JP2019210454A - 粘着剤組成物、粘着剤層、および保護フィルム - Google Patents
粘着剤組成物、粘着剤層、および保護フィルム Download PDFInfo
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- JP2019210454A JP2019210454A JP2019081839A JP2019081839A JP2019210454A JP 2019210454 A JP2019210454 A JP 2019210454A JP 2019081839 A JP2019081839 A JP 2019081839A JP 2019081839 A JP2019081839 A JP 2019081839A JP 2019210454 A JP2019210454 A JP 2019210454A
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- sensitive adhesive
- polyol
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- TXIYCNRKHPXJMW-UHFFFAOYSA-N nickel;1-octyl-2-(2-octylphenyl)sulfanylbenzene Chemical compound [Ni].CCCCCCCCC1=CC=CC=C1SC1=CC=CC=C1CCCCCCCC TXIYCNRKHPXJMW-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 1
- VJQGGZWPOMJLTP-UHFFFAOYSA-N octadecane-1,1-diol Chemical compound CCCCCCCCCCCCCCCCCC(O)O VJQGGZWPOMJLTP-UHFFFAOYSA-N 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
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- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
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- SNGREZUHAYWORS-UHFFFAOYSA-N perfluorooctanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SNGREZUHAYWORS-UHFFFAOYSA-N 0.000 description 1
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- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
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- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 229920006264 polyurethane film Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
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- 239000000600 sorbitol Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- LVEOKSIILWWVEO-UHFFFAOYSA-N tetradecyl 3-(3-oxo-3-tetradecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCC LVEOKSIILWWVEO-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
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- 238000012546 transfer Methods 0.000 description 1
- YJGJRYWNNHUESM-UHFFFAOYSA-J triacetyloxystannyl acetate Chemical compound [Sn+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O YJGJRYWNNHUESM-UHFFFAOYSA-J 0.000 description 1
- BDIWFCKBPZPBQT-UHFFFAOYSA-N tributyl(tributylstannylsulfanyl)stannane Chemical compound CCCC[Sn](CCCC)(CCCC)S[Sn](CCCC)(CCCC)CCCC BDIWFCKBPZPBQT-UHFFFAOYSA-N 0.000 description 1
- PWBHRVGYSMBMIO-UHFFFAOYSA-M tributylstannanylium;acetate Chemical compound CCCC[Sn](CCCC)(CCCC)OC(C)=O PWBHRVGYSMBMIO-UHFFFAOYSA-M 0.000 description 1
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- 239000002351 wastewater Substances 0.000 description 1
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- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
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Abstract
Description
ベースポリマーを含む粘着剤組成物であって、
平均一次粒子径が1nm〜300nmの金属酸化物粒子を含む。
本発明の粘着剤組成物は、ベースポリマーを含む。ベースポリマーは、1種であってもよいし、2種以上であってもよい。
金属酸化物粒子の平均一次粒子径は1nm〜300nmであり、好ましくは1nm〜250nmであり、より好ましくは1nm〜200nmであり、さらに好ましくは1nm〜175nmであり、さらに好ましくは1nm〜150nmであり、さらに好ましくは1nm〜100nmであり、特に好ましくは5nm〜75nmであり、最も好ましくは5nm〜50nmである。金属酸化物粒子の平均一次粒子径が上記範囲内にあれば、レーザー加工性により優れ、デブリの発生をより抑制し、製造工程における検査性により優れる保護フィルムに有用な粘着剤組成物を提供し得る。金属酸化物粒子の平均一次粒子径が上記範囲を外れて小さ過ぎると、平均一次粒子の凝集により見かけの粒子の大きさが粗大となり、Haze値の上昇や粘着面が荒れて保護フィルム貼り合せ時に気泡を噛み込むおそれがある。金属酸化物粒子の平均一次粒子径が上記範囲を外れて大き過ぎると、Haze値の上昇や粘着面が荒れて保護フィルム貼り合せ時に気泡を噛み込むおそれがある。
ベースポリマーは、好ましくは、ウレタンプレポリマー、ポリオール、アクリル系樹脂、ゴム系樹脂、シリコーン系樹脂から選ばれる少なくとも1種である。ベースポリマーが、ウレタンプレポリマー、ポリオール、アクリル系樹脂、ゴム系樹脂、シリコーン系樹脂から選ばれる少なくとも1種であれば、平均一次粒子径が1nm〜300nmの金属酸化物粒子と組み合わせて粘着剤組成物に含ませることにより、レーザー加工性により優れ、デブリの発生をより抑制し、製造工程における検査性により優れる保護フィルムに有用な粘着剤組成物を提供し得る。
ウレタンプレポリマーは、好ましくは、ポリウレタンポリオールであり、より好ましくは、ポリエステルポリオール(a1)またはポリエーテルポリオール(a2)を、それぞれ単独で、もしくは、(a1)と(a2)の混合物で、触媒存在下または無触媒下で、有機ポリイソシアネ−ト化合物(a3)と反応させてなるものである。
ポリオールとしては、例えば、好ましくは、ポリエステルポリオール、ポリエーテルポリオール、ポリカプロラクトンポリオール、ポリカーボネートポリオール、ひまし油系ポリオールが挙げられる。ポリオールとしては、より好ましくは、ポリエーテルポリオールである。
アクリル系樹脂としては、本発明の効果を損なわない範囲で、例えば、特開2013−241606号公報などに記載の公知のアクリル系粘着剤など、任意の適切なアクリル系粘着剤を採用し得る。
ゴム系樹脂としては、本発明の効果を損なわない範囲で、例えば、特開2015−074771号公報などに記載の公知のゴム系粘着剤など、任意の適切なゴム系粘着剤を採用し得る。これらは、1種のみであってもよいし、2種以上であってもよい。
シリコーン系粘着剤としては、本発明の効果を損なわない範囲で、例えば、特開2014−047280号公報などに記載の公知のシリコーン系粘着剤など、任意の適切なシリコーン系粘着剤を採用し得る。これらは、1種のみであってもよいし、2種以上であってもよい。
本発明の粘着剤組成物は、架橋剤を含んでいてもよい。架橋剤は、1種のみであってもよいし、2種以上であってもよい。
ベースポリマーとしてのウレタンプレポリマーおよびポリオールは、それぞれ、多官能イソシアネート化合物と組み合わせて、ウレタン系樹脂を形成するための組成物の成分となり得る。ウレタン系樹脂を形成するための組成物の成分として上記のようなものを採用することにより、そのようなベースポリマーと平均一次粒子径が1nm〜300nmの金属酸化物粒子と組み合わせて粘着剤組成物に含ませることにより、レーザー加工性により優れ、デブリの発生をより抑制し、製造工程における検査性により優れる保護フィルムに有用な粘着剤組成物を提供し得る。
ウレタンプレポリマーと多官能イソシアネート化合物を含有する組成物から形成されるウレタン系樹脂は、例えば、ウレタンプレポリマーとしてのポリウレタンポリオールと多官能イソシアネート化合物を含有する組成物から形成されるウレタン系樹脂が挙げられる。
ポリオールと多官能イソシアネート化合物を含有する組成物から形成されるウレタン系樹脂は、具体的には、好ましくは、ポリオールと多官能イソシアネート化合物を含有する組成物を硬化させて得られるウレタン系樹脂である。
本発明の粘着剤組成物は、脂肪酸エステルを含んでいてもよい。脂肪酸エステルは、1種のみであってもよいし、2種以上であってもよい。本発明の粘着剤組成物が脂肪酸エステルを含むことにより、レーザー加工性により優れ、デブリの発生をより抑制し、製造工程における検査性により優れる保護フィルムに有用な粘着剤組成物を提供し得る。
本発明の粘着剤組成物は、フルオロ有機アニオンを含むイオン性液体を含んでいてもよい。本発明の粘着剤組成物がフルオロ有機アニオンを含むイオン性液体を含むことにより、帯電防止性に非常に優れた粘着剤組成物を提供することができる。このようなイオン性液体は、1種のみであってもよいし、2種以上であってもよい。
本発明の粘着剤組成物は、フッ素系添加剤を含んでいてもよい。フッ素系添加剤は、1種のみであってもよいし、2種以上であってもよい。
本発明の粘着剤組成物は、本発明の効果を損なわない範囲で任意の適切なその他の成分を含んでいてもよい。このようなその他の成分は、1種のみであってもよいし、2種以上であってもよい。このようなその他の成分としては、例えば、他の樹脂成分、粘着付与剤、無機充填剤、有機充填剤、金属粉、顔料、箔状物、軟化剤、老化防止剤、導電剤、紫外線吸収剤、酸化防止剤、光安定剤、表面潤滑剤、レベリング剤、腐食防止剤、耐熱安定剤、重合禁止剤、滑剤、溶剤、触媒などが挙げられる。
本発明の粘着剤層は、本発明の粘着剤組成物から形成される。粘着剤層は粘着剤から構成される。
本発明の保護フィルムは、本発明の粘着剤層を有する。本発明の保護フィルムは、本発明の粘着剤層を有していれば、本発明の効果を損なわない範囲で任意の適切な他の部材を備えていてもよい。代表的には、本発明の保護フィルムは、基材層と粘着剤層を有する。
(1)粘着剤層の形成材料の溶液や熱溶融液を基材層上に塗布する方法、
(2)粘着剤層の形成材料の溶液や熱溶融液をセパレーター上に塗布して形成した粘着剤層を基材層上に移着する方法、
(3)粘着剤層の形成材料を基材層上に押出して形成塗布する方法、
(4)基材層と粘着剤層を二層または多層にて押出しする方法、
(5)基材層上に粘着剤層を単層ラミネートする方法またはラミネート層とともに粘着剤層を二層ラミネートする方法、
(6)粘着剤層とフィルムやラミネート層等の基材層形成材料とを二層または多層ラミネートする方法、
などの、任意の適切な製造方法に準じて行うことができる。
基材層は、1層のみであってもよいし、2層以上であってもよい。基材層は、延伸されたものであってもよい。
(レーザー光の照射条件)
使用したレーザー光照射装置は以下の通りである。
レーザー光源:炭酸ガスレーザー
レーザー波長:10.6m
スポット径:150μm
走査速度:400mm/sec
パワー:55W
(評価)
ポリイミド(カプトン200H、東レ・デュポン製)に保護フィルムを貼り合せ、上記レーザ光の照射条件にて25mm×35mm角にカットし、加工後のサンプル切断断面をガラスに押し付け、タックが大きい場合を不良、タックを感じない場合を良とした。
前述の加工後のサンプルをレーザー入射側からレーザー顕微鏡(VK−9500、キーエンス(株)製)にて、50倍の倍率で加工端部のレーザー入射側表面を観察した。この時画像の明るさは12dBに設定し、加工端部より280μm×150μmの範囲を撮影した。撮影後の画像を「Matrox inspector 9.0」(キヤノンITソリューションズ(株)製)を用いて2値化し、閾値0〜135の範囲で黒点(デブリ)の占める面積を算出し、以下評価基準にてデブリ発生抑制効果を判断した。
黒点(デブリ)面積割合が3.00%以下:抑制効果が○
黒点(デブリ)面積割合が3.00%を超えて4.20%以下:抑制効果が△
黒点(デブリ)面積割合が4.20%を超える:抑制効果が×
全光線透過率、Hazeは、保護フィルムを青板ガラス(松浪硝子工業製)に貼り付け、ヘイズ測定装置(村上色彩研究所製、HM−150N)を用いて、室温(23℃)にて測定した。繰り返し回数3回測定し、その平均値を測定値とした。
1L丸底セパラブルフラスコ、セパラブルカバー、分液ロート、温度計、窒素導入管、リービッヒ冷却器、バキュームシール、攪拌棒、攪拌羽が装備された重合用実験装置に、ポリプロピレングリコール(製品名「サンニックスPP−2000」、三洋化成社製):150g、ポリエステルポリオール(製品名「クラレポリオールP−2010」、クラレ社製):150g、溶剤としてトルエン(東ソー社製):110g、触媒としてジラウリン酸ジブチル錫(IV)(和光純薬工業社製):0.041gを投入し、撹拌しながら、常温で窒素置換を1時間実施した。その後、窒素流入下、攪拌しながら、ヘキサメチレンジイソシアネート(製品名「HDI」、東ソー社製):22.4gを投入し、ウォーターバスにて実験装置内溶液温度が90±2℃となるように制御しつつ、4時間保持した後、ポリプロピレングリコール(製品名「GP1000」、三洋化成社製):48.9gを投入し、ウォーターバスにて実験装置内溶液温度が90±2℃となるように制御しつつ、2時間保持した後、ヘキサメチレンジイソシアネート(製品名「HDI」、東ソー社製):3.1gを投入し、ウォーターバスにて実験装置内溶液温度が90±2℃となるように制御しつつ、2時間保持し、ウレタンプレポリマー溶液Aを得た。なお、重合途中に、重合中の温度制御および粘度上昇による撹拌性低下防止のために、適宜トルエンを滴下した。滴下したトルエンの総量は376gであった。ウレタンプレポリマー溶液Aの固形分濃度は50重量%であった。
製造例1で得られたウレタンプレポリマー溶液Aをポリマー固形分換算で100重量部と、イソシアネート系架橋剤(商品名「コロネートHX」、東ソー株式会社製)を固形分換算で3.4重量部と、耐熱安定剤(商品名「イルガノックス1010」、BASF製)を固形分換算で0.5重量部と、シリカ分散液(商品名「MEK−EC―2130Y」、日産化学工業株式会社製)を固形分換算で10重量部とを配合し、全体の固形分が45重量%となるように酢酸エチルで希釈し、粘着剤組成物(1)を得た。
得られた粘着剤組成物(1)を、ポリエステル樹脂からなる基材(商品名「T100−75S」、厚み75μm、三菱ケミカル株式会社製)に乾燥後の厚みが75μmとなるよう塗布し、乾燥温度130℃、乾燥時間3分の条件でキュアーして乾燥した。このようにして、基材上に、粘着剤組成物(1)から形成される粘着剤層(1)を作製した。
次いで、得られた粘着剤層(1)の表面に、一方の面にシリコーン処理を施した厚さ25μmのポリエステル樹脂からなるセパレーター(商品名「MRF25」、厚み25μm、三菱ケミカル社製)のシリコーン処理面を貼り合わせて、保護フィルム(1)を得た。
得られた保護フィルム(1)は、常温で7日間エージングを行い、評価を行った。剥離シートは評価の直前に剥離した。結果を表1に示した。
実施例1と同様の方法でシリカ分散液の種類および配合部数を、表1中に記載のようにして調製した粘着剤組成物(2)〜(6)を用い、実施例1と同様の方法を用いて保護フィルムを得た。さらに実施例1と同様の方法で評価を行った。結果を表1に示す。
製造例1で得られたウレタンプレポリマー溶液Aをポリマー固形分換算で100重量部と、シリカ粉末(商品名「HM−30S」、トクヤマ製)4.4部を配合し、ディスパーで1500rpm、15分撹拌し、撹拌後のウレタンプレポリマー溶液をSUS400メッシュにて濾過した。濾過後の溶液にイソシアネート系架橋剤(商品名「コロネートHX」、東ソー株式会社製)を固形分換算で3.4重量部と、耐熱安定剤(商品名「イルガノックス1010」、BASF製)を固形分換算で0.5重量部と、シリカ分散液(商品名「MEK−EC―2130Y」、日産化学工業株式会社製)を固形分換算で10重量部とを配合し、全体の固形分が45重量%となるように酢酸エチルで希釈し、粘着剤組成物(7)を得た。
得られた粘着剤組成物(7)を用い、実施例1と同様の方法を用いて保護フィルムを得た。さらに実施例1と同様の方法で評価を行った。結果を表1に示す。
実施例1と同様の方法でシリカ分散液を表1中に記載の金属酸化物分散液に置き換え、種類および配合部数を表1中に記載のようにして調製した粘着剤組成物(8)〜(26)を用い、実施例1と同様の方法を用いて保護フィルムを得た。さらに実施例1と同様の方法で評価を行った。結果を表1に示す。
シリカ分散液を配合しなかった以外は実施例1と同様に行い、粘着剤組成物(C1)を調製した。調製した粘着剤組成物(C1)を用い、実施例1と同様の方法を用いて保護フィルムを得た。さらに実施例1と同様の方法で評価を行った。結果を表1に示す。
20 粘着剤層
100 保護フィルム
Claims (7)
- ベースポリマーを含む粘着剤組成物であって、
平均一次粒子径が1nm〜300nmの金属酸化物粒子を含む、
粘着剤組成物。 - 前記ベースポリマー100重量部に対する前記金属酸化物粒子の含有割合が0.1重量部〜50重量%である、請求項1に記載の粘着剤組成物。
- 前記金属酸化物粒子がシリカである、請求項1または2に記載の粘着剤組成物。
- 前記ベースポリマーが、ウレタンプレポリマー、ポリオール、アクリル系樹脂、ゴム系樹脂、シリコーン系樹脂から選ばれる少なくとも1種である、請求項1から3までのいずれかに記載の粘着剤組成物。
- 請求項1から4までのいずれかに記載の粘着剤組成物から形成される、粘着剤層。
- 請求項5に記載の粘着剤層を有する、保護フィルム。
- Hazeが50%以下である、請求項6に記載の保護フィルム。
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Publication number | Priority date | Publication date | Assignee | Title |
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JP2009001773A (ja) * | 2007-05-21 | 2009-01-08 | Sekisui Chem Co Ltd | 半導体加工用テープ |
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WO2014065126A1 (ja) * | 2012-10-22 | 2014-05-01 | 三菱樹脂株式会社 | 透明両面粘着シート及びこれを用いた画像表示装置 |
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