JP2019125456A - Battery module - Google Patents

Abstract

To provide a battery module in which deterioration of battery performance can be suppressed by suitably controlling a restraint pressure applied to each stacked unit cell over the entire stack surface of the unit cells.SOLUTION: A battery module according to the present invention includes a laminate in which a plurality of unit cells are stacked, and a pressure adjusting member disposed in at least one of a gap between the stacked unit cells, one end in the stacking direction, and the other end, and adjusting a pressure applied in the stacking direction of the stack. The pressure adjusting member includes a back plate, a frame portion, and a plurality of protrusions, and the frame portion and the protrusions are formed of a material exhibiting rubber elasticity. Here, when the battery module is viewed in the stacking direction, the outer periphery of the stacked surface of the stacked unit cells is disposed in a region where the frame portion is formed.SELECTED DRAWING: Figure 1

Description

  The present invention relates to a battery module. Specifically, the present invention relates to a battery module that holds a plurality of single cells in a restricted state.

  Battery modules equipped with single cells such as lithium ion secondary batteries and nickel hydrogen batteries are becoming increasingly important as power supplies for vehicles mounted with electricity as a driving source, or power supplies for personal computers and portable devices. ing. In particular, a battery module using a lithium ion secondary battery, which is light in weight and capable of obtaining a high energy density, as a single battery is for driving a vehicle such as an electric vehicle (EV), a plug-in hybrid vehicle (PHV) or a hybrid vehicle (HV). It is preferable as a high output power source, and it is expected that demand will continue to expand in the future.

  As a typical configuration of such a battery module, there is one in which a plurality of single cells are stacked, and the battery module is configured to be restrained in a state where a predetermined load is applied in the stacking direction. Such restraint of the unit cells is mainly performed from the viewpoints of the vibration resistance and shock resistance of the battery module, and the battery performance securing. However, in such a battery module, a part of the unit cell expands and contracts when the battery is used (during charge and discharge) or the battery module ages and is added to the unit cell at the time of construction of the battery module. The size of the restraining load may change, and the pressure applied to the unit cell needs to be adjusted according to the change in the restraining load. Patent documents 1 and 2 are mentioned as conventional technology literature about this kind of technology.

Unexamined-Japanese-Patent No. 2017-103083 JP, 2016-18704, A

  However, there is still room for improvement in the method of adjusting the restraint pressure of the battery module in these conventional techniques. In particular, at the time of use (charge and discharge) of the battery module, the edge of the stacked surface is smaller than the central portion of the surfaces (hereinafter referred to as “stacked surface”) facing each other in the stacked direction of the stacked single cells. In the case of a battery module using a single cell which tends to be greatly expanded and shrunk, there is a possibility that sufficient restraint pressure control can not be achieved in the entire area of the laminated surface of the single cell by the prior art, resulting in a decrease in battery performance. was there.

  The present invention has been made in view of such a point, and the restraint pressure applied to each stacked unit cell is suitably controlled in the entire area of the stacking surface of the unit cell, thereby suppressing the deterioration of the battery performance. To provide a battery module that can be

  According to the present invention, it is arranged in at least one of a laminated body in which a plurality of single-electric lands are stacked, a gap between the stacked single cells, and one end and the other end in the stacking direction. There is provided a battery module comprising a pressure control member for controlling the pressure applied in the stacking direction of the stack. The pressure adjusting member is provided with a back plate, a frame portion protruding from one surface of the back plate and formed along the peripheral edge portion of the back plate, and the frame portion of the back plate. And a plurality of projections formed on the same surface as the surface and formed inside the frame portion. At least the frame portion and the projection of the pressure adjusting member are formed of a material exhibiting rubber elasticity. Further, the pressure adjustment member is disposed such that the frame portion and the projection face the side on which the laminate is positioned. Here, when the battery module is viewed from the stacking direction, an outer periphery of a stacking surface of the stacked single cells is disposed in a region where the frame portion is formed.

  According to this configuration, during use of the battery module, even if the cells constituting the module expand and contract in the stacking direction, the pressure applied in the stacking direction of the stacked body is suitably adjusted and less likely to fluctuate. Moreover, according to such a configuration, the configuration of the battery module is simplified, so that the battery module can be made compact. Furthermore, according to such a configuration, a suitable restraint pressure can be applied to the edge of the laminated surface of each unit cell by the frame portion of the pressure adjustment member, so that deterioration of the unit cell due to local expansion and contraction is achieved. It is possible to realize a battery module capable of suppressing and suppressing a decrease in battery performance.

It is a perspective view showing typically the battery module concerning one embodiment. It is II-II 'arrow sectional drawing of FIG. It is a perspective view showing a pressure control member concerning one embodiment. It is IV-IV 'arrow sectional drawing of FIG. It is a figure showing typically the important section of the pressure regulation member concerning one embodiment. It is a figure corresponded to the IV-IV 'arrow line view of FIG. 1 in the battery module which concerns on other one Embodiment.

  Hereinafter, preferred embodiments of the present invention will be described with reference to the drawings as appropriate. Matters necessary for the implementation of the present invention other than the matters specifically mentioned in the present specification can be understood as design matters for a person skilled in the art based on prior art in the art. The present invention can be implemented based on the contents disclosed in the present specification and common technical knowledge in the field. In addition, in the following drawings, the same code | symbol is attached | subjected and demonstrated to the member and site | part which show the same effect | action, and the overlapping description may be abbreviate | omitted or simplified. Also, the dimensional relationships (length, width, thickness, etc.) in the drawings do not necessarily reflect the actual dimensional relationships. Each drawing shows only an example, and each drawing does not limit the present invention unless otherwise stated.

  FIG. 1 is a perspective view schematically showing the structure of a battery module 100 according to an embodiment. FIG. 2 is a schematic view schematically showing a cross section taken along line II-II 'of FIG. As shown in FIGS. 1 and 2, the battery module 100 includes a stack 20 having a plurality of single cells 10, a pair of end plates 30A and 30B, a pair of side plates 40A and 40B, and a pressure adjustment member 60. Is equipped.

  The stacked body 20 is configured by stacking and arranging a plurality of unit cells 10 (preferably, chargeable and dischargeable unit cells 10) in a predetermined stacking direction (the arrow X direction in FIG. 1). Between the plurality of unit cells 10, a member (for example, a cooling plate or the like) other than the unit cells 10 may be interposed.

<Single cell>
The unit cell 10 is preferably an all solid battery, and more preferably an all solid lithium secondary battery or a lithium-sulfur secondary battery. All-solid-state batteries typically comprise a positive electrode, a negative electrode, and a solid electrolyte. When the unit cell 10 is an all solid battery, the stacking direction of the positive electrode, the negative electrode, and the solid electrolyte is the same as the stacking direction X of the stacked body 20. The unit cell 10 may be a non-aqueous electrolyte secondary battery. The non-aqueous electrolyte secondary battery typically includes a positive electrode, a negative electrode, a separator, and a non-aqueous electrolyte. When the unit cell 10 is a non-aqueous electrolyte secondary battery, the stacking direction of the positive electrode, the negative electrode, and the separator is the same as the stacking direction X of the stacked body 20. Therefore, according to the battery module 100 of one embodiment disclosed herein, a restraint load is applied in a direction perpendicular to the electrode surface in the unit cell 10.

  When an all solid battery is used as the unit cell 10, the surface of the unit cell 10 in the direction orthogonal to the stacking direction X of the stack 20 (that is, the in-plane direction of the YZ plane in FIG. 1) The edge of a laminated surface tends to expand and contract more than the central portion. According to the technology disclosed herein, since the restraint pressure applied to the edge of the unit cell 10 can be suitably adjusted, it is meaningful to apply the present invention to the unit cell 10 which is an all solid battery. is there.

  Also, the unit cell 10 may be a fuel cell, a nickel hydrogen battery or other secondary battery. In the present specification, the term "secondary battery" refers to a storage device in general that can be repeatedly charged and discharged, and is a term including storage devices such as so-called storage batteries and electric double layer capacitors.

  The unit cell 10 includes an exterior body 14 that accommodates therein the power generation elements such as the positive electrode, the negative electrode, and the electrolyte described above, and a positive electrode terminal 12A and a negative electrode terminal 12B drawn from the exterior body 14. According to the example shown in FIG. 1, the positive electrode terminal 12 </ b> A and the negative electrode terminal 12 </ b> B are respectively drawn from the same side of the exterior body 14.

  The positive electrode terminal 12A and the negative electrode terminal 12B of the unit cell 10 may be drawn out from the two opposing sides of the exterior body 14, respectively. The unit cell 10 can be preferably adopted from the viewpoint of improving the battery capacity and the like.

When the unit cell 10 is an all solid battery, the material used for the positive electrode constituting the unit cell 10 is not particularly limited as long as it is a material used for the positive electrode of the conventional all solid battery. it can. For example, as a positive electrode active material contained in the positive electrode, a layered, olivine-based or spinel-type compound may be used. Specifically, lithium cobaltate (LiCoO ₂ ), lithium nickelate (LiNiO ₂ ), lithium manganate (LiMnO ₂ ), nickel manganese cobaltate (LiNi _1-y-z Co _y Mn _z O ₂ , for example, LiNi) _1/3 Co _1/3 Mn _1/3 O ₂ ), lithium nickel cobaltate (LiNi _1-x Co _x O ₂ ), lithium nickel manganate (LiNi _1-x Mn _x O ₂ ), lithium manganate (LiMn) ₂ O ₄ ), lithium manganate compound (Li _{1 + x} M _y Mn _2-xy O ₄ ; M = Al, Mg, Fe, Cr, Co, Ni, Zn), lithium metal phosphate (LiMPO ₄ , M = Fe, Mn, Co, Ni), lithium metal fluorophosphate (Li ₂ MPO ₄ F, M = Fe, Mn, Co, Ni And lithium metal phosphate (Li ₂ MP ₂ O ₇ , M = Fe, Mn, Co, Ni), lithium titanate (Li _x TiO _y ) and the like. Alternatively, the positive electrode active material may contain elemental sulfur and may be sulfur (S).

  According to the technology disclosed herein, the restraint pressure applied in the stacking direction X of the stacked body 20 can be suitably adjusted even if the unit cell 10 expands and contracts when the battery is charged and discharged. For this reason, it is particularly significant to apply the technology according to the present invention to a unit cell 10 using, as a positive electrode material, sulfur (S) which tends to expand and contract greatly at the time of charge and discharge.

  When the unit cell 10 is an all solid battery, the material used for the negative electrode constituting the unit cell 10 is not particularly limited as long as it is a material used for the conventional all solid battery negative electrode it can. For example, as the negative electrode active material contained in the negative electrode, metals, carbon materials and the like can be used. Examples of the metal include metals such as Li, Sn, Si, Al, In and Sb, alloys obtained by combining some of these, and the like. As the carbon material, a carbon material containing a graphite structure (layered structure) at least partially, specifically, natural or man-made graphite, soft carbon, hard carbon, low temperature calcined carbon, or some of them The material which combined and is illustrated.

  According to the technology disclosed herein, the restraint pressure applied in the stacking direction X of the stacked body 20 can be suitably adjusted even if the unit cell 10 expands and contracts when the battery is charged and discharged. Therefore, it is possible to apply the technology according to the present invention to a unit cell 10 using, as a negative electrode material, a metal such as Sn, Si or the like which tends to expand and contract greatly at the time of charge and discharge. Especially significant.

When the unit cell 10 is an all solid battery, the solid electrolyte contained in the unit cell 10 can be used without particular limitation as long as it is a material used as a solid electrolyte of a conventional all solid battery. . For example, inorganic solid electrolytes such as sulfides and oxides may be used as the solid electrolyte. Among them, a sulfide solid electrolyte can be preferably employed. The solid electrolyte may be either crystalline, noncrystalline or glass ceramic. As a sulfide-based solid electrolyte, non-crystals such as Li ₂ S-SiS ₂ system, Li ₂ S-SiS ₂ -LiI system, Li ₂ S-SiS ₂ -Li ₃ PO ₄ system, Li ₁₀ GeP ₂ S ₁₂ etc. And glass ceramics such as Li ₇ P ₃ S ₁₁ and Li _3.25 P _0.95 S ₄ . Examples of the oxide-based solid electrolyte include La _0.51 Li _0.34 TiO _2.94 , Li _1.3 Al _0.3 Ti _1.7 (PO ₄ ) ₃ , Li ₇ La ₃ Zr ₂ O _{12 and the} like. Be done.

  The exterior body 14 is preferably thin and light, has high flexibility, can be easily fused by heat welding, ultrasonic welding or the like, and is made of a material excellent in airtightness and moisture impermeability. The exterior body 14 may be made of, for example, a laminate film having a three-layer structure in which a metal layer is disposed between two polymer resin layers. The metal layer may be made of, for example, a metal foil such as aluminum, stainless steel, nickel, copper or the like. The polymer resin layer may be made of, for example, a polyolefin such as polyethylene or polypropylene, or a thermoplastic resin film such as ethylene vinyl acetate. In the flat-shaped unit cell 10 composed of a laminate film having such an exterior body 14 as illustrated, the expansion and expansion tends to be large at the time of charge and discharge particularly at the edge of the laminated surface. It is suitable for applying such technology.

<End plate>
The pair of end plates 30A and 30B are disposed at both ends in the stacking direction X of the stacked body 20. In the present embodiment, the end plate 30A is disposed with the pressure plate 50 and the pressure adjustment member 60 interposed at one end of the laminate 20 in the stacking direction X. The end plate 30B is disposed at the other end in the stacking direction X of the stack 20. The end plates 30A and 30B are made of a material and a shape that can withstand the restraint load applied to the laminate 20. The end plates 30A, 30B may be made of metal or resin, and may be made of carbon steel, for example. The end plates 30A, 30B are formed in a plate shape.

<Side plate>
The stacked body 20 is disposed between the pair of side plates 40A and 40B. As shown in FIG. 2, the side plates 40 </ b> A and 40 </ b> B are disposed apart from the stacked body 20. The side plate 40 </ b> A and the side plate 40 </ b> B face each other through the stacked body 20. The side plates 40A and 40B connect the pair of end plates 30A and 30B, respectively. That is, the side plate 40A couples one end of the end plate 30A in the direction of arrow Z in FIG. 1 with the end of one end of the end plate 30B in the direction of arrow Z in FIG. The side plate 40B couples the other end of the end plate 30A in the direction of arrow Z in FIG. 1 to the end of the end plate 30B in the direction of arrow Z in FIG. The side plates 40A, 40B may be formed of the same material as the end plates 30A, 30B, or may be formed of different materials.

  The connection between the side plates 40A, 40B and the end plates 30A, 30B may be by fastening members such as bolts. Alternatively, the connection between the side plates 40A, 40B and the end plates 30A, 30B may be by strong bonding such as welding. When the side plates 40A, 40B and the end plates 30A, 30B are joined by welding, metals are preferably adopted as the material of the end plates 30A, 30B and the side plates 40A, 40B.

<Pressure plate>
In the embodiment shown in FIGS. 1 and 2, the pressing plate 50 is disposed adjacent to one end of the stack 20 in the stacking direction X. One end of the pressing plate 50 in the direction of arrow Z in FIG. 1 is in contact with the side plate 40A, and the other end of the pressing plate 50 in the direction of arrow Z in FIG. 1 is in contact with the side plate 40B. There is. The pressure plate 50 is disposed in a state where it is not joined to the side plates 40A and 40B, and can move reversibly in the stacking direction X in accordance with expansion and contraction of the stacked body 20 in the stacking direction X. Arranged in the state. According to the pressure plate 50, the elastic force generated by the elastic deformation of the frame portion 64A and the projection 64B of the pressure adjusting member 60 described later can be uniformly transmitted to the laminated surface of the laminated body 20.

<Pressure adjustment member>
In the embodiment shown in FIGS. 1 and 2, the pressure adjusting member 60 is disposed between one end of the laminate 20 in the stacking direction X and the end plate 30A. Specifically, the pressure adjusting member 60 is disposed between the pressure plate 50 disposed adjacent to one end of the laminate 20 in the stacking direction X and the end plate 30A. The pressure adjustment member 60 can adjust the pressure (restraint pressure) applied in the stacking direction X of the stack 20. According to this configuration, the pressure adjustment member 60 is disposed only at one end in the stacking direction X of the stacked body 20, and the configuration of the battery module 100 is simple, so downsizing of the battery module 100 is achieved. Cheap.

  FIG. 3 is a perspective view showing a pressure adjustment member 60 according to an embodiment. The pressure adjustment member 60 is provided on the same surface as the back plate 62, the frame portion 64A projecting from one surface of the back plate 62, and one surface of the back plate 62 provided with the frame portion 64A. And a plurality of projections 64B. The frame portion 64A is formed along the periphery of the back plate 62 with a predetermined width. A plurality of cylindrical projections 64 B are regularly arranged on the inside of the peripheral edge of the back plate 62.

  Here, the frame portion 64A and the projection portion 64B are each formed of a material showing rubber elasticity, and elastic deformation is caused by elastic deformation in a direction in which the frame portion 64A and the projection portion 64B are provided in a protruding manner. It is possible to occur.

  FIG. 4 is a schematic view schematically showing a cross section taken along line IV-IV 'of FIG. As shown in FIGS. 2 and 4, the pressure adjustment member 60 is disposed such that the frame portion 64A and the projection 64B face the position where the laminate 20 is positioned. The dotted line in FIG. 4 shows the outer periphery of the region where the stacked body 20 (or the unit cells 10 constituting the stacked body 20) is disposed when the battery module 100 is viewed from the stacking direction X. As shown in FIG. 4, when the battery module 100 disclosed herein is viewed from the stacking direction X, the outer edge of the stacked body 20 (or the unit cell 10) is disposed in the area where the frame portion 64A is formed. There is. That is, with the frame portion 64A, pressure is applied to the edge portion in the direction (that is, the in-plane direction of the YZ plane in FIG. 4) orthogonal to the stacking direction X of the stacked body 20 (unit cells 10) via the pressure plate 50. Can be applied. In addition, the protrusion 64 </ b> B can apply pressure to the central portion of the stacking surface of the stacked body 20 (unit cells 10) through the pressing plate 50.

  According to this configuration, the pressure adjustment member 60 can adjust the pressure applied in the stacking direction X of the stacked body 20. In particular, even in the case of using the unit cell 10 in which the edge of the unit cell 10 in the stacking surface of the stack 20 tends to expand and contract more than the central portion of the unit cell 10 in the direction, the unit cell 10 Since the pressure applied to the edge can be suitably adjusted by the action of the frame portion 64A according to the local expansion and contraction at the edge, the uniformity of the restraint pressure applied to the lamination surface of the laminate 20 is improved. For this reason, according to such a configuration, the battery module 100 in which the deterioration due to the local expansion and contraction of the unit cell 10 is suppressed can be realized.

FIG. 5 is a view for explaining the arrangement and size of the projection 64B according to a preferred embodiment. Assuming that the diameter of the cylindrical protrusion 64B is a and the distance between the protrusions 64B is b, the arrangement and size of the protrusions 64B are designed so that the diameter a and the distance b satisfy the inequality formula (1) below. , With more suitable pressure control function.
a b b a a / 2 (1)

  When the distance b is smaller than half the diameter a (ie, a / 2), the protrusions 64B are less likely to be elastically deformed. Also, if the distance b is too larger than the diameter a, the number of the protrusions 64B in the pressure adjusting member 60 decreases, so the function of adjusting the pressure applied to the central portion of the laminated surface of the laminated body 20 (or unit cell 10) Is likely to be inadequate.

  As a material which shows rubber elasticity which constitutes frame part 64A and projection part 64B (preferably frame part 64A, projection part 64B, and back board 62), various rubber materials may be used, without being limited in particular. Examples of such a material include synthetic rubbers such as butadiene rubber, styrene butadiene rubber, chloropropylene rubber, polyurethane, silicone rubber and the like. Among them, styrene butadiene rubber can be suitably adopted from the viewpoint of being able to control the restraint pressure applied to the lamination direction X of the laminate 20 suitably. The frame portion 64A, the projection 64B and the back plate 62 may be made of different materials, or may be made of the same material. From the viewpoint of ease of manufacture, it is preferable that the frame portion 64A, the projection 64B, and the back plate 62 be made of the same material and be integrated.

  FIG. 6 is a view corresponding to the IV-IV 'arrow view of FIG. 1 of the battery module 100 using the pressure adjustment member 60 according to another embodiment. According to the example shown in FIG. 6, the projection 64B has a square pole shape. The shape of the projection 64B is cylindrical (FIG. 4) and a quadrangular prism (FIG. 6) as long as it exhibits an effect of resiliently deforming suitably in the direction in which the projection 64B is provided to generate a restoring force (elastic force). It is not limited to the above, but can take various shapes. For example, when viewed from the stacking direction of the stack as shown in FIG. 6, the protruding portions may be formed by connecting a plurality of projecting portions to form a linear or wavy line having a certain width.

  In the battery module 100 according to another embodiment, the pressure adjusting member 60 is disposed in the gap between the unit cells 10 constituting the stacked body 20. For example, the pressure adjustment member 60 may be disposed at a central portion in the stacking direction X of the stacked body 20. According to this configuration, the uniformity of the constraining pressure applied to the laminated surface of the laminated body 20 can be improved.

  Although the specific examples of the present invention have been described above in detail, these are merely examples and do not limit the scope of the claims. The art set forth in the claims includes various variations and modifications of the specific examples illustrated above.

DESCRIPTION OF SYMBOLS 10 single battery 12A positive electrode terminal 12B negative electrode terminal 14 exterior body 20 laminated body 30A end plate 30B end plate 40A side plate 40A side plate 50 pressing plate 60 pressure control member 62 back plate 64A frame part 64B protrusion part 100 battery module

Claims (1)

A laminate in which a plurality of single-electric grounds are stacked
A pressure control member disposed in at least one of the gap between the stacked unit cells, one end and the other end of the stacking direction, for adjusting the pressure applied in the stacking direction of the stack; A battery module comprising
The pressure adjustment member is
Backboard,
A frame portion protruding from at least one surface of the back plate and formed along the peripheral edge portion of the back plate;
And a plurality of projections formed on the same surface as the surface on which the frame portion of the back plate is provided, and formed inside the frame portion,
At least the frame portion and the projection portion of the pressure adjustment member are formed of a material exhibiting rubber elasticity,
The pressure adjustment member is disposed such that the frame portion and the protrusion face the side on which the laminate is located,
When the battery module is viewed from the stacking direction, an outer periphery of a stacking surface of the stacked single cells is disposed in a region where the frame portion is formed,
Battery module characterized by

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