JP2019081735A - Fabric-type hair cosmetics - Google Patents
Fabric-type hair cosmetics Download PDFInfo
- Publication number
- JP2019081735A JP2019081735A JP2017210418A JP2017210418A JP2019081735A JP 2019081735 A JP2019081735 A JP 2019081735A JP 2017210418 A JP2017210418 A JP 2017210418A JP 2017210418 A JP2017210418 A JP 2017210418A JP 2019081735 A JP2019081735 A JP 2019081735A
- Authority
- JP
- Japan
- Prior art keywords
- fabric
- hair
- acid
- type hair
- cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003676 hair preparation Substances 0.000 title abstract description 7
- 239000004744 fabric Substances 0.000 claims abstract description 56
- 239000000835 fiber Substances 0.000 claims abstract description 39
- -1 polyethylene terephthalate Polymers 0.000 claims abstract description 38
- 229920000728 polyester Polymers 0.000 claims abstract description 33
- 229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 10
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 10
- 150000002148 esters Chemical class 0.000 claims abstract description 7
- 229920001707 polybutylene terephthalate Polymers 0.000 claims abstract description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 5
- 229920000570 polyether Polymers 0.000 claims abstract description 5
- 229920002215 polytrimethylene terephthalate Polymers 0.000 claims abstract description 4
- 239000002537 cosmetic Substances 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 14
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 238000009940 knitting Methods 0.000 description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 238000011282 treatment Methods 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 9
- 231100000640 hair analysis Toxicity 0.000 description 9
- 238000010306 acid treatment Methods 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 230000006872 improvement Effects 0.000 description 8
- 230000007935 neutral effect Effects 0.000 description 8
- 230000004888 barrier function Effects 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
- 230000003699 hair surface Effects 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- 229940077388 benzenesulfonate Drugs 0.000 description 3
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 230000037308 hair color Effects 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002759 woven fabric Substances 0.000 description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- QCSIRLGSMWDFMF-UHFFFAOYSA-K 5-sulfonatobenzene-1,3-dicarboxylate tetrabutylphosphanium Chemical compound [O-]C(=O)c1cc(cc(c1)S([O-])(=O)=O)C([O-])=O.CCCC[P+](CCCC)(CCCC)CCCC.CCCC[P+](CCCC)(CCCC)CCCC.CCCC[P+](CCCC)(CCCC)CCCC QCSIRLGSMWDFMF-UHFFFAOYSA-K 0.000 description 2
- BWLOPTUNEMCWSZ-UHFFFAOYSA-K 5-sulfonatobenzene-1,3-dicarboxylate tetraphenylphosphanium Chemical compound [O-]C(=O)c1cc(cc(c1)S([O-])(=O)=O)C([O-])=O.c1ccc(cc1)[P+](c1ccccc1)(c1ccccc1)c1ccccc1.c1ccc(cc1)[P+](c1ccccc1)(c1ccccc1)c1ccccc1.c1ccc(cc1)[P+](c1ccccc1)(c1ccccc1)c1ccccc1 BWLOPTUNEMCWSZ-UHFFFAOYSA-K 0.000 description 2
- FQVMIQKRLZHUDJ-UHFFFAOYSA-K 5-sulfonatobenzene-1,3-dicarboxylate tributyl(ethyl)phosphanium Chemical compound CCCC[P+](CC)(CCCC)CCCC.CCCC[P+](CC)(CCCC)CCCC.CCCC[P+](CC)(CCCC)CCCC.[O-]C(=O)c1cc(cc(c1)S([O-])(=O)=O)C([O-])=O FQVMIQKRLZHUDJ-UHFFFAOYSA-K 0.000 description 2
- DALNSBKXJGCIGM-UHFFFAOYSA-K 5-sulfonatobenzene-1,3-dicarboxylate tributyl(phenyl)phosphanium Chemical compound [O-]C(=O)c1cc(cc(c1)S([O-])(=O)=O)C([O-])=O.CCCC[P+](CCCC)(CCCC)c1ccccc1.CCCC[P+](CCCC)(CCCC)c1ccccc1.CCCC[P+](CCCC)(CCCC)c1ccccc1 DALNSBKXJGCIGM-UHFFFAOYSA-K 0.000 description 2
- 229920001634 Copolyester Polymers 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229920001410 Microfiber Polymers 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 2
- MAAPEMRACZBJAD-UHFFFAOYSA-K benzyl(tributyl)phosphanium 5-sulfonatobenzene-1,3-dicarboxylate Chemical compound [O-]C(=O)c1cc(cc(c1)S([O-])(=O)=O)C([O-])=O.CCCC[P+](CCCC)(CCCC)Cc1ccccc1.CCCC[P+](CCCC)(CCCC)Cc1ccccc1.CCCC[P+](CCCC)(CCCC)Cc1ccccc1 MAAPEMRACZBJAD-UHFFFAOYSA-K 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000002781 deodorant agent Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000747 poly(lactic acid) Polymers 0.000 description 2
- 239000004626 polylactic acid Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- USFPINLPPFWTJW-UHFFFAOYSA-N tetraphenylphosphonium Chemical class C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 USFPINLPPFWTJW-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- ZRPKEUVFESZUKX-UHFFFAOYSA-N 2-(2-hydroxyethoxy)benzoic acid Chemical compound OCCOC1=CC=CC=C1C(O)=O ZRPKEUVFESZUKX-UHFFFAOYSA-N 0.000 description 1
- XCSGHNKDXGYELG-UHFFFAOYSA-N 2-phenoxyethoxybenzene Chemical compound C=1C=CC=CC=1OCCOC1=CC=CC=C1 XCSGHNKDXGYELG-UHFFFAOYSA-N 0.000 description 1
- WLPLZSMVVXVBNF-UHFFFAOYSA-M 3,5-bis(2-hydroxyethoxycarbonyl)benzenesulfonate;tetrabutylphosphanium Chemical compound CCCC[P+](CCCC)(CCCC)CCCC.OCCOC(=O)C1=CC(C(=O)OCCO)=CC(S([O-])(=O)=O)=C1 WLPLZSMVVXVBNF-UHFFFAOYSA-M 0.000 description 1
- YRUPCSWZCGCUJC-UHFFFAOYSA-M 3,5-bis(2-hydroxyethoxycarbonyl)benzenesulfonate;tetraphenylphosphanium Chemical compound OCCOC(=O)C1=CC(C(=O)OCCO)=CC(S([O-])(=O)=O)=C1.C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 YRUPCSWZCGCUJC-UHFFFAOYSA-M 0.000 description 1
- UJTVVWPLCZHEJR-UHFFFAOYSA-N 3,7-bis(methoxycarbonyl)naphthalene-1-sulfonic acid Chemical compound C1=C(C(=O)OC)C=C(S(O)(=O)=O)C2=CC(C(=O)OC)=CC=C21 UJTVVWPLCZHEJR-UHFFFAOYSA-N 0.000 description 1
- NMYFVWYGKGVPIW-UHFFFAOYSA-N 3,7-dioxabicyclo[7.2.2]trideca-1(11),9,12-triene-2,8-dione Chemical compound O=C1OCCCOC(=O)C2=CC=C1C=C2 NMYFVWYGKGVPIW-UHFFFAOYSA-N 0.000 description 1
- KIINLFFTVAGQMM-UHFFFAOYSA-M 3-(2-hydroxyethoxycarbonyl)benzenesulfonate;tetraphenylphosphanium Chemical compound OCCOC(=O)C1=CC=CC(S([O-])(=O)=O)=C1.C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 KIINLFFTVAGQMM-UHFFFAOYSA-M 0.000 description 1
- OWNFQPAIKMPBGF-UHFFFAOYSA-N 3-methoxycarbonylbenzenesulfonic acid Chemical compound COC(=O)C1=CC=CC(S(O)(=O)=O)=C1 OWNFQPAIKMPBGF-UHFFFAOYSA-N 0.000 description 1
- QMWGSOMVXSRXQX-UHFFFAOYSA-N 3-sulfobenzoic acid Chemical compound OC(=O)C1=CC=CC(S(O)(=O)=O)=C1 QMWGSOMVXSRXQX-UHFFFAOYSA-N 0.000 description 1
- BSELDXNAHWCMLH-UHFFFAOYSA-L 3-sulfonatobenzoate tetrabutylphosphanium Chemical compound [O-]C(=O)c1cccc(c1)S([O-])(=O)=O.CCCC[P+](CCCC)(CCCC)CCCC.CCCC[P+](CCCC)(CCCC)CCCC BSELDXNAHWCMLH-UHFFFAOYSA-L 0.000 description 1
- JYQJLVPMTBJMTI-UHFFFAOYSA-M 4-(2-hydroxyethoxy)benzenesulfonate;tetrabutylphosphanium Chemical compound OCCOC1=CC=C(S([O-])(=O)=O)C=C1.CCCC[P+](CCCC)(CCCC)CCCC JYQJLVPMTBJMTI-UHFFFAOYSA-M 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- XSKHNLJEVZQCQU-UHFFFAOYSA-L C(CCC)[P+](CCCC)(CCCC)CCCC.C(=O)([O-])C1=CC=C(C2=CC=CC=C12)S(=O)(=O)[O-].C(CCC)[P+](CCCC)(CCCC)CCCC Chemical compound C(CCC)[P+](CCCC)(CCCC)CCCC.C(=O)([O-])C1=CC=C(C2=CC=CC=C12)S(=O)(=O)[O-].C(CCC)[P+](CCCC)(CCCC)CCCC XSKHNLJEVZQCQU-UHFFFAOYSA-L 0.000 description 1
- CJFPMTARSAMKHW-UHFFFAOYSA-L CCCC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[O-]C(C1=CC(S(O)(=O)=O)=CC(C([O-])=O)=C1)=O.OC(C1=CC(S(O)(=O)=O)=CC(C(O)=O)=C1)=O.C(C1=CC=CC=C1)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound CCCC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[O-]C(C1=CC(S(O)(=O)=O)=CC(C([O-])=O)=C1)=O.OC(C1=CC(S(O)(=O)=O)=CC(C(O)=O)=C1)=O.C(C1=CC=CC=C1)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 CJFPMTARSAMKHW-UHFFFAOYSA-L 0.000 description 1
- 101150001310 DPH2 gene Proteins 0.000 description 1
- 235000012012 Paullinia yoco Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920001283 Polyalkylene terephthalate Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- VEGPYAOWYWDJKW-UHFFFAOYSA-M benzenesulfonate;tetrabutylphosphanium Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1.CCCC[P+](CCCC)(CCCC)CCCC VEGPYAOWYWDJKW-UHFFFAOYSA-M 0.000 description 1
- BUDPGRUUAXTNRB-UHFFFAOYSA-K benzyl(triphenyl)phosphanium 5-sulfonatobenzene-1,3-dicarboxylate Chemical compound [O-]C(=O)c1cc(cc(c1)S([O-])(=O)=O)C([O-])=O.C(c1ccccc1)[P+](c1ccccc1)(c1ccccc1)c1ccccc1.C(c1ccccc1)[P+](c1ccccc1)(c1ccccc1)c1ccccc1.C(c1ccccc1)[P+](c1ccccc1)(c1ccccc1)c1ccccc1 BUDPGRUUAXTNRB-UHFFFAOYSA-K 0.000 description 1
- 239000012620 biological material Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- JHPRWPIHJBDGSI-UHFFFAOYSA-K butyl(triphenyl)phosphanium 5-sulfonatobenzene-1,3-dicarboxylate Chemical compound [O-]C(=O)c1cc(cc(c1)S([O-])(=O)=O)C([O-])=O.CCCC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.CCCC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.CCCC[P+](c1ccccc1)(c1ccccc1)c1ccccc1 JHPRWPIHJBDGSI-UHFFFAOYSA-K 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
- YGSZNSDQUQYJCY-UHFFFAOYSA-L disodium;naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1S([O-])(=O)=O YGSZNSDQUQYJCY-UHFFFAOYSA-L 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- GVBWZHALHMDKQL-UHFFFAOYSA-K ethyl(triphenyl)phosphanium 5-sulfonatobenzene-1,3-dicarboxylate Chemical compound [O-]C(=O)c1cc(cc(c1)S([O-])(=O)=O)C([O-])=O.CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1 GVBWZHALHMDKQL-UHFFFAOYSA-K 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000003230 hygroscopic agent Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- ZERIVMMUDSPYOZ-UHFFFAOYSA-M lithium;3,7-bis(methoxycarbonyl)naphthalene-1-sulfonate Chemical compound [Li+].C1=C(C(=O)OC)C=C(S([O-])(=O)=O)C2=CC(C(=O)OC)=CC=C21 ZERIVMMUDSPYOZ-UHFFFAOYSA-M 0.000 description 1
- GGKPBCOOXDBLLG-UHFFFAOYSA-M lithium;3-carboxy-5-sulfobenzoate Chemical compound [Li+].OC(=O)C1=CC(C(O)=O)=CC(S([O-])(=O)=O)=C1 GGKPBCOOXDBLLG-UHFFFAOYSA-M 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- XTEGVFVZDVNBPF-UHFFFAOYSA-N naphthalene-1,5-disulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1S(O)(=O)=O XTEGVFVZDVNBPF-UHFFFAOYSA-N 0.000 description 1
- KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical compound C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- FJIZBDJKYXYPAE-UHFFFAOYSA-M potassium;3,5-bis(methoxycarbonyl)benzenesulfonate Chemical compound [K+].COC(=O)C1=CC(C(=O)OC)=CC(S([O-])(=O)=O)=C1 FJIZBDJKYXYPAE-UHFFFAOYSA-M 0.000 description 1
- DVBBBJFTGOHNHC-UHFFFAOYSA-M potassium;3,5-dicarboxybenzenesulfonate Chemical compound [K+].OC(=O)C1=CC(C(O)=O)=CC(S([O-])(=O)=O)=C1 DVBBBJFTGOHNHC-UHFFFAOYSA-M 0.000 description 1
- KJNLNBUCZYHGPG-UHFFFAOYSA-M potassium;3,7-bis(methoxycarbonyl)naphthalene-1-sulfonate Chemical compound [K+].C1=C(C(=O)OC)C=C(S([O-])(=O)=O)C2=CC(C(=O)OC)=CC=C21 KJNLNBUCZYHGPG-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229940077386 sodium benzenesulfonate Drugs 0.000 description 1
- LLHSEQCZSNZLRI-UHFFFAOYSA-M sodium;3,5-bis(methoxycarbonyl)benzenesulfonate Chemical compound [Na+].COC(=O)C1=CC(C(=O)OC)=CC(S([O-])(=O)=O)=C1 LLHSEQCZSNZLRI-UHFFFAOYSA-M 0.000 description 1
- YXTFRJVQOWZDPP-UHFFFAOYSA-M sodium;3,5-dicarboxybenzenesulfonate Chemical compound [Na+].OC(=O)C1=CC(C(O)=O)=CC(S([O-])(=O)=O)=C1 YXTFRJVQOWZDPP-UHFFFAOYSA-M 0.000 description 1
- PXMZGQMCKRIHHE-UHFFFAOYSA-M sodium;3,7-dicarboxynaphthalene-1-sulfonate Chemical compound [Na+].C1=C(C(O)=O)C=C(S([O-])(=O)=O)C2=CC(C(=O)O)=CC=C21 PXMZGQMCKRIHHE-UHFFFAOYSA-M 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- BJQWBACJIAKDTJ-UHFFFAOYSA-N tetrabutylphosphanium Chemical class CCCC[P+](CCCC)(CCCC)CCCC BJQWBACJIAKDTJ-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Artificial Filaments (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
Abstract
Description
本発明は、毛髪を保護する布帛型毛髪用化粧料に関する。 The present invention relates to a fabric-type hair cosmetic for protecting hair.
毛髪はカラーリングやパーマ処理等の化学的処理によりバリア機能が低下し、パサつき感や毛髪の広がり、毛髪そのものが損傷を受ける。このような痛んだ毛髪を洗髪すると蛋白質や色素成分等の毛髪内部の成分が流出する。 Hair has a reduced barrier function due to chemical treatments such as coloring and perming treatment, so that the feeling of spreading, spreading of hair, and hair itself are damaged. When such painful hair is washed, components inside the hair such as protein and pigment components flow out.
このような問題に対し、ヘアリンス組成物を洗髪後に使用する事で毛髪を被覆し、毛髪内部の水分が蒸発する事を防ぎ、潤いや艶を与え、ボリュームダウンを図るということが知られている（例えば特許文献１参照）。 To solve these problems, it is known that hair rinse composition is used after hair-washing to coat the hair, prevent evaporation of the water inside the hair, impart moisture and gloss, and achieve volume reduction. (See, for example, Patent Document 1).
但し、ヘアリンス組成物は毛髪内部へ浸透するわけではないため、洗髪や日常生活の中で効果を失う。さらには、カラーリング直後等の毛髪のダメージが大きい場合は効果を得ることが難しかった。 However, since the hair rinse composition does not penetrate into the hair, it loses its effect in hair washing and daily life. Furthermore, it was difficult to obtain an effect when hair damage is large immediately after coloring and the like.
本発明は上記の背景に鑑みなされたものであり、その目的は、毛髪を保護する布帛型毛髪用化粧料を提供することにある。 The present invention has been made in view of the above background, and an object thereof is to provide a fabric-type hair cosmetic composition for protecting hair.
本発明者らは上記の課題を達成するため鋭意検討した結果、低ｐＨの布帛を用いて毛髪用化粧料を構成することにより、常時毛髪を健全なバリア機能を発現する弱酸性状態になることを見出し、さらに鋭意検討を重ねることにより本発明を完成するに至った。 As a result of intensive investigations to achieve the above-mentioned problems, the present inventors have constructed a hair cosmetic composition using a low pH fabric to make the hair always in a weakly acidic state that expresses a healthy barrier function. The present invention has been completed by further intensive studies.
かくして本発明によれば、「毛髪用化粧料であって、ｐＨが４．０〜６．５の範囲内である布帛を含むことを特徴とする布帛型毛髪用化粧料。」が提供される。
その際、布帛型毛髪用化粧料をＪＩＳ Ｌ ０２１７法に規定された洗濯を５回行った後において、布帛型毛髪用化粧料のｐＨが７．０未満であることが好ましい。
また、ポリエチレンテレフタレートまたはポリブチレンテレフタレートまたはポリトリメチレンテレフタレートまたはポリエーテルエステルを含むポリエステル繊維が布帛に含まれることが好ましい。
その際、ポリエステル繊維に第３成分が共重合され、スルホン酸基またはカルボキシル基を有することが好ましい。
また、前記布帛型毛髪用化粧料の構造が、枕カバー構造、ヘアキャップ構造、帽子構造、タオル構造、ハンカチ構造、スカーフ構造、ヘアバンド構造、フェイスマスク構造、布団カバー構造、シーツ構造からなる群より選択されるいずれかであることが好ましい。
Thus, according to the present invention, there is provided "a cosmetic for hair, which comprises a fabric having a pH in the range of 4.0 to 6.5." .
At that time, it is preferable that the pH of the cosmetic for fabric type hair is less than 7.0 after the cosmetic for fabric type hair is washed five times according to the JIS L 0217 method.
In addition, it is preferable that the fabric contains polyester fibers containing polyethylene terephthalate or polybutylene terephthalate or polytrimethylene terephthalate or polyether ester.
At that time, it is preferable that the third component is copolymerized with the polyester fiber and has a sulfonic acid group or a carboxyl group.
In addition, the structure of the fabric type hair cosmetic comprises a pillow cover structure, a hair cap structure, a hat structure, a towel structure, a handkerchief structure, a scarf structure, a hair band structure, a face mask structure, a duvet cover structure, and a sheet structure. It is preferable that it is any selected.
本発明によれば、毛髪を保護する布帛型毛髪用化粧料が得られる。 According to the present invention, a fabric-type hair cosmetic that protects hair is obtained.
以下、本発明の実施の形態ついて詳細に説明する。本発明の布帛型毛髪用化粧料は、布帛を用いた布帛型毛髪用化粧料であって、前記布帛のｐＨが４．０〜６．５（好ましくは４．０〜６．０、特に好ましくは４．０〜５．５）である。本発明の布帛型毛髪用化粧料は、布帛のｐＨが前記範囲であることにより、驚くべきことに、毛髪のバリア機能生成および艶感を付与する性能に優れる。 Hereinafter, embodiments of the present invention will be described in detail. The cosmetic for fabric-type hair of the present invention is a cosmetic for fabric-type hair using a fabric, and the pH of the fabric is 4.0 to 6.5 (preferably 4.0 to 6.0, particularly preferably). Is 4.0 to 5.5). The fabric-type hair cosmetic of the present invention is surprisingly excellent in the performance of imparting a hair barrier function and imparting a luster when the pH of the fabric is in the above-mentioned range.
ここで、ｐＨの測定は、以下の方法で行うことが好ましい。すなわち、前記布帛をｐＨ７．０の水（中性水）に、浴比１：５（ウェア型毛髪用化粧料と中性水の重量比が（布帛：中性水）１：５）で浸漬し、温度１２０℃で３０分間処理した後、布帛を取り出し、残液のｐＨを市販のｐＨメーターで測定し、これを布帛のｐＨとすることが好ましい。また、布帛の上に市販の万能ｐＨ試験紙を置き、その上からｐＨ７．０の水０．０５〜０．１０ｃｃを垂らし、次いで、ガラス棒で万能ｐＨ試験紙を布帛に押し付け、万能ｐＨ試験紙から布帛上に転写された色でｐＨをグレースケールにて目視判定することにより、布帛のｐＨを測定することができる。 Here, the pH is preferably measured by the following method. That is, the fabric is immersed in water (neutral water) having a pH of 7.0 and a bath ratio of 1: 5 (the weight ratio of the cosmetic for wear-type hair to neutral water is 1: 5 (fabric: neutral water)) After treatment for 30 minutes at a temperature of 120.degree. C., the fabric is taken out and the pH of the residue is measured with a commercially available pH meter, which is preferably used as the pH of the fabric. Also, place a commercially available universal pH test paper on the fabric, drop 0.05 to 0.10 cc of water at pH 7.0 from above, then press the universal pH test paper on the fabric with a glass rod, and then perform a universal pH test The pH of the fabric can be measured by visually determining the pH in grayscale on the color transferred from the paper onto the fabric.
ここで、前記布帛を形成する繊維としては、例えば、特許第５７５８８０７号に記載されているようなポリエステル繊維を含むことが好ましい。特に、ポリエチレンテレフタレートまたはポリブチレンテレフタレートまたはポリトリメチレンテレフタレートであるポリエステル繊維が３０重量％以上含まれていることが好ましい。すなわち、前記繊維としては、テレフタル酸を主たる二官能性カルボン酸成分とし、エチレングリコール、トリメチレンテレングリコール、テトラメチレングリコールなどを主たるグリコール成分とするポリアルキレンテレフタレート系ポリエステルが好ましい。 Here, as fibers forming the fabric, for example, it is preferable to include polyester fibers as described in Japanese Patent No. 5758807. In particular, it is preferable that 30% by weight or more of polyester fibers which are polyethylene terephthalate, polybutylene terephthalate or polytrimethylene terephthalate be contained. That is, as said fiber, the polyalkylene terephthalate type polyester which uses a terephthalic acid as a main difunctional carboxylic acid component, and uses ethylene glycol, trimethylene terephthalate, tetramethylene glycol etc. as a main glycol component is preferable.
また、前記繊維は、特許第４２０２３６１号公報に記載されているような、ポリブチレンテレフタレートをハードセグメントとしポリオキシエチレングリコールをソフトセグメントとするポリエーテルエステルや、ポリブチレンテレフタレートをハードセグメントとし、ポリ（オキシテトラメチレン）グリコールをソフトセグメントとするポリエーテルエステルでもよい。また、前記ポリエステルとしては、マテリアルリサイクルまたはケミカルリサイクルされたポリエステルでもよいし、特開２００４−２７００９７号公報や特開２００４−２１１２６８号公報に記載されているような、特定のリン化合物およびチタン化合物を含む触媒を用いて得られたポリエステルでもよいし、バイオマスすなわち生物由来の物質を原材料として得られたモノマー成分を使用してなるポリエチレンテレフタレート、ポリ乳酸、ステレオコンプレックスポリ乳酸であってもよい。 Further, the fibers may be made of polyether ester having polybutylene terephthalate as a hard segment and polyoxyethylene glycol as a soft segment as described in Japanese Patent No. 4202361, and polybutylene terephthalate as a hard segment, poly ( It may be a polyether ester having oxytetramethylene glycol as a soft segment. The polyester may be material recycled or chemically recycled polyester, or specific phosphorus compounds and titanium compounds as described in JP-A 2004-270097 and JP-A 2004-211268. It may be a polyester obtained by using a catalyst containing it, or polyethylene terephthalate, polylactic acid or stereocomplex polylactic acid formed using a monomer component obtained by using biomass, ie, a substance derived from a biological material as a raw material.
また、前記繊維は、テレフタル酸成分の一部を他の二官能性カルボン酸成分で置換えたポリエステルであってもよく、および／またはグリコール成分の一部を他のジオール化合物で置換えたポリエステルであってもよい。 In addition, the fiber may be a polyester in which a part of terephthalic acid component is substituted by another difunctional carboxylic acid component, and / or a polyester in which a part of glycol component is substituted by another diol compound. May be
その際、使用されるテレフタル酸以外の二官能性カルボン酸としては、例えばイソフタ
ル酸、ナフタレンジカルボン酸、ジフェニルジカルボン酸、ジフェノキシエタンジカルボ
ン酸、β−ヒドロキシエトキシ安息香酸、ｐ−オキシ安息香酸、アジピン酸、セバシン酸
、１，４−シクロヘキサンジカルボン酸の如き芳香族、脂肪族、脂環族の二官能性カルボ
ン酸をあげることができる。
In that case, as difunctional carboxylic acids other than the terephthalic acid used, for example, isophthalic acid, naphthalene dicarboxylic acid, diphenyl dicarboxylic acid, diphenoxy ethane dicarboxylic acid, β-hydroxyethoxybenzoic acid, p-hydroxybenzoic acid, adipine There may be mentioned aromatic, aliphatic and alicyclic difunctional carboxylic acids such as acid, sebacic acid and 1,4-cyclohexanedicarboxylic acid.
また、前記繊維に用いるポリエステルに硫黄（Ｓ）が含まれていると、後記のような酸性処理により布帛のｐＨを前記範囲とすることができ好ましい。その際、硫黄（Ｓ）は全ポリエステル重量に対して０．０３〜１．０重量％含まれていることが好ましい。ポリエステルに含まれる硫黄の量が該範囲よりも小さいと、後記のような酸性処理を施しても布帛のｐＨが前記範囲にならないおそれがある。逆に、ポリエステルに含まれる硫黄の量が該範囲よりも大きいと、後記のような酸性処理を施した際に布帛の強力が低下するおそれがある。 Moreover, when sulfur (S) is contained in polyester used for the said fiber, pH of a cloth can be made into the said range by acid treatment like a postscript, and it is preferable. In that case, it is preferable that sulfur (S) is contained 0.03 to 1.0 weight% with respect to the total polyester weight. If the amount of sulfur contained in the polyester is smaller than the above range, the pH of the fabric may not fall within the above range even after the acid treatment as described later. On the contrary, when the amount of sulfur contained in the polyester is larger than the above range, the strength of the fabric may be reduced when the acid treatment as described later is performed.
前記ポリエステルに硫黄（Ｓ）を含有させる方法としては、前記ポリエステルに、エステル形成性スルホン酸基含有化合物を共重合させることが好ましい。かかるエステル形成性スルホン酸基含有化合物としてはエステル形成性官能基を有するスルホン酸基含有化合物であれば特に限定する必要はなく、下記一般式（１）で表わされるエステル形成性スルホン酸金属塩化合物および／または下記一般式（２）で表わされるエステル形成性スルホン酸ホスホニウム塩化合物を好ましいものとしてあげることができる。 As a method of containing sulfur (S) in the polyester, it is preferable to copolymerize an ester-forming sulfonic acid group-containing compound in the polyester. The ester-forming sulfonic acid group-containing compound is not particularly limited as long as it is a sulfonic acid group-containing compound having an ester-forming functional group, and an ester-forming sulfonic acid metal salt compound represented by the following general formula (1) An ester-forming sulfonic acid phosphonium salt compound represented by the following general formula (2) can be mentioned as a preferable one.
式（１）
式（２）
上記一般式（１）において、Ａ１は芳香族基または脂肪族基を示し、好ましくは炭素数６〜１５の芳香族炭化水素基または炭素数１０以下の脂肪族炭化水素基である。特に好ましいＡ１は、炭素数６〜１２の芳香族炭化水素基、とりわけベンゼン環である。Ｘ１はエステル形成性官能基を示し、具体例として下記式（３）等をあげることができる。 In the above general formula (1), A1 represents an aromatic group or an aliphatic group, preferably an aromatic hydrocarbon group having 6 to 15 carbon atoms or an aliphatic hydrocarbon group having 10 or less carbon atoms. Particularly preferable A1 is an aromatic hydrocarbon group having 6 to 12 carbon atoms, particularly a benzene ring. X 1 represents an ester-forming functional group, and the following formula (3) can be mentioned as a specific example.
式（３）
また、上記一般式（１）において、Ｘ２はＸ１と同一もしくは異なるエステル形成性官能基又は水素原子を示し、なかでもエステル形成性官能基であることが好ましい。Ｍはアルカリ金属またはアルカリ土類金属であり、ｍは正の整数である。なかでもＭがアルカリ金属（例えばリチウムまたはナトリウムまたはカリウム）であり、かつｍが１であるものが好ましい。 In the above general formula (1), X2 represents an ester-forming functional group which is the same as or different from X1 or a hydrogen atom, and among these, an ester-forming functional group is preferable. M is an alkali metal or alkaline earth metal, and m is a positive integer. Among them, those in which M is an alkali metal (for example, lithium or sodium or potassium) and m is 1 are preferable.
上記一般式（１）で表わされるエステル形成性スルホン酸金属塩化合物の好ましい具体例としては、３，５−ジカルボメトキシベンゼンスルホン酸ナトリウム、３，５−ジカルボメトキシベンゼンスルホン酸カリウム、３，５−ジカルボメトキシベンゼンスルホン酸リチウム、３，５−ジカルボキシベンゼンスルホン酸ナトリウム、３，５−ジカルボキシベンゼンスルホン酸カリウム、３，５−ジカルボキシベンゼンスルホン酸リチウム、３，５−ジ（β−ヒドロキシエトキシカルボニル）ベンゼンスルホン酸ナトリウム、３，５−ジ（β−ヒドロキシエトキシカルボニル）ベンゼンスルホン酸カリウム、３，５−ジ（β−ヒドロキシエトキシカルボニル）ベンゼンスルホン酸リチウム、２，６−ジカルボメトキシナフタレン−４−スルホン酸ナトウリム、２，６−ジカルボメトキシナフタレン−４−スルホン酸カリウム、２，６−ジカルボメトキシナフタレン−４−スルホン酸リチウム、２，６−ジカルボキシナフタレン−４−スルホン酸ナトリウム、２，６−ジカルボメトキシスフタレン−１−スルホン酸ナトリウム、２，６−ジカルボメトキシナフタレン−３−スルホン酸ナトリウム、２，６−ジカルボメトキシナフタレン−４，８−ジスルホン酸ナトリウム、２，６−ジカルボキシナフタレン−４，８−ジスルホン酸ナトリウム、２，５−ビス（ヒドロエトキシ）ベンゼンスルホン酸ナトリウム、α−ナトリウムスルホコハク酸などをあげることができる。上記エステル形成性スルホン酸金属塩化合物は１種のみを単独で用いても、２種以上併用してもよい。 Preferred specific examples of the ester-forming metal sulfonate compound represented by the above general formula (1) include sodium 3,5-dicarbomethoxybenzenesulfonate, potassium 3,5-dicarbomethoxybenzenesulfonate, and 3, Lithium 5-dicarbomethoxybenzenesulfonate, sodium 3,5-dicarboxybenzenesulfonate, potassium 3,5-dicarboxybenzenesulfonate, lithium 3,5-dicarboxybenzenesulfonate, 3,5-di (β -Hydroxyethoxycarbonyl) sodium benzenesulfonate, potassium 3,5-di (β-hydroxyethoxycarbonyl) benzenesulfonate, lithium 3,5-di (β-hydroxyethoxycarbonyl) benzenesulfonate, 2,6-dicarbo Methoxynaphthalene-4-sulfonic acid Tourim, potassium 2,6-dicarbomethoxynaphthalene-4-sulfonate, lithium 2,6-dicarbomethoxynaphthalene-4-sulfonate, sodium 2,6-dicarboxynaphthalene-4-sulfonate, 2,6- Sodium dicarbomethoxy phthalene 1-sulfonate, sodium 2,6-dicarbomethoxy naphthalene-3-sulfonate, sodium 2,6-dicarbomethoxy naphthalene-4,8-disulfonate, 2,6-dicarboxy Sodium naphthalene-4,8-disulfonate, sodium 2,5-bis (hydroethoxy) benzenesulfonate, α-sodium sulfosuccinic acid and the like can be mentioned. The ester forming metal sulfonate metal salt compounds may be used alone or in combination of two or more.
上記一般式（２）において、Ａ２は芳香族基または脂肪族基を示し、上記一般式（１）におけるＡ１の定義と同じである。Ｘ３はエステル形成性官能基を示し、上記一般式（１）におけるＸ１の定義と同じであり、Ｘ４はＸ３と同一もしくは異なるエステル形成性官能基又は水素原子を示し、上記一般式（１）におけるＸ２の定義と同じである。Ｒ１、Ｒ２、Ｒ３およびＲ４はアルキル基およびアリール基よりなる群から選ばれた同一または異なる基を示す。ｎは正の整数であり、なかでも１であるものが好ましい。 In the general formula (2), A2 represents an aromatic group or an aliphatic group, and is the same as the definition of A1 in the general formula (1). X3 represents an ester-forming functional group, which is the same as the definition of X1 in the general formula (1), and X4 represents an ester-forming functional group or a hydrogen atom which is the same as or different from X3, and in the general formula (1) It is the same as the definition of X2. R1, R2, R3 and R4 each represent the same or different group selected from the group consisting of an alkyl group and an aryl group. n is a positive integer, preferably one.
上記エステル形成性スルホン酸ホスホニウム塩化合物の好ましい具体例としては、３，５―ジカルボキシベンゼンスルホン酸テトラブチルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸エチルトリブチルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸ベンジルトリブチルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸フェニルトリブチルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸テトラフェニルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸ブチルトリフェニルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸ベンジルトリフェニルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸テトラブチルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸エチルトリブチルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸ベンジルトリブチルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸フェニルトリブチルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸テトラフェニルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸エチルトリフェニルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸ブチルトリフェニルホスホニウム塩、３，５―ジカルボキシベンゼンスルホン酸ベンジルトリフェニルホスホニウム塩、３―カルボキシベンゼンスルホン酸テトラブチルホスホニウム塩、３―カルボキシベンゼンスルホン酸テトラフェニルホスホニウム塩、３―カルボメトキシベンゼンスルホン酸テトラブチルホスホニウム塩、３―カルボメトキシベンゼンスルホン酸テトラフェニルホスホニウム塩、３，５―ジ（β―ヒドロキシエトキシカルボニル）ベンゼンスルホン酸テトラブチルホスホニウム塩、３，５―ジ（β―ヒドロキシエトキシカルボニル）ベンゼンスルホン酸テトラフェニルホスホニウム塩、３―（β―ヒドロキシエトキシカルボニル）ベンゼンスルホン酸テトラブチルホスホニウム塩、３―（β―ヒドロキシエトキシカルボニル）ベンゼンスルホン酸テトラフェニルホスホニウム塩、４―ヒドロキシエトキシベンゼンスルホン酸テトラブチルホスホニウム塩、２，６―ジカルボキシナフタレン―４―スルホン酸テトラブチルホスホニウム塩、α―テトラブチルホスホニウムスルホコハク酸等をあげることができる。上記エステル形成性スルホン酸ホスホニウム塩は１種のみを単独で用いても、２種以上併用してもよい。 Preferred specific examples of the ester-forming sulfonic acid phosphonium salt compound include 3,5-dicarboxybenzenesulfonic acid tetrabutylphosphonium salt, 3,5-dicarboxybenzenesulfonic acid ethyl tributylphosphonium salt, 3,5-dicarboxy Benzenesulfonic acid benzyltributylphosphonium salt, 3,5-dicarboxybenzenesulfonic acid phenyltributylphosphonium salt, 3,5-dicarboxybenzenesulfonic acid tetraphenylphosphonium salt, 3,5-dicarboxybenzenesulfonic acid butyltriphenylphosphonium salt 3,5-Dicarboxybenzenesulfonic acid benzyltriphenylphosphonium salt, 3,5-dicarboxybenzenesulfonic acid tetrabutylphosphonium salt, 3,5-dicarboxybenzenesulfonic acid Ethyl tributyl phosphonium salt, 3,5-dicarboxy benzene sulfonic acid benzyl tributyl phosphonium salt, 3,5- dicarboxy benzene sulfonic acid phenyl tributyl phosphonium salt, 3,5- dicarboxy benzene sulfonic acid tetraphenyl phosphonium salt, 3 , 5-Dicarboxybenzenesulfonic acid ethyltriphenylphosphonium salt, 3,5-dicarboxybenzenesulfonic acid butyltriphenylphosphonium salt, 3,5-dicarboxybenzenesulfonic acid benzyltriphenylphosphonium salt, 3-carboxybenzenesulfonic acid Tetrabutylphosphonium salt, Tetraphenylphosphonium salt of 3-carboxybenzenesulfonic acid, Tetrabutylphosphonium salt of 3-carbomethoxybenzenesulfonic acid, 3-carbome Xylbenzenesulfonic acid tetraphenylphosphonium salt, 3,5-di (β-hydroxyethoxycarbonyl) benzenesulfonic acid tetrabutylphosphonium salt, 3,5-di (β-hydroxyethoxycarbonyl) benzenesulfonic acid tetraphenylphosphonium salt, 3 -(Β-hydroxyethoxycarbonyl) benzenesulfonic acid tetrabutylphosphonium salt, 3- (β-hydroxyethoxycarbonyl) benzenesulfonic acid tetraphenylphosphonium salt, 4-hydroxyethoxybenzenesulfonic acid tetrabutylphosphonium salt, 2,6-dibasic Examples thereof include carboxynaphthalene-4-sulfonic acid tetrabutyl phosphonium salt, α-tetrabutyl phosphonium sulfosuccinic acid and the like. The ester-forming sulfonic acid phosphonium salts may be used alone or in combination of two or more.
前記共重合ポリエステルポリマー中には、本発明の目的を損なわない範囲内で必要に応じて、微細孔形成剤、カチオン染料可染剤、着色防止剤、熱安定剤、蛍光増白剤、艶消し剤、着色剤、吸湿剤、無機微粒子が１種または２種以上含まれていてもよい。 In the above-mentioned copolymerized polyester polymer, a micropore forming agent, a cationic dye dyeable agent, a coloring inhibitor, a heat stabilizer, a fluorescent whitening agent, and a matting agent as needed within the range not impairing the object of the present invention. The agent, the colorant, the hygroscopic agent, and the inorganic fine particles may be contained alone or in combination of two or more.
上記エステル形成性スルホン酸基含有化合物をポリエステルに共重合するには、前述したポリエステルの合成が完了する以前の任意の段階で、好ましくは第２段階の反応の初期以前の任意の段階で添加すればよい。２種以上併用する場合、それぞれの添加時期は任意でよく、両者を別々に添加しても、予め混合して同時に添加してもよい。 In order to copolymerize the ester-forming sulfonic acid group-containing compound into a polyester, it may be added at any stage before the synthesis of the polyester described above is completed, preferably at any stage before the initial stage of the second stage reaction. Just do it. When 2 or more types are used together, each addition time may be arbitrary, and both may be added separately, or they may be mixed in advance and simultaneously added.
また、前記ポリエステルは特開２００９−１６１６９３号公報に記載されているような、常圧カチオン可染性ポリエステルであってもよい。 The polyester may be an atmospheric pressure cationic dyeable polyester as described in JP-A-2009-161693.
前記ポリエステル繊維の繊維形態は特に限定されないが、繊維の表面積を大きくして優れた抗菌性や消臭性を得る上で短繊維（紡績糸）よりも長繊維（マルチフィラメント糸）であることが好ましい。特に、前記ポリエステル繊維を芯鞘型複合繊維とし、前記共重合ポリエステルを鞘部に配し、第３成分を共重合しないポリエチレンテレフタレートなどを芯部に配したり、または、前記ポリエステル繊維をサイドバイサイド型複合繊維とし、前記共重合ポリエステルを１方に配し、第３成分を共重合しないポリエチレンテレフタレートなどを他方に配することは好ましいことである。 The fiber form of the polyester fiber is not particularly limited, but in order to increase the surface area of the fiber to obtain excellent antibacterial and deodorant properties, it is a long fiber (multifilament yarn) rather than a short fiber (spun yarn) preferable. In particular, the polyester fiber is used as a core-sheath composite fiber, the copolyester is disposed in the sheath, and a polyethylene terephthalate or the like in which the third component is not copolymerized is disposed in the core, or the polyester fiber is side-by-side type It is preferable to use a composite fiber in which the copolyester is disposed in one direction and a polyethylene terephthalate or the like in which the third component is not copolymerized is disposed in the other.
前記ポリエステル繊維において、単繊維の断面形状は特に限定されないが、丸断面よりも、三角、扁平、くびれ部が３箇所以上のくびれ付扁平、丸中空、三角中空、四角中空、Ｈ型、Ｗ型、フィン付断面など異型断面（すなわち、丸断面以外の断面）のほうが、単繊維の表面積が大きくなり好ましい。また、かかるポリエステル繊維には、通常の空気加工、仮撚捲縮加工、撚糸が施されていてもさしつかえない。特に、ポリエステル繊維の嵩を高めて繊維の表面積を大きくして優れた抗菌性や消臭性を得る上で、仮撚捲縮加工を施すことは好ましいことである。その際、仮撚捲縮加工糸の捲縮率としては１％以上であることが好ましい。また、国際公開第２００８／００１９２０号パンフレットに記載されているような、Ｓ方向のトルクを有する仮撚捲縮加工糸とＺ方向のトルクを有する仮撚捲縮加工糸とを複合させることにより得られた、低トルクの複合糸であってもよい。 In the polyester fiber, the cross-sectional shape of the single fiber is not particularly limited, but it is triangular, flat, narrow with three or more constricted portions, round hollow, round hollow, triangular hollow, square hollow, square H, W type than round cross section , And a cross section other than a round shape such as a finned cross section (that is, a cross section other than a round cross section) is preferable because the surface area of the single fiber is large. In addition, such polyester fibers may be subjected to ordinary air processing, false twist crimping, or twisting. In particular, in order to increase the bulk of the polyester fiber and to increase the surface area of the fiber to obtain excellent antibacterial and deodorant properties, it is preferable to perform a false twist crimp process. At that time, the crimp rate of the false twist crimped yarn is preferably 1% or more. In addition, it is obtained by combining a false twist crimped yarn having a torque in the S direction and a false twist crimped yarn having a torque in the Z direction as described in WO 2008/001920 pamphlet. It may be a low torque composite yarn.
また、前記ポリエステル繊維において、単繊維繊度およびフィラメント数としては、繊
維の表面積を大きくして毛髪への接触面積を増やし、優れた毛髪のバリア機能生成及び艶感を得る上で、単繊維繊度は小さいほどよく、フィラメント数は大きいほどよい。単繊維繊度としては５．０ｄｔｅｘ以下（より好ましくは０．０００１〜２．５ｄｔｅｘ、さらに好ましくは０．００１〜１．５ｄｔｅｘ）であることが好ましい。また、フィラメント数３０〜５００００本（より好ましくは３０〜２００本）であることが好ましい。また、特公平７−６３４３８号公報に記載されているような極細繊維や、特開２００９−０２４２７８号公報に記載されているような超極細繊維であってもよい。前記ポリエステル繊維の総繊度（単繊維繊度とフィラメント数との掛け算）としては、毛髪への接触時の着用快適性を得る上で１０〜２００ｄｔｅｘであることが好ましい。
In the polyester fiber, the single fiber fineness and the number of filaments are such that the surface area of the fiber is increased to increase the contact area with the hair, and the fineness of the single fiber is obtained to obtain excellent hair barrier function generation and glossiness. The smaller the better, the larger the number of filaments. The single fiber fineness is preferably 5.0 dtex or less (more preferably 0.0001 to 2.5 dtex, further preferably 0.001 to 1.5 dtex). The number of filaments is preferably 30 to 50,000 (more preferably 30 to 200). Moreover, the ultrafine fibers as described in Japanese Patent Publication No.7-63438, and the ultrafine fibers as described in Japanese Patent Application Laid-Open No. 2009-024278 may be used. The total fineness (the multiplication of the single fiber fineness and the number of filaments) of the polyester fiber is preferably 10 to 200 dtex in order to obtain wearing comfort when in contact with hair.
前記のｐＨを有する布帛は、例えば、以下の製造方法により製造することができる。すなわち、エステル形成性スルホン酸金属塩化合物および／またはエステル形成性スルホン酸ホスホニウム塩化合物を共重合した、前記のポリエステル繊維を用いて布帛を得る。 The fabric having the above pH can be produced, for example, by the following production method. That is, a polyester fiber obtained by copolymerizing an ester-forming sulfonic acid metal salt compound and / or an ester-forming sulfonic acid phosphonium salt compound is used to obtain a fabric.
その際、前記の布帛の組織は特に限定されず、織物でもよいし編物でもよいし不織布でもよい。例えば、織物の織組織では、平織、斜文織、朱子織等の三原組織、変化組織、変化斜文織等の変化組織、たて二重織、よこ二重織等の片二重組織、たてビロード、タオル、ベロア等のたてパイル織、別珍、よこビロード、ベルベット、コール天等のよこパイル織などが例示される。なお、これらの織組織を有する織物は、レピア織機やエアージェット織機など通常の織機を用いて通常の方法により製織することができる。層数も特に限定されず単層でもよいし２層以上の多層構造を有する織物でもよい。 At this time, the structure of the above-mentioned fabric is not particularly limited, and may be a woven fabric, a knitted fabric or a non-woven fabric. For example, in the woven structure of woven fabric, Mihara tissue such as plain weave, twill weave, satin weave, change texture, change texture such as change twill weave, single double texture such as warp double weave, weft double weave, Vertical pile, such as vertical velvet, towel, velor, Bevelen, Yoko velvet, velvet, horizontal pile, such as call heaven, etc. are illustrated. In addition, the woven fabric having these woven structures can be woven by a usual method using a usual loom such as a rapier loom or an air jet loom. The number of layers is not particularly limited, and may be a single layer or a fabric having a multilayer structure of two or more layers.
また、編物の種類では、よこ編物であってもよいしたて編物であってもよい。よこ編組
織としては、平編、ゴム編、両面編、パール編、タック編、浮き編、片畔編、レース編、
添え毛編等が好ましく例示され、たて編組織としては、シングルデンビー編、シングルア
トラス編、ダブルコード編、ハーフトリコット編、裏毛編、ジャガード編等が好ましく例
示される。なお、製編は、丸編機、横編機、トリコット編機、ラッシェル編機等など通常
の編機を用いて通常の方法により製編することができる。層数も特に限定されず単層でも
よいし２層以上の多層構造を有する編物でもよい。
Moreover, in the kind of knitting, it may be a warp knitting or a warp knitting. The horizontal knitting structure includes flat knitting, rubber knitting, double-sided knitting, pearl knitting, tack knitting, floating knitting, single-piece knitting, lace knitting,
Supplementary knitting is preferably exemplified, and examples of warp knitting include single denby knitting, single atlas knitting, double cord knitting, half tricot knitting, fleece knitting, jacquard knitting and the like. The knitting can be performed by a usual method using a usual knitting machine such as a circular knitting machine, a flat knitting machine, a tricot knitting machine, a Raschel knitting machine and the like. The number of layers is not particularly limited, and may be a single layer or a knitted fabric having a multilayer structure of two or more layers.
次いで、該布帛に酸性処理を施す。かかる方法によれば、繊維に含まれる、エステル形成性スルホン酸金属塩化合物および／またはエステル形成性スルホン酸ホスホニウム塩化合物のイオン部がプロトン化され、布帛が酸性化する。 The fabric is then subjected to an acid treatment. According to this method, the ion portion of the ester-forming sulfonic acid metal salt compound and / or the ester-forming sulfonic acid phosphonium salt compound contained in the fiber is protonated to acidify the fabric.
布帛に酸性処理を施す方法としては、例えば、前記布帛を酢酸やりんご酸などによりｐＨが５．０以下（好ましくは２．０〜５．０）に調製された浴中に温度７０℃以上（好ましくは８０〜１３０℃、特に好ましくは９０〜１３０℃）、時間２０〜４０分間で浸漬するとよい。その際、繊維の段階で浴中に浸漬してもよいし、布帛を得た後、浴中に浸漬してもよい。また、使用する設備としては、公知の繊維生地を染色する液流染色機を用いるとよい。 As a method of subjecting the fabric to acid treatment, for example, the temperature of 70 ° C. or more (in a bath prepared by adjusting the above-mentioned fabric to 5.0 or less (preferably 2.0 to 5.0) with acetic acid or malic acid etc. Preferably, the substrate is dipped at 80 to 130 ° C., particularly preferably 90 to 130 ° C., for 20 to 40 minutes. At that time, it may be immersed in the bath at the fiber stage, or may be immersed in the bath after obtaining the fabric. In addition, as equipment to be used, it is preferable to use a jet flow dyeing machine for dyeing known fiber fabrics.
また、布帛には、前記酸性処理の前および／または後の工程において、常法の繊維生地の染色加工、精練、リラックス、プレセット、ファイナルセット、吸水加工などの各種加工を施してもよい。 In addition, the fabric may be subjected to various processes such as dyeing, scouring, relaxation, presetting, final setting, water absorption, etc. of a conventional fiber fabric in the steps before and / or after the acid treatment.
本発明の布帛型毛髪用化粧料は前記の布帛を用いてなる。その際、布帛に前記布帛が布帛型毛髪用化粧料重量に対し１０重量％以上（より好ましくは４０重量％以上、最も好ましくは１００重量％）含まれることが好ましい。 The cosmetic for fabric-type hair of the present invention uses the above-mentioned fabric. At that time, it is preferable that the fabric contains 10% by weight or more (more preferably 40% by weight or more, most preferably 100% by weight) based on the weight of the cosmetic for fabric type hair.
本発明の布帛型毛髪用化粧料は、前記の布帛を用いているので、毛髪のバリア生成機能性に耐久性よく優れる。その際、布帛において、毛髪試験による平均摩擦係数の改善率としては３０％であることが好ましい。また、毛髪試験による艶感評価において２級以上（より好ましくは、３級以上）であることが好ましい。 The fabric-type hair cosmetic of the present invention uses the above-described fabric, and is thus excellent in durability with respect to the barrier generation functionality of the hair. At that time, in the fabric, the improvement rate of the average coefficient of friction by the hair test is preferably 30%. Moreover, it is preferable that it is 2nd or more (more preferably 3rd or more) in gloss evaluation by a hair test.
本発明の布帛型毛髪用化粧料は、枕カバー構造、ヘアキャップ構造、帽子構造、タオル構造、ハンカチ構造、スカーフ構造、ヘアバンド構造、フェイスマスク構造、布団カバー構造、シーツ構造の群より選ばれるいずれかの構造を有することが好ましい。 The cosmetic for fabric type hair of the present invention is selected from the group of pillow cover structure, hair cap structure, hat structure, towel structure, handkerchief structure, scarf structure, hair band structure, face mask structure, duvet cover structure, sheet structure. It is preferable to have any structure.
本発明の布帛型毛髪用化粧料において、毛髪のバリア生成機能性に耐久性よく優れる理由についてはまだ明らかにされていないが、ウェア型毛髪用化粧が酸性化されているので、毛髪へ接触する事により毛髪の雰囲気環境も酸性化し、毛髪が健康な状態にしめしているためであろうと推定している。 In the fabric-type hair cosmetic of the present invention, the reason why the barrier-generating functionality of the hair is excellently durable is not clarified yet, but since the wear-type hair cosmetic is acidified, it contacts the hair. It is presumed that it is probably because the atmosphere environment of the hair is also acidified and the hair is in a healthy condition.
以下、実施例及び比較例をあげて本発明を具体的に説明する。但し、本発明はこれらによって何ら限定されるものではない。各測定値は以下の方法で測定される値である。 Hereinafter, the present invention will be specifically described by way of examples and comparative examples. However, the present invention is not limited at all by these. Each measured value is a value measured by the following method.
（１）布帛型毛髪用化粧料のｐＨ
試料をｐＨ７．０（中性水）に、浴比１：５（試料と中性水との重量比が（試料：中性水）１：５で浸漬し、温度１２０℃で３０分間処理した後、試料を取り出し、残液のｐＨを市販のｐＨメーター（株式会社アタゴ製、型式ＤＰＨ−２）で測定し、これを布帛型毛髪用化粧料のｐＨとした。なお、洗濯前（Ｌ０）と、ＪＩＳ Ｌ０２１７法に規定された洗濯を５回行なった後（Ｌ５）について測定した。
(1) pH of fabric-type hair cosmetic
The sample was immersed in pH 7.0 (neutral water) at a bath ratio of 1: 5 (weight ratio of sample to neutral water (sample: neutral water) 1: 5) and treated at a temperature of 120 ° C. for 30 minutes Thereafter, the sample was taken out, and the pH of the residual liquid was measured with a commercially available pH meter (manufactured by Atago Co., Ltd., model DPH-2), and this was used as the pH of the cosmetic for fabric type hair. And it measured about (L5), after performing the washing | cleaning prescribed | regulated to the JIS L0217 method 5 times.
（２）毛髪の準備
ヘアカラー用処理剤として、酸化染料が配合されたアルカリカラーからなる１剤と６％重量％過酸化水素が配合されｐＨが３．０に調整された２剤を１：１の割合で混合し、ヘアカラー用処理剤とした。
次いで化学的処理を施していないテスト用人毛黒髪毛束（株式会社ビューラックス製）（毛髪サンプル１）にヘアカラー用処理剤を塗布し、３５℃で３０分間放置した。その後、精製水で１分間すすぎ、ドライヤーを用いて乾燥させ、ダメージ毛髪（毛髪サンプル２）を作成した。しかる後に毛髪サンプル１及び毛髪サンプル２については、常法のシャンプーとカチオン界面活性剤が配合をされたトリートメント処理を施し、ドライヤーを用いて乾燥させた。
(2) Preparation of hair As a hair coloring treatment agent, one agent consisting of an alkali color compounded with an oxidation dye and two agents compounded with 6% by weight of hydrogen peroxide and adjusted to a pH of 3.0 1: It mixed by the ratio of 1, and was set as the processing agent for hair colors.
Subsequently, the treatment agent for hair coloring was apply | coated to the test human hair black hair tress (made by Beaulax Co., Ltd.) (hair sample 1) which has not given the chemical processing, and it left at 35 degreeC for 30 minutes. Thereafter, it was rinsed with purified water for 1 minute and dried using a drier to prepare damaged hair (hair sample 2). Thereafter, the hair sample 1 and the hair sample 2 were treated with a conventional shampoo and a cationic surfactant, and dried using a drier.
（３）毛髪表面摩擦抵抗値
毛髪サンプル（毛束）について摩擦感テスター（ＫＥＳ−ＳＥ、カトーテック株式会社製）を用いて測定し、これを布帛型毛髪用化粧料により処理を行なった平均摩擦係数（ＭＩＵ）とした。なお、平均摩擦係数（ＭＩＵ）の数値が小さいときに、バリア機能生成効果が高いと評価できる。
(3) Hair surface friction resistance value A hair sample (hair bundle) is measured using a friction tester (KES-SE, manufactured by Kato Tech Co., Ltd.), and this is an average friction treated with a fabric-type hair cosmetic. It is a coefficient (MIU). In addition, when the numerical value of the mean friction coefficient (MIU) is small, it can be evaluated that the barrier function generation effect is high.
（４）艶感評価
試験者３人の官能評価により下記の３段階に評価した。３級：処理前に比べて改善した。２級：処理前にくらべてやや改善した。１級：処理前と比べて改善が無い。
(4) Evaluation of glossiness Evaluation was made on the following three levels by sensory evaluation of three examiners. Grade 3: Improved compared to before treatment. Level 2: Slightly improved compared to before treatment. Level 1: There is no improvement compared to before processing.
［実施例１］
衣料用繊維生地の編成に用いる２８ゲージ丸編機を使用し、エステル反応性スルホン酸基含有化合物を１．５モル％にて共重合し、カルボキシル基が付与されたポリエチレンテレフタレート仮撚捲縮加工糸（総繊度８４ｄｔｅｘ／７２ｆｉｌ）のみを用いてスムース丸編組織を有する布帛を作製した。
Example 1
Using a 28 gauge circular knitting machine used for knitting textile fabric for clothes, 1.5 mol% of an ester reactive sulfonic acid group containing compound is copolymerized to give a carboxyl group-added polyethylene terephthalate false twist crimped process Only yarn (total fineness 84 dtex / 72 fil) was used to prepare a fabric having a smooth circular knit structure.
次いで、該布帛を酢酸によりｐＨ３．９に調整された浴中に１１０℃、３０分で浸漬することにより酸性処理を実施し、しかる後に１５０℃で６０秒間の乾燥を実施した。得られた布帛を基材に用いた布帛型毛髪用化粧料のｐＨは５．９を示し、５回の洗濯後においてもｐＨ６．５を示した。 The acid treatment was then carried out by immersing the fabric in a bath adjusted to pH 3.9 with acetic acid at 110 ° C. for 30 minutes, followed by drying at 150 ° C. for 60 seconds. The pH of the cosmetic for fabric type hair using the obtained fabric as a base material was 5.9, and it was 6.5 even after 5 times of washing.
得られた布帛型毛髪用化粧料について、毛髪に対するバリア機能生成作用試験を実施した。蒸留水にて湿潤させ、しかる後に脱水を実施した布帛型毛髪用化粧料に１ｇの毛髪サンプル１の毛束を面圧７．８ｋＰａにて均一に３時間接触させ、使用試験を実施した。毛髪表面摩擦抵抗値測定による平均摩擦係数（ＭＩＵ）の改善率は５７．９％を示し、毛髪表面の艶感が、処理前と比べて改善した（３級）。評価結果を表１に示す。 About the obtained fabric type hair cosmetics, the barrier function production | generation effect test with respect to hair was implemented. The use test was carried out by bringing the hair bundle of 1 g of the hair sample 1 into contact with the fabric type hair cosmetic which was moistened with distilled water and then dewatered uniformly for 3 hours at a surface pressure of 7.8 kPa. The improvement rate of the average coefficient of friction (MIU) by hair surface frictional resistance value measurement showed 57.9%, and the glossiness of the hair surface was improved compared with that before treatment (grade 3). The evaluation results are shown in Table 1.
［実施例２］
実施例１において、使用評価に用いるサンプルを化学的処理による損傷を伴ったダメージ毛髪（毛髪サンプル２）を用いたこと以外は同様にした。得られた結果は、平均摩擦係数（ＭＩＵ）の改善率は５０．０％を示し、毛髪表面の艶感が、処理前と比べて改善した（３級）。評価結果を表１に示す。
Example 2
The same procedure as in Example 1 was repeated except that the sample used for the use evaluation was damaged hair (hair sample 2) damaged by chemical treatment. The results obtained show that the improvement rate of the average coefficient of friction (MIU) is 50.0%, and the gloss of the hair surface is improved compared to that before the treatment (third grade). The evaluation results are shown in Table 1.
［比較例１］
実施例２において酸性処理を施さないこと以外は実施例２と同様にした。得られた布帛型化粧料は、ｐＨは中性（Ｌ０、Ｌ５ともにｐＨ７．０）であり、平均摩擦係数（ＭＩＵ）の改善率及び毛髪表面の艶感の改善も不十分であった。評価結果を表１に示す。
Comparative Example 1
Example 2 was the same as Example 2 except that the acid treatment was not performed. The obtained fabric type cosmetic had a pH of neutral (pH 7.0 for both L0 and L5), and the improvement of the average coefficient of friction (MIU) and the improvement of the gloss of the hair surface were also insufficient. The evaluation results are shown in Table 1.
［比較例２］
実施例２において通常のポリエチレンテレフタレート（第３成分を共重合していないポリエチレンテレフタレート）仮撚捲縮加工糸（総繊度８４ｄｔｅｘ／７２ｆｉｌ）のみを用いてスムース丸編組織を有する繊維構造体を作成したこと以外は実施例２と同様にした。得られた布帛型化粧料は、ｐＨは中性（Ｌ０、Ｌ５ともにｐＨ７．０）であり、平均摩擦係数（ＭＩＵ）の改善率及び毛髪表面の艶感の改善も不十分であった。評価結果を表１に示す。
Comparative Example 2
In Example 2, a fibrous structure having a smooth circular knit structure was prepared using only normal polyethylene terephthalate (polyethylene terephthalate not copolymerized with the third component) false twist crimped yarn (total fineness 84 dtex / 72 fil). The same as Example 2 except for the above. The obtained fabric type cosmetic had a pH of neutral (pH 7.0 for both L0 and L5), and the improvement of the average coefficient of friction (MIU) and the improvement of the gloss of the hair surface were also insufficient. The evaluation results are shown in Table 1.
本発明によれば、毛髪を保護する布帛型毛髪用化粧料が提供され、その工業的価値は極めて大である。 According to the present invention, a fabric-type hair cosmetic for protecting hair is provided, and its industrial value is extremely great.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017210418A JP6967425B2 (en) | 2017-10-31 | 2017-10-31 | Fabric type hair cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017210418A JP6967425B2 (en) | 2017-10-31 | 2017-10-31 | Fabric type hair cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2019081735A true JP2019081735A (en) | 2019-05-30 |
| JP6967425B2 JP6967425B2 (en) | 2021-11-17 |
Family
ID=66670012
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017210418A Active JP6967425B2 (en) | 2017-10-31 | 2017-10-31 | Fabric type hair cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6967425B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020132580A (en) * | 2019-02-21 | 2020-08-31 | 帝人フロンティア株式会社 | Fabric type hair cosmetic |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002518414A (en) * | 1998-06-22 | 2002-06-25 | ザ、プロクター、エンド、ギャンブル、カンパニー | Treated wipes |
| JP2002325619A (en) * | 2001-02-28 | 2002-11-12 | Kao Corp | Hair wig tool and hair treating method |
| JP2011020937A (en) * | 2009-07-14 | 2011-02-03 | Hoyu Co Ltd | Hair-treating agent composition and method for treating hair |
| US20110048446A1 (en) * | 2009-05-12 | 2011-03-03 | Peter Marte Torgerson | Method of Delivering a Hair-Care Benefit and a Fragrance |
| WO2011048888A1 (en) * | 2009-10-20 | 2011-04-28 | 帝人ファイバー株式会社 | Polyester fibers, process for production of the polyester fibers, cloth, fiber product, and polyester molded article |
| JP2013512203A (en) * | 2009-11-25 | 2013-04-11 | コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Concentrate for substrate processing |
| JP2015030676A (en) * | 2013-07-31 | 2015-02-16 | ホーユー株式会社 | Hair cosmetic |
| JP2015189727A (en) * | 2014-03-28 | 2015-11-02 | 花王株式会社 | Sheet-shaped hair cosmetic, and hair treatment method and scalp cleaning method using the same |
-
2017
- 2017-10-31 JP JP2017210418A patent/JP6967425B2/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002518414A (en) * | 1998-06-22 | 2002-06-25 | ザ、プロクター、エンド、ギャンブル、カンパニー | Treated wipes |
| JP2002325619A (en) * | 2001-02-28 | 2002-11-12 | Kao Corp | Hair wig tool and hair treating method |
| US20110048446A1 (en) * | 2009-05-12 | 2011-03-03 | Peter Marte Torgerson | Method of Delivering a Hair-Care Benefit and a Fragrance |
| JP2011020937A (en) * | 2009-07-14 | 2011-02-03 | Hoyu Co Ltd | Hair-treating agent composition and method for treating hair |
| WO2011048888A1 (en) * | 2009-10-20 | 2011-04-28 | 帝人ファイバー株式会社 | Polyester fibers, process for production of the polyester fibers, cloth, fiber product, and polyester molded article |
| JP2013512203A (en) * | 2009-11-25 | 2013-04-11 | コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Concentrate for substrate processing |
| JP2015030676A (en) * | 2013-07-31 | 2015-02-16 | ホーユー株式会社 | Hair cosmetic |
| JP2015189727A (en) * | 2014-03-28 | 2015-11-02 | 花王株式会社 | Sheet-shaped hair cosmetic, and hair treatment method and scalp cleaning method using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6967425B2 (en) | 2021-11-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5758807B2 (en) | POLYESTER FIBER, PROCESS FOR PRODUCING THE SAME, AND FABRIC AND FIBER PRODUCT | |
| JP2015108204A (en) | Woven fabric made of composite spun yarn | |
| CN104602905B (en) | Imitation leather textile and its production method | |
| JP6967425B2 (en) | Fabric type hair cosmetics | |
| JP2012001827A (en) | Polyester fiber | |
| JP2007186811A (en) | Thermal-storage interlining cloth | |
| JP2005154994A (en) | Elastic conjugated yarn, woven or knitted fabric, and fiber product | |
| JP5693171B2 (en) | Easily degradable aromatic polyester fiber, method for producing the same, fiber structure and fiber product | |
| JP2012017530A (en) | Core-sheath type polyester conjugate fiber | |
| JP7267818B2 (en) | Hair fabrics and textiles | |
| JP2009263807A (en) | Electrostatic water-repellent fabric and clothes | |
| JP2012112050A (en) | Polyester fiber | |
| JP2012012749A (en) | Core-sheath type polyester conjugate fiber | |
| JP5290833B2 (en) | Antistatic fabric manufacturing method and apparel manufacturing method | |
| JP2006176916A (en) | Cellulose-based union fabric | |
| JP6266953B2 (en) | Deodorant fiber structure and textile product | |
| JP2010265560A (en) | Water-absorbing fabric and fiber product | |
| JP2019137945A (en) | Fabric and fiber structure | |
| JP6983019B2 (en) | Cloth for bathing and bathing | |
| JP2006161204A (en) | Polyester woven fabric | |
| JP2007154363A (en) | Water-repelling plush fabric, method for producing the same and textile product | |
| JP2005023475A (en) | Uniform having excellent performance of preventing see-through and hygroscopic property | |
| JP6638437B2 (en) | Mixed yarn, woven or knitted fabric using the same, and suede-like woven or knitted fabric | |
| JP2022021872A (en) | Woven knit and manufacturing method of woven knit | |
| JP2007063691A (en) | Antistatic fabric and skin material for car seat |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20200818 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20210514 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20210601 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20210706 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20211005 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20211025 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6967425 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |