JP2019104823A - Soil modifying agent and solid modifying method - Google Patents
Soil modifying agent and solid modifying method Download PDFInfo
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Abstract
Description
本発明は、農地などの土壌の透水性を改善させることができる土壌改質剤及び土壌改質方法に関する。 The present invention relates to a soil modifying agent and a soil modifying method that can improve the permeability of soil such as farmland.
農地などの土壌が粒子径の小さい粒子で構成されている場合、水を散布しても、水が十分に土壌内に浸透せずに、多くが表層から流れ出してしまう場合がある。このような土壌では、貴重な水資源を有効に使うことができなかったり、降雨の際に雨水が土壌内に十分に浸透しないので、下流域に水害を引き起こしたりする場合があるので、土壌の透水性を改善させることが重要である。 When the soil such as farmland is composed of particles with a small particle diameter, even if the water is sprayed, a large amount of water may not flow into the soil and may flow out of the surface layer. In such soils, valuable water resources can not be used effectively, and because rainwater does not sufficiently penetrate into the soil when it rains, it may cause flood damage in the downstream area. It is important to improve permeability.
特許文献１には、土壌団粒化剤や固化剤を土と混合することによって透水性を高める技術が開示されている。 Patent Document 1 discloses a technique for enhancing water permeability by mixing a soil aggregating agent and a solidifying agent with soil.
特許文献１の技術によっても、透水性がある程度改善するが、透水性をさらに改善させることが望まれている。 Although the water permeability is improved to some extent by the technique of Patent Document 1, it is desired to further improve the water permeability.
本発明はこのような事情に鑑みてなされたものであり、透水性の改善効果に優れた土壌改質剤を提供するものである。 This invention is made in view of such a situation, and provides the soil modifier excellent in the improvement effect of water permeability.
水性樹脂エマルジョンと水溶性高分子を含む土壌改質剤を土壌に散布した後に土壌を乾燥させることによって、土壌の透水性を大幅に高めることができることを見出し、本発明の完成に到った。 The present inventors have found that the water permeability of the soil can be significantly enhanced by applying the soil modifying agent containing the aqueous resin emulsion and the water-soluble polymer to the soil and then drying the soil, and the present invention has been accomplished.
すなわち、本発明は以下の通りである。
（１）水性樹脂エマルジョンと、水溶性高分子を含む、土壌改質剤。
（２）前記土壌改質剤中の前記水溶性高分子の含有量が、固形分換算で、１〜２０質量％である、（１）に記載の土壌改質剤。
（３）前記水性樹脂エマルジョンが、酢酸ビニルに由来する構造単位を含む、（１）又は（２）に記載の土壌改質剤。
（４）前記水性樹脂エマルジョンが、エチレン−酢酸ビニル共重合体エマルジョンである、（１）〜（３）の何れか１つに記載の土壌改質剤。
（５）（１）〜（４）の何れか１つに記載の土壌改質剤を土壌に散布し、前記土壌を乾燥させる工程を備える、土壌改質方法。
（６）前記土壌改質剤は、固形分質量が１００〜１０００ｇ／ｍ２となるように散布する、（５）に記載の土壌改質方法。
（７）前記土壌改質剤は、散布液量が１．５〜８Ｌ／ｍ２となるように散布する、（５）又は（６）に記載の土壌改質方法。
That is, the present invention is as follows.
(1) A soil modifying agent comprising an aqueous resin emulsion and a water-soluble polymer.
(2) The soil modifier as described in (1) whose content of the said water-soluble polymer in the said soil modifier is 1-20 mass% in conversion of solid content.
(3) The soil modifier according to (1) or (2), wherein the aqueous resin emulsion contains a structural unit derived from vinyl acetate.
(4) The soil modifier according to any one of (1) to (3), wherein the aqueous resin emulsion is an ethylene-vinyl acetate copolymer emulsion.
(5) A soil reforming method comprising the step of spraying the soil modifying agent according to any one of (1) to (4) to soil and drying the soil.
(6) The soil-reforming method as described in (5) which disperses the said soil modifier so that solid content mass may be 100-1000 g / m < 2 >.
(7) The soil reforming method according to (5) or (6), wherein the soil modifying agent is sprayed such that the amount of spray liquid is 1.5 to 8 L / m 2 .
本発明によれば、土壌の透水性を大幅に高めることができる。 According to the present invention, the permeability of soil can be greatly enhanced.
以下、本発明の実施形態について、詳細に説明する。 Hereinafter, embodiments of the present invention will be described in detail.
１．土壌改質剤の組成
本発明の土壌改質剤は、水性樹脂エマルジョンと、水溶性高分子を含む。
1. Composition of Soil Modifier The soil modifier of the present invention comprises an aqueous resin emulsion and a water-soluble polymer.
＜水性樹脂エマルジョン＞
水性樹脂エマルジョンの種類は、水を分散媒、樹脂を分散質としたものであれば特に限定されず、主モノマーとして、酢酸ビニル、アクリル酸エステル、スチレン、エチレン、ブタジエン等の、種々のオレフィン系化合物を単独または複数用いて重合し調製した水性樹脂エマルジョンが使用できる。具体的には、酢酸ビニル樹脂エマルジョン、酢酸ビニル共重合体エマルジョン、アクリル酸エステル樹脂エマルジョン、スチレンアクリル酸エステル共重合体エマルジョン、エチレン−酢酸ビニル共重合体エマルジョン、スチレン−ブタジエン共重合体エマルジョン、ビニリデン樹脂エマルジョン、ポリブテン樹脂エマルジョン、アクリルニトリル−ブタジエン樹脂エマルジョン、メタアクリレート−ブタジエン樹脂エマルジョン、アスファルトエマルジョン、エポキシ樹脂エマルジョン、ウレタン樹脂エマルジョン、シリコン樹脂エマルジョンなどが例示され、このうち、酢酸ビニルに由来する構造単位を含む樹脂のエマルジョン（酢酸ビニル樹脂エマルジョン、酢酸ビニル共重合体エマルジョン、エチレン−酢酸ビニル共重合体エマルジョン等）が好ましく、エチレン−酢酸ビニル共重合体エマルジョンがさらに好ましい。
<Aqueous resin emulsion>
The type of aqueous resin emulsion is not particularly limited as long as it is water as a dispersion medium and resin as a dispersoid, and various olefins such as vinyl acetate, acrylic ester, styrene, ethylene and butadiene as main monomers An aqueous resin emulsion prepared by polymerizing one or more compounds can be used. Specifically, vinyl acetate resin emulsion, vinyl acetate copolymer emulsion, acrylic acid ester resin emulsion, styrene acrylic acid ester copolymer emulsion, ethylene-vinyl acetate copolymer emulsion, styrene-butadiene copolymer emulsion, vinylidene Examples include resin emulsions, polybutene resin emulsions, acrylonitrile-butadiene resin emulsions, methacrylate-butadiene resin emulsions, asphalt emulsions, epoxy resin emulsions, urethane resin emulsions, silicone resin emulsions, etc., among which structural units derived from vinyl acetate Emulsion of resin containing vinyl acetate (vinyl acetate resin emulsion, vinyl acetate copolymer emulsion, ethylene-vinyl acetate copolymer emulsion Emissions, etc.) are preferable, ethylene - vinyl acetate copolymer emulsion is more preferred.
水性樹脂エマルジョンの製造方法は、特に限定されないが、例えば、水を主成分とする分散媒中に乳化剤とモノマーを添加し、撹拌させながらモノマーを乳化重合させることによって製造することができる。この製造時に使用するモノマーの種類や添加速度によって、得られるエマルジョンのトルエン不溶分を変化させることができる。乳化剤としては、イオン性（カチオン性・アニオン性・双性）界面活性剤や非イオン性（ノニオン性）界面活性剤が挙げられる。非イオン性界面活性剤としては、アルキルグリコシドのような低分子系界面活性剤、あるいはポリエチレングリコールやポリビニルアルコールのような高分子系界面活性剤が挙げられ、高分子系界面活性剤が好ましい。高分子系界面活性剤は、ポリビニルアルコールからなるものが特に好ましく、その平均重合度は例えば２００〜２５００であり、４００〜２２００が好ましく、５００〜２０００がさらに好ましい。ポリビニルアルコールは、平均重合度が大きいほど乳化分散力が高まるので、所望の分散度のエマルジョンが得られるように、適切な平均重合度を有するポリビニルアルコールを使用すればよい。また、ポリビニルアルコールは、平均重合度が互いに異なる複数種類のものを組み合わせて使用してもよい。ポリビニルアルコールのケン化度は、特に限定されないが、例えば、７０％以上であり、８０〜９５％が好ましい。ケン化度が低すぎると極端に水への溶解性が低下し、特殊な溶解方法を用いなければ溶解できず、工業的には使用し難いからである。ポリビニルアルコールは、ケン化度が低いほど乳化分散力が高まるので、所望の分散度のエマルジョンが得られるように、適切なケン化度を有するポリビニルアルコールを使用すればよい。乳化剤は異なる複数種類のものを組み合わせて使用してもよい。乳化剤の添加量は、特に限定されないが、例えば、分散媒１００質量部に対して０．５〜２０質量部であり、１から１０質量部が好ましい。乳化剤は添加量が多いほど乳化分散力が高まるので、乳化剤の添加量は、所望の分散度のエマルジョンが得られるように、適宜調整される。 The method for producing the aqueous resin emulsion is not particularly limited, but can be produced, for example, by adding an emulsifier and a monomer in a dispersion medium containing water as a main component, and emulsion-polymerizing the monomer while stirring. The toluene insoluble content of the resulting emulsion can be changed depending on the type of monomer used in the production and the addition rate. Emulsifying agents include ionic (cationic, anionic, zwitterionic) surfactants and nonionic (nonionic) surfactants. Examples of nonionic surfactants include low molecular weight surfactants such as alkyl glycosides, and high molecular weight surfactants such as polyethylene glycol and polyvinyl alcohol, and high molecular weight surfactants are preferable. The polymer surfactant is particularly preferably one comprising polyvinyl alcohol, and the average degree of polymerization thereof is, for example, 200 to 2,500, preferably 400 to 2200, and more preferably 500 to 2,000. As the polyvinyl alcohol has higher emulsifying and dispersing power as the average degree of polymerization is higher, polyvinyl alcohol having an appropriate degree of polymerization may be used so that an emulsion having a desired degree of dispersion can be obtained. In addition, polyvinyl alcohol may be used in combination of two or more types having different average polymerization degrees. The degree of saponification of polyvinyl alcohol is not particularly limited, and is, for example, 70% or more, preferably 80 to 95%. If the degree of saponification is too low, the solubility in water is extremely reduced, and it can not be dissolved unless a special dissolution method is used, and it is difficult to use industrially. The lower the degree of saponification, the higher the emulsifying and dispersing power, so that polyvinyl alcohol having an appropriate degree of saponification may be used so as to obtain an emulsion having a desired degree of dispersion. The emulsifier may be used in combination of two or more different types. Although the addition amount of an emulsifier is not specifically limited, For example, it is 0.5-20 mass parts with respect to 100 mass parts of dispersion media, and 1-10 mass parts is preferable. Since the emulsifying and dispersing power increases as the amount of the emulsifier added increases, the amount of the emulsifier added is appropriately adjusted so as to obtain an emulsion having a desired degree of dispersion.
＜水溶性高分子＞
水溶性高分子の種類は、特に限定されず、メチルセルロース、エチルセルロース、ヒドロキシメチルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシブチルメチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース、アミノメチルヒドロキシプロピルセルロース、アミノエチルヒドロキシプロピルセルロース等のセルロース誘導体類；デンプン、カラギーナン、マンナン、アガロース、デキストラン、トラガント、ペクチン、グルー、アルギン酸又はその塩；ゼラチン；ポリビニルピロリドン；ポリアクリル酸又はその塩ポリメタクリル酸又はその塩；ポリアクリルアミド、ポリメタクリルアミド等のアクリルアミド類；ヒアルロン酸及びその塩、コンドロイチン硫酸及びその塩、ポリビニルアルコール、ポリエチレンイミン、ポリエチレンオキシド、ポリエチレングリコール、ポリプロピレングリコール、グリセリンが例示され、複数種を組み合わせて使用することもできる。また、水と混和するノニオン性界面活性剤も用いることができ、ポリオキシエチレンノニルフェニルエーテル、ポリオキシエチレンスチレン化フェニルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレンラウリルエーテル等のポリオキシエチレンアルキルアリールエーテル類又はポリオキシエチレンアルキルエーテル類、ポリエチレングリコールモノラウレート、ポリエチレングリコールモノステアレート、ポリエチレングリコールモノオレエート等のポリオキシエチレン脂肪酸エステル類、オキシエチレン／オキシプロピレンブロックコポリマー等が例示される。
<Water-soluble polymer>
The type of water-soluble polymer is not particularly limited, and cellulose derivatives such as methyl cellulose, ethyl cellulose, hydroxymethyl cellulose, hydroxypropyl methyl cellulose, hydroxybutyl methyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose, aminomethyl hydroxypropyl cellulose, aminoethyl hydroxypropyl cellulose and the like Starch, carrageenan, mannan, agarose, dextran, tragacanth, pectin, glue, alginic acid or a salt thereof; gelatin; polyvinyl pyrrolidone; polyacrylic acid or a salt thereof polymethacrylic acid or a salt thereof; acrylamides such as polyacrylamide or polymethacrylamide Hyaluronic acid and salts thereof, chondroitin sulfate and salts thereof, polyvinyl alcohol Polyethyleneimine, polyethylene oxide, polyethylene glycol, polypropylene glycol, glycerin and the like, can also be used in combination. In addition, nonionic surfactants which are miscible with water can also be used, and polyoxyethylene alkyl aryl such as polyoxyethylene nonyl phenyl ether, polyoxyethylene styrenated phenyl ether, polyoxyethylene oleyl ether, polyoxyethylene lauryl ether, etc. Ethers or polyoxyethylene alkyl ethers, polyethylene glycol monolaurate, polyethylene glycol monostearate, polyoxyethylene fatty acid esters such as polyethylene glycol monooleate, oxyethylene / oxypropylene block copolymers and the like are exemplified.
水溶性高分子は、水性樹脂エマルジョンの製造の際に乳化剤として添加してもよいし、水性樹脂エマルジョンの製造後に添加してもよい。 The water-soluble polymer may be added as an emulsifying agent in the production of the aqueous resin emulsion, or may be added after the production of the aqueous resin emulsion.
土壌改質剤中の水溶性高分子の含有量は、固形分換算で、１〜２５質量％であることが好ましく、１〜２０質量％であることがさらに好ましく、１〜１２質量％であることがさらに好ましく、１〜１０質量％であることがさらに好ましく、１〜７質量％であることがさらに好ましく、２〜６質量％であることがさらに好ましい。水溶性高分子が適量含まれることによって透水性の向上がより顕著になるからである。 The content of the water-soluble polymer in the soil modifying agent is preferably 1 to 25% by mass, more preferably 1 to 20% by mass, and still more preferably 1 to 12% by mass in terms of solid content. Is more preferably, 1 to 10% by mass is further preferable, 1 to 7% by mass is more preferable, and 2 to 6% by mass is more preferable. It is because the improvement of the water permeability becomes more remarkable by containing a suitable amount of the water-soluble polymer.
＜固形分率＞
土壌改質剤の固形分率は、２０〜８０質量％であることが好ましく、４５〜６５質量％であることがさらに好ましい。この固形分率が低すぎると、土壌改質剤のポリマー量が少なすぎて透水性改善効果が弱く、固形分率が高すぎると粘度が高くなりすぎて散布が困難になる場合があるからである。
<Solid fraction>
The solid content of the soil modifying agent is preferably 20 to 80% by mass, and more preferably 45 to 65% by mass. If the solid content is too low, the polymer modification amount of the soil modifier is too small to improve the permeability, and if the solid content is too high, the viscosity may be too high to be difficult to disperse. is there.
２．土壌改質剤の使用方法
上記の土壌改質剤を土壌に散布し、前記土壌を乾燥させることによって、土壌を改質させることができる。
2. Method of Using Soil Modifier The soil can be reformed by spraying the soil modifier onto the soil and drying the soil.
土壌改質剤は、固形分質量が１００〜１０００（好ましくは、２５０〜１０００）ｇ／ｍ２となるように散布することが好ましい。散布量が少なすぎると透水性改善効果が十分でなく、散布量が多すぎても、透水性のさらなる改善がほとんどないからである。 The soil modifier is preferably sprayed so as to have a solid content mass of 100 to 1000 (preferably 250 to 1000) g / m 2 . If the application amount is too low, the permeability improvement effect is not sufficient, and if the application amount is too high, there is almost no further improvement in water permeability.
土壌改質剤は、散布液量が１．５〜８Ｌ／ｍ２となるように散布する。散布液量が少なすぎる場合、十分な樹脂を散布するためには土壌改質剤中の固形分率が高くなりすぎるという問題がある。散布液量が多すぎると、散布に手間がかかるので好ましくない。 The soil modifier is sprayed so that the amount of spray liquid is 1.5 to 8 L / m 2 . If the amount of spray liquid is too small, there is a problem that the solid content in the soil modifier becomes too high to spray a sufficient amount of resin. If the amount of spray liquid is too large, it takes time and effort to spray, which is not preferable.
土壌の乾燥は、自然乾燥であってもよく、加熱又は送風などによる強制乾燥であってもよい。土壌を乾燥させることによって土壌改質剤中の樹脂が土壌と強固に結合して透水性向上効果を発揮しやすくなる。 The drying of the soil may be natural drying or forced drying by heating or air blowing. By drying the soil, the resin in the soil modifying agent is strongly bonded to the soil, which facilitates the effect of improving permeability.
以下、本発明の実施例を説明する。以下の説明中で特に断りがない限り、「部」、「％」、「割合」は、それぞれ、「質量部」、「質量％」、「質量割合」を意味する。 Hereinafter, examples of the present invention will be described. Unless otherwise noted in the following description, “parts”, “%” and “proportions” mean “parts by mass”, “% by mass” and “% by mass”, respectively.
１．土壌改質剤の製造例
表１に示す乳化剤の存在下で、純水中で表１示すモノマーを表１に示す割合で乳化重合させることによって、水性樹脂エマルジョンを含む土壌改質剤Ｍ１〜Ｍ５を作製した。Ｍ１〜Ｍ４は、乳化剤としてポリビニルアルコールを用いた。ポリビニルアルコールは水溶性高分子であるので、土壌改質剤Ｍ１〜Ｍ４には、水溶性高分子が含まれている。
1. Production Examples of Soil Modifier Soil modifiers M1 to M5 containing an aqueous resin emulsion by emulsion-polymerizing the monomers shown in Table 1 in pure water in the presence of the emulsifiers shown in Table 1 in Table 1 Was produced. In M1 to M4, polyvinyl alcohol was used as an emulsifier. Since polyvinyl alcohol is a water soluble polymer, the soil modifiers M1 to M4 contain a water soluble polymer.
＜Ｍ１＞
攪拌機付きの高圧重合缶に、予め１００部の純水に乳化剤としてポリビニルアルコール（デンカポバールＢ−０５（鹸化度８８ｍｏｌ％、平均重合度６００、デンカ株式会社製））４．１部及びデンカポバールＢ−１７（鹸化度８８ｍｏｌ％、平均重合度１７００、デンカ株式会社製）１．５部、助剤としてホルムアミジンスルフィン酸０．１部、酢酸ソーダ０．２部、硫酸第一鉄七水和物０．００５部、エチレンジアミン四酢酸四ナトリウム０．０１部を溶解したものを投入後、攪拌下酢酸ビニルモノマー及びエチレンを充填し内液温度を５５℃とした後、過硫酸アンモニウム水溶液を連続添加し重合を行った。酢酸ビニルモノマーは１０９部、エチレンは２０部を仕込んだ。重合末期にｔ−ブチルハイドロパーオキサイド水溶液を添加し、未反応の酢酸ビニルモノマー量が２％未満になるまで重合を継続した。
重合後に残存するエチレンをパージし、生成したエマルジョン中の未反応の酢酸ビニルモノマーを減圧除去した結果、未反応の酢酸ビニルモノマーが０．５％以下の水性樹脂エマルジョンを得た。
得られた水性樹脂エマルジョンの固形分率をＪＩＳ Ｋ ６８２８に準じて測定した。乾燥条件は、１０５℃で３時間とした。固形分率は５５％であった。トルエン不溶分は４８％であった。
<M1>
In a high-pressure polymerization can equipped with a stirrer, 100 parts of pure water in advance as an emulsifier, 4.1 parts of polyvinyl alcohol (DENKA POVAL B-05 (saponification degree 88 mol%, average polymerization degree 600, manufactured by DENKA CORPORATION)) and DENKA POVAL B -17 (Saponification degree 88 mol%, average degree of polymerization 1700, Denka Co., Ltd.) 1.5 parts, 0.1 part of formamidinesulfinic acid as auxiliary, 0.2 parts of sodium acetate, ferrous sulfate heptahydrate A charged solution of 0.005 part and 0.01 part of tetrasodium ethylenediaminetetraacetate is charged, filled with a vinyl acetate monomer and ethylene under stirring, and the internal solution temperature is set to 55 ° C., and then an aqueous solution of ammonium persulfate is continuously added and polymerized. Did. 109 parts of vinyl acetate monomer and 20 parts of ethylene were charged. At the end of polymerization, t-butyl hydroperoxide aqueous solution was added, and polymerization was continued until the amount of unreacted vinyl acetate monomer was less than 2%.
As a result of purging ethylene remaining after polymerization and removing unreacted vinyl acetate monomer in the formed emulsion under reduced pressure, an aqueous resin emulsion containing 0.5% or less of unreacted vinyl acetate monomer was obtained.
The solid fraction of the obtained aqueous resin emulsion was measured according to JIS K 6828. Drying conditions were at 105 ° C. for 3 hours. The solid content was 55%. The toluene insoluble content was 48%.
＜Ｍ２〜Ｍ３＞
予めデンカポバールＢ−２０（鹸化度８８ｍｏｌ％、平均重合度２０００、デンカ株式会社製）の１２％水溶液を作成し、土壌改質剤Ｍ１に表１に示す濃度となるようそれぞれ添加して土壌改質剤Ｍ２及び土壌改質剤Ｍ３を得た。
<M2 to M3>
Prepare a 12% aqueous solution of Denkapovar B-20 (saponification degree 88 mol%, average degree of polymerization 2000, Denka Co., Ltd.) in advance and add it to the soil modifier M1 to give the concentrations shown in Table 1 A texture agent M2 and a soil conditioner M3 were obtained.
＜Ｍ５＞
攪拌機付きの重合缶に、アクリル酸ブチル７８部、メタクリル酸メチル２０部、ドデシルベンゼンスルホン酸ナトリウム２部、水１００部を加え、過硫酸アンモニウム０．２部により８０℃で６時間重合させた。重合転化率は９９％であった。１０％水酸化カリウム水溶液でｐＨ７に中和し、固形分５０質量％のポリマーエマルジョンを得た。トルエン不溶分は０％であった。
<M5>
78 parts of butyl acrylate, 20 parts of methyl methacrylate, 2 parts of sodium dodecylbenzene sulfonate, and 100 parts of water were added to a polymerization can equipped with a stirrer and polymerized with 0.2 parts of ammonium persulfate at 80 ° C. for 6 hours. The polymerization conversion was 99%. The mixture was neutralized to pH 7 with a 10% aqueous potassium hydroxide solution to obtain a polymer emulsion having a solid content of 50% by mass. The toluene insoluble content was 0%.
＜Ｍ４＞
予めデンカポバールＢ−２０（鹸化度８８ｍｏｌ％、平均重合度２０００、デンカ株式会社製）の１４％水溶液を作成し、土壌改質剤Ｍ５に表１に示す濃度となるよう添加して土壌改質剤Ｍ４を得た。
<M4>
Prepare a 14% aqueous solution of Denkapovar B-20 (saponification degree 88 mol%, average degree of polymerization 2000, Denka Co., Ltd.) in advance and add it to the soil modifier M5 to the concentration shown in Table 1 to modify the soil An agent M4 was obtained.
２．実施例・比較例
＜試験土壌の準備＞
開口面積０．１１ｍ２、容量２６Ｌのプランターに石垣島で採取した赤土１９ｋｇを仕込み、２ｋｇのハンドローラーを５回往復させて赤土表面を平らに均し、赤土表面が水平になるようにプランターを静置した。表２に示す土壌改質剤を、表２に示す散布液に調整して、静置したプランターの縁から散布液及び赤土が流出しない程度の流量で、霧吹きを用いて散布液を散布して２４時間自然乾燥させた。比較例３及び比較例４は、固形の土壌改質剤のため、それぞれ赤土１８ｋｇにセメント系固化剤１．３ｋｇを混合、赤土１９ｋｇにポリビニルアルコール１９ｇを混合した後、各実施例と同じ条件でプランターに仕込み、水のみを同様に霧吹きを用いて散布して２４時間自然乾燥させた。
2. Examples and Comparative Examples <Preparation of Test Soil>
Charge 19 kg of red soil collected on Ishigaki Island to a planter with an opening area of 0.11 m 2 and a capacity of 26 L, reciprocate the red soil surface evenly by reciprocating 2 kg hand roller 5 times, level the red soil surface so that the red soil surface becomes horizontal. Let stand. The soil modifiers shown in Table 2 are adjusted to the spray solution shown in Table 2, and the spray solution is sprayed using mist blowing at such a flow rate that the spray solution and red soil do not flow out from the edge of the stationary planter. Allow to dry naturally for 24 hours. In Comparative Example 3 and Comparative Example 4, after mixing 18 kg of red soil with 1.3 kg of a cement-based solidifying agent and mixing 19 kg of red soil with 19 g of polyvinyl alcohol for solid soil modifiers, respectively, under the same conditions as each example. The planter was charged, and water was sprayed in the same manner using a spray and allowed to dry naturally for 24 hours.
＜透水率＞
試験土壌の赤土表面が１０度の傾斜角度になるようにプランターを固定し、高さ１．５ｍの位置から、水を赤土表面全体に１２０ｍｍ／ｈで４０分間散布した。水を散布している間にプランターの縁から流出した赤土を含む水を全量回収し、赤土と水を分離して表層流出水の質量を測定した。試験は１週間間隔を空けて１０回繰り返して行い、散布水量と表層流出水の質量の１０回分の積算量について、以下の式に基づいて透水率を算出した。
透水率（％）＝１００×（散布水量（ｋｇ）−表層流出水の質量（ｋｇ））／散布水量（ｋｇ）
<Permeability>
The planter was fixed so that the red soil surface of the test soil had an inclination angle of 10 degrees, and water was sprayed from the position of 1.5 m at the surface of the red soil for 40 minutes at 120 mm / h. While spraying the water, all the water including red soil which flowed out from the edge of the planter was recovered, the red soil and the water were separated, and the mass of surface runoff water was measured. The test was repeated ten times at intervals of one week, and the water permeability was calculated based on the following equation for the integrated amount of the sprayed water amount and the mass of surface runoff water for 10 times.
Permeability (%) = 100 × (Sprayed water volume (kg)-Mass of surface runoff water (kg)) / Sprayed water volume (kg)
＜表層流出土壌量＞
表層流出水の質量を測定する際に分離した赤土の質量を測定し、１０回分の積算量について、以下の式に基づいて表層流出土壌量を算出した。
表層流出土壌量（ｇ／ｍ２）＝赤土の質量（ｇ）／プランターの開口面積（ｍ２）
<Surface runoff soil volume>
When measuring the mass of surface runoff water, the mass of the red soil separated was measured, and the surface runoff soil amount was calculated based on the following formula about the accumulated amount of 10 times.
Surface runoff soil amount (g / m 2 ) = mass of red soil (g) / opening area of planter (m 2 )
表２中のＭ６〜Ｍ８の詳細は、以下の通りである。
Ｍ６：水
Ｍ７：セメント系固化剤（フライアッシュセメント）
Ｍ８：ポリビニルアルコール（デンカポバールＢ−２０、デンカ株式会社製）
The details of M6 to M8 in Table 2 are as follows.
M6: Water M7: Cement-based solidifying agent (fly ash cement)
M8: Polyvinyl alcohol (DENKA POVAL B-20, manufactured by DENKA CORPORATION)
３．考察
表１及び表２に示すように、水性樹脂エマルジョンと水溶性高分子を含む土壌改質剤Ｍ１〜Ｍ４を用いた実施例１〜６では、比較例１〜４に比べて透水率が高く、表層流出土壌量が少なかった。
また、水性樹脂エマルジョンが酢酸ビニルに由来する構造単位を含む土壌改質剤Ｍ１〜Ｍ３では、透水率が特に高かった。
さらに、土壌改質剤中の水溶性高分子の含有量が固形分換算で１〜１２質量％である土壌改質剤Ｍ１〜Ｍ２では、表層流出土壌量が特に少なく、水溶性高分子の含有量が１〜７質量％である土壌改質剤Ｍ１では、表層流出土壌量がさらに少なかった。
3. Discussion As shown in Tables 1 and 2, in Examples 1 to 6 using the soil modifiers M1 to M4 containing an aqueous resin emulsion and a water-soluble polymer, the water permeability is higher than in Comparative Examples 1 to 4. And the amount of surface runoff soil was small.
Moreover, water permeability was particularly high in the soil modifiers M1 to M3 in which the aqueous resin emulsion contains a structural unit derived from vinyl acetate.
Furthermore, in the soil modifying agents M1 to M2 in which the content of the water-soluble polymer in the soil modifying agent is 1 to 12% by mass in terms of solid content, the amount of surface runoff soil is particularly small and the water-soluble polymer is contained The amount of surface runoff soil amount was further smaller in the soil modifying agent M1 having an amount of 1 to 7% by mass.
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| WO2021075104A1 (en) * | 2019-10-18 | 2021-04-22 | デンカ株式会社 | Method for spraying resin emulsion |
| WO2021090751A1 (en) * | 2019-11-05 | 2021-05-14 | デンカ株式会社 | Soil modification method |
| WO2022230462A1 (en) * | 2021-04-30 | 2022-11-03 | デンカ株式会社 | Method for scattering soil erosion inhibitor |
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