JP2019123856A5 - - Google Patents
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- JP2019123856A5 JP2019123856A5 JP2018218829A JP2018218829A JP2019123856A5 JP 2019123856 A5 JP2019123856 A5 JP 2019123856A5 JP 2018218829 A JP2018218829 A JP 2018218829A JP 2018218829 A JP2018218829 A JP 2018218829A JP 2019123856 A5 JP2019123856 A5 JP 2019123856A5
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- 125000004432 carbon atoms Chemical group C* 0.000 description 39
- 125000001424 substituent group Chemical group 0.000 description 33
- 238000004040 coloring Methods 0.000 description 8
- 125000004429 atoms Chemical group 0.000 description 7
- 125000000623 heterocyclic group Chemical group 0.000 description 6
- 125000000000 cycloalkoxy group Chemical group 0.000 description 5
- -1 cyclodecyl group Chemical group 0.000 description 5
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 3
- 125000000753 cycloalkyl group Chemical group 0.000 description 3
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 description 3
- WFFZGYRTVIPBFN-UHFFFAOYSA-N 3H-indene-1,2-dione Chemical group C1=CC=C2C(=O)C(=O)CC2=C1 WFFZGYRTVIPBFN-UHFFFAOYSA-N 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical group 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000004104 aryloxy group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 125000004093 cyano group Chemical group *C#N 0.000 description 2
- 125000002541 furyl group Chemical group 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 125000003226 pyrazolyl group Chemical group 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 125000000641 acridinyl group Chemical group C1(=CC=CC2=NC3=CC=CC=C3C=C12)* 0.000 description 1
- 125000003670 adamantan-2-yl group Chemical group [H]C1([H])C(C2([H])[H])([H])C([H])([H])C3([H])C([*])([H])C1([H])C([H])([H])C2([H])C3([H])[H] 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 125000000499 benzofuranyl group Chemical group O1C(=CC2=C1C=CC=C2)* 0.000 description 1
- 125000001164 benzothiazolyl group Chemical group S1C(=NC2=C1C=CC=C2)* 0.000 description 1
- 125000004196 benzothienyl group Chemical group S1C(=CC2=C1C=CC=C2)* 0.000 description 1
- 125000004541 benzoxazolyl group Chemical group O1C(=NC2=C1C=CC=C2)* 0.000 description 1
- 125000004623 carbolinyl group Chemical group 0.000 description 1
- 125000005112 cycloalkylalkoxy group Chemical group 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000006547 cyclononyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000004988 dibenzothienyl group Chemical group C1(=CC=CC=2SC3=C(C21)C=CC=C3)* 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing Effects 0.000 description 1
- 125000002883 imidazolyl group Chemical group 0.000 description 1
- 125000001041 indolyl group Chemical group 0.000 description 1
- 125000005956 isoquinolyl group Chemical group 0.000 description 1
- 125000004593 naphthyridinyl group Chemical group N1=C(C=CC2=CC=CN=C12)* 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000002971 oxazolyl group Chemical group 0.000 description 1
- 125000004625 phenanthrolinyl group Chemical group N1=C(C=CC2=CC=C3C=CC=NC3=C12)* 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 125000000714 pyrimidinyl group Chemical group 0.000 description 1
- 125000000168 pyrrolyl group Chemical group 0.000 description 1
- 125000005493 quinolyl group Chemical group 0.000 description 1
- 125000001567 quinoxalinyl group Chemical group N1=C(C=NC2=CC=CC=C12)* 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 125000000335 thiazolyl group Chemical group 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 125000004306 triazinyl group Chemical group 0.000 description 1
- 125000001425 triazolyl group Chemical group 0.000 description 1
Description
[式中、R1〜R6は、それぞれ独立に、水素原子、水酸基、ハロゲン原子、シアノ基、ニトロ基、―SO3H、―SO3M、
置換基を有していてもよい炭素原子数9〜25、好ましくは9〜20のインダンジオン基、
置換基を有していてもよい炭素原子数1〜25、好ましくは1〜20のスルホ基、
置換基を有していてもよい炭素原子数1〜25、好ましくは1〜20の直鎖状もしくは分岐状のアルキル基、
置換基を有していてもよい炭素原子数5〜25、好ましくは5〜20のシクロアルキル基、
置換基を有していてもよい炭素原子数2〜25、好ましくは2〜20の直鎖状もしくは分岐状のアルケニル基、
置換基を有していてもよい炭素原子数1〜25、好ましくは1〜20の直鎖状もしくは分岐状のアルコキシ基、
置換基を有していてもよい炭素原子数5〜25、好ましくは5〜20のシクロアルコキシ基、
置換基を有していてもよい炭素原子数1〜25、好ましくは1〜20のアシル基、
置換基を有していてもよい炭素原子数6〜25、好ましくは6〜20の芳香族炭化水素基、
置換基を有していてもよい環形成原子数5〜25、好ましくは5〜20の複素環基、または
置換基を有していてもよい環形成原子数5〜25、好ましくは5〜20のアリールオキシ基を表し、
R1〜R6は、隣り合う基同士で互いに結合して環を形成していてもよい。
Mはアルカリ金属原子を表す。
R1〜R6のうち任意のn個は−NR7R8によって置き換えられており、
R7およびR8は、それぞれ独立に、水素原子、
置換基を有していてもよい炭素原子数1〜25、好ましくは1〜20の直鎖状もしくは分岐状のアルキル基、
置換基を有していてもよい炭素原子数5〜25、好ましくは5〜20のシクロアルキル基、
置換基を有していてもよい炭素原子数2〜25、好ましくは2〜20の直鎖状もしくは分岐状のアルケニル基、
置換基を有していてもよい炭素原子数5〜25、好ましくは5〜20のシクロアルコキシ基、
置換基を有していてもよい炭素原子数6〜25、好ましくは6〜20の芳香族炭化水素基、または
置換基を有していてもよい環形成原子数5〜25、好ましくは5〜20の複素環基を表し、
R7およびR8は、互いに結合して環を形成していてもよい。
nは1〜3の整数を表す。
Zは1価基を表す。]
[In the formula, R 1 to R 6 are independently hydrogen atom, hydroxyl group, halogen atom, cyano group, nitro group, -SO 3 H, -SO 3 M, respectively.
An indandion group having 9 to 25 carbon atoms, preferably 9 to 20, which may have a substituent.
A sulfo group having 1 to 25 carbon atoms, preferably 1 to 20 carbon atoms, which may have a substituent.
A linear or branched alkyl group having 1 to 25 carbon atoms, preferably 1 to 20, which may have a substituent.
A cycloalkyl group having 5 to 25 carbon atoms, preferably 5 to 20 carbon atoms, which may have a substituent.
A linear or branched alkenyl group having 2 to 25 carbon atoms, preferably 2 to 20, which may have a substituent.
A linear or branched alkoxy group having 1 to 25 carbon atoms, preferably 1 to 20, which may have a substituent.
A cycloalkoxy group having 5 to 25 carbon atoms, preferably 5 to 20 carbon atoms, which may have a substituent.
An acyl group having 1 to 25 carbon atoms, preferably 1 to 20, which may have a substituent.
An aromatic hydrocarbon group having 6 to 25 carbon atoms, preferably 6 to 20 carbon atoms, which may have a substituent.
A heterocyclic group having 5 to 25 ring-forming atoms, preferably 5 to 20, which may have a substituent, or 5 to 25 ring-forming atoms, preferably 5 to 20, which may have a substituent. Represents the aryloxy group of
R 1 to R 6 may be bonded to each other by adjacent groups to form a ring.
M represents an alkali metal atom.
Any n of R 1 to R 6 have been replaced by -NR 7 R 8
R 7 and R 8 are independent hydrogen atoms, respectively.
A linear or branched alkyl group having 1 to 25 carbon atoms, preferably 1 to 20, which may have a substituent.
A cycloalkyl group having 5 to 25 carbon atoms, preferably 5 to 20 carbon atoms, which may have a substituent.
A linear or branched alkenyl group having 2 to 25 carbon atoms, preferably 2 to 20, which may have a substituent.
A cycloalkoxy group having 5 to 25 carbon atoms, preferably 5 to 20 carbon atoms, which may have a substituent.
It may have a substituent and may have 6 to 25 carbon atoms, preferably 6 to 20 aromatic hydrocarbon groups, or may have a substituent and may have 5 to 25 ring-forming atoms, preferably 5 to 25. It represents 20 heterocyclic group,
R 7 and R 8 may be coupled to each other to form a ring.
n represents an integer of 1 to 3.
Z represents a monovalent group. ]
[式中、R13〜R18は、それぞれ独立に、水素原子、水酸基、ハロゲン原子、シアノ基、ニトロ基、―SO3H、―SO3M、
置換基を有していてもよい炭素原子数9〜25、好ましくは9〜20のインダンジオン基、
置換基を有していてもよい炭素原子数1〜25、好ましくは1〜20のスルホ基、
置換基を有していてもよい炭素原子数1〜25、好ましくは1〜20の直鎖状もしくは分岐状のアルキル基、
置換基を有していてもよい炭素原子数5〜25、好ましくは5〜20のシクロアルキル基、
置換基を有していてもよい炭素原子数2〜25、好ましくは2〜20の直鎖状もしくは分岐状のアルケニル基、
置換基を有していてもよい炭素原子数1〜25、好ましくは1〜20の直鎖状もしくは分岐状のアルコキシ基、
置換基を有していてもよい炭素原子数5〜25、好ましくは5〜20のシクロアルコキシ基、
置換基を有していてもよい炭素原子数1〜25、好ましくは1〜20のアシル基、
置換基を有していてもよい炭素原子数6〜25、好ましくは6〜20の芳香族炭化水素基、
置換基を有していてもよい環形成原子数5〜25、好ましくは5〜20の複素環基、または
置換基を有していてもよい環形成原子数5〜25、好ましくは5〜20のアリールオキシ基を表し、
R9〜R12は、隣り合う基同士で互いに結合して環を形成していてもよい。
Mはアルカリ金属原子を表す。]
[In the formula, R 13 to R 18 are independently hydrogen atom, hydroxyl group, halogen atom, cyano group, nitro group, -SO 3 H, -SO 3 M, respectively.
An indandion group having 9 to 25 carbon atoms, preferably 9 to 20, which may have a substituent.
A sulfo group having 1 to 25 carbon atoms, preferably 1 to 20 carbon atoms, which may have a substituent.
A linear or branched alkyl group having 1 to 25 carbon atoms, preferably 1 to 20, which may have a substituent.
A cycloalkyl group having 5 to 25 carbon atoms, preferably 5 to 20 carbon atoms, which may have a substituent.
A linear or branched alkenyl group having 2 to 25 carbon atoms, preferably 2 to 20, which may have a substituent.
A linear or branched alkoxy group having 1 to 25 carbon atoms, preferably 1 to 20, which may have a substituent.
A cycloalkoxy group having 5 to 25 carbon atoms, preferably 5 to 20 carbon atoms, which may have a substituent.
An acyl group having 1 to 25 carbon atoms, preferably 1 to 20, which may have a substituent.
An aromatic hydrocarbon group having 6 to 25 carbon atoms, preferably 6 to 20 carbon atoms, which may have a substituent.
A heterocyclic group having 5 to 25 ring-forming atoms, preferably 5 to 20, which may have a substituent, or 5 to 25 ring-forming atoms, preferably 5 to 20, which may have a substituent. Represents the aryloxy group of
R 9 to R 12 may be bonded to each other by adjacent groups to form a ring.
M represents an alkali metal atom. ]
一般式(1)において、R1〜R6で表される「置換基を有していてもよい炭素原子数1〜25、好ましくは1〜20のスルホ基」における「炭素原子数1〜25、好ましくは1〜20のスルホ基」は、「―SO3―R」と表される基を意味し、Rは、「置換基を有していてもよい炭素原子数1〜25、好ましくは1〜20のスルホ基」における「置換基」を意味する。 In the general formula (1), R 1 ~R 6 "substituent optionally 1 to 25 carbon atoms which may have a, preferably sulfo group of 1 to 20" represented by the number "carbon atoms in the 1 to 25 , preferably sulfo group having from 1 to 20 "is" - refers to a group represented as SO 3 -R ', R represents the number "carbon atoms which may have a substituent 1 to 25, preferably It means a "substituent" in "1 to 20 sulfo groups".
一般式(1)において、R1〜R6で表される、「置換基を有していてもよい炭素原子数5〜25、好ましくは5〜20のシクロアルコキシ基」における「炭素原子数5〜25、好ましくは5〜20のシクロアルコキシ基」としては、具体的に、シクロペンチルオキシ基、シクロヘキシルオキシ基、シクロヘプチルオキシ基、シクロオクチルオキシ基、シクロノニルオキシ基、シクロデシルオキシ基などのシクロアルコキシ基;1−アダマンチルオキシ基、2−アダマンチルオキシ基、などがあげられる。 In the general formula (1), "the number of carbon atoms is 5" in "a cycloalkoxy group having 5 to 25 carbon atoms, preferably 5 to 20 carbon atoms which may have a substituent" represented by R 1 to R 6. 25, as preferably cycloalkoxy group having 5 to 20 ", specifically, cyclopentyl group, cyclohexyl group, cycloheptyl group, cyclooctyl group, cyclononyl group, a cycloalkyl alkoxy group such as a cyclodecyl group ; 1-adamantyl group, 2-adamantyl group, and the like.
一般式(1)において、R1〜R6で表される、「置換基を有していてもよい環形成原子数5〜25、好ましくは5〜20の複素環基」における「環形成原子数5〜25、好ましくは5〜20の複素環基」としては、具体的に、ピリジル基、ピリミジニル基、トリアジニル基、イミダゾリル基、ピラゾリル基、トリアゾリル基、チエニル基、フリル基(フラニル基)、ピロリル基、キノリル基、イソキノリル基、ナフチリジニル基、インドリル基、アクリジニル基、フェナントロリニル基、ベンゾフラニル基、ベンゾチエニル基、カルバゾリル基、オキサゾリル基、ベンゾオキサゾリル基、チアゾリル基、ベンゾチアゾリル基、キノキサリル基、ベンゾイミダゾリル基、ピラゾリル基、ジベンゾフラニル基、ジベンゾチエニル基、カルボリニル基などの複素環基(もしくは複素芳香族炭化水素基)があげられる。 In the general formula (1), the "ring-forming atom" in the "heterocyclic group having 5 to 25, preferably 5 to 20 ring-forming atoms which may have a substituent" represented by R 1 to R 6 is used. Specific examples of the "heterocyclic group having a number of 5 to 25, preferably 5 to 20" include a pyridyl group, a pyrimidinyl group, a triazinyl group, an imidazolyl group, a pyrazolyl group, a triazolyl group, a thienyl group and a furyl group (furanyl group). pyrrolyl group, quinolyl group, isoquinolyl group, naphthyridinyl group, indolyl group, acridinyl group, phenanthrolinyl group, benzofuranyl group, benzothienyl group, mosquitoes Rubazoriru group, oxazolyl group, benzoxazolyl group, a thiazolyl group, benzothiazolyl group, Examples thereof include heterocyclic groups (or heteroaromatic hydrocarbon groups) such as quinoxalyl group, benzoimidazolyl group, pyrazolyl group, dibenzofuranyl group, dibenzothienyl group and carbolinyl group.
本発明の着色組成物は、一般式(1)で表される本発明の化合物を含有しており、1種類の構造の化合物を含有していてもよく、2種類以上の構造の化合物を含有していてもよい。本発明においては、化合物の構造は1種類であるのが好ましい。 The coloring composition of the present invention contains the compound of the present invention represented by the general formula (1), one of which optionally contains a compound of structure, compounds of two or more structural May be contained. In the present invention, the structure of the compound is preferably one kind.
本発明の着色組成物は、カラーフィルター用着色剤としての性能を高めるために、着色組成物の他の成分として、界面活性剤、分散剤、消泡剤、レベリング剤、その他のカラーフィルター用着色剤の製造時に混合する添加剤、などの有機化合物などを添加することができる。ただし、着色組成物におけるこれらの添加剤の含有率は適量であることが好ましく、本発明の着色組成物の溶媒中の溶解性を低下させたり、もしくは必要以上に向上させたり、また、カラーフィルター製造時に用いる他の同種の添加剤の効果に影響しない範囲の含有率であることが好ましい。これらの添加物は、着色組成物の調製の任意のタイミングで投入することができる。 In order to enhance the performance of the coloring composition for a color filter, the coloring composition of the present invention contains, as other components of the coloring composition , a surfactant, a dispersant, an antifoaming agent, a leveling agent, and other coloring for a color filter. Organic compounds such as additives to be mixed during the production of the agent can be added. However, the content of these additives in the coloring composition is preferably an appropriate amount, and the solubility of the coloring composition of the present invention in a solvent may be lowered or improved more than necessary, or a color filter may be used. The content is preferably in a range that does not affect the effects of other additives of the same type used in production. These additives can be added at any time in the preparation of the coloring composition.
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KR (1) | KR102635002B1 (en) |
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JP2022140287A (en) | 2021-03-11 | 2022-09-26 | 保土谷化学工業株式会社 | Yellowish compound, coloring composition containing that compound, collar filter colorant, and collar filter |
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JPH05333599A (en) * | 1992-05-29 | 1993-12-17 | Mitsui Toatsu Chem Inc | Dye and composition for yellow color toner |
JP4785222B2 (en) | 2000-02-09 | 2011-10-05 | 東洋インキScホールディングス株式会社 | Color filter pigment, process for producing the same, color filter coloring composition using the same, and color filter |
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