yogurt in which milk protein has been denatured, the milk protein proportion remains unchanged, While maintaining the shape-retaining property of the protein, the mucous-like texture peculiar to the denatured milk protein was reduced, and the mouthfeel and flavor were improved.

試験例15
実施例12で調製した本発明品12について、表18に記載の試験品37〜48と同様の配合割合で、図13に記載の試験品37〜48と同様の操作に従って、試験品111の充填豆腐を調製した。
また、試験例15で調製した充填豆腐について、試験例5と同様の評価を行った。
試験例15の評価結果を、表38に示した。
Test Example 15
The product 12 of the present invention prepared in Example 12 was filled with the test product 111 at the same mixing ratio as that of the test products 37 to 48 shown in Table 18 according to the same operation as the test products 37 to 48 shown in FIG. Tofu was prepared.
The same evaluation as in Test Example 5 was performed on the packed tofu prepared in Test Example 15.
Table 38 shows the evaluation results of Test Example 15.

Figure 2020036584
Figure 2020036584

表38の結果より、メジアン径が500μm以下の微細なゲルを含有する本発明品12を添加した試験品111は、ゲル強度が対照品5とほぼ同様で、保形性も良好であり、粘質様食感が弱く口どけは良好であり、風味も強い充填豆腐であった。   From the results shown in Table 38, the test article 111 to which the inventive article 12 containing a fine gel having a median diameter of 500 μm or less was added, the gel strength was almost the same as the control article 5, the shape retention was good, and the viscosity was good. The textured texture was weak, the mouthfeel was good, and the flavor was a packed tofu with a strong flavor.

以上のことから、メジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤は、大豆蛋白質を変性させた充填豆腐において、大豆蛋白質の配合割合はそのままで、変性した大豆蛋白質による保形性を維持したまま、変性した大豆蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   From the above, the protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less is the modified soybean in the packed soybean protein-modified tofu with the soybean protein proportion unchanged. While maintaining the shape-retaining property of the protein, the sticky texture unique to the denatured soybean protein was reduced, and the mouthfeel and flavor were improved.

試験例16
実施例12で調製した本発明品12について、表22に記載の試験品55〜66と同様の配合割合で、図15に記載の試験品55〜66と同様の操作に従って、試験品112のゼラチンで固めた麺つゆを調製した。
また、試験例16で調製したゼラチンで固めた麺つゆについて、試験例7と同様の評価を行った。
試験例16の評価結果を、表39に示した。
Test Example 16
For the product 12 of the present invention prepared in Example 12, the gelatin of the test product 112 was prepared in the same mixing ratio as that of the test products 55 to 66 shown in Table 22 according to the same operation as that of the test products 55 to 66 shown in FIG. A noodle soup hardened in was prepared.
The same evaluation as in Test Example 7 was performed on the noodle soup solidified with gelatin prepared in Test Example 16.
Table 39 shows the evaluation results of Test Example 16.

Figure 2020036584
Figure 2020036584

表39の結果より、メジアン径が500μm以下の微細なゲルを含有する本発明品12を添加した試験品112は、ゲル強度が対照品7とほぼ同様で、保形性も良好であり、蕎麦のゼラチンで固めた麺つゆへの沈み込みも少なく、粘質様食感が弱く口どけは良好であり、風味も強いゼラチンで固めた麺つゆであった。   From the results in Table 39, it is found that the test product 112 to which the product 12 of the present invention containing a fine gel having a median diameter of 500 μm or less has almost the same gel strength as the control product 7, good shape retention, and buckwheat noodles There was little sinking into the noodle soup hardened with gelatin, and the noodle soup hardened with gelatin having a weak sticky-like texture and good mouthfeel and a strong flavor.

以上のことから、メジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤は、ゼラチンで固めた麺つゆにおいて、ゼラチンの配合割合はそのままで、ゲル化したゼラチンによる保形性を維持したまま、融解したゼラチン特有の粘質様食感を低減させ、口どけや風味を向上した。
From the above, the protein-containing sol food modifier containing a fine gel having a median diameter of 500 μm or less can be preserved in gelled gelatin while maintaining the mixing ratio of gelatin in noodle soup hardened with gelatin. While maintaining the formability, the viscous-like texture peculiar to the melted gelatin was reduced, and the mouthfeel and flavor were improved.

試験例17
実施例12で調製した本発明品12について、表26に記載の試験品73〜84と同様の配合割合で、図17に記載の試験品73〜84と同様の操作に従って、試験品113の鶏つくねを調製した。
また、試験例17で調製した鶏つくねについて、試験例9と同様の評価を行った。
試験例17の評価結果を、表40に示した。
Test Example 17
About the product 12 of the present invention prepared in Example 12, the chicken of the test product 113 was prepared according to the same operation as the test products 73 to 84 shown in FIG. Tsukune was prepared.
In addition, the same evaluation as in Test Example 9 was performed on the chicken tsukune prepared in Test Example 17.
Table 40 shows the evaluation results of Test Example 17.

Figure 2020036584
Figure 2020036584

表40の結果より、メジアン径が500μm以下の微細なゲルを含有する本発明品12を添加した試験品113は、ゲル強度が対照品9とほぼ同様で、保形性も良好であり、粘質様食感が弱く口どけは良好であり、風味も強い鶏つくねであった。   From the results in Table 40, it is found that the test product 113 to which the product 12 of the present invention containing a fine gel having a median diameter of 500 μm or less has almost the same gel strength as the control product 9 and has good shape retention and viscosity. The chicken had a weak texture, good mouthfeel, and a strong flavor.

以上のことから、メジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤は、畜肉蛋白質を変性させた鶏つくねにおいて、畜肉蛋白質の配合割合はそのままで、変性した畜肉蛋白質による保形性を維持したまま、変性した畜肉蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   From the above, the protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less is a chicken meat meat modified meat meat protein, the mixture ratio of meat meat protein, denatured meat meat While maintaining the shape-retaining property of the protein, the mucous-like texture peculiar to the denatured meat protein was reduced, and the mouthfeel and flavor were improved.

試験例18
実施例12で調製した本発明品12について、表30に記載の試験品91〜102と同様の配合割合で、図19に記載の試験品91〜102と同様の操作に従って、試験品114のアジのつみれを調製した。
また、試験例18で調製したアジのつみれについて、試験例11と同様の評価を行った。
試験例18の評価結果を、表41に示した。
Test Example 18
The product 12 of the present invention prepared in Example 12 was mixed at the same mixing ratio as that of the test products 91 to 102 shown in Table 30 and in accordance with the same operation as that of the test products 91 to 102 shown in FIG. Was prepared.
The same evaluation as in Test Example 11 was performed on the horse mackerel claws prepared in Test Example 18.
Table 41 shows the evaluation results of Test Example 18.

Figure 2020036584
Figure 2020036584

表41の結果より、メジアン径が500μm以下の微細なゲルを含有する本発明品12を添加した試験品114は、ゲル強度が対照品11とほぼ同様で、保形性も良好であり、粘質様食感が弱く口どけは良好であり、風味も強いアジのつみれであった。   From the results shown in Table 41, the test article 114 to which the inventive article 12 containing a fine gel having a median diameter of 500 μm or less was added, the gel strength was almost the same as the control article 11, the shape retention was good, and the viscosity was good. The texture was weak, the mouth was good, and the flavor was strong.

以上のことから、メジアン径が500μm以下の微細なゲルを含有する蛋白質含有ゾル状食品用改質剤は、魚肉蛋白質を変性させたアジのつみれにおいて、魚肉蛋白質の配合割合はそのままで、変性した魚肉蛋白質による保形性を維持したまま、変性した魚肉蛋白質特有の粘質様食感を低減させ、口どけや風味を向上した。   From the above, the protein-containing sol-like food modifier containing a fine gel having a median diameter of 500 μm or less was modified in fish mackerel tuna claws, in which the mixture ratio of fish protein was unchanged. While maintaining the shape retention property of the fish meat protein, the sticky-like texture peculiar to the denatured fish meat protein was reduced, and the mouthfeel and flavor were improved.

本発明により、蛋白質含有ゾル状食品に、蛋白質の配合割合はそのままで、変性した蛋白質による保形性を維持し、変性した蛋白質特有の粘質様食感を低減させ、口どけや風味の向上等の品質を改質する改質剤を提供することが可能となり、産業上の貢献度は高いものである。   According to the present invention, the protein-containing sol food maintains the shape retention of the denatured protein while maintaining the proportion of the protein, reduces the sticky-like texture peculiar to the denatured protein, and improves the mouthfeel and flavor. Thus, it is possible to provide a modifier for improving the quality such as the above, and the industrial contribution is high.

Claims (5)

メジアン径が500μm以下である、ゲル化剤の微細なゲルを含有することを特徴とする、蛋白質含有ゾル状食品用改質剤。   A protein-containing sol food modifier containing a fine gel of a gelling agent having a median diameter of 500 μm or less. ゲル化剤が、寒天、カラギナン、ジェランガム、キサンタンガム、ローカストビーンガム、タラガム、グルコマンナン、こんにゃく粉(芋)、ペクチン、アルギン酸、アルギン酸塩類、及びカードランからなる群より選ばれる少なくとも1種以上の多糖類である請求項1記載の蛋白質含有ゾル状食品用改質剤。   The gelling agent is at least one or more selected from the group consisting of agar, carrageenan, gellan gum, xanthan gum, locust bean gum, tara gum, glucomannan, konjac powder (potato), pectin, alginic acid, alginates, and curdlan. The protein-containing sol food modifier according to claim 1, which is a saccharide. 蛋白質含有ゾル状食品の蛋白質が、ゼラチン、卵由来、乳由来、豆由来、畜肉由来及び魚肉由来の蛋白質からなる群より選ばれる少なくとも1種以上の蛋白質を含有する請求項1又は2記載の蛋白質含有ゾル状食品用改質剤。   The protein according to claim 1 or 2, wherein the protein of the protein-containing sol food contains at least one protein selected from the group consisting of gelatin, eggs, milk, beans, meat and fish. Modifier for food containing sol. 請求項1〜3いずれか記載の改質剤を含有する蛋白質含有ゾル状食品。   A protein-containing sol food containing the modifier according to claim 1. 蛋白質含有ゾル状食品の蛋白質が、ゼラチン、卵由来、乳由来、豆由来、畜肉由来及び魚肉由来の蛋白質からなる群より選ばれる少なくとも1種以上の蛋白質を含有する請求項4記載の蛋白質含有ゾル状食品。 5. The protein-containing sol according to claim 4, wherein the protein of the protein-containing sol food contains at least one protein selected from the group consisting of gelatin, eggs, milk, beans, livestock and fish. Food.
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