JP2019180276A - Method of suppressing green leaf-like flavor of japanese pepper oil - Google Patents

Method of suppressing green leaf-like flavor of japanese pepper oil Download PDF

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JP2019180276A
JP2019180276A JP2018073529A JP2018073529A JP2019180276A JP 2019180276 A JP2019180276 A JP 2019180276A JP 2018073529 A JP2018073529 A JP 2018073529A JP 2018073529 A JP2018073529 A JP 2018073529A JP 2019180276 A JP2019180276 A JP 2019180276A
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雅典 川原
Masanori Kawahara
雅典 川原
敬之 奈須
Noriyuki Nasu
敬之 奈須
明浩 中谷
Akihiro Nakatani
明浩 中谷
茂雄 竹内
Shigeo Takeuchi
茂雄 竹内
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J Oil Mills Inc
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Abstract

To provide a method of suppressing green leaf-like flavor of Japanese pepper oil, and to provide a production method of a Japanese pepper flavor oil composition.SOLUTION: A method of suppressing green leaf-like flavor of Japanese pepper oil includes mixing 3 to 45 pts.mass of red pepper oil with 100 pts.mass of Japanese pepper oil. A production method of a Japanese pepper flavor oil composition includes a step of mixing 3 to 45 pts.mass of red pepper oil with 100 pts.mass of Japanese pepper oil, wherein the Japanese pepper oil is obtained by steps including: (a1) a step of obtaining Japanese pepper mixed oil by mixing 1 to 12 pts.mass of one or two kinds selected from fruits or fruit skins of Japanese pepper with 100 pts.mass of edible oil; (a2) a step of maintaining the Japanese pepper mixed oil at 50 to 90°C; and (a3) a step of removing a solid content from the maintained Japanese pepper mixed oil, and red pepper oil is obtained by steps including: (b1) a step of obtaining red pepper mixed oil by mixing 1 to 18 pts.mass of red pepper with 100 pts.mass of edible oil; (b2) a step of maintaining the red pepper mixed oil at 100 to 180°C; and (b3) a step of removing a solid content from the maintained red pepper mixed oil.SELECTED DRAWING: None

Description

本発明は、山椒油の青葉様風味を抑制する方法及び風味に優れた山椒風味油脂組成物の製造方法である。   The present invention is a method for suppressing the green leaf-like flavor of yam oil and a method for producing a yam-flavored oil and fat composition excellent in flavor.

従来から、山椒の代表的な風味として、フレッシュな柑橘類のような柑橘様風味及び摘みたての青葉のような青葉様風味が知られている。   Conventionally, citrus-like flavors such as fresh citrus fruits and green leaf-like flavors such as freshly picked green leaves are known as representative flavors of yam.

各風味の強度は、原料となる山椒の産地や、成熟度合によって異なる。青葉様風味が強すぎる場合には、柑橘様風味が感じにくくなるため、調理現場においては、柑橘様風味と青葉様風味のバランスを考慮して、適用する食品に最適な風味を有する山椒を選択することが行われてきた。   The intensity of each flavor varies depending on the production area of the raw yam and the maturity. When the green leaf-like flavor is too strong, it becomes difficult to feel the citrus-like flavor, so at the cooking site, consider the balance between the citrus-like flavor and the green leaf-like flavor, and select the yam that has the optimum flavor for the food to be applied Has been done.

工業的に山椒油を製造する場合には、原料に最適な山椒を安定的に確保し続けることは、季節的な課題、気候的な課題又はコスト的な課題から容易ではない。原料の青葉様風味が強すぎる場合には、当該原料より得た山椒油の青葉様風味を抑制することが求められていた。   In the case of industrially producing yam oil, it is not easy to stably secure the optimum yam for the raw material due to seasonal problems, climatic problems, or cost problems. When the green leaf-like flavor of the raw material is too strong, it has been required to suppress the green leaf-like flavor of the yam oil obtained from the raw material.

特許文献1には、青花椒油抽出物に胡椒、パプリカ、カルダモン、セロリ、カシア、ニンニク及びチリオレオレジンから選択されるオレオレジンを添加することにより、花椒芳香及び香味を増強することが記載されている。しかしながら、特許文献1には、山椒油の青葉様風味を抑制することについては一切記載されておらず、示唆すらない。   Patent Document 1 describes that the fragrance and flavor of florets are enhanced by adding oleoresin selected from pepper, paprika, cardamom, celery, cassia, garlic and chillioleoresin to the blue flower bud oil extract. ing. However, Patent Document 1 does not describe or suggest any suppression of the green leaf-like flavor of yam oil.

特開2016−517689号公報JP, 2006-517689, A

そこで、本発明においては、山椒油の青葉様風味の抑制方法及び山椒風味油脂組成物の製造方法を提供することを目的とする。   Therefore, an object of the present invention is to provide a method for suppressing the green leaf-like flavor of yam oil and a method for producing a yam flavor oil and fat composition.

本発明者等は、鋭意検討の結果、山椒油に所定量の唐辛子油を配合することにより、青葉様風味の抑制が可能であることを見出し、本発明を完成させた。   As a result of intensive studies, the present inventors have found that a green leaf-like flavor can be suppressed by adding a predetermined amount of chili oil to yam oil, and completed the present invention.

本発明の山椒油の青葉様風味の抑制方法は、山椒油100質量部に対して、唐辛子油を3質量部以上45質量部以下配合することを特徴とする。   The method for suppressing the green leaf-like flavor of yam oil of the present invention is characterized in that chili oil is blended in an amount of 3 to 45 parts by mass with respect to 100 parts by mass of yam oil.

前記抑制方法は、前記山椒油の製造方法が以下の工程を含む。
(a1)食用油脂100質量部に対し、山椒の果実及び果皮から選ばれる1種または2種を、1質量部以上12質量部以下混合して山椒混合油脂を得る工程、及び、
(a2)前記山椒混合油脂を、50℃以上90℃以下の温度で保持する工程
In the suppression method, the method for producing the yam oil includes the following steps.
(A1) A step of mixing 1 part by mass or more and 12 parts by mass or less of yam fruit and pericarp with 100 parts by mass of edible oil and fat to obtain a yam mixed oil and fat, and
(A2) The process of hold | maintaining the said yam mixed oil and fat at the temperature of 50 to 90 degreeC

前記抑制方法は、前記唐辛子油の製造方法が以下の工程を含む。
(b1)食用油脂100質量部に対し、唐辛子を1質量部以上18質量部以下混合して唐辛子混合油脂を得る工程、及び、
(b2)前記唐辛子混合油脂を、100℃以上180℃以下の温度で保持する工程
In the suppression method, the method for producing chili oil includes the following steps.
(B1) A step of mixing 1 to 18 parts by mass of chili pepper with respect to 100 parts by mass of edible oil and fat to obtain a chili mixed oil and fat, and
(B2) The process of hold | maintaining the said pepper mixed oil and fat at the temperature of 100 to 180 degreeC.

本発明の山椒風味油脂組成物の製造方法は、山椒油及び唐辛子油を含む山椒風味油脂組成物の製造方法であって、前記山椒油100質量部に対して、前記唐辛子油を3質量部以上45質量部以下配合する工程を含み、
前記山椒油が、
(a1)食用油脂100質量部に対し、山椒の果実及び果皮から選ばれる1種又は2種を、1質量部以上12質量部以下混合して山椒混合油脂を得る工程、
(a2)前記山椒混合油脂を、50℃以上90℃以下の温度で保持する工程、及び、
(a3)保持した前記山椒混合油脂から、固形分を除去する工程を含む、工程から得られ、
前記唐辛子油が、
(b1)食用油脂100質量部に対し、唐辛子を1質量部以上18質量部以下混合して唐辛子混合油脂を得る工程、
(b2)前記唐辛子混合油脂を、100℃以上180℃以下の温度で保持する工程、及び、
(b3)保持した前記唐辛子混合油脂から、固形分を除去する工程を含む、工程から得られる。
The method for producing a potato-flavored oil / fat composition of the present invention is a method for producing a potato-flavored oil / fat composition containing potato oil and pepper oil, and 3 parts by mass or more of the pepper oil with respect to 100 parts by mass of the potato oil. Including the step of blending 45 parts by mass or less,
The yam oil is
(A1) A step of mixing 1 part by mass or more and 12 parts by mass or less of 1 type or 2 types selected from the fruit and pericarp of yam with respect to 100 parts by mass of edible fat and oil,
(A2) a step of holding the yam mixed oil and fat at a temperature of 50 ° C. or higher and 90 ° C. or lower; and
(A3) obtained from the step including the step of removing the solid content from the retained yam mixed oil and fat,
The chili oil is
(B1) A step of mixing 1 to 18 parts by mass of chili pepper with respect to 100 parts by mass of edible oil and fat to obtain a chili mixed oil and fat,
(B2) a step of holding the pepper mixed fat at a temperature of 100 ° C. or higher and 180 ° C. or lower; and
(B3) It is obtained from the process including the process of removing solid content from the said pepper mixed fats and oils hold | maintained.

上述の本発明の山椒油の青葉様風味の抑制方法によれば、山椒の風味のうち青葉様風味を容易に抑制することができる。
そして、本発明の山椒風味油脂組成物の製造方法によれば、柑橘様風味を維持しつつ、青葉様風味が抑制された山椒風味油脂組成物を提供することができる。
According to the above-described method for suppressing the green leaf-like flavor of the yam oil of the present invention, the green leaf-like flavor of the yam flavor can be easily suppressed.
And according to the manufacturing method of the Japanese yam flavor oil-fat composition of this invention, the Japanese yam-flavored oil-fat composition by which the green leaf-like flavor was suppressed can be provided, maintaining a citrus-like flavor.

本発明の山椒油の青葉様風味の抑制方法は、山椒油100質量部に対して、唐辛子油を3質量部以上45質量部以下、好ましくは3質量部以上35質量部以下、より好ましくは5質量部以上25質量部以下、さらに好ましくは7質量部以上15質量部以下配合するものである。   In the method for suppressing the green leaf-like flavor of Japanese yam oil of the present invention, chili oil is 3 parts by mass or more and 45 parts by mass or less, preferably 3 parts by mass or more and 35 parts by mass or less, more preferably 5 parts per 100 parts by mass of yam oil. The blending amount is from 5 parts by weight to 25 parts by weight, and more preferably from 7 parts by weight to 15 parts by weight.

なお、本発明において、山椒油とは、食用油脂に乾燥した山椒を混合し、当該食用油脂にて山椒の風味等の成分を抽出したものである。同様に、唐辛子油とは、食用油脂に乾燥した唐辛子を混合し、当該食用油脂にて唐辛子の風味等の成分を抽出したものである。   In addition, in this invention, a yam oil mixes dried yam with edible fats and oils, and extracts components, such as a flavor of yam, with the said edible fats and oils. Similarly, chili oil is a mixture of edible oil and fat mixed with dried chili and extracted components such as chili flavor from the edible oil and fat.

また、本発明の抑制方法は、山椒油の製造方法が以下の工程を含むことが好ましい。
(a1)食用油脂100質量部に対し、山椒の果実及び果皮から選ばれる1種又は2種を、1質量部以上12質量部以下、好ましくは3質量部以上12質量部以下、より好ましくは4質量部以上10質量部以下、さらに好ましくは5質量部以上8質量部以下混合して山椒混合油脂を得る工程、及び、
(a2)前記山椒混合油脂を、50℃以上90℃以下、好ましくは55℃以上85℃以下、より好ましくは60℃以上80℃以下の温度で保持する工程
Moreover, as for the suppression method of this invention, it is preferable that the manufacturing method of a yam oil includes the following processes.
(A1) One or two kinds selected from yam fruit and pericarp with respect to 100 parts by weight of edible fats and oils are 1 part by weight to 12 parts by weight, preferably 3 parts by weight to 12 parts by weight, more preferably 4 parts. A step of mixing 5 parts by weight or more and 10 parts by weight or less, more preferably 5 parts by weight or more and 8 parts by weight or less to obtain a yam mixed oil and fat, and
(A2) A step of holding the yam-mixed fat at a temperature of 50 ° C. or higher and 90 ° C. or lower, preferably 55 ° C. or higher and 85 ° C. or lower, more preferably 60 ° C. or higher and 80 ° C. or lower.

さらに、本発明の抑制方法は、唐辛子油の製造方法が以下の工程を含むことが好ましい。
(b1)食用油脂100質量部に対し、唐辛子を、1質量部以上18質量部以下、好ましくは5質量部以上18質量部以下、より好ましくは6質量部以上16質量部以下、さらに好ましくは7質量部以上13質量部以下混合して唐辛子混合油脂を得る工程、及び、
(b2)前記唐辛子混合油脂を、100℃以上180℃以下、好ましくは110℃以上160℃以下、より好ましくは120℃以上150℃以下の温度で保持する工程
Furthermore, in the suppression method of the present invention, the method for producing chili oil preferably includes the following steps.
(B1) For 100 parts by weight of edible fats and oils, 1 to 18 parts by weight, preferably 5 to 18 parts by weight, more preferably 6 to 16 parts by weight, and even more preferably 7 to 7 parts by weight. A step of mixing not less than 13 parts by mass and obtaining a pepper mixed oil and fat, and
(B2) The process of hold | maintaining the said pepper mixed fats and oils at the temperature of 100 to 180 degreeC, Preferably it is 110 to 160 degreeC, More preferably, it is 120 to 150 degreeC.

前記山椒とは、ミカン科サンショウ属(Zanthoxylum)のことであり、山椒、青花椒、赤花椒、ホワジャオ等と称される。本発明においては、食用の山椒であればいずれの品種でも用いることが可能であり、例えば、華北山椒(Zanthoxylun bungeanum)が好ましい。山椒は、フレッシュな柑橘類のような柑橘様風味と、摘みたての青葉のような青葉様風味、舌が麻痺して痺れるような独特の辛味を有している。山椒の部位は、樹皮、花弁、葉、果実又は果皮等を適用することができるが、風味の観点から山椒の果実及び果皮から選ばれる1種又は2種を原料として用いることが好ましい。また、山椒の水分含量は、15質量%以下であることが好ましく、下限は特にないが、例えば0質量%以上である。山椒は、必要に応じて、粉砕して用いることができるが、風味の揮発を抑制する観点から、石臼式粉砕等の低温粉砕法を採用することが好ましい。粒度は、10メッシュ篩下50メッシュ篩上が好ましい。   The above-mentioned yam refers to the genus Zanthoxylum, and is referred to as yam, blue flower basket, red flower basket, huajao and the like. In the present invention, any variety can be used as long as it is an edible yam. For example, Zanthoxylun bungeanum is preferable. The yam has a citrus-like flavor like fresh citrus, a green leaf-like flavor like freshly picked green leaves, and a unique pungent taste that numbs the tongue. Bark, petal, leaf, fruit, or skin can be applied to the portion of the yam, but from the viewpoint of flavor, it is preferable to use one or two kinds selected from yam fruit and pericarp as the raw material. The water content of the yam is preferably 15% by mass or less, and there is no particular lower limit, but it is, for example, 0% by mass or more. The yam can be used after being pulverized if necessary, but it is preferable to employ a low-temperature pulverization method such as a stone mill type pulverization from the viewpoint of suppressing volatilization of flavor. The particle size is preferably 10 mesh and 50 mesh.

前記唐辛子とは、ナス科トウガラシ属(Capsicum)及び、その同属植物のことであり、唐辛子、蕃椒、赤トウガラシ、カプシカムペッパー等と称される。本発明においては、食用に用いられる唐辛子であれば、いずれの品種でも用いることができる。唐辛子の部位は、果実を用いることができる。また、唐辛子の水分含量は、15質量%以下であることが好ましく、下限は特にないが、例えば0質量%以上である。唐辛子は、必要に応じて、既知の方法にて粉砕して用いることができる。粒度は、20メッシュ篩下40メッシュ篩上が好ましい。   The chili pepper refers to the genus Capsicum and the plants belonging to the same family, and is referred to as chili pepper, persimmon, red chili pepper, capsicum pepper and the like. In the present invention, any variety can be used as long as it is used for food. A fruit can be used for the part of a chili pepper. Moreover, it is preferable that the water | moisture content of a chili is 15 mass% or less, and although there is no minimum in particular, it is 0 mass% or more, for example. The chili can be used after being pulverized by a known method, if necessary. The particle size is preferably 20 mesh and 40 mesh.

前記食用油脂としては、特に限定されないが、例えば、菜種油、大豆油、コーン油、ヤシ油、パーム油、パーム核油、サル脂、カカオ脂、シア油、米油、綿実油、紅花油、ヒマワリ油、オリーブ油、亜麻仁油、落花生油などの植物油脂、牛脂、豚脂、鶏脂、乳脂、魚油などの動物油脂、中鎖脂肪酸トリグリセリドなどの合成油脂が挙げられる。また、これらの分別油、エステル交換油、水素添加油脂などの加工油脂を使用することができる。前記食用油脂は、これらの油脂から一種または二種以上を選択して用いることができるが、菜種油、大豆油、コーン油、パームオレイン、牛脂及び豚脂から選ばれる一種または二種以上を含むものが好ましく、特に菜種油が好ましい。前記食用油脂は、通常の工程にて精製を施されていることが好ましい。   The edible oil and fat is not particularly limited. For example, rapeseed oil, soybean oil, corn oil, palm oil, palm oil, palm kernel oil, monkey fat, cacao butter, shea oil, rice oil, cottonseed oil, safflower oil, sunflower oil And vegetable oils such as olive oil, linseed oil and peanut oil, beef fat, pork fat, chicken fat, milk fat, fish oil and other animal fats, and synthetic fats such as medium chain fatty acid triglycerides. Moreover, processing oils and fats, such as these fractionation oil, transesterification oil, and hydrogenated oil, can be used. The edible fats and oils can be used by selecting one or more kinds from these fats and oils, and those containing one or more kinds selected from rapeseed oil, soybean oil, corn oil, palm olein, beef tallow and pork fat Rapeseed oil is particularly preferable. It is preferable that the said edible fat is refine | purified in the normal process.

また、前記食用油脂のヨウ素価は、好ましくは30以上180以下であり、より好ましくは40以上160以下であり、さらに好ましくは80以上150以下である。   The iodine value of the edible fat is preferably 30 or more and 180 or less, more preferably 40 or more and 160 or less, and still more preferably 80 or more and 150 or less.

本発明の山椒風味油脂組成物の製造方法は、山椒油及び唐辛子油を含む山椒風味油脂組成物の製造方法であって、前記山椒油100質量部に対して、前記唐辛子油を3質量部以上45質量部以下、好ましくは3質量部以上35質量部以下、より好ましくは5質量部以上25質量部以下、さらに好ましくは7質量部以上15質量部以下配合する工程を含む。   The method for producing a potato-flavored oil / fat composition of the present invention is a method for producing a potato-flavored oil / fat composition containing potato oil and pepper oil, and 3 parts by mass or more of the pepper oil with respect to 100 parts by mass of the potato oil. 45 parts by mass or less, preferably 3 parts by mass or more and 35 parts by mass or less, more preferably 5 parts by mass or more and 25 parts by mass or less, and further preferably 7 parts by mass or more and 15 parts by mass or less.

また、本発明の製造方法は、前記山椒油が以下の工程から得られる。
(a1)食用油脂100質量部に対し、山椒の果実又は果皮から選ばれる1種又は2種を、1質量部以上12質量以下、好ましくは3質量部以上12質量以下、より好ましくは4質量部以上10質量部以下、さらに好ましくは5質量部以上8質量部以下混合して山椒混合油脂を得る工程
(a2)前記山椒混合油脂を、50℃以上90℃以下、好ましくは55℃以上85℃以下、より好ましくは60℃以上80℃以下の温度で保持する工程、及び、
(a3)保持した前記山椒混合油脂から、固形分を除去する工程
In the production method of the present invention, the yam oil is obtained from the following steps.
(A1) One or two kinds selected from yam fruit or pericarp with respect to 100 parts by weight of edible fats and oils are 1 part by weight to 12 parts by weight, preferably 3 parts by weight to 12 parts by weight, more preferably 4 parts by weight. Step of mixing 10 parts by mass or less, more preferably 5 parts by mass or more and 8 parts by mass or less to obtain a yam mixed oil or fat (a2) 50 to 90 ° C., preferably 55 to 85 ° C. More preferably, a step of holding at a temperature of 60 ° C. or higher and 80 ° C. or lower, and
(A3) The process of removing solid content from the said yam mixed fats and oils hold | maintained

前記(a1)工程における食用油脂の温度は、特に限定されないが、好ましくは0℃以上90℃以下、より好ましくは15℃以上80℃以下、さらに好ましくは15℃以上60℃以下、さらにより好ましくは15℃以上50℃以下、特に好ましくは30℃以上45℃以下である。   The temperature of the edible oil and fat in the step (a1) is not particularly limited, but is preferably 0 ° C. or higher and 90 ° C. or lower, more preferably 15 ° C. or higher and 80 ° C. or lower, further preferably 15 ° C. or higher and 60 ° C. or lower, and even more preferably It is 15 to 50 ° C., particularly preferably 30 to 45 ° C.

前記(a2)工程においては、山椒混合油脂を撹拌しながら前記温度にて保持することが好ましい。前記温度での保持時間は、0分超200分以下であることが好ましく、5分以上120分以下であることがより好ましく、10分以上60分以下であることがさらに好ましく、20分以上50分以下であることがさらにより好ましく、15分以上45分以下であるこが特に好ましい。   In the step (a2), it is preferable to hold the yam mixed oil and fat at the temperature while stirring. The holding time at the temperature is preferably more than 0 minutes and not more than 200 minutes, more preferably not less than 5 minutes and not more than 120 minutes, further preferably not less than 10 minutes and not more than 60 minutes, more preferably not less than 20 minutes and not more than 50 minutes. Even more preferably, it is even more preferably 15 minutes or less and 45 minutes or less.

前記(a2)工程後、好ましくは3時間以上24時間以下、より好ましくは6時間以上24時間以下、さらに好ましくは8時間以上15時間以下、山椒混合油脂の状態を保持した後、前記(a3)工程を開始することが好ましい。   After the step (a2), preferably 3 hours or more and 24 hours or less, more preferably 6 hours or more and 24 hours or less, and further preferably 8 hours or more and 15 hours or less, after maintaining the state of the yam mixed fats and oils (a3) It is preferable to start the process.

さらに、本発明の製造方法は、前記唐辛子油が以下の工程から得られる。
(b1)食用油脂100質量部に対し、唐辛子を1質量部以上18質量部以下、好ましくは5質量部以上18質量部以下、より好ましくは6質量部以上16質量部以下、さらに好ましくは7質量部以上13質量部以下混合して唐辛子混合油脂を得る工程
(b2)前記唐辛子混合油脂を、100℃以上180℃以下、好ましくは110℃以上160℃以下、より好ましくは120℃以上150℃以下の温度で保持する工程、及び、
(b3)保持した前記唐辛子混合油脂から、固形分を除去する工程
Furthermore, in the production method of the present invention, the chili oil is obtained from the following steps.
(B1) 1 to 18 parts by mass, preferably 5 to 18 parts by mass, more preferably 6 to 16 parts by mass, and more preferably 7 parts by mass with respect to 100 parts by mass of edible fats and oils (B2) 100 to 180 ° C., preferably 110 to 160 ° C., more preferably 120 to 150 ° C. Holding at temperature, and
(B3) The process of removing solid content from the said pepper mixed fats and oils hold | maintained

前記(b1)工程における食用油脂の温度は、特に限定されないが、好ましくは0℃以上180℃以下、より好ましくは50℃以上170℃以下、さらに好ましくは80℃以上150℃以下、さらにより好ましくは90℃以上140℃以下である。   The temperature of the edible oil and fat in the step (b1) is not particularly limited, but is preferably 0 ° C. or higher and 180 ° C. or lower, more preferably 50 ° C. or higher and 170 ° C. or lower, still more preferably 80 ° C. or higher and 150 ° C. or lower, even more preferably It is 90 degreeC or more and 140 degrees C or less.

前記(b2)工程においては、唐辛子混合油脂を撹拌しながら前記温度にて保持することが好ましい。   In the step (b2), it is preferable to hold the pepper mixed oil and fat at the temperature while stirring.

また、前記(a3)工程又は前記(b3)工程は、周知の方法によって固形分を除去することが可能である。その方法を限定するものではないが、例えば、前記山椒混合油脂又は前記唐辛子混合油脂から、濾過分離、静置分離、遠心分離又はこれらを組み合わせた方法によって固形分を取り除き、山椒油又は唐辛子油を得ることができる。   In the step (a3) or the step (b3), the solid content can be removed by a known method. Although the method is not limited, for example, solid content is removed from the yam-mixed oil or fat or the chili-mixed fat by filtration, stationary separation, centrifugation, or a combination of these, Obtainable.

山椒油に対して唐辛子油を配合する工程においては、山椒油の風味が損なわれることを抑制する観点から、唐辛子油の温度が10℃以上70℃以下であることが好ましく、10℃以上60℃以下であることがより好ましく、さらに好ましくは10℃以上50℃以下である。   In the step of blending chili oil with yam oil, the temperature of chili oil is preferably 10 ° C. or higher and 70 ° C. or lower, from the viewpoint of suppressing the deterioration of the flavor of yam oil. More preferably, it is 10 degreeC or more and 50 degrees C or less.

本発明の製造方法には、必要に応じて、通常、食用の油脂組成物に配合される成分を、発明の効果を損なわない範囲において添加する工程を設けてもよい。例えば、トコフェロール、アスコルビン酸パルミテート、ローズマリー抽出物、茶抽出物、甘草抽出物等の酸化防止剤;クエン酸やリンゴ酸等の金属キレート剤;ビタミンA、ビタミンD等のビタミン類;香料等を添加する工程である。   If necessary, the production method of the present invention may be provided with a step of adding components that are usually blended in an edible oil or fat composition within a range that does not impair the effects of the invention. For example, antioxidants such as tocopherol, ascorbyl palmitate, rosemary extract, tea extract, licorice extract; metal chelating agents such as citric acid and malic acid; vitamins such as vitamin A and vitamin D; It is a process of adding.

以下に、本発明の実施例について説明するが、これに限定するものではない。まず、本実施例に用いた山椒風味油脂組成物の製造方法を説明する。   Examples of the present invention will be described below, but the present invention is not limited thereto. First, the manufacturing method of the Japanese yam flavor oil-fat composition used for the present Example is demonstrated.

(A)山椒油の調製
(原料)
山椒1:四川花椒末、株式会社カネカサンスパイス製(水分含量14%質量以下、粒度16メッシュ通過品)
山椒2:山椒コースA1、株式会社カネカサンスパイス製(水分含量14%質量以下、粒度20メッシュ通過品)
精製菜種油:さらさらキャノーラ油、株式会社J−オイルミルズ製(ヨウ素価112)
(調製方法)
2000mL容三つ口フラスコに入れた精製菜種油1000gをオイルバスにて加熱し、精製菜種油が40℃に達したら山椒1を33gと山椒2を33g投入して山椒混合菜種油とした。撹拌しながら山椒混合菜種油が70℃に達するまで加熱した。70℃に達したら撹拌しながら30分間その状態を保持した。保持後、オイルバスから取り出し、山椒混合菜種油が50℃になるまで撹拌しながら自然冷却した。50℃まで温度が低下したら、撹拌を停止し、12時間静置した。静置後、遠心分離機(3000rpm、3分)にて山椒混合菜種油を遠心分離した後、目開き100μmのストレーナーに通して固形分を除去し、山椒油を得た。
(A) Preparation of yam oil (raw material)
Yamabuchi 1: Sichuan Hanada powder, manufactured by Kaneka Sun Spice Co., Ltd. (water content 14% mass or less, particle size 16 mesh passing product)
Yamagata 2: Yamazaki Course A1, manufactured by Kaneka Sun Spice Co., Ltd. (water content 14% mass or less, particle size 20 mesh passing product)
Refined rapeseed oil: Sarasara canola oil, manufactured by J-Oil Mills Co., Ltd. (iodine value 112)
(Preparation method)
1000 g of refined rapeseed oil placed in a 2000 mL three-necked flask was heated in an oil bath, and when the refined rapeseed oil reached 40 ° C., 33 g of yam 1 and 33 g of yam 2 were added to form a mixed rapeseed oil. While stirring, the yam mixed rapeseed oil was heated until it reached 70 ° C. When the temperature reached 70 ° C., the state was maintained for 30 minutes with stirring. After holding, it was taken out from the oil bath and naturally cooled with stirring until the rapeseed mixed rapeseed oil reached 50 ° C. When the temperature dropped to 50 ° C., stirring was stopped and the mixture was allowed to stand for 12 hours. After standing, the mixed rapeseed oil was centrifuged with a centrifuge (3000 rpm, 3 minutes), and then the solid content was removed by passing through a strainer with an opening of 100 μm to obtain potato oil.

(B)唐辛子油の調製
(原料)
唐辛子1:赤唐辛子末S50、株式会社カネカサンスパイス製(水分含量14質量%以下、粒度30メッシュ通過品)
唐辛子2:赤唐辛子末ROK−50、株式会社カネカサンスパイス製(水分含量14質量%以下、粒度30メッシュ通過品)
精製菜種油:さらさらキャノーラ油、株式会社J−オイルミルズ製(ヨウ素価112)
(調製方法)
2000mL容三つ口フラスコに入れた精製菜種油1000gをオイルバスにて加熱し、精製菜種油が90℃に達したら唐辛子1を71gと唐辛子2を29g投入して唐辛子混合菜種油とした。撹拌しながら唐辛子混合菜種油が140℃に達するまで加熱した。140℃に達したらオイルバスから取り出し、2時間静置させた。静置後、ステンレス製メッシュで濾過した後、12時間自然冷却した。冷却後、目開き75μmのストレーナーに通して固形分を除去して唐辛子油を得た。
(B) Preparation of chili oil (raw material)
Pepper 1: Red Pepper Powder S50, manufactured by Kaneka Sun Spice Co., Ltd. (moisture content 14% by mass or less, product with a particle size of 30 mesh)
Pepper 2: red pepper powder ROK-50, manufactured by Kaneka Sun Spice Co., Ltd. (water content 14 mass% or less, particle size 30 mesh pass product)
Refined rapeseed oil: Sarasara canola oil, manufactured by J-Oil Mills Co., Ltd. (iodine value 112)
(Preparation method)
1000 g of refined rapeseed oil placed in a 2000 mL three-necked flask was heated in an oil bath. When the refined rapeseed oil reached 90 ° C., 71 g of chili 1 and 29 g of chili 2 were added to make a mixed rapeseed oil of chili. The mixture was heated with stirring until the pepper mixed rapeseed oil reached 140 ° C. When it reached 140 ° C., it was removed from the oil bath and allowed to stand for 2 hours. After standing, the mixture was filtered through a stainless steel mesh and then naturally cooled for 12 hours. After cooling, the mixture was passed through a strainer having an opening of 75 μm to remove solids, thereby obtaining chili oil.

(C)山椒風味油脂組成物の調製
前記(A)山椒油の調製方法によって得た20℃の山椒油に対して、前記(B)唐辛子油の調製方法によって得た20℃の唐辛子油を配合して山椒風味油脂組成物を得た。
(C) Preparation of a potato-flavored fat and oil composition Blended with a 20 ° C pepper oil obtained by the preparation method of the (B) pepper oil to the 20 ° C potato oil obtained by the preparation method of the (A) potato oil. Thus, a yam-flavored oil and fat composition was obtained.

<評価方法>
本実施例の評価方法について説明する。まず、前記山椒油、前記唐辛子油及び精製菜種油を用いて表1に示す評価指標を用意した。評価は、3人の専門パネラーの官能評価にて行った。評価手順は、評価指標の油脂を試食して、それぞれ青葉様風味、柑橘様風味及び唐辛子風味の感じ方を共有化した後、各試験油等について官能評価を行った。
<Evaluation method>
The evaluation method of a present Example is demonstrated. First, the evaluation index shown in Table 1 was prepared using the said yam oil, the said chili oil, and refined rapeseed oil. Evaluation was performed by sensory evaluation of three specialized panelists. The evaluation procedure was to taste the oils and fats of the evaluation index and share the feeling of green leaf-like flavor, citrus-like flavor and chili flavor, respectively, and then sensory evaluation was performed on each test oil and the like.

各評価値は、青葉様風味、柑橘様風味及び唐辛子風味について、いずれも2以上で合格とした。また、評価値は、3人の専門パネラーの合議にて決定した。   Each of the evaluation values was 2 or more for the green leaf-like flavor, the citrus-like flavor, and the chili flavor. In addition, the evaluation value was determined by a meeting of three specialized panelists.

ここで、各風味の具体的な感じ方は、以下の通りである。
青葉様風味:摘みたての青葉様の風味
柑橘様風味:爽やかなフレッシュ感のある柑橘類の風味
唐辛子風味:唐辛子が焦げた穀物様の風味
Here, the specific way of feeling each flavor is as follows.
Green leaf-like flavor: Freshly picked green leaf-like flavor Citrus-like flavor: Fresh and fresh citrus flavor Hot pepper flavor: Grain-like flavor with burnt chili

Figure 2019180276
Figure 2019180276

<唐辛子油の配合量の検討>
前記山椒油及び前記唐辛子油を用いて、表2に示す配合比にて山椒風味油脂組成物(以降、試験油1−1乃至1−4と称する)を調製した。また、各試験油の比較対照として、前記唐辛子油に替えて精製菜種油を配合した対照油1−1乃至1−4を調製した。前記山椒風味油脂組成物及び対照油について、前記評価方法により官能評価を行った。得られた評価結果を表2に示す。
<Examination of blending amount of chili oil>
Using the yam oil and the chili oil, yam-flavored oil and fat compositions (hereinafter referred to as test oils 1-1 to 1-4) were prepared at the blending ratios shown in Table 2. Moreover, the control oil 1-1 thru | or 1-4 which mix | blended refined rapeseed oil instead of the said chili oil was prepared as a comparison control of each test oil. Sensory evaluation was performed by the said evaluation method about the said yam-flavored oil-fat composition and control oil. The obtained evaluation results are shown in Table 2.

Figure 2019180276
Figure 2019180276

青葉様風味の抑制効果は、表2に示すように、いずれの配合においても対照油に比べて試験油の方が優れていた。この結果から、唐辛子油は、精製菜種油に比べて青葉様風味の抑制効果に優れていることがわかる。特に、試験油1−2及び1−3において、唐辛子油による青葉様風味の抑制効果が顕著であった。   As shown in Table 2, the inhibitory effect of the green leaf-like flavor was superior to the test oil compared to the control oil in any formulation. From this result, it can be seen that the chili oil is more excellent in suppressing the green leaf-like flavor than the refined rapeseed oil. In particular, in test oil 1-2 and 1-3, the inhibitory effect of the green leaf-like flavor by chili oil was remarkable.

柑橘様風味の強度は、表2に示すように、いずれの配合においても対照油に比べて試験油の方が高かった。この結果から、唐辛子油は、精製菜種油と比較して柑橘様風味の発現を阻害しにくいことがわかる。   As shown in Table 2, the strength of the citrus-like flavor was higher in the test oil than in the control oil in any formulation. From this result, it can be seen that pepper oil is less likely to inhibit the expression of citrus-like flavor as compared to refined rapeseed oil.

試験油1−4においては、唐辛子が焦げたような唐辛子油の風味が強く感じられた。   In the test oil 1-4, the flavor of chili oil as if the chili was burnt was strongly felt.

上記3つの評価項目を総合して検討すると、山椒油100質量部に対して、唐辛子油を5質量部以上25質量部以下配合することで、青葉様風味、柑橘様風味及び唐辛子風味のバランスのとれた山椒風味油脂組成物が得られることが明らかとなった。   Comprehensively examining the above three evaluation items, blending 5 to 25 parts by mass of chili oil with 100 parts by mass of yam oil, the balance of green leaf-like flavor, citrus-like flavor and chili flavor It was clarified that a thick potato-flavored oil and fat composition was obtained.

<製造方法の検討>
製造方法と青葉様風味の抑制効果との関係を検討した。
(1)山椒唐辛子油1
まず、比較例1として、試験油1−2の原料比率に相当する精製菜種油、山椒及び唐辛子を用いて、前記(A)山椒油の調製に説明の方法により山椒唐辛子油1を調製した。より具体的には、300mL容三つ口フラスコ、精製菜種油182g、山椒1を10.8g、唐辛子1を1.8gとした以外は前記(A)山椒油の調製と同じ条件にて調製した。
<Examination of manufacturing method>
The relationship between the production method and the inhibitory effect of green leaf-like flavor was examined.
(1) Yam pepper oil 1
First, as Comparative Example 1, using rapeseed oil, yam, and chili corresponding to the raw material ratio of test oil 1-2, yam chili oil 1 was prepared by the method described in (A) Preparation of yam oil. More specifically, it was prepared under the same conditions as the preparation of (A) potato oil, except that a 300 mL three-necked flask, 182 g of purified rapeseed oil, 10.8 g of yam 1 and 1.8 g of chili 1 were used.

(2)山椒唐辛子油2
また、比較例2として、試験油1−2の原料比率に相当する精製菜種油、山椒及び唐辛子を用いて、前記(B)唐辛子油の調製に説明の方法により山椒唐辛子油2を調製した。より具体的には、2000mL容三つ口フラスコに替えて片手鍋、オイルバスに替えて直火コンロ、精製菜種油187g、山椒1を10.8g、唐辛子1を1.8gとした以外は前記(B)唐辛子油の調製と同じ条件にて調製した。
(2) Yam pepper oil 2
Moreover, as comparative example 2, using refined rapeseed oil corresponding to the raw material ratio of test oil 1-2, yam and chili, yam chili oil 2 was prepared by the method described in the preparation of (B) chili oil. More specifically, the above except that the 2000 mL three-necked flask was replaced with a one-handed pan, an oil bath, an open-fired stove, 187 g of refined rapeseed oil, 10.8 g of yam 1 and 1.8 g of chili 1 B) It was prepared under the same conditions as the preparation of pepper oil.

得られた山椒唐辛子油1及び山椒唐辛子油2について、前記評価方法により官能評価を行った。試験油1−2、山椒唐辛子油1及び山椒唐辛子油2の評価結果を表3に示す。   About the obtained Japanese yam pepper oil 1 and Japanese yam pepper oil 2, sensory evaluation was performed by the said evaluation method. Table 3 shows the evaluation results of test oil 1-2, yam pepper oil 1 and yam pepper oil 2.

Figure 2019180276
Figure 2019180276

表3に示すように、試験油1−2及び比較例1を比較すると、試験油1−2の方が、青葉様風味の抑制効果が高かった。比較例2は、青葉様風味及び柑橘様風味を含めた山椒の風味が感じられなかった。唐辛子風味の強度については、試験油1−2、比較例1及び比較例2において、大きな差は認められなかった。   As shown in Table 3, when test oil 1-2 and Comparative Example 1 were compared, test oil 1-2 was more effective in suppressing the green leaf-like flavor. In Comparative Example 2, the flavor of yam including a green leaf-like flavor and a citrus-like flavor was not felt. About the intensity | strength of the pepper flavor, the big difference was not recognized in the test oil 1-2, the comparative example 1, and the comparative example 2. FIG.

この結果から、山椒油に唐辛子油を配合することにより、青葉様風味、柑橘様風味及び唐辛子風味のバランスのとれた山椒風味油脂組成物を得られることが明らかとなった。   From this result, it was clarified that by adding chili oil to yam oil, a yam-flavored oil and fat composition having a balanced green leaf-like flavor, citrus-like flavor and chili flavor can be obtained.

<麻婆豆腐による評価>
麻婆豆腐に対して、試験油1−2及び1−4の山椒風味油脂組成物を添加して青葉様風味と柑橘様風味の感じ方について評価した。得られた評価結果を表4に示す。
<Evaluation by mapo tofu>
The yam-flavored oil and fat compositions of test oils 1-2 and 1-4 were added to mapo tofu, and the way of feeling the green leaf-like flavor and citrus-like flavor was evaluated. The obtained evaluation results are shown in Table 4.

麻婆豆腐は以下の材料及び手順にて調製した。
(材料)
麻婆豆腐の素中辛(丸美屋食品工業株式会社製)
豆腐450g
水180mL
トロミ粉液用の水30mL
(調製方法)
1.トロミ粉に水30mLを混ぜてトロミ粉液を調製する
2.フライパンに麻婆豆腐の素中辛と水180mLを入れて、中火で煮立たせた。
3.煮立ったら、1.5cm角にカットした豆腐を入れ、さらにひと煮立ちさせてから火を止めた。
4.トロミ粉液をよくかき混ぜてから、上記3に回しかけ、混ぜあわせた。
5.再度、中火にして煮立つまで加熱し麻婆豆腐を得た。
Mapo tofu was prepared by the following materials and procedures.
(material)
Mapo tofu with spicy spicy (Marumiya Food Industry Co., Ltd.)
Tofu 450g
180mL water
30 mL of water for trolley powder
(Preparation method)
1. 1. Mix trolley powder with 30 mL of water to prepare a trolley powder solution. Into a frying pan, put the raw medium spicy of mapo tofu and 180 mL of water and boil it over medium heat.
3. When boiled, put the tofu cut into 1.5cm square, and boiled for a while, then stopped the fire.
4). After thoroughly mixing the trolley powder solution, it was turned to 3 and mixed.
5. Again, it was heated to medium heat and boiled to obtain mapo tofu.

(官能評価)
得られた麻婆豆腐に山椒風味油脂組成物を2質量%添加し、風味について官能評価を行った。
(sensory evaluation)
To the obtained mapo tofu, 2% by mass of the yamato flavor oil and fat composition was added, and the sensory evaluation was performed on the flavor.

Figure 2019180276
Figure 2019180276

表4に示すように、試験油1−2の山椒風味油脂組成物を添加した麻婆豆腐は、爽やかでフレッシュ感のある柑橘様風味に優れた麻婆豆腐であった。一方、試験油1−4の山椒風味油脂組成物を添加した麻婆豆腐は、山椒油に由来する青葉様風味も柑橘様風味も感じられない麻婆豆腐であった。
As shown in Table 4, the mapo tofu to which the yam-flavored oil and fat composition of test oil 1-2 was added was a mapo tofu with a refreshing and fresh citrus-like flavor. On the other hand, the mapo tofu added with the potato flavor oil composition of test oil 1-4 was a mapo tofu in which neither the green leaf-like flavor nor the citrus-like flavor derived from potato oil was felt.

Claims (4)

山椒油の青葉様風味の抑制方法であって、
前記山椒油100質量部に対して、
唐辛子油を3質量部以上45質量部以下配合することを特徴とする、前記抑制方法。
A method for suppressing the green leaf-like flavor of yam oil,
For 100 parts by mass of the yam oil,
The said suppression method characterized by mix | blending 3 to 45 mass parts chili pepper oil.
前記山椒油の製造方法が以下の工程を含む、請求項1に記載の抑制方法。
(a1)食用油脂100質量部に対し、山椒の果実及び果皮から選ばれる1種又は2種を、1質量部以上12質量部以下混合して山椒混合油脂を得る工程、及び、
(a2)前記山椒混合油脂を、50℃以上90℃以下の温度で保持する工程
The suppression method of Claim 1 with which the manufacturing method of the said yam oil includes the following processes.
(A1) A step of mixing 1 part by mass or more and 12 parts by mass or less of 1 type or 2 types selected from the fruit and pericarp of yam with respect to 100 parts by mass of edible oil and fat, and obtaining a yam mixed oil and fat, and
(A2) The process of hold | maintaining the said yam mixed oil and fat at the temperature of 50 to 90 degreeC
前記唐辛子油の製造方法が以下の工程を含む、請求項1または2に記載の抑制方法。
(b1)食用油脂100質量部に対し、唐辛子を1質量部以上18質量部以下混合して唐辛子混合油脂を得る工程、及び、
(b2)前記唐辛子混合油脂を、100℃以上180℃以下の温度で保持する工程
The suppression method of Claim 1 or 2 with which the manufacturing method of the said chili oil contains the following processes.
(B1) A step of mixing 1 to 18 parts by mass of chili pepper with respect to 100 parts by mass of edible oil and fat to obtain a chili mixed oil and fat, and
(B2) The process of hold | maintaining the said pepper mixed oil and fat at the temperature of 100 to 180 degreeC.
山椒油及び唐辛子油を含む山椒風味油脂組成物の製造方法であって、
前記山椒油100質量部に対して、前記唐辛子油を3質量部以上45質量部以下配合する工程を含み、
前記山椒油が、
(a1)食用油脂100質量部に対し、山椒の果実又は果皮から選ばれる1種又は2種を、1質量部以上12質量部以下混合して山椒混合油脂を得る工程、
(a2)前記山椒混合油脂を、50℃以上90℃以下の温度で保持する工程、及び
(a3)保持した前記山椒混合油脂から、固形分を除去する工程
を含む、工程から得られ、
前記唐辛子油が、
(b1)食用油脂100質量部に対し、唐辛子を1質量部以上18質量部以下混合して唐辛子混合油脂を得る工程、
(b2)前記唐辛子混合油脂を、100℃以上180℃以下の温度で保持する工程、及び
(b3)保持した前記唐辛子混合油脂から、固形分を除去する工程を含む、工程から得られる、前記製造方法。
A method for producing a samurai-flavored oil / fat composition containing yam oil and chili oil,
Including the step of blending 3 to 45 parts by mass of the pepper oil with respect to 100 parts by mass of the yam oil,
The yam oil is
(A1) A step of mixing 1 part by mass or more and 12 parts by mass or less of 1 type or 2 types selected from the fruit or pericarp of yam with respect to 100 parts by mass of edible oil and fat,
(A2) obtained from a process including a step of holding the yam mixed fat / oil at a temperature of 50 ° C. or higher and 90 ° C. or lower, and (a3) removing a solid content from the held yam mixed fat / oil.
The chili oil is
(B1) A step of mixing 1 to 18 parts by mass of chili pepper with respect to 100 parts by mass of edible oil and fat to obtain a chili mixed oil and fat,
(B2) The production obtained from the step, comprising the step of holding the pepper mixed fat and oil at a temperature of 100 ° C. or higher and 180 ° C. or lower, and (b3) removing the solid content from the held pepper mixed fat and oil. Method.
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