JP7283900B2 - Meat-like emulsion composition and meat-like processed food - Google Patents

Meat-like emulsion composition and meat-like processed food Download PDF

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JP7283900B2
JP7283900B2 JP2018240456A JP2018240456A JP7283900B2 JP 7283900 B2 JP7283900 B2 JP 7283900B2 JP 2018240456 A JP2018240456 A JP 2018240456A JP 2018240456 A JP2018240456 A JP 2018240456A JP 7283900 B2 JP7283900 B2 JP 7283900B2
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敬司 川上
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Nippon Shinyaku Co Ltd
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本発明は、水溶性乳タンパク、および可食性油脂を主原料とした食肉様乳化組成物、また食肉の様な食感を有し、かつ風味が良好な食肉様加工食品、およびその製造方法に関する。 TECHNICAL FIELD The present invention relates to a meat-like emulsified composition containing water-soluble milk protein and edible oil as main raw materials, a meat-like processed food having meat-like texture and good flavor, and a method for producing the same. .

近年、日本国内において、メタボリックシンドロームや成人病等の予防のため、健康な食生活に対する意識が高まっており、低脂肪、低カロリー食品が好まれて使用されている。これは、近年の政府による食育の取組みなどの影響のほか(非特許文献1)、インターネットやテレビなどを通じて食品についての消費者の知識がますます豊富になってきていることも理由として挙げられる。以上のような背景から、動物脂肪、コレステロールやカロリーの摂取を減らすべく、食肉、またはソーセージ、およびハムといった加工肉の摂取を控え、肉製品の食感を有する、いわゆる肉様食品を摂取する消費者が増えている。
食肉様加工食品とは、肉の代替品として、卵白、こんにゃく、または大豆タンパクなどを混合して、肉の食感を出来るだけ損なわずに加工されたものである。従来、欧米においては菜食主義者(ベジタリアン)向けの食品であった食肉様加工食品は、近年、日本国内においても健康意識の高い消費者から関心が寄せられている。
In recent years, in Japan, there has been an increasing awareness of healthy eating habits in order to prevent metabolic syndrome, geriatric diseases, etc., and low-fat, low-calorie foods are preferred and used. This is partly due to the impact of recent government efforts to promote food education (Non-Patent Document 1), and partly because consumers are becoming more and more knowledgeable about food through the Internet and television. . Against this background, in order to reduce the intake of animal fat, cholesterol and calories, the consumption of so-called meat-like foods, which have the texture of meat products, is avoided by refraining from the intake of meat or processed meat such as sausages and hams. people are increasing.
Meat-like processed foods are those which are mixed with egg white, konnyaku, soybean protein, etc. as substitutes for meat and processed without impairing the texture of meat as much as possible. Meat-like processed foods, which have traditionally been foods for vegetarians in Europe and the United States, have recently attracted interest from health-conscious consumers in Japan as well.

食肉様加工食品は従来、大豆タンパクや小麦タンパクなどに代表される、植物性タンパクや卵白タンパクをタンパク源として製造されたものが多く知られているが、これらのタンパク由来の臭気による風味や食感の悪さが問題であった。これらのタンパクは、ハンバーグや肉団子など、肉や野菜をまとめるいわゆるつなぎとして多く用いられているが、天然の肉を一切使用しない場合には、植物性タンパクや卵白タンパク特有の臭気や食感がより直接的に残ることから、風味や食感の観点から消費者が美味しいと感じられる加工食品を得ることはより難しい。 Conventionally, many meat-like processed foods are known to be manufactured using vegetable proteins and egg white proteins, typified by soybean protein and wheat protein, as protein sources. The problem was the bad feeling. These proteins are often used as binders for meat and vegetables such as hamburger steaks and meatballs, but if natural meat is not used at all, the odor and texture peculiar to vegetable proteins and egg white proteins will be lost. Because it remains more direct, it is more difficult to obtain processed foods that consumers find palatable in terms of flavor and texture.

天然の肉を使用せず、風味に優れた食肉様の組成物の例として、特許文献1にはカゼインと酸性多糖類と多価金属化合物を含有する、アルカリ性の耐熱性の乳タンパク組成物の製造方法が開示されている。該特許文献には、タンパク源として使用するカゼインを、アルカリ性条件下で溶解し、アルギン酸ナトリウムやカラギーナン等の酸性多糖類を混合した後、得られた混合物を塩化カルシウムや塩化マグネシウム等の多価金属化合物の水溶液に浸すことで所望の乳タンパク固形物が得られると述べられている。また、得られた乳タンパク固形物は肉のようなテクスチャーを有すると述べられているが、耐熱性や保形性を担保するために酸性多糖類と多価金属化合物の添加が必須である。さらに本発明で使用する可食性油脂を使用しない点で本発明と異なる。 As an example of a meat-like composition excellent in flavor without using natural meat, Patent Document 1 discloses an alkaline heat-resistant milk protein composition containing casein, an acidic polysaccharide and a polyvalent metal compound. A method of manufacture is disclosed. In this patent document, casein used as a protein source is dissolved under alkaline conditions, mixed with acidic polysaccharides such as sodium alginate and carrageenan, and then the resulting mixture is treated with a polyvalent metal such as calcium chloride and magnesium chloride. The desired milk protein solids are said to be obtained by soaking in an aqueous solution of the compound. It is also stated that the resulting milk protein solid has a meat-like texture, but the addition of an acidic polysaccharide and a polyvalent metal compound is essential in order to ensure heat resistance and shape retention. Furthermore, it differs from the present invention in that it does not use the edible oil used in the present invention.

特許文献2には大豆タンパクおよび/もしくは乳タンパク、増粘剤、凝固剤または沈殿剤、油脂を含有するタンパク組成物の製造方法が開示されている。該特許文献の実施例にはタンパク源として使用するタンパクと水を加熱して乳化した後、増粘剤であるアルギン酸ナトリウム、凝固剤である塩化カルシウム水溶液を加えて静置した後、所望の乳タンパク固形物を水相から分離することで得られると述べられている。該特許文献で得られた食品中間体は繊維構造を有すると述べられているが、本発明の乳化組成物および加工食品は非繊維状で、ゲル状であるという点で異なる。また特許文献2は、酸性多糖類と多価金属化合物の添加を好適としている点で本発明と異なる。 Patent Document 2 discloses a method for producing a protein composition containing soybean protein and/or milk protein, a thickener, a coagulant or a precipitant, and fats and oils. In the examples of the patent document, a protein used as a protein source and water are heated and emulsified. It is said to be obtained by separating the protein solids from the aqueous phase. Although the food intermediate obtained in said patent document is said to have a fibrous structure, the emulsified composition and processed food of the present invention differ in that they are non-fibrous and gel-like. Moreover, Patent Document 2 differs from the present invention in that it is preferable to add an acidic polysaccharide and a polyvalent metal compound.

特許文献3にはカゼイン塩、カルシウム塩および/またはリン酸カルシウム塩、ならびに水の混合物を乳化させ、クエン酸などの有機酸で酸性(pH5.6~6.2)とし、加熱後冷却することでかまぼこ様の乳タンパク組成物を製造する方法が開示されている。該特許文献で得られた乳タンパク固形物は繊維状の食感を有すると述べられているが、本発明の乳化組成物および加工食品は非繊維状で、ゲル状であるという点で異なる。また特許文献3に記載の乳タンパク組成物は、所望の形状を担保するために酸性多糖類と多価金属化合物の添加が必須であるのに対し、これらの成分を必要としない点においても本発明と異なる。 In Patent Document 3, a mixture of caseinate, calcium salt and/or calcium phosphate and water is emulsified, acidified (pH 5.6 to 6.2) with an organic acid such as citric acid, heated and then cooled to prepare kamaboko. Disclosed is a method for producing a milk protein composition similar to Although the milk protein solids obtained in the patent document are said to have a fibrous texture, the emulsified composition and processed food of the present invention differ in that they are non-fibrous and gel-like. In addition, the milk protein composition described in Patent Document 3 requires the addition of an acidic polysaccharide and a polyvalent metal compound to ensure the desired shape, whereas the present invention does not require these components. Different from invention.

特開昭61-63249号公報JP-A-61-63249 欧州特許番号第1790233号公報European Patent No. 1790233 米国特許番号第5368871号公報U.S. Pat. No. 5,368,871

農林水産省発表「わが国の食生活の現状と食育の推進について(平成29年10月)Announcement by the Ministry of Agriculture, Forestry and Fisheries "About the current state of dietary habits in Japan and the promotion of food education (October 2017)

本発明の課題は、非繊維状の滑らかで弾力に富んだ、天然肉に近い食感で、かつ風味に優れた非繊維状の食肉様加工食品を提供すること、およびそのために必要な食肉様乳化組成物を提供することにある。また、適切な食肉様乳化組成物を用いて、食肉様加工食品の製造方法を提供することも本発明の課題である。 An object of the present invention is to provide a non-fibrous meat-like processed food that is non-fibrous, smooth, highly elastic, has a texture close to that of natural meat, and has an excellent flavor, and to provide a meat-like processed food necessary for that purpose. An object of the present invention is to provide an emulsified composition. Another object of the present invention is to provide a method for producing a meat-like processed food using an appropriate meat-like emulsified composition.

本発明者らは、上記課題を解決するために鋭意検討した結果、水溶性乳タンパクを主なタンパク源とし、かつ可食性油脂を一定量配合した食肉様乳化組成物を調製し、加熱処理等の工程を経ることで、非繊維状の滑らかで弾力に富んだ、天然肉に近い食感で、かつタンパク臭が少なく風味に優れた食肉様加工食品が得られることを見出し、本発明を完成させた。
すなわち、本発明は以下の通りである。
As a result of intensive studies to solve the above problems, the present inventors prepared a meat-like emulsified composition containing a water-soluble milk protein as a main protein source and a certain amount of edible oil, followed by heat treatment and the like. Through the process of (1), it is possible to obtain a meat-like processed food that is non-fibrous, smooth and elastic, has a texture close to that of natural meat, and has a low protein odor and an excellent flavor, and completed the present invention. let me
That is, the present invention is as follows.

(I)
水溶性乳タンパクおよび可食性油脂を含有する、食肉様乳化組成物。
(II)
水溶性乳タンパクとして、水溶性カゼインタンパクおよびホエイタンパクからなる群から選択される少なくとも一種を含有する、前記(I)に記載の食肉様乳化組成物。
(III)
水溶性カゼインタンパクが、カゼインナトリウム、カゼインカリウム、カゼインカルシウムおよびカゼインマグネシウムからなる群から選択される少なくとも一種を含有する、(II)に記載の食肉様乳化組成物。
(IV)
全タンパク成分に対する水溶性乳タンパクの重量比がタンパク質ベースで0.18~1.0である、(I)~(III)のいずれかに記載の食肉様乳化組成物。
(V)
食肉様乳化組成物中の水溶性乳タンパクの含有量がタンパク質ベースで1.1重量%~16重量%である、(I)~(IV)のいずれかに記載の食肉様乳化組成物。
(VI)
全タンパク成分に対する水溶性カゼインタンパクの重量比がタンパク質ベースで0.16~0.66である、(II)~(V)のいずれかに記載の食肉様乳化組成物。
(VII)
食肉様乳化組成物中の水溶性カゼインタンパクの含有量がタンパク質ベースで1.0重量%~10重量%である、(II)~(VI)のいずれかに記載の食肉様乳化組成物。
(VIII)
食肉様乳化組成物中の可食性油脂の含有量が2重量%~40重量%である、(I)~(VII)のいずれか一項に記載の食肉様乳化組成物。
(IX)
さらに卵白タンパクを含有する、(I)~(VIII)のいずれか一項に記載の食肉様乳化組成物。
(X)
全タンパク成分に対する卵白タンパクの重量比がタンパク質ベースで0.8以下(ただし0ではない)であり、全タンパク成分に対する水溶性乳タンパクの重量比がタンパク質ベースで0.18~1.0未満である、(IX)に記載の食肉様乳化組成物。
(XI)
さらにデンプンまたは増粘多糖類を含有する、(I)~(X)のいずれか一項に記載の食肉様乳化組成物。
(XII)
食肉様乳化組成物中の可食性油脂の含有量が2重量%~25重量%である、(I)~(XI)のいずれか一項に記載の食肉様乳化組成物。
(XIII)
タンパク成分として、さらに大豆タンパクを含有する、下記1)または2)のいずれか一項の場合である、(I)~(XII)のいずれか一項に記載の食肉様乳化組成物:
1) 全タンパク成分に対する大豆タンパクの重量比がタンパク質ベースで0.1以下(ただし、0ではない。)であり、全タンパク成分に対する水溶性乳タンパクの重量比がタンパク質ベースで0.9以下(ただし0ではない)であり、食肉様乳化組成物中の可食性油脂の含有量が30重量%以下である。
2) タンパク成分として、さらに卵白タンパクを含有し、全タンパク成分に対する大豆タンパクの重量比がタンパク質ベースで0.5以下(ただし、0ではない。)であり、全タンパク成分に対する卵白タンパクの重量比がタンパク質ベースで0.8以下(ただし、0ではない。)であり、全タンパク成分に対する水溶性乳タンパクの重量比がタンパク質ベースで0.18~1.0未満であり、食肉様乳化組成物中の可食性油脂の含有量が2重量%~30重量%の範囲内である。
(XIV)
(I)~(XIII)のいずれかに記載の食肉様乳化組成物を加熱処理して製造される、食肉様加工食品。
(XV)
破断強度が320g~1200gである、(XIV)に記載の食肉様加工食品。
(XVI)
食肉様加工食品がハムまたはソーセージ様加工食品である、(XIV)または(XV)に記載の食肉様加工食品。
(XVII)
A.全タンパク成分、可食性油脂および水を加温処理することなく混合して乳化し、食肉様乳化組成物を調製する工程、
B.食肉様乳化組成物をケーシングに充填する工程、および
C.ケーシングに充填したものを加熱処理し、食肉様加工食品を得る工程、
を含む、(XIV)~(XVI)のいずれかに記載の食肉様加工食品の製造方法。
(XVIII)
(XVII)の製造方法にて得られる、食肉様加工食品。
(I)
A meat-like emulsified composition containing a water-soluble milk protein and an edible fat.
(II)
The meat-like emulsified composition according to (I) above, which contains, as the water-soluble milk protein, at least one selected from the group consisting of water-soluble casein protein and whey protein.
(III)
The meat-like emulsified composition according to (II), wherein the water-soluble casein protein contains at least one selected from the group consisting of sodium caseinate, potassium caseinate, calcium caseinate and magnesium caseinate.
(IV)
The meat-like emulsion composition according to any one of (I) to (III), wherein the weight ratio of water-soluble milk protein to total protein component is 0.18 to 1.0 on a protein basis.
(V)
The meat-like emulsion composition according to any one of (I) to (IV), wherein the content of water-soluble milk protein in the meat-like emulsion composition is 1.1% by weight to 16% by weight on a protein basis.
(VI)
The meat-like emulsified composition according to any one of (II) to (V), wherein the weight ratio of water-soluble casein protein to all protein components is 0.16 to 0.66 on a protein basis.
(VII)
The meat-like emulsion composition according to any one of (II) to (VI), wherein the content of water-soluble casein protein in the meat-like emulsion composition is 1.0% by weight to 10% by weight on a protein basis.
(VIII)
The meat-like emulsion composition according to any one of (I) to (VII), wherein the content of edible oil in the meat-like emulsion composition is 2% to 40% by weight.
(IX)
The meat-like emulsified composition according to any one of (I) to (VIII), further comprising egg white protein.
(X)
The weight ratio of egg white protein to the total protein component is 0.8 or less (but not 0) on a protein basis, and the weight ratio of water-soluble milk protein to the total protein component is 0.18 to less than 1.0 on a protein basis. The meat-like emulsion composition according to (IX).
(XI)
The meat-like emulsified composition according to any one of (I) to (X), further comprising starch or polysaccharide thickener.
(XII)
The meat-like emulsion composition according to any one of (I) to (XI), wherein the content of the edible fat in the meat-like emulsion composition is 2% to 25% by weight.
(XIII)
The meat-like emulsified composition according to any one of (I) to (XII), which further contains soybean protein as a protein component and is the case of any one of 1) or 2) below:
1) The weight ratio of soy protein to the total protein component is 0.1 or less (but not 0) on a protein basis, and the weight ratio of water-soluble milk protein to the total protein component is 0.9 or less on a protein basis ( However, it is not 0), and the content of edible fats and oils in the meat-like emulsified composition is 30% by weight or less.
2) It further contains egg white protein as a protein component, the weight ratio of soy protein to the total protein component is 0.5 or less (but not 0) on a protein basis, and the weight ratio of the egg white protein to the total protein component. is 0.8 or less (but not 0) on a protein basis, and the weight ratio of water-soluble milk protein to the total protein component is 0.18 to less than 1.0 on a protein basis, and a meat-like emulsified composition The content of edible fats and oils is in the range of 2% to 30% by weight.
(XIV)
A meat-like processed food produced by heat-treating the meat-like emulsified composition according to any one of (I) to (XIII).
(XV)
The meat-like processed food according to (XIV), which has a breaking strength of 320 g to 1200 g.
(XVI)
The meat-like processed food according to (XIV) or (XV), wherein the meat-like processed food is ham- or sausage-like processed food.
(XVII)
A. A step of mixing and emulsifying all protein components, edible fats and oils and water without heat treatment to prepare a meat-like emulsified composition;
B. B. filling the casing with the meat-like emulsified composition; a step of heat-treating the casing-filled product to obtain a meat-like processed food;
A method for producing a meat-like processed food according to any one of (XIV) to (XVI), comprising
(XVIII)
A meat-like processed food obtained by the production method of (XVII).

本発明の食肉様乳化組成物を調製することで、タンパク由来の臭気による風味が改善された、肉含有食品と同様の食感と風味を有する食肉様加工食品を得ることができる。 By preparing the meat-like emulsified composition of the present invention, it is possible to obtain a meat-like processed food in which the flavor due to protein-derived odor is improved and which has the same texture and flavor as meat-containing foods.

本発明の食肉様乳化組成物および食肉様加工食品について説明する。
本発明の食肉様乳化組成物は、水溶性乳タンパクを含有する成分、および可食性油脂を含有することを特徴とする。
The meat-like emulsified composition and meat-like processed food of the present invention will be described.
The meat-like emulsified composition of the present invention is characterized by containing a component containing a water-soluble milk protein and edible fats and oils.

本発明に用いる水溶性乳タンパクは、水溶性カゼインタンパクおよびホエイタンパクのいずれか一方、またはその両方を含有することを意味する。すなわち、本発明における水溶性乳タンパクは、水溶性カゼインタンパクおよびホエイタンパクからなる群から選択される少なくとも一種を含有する。水溶性乳タンパクとして、水溶性カゼインタンパクとホエイタンパクの両方を含有する素材や原料を使用することもできる。市販品として、水溶性乳タンパク質を85重量%含有し、水溶性乳タンパクとしてミセル性カゼインおよびホエイタンパクを含有する「Refit MCI 88(FrieslandCampina DOMO社製)」を挙げることができる。 The water-soluble milk protein used in the present invention means containing either or both of water-soluble casein protein and whey protein. That is, the water-soluble milk protein in the present invention contains at least one selected from the group consisting of water-soluble casein protein and whey protein. Materials and raw materials containing both water-soluble casein protein and whey protein can also be used as the water-soluble milk protein. As a commercial product, "Refit MCI 88 (manufactured by FrieslandCampina DOMO)" containing 85% by weight of water-soluble milk protein and containing micellar casein and whey protein as water-soluble milk protein can be mentioned.

本発明の食肉様乳化組成物の水溶性乳タンパクの含有量としては、例えば、全タンパク質に対する水溶性乳タンパク質の重量比がタンパク質ベースで0.18~1.0が好ましく、0.37~0.91がより好ましい。また、食肉様乳化組成物に対する水溶性乳タンパクの含有量は、例えば、タンパク質ベースで1.1重量%~16重量%が好ましく、2.4重量%~8重量%がより好ましい。 The content of the water-soluble milk protein in the meat-like emulsified composition of the present invention is, for example, preferably 0.18 to 1.0, preferably 0.37 to 0.37 to 0.37, based on the weight ratio of the water-soluble milk protein to the total protein. .91 is more preferred. The content of water-soluble milk protein in the meat-like emulsified composition is, for example, preferably 1.1% to 16% by weight, more preferably 2.4% to 8% by weight, based on protein.

水溶性カゼインタンパクとは、牛乳中のカゼインタンパクを分離、分画、濃縮等の処理を行った後、乾燥することにより得られる水溶性の素材であり、例えば、カゼインナトリウム、カゼインカリウム、カゼインカルシウム、カゼインマグネシウムなどを挙げることができる。なかでも、カゼインカルシウムもしくはカゼインカリウムが好ましく、カゼインカルシウムが最も好ましい。市販品では、例えば、88.5重量%の水溶性カゼインタンパク質を含有する「カゼインカルシウムDI-8905(Arla Foods製)」や、89.5重量%の水溶性カゼインタンパク質を含有する「カゼインカリウムSpray(FrieslandCampina DMV製)」を挙げることができる。 Water-soluble casein protein is a water-soluble material obtained by drying the casein protein in milk after performing treatments such as separation, fractionation, and concentration. Examples include sodium caseinate, potassium caseinate, and calcium caseinate. , magnesium caseinate, and the like. Among them, calcium caseinate or potassium caseinate is preferred, and calcium caseinate is most preferred. Commercially available products include, for example, "Calcium Caseinate DI-8905 (manufactured by Arla Foods)" containing 88.5% by weight of water-soluble casein protein, and "Potassium Caseinate Spray" containing 89.5% by weight of water-soluble casein protein. (manufactured by FrieslandCampina DMV)”.

本発明の食肉様乳化組成物の水溶性カゼインの含有量としては、例えば、全タンパク質に対する水溶性カゼインタンパク質の重量比がタンパク質ベースで0.16~0.66が好ましく、0.25~0.60がより好ましい。また、食肉様乳化組成物に対する水溶性カゼインタンパクの含有量は、例えば、タンパク質ベースで1重量%~10重量%が好ましく、1重量%~8重量%がより好ましい。 The content of water-soluble casein in the meat-like emulsified composition of the present invention is, for example, preferably 0.16 to 0.66, more preferably 0.25 to 0.66, based on the weight ratio of water-soluble casein protein to total protein. 60 is more preferred. The content of water-soluble casein protein in the meat-like emulsified composition is, for example, preferably 1% to 10% by weight, more preferably 1% to 8% by weight, based on protein.

ホエイタンパクとは、牛乳中のホエイタンパク質を濃縮、分離、分画等の処理を行って得られる水溶性の素材であり、α-ラクトアルブミン、β-ラクトグロブリンなどを含有している。具体的には、例えば、ホエイタンパク濃縮物(Whey Protein Concentrate 以下、WPCともいう)や、ホエイタンパク分離物(Whey Protein Isolate、WPIともいう)なども用いることができる。市販品では、例えば、93.1重量%のホエイタンパク質を含有する「乳タンパクGL(日本新薬(株)製)」、91.3重量%のホエイタンパク質を含有する「エンラクトYYY(日本新薬(株)製)」、または78.4重量%のホエイタンパク質を含有する「PROGEL800(FrieslandCampina DMV製)」を挙げることができる。 Whey protein is a water-soluble material obtained by concentrating, separating, and fractionating whey protein in milk, and contains α-lactalbumin, β-lactoglobulin, and the like. Specifically, for example, whey protein concentrate (hereinafter also referred to as WPC) and whey protein isolate (also referred to as Whey Protein Isolate, WPI) can be used. Commercially available products include, for example, "Milk Protein GL (manufactured by Nippon Shinyaku Co., Ltd.)" containing 93.1% by weight of whey protein, and "Enlacto YYY (Nippon Shinyaku Co., Ltd.)" containing 91.3% by weight of whey protein. )”, or “PROGEL 800 (manufactured by FrieslandCampina DMV)” containing 78.4% by weight of whey protein.

本発明の食肉様乳化組成物のホエイタンパクの含有量としては、食肉様乳化組成物に対してタンパク質ベースで6重量%以下が好ましく、1重量%~4重量%がより好ましい。 The whey protein content of the meat-like emulsified composition of the present invention is preferably 6% by weight or less, more preferably 1% to 4% by weight, based on protein based on the meat-like emulsified composition.

本発明に用いる卵白タンパクは、鶏卵から卵白タンパク質を濃縮、分離、分画等の処理を行って得られる。市販品では、例えば、81.4重量%の卵白タンパク質を含有する「カンソウランパクH(日本新薬(株)製)」を挙げることができる。 The egg white protein used in the present invention is obtained by concentrating, separating and fractionating the egg white protein from chicken eggs. Commercially available products include, for example, “Glycyrrhiza Ranpaku H (manufactured by Nippon Shinyaku Co., Ltd.)” containing 81.4% by weight of egg white protein.

本発明に用いる大豆タンパクは、大豆から大豆タンパク質を濃縮、分離、分画等の処理を行って得られる。市販品では、例えば、88.8重量%の大豆タンパク質を含有する「ウィルプロN10(Wilmar製)」を挙げることができる。 The soybean protein used in the present invention is obtained by subjecting soybeans to treatments such as concentration, separation and fractionation of soybean protein. Commercially available products include, for example, “Wilpro N10 (manufactured by Wilmar)” containing 88.8% by weight of soybean protein.

本発明に用いる可食性油脂としては、一般に食用として利用されている油脂であれば特に限定されず、各種の油脂を用いることができる。例えば、大豆油、大豆胚芽油、サフラワー油、トウモロコシ油、ナタネ油、落花生油、綿実油、オリーブ油、ヒマワリ油、米油、液状魚油、液状鯨油、パームオレイン油、パーム油、パーム核油、ヤシ油、カカオ脂、パーム硬化油、パーム核硬化油、ヤシ硬化油、大豆硬化油、ナタネ硬化油、魚油、鯨油、魚硬化油、鯨硬化油、ラード(豚脂)、および牛脂を挙げることができ、これらを2種以上混合して用いることもできる。例えば、2種以上の可食性油脂を混合したサラダ油等を用いることもできる。 The edible fats and oils used in the present invention are not particularly limited as long as they are generally used as food, and various types of fats and oils can be used. For example, soybean oil, soybean germ oil, safflower oil, corn oil, rapeseed oil, peanut oil, cottonseed oil, olive oil, sunflower oil, rice oil, liquid fish oil, liquid whale oil, palm olein oil, palm oil, palm kernel oil, palm oil oils, cocoa butter, hardened palm, hardened palm kernel, hardened palm, hardened soybean, hardened rapeseed, fish oil, whale oil, hardened fish, hardened whale, lard, and beef tallow. It is also possible to use a mixture of two or more of these. For example, salad oil or the like in which two or more kinds of edible oils and fats are mixed can be used.

本発明の食肉様乳化組成物の可食性油脂の添加量が少ないと、物性が柔らかくなり、風味も悪くなる。特に、可食性油脂を一切加えない場合には、白色の凝集物が生成するため不適である。一方、添加量が多すぎても食感が悪くなるため適当ではない。 If the amount of edible oil added to the meat-like emulsified composition of the present invention is small, the physical properties become soft and the flavor deteriorates. In particular, when no edible oil is added, white aggregates are produced, which is not suitable. On the other hand, if the amount added is too large, it is not suitable because the texture becomes poor.

本発明の食肉様乳化組成物の可食性油脂の含有量としては、例えば、食肉様乳化組成物に対して2重量%~40重量%が好ましく、2重量%~30重量%がさらに好ましく、10重量%~25重量%がより好ましく、15重量%~25重量%が最も好ましい。
本発明の食肉様乳化組成物に卵白タンパクを含有する場合は、風味や食感を向上させる観点から、2重量%~25重量%が好ましい。
The content of edible fats and oils in the meat-like emulsified composition of the present invention is, for example, preferably 2% to 40% by weight, more preferably 2% to 30% by weight, with respect to the meat-like emulsified composition. % to 25% by weight is more preferred, and 15% to 25% by weight is most preferred.
When egg white protein is contained in the meat-like emulsified composition of the present invention, it is preferably 2% by weight to 25% by weight from the viewpoint of improving flavor and texture.

本発明において、食肉様乳化組成物の生成の妨げにならない限り、デンプンや増粘多糖類を使用してもよい。本発明の食肉様乳化組成物の風味や食感を向上させる観点から、デンプンおよび増粘多糖類を一定量含有することが好ましい。 In the present invention, starch and thickening polysaccharides may be used as long as they do not hinder the production of the meat-like emulsified composition. From the viewpoint of improving the flavor and texture of the meat-like emulsified composition of the present invention, it is preferable to contain certain amounts of starch and polysaccharide thickener.

デンプンとしては、一般に食用として利用されているデンプンであれば特に限定されず、各種のデンプンを用いることができる。例えば、コーンスターチ、ワキシーコーンスターチ、タピオカデンプン、馬鈴薯デンプン、甘藷デンプン、小麦デンプン、米デンプン、サゴデンプン、またはこれらの加工デンプンが挙げられる。加工デンプンとしては、エーテル化デンプン、エステル化デンプン、アルファ化デンプン、酸処理デンプン、酸化デンプン、架橋デンプン、油脂加工デンプンなどが挙げられる。また、上記の加工デンプンは、同種または異種の処理を2種以上組み合わせて行ったものであってもよい。また、化学的処理に加えて、湿熱処理、微粉砕処理、加熱処理、温水処理等の物理的処理を行ったものでもよい。市販品では、例えば、タピオカデンプンである「ミルフィクスD」(王子コーンスターチ社)を挙げることができる。 The starch is not particularly limited as long as it is a starch generally used for food, and various types of starch can be used. Examples include corn starch, waxy corn starch, tapioca starch, potato starch, sweet potato starch, wheat starch, rice starch, sago starch, or modified starches thereof. Modified starches include etherified starch, esterified starch, pregelatinized starch, acid-treated starch, oxidized starch, cross-linked starch, oil-modified starch, and the like. Moreover, the above-mentioned modified starch may be obtained by combining two or more of the same or different treatments. In addition to the chemical treatment, it may also be subjected to physical treatment such as wet heat treatment, pulverization treatment, heat treatment, hot water treatment, and the like. Commercially available products include, for example, tapioca starch “Milfix D” (Oji Cornstarch Co.).

本発明の食肉様乳化組成物にデンプンを使用する場合、デンプンの含有量としては、食肉様乳化組成物に対して、例えば、15重量%以下が好ましく、5重量%~10重量%がより好ましい。 When starch is used in the meat-like emulsified composition of the present invention, the content of starch is, for example, preferably 15% by weight or less, more preferably 5% to 10% by weight, relative to the meat-like emulsified composition. .

増粘多糖類としては、一般に食用として利用されている増粘多糖類であれば特に限定されず、各種の増粘多糖類を用いることができる。例えば、ウェランガム、キサンタンガム、ペクチン、カラギーナン、グアーガム、ローカストビーンガム、タマリンドガムを挙げることができ、これらを2種以上混合して用いることもできる。特に、常温の水に溶解するウェランガム、キサンタンガムが好ましい。市販品では、例えば、ウェランガムである「ビストップW」(三栄源エフ・エフ・アイ(株)製)を挙げることができる。 The polysaccharide thickener is not particularly limited as long as it is a polysaccharide thickener generally used for food, and various polysaccharide thickeners can be used. Examples thereof include welan gum, xanthan gum, pectin, carrageenan, guar gum, locust bean gum and tamarind gum, and two or more of these can be used in combination. In particular, welan gum and xanthan gum, which dissolve in water at room temperature, are preferred. Commercially available products include, for example, welan gum “Bistop W” (manufactured by San-Ei Gen FFI Co., Ltd.).

本発明の食肉様乳化組成物の増粘多糖類を使用する場合、増粘多糖類の含有量としては、使用する増粘多糖類の種類にもよるが、食肉様乳化組成物に対して0.8重量%以下が好ましく、0.2重量%~0.5重量%がより好ましい。 When using the thickening polysaccharide of the meat-like emulsified composition of the present invention, the content of the thickening polysaccharide is 0 with respect to the meat-like emulsified composition, although it depends on the type of thickening polysaccharide used. 0.8% by weight or less is preferable, and 0.2% by weight to 0.5% by weight is more preferable.

水分は、本発明の食肉様乳化組成物に含まれる。使用する原料の組成にもよるが、通常、食肉様乳化組成物は0~90重量%程度の水分を含有する。例えば、本発明の食肉様乳化組成物中、10~80重量%が好ましく、35~74重量%がより好ましく、49~66重量%がさらに好ましい。他の配合原料にもよるが、一般的に水分が少ないと食肉様乳化組成物が硬くなるため適当でなく、多すぎると柔らなくなり適当でない。
また、本発明の食肉様乳化組成物が加熱処理や凍結乾燥等の工程を経た後の、本発明食肉様加工食品の水分については、前記の水分量に比べて一般的に低下する。温度や時間等により変化するため、一定にすることは困難である。
Moisture is contained in the meat-like emulsified composition of the present invention. Depending on the composition of the raw materials used, the meat-like emulsified composition usually contains about 0 to 90% by weight of water. For example, it is preferably 10 to 80% by weight, more preferably 35 to 74% by weight, and even more preferably 49 to 66% by weight in the meat-like emulsified composition of the present invention. Although it depends on other compounding ingredients, a meat-like emulsified composition generally becomes hard when the water content is too small and is not suitable, and when the water content is too high, the composition becomes soft and unsuitable.
After the meat-like emulsified composition of the present invention has been subjected to heat treatment, freeze-drying, and the like, the water content of the meat-like processed food of the present invention generally decreases compared to the water content described above. It is difficult to make it constant because it changes depending on temperature, time, and the like.

本発明の食肉様乳化組成物は、水溶性乳タンパク、および可食性油脂を主成分として製造することができるが、タンパク成分として、水溶性乳タンパク以外に、必要に応じて卵白タンパクや大豆タンパクを混合してもよい。 The meat-like emulsified composition of the present invention can be produced using water-soluble milk protein and edible fat as main components, and the protein component may include egg white protein and soybean protein as needed in addition to water-soluble milk protein. may be mixed.

本発明の食肉様乳化組成物のタンパク成分として水溶性乳タンパク以外に卵白タンパクを使用する場合、上記の卵白タンパクを使用することが出来る。本発明の食肉様乳化組成物の卵白タンパクの含有量としては、全タンパク質に対する卵白タンパク質の重量比が、例えば、タンパク質ベースで0.8以下が好ましく、0.6以下がより好ましい。また、食肉様乳化組成物に対する卵白タンパクの含有量はタンパク質ベースで5重量%以下が好ましく、1重量%~5重量%がより好ましい。 When egg white protein is used in addition to water-soluble milk protein as the protein component of the meat-like emulsified composition of the present invention, the above egg white protein can be used. As for the content of egg white protein in the meat-like emulsified composition of the present invention, the weight ratio of egg white protein to total protein is preferably 0.8 or less, more preferably 0.6 or less, on a protein basis. The content of egg white protein in the meat-like emulsified composition is preferably 5% by weight or less, more preferably 1% to 5% by weight, based on protein.

本発明の食肉様乳化組成物のタンパク成分として乳タンパク以外に卵白タンパクおよび大豆タンパクを使用する場合、卵白タンパクは上記の卵白タンパクを使用することが出来、全タンパク質に対する卵白タンパク質の重量比は、例えば、タンパク質ベースで0.8以下が好ましく、0.6以下がより好ましい。大豆タンパクは上記の大豆タンパクを使用することが出来、全タンパク質に対する大豆タンパク質の重量比はタンパク質ベースで0.5以下が好ましく、0.3以下がより好ましい。 When egg white protein and soybean protein are used in addition to milk protein as the protein component of the meat-like emulsified composition of the present invention, the above egg white protein can be used as the egg white protein, and the weight ratio of the egg white protein to the total protein is For example, it is preferably 0.8 or less, more preferably 0.6 or less, on a protein basis. The above soybean protein can be used as the soybean protein, and the weight ratio of the soybean protein to the total protein is preferably 0.5 or less, more preferably 0.3 or less on a protein basis.

本発明の食肉様乳化組成物のタンパク成分として乳タンパク以外に大豆タンパクのみを使用する場合、大豆タンパクは上記の大豆タンパクを使用することが出来、全タンパク質に対する大豆タンパク質の重量比は、例えば、タンパク質ベースで0.1以下が好ましい。 When only soy protein is used in addition to milk protein as the protein component of the meat-like emulsified composition of the present invention, the above-mentioned soy protein can be used as the soy protein, and the weight ratio of soy protein to total protein is, for example, 0.1 or less is preferred on a protein basis.

本発明の食肉様乳化組成物には下記の官能試験に供することができる程度に食塩や調味料を添加することができる。調味料としては、ペッパーやスパイスミックスといった香辛料、パックビーフエキスやベジタブルエキス、レモンエキスといったエキス料、セロリ、タイム、ローレル、パセリといったハーブ等を加えることができる。食肉様乳化組成物に対する食塩の含有量は0.2~2.5重量%程度が好ましく、調味料の含有量は1重量%~5重量%程度がより好ましい。 Salt and seasonings can be added to the meat-like emulsified composition of the present invention to the extent that it can be subjected to the following sensory test. As seasonings, spices such as pepper and spice mix, extracts such as packed beef extract, vegetable extract and lemon extract, and herbs such as celery, thyme, laurel and parsley can be added. The salt content of the meat-like emulsified composition is preferably about 0.2 to 2.5% by weight, and the seasoning content is more preferably about 1 to 5% by weight.

本発明の食肉様加工食品は、前記の食肉様乳化組成物を混合乳化し、ケーシングに充填し、加熱処理する工程を経て製造される。次に、本発明の食肉様乳化組成物を用いた食肉様加工食品の製造工程について述べる。本発明の食肉様加工食品は、一般に知られた下記A~Cの工程を経ることにより製造することができるが、後述する実施例1~32に記載の方法によっても製造することができる。 The meat-like processed food of the present invention is produced through the steps of mixing and emulsifying the meat-like emulsified composition, filling a casing, and heat-treating. Next, the manufacturing process of the meat-like processed food using the meat-like emulsion composition of the present invention will be described. The meat-like processed food of the present invention can be produced through the generally known steps A to C below, but can also be produced by the methods described in Examples 1 to 32 below.

A.全タンパク成分、可食性油脂、および水を主成分とする原料を加温処理することなく混合して乳化し、食肉様乳化組成物を調製する工程
本工程では、使用する原料を添加する順番を問わず、一度にすべての原料を混合することが可能である。また、原料溶解時に加温処理する必要もなく、冷水でも簡便に調製が可能である。混合には、せん断能力を有する乳化機を使用することが好ましい。例えば、真空カッターなどの各種カッター、ホモミキサーなどの各種ミキサーなど、せん断能力を有する任意の公知の装置を用いることができる。例えば、「ステファンクッカー」(ステファン社製)を挙げることができる。または、プロペラ攪拌機等のせん断能力の低い攪拌機で混合した後、マイルダーやホモジナイザーなどの乳化機で別途乳化処理を行ってもよい。乳化機は4℃以下の冷水で還流した状態が好ましく、攪拌時は真空脱気することが好ましい。また、好ましい回転数は1000rpm~3000rpmであり、3分間以上攪拌することが好ましい。
A. A process for preparing a meat-like emulsified composition by mixing and emulsifying all protein ingredients, edible fats and oils, and water as main ingredients without heat treatment. Regardless, it is possible to mix all ingredients at once. In addition, there is no need for heating treatment when dissolving the raw materials, and cold water can be used for easy preparation. For mixing, it is preferred to use an emulsifier with shearing capability. For example, any known device having a shearing capability can be used, such as various cutters such as a vacuum cutter and various mixers such as a homomixer. For example, "Stephan Cooker" (manufactured by Stephan) can be mentioned. Alternatively, after mixing with a propeller stirrer or other agitator with low shearing ability, emulsification may be separately performed with an emulsifier such as a milder or homogenizer. The emulsifier is preferably in a state in which cold water of 4° C. or less is refluxed, and vacuum deaeration is preferably performed during stirring. Moreover, the rotation speed is preferably 1000 rpm to 3000 rpm, and it is preferable to stir for 3 minutes or longer.

B.食肉様乳化組成物をケーシングに充填する工程
Aの工程で調製した乳化物を充填するケーシングは、塩化ビニリデンケーシング、コラーゲン、羊腸など、任意の公知のケーシングを用いることができる。乳化物は流動性を有するため、ケーシングではなく、金型など形状の定まった容器に充填してもよい。
B. Step of Filling Casing with Meat-Like Emulsified Composition Any known casing such as vinylidene chloride casing, collagen, sheep intestine, etc. can be used as the casing filled with the emulsion prepared in step A. Since the emulsion has fluidity, it may be filled in a container with a fixed shape such as a mold instead of a casing.

C.ケーシングに充填した食肉様乳化組成物を加熱処理し、食肉様加工食品を得る工程
加熱は、レトルト加熱、熱湯中でのボイル、蒸気加熱、マイクロ波加熱等の任意の公知の方法を用いて行うことができる。例えば、120℃40分間のレトルト加熱、90℃30分間の湯浴加熱を挙げることができる。十分に加熱するため、温度は60℃以上、特に80℃~150℃が好ましい。また時間は20分間以上、30~60分間程度加熱することが望ましい。加熱後、室温で冷却してもよいが、必要であれば流水で冷却したり、凍結したりすることもできる。
C. Heat treatment of the meat-like emulsified composition filled in the casing to obtain a meat-like processed food Heating is performed by any known method such as retort heating, boiling in hot water, steam heating, microwave heating, etc. be able to. Examples include retort heating at 120°C for 40 minutes and hot water bath heating at 90°C for 30 minutes. For sufficient heating, the temperature is preferably 60°C or higher, particularly 80°C to 150°C. Moreover, the heating time is preferably 20 minutes or longer, preferably 30 to 60 minutes. After heating, it may be cooled at room temperature, but if necessary, it may be cooled with running water or frozen.

本明細書における「食肉様加工食品」は、加工食品や経口組成物の一構成として実施される態様も包含する。また、本発明の食肉様加工食品を調製後、凍結および乾燥させた状態の組成物も、本明細書における「食肉様加工食品」に含まれる。本発明の食肉様加工食品は、ハム、ハンバーグ、ソーセージ、ミートボール、ベーコン、ブロック肉、即席麺用の乾燥具材等の加工食品に用いることができるが、特にハムまたはソーセージ様加工食品として有用である。また、本発明の食肉様乳化組成物および食肉様加工食品は、食肉と混合して用いることもできる。本発明の食肉様乳化組成物および食肉様加工食品に食肉をごく少量だけ配合した食肉加工品も調製が可能である。 The term "meat-like processed food" as used herein also includes aspects implemented as one component of processed food and oral compositions. In addition, a composition obtained by freezing and drying the meat-like processed food of the present invention after preparation is also included in the "meat-like processed food" in the present specification. The meat-like processed food of the present invention can be used for processed foods such as ham, hamburgers, sausages, meatballs, bacon, meat blocks, dried ingredients for instant noodles, and is particularly useful as ham- or sausage-like processed foods. is. The meat-like emulsion composition and meat-like processed food of the present invention can also be used by mixing with meat. Processed meat products can also be prepared by adding a very small amount of meat to the meat-like emulsion composition and meat-like processed food of the present invention.

次に、実施例・比較例について説明する。なお、以下に示す実施例は、あくまで本発明の中に含まれる具体例をいくつか示したものに過ぎず、本発明は以下の実施例に限定されるものではない。 Next, examples and comparative examples will be described. The examples shown below merely show some specific examples included in the present invention, and the present invention is not limited to the following examples.

以下の実施例・比較例においては、表1~4に従って各原材料を秤量し、下記に示す方法により食肉様乳化組成物を調整した。 In the following examples and comparative examples, each raw material was weighed according to Tables 1 to 4, and a meat-like emulsified composition was prepared by the method shown below.

実施例、比較例で特に記載のない場合は以下の原料を使用した。水溶性カゼインは、カゼインカルシウムDI-8905(88.5重量%のカゼインタンパク質を含有。Arla Foods社製)、カゼインカリウムSpray(89.5重量%のカゼインタンパク質を含有。FrieslandCampina DMV社製)を使用した。ホエイタンパクは乳たん白GL(93.1重量%のホエイタンパク質を含有。日本新薬(株)製)、エンラクトYYY(91.3重量%のホエイタンパク質を含有。日本新薬(株)製)、PROGEL800(78.4重量%のホエイタンパク質を含有。FrieslandCampina DMV社製)を使用した。卵白タンパクはカンソウランパクH(81.4重量%の卵白タンパク質を含有。日本新薬(株)製)を使用した。大豆タンパクはウィルプロN10(88.8重量%の大豆タンパク質を含有。Wilmar社製)を使用した。デンプンはタピオカ由来のミルフィクスD(王子コーンスターチ(株)製)を使用した。増粘多糖類はビストップW(ウェランガム、三栄源エフ・エフ・アイ(株)製)を使用した。可食性油脂は市販のサラダ油(日清オイリオグループ(株)社製:大豆油とナタネ油の混合物)を使用した。 The following raw materials were used unless otherwise specified in Examples and Comparative Examples. As the water-soluble casein, calcium caseinate DI-8905 (containing 88.5% by weight of casein protein, manufactured by Arla Foods) and potassium casein Spray (containing 89.5% by weight of casein protein, manufactured by FrieslandCampina DMV) are used. bottom. Whey protein is milk protein GL (containing 93.1% by weight of whey protein, manufactured by Nippon Shinyaku Co., Ltd.), Enlact YYY (containing 91.3% by weight of whey protein, manufactured by Nippon Shinyaku Co., Ltd.), PROGEL800 (containing 78.4% by weight of whey protein, manufactured by FrieslandCampina DMV) was used. As the egg white protein, Glycyrrhiza Ranpaku H (containing 81.4% by weight of egg white protein, manufactured by Nippon Shinyaku Co., Ltd.) was used. Wilpro N10 (containing 88.8% by weight of soybean protein, manufactured by Wilmar) was used as the soybean protein. Milfix D (manufactured by Oji Cornstarch Co., Ltd.) derived from tapioca was used as the starch. Bistop W (welan gum, manufactured by San-Ei Gen FFI Co., Ltd.) was used as the polysaccharide thickener. As the edible oil, commercially available salad oil (manufactured by Nisshin OilliO Group Co., Ltd.: a mixture of soybean oil and rapeseed oil) was used.

<食肉様乳化組成物>
実施例・比較例に示す、本発明の食肉様乳化組成物は具体的には以下の工程を経て製造した。
1.粉体原料は事前に混合した。
2.2℃の冷水を還流したステファンクッカーに1.の原料、可食性油脂、および水を加え、真空脱気しながら1500rpmで5分間撹拌し、食肉様乳化組成物を調製した。
3.2.で調製した食肉様乳化組成物を折径50mmの塩化ビニリデンケーシングに充填し、120℃40分間または90℃30分間加熱した。
4.ケーシングに充填した充填物を流水で冷却し、食肉様加工食品を得た。
なお、得られた食肉様乳化組成物および食肉様加工食品を冷凍し、解凍した後でも物性が保持されるため、冷凍・解凍特性も具備していた。
<Meat-like emulsion composition>
Specifically, the meat-like emulsified compositions of the present invention shown in Examples and Comparative Examples were produced through the following steps.
1. The powder raw materials were premixed.
2. Add cold water at 2° C. to a refluxed Stephan cooker. , edible fats and oils, and water were added and stirred at 1500 rpm for 5 minutes while vacuum degassing to prepare a meat-like emulsified composition.
3.2. A vinylidene chloride casing having a folded diameter of 50 mm was filled with the meat-like emulsified composition prepared in 1. and heated at 120° C. for 40 minutes or 90° C. for 30 minutes.
4. The stuffing in the casing was cooled with running water to obtain a meat-like processed food.
In addition, the obtained meat-like emulsified composition and meat-like processed food were frozen and thawed, and their physical properties were retained, so they also possessed freezing and thawing properties.

得られた食肉様乳化組成物の物性評価、および官能評価については、以下に示す方法で評価した。 The obtained meat-like emulsified composition was evaluated for physical properties and sensory evaluation by the following methods.

評価項目は以下の通りである。
<物性評価>
I.破断強度
破断強度は、撹拌後加熱前の試料を折径50mmの塩化ビニリデンケーシングに充填し、所定の加熱条件で加熱し、一晩以上静置した後、得られた試料を15mmの厚さにカットし、テクスチャアナライザー(Stable Micro Systems(株)製TA.XTPLUS)で球状φ8mmのプランジャーで1mm/sにて侵入させ、破断した際の強度を破断強度とする。破断強度は、単位をg(force)に設定して測定した(1g≒0.0098N)。破断強度が、320g~1200gであった場合、適切な硬さを有していると判定した。破断強度が、350g~1000g、さらに350~950gであった場合は、より適切な硬さを有しているといえる。粘性は目視で評価した。
<官能評価>
風味・食感の評価について十分な教育を受け、経験を積んだ3名もしくは4名のモニターが官能評価を行い、その点数により評価した。評価点は平均値を四捨五入して示した。官能評価の項目は以下の通りである。
II.風味
風味は以下の4段階で評価した。タンパク臭があまり感じられなく、問題なく食べられる場合を4とし、3、4を適合範囲とした。
1:タンパク臭を非常に強く感じ、食べるのが非常に困難。
2:タンパク臭を強く感じ、食べるのが困難。
3:タンパク臭を感じるが強くはなく、かろうじて食べられる。
4:タンパク臭があまり感じられなく、問題なく食べられる。
III.食感
食感は、得られた組成物の硬さが非常にやわらかい場合を1、非常に硬い場合を5とし、5段階で評価した。3(適度な食感)に近いほど良好な食感であると評価し、2~4を適合範囲とした。
1:非常に柔らかく、好ましくない食感
2:柔らかいが、食肉加工品に近い食感
3:適度な食感
4:硬いが、食べられる。
5:非常に硬く、食べるのが困難である
IV.総合評価
A:風味が4(最適)、食感が3(最適)
B:風味が4(最適)で食感が2又は4(適)もしくは風味が3(適)で食感が3(最適)
C:風味が3(適)で食感が2又は4 (適)
D:風味が3又は4(適)だが食感が1又は5(不適)もしくは風味が1又は2 (不適)で食感が2-4(適)
E:風味が1又は2(不適)で食感が1又は5(不適)
Evaluation items are as follows.
<Physical property evaluation>
I. Breaking strength Breaking strength was measured by filling a vinylidene chloride casing with a folded diameter of 50 mm with a sample before heating after stirring, heating under predetermined heating conditions, allowing to stand overnight or more, and cutting the resulting sample into a thickness of 15 mm. It is cut, penetrated at 1 mm/s with a spherical plunger of φ8 mm with a texture analyzer (TA.XTPLUS manufactured by Stable Micro Systems Co., Ltd.), and the breaking strength is defined as the breaking strength. Breaking strength was measured by setting the unit to g (force) (1 g≈0.0098 N). When the breaking strength was 320 g to 1200 g, it was judged to have appropriate hardness. When the breaking strength is 350 g to 1000 g, and further 350 to 950 g, it can be said that the hardness is more appropriate. Viscosity was evaluated visually.
<Sensory evaluation>
Sensory evaluation was carried out by 3 or 4 monitors who were sufficiently educated and experienced in the evaluation of flavor and texture, and evaluation was made based on the score. Evaluation points are shown by rounding off the average value. The items of sensory evaluation are as follows.
II. Flavor Flavor was evaluated in the following four stages. 4 was given when the protein smell was not so noticeable and the food could be eaten without any problem, and 3 and 4 were taken as the appropriate range.
1: A very strong protein smell is felt, and it is very difficult to eat.
2: A strong protein smell is felt, and it is difficult to eat.
3: A protein smell is sensed, but it is not strong and is barely edible.
4: The protein smell is hardly felt and can be eaten without problems.
III. Texture The texture was evaluated on a 5-point scale, with 1 indicating that the hardness of the resulting composition was very soft and 5 indicating that it was extremely hard. The closer to 3 (moderate texture), the better the texture was evaluated, and 2 to 4 was defined as the appropriate range.
1: Very soft and unfavorable texture 2: Soft but texture close to processed meat 3: Moderate texture 4: Hard but edible.
5: Very hard and difficult to eat IV. Comprehensive evaluation A: Flavor is 4 (optimal), texture is 3 (optimal)
B: Flavor is 4 (optimal) and texture is 2 or 4 (suitable) or flavor is 3 (suitable) and texture is 3 (optimal)
C: Flavor is 3 (suitable) and texture is 2 or 4 (suitable)
D: Flavor is 3 or 4 (suitable) but texture is 1 or 5 (unsuitable) or flavor is 1 or 2 (unsuitable) and texture is 2-4 (suitable)
E: Flavor is 1 or 2 (unsuitable) and texture is 1 or 5 (unsuitable)

調整した各種食肉様乳化組成物において使用したタンパク成分のうち、乳タンパクのみを使用した場合の結果を表1、乳タンパク、および卵白タンパクを使用した場合の結果を表2と3、乳タンパク、大豆タンパク、および卵白タンパクを使用した場合、乳タンパクと大豆を使用した場合の結果を表4に示す。これらは上記、C.ケーシングに充填したものを加熱処理する工程を120℃40分間行った場合の結果であるが、実施例20、21、22、31、32は同様の方法により調製した各種食肉様乳化組成物の加熱処理を90℃30分間で行った場合の結果である。また、得られた食肉様乳化組成物の物性評価、および官能評価の結果を合わせて示す。 Among the protein components used in various prepared meat-like emulsified compositions, Table 1 shows the results when only milk protein was used, Tables 2 and 3 show the results when milk protein and egg white protein were used, milk protein, Table 4 shows the results when soybean protein and egg white protein were used, and when milk protein and soybean were used. These are described above in C.I. The results are the results when the step of heat-treating the stuffed casing was performed at 120° C. for 40 minutes. This is the result when the treatment was performed at 90° C. for 30 minutes. In addition, the results of physical property evaluation and sensory evaluation of the obtained meat-like emulsified composition are also shown.

Figure 0007283900000001
Figure 0007283900000001

Figure 0007283900000002
Figure 0007283900000002

Figure 0007283900000003
Figure 0007283900000003

Figure 0007283900000004
Figure 0007283900000004

本発明は、タンパク臭が少なく、風味や食感に優れた食肉様加工食品を提供することができ、食品の分野において有用である。
INDUSTRIAL APPLICABILITY The present invention can provide meat-like processed foods with less protein odor and excellent flavor and texture, and is useful in the field of foods.

Claims (7)

水溶性乳タンパク、可食性油脂および卵白タンパクを含有する肉様乳化組成物であって、
水溶性乳タンパクが水溶性カゼインタンパクを含有し、全タンパク成分に対する水溶性カゼインタンパクの重量比がタンパク質ベースで0.16~0.66であり、
食肉様乳化組成物中の可食性油脂の含有量が2重量%~40重量%であり、
全タンパク成分に対する卵白タンパクの重量比がタンパク質ベースで0.09~0.8である、
ゲル状の食肉様乳化組成物
A meat -like emulsified composition containing water-soluble milk protein , edible fat and egg white protein ,
The water-soluble milk protein contains water-soluble casein protein, and the weight ratio of the water-soluble casein protein to the total protein component is 0.16 to 0.66 on a protein basis,
The content of edible fats and oils in the meat-like emulsified composition is 2% to 40% by weight,
The weight ratio of egg white protein to the total protein component is 0.09 to 0.8 on a protein basis.
A gel-like meat-like emulsified composition .
水溶性カゼインタンパクが、カゼインナトリウム、カゼインカリウム、カゼインカルシウムおよびカゼインマグネシウムからなる群から選択される少なくとも一種を含有する、請求項に記載のゲル状の食肉様乳化組成物。 2. The gel-like meat-like emulsified composition according to claim 1 , wherein the water-soluble casein protein contains at least one selected from the group consisting of sodium caseinate, potassium caseinate, calcium caseinate and magnesium caseinate. 食肉様乳化組成物中の水溶性カゼインタンパクの含有量がタンパク質ベースで1.0重量%~10重量%である、請求項1または2に記載のゲル状の食肉様乳化組成物。 3. The gel-like meat-like emulsified composition according to claim 1 , wherein the content of water-soluble casein protein in the meat-like emulsified composition is 1.0% by weight to 10% by weight on a protein basis. さらにデンプンまたは増粘多糖類を含有する、請求項1~のいずれか一項に記載のゲル状の食肉様乳化組成物。 The gel-like meat- like emulsified composition according to any one of claims 1 to 3 , further comprising starch or polysaccharide thickener. 請求項1~のいずれか一項に記載のゲル状の食肉様乳化組成物を加熱処理して製造される食肉様加工食品であって、破断強度が320g~1200gである、食肉様加工食品A processed meat-like food produced by heat-treating the gel -like meat-like emulsified composition according to any one of claims 1 to 4 , wherein the processed meat-like food has a breaking strength of 320 g to 1200 g. food . 食肉様加工食品がハムまたはソーセージ様加工食品である、請求項5に記載の食肉様加工食品。 6. The meat-like processed food according to claim 5 , wherein the meat-like processed food is ham- or sausage-like processed food. A.全タンパク成分、可食性油脂、および水を主成分とする原料を加温処理することなく混合して乳化し、ゲル状の食肉様乳化組成物を調製する工程、
B.ゲル状の食肉様乳化組成物をケーシングに充填する工程、および
C.ケーシングに充填したゲル状の食肉様乳化組成物を加熱処理し、食肉様加工食品を得る工程、を含む、請求項5または6に記載の食肉様加工食品の製造方法。
A. A step of mixing and emulsifying raw materials containing all protein components, edible fats and oils, and water as main components without heat treatment to prepare a gel-like meat-like emulsified composition;
B. B. Filling a casing with a gelled meat-like emulsified composition; 7. The method for producing a meat-like processed food according to claim 5 or 6 , comprising the step of heat-treating the gelatinous meat-like emulsified composition filled in the casing to obtain the meat-like processed food.
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