JP2006176916A - Cellulose-based union fabric - Google Patents

Cellulose-based union fabric Download PDF

Info

Publication number
JP2006176916A
JP2006176916A JP2004370706A JP2004370706A JP2006176916A JP 2006176916 A JP2006176916 A JP 2006176916A JP 2004370706 A JP2004370706 A JP 2004370706A JP 2004370706 A JP2004370706 A JP 2004370706A JP 2006176916 A JP2006176916 A JP 2006176916A
Authority
JP
Japan
Prior art keywords
cellulose
fabric
cellulosic
fibers
epoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2004370706A
Other languages
Japanese (ja)
Other versions
JP4518936B2 (en
Inventor
Toshihiko Matsui
敏彦 松井
Keiko Yoneda
圭子 米田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Original Assignee
Asahi Kasei Fibers Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Fibers Corp filed Critical Asahi Kasei Fibers Corp
Priority to JP2004370706A priority Critical patent/JP4518936B2/en
Publication of JP2006176916A publication Critical patent/JP2006176916A/en
Application granted granted Critical
Publication of JP4518936B2 publication Critical patent/JP4518936B2/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a cellulose-based union fabric having moderate stretchability, high followability to movement in wearing the same, excellent in durability for seam slipping off and the like and having W&W properties sufficiently washable in home, especially lining cloth comprising the union fabric. <P>SOLUTION: The cellulose-based union fabric is constituted of a cellulose fiber as a warp yarn and the cellulose fiber and a synthetic fiber as weft yarns and treated with an epoxy-modified silicone during resin processing of the union fabric and satisfies the following characteristics: (1) ≥3.5 grade W&W properties, (2) ≥5% stretchability in the lateral direction, (3) ≥7.5% moisture absorption. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、家庭水洗い洗濯可能で着用快適性に優れたセルロース系交織織物に関する。   The present invention relates to a cellulosic interwoven fabric that can be washed with domestic water and has excellent wearing comfort.

セルロース繊維からなる織物は、発色性の高さ、独特の風合い、吸湿性や制電性能の高さ、滑り性の良さなど数多くの特徴を持つが、反面、洗濯時に収縮したりシワに成り易く、また、強度面でも劣るといった欠点がある。これらを改善するために後加工により樹脂架橋を施して防縮性や防シワ性を向上させる技術が種々検討されてきたが、高混率セルロース繊維に於いては本発明者らの知る限り家庭で水洗い洗濯(以下、単に水洗いと記する。)が可能な技術レベルに到達したものは存在しない。一方、合成繊維からなる織物はセルロース繊維の特徴は持たないが、強度・収縮面での物性は優れる。近年、セルロース繊維と合成繊維の夫々の長所を付与させる目的で、エアー加工や仮撚加工等による複合混繊糸の開発が進められている。しかしながら、複合混繊糸を製造するのにコストがかかりすぎること、また、セルロース繊維独特の風合いが出せないこと等から汎用性の高い用途には使われていない。   Fabric made of cellulose fibers has many features such as high color development, unique texture, high moisture absorption and anti-static performance, and good slipperiness, but on the other hand, it tends to shrink or wrinkle during washing. Also, there is a disadvantage that it is inferior in strength. In order to improve these, various techniques for improving the shrinkage resistance and wrinkle resistance by applying resin cross-linking by post-processing have been studied. However, as far as the present inventors know, high-mixed cellulose fibers are washed with water at home. No one has reached the technical level at which washing (hereinafter simply referred to as water washing) is possible. On the other hand, fabrics made of synthetic fibers do not have the characteristics of cellulose fibers, but have excellent physical properties in terms of strength and shrinkage. In recent years, for the purpose of imparting the respective advantages of cellulose fibers and synthetic fibers, development of composite mixed yarns by air processing, false twisting, and the like has been advanced. However, it is not used for highly versatile applications because it is too costly to produce a composite blended yarn and the unique texture of cellulose fibers cannot be produced.

一方、経糸及び/又は緯糸のいずれかにセルロース繊維と合繊繊維を用いた交織織物は両者の特徴を活かした織物として、例えば特許文献1に開示され公知である。これらの織物の場合、家庭水洗い対応可能な織物は得られるが、セルロース繊維の混率が50%前後となるため風合いや吸湿性・制電性の観点から充分満足のいく織物とは云い難いものである。
交織織物に於いてセルロース繊維の混率を高める方法としては、特許文献2に経糸に化繊フィラメントおよび合繊フィラメントを一本交互使いで用い、且つ、セルロース繊維側に太い繊度の糸を用いる方法が開示されている。実施例によれば緯糸側も一本交互か混繊糸使いの例が開示されている。セルロース繊維の混率は、計算上54.7%〜71.4%で良好な品位と風合いを有し、洗濯収縮率が経緯ともに0%、耐磨耗性が5級の織物が開示されている。洗濯シワ等の水洗い性能の具体的な記載は無いが水洗いが可能なレベルにあるものと推測される。しかしながら、実施例の工程性量、特に経密度変化、から見る限り緯方向のストレッチ性は殆んど無いことは明確であり、着用快適性に関しては低いことは明らかである。また、該特許文献の記載に依れば、織物の風合い及び物性は、経糸の影響をより強く受けることから、緯糸にのみ化繊フィラメントと合繊フィラメントを一本づつ交互に配列して用いても化繊と合繊の長所を充分に引き出すことはできないとのことであり、該発明では経糸は一本交互使いが必須となっている。また、経糸一本交互織物は、経糸準備が煩雑であることは基より、製織工程時に化繊フィラメントと合繊フィラメントとの湿潤・乾燥特性の違いから局所的に経筋が発生し易いなどの欠点を有しており汎用性があるとはいえない。
On the other hand, a woven fabric using cellulose fibers and synthetic fibers for either warp and / or weft is disclosed in, for example, Patent Document 1 as a woven fabric utilizing the characteristics of both. In the case of these fabrics, fabrics that can be washed with home water can be obtained. However, since the mixing ratio of cellulose fibers is around 50%, it is difficult to say that the fabrics are sufficiently satisfactory from the viewpoint of texture, hygroscopicity, and antistatic properties. is there.
As a method for increasing the mixing ratio of cellulose fibers in union woven fabrics, Patent Document 2 discloses a method in which a single synthetic fiber and synthetic filament are alternately used for warp yarns, and a thick yarn is used on the cellulose fiber side. ing. According to the embodiment, an example in which one weft side is alternate or mixed yarn is used is disclosed. Cellulose fiber mixing ratio is calculated to be 54.7% to 71.4%, which has good quality and texture, and the shrinkage rate of washing is 0% for both the background and the abrasion resistance is grade 5. . Although there is no specific description of washing performance such as washing wrinkles, it is estimated that the washing performance is at a level that allows washing. However, it is clear that there is almost no stretchability in the weft direction from the viewpoint of the amount of processability in the examples, particularly the change in warp density, and it is clear that the wearing comfort is low. In addition, according to the description of the patent document, the texture and physical properties of the fabric are more strongly affected by the warp. Therefore, even if the synthetic filaments and synthetic filaments are alternately arranged only on the wefts, the synthetic fibers It is said that the advantages of synthetic fiber cannot be fully extracted, and in the present invention, it is essential to use one warp alternately. In addition, the single warp alternating fabric has the disadvantage that warp preparation tends to occur locally due to the difference in wet and dry characteristics between the synthetic filament and the synthetic filament during the weaving process, because warp preparation is complicated. It does not have versatility.

特開平6−25937号公報JP-A-6-25937 特開平7−42044号公報Japanese Patent Laid-Open No. 7-42044

上述したように先行技術に於いては、セルロース繊維の特徴を維持したまま家庭で水洗いが可能で、かつ、着用快適性に優れたセルロース系交織織物はこれまでに無かったのが実態であった。それらを加味し本発明では、家庭でも安心して水洗いができ、しかも、緯方向に適度なストレッチを付与することで着用快適性を高めたセルロース系交織織物を提供することを目的としている。   As described above, in the prior art, there has never been a cellulosic interwoven fabric that can be washed in the home while maintaining the characteristics of cellulose fiber and has excellent wearing comfort. . In consideration of them, the present invention has an object to provide a cellulosic interwoven fabric that can be washed with water at home and that has an appropriate stretch in the weft direction and has improved wearing comfort.

本発明者らは前記課題を解決するために鋭意検討した結果、製織時にセルロース繊維に少量の合成繊維を導入し、かつ、染色仕上げ加工時に適度な幅入れ処理とエポキシ変性シリコーン処理を行うことでセルロ−ス繊維の風合いや物性を損ねることなく緯伸びとイージーケア性を付与できることを見出し、本発明に到達したものである。
すなわち、本発明の構成は以下の通りからなる。
〔1〕経糸がセルロース繊維、緯糸がセルロース繊維と合成繊維から構成される交織織物において、該交織織物が樹脂加工時にエポキシ変性シリコーンで処理されてなるところの織物であって、かつ、下記(1)〜(3)の特性を満たすことを特徴とするセルロース系交織織物。
(1)W&W性が3.5級以上
(2)緯方向のストレッチ率が5%以上
(3)吸湿性が7.5%以上
As a result of intensive studies to solve the above problems, the present inventors have introduced a small amount of synthetic fiber into the cellulose fiber during weaving, and by performing appropriate width-filling treatment and epoxy-modified silicone treatment during dyeing finishing. The present inventors have found that it is possible to impart weft elongation and easy care properties without impairing the texture and physical properties of the cellulose fiber, and have reached the present invention.
That is, the configuration of the present invention is as follows.
[1] An unwoven fabric composed of cellulose fibers and warps composed of cellulose fibers and synthetic fibers, wherein the unwoven fabric is treated with epoxy-modified silicone during resin processing, and the following (1 A cellulosic union woven fabric satisfying the characteristics of (3) to (3).
(1) W & W property is 3.5 or higher (2) Stretch rate in the weft direction is 5% or higher (3) Hygroscopicity is 7.5% or higher

〔2〕前記セルロース繊維が再生セルロース繊維であることを特徴とする上記〔1〕記載のセルロース系交織織物。
〔3〕前記合成繊維がポリエステル系繊維であることを特徴とする上記〔1〕または〔2〕記載のセルロース系交織織物。
〔4〕ポリエステル系繊維がポリトリメチレンテレフタレートの加工糸であることを特徴とする上記〔3〕記載のセルロース系交織織物。
〔5〕セルロース繊維の混率が70%以上であることを特徴とする上記〔1〕〜〔4〕のいずれかに記載のセルロース系交織織物。
〔6〕上記〔1〕〜〔5〕のいずれかに記載のセルロース系交織織物からなることを特徴とするセルロース系交織裏地。
[2] The cellulose-based woven fabric according to [1], wherein the cellulose fiber is a regenerated cellulose fiber.
[3] The cellulose-based woven fabric according to [1] or [2], wherein the synthetic fiber is a polyester fiber.
[4] The cellulosic woven fabric according to the above [3], wherein the polyester fiber is a processed yarn of polytrimethylene terephthalate.
[5] The cellulosic interwoven fabric according to any one of [1] to [4], wherein a mixing ratio of the cellulose fibers is 70% or more.
[6] A cellulosic union lining comprising the cellulosic union fabric according to any one of [1] to [5] above.

本発明のセルロース系交織織物は、適度なストレッチ性を有するので着用時の運動追従性が高く、滑脱等の耐久性にも優れる。また、セルロース混率が高い織物である為吸湿性や制電性能にも優れる。更にW&W性に優れており、家庭で充分水洗いが可能なイージーケア性を有するセルロース繊維が高混率な交織織物、特に裏地適性を有するセルロース系交織裏地を提供することができる。   Since the cellulosic union woven fabric of the present invention has an appropriate stretch property, it has a high movement follow-up property when worn and is excellent in durability such as slipping. Moreover, since it is a woven fabric with a high cellulose mixing ratio, it is excellent in hygroscopicity and antistatic performance. Furthermore, it is excellent in W & W property and can provide a woven fabric having a high blending ratio of cellulose fibers having easy care properties that can be sufficiently washed with water at home, and in particular, a cellulose-based woven fabric lining having suitability for lining.

本発明について、以下具体的に説明する。
本発明の構成上の第一の特徴は、経糸がセルロース繊維、緯糸がセルロース繊維と合成繊維から構成される交織織物において、かかる織物が樹脂加工時にエポキシ変性シリコーンで処理されてなる織物から構成されている点にある。
セルロース系交織織物において、経糸か緯糸のいずれか一方にセルロース繊維を用い他方に合成繊維を用いた織物が一般的に知られており、例えば、プレーンな織物裏地用途では大半がこの単純交織品が使われている。この単純交織品の場合、セルロース繊維の混率は40〜60%が一般的である。この交織品はセルロース繊維の強度面を補う点と色合いがシャンブレーになる点が特徴になっているが、反面、風合いが合繊タッチになったり、吸湿性も半減するため摩擦帯電圧が高くなると言った欠点を持ち、必ずしも着用快適性に優れたものではなかった。
The present invention will be specifically described below.
The first structural feature of the present invention is a cross-woven fabric in which the warp is composed of cellulose fibers and the weft is composed of cellulose fibers and synthetic fibers, and the fabric is composed of a fabric that is treated with epoxy-modified silicone during resin processing. There is in point.
Among cellulosic woven fabrics, fabrics using cellulose fibers for either warp or weft and synthetic fibers for the other are generally known. For example, in plain fabric lining applications, most of these simple woven products are It is used. In the case of this simple union product, the mixing ratio of cellulose fibers is generally 40 to 60%. This unwoven product is characterized by the fact that the strength of the cellulose fiber is supplemented and the hue becomes chambray, but on the other hand, the texture becomes a synthetic fiber touch and the hygroscopic property is also halved, so the frictional voltage increases. However, it was not always excellent in wearing comfort.

これらの欠点をクリアするためにはセルロース繊維混率を高めることが必要になってくるが、そうすると逆に本発明の目的の1つである水洗い性能(洗濯シワが付き易くなる)が低下する。従って、これまでの概念では、例えば経糸か緯糸のいずれか一方にセルロース繊維を、他方にセルロース繊維と合繊繊維から構成され、セルロース繊維混率が約70%以上のセルロース系交織織物裏地の場合では、セルロース繊維の長所と水洗い性能を兼ね備えさせることは困難と考えられていたのが実状であった。
しかるに、前述したように本発明では、織物を仕上げ樹脂加工する際にエポキシ変性シリコーンを併用することにより、洗濯シワが付き難く風合い変化も少ないと言った水洗い性能が格段に向上することを発見し、困難な課題を克服するに至ったものである。本発明の最大の特徴はこのエポキシ変性シリコーンを併用処理し、水洗い性能と風合い耐久性を高めた点にある。
In order to clear these drawbacks, it is necessary to increase the mixing ratio of cellulose fibers, but conversely, the water washing performance (which easily causes washing wrinkles), which is one of the objects of the present invention, decreases. Therefore, in the conventional concept, for example, in the case of a cellulosic interwoven fabric lining composed of cellulose fibers in either warp or weft and cellulose fibers and synthetic fibers on the other side, and a cellulose fiber mixture ratio of about 70% or more, Actually, it was considered difficult to combine the advantages of cellulose fibers with water washing performance.
However, as described above, in the present invention, it was discovered that the use of an epoxy-modified silicone in combination with finishing resin processing of a woven fabric significantly improves the washing performance of washing with less wrinkling and less texture change. This has led to overcoming difficult challenges. The greatest feature of the present invention is that this epoxy-modified silicone is used in combination to improve washing performance and texture durability.

本発明の織物におけるセルロース繊維の混率は、70%以上であることが好ましく、より好ましくは72%以上、特に好ましくは80%以上である。上限は特に限定されないが、95%以下であることが好ましく、より好ましくは90%以下である。
本発明において樹脂加工時に用いるエポキシ変性シリコーンとは、数平均分子量が10000から200000のポリマーであり、セルロースの水酸基と直接反応する官能基であるエポキシ基を持つジメチルシリコーン誘導体を意味する。エポキシ基にはグリシジルタイプのものと脂環式タイプのものとがあるがいずれのタイプでも構わない。これらは単独でも混合系で使用しても構わない。
使用濃度は、他の樹脂加工剤との兼ね合いもあるが、通常0.3〜10重量%が望ましく、更に好ましくは0.5〜5重量%の範囲で用いられる。0.3重量%以下の場合は、水洗い洗濯時にシワが発生し易く所望の水洗い性能を得ることができない。一方、10重量%以上の場合は性能的には充分満たすが、過剰の未反応エポキシ変性シリコーンを除去する必要があり、手間や剤コスト的に無駄になるので望ましくない。
The mixing ratio of the cellulose fibers in the woven fabric of the present invention is preferably 70% or more, more preferably 72% or more, and particularly preferably 80% or more. Although an upper limit is not specifically limited, It is preferable that it is 95% or less, More preferably, it is 90% or less.
The epoxy-modified silicone used at the time of resin processing in the present invention is a polymer having a number average molecular weight of 10,000 to 200,000 and means a dimethyl silicone derivative having an epoxy group which is a functional group that directly reacts with a hydroxyl group of cellulose. Epoxy groups include glycidyl type and alicyclic type, but any type may be used. These may be used alone or in a mixed system.
The concentration used is preferably in the range of 0.3 to 10% by weight, more preferably 0.5 to 5% by weight, although there is a balance with other resin processing agents. In the case of 0.3% by weight or less, wrinkles are likely to occur during washing and washing, and a desired washing performance cannot be obtained. On the other hand, when the amount is 10% by weight or more, the performance is satisfactorily satisfied, but it is not desirable because it is necessary to remove excess unreacted epoxy-modified silicone, which is wasteful in labor and agent cost.

エポキシ変性シリコーンの触媒としては、後述するノンホル型グリオキザール樹脂の触媒をそのまま使用することができる。これらはエポキシ変性シリコーンに対し10〜30重量%の割合で使用すればよい。また、アミノシランカップリング剤等のバイダーを使用しても良く、他の柔軟剤を併用して使用しても構わない。エポキシ変性度(エポキシ当量)はセルロースとの反応効率を考えて選択すべきであるが、一般に市販されている数百から数千のエポキシ当量のもので充分である。
このエポキシ変性シリコーンの風合い硬化や洗濯シワの抑制効果は、エポキシ変性のシリコーンの分子量が大きいためセルロース繊維の内部まで浸透できず繊維表面の水酸基と直接反応し、強固に固定されるため繊維表面間の摩擦抵抗が低減して発現したものと推察される。また、1分子当たり多数個のエポキシ基を持つため、そのうち2個以上が反応すれば架橋的な役割を果たし、形態安定性が向上したものと推察される。この架橋作用が洗濯を繰り返しても風合い硬化が起こり難かったり、シワの付き難さに反映されているものと推測される。そのため本発明を構成する交織織物に該エポキシ変性シリコーン処理を施さない場合は、W&W性が3.5級以下になり、しかも、風合いが洗濯することで変化して硬くなるといった問題が発現する。
As the catalyst for the epoxy-modified silicone, the catalyst for the non-hol type glyoxal resin described later can be used as it is. These may be used in a proportion of 10 to 30% by weight based on the epoxy-modified silicone. Further, a binder such as an aminosilane coupling agent may be used, and other softeners may be used in combination. The degree of epoxy modification (epoxy equivalent) should be selected in consideration of the efficiency of reaction with cellulose, but a commercially available epoxy equivalent having hundreds to thousands of epoxy equivalents is sufficient.
The effect of this epoxy-modified silicone on the texture hardening and washing wrinkles is that the epoxy-modified silicone has a large molecular weight, so it cannot penetrate into the inside of the cellulose fiber and reacts directly with the hydroxyl groups on the fiber surface, so that it is firmly fixed. It is inferred that the frictional resistance was reduced. Moreover, since it has many epoxy groups per molecule | numerator, if two or more of them react, it will play the role of bridge | crosslinking and it will be guessed that the form stability improved. It is presumed that this cross-linking action hardly causes texture hardening even when washing is repeated, or is reflected in wrinkle difficulty. For this reason, when the unwoven fabric constituting the present invention is not subjected to the epoxy-modified silicone treatment, the W & W property becomes 3.5 or lower, and the problem that the texture changes and becomes harder when washed is developed.

本発明の織物の経糸および緯糸に用いられるセルロース繊維としては、キュプラアンモニウムレーヨン、ビスコースレーヨンなどの再生セルロース繊維、アセテート鹸化繊維、リヨセルに代表される精製セルロース系繊維、および、それら短繊維の紡績糸が含まれる。また、綿、麻に代表される天然繊維も包含する。好ましくは再生セルロース長繊維である。必要に応じて撚糸したり、混紡して用いても構わない。単糸繊度としては0.5〜5.5dtex、フィラメント数20〜100本、トータル繊度は30〜167dtex程度のものが好ましく用いられる。紡績糸の場合は20番から80番のものを用いることができる。場合によっては吸湿性の高い絹やウールをセルロース繊維に混紡して用いても構わない。
本発明の織物の緯糸に用いる合成繊維としては、ポリエチレンテレフタレート、ポリトリメチレンテレフタレート、ポリブチレンテレフタレート、ポリ乳酸繊維等のポリエステル系繊維、ナイロン6、ナイロン66に代表されるポリアミド繊維、ポリアクリロニトリル繊維、アセテート繊維、ポリウレタン包含糸、および、前述の合成樹脂の共重合体からなる繊維等が挙げられる。これら繊維の総繊度は33〜167dtex、好ましくは33〜110dtexの範囲であり、単糸繊度は0.5〜10dtex、好ましくは1〜5dtexの範囲である。これらの繊維は、必要に応じて、仮撚り加工されたり、撚糸されたり、混繊やカバリング等の複合糸の形で用いることができる。勿論、サイドバイサイド型のコンジュゲート糸も包含する。緯糸がセルロース繊維と合成繊維とからなる糸構成としては、一本交互使いが好ましいが、糸構成(繊度)によってはセルロース繊維対合成繊維の比率が3:1〜1:3の範囲でも良い。
The cellulose fibers used for the warp and weft of the fabric of the present invention include regenerated cellulose fibers such as cupra ammonium rayon and viscose rayon, saponified acetate fibers, purified cellulosic fibers represented by lyocell, and spinning of these short fibers. Yarn is included. In addition, natural fibers represented by cotton and hemp are also included. Regenerated cellulose long fibers are preferred. If necessary, it may be twisted or mixed and used. A single yarn fineness of 0.5 to 5.5 dtex, 20 to 100 filaments, and a total fineness of about 30 to 167 dtex are preferably used. In the case of spun yarn, yarns 20 to 80 can be used. In some cases, silk or wool having high hygroscopicity may be blended with cellulose fibers and used.
As synthetic fibers used for the wefts of the woven fabric of the present invention, polyester fibers such as polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polylactic acid fibers, nylon 6, polyamide fibers represented by nylon 66, polyacrylonitrile fibers, Examples thereof include acetate fibers, polyurethane-containing yarns, and fibers made of the aforementioned synthetic resin copolymer. The total fineness of these fibers is 33 to 167 dtex, preferably 33 to 110 dtex, and the single yarn fineness is 0.5 to 10 dtex, preferably 1 to 5 dtex. These fibers can be used in the form of a composite yarn such as false twisting, twisted yarn, mixed fiber, covering, or the like, if necessary. Of course, a side-by-side type conjugate yarn is also included. As the yarn configuration in which the wefts are composed of cellulose fibers and synthetic fibers, the alternate use is preferable, but the ratio of cellulose fibers to synthetic fibers may be in the range of 3: 1 to 1: 3 depending on the yarn configuration (fineness).

本発明の交織織物を製造するに当たっては、通常の製織条件(製織機、織密度など)で製織することができる。本発明に適用される織物組織としては、平組織、綾組織、朱子組織およびその変形組織が挙げられる。織密度に関しては、経糸密度90〜160本/吋、緯糸密度70〜120本/吋の範囲であり、使用する糸の素材、繊度に応じて適宜選定すればよい。織物の目付けは、特に制限はないが40〜120g/m2の範囲であれば特に問題はない。裏地として40〜90g/m2の範囲が特に好ましい。本発明の交織織物を製織する方法としては、普通織機、レピア織機、エアージェットルーム、ウオータージェットルーム、グリッパー織機、多相織機等が代表的に挙げられるが、単にこれらに限定さ
れるものではない。
本発明の織物は、製織された生機を常法の精錬、染色、仕上げ加工で処理することで得ることができる。例えば、精錬はオープンソーパー型連続精錬機、ソフサー精錬機、液流型染色機、浴中懸垂型連続精錬機などを用いて行うことができる。また、染色加工は、コールドパッドバッチ法、パッドスチーム法、パッドロール法、ジッガー法、液流染色法、ウインス法、ビーム法など織物構成に合わせて染料と共に適宜選択すればよい。
In producing the unwoven fabric of the present invention, it can be woven under normal weaving conditions (weaving machine, weaving density, etc.). Examples of the fabric structure applied to the present invention include a plain structure, a twill structure, a satin structure, and a deformed structure thereof. The weaving density is in the range of warp density of 90 to 160 yarns / 吋 and weft density of 70 to 120 yarns / 吋, and may be appropriately selected according to the material and fineness of the yarn used. Basis weight of the fabric, but are not there is no problem as long as the range of 40 to 120 g / m 2 particularly limited. A range of 40 to 90 g / m 2 is particularly preferred as the backing. Typical examples of the method for weaving the union woven fabric of the present invention include ordinary looms, rapier looms, air jet looms, water jet looms, gripper looms, and multiphase looms, but are not limited thereto. .
The woven fabric of the present invention can be obtained by treating a woven raw machine by conventional refining, dyeing and finishing. For example, the refining can be performed using an open soap type continuous refining machine, a softener refining machine, a liquid flow type dyeing machine, a suspended in-bath type continuous refining machine, or the like. In addition, the dyeing process may be appropriately selected together with the dye according to the fabric configuration such as a cold pad batch method, a pad steam method, a pad roll method, a jigger method, a liquid dyeing method, a wins method, and a beam method.

引き続く樹脂加工は、通常のセルロース系繊維の収縮や湿摩擦堅牢度を損ねない程度の加工を施せばよく、特に限定されない。本発明では樹脂加工時に前述したエポキシ変性シリコーンを所望の濃度で併用して調合し、通常の処方で仕上げればよい。樹脂加工剤以外に必要に応じて、帯電防止剤、撥水剤、柔軟剤、スリップ防止剤、吸汗剤、紫外線吸収剤、光触媒等を付与してもかまわない。また、織物表面の光沢、平滑性、風合い等を改善するために、カレンダー処理を施しても構わない。
本発明に使用できるエポキシ変性シリコーン以外の樹脂加工剤としては、グリオキザール系樹脂、エポキシ系樹脂、ウレタン系樹脂、エステル系樹脂、アクリル酸エステル系樹脂、ポリカルボン酸系樹脂が挙げられる。触媒は樹脂との組み合わせで適宜決めればよく、グリオキザール系樹脂用の触媒である酸性触媒や潜在酸性触媒を使用すればよい。例えば、酸性触媒としては、塩酸、硫酸などの無機酸、有機酸、乳酸、酒石酸、クエン酸、グリコール酸などのオキシ酸、アミン塩酸塩等が挙げられ、潜在酸性触媒としては、塩化アルミニウム、硝酸アルミニウム、硫酸アルニウム、塩化亜鉛、硝酸亜鉛、ホウフッ化亜鉛、塩化マグネシウム、ホウフッ化マグネシウムなどの無機金属塩等が挙げられる。
Subsequent resin processing is not particularly limited as long as it is performed so as not to impair the shrinkage and fastness to wet friction of normal cellulosic fibers. In the present invention, the above-described epoxy-modified silicone may be used in combination at a desired concentration at the time of resin processing, and finished with a normal formulation. In addition to the resin processing agent, an antistatic agent, a water repellent agent, a softening agent, an antislip agent, an antiperspirant, an ultraviolet absorber, a photocatalyst, or the like may be added as necessary. Moreover, in order to improve the gloss, smoothness, texture, etc. of the fabric surface, a calendar process may be applied.
Examples of the resin processing agent other than the epoxy-modified silicone that can be used in the present invention include glyoxal resins, epoxy resins, urethane resins, ester resins, acrylic ester resins, and polycarboxylic acid resins. The catalyst may be appropriately determined depending on the combination with the resin, and an acidic catalyst or a latent acidic catalyst that is a catalyst for a glyoxal resin may be used. Examples of acidic catalysts include inorganic acids such as hydrochloric acid and sulfuric acid, organic acids, lactic acid, tartaric acid, citric acid, glycolic acid and other oxyacids, amine hydrochlorides, etc., and latent acidic catalysts include aluminum chloride and nitric acid. Examples thereof include inorganic metal salts such as aluminum, aluminum sulfate, zinc chloride, zinc nitrate, zinc borofluoride, magnesium chloride, and magnesium borofluoride.

本発明の構成上の第二の特徴は、織物を構成するセルロース繊維の混率が72%以上のセルロース系交織織物において、そのW&W性が3.5級以上、吸湿性が7.5%以上、緯方向のストレッチ率が5%以上の条件を全て満たす点にある。
これらの条件をすべて充足することによって初めて家庭水洗いが可能で着用快適性に優れた織物となるが、本発明者らの知る限り、これらの構成要件のうち2つは満たすものは存在するが、これら全てを満たす織物は存在しない。
先ず、W&W性であるが、洗濯後の布帛を見てアイロン掛け等のケアをしなくてもそのまま着用可能と判断できるレベルが3.5級であり、3.5級以下ではアイロン掛けをしないと着用する気になれないレベルであると一般的には判断される。本発明では緯糸に合成繊維を少し挿入してセルロース繊維の柔かさ・変形のし易さを補強すると共に、エポキシ変性シリコーン付与に伴う滑性向上により洗濯時に受ける変形を緩和させることで3.5級以上のW&W性を発現せし得たものと推察する。緯糸に合成繊維を全く挿入しないでエポキシ変性シリコーンの処理を行った場合のW&W性は3.0級、同様に合成繊維を全く挿入しないでエポキシ変性シリコーンの処理を行わなかった場合のW&W性は2.25級、合成繊維を挿入してもエポキシ変性シリコーン処理を行わなかった場合のW&W性は3.2級であり、いずれも本発明の3.5級を充足させることはできないことを確認している。すなわち、本発明では前述した交織織物の糸構成とエポキシ変性シリコーンの処理が必須要件となっており、これらが後述する吸湿性の高さやストレッチ性の発現にも寄与している。
The second feature of the structure of the present invention is that the cellulose-based interwoven fabric having a mixing ratio of cellulose fibers constituting the woven fabric of 72% or more has a W & W property of 3.5 or higher, a hygroscopicity of 7.5% or higher, The stretch rate in the weft direction satisfies all the conditions of 5% or more.
Only by satisfying all these conditions, it becomes a woven fabric that can be washed with home water and has excellent wearing comfort, but as far as the inventors know, there are those that satisfy two of these constituent requirements, There is no fabric that meets all these requirements.
First, although it is W & W property, the level that can be judged as being wearable without taking care of ironing etc. by looking at the fabric after washing is grade 3.5, and ironing is not done below grade 3.5 It is generally judged that it is a level that is not worried about wearing. In the present invention, a little synthetic fiber is inserted into the weft to reinforce the softness / easiness of deformation of the cellulose fiber, and it also reduces the deformation caused by washing by improving the lubricity accompanying the addition of epoxy-modified silicone. It is presumed that the W & W property higher than the grade could be expressed. The W & W property when the epoxy-modified silicone treatment is performed without inserting any synthetic fiber into the weft is 3.0 grade. Similarly, the W & W property when the epoxy-modified silicone treatment is not performed without inserting any synthetic fiber is 2.25 grade, W & W property when epoxy-modified silicone treatment is not performed even if a synthetic fiber is inserted is 3.2 grade, and it is confirmed that neither can satisfy the 3.5 grade of the present invention. is doing. That is, in the present invention, the yarn configuration of the unwoven fabric and the treatment with the epoxy-modified silicone are essential requirements, which contribute to the expression of hygroscopicity and stretchability described later.

次に、セルロース繊維の特徴として吸湿性が挙げられる。ここで吸湿性とは、20℃で65%RHの環境下での公定水分率を意味する。この吸湿性はセルロース繊維にとって非常に大事で環境に応じて湿気を吸ったり吐いたりする特性(吸放湿性)に繋がり、ひいては着用快適性を高める武器となる。例えば、通常セルロース繊維は20℃で65%RHの雰囲気下では12%程度の気体の水分を取り込んでいるが、環境が90%RHのような多湿環境下に変化すると25%前後の気体の水分を取り込むことができる。従って、全く吸放湿性の無い合成繊維に較べて衣服内の環境、特に衣服内の湿度を下げることができるので着用感が快適となる。これらの特性を充分活かすには吸湿性としては7.5%以上が必要と考えられる。また、冬場のスカートの纏わり付きは静電気によって発現するが、ここでも吸湿性が重要な因子となる。低湿度環境下になるとセルロース繊維自体の吸湿性も低下するが、着用時の体から蒸散される気体の水分を取り込むことができるので織物の吸湿性としては7.5%以上あれば充分と考えられる。経験上、吸湿性が7.5%以下になると梅雨時や夏場の着用快適性が劣るばかりか制電性能も低下するので好ましくない。一方、吸湿性の上限はセルロース繊維100%の織物でも特殊な化学加工を施さない限り12%前後が最大であり、本発明の織物についても基本的には12%を上限と考えて差し支えない。但し、盛夏や梅雨用に限っては、吸湿性を高めるような化学加工を施しても何らかまわない。   Next, hygroscopicity is mentioned as a characteristic of cellulose fiber. Here, hygroscopicity means the official moisture content in an environment of 65% RH at 20 ° C. This hygroscopicity is very important for cellulose fibers and leads to the characteristic of absorbing and discharging moisture (absorbing and releasing properties) according to the environment. For example, normally, cellulose fibers take in about 12% gaseous moisture in an atmosphere of 65% RH at 20 ° C., but when the environment changes to a humid environment such as 90% RH, the moisture content of gas around 25%. Can be imported. Therefore, the environment in the clothes, particularly the humidity in the clothes, can be lowered compared to a synthetic fiber that does not absorb and release moisture at all. In order to fully utilize these characteristics, it is considered that 7.5% or more is necessary as the hygroscopicity. In addition, the skirts in winter are manifested by static electricity, but hygroscopicity is an important factor here. Although the hygroscopicity of the cellulose fiber itself decreases when it is in a low-humidity environment, 7.5% or more is sufficient for the hygroscopicity of the fabric because it can take in moisture from the gas evaporated from the body when worn. It is done. From experience, it is not preferable that the hygroscopicity is 7.5% or less because the wearing comfort in the rainy season or summer is inferior and the antistatic performance is also lowered. On the other hand, the upper limit of hygroscopicity is about 12% maximum even when a 100% cellulose fiber woven fabric is not subjected to special chemical processing, and the upper limit of the woven fabric of the present invention can be basically considered to be 12%. However, for midsummer and rainy seasons, chemical processing that increases hygroscopicity may be applied.

本発明の次の特徴は、緯方向のストレッチ率が5%以上である点が挙げられる。近年の一般的な衣料の表地のストレッチ率を調査すると8〜10%の範囲のものが多いことが判っている。これは人間の動作時の皮膚の伸びが結構大きく、ゆとりを考慮しても生地に8〜10%程度のストレッチ率がないと着用快適性を損ねる恐れがあるからと推察されている。これに対し裏地のストレチ率は半分程度で充分であることが経験的に判っている。この理由はキセや縫い目が表地のストレッチに対応し、かつ、表地の保型性にも関係しているものと思われる。ストレッチに関しては、表地の場合、スパン使いが故にこの程度ストレッチは可能であるが、フィラメント使いの場合は難しく、本発明者らの知る限り国際公開第99/31309号パンフレットの記述しか知らない。ただ、この特許文献でも家庭での水洗い洗濯対応に至る織物の糸使いやエポキシ変性シリコーンの使用を示唆するものはない。   The next feature of the present invention is that the stretch rate in the weft direction is 5% or more. A recent survey of stretch rates for general clothing outerwear has shown that many are in the range of 8-10%. It is presumed that this is because the stretch of the skin during human movement is quite large, and even if the allowance is taken into account, there is a risk that wearing comfort may be impaired if the fabric does not have a stretch rate of about 8 to 10%. On the other hand, it has been empirically found that the stretch ratio of the lining is about half. The reason for this seems to be that the knots and seams correspond to the stretch of the outer material and are related to the shape retention of the outer material. Regarding the stretch, in the case of the outer material, it is possible to stretch to this extent because of the use of the span, but in the case of using the filament, it is difficult, and as far as the present inventors know, only the description of WO 99/31309 is known. However, in this patent document, there is no suggestion of the use of textile yarn or the use of epoxy-modified silicone that can be used for washing and washing at home.

以下に、本発明を実施例などを用いて更に具体的に説明するが、本発明はこれら実施例などにより何ら限定されるものではない。尚本発明における、測定方法、評価方法等は下記の通りである。
(1)緯ストレッチ率の評価
カトーテック(株)製のKES−FB1を用いて、20cm×20cmの織物を引張り速度0.2mm/秒で緯方向に伸長し、500g/cmの応力下での伸びE(%)を次式により算出した。
E(%)=(ΔL/L)×100
ここでΔLは500g/cm荷重下で伸びた長さ(cm)、Lは織物の把持長で5cmである。
Hereinafter, the present invention will be described more specifically with reference to examples, but the present invention is not limited to these examples. In the present invention, measurement methods, evaluation methods, and the like are as follows.
(1) Evaluation of Weft Stretch Rate Using KES-FB1 manufactured by Kato Tech Co., Ltd., a 20 cm × 20 cm woven fabric was stretched in the weft direction at a pulling speed of 0.2 mm / sec, and under a stress of 500 g / cm. Elongation E (%) was calculated by the following formula.
E (%) = (ΔL / L) × 100
Here, ΔL is the length (cm) stretched under a load of 500 g / cm, and L is the grip length of the fabric, which is 5 cm.

(2)W&W性の評価
JIS−L−1096:A法で平干し後のシワの状態を官能評価した。3人の評価者がn=3のサンプルについて観察し、AATCC評価版をもとに1級から5級に格付け評価して平均値を出して級付けした。
(3)吸湿性の評価
JIS−L−1096に準拠して評価した。公定水分率で%表示している。
(4)寸法変化率
JIS−L−1096に準拠して評価した。マイナス表示は収縮を意味し、%表示している。
(5)縫目滑脱
JIS−L−1096に準拠して評価した(B法縫目ずれ)。単位はmm。
(2) Evaluation of W & W property JIS-L-1096: The wrinkle state after flat-drying was sensory-evaluated by A method. Three evaluators observed n = 3 samples, rated from 1st grade to 5th grade based on the AATCC evaluation version, and averaged and graded.
(3) Evaluation of hygroscopicity It evaluated based on JIS-L-1096. It is displayed in% with the official moisture content.
(4) Dimensional change rate It evaluated based on JIS-L-1096. Minus display means contraction and is displayed in%.
(5) Stitch slippage Evaluated according to JIS-L-1096 (B method stitch deviation). The unit is mm.

〔実施例1〕
経糸にキュプラアンモニウムレーヨンフィラメント56dtex/30fを用い、緯糸にキュプラアンモニウムレーヨン56dtex/45fとポリトリメチレンテレフタレート(以後「PTT」と呼称)56dtex/24f加工糸(Z加撚)逆追撚S900t/mした糸を用いて一本交互に緯打ちした。織り上がった生機の経糸密度は137本/吋、緯糸密度は96本/吋であった。この生機をオープンソーパータイプの精練機で精練した後、ハイジガー染色機でPTTを染色しシリンダー乾燥させた。しかる後、キュプラアンモニウムレーヨン側をパッドバッチ染色し、ソーピング乾燥させた。引き続く樹脂加工はノンホル型グリオキザール樹脂4重量%、その触媒1.5重量%、エポキシ変性シリコーンとしてDIC社製「DICシリコーンソフナー Y−8」を1重量%、柔軟剤1.5重量%、帯電防止剤0.5重量%、フィックス剤1.8重量%等を含む浴を用いて生地を浸
漬し、絞った後、テンターを用いて硬化させた。しかる後、水パッドし乾燥させ、最後にコールドペーパー処理を行い風合い調整を行った。
得られた織物の経糸密度は150本/吋、緯糸密度96本/吋であった。この織物のセルロース混率は80%、緯伸びは7%、摩擦帯電圧240V(公定水分率9.1%)、寸法変化率−0.1/−1.3、縫目滑脱1.4/1.5、且つ、W&W性も3.9級で着用快適性と家庭水洗い洗濯対応に優れていることが判った。
[Example 1]
Cupra ammonium rayon filament 56dtex / 30f was used for the warp, and cupra ammonium rayon 56dtex / 45f and polytrimethylene terephthalate (hereinafter referred to as "PTT") 56dtex / 24f processed yarn (Z twisted) reverse twisted S900t / m for the weft. Wefted one by one using yarn. The woven green machine had a warp density of 137 yarns / 吋 and a weft density of 96 yarns / 吋. After this raw machine was scoured with an open soaper type scourer, PTT was dyed with a Heiger dyeing machine and dried in a cylinder. Thereafter, the cupra ammonium rayon side was pad-batch dyed and soaped and dried. Subsequent resin processing is 4% by weight of non-hol type glyoxal resin, 1.5% by weight of its catalyst, 1% by weight of “DIC Silicone Softener Y-8” manufactured by DIC as an epoxy-modified silicone, 1.5% by weight of softening agent, antistatic The dough was dipped in a bath containing 0.5% by weight of the agent, 1.8% by weight of the fixing agent, squeezed, and then cured using a tenter. Thereafter, it was dried with a water pad, and finally, cold paper treatment was performed to adjust the texture.
The warp density of the obtained woven fabric was 150 yarns / 吋, and the weft density was 96 yarns / 吋. The woven fabric has a cellulose mixing ratio of 80%, a weft elongation of 7%, a frictional voltage of 240 V (official moisture content of 9.1%), a dimensional change rate of -0.1 / -1.3, and a stitch slippage of 1.4 / 1. .5, and the W & W property was also 3.9 grade, and it was found that it was excellent in wear comfort and compatibility with domestic washing and washing.

〔比較例1〕
実施例1の生機を用い、実施例1の精練・染色処方に準拠して染め上がり品を作成した。引き続く樹脂加工はエポキシ変性シリコーンを用いない以外は実施例1の処方に準拠して実施し、その後の工程は実施例1と同じ処理を行った。得られた織物の緯伸びは6.7%と本発明の特性を満たすが、W&W性が3.2級と家庭水洗い洗濯対応裏地としては不充分なレベルであった。また、寸法変化率は−0.2/−1.3、縫目滑脱は1.6/1.5、公定水分率は9.2%であった。
[Comparative Example 1]
Using the raw machine of Example 1, a dyed product was prepared in accordance with the scouring and dyeing prescription of Example 1. Subsequent resin processing was carried out according to the formulation of Example 1 except that no epoxy-modified silicone was used, and the subsequent steps were the same as in Example 1. The weft elongation of the obtained fabric was 6.7%, which satisfies the characteristics of the present invention, but the W & W property was 3.2, which was an insufficient level for a lining for washing with domestic water. Further, the dimensional change rate was -0.2 / -1.3, the stitch slippage was 1.6 / 1.5, and the official moisture content was 9.2%.

〔実施例2〕
経糸にキュプラアンモニウムレーヨンフィラメント56dtex/30fを用い、緯糸にキュプラアンモニウムレーヨン56dtex/45fとPTT/PTT2成分系コンジュゲート糸原糸40dtex/24fを用いて一本交互に緯打ちした。織り上がった生機の経糸密度は135本/吋、緯糸密度は105本/吋であった。この生機をオープンソーパータイプの精練機で精練した後、ハイジガー染色機でPTTを染色しシリンダー乾燥させた。しかる後、キュプラアンモニウムレーヨン側をパッドバッチ染色し、ソーピング乾燥させた。引き続く樹脂加工はノンホル型グリオキザール樹脂4重量%、その触媒1.5重量%、実施例1と同じエポキシ変性シリコーン1重量%、柔軟剤1.5重量%、帯電防止剤0.5重量%、フィックス剤1.8重量%等を含む浴を用いて生地を浸漬し、絞った後、テンターを用いて硬化させた。しかる後、水パッドし乾燥させ、最後にコールドペーパー処理を行い風合い調整を行った。
得られた織物の経糸密度は155本/吋、緯糸密度97本/吋であった。また、セルロース混率は85%、緯伸びは8.1%、摩擦帯電圧210V(公定水分率9.5%)、寸法変化率−0.5/−0.8、縫目滑脱1.6/0.7、且つ、W&W性も3.6級で着用快適性と家庭水洗い洗濯対応に優れていることが判った。
[Example 2]
Cupra ammonium rayon filament 56dtex / 30f was used for the warp, and cupra ammonium rayon 56dtex / 45f and PTT / PTT two-component conjugate yarn yarn 40dtex / 24f were used for the weft. The woven green machine had a warp density of 135 yarns / 吋 and a weft density of 105 yarns / 吋. After this raw machine was scoured with an open soaper type scourer, PTT was dyed with a Heiger dyeing machine and dried in a cylinder. Thereafter, the cupra ammonium rayon side was pad-batch dyed and soaped and dried. Subsequent resin processing was 4% by weight of non-hol type glyoxal resin, 1.5% by weight of the catalyst, 1% by weight of epoxy-modified silicone as in Example 1, 1.5% by weight of softening agent, 0.5% by weight of antistatic agent, fixed The dough was immersed in a bath containing 1.8% by weight of the agent, squeezed, and then cured using a tenter. Thereafter, it was dried with a water pad, and finally, cold paper treatment was performed to adjust the texture.
The warp density of the obtained woven fabric was 155 yarns / 吋, and the weft density was 97 yarns / 吋. In addition, the mixing ratio of cellulose is 85%, the weft elongation is 8.1%, the frictional voltage is 210V (official moisture content is 9.5%), the dimensional change is -0.5 / -0.8, and the slippage is 1.6 / It was 0.7 and the W & W property was 3.6 grade, and it was found that it was excellent in wearing comfort and washing and washing for home use.

〔実施例3〕
実施例2のPTT/PTT2成分系コンジュゲート糸原糸の替わりにPTT/PTT2成分系コンジュゲート糸加工糸56dtex/24fを用い、エポキシ変性シリコーンの濃度を0.5重量%に変更した以外は実施例2と同様の方法で裏地を作成した。生機の経糸密度は135本/吋、緯糸密度は97本/吋であった。得られた織物の経糸密度は165本/吋、緯糸密度100本/吋であった。また、セルロース混率は81%、緯伸びは16.2%、摩擦帯電圧200V(公定水分率9.2%)、寸法変化率−0.4/−1.0、縫目滑脱1.3/0.7、且つ、W&W性も3.8級で着用快適性と家庭水洗い洗濯対応に優れていることが判った。
Example 3
Example except that PTT / PTT two-component conjugate yarn processed yarn 56 dtex / 24f was used in place of the PTT / PTT two-component conjugate yarn base yarn of Example 2 and the concentration of the epoxy-modified silicone was changed to 0.5% by weight. A lining was prepared in the same manner as in 2. The raw machine had a warp density of 135 yarns / 吋 and a weft density of 97 yarns / 吋. The warp density of the obtained woven fabric was 165 yarns / 吋, and the weft density was 100 yarns / 吋. In addition, the cellulose mixing ratio is 81%, the weft elongation is 16.2%, the frictional voltage is 200V (official moisture content is 9.2%), the dimensional change is -0.4 / -1.0, and the stitch slippage is 1.3 /. It was found to be 0.7 and the W & W property was 3.8 grade, and it was found to be excellent in wearing comfort and washing with home washing.

〔実施例4〕
実施例2のPTT/PTT2成分系コンジュゲート糸原糸の替わりにW型断面形状のポリエチレンテレフタレート56dtex/30fを用いた以外は実施例2と同様の方法で裏地を作成した。生機の経糸密度は135本/吋、緯糸密度は96本/吋であった。得られた織物の経糸密度は149本/吋、緯糸密度100本/吋であった。また、セルロース混率は80%、緯伸びは6.4%、摩擦帯電圧205V(公定水分率9.1%)、寸法変化率―0.3/−0.5、縫目滑脱1.0/1.4、且つ、W&W性も3.6級で着用快適性と家庭水洗い洗濯対応に優れていることが判った。
Example 4
A lining was prepared in the same manner as in Example 2 except that polyethylene terephthalate 56 dtex / 30f having a W-shaped cross-section was used instead of the PTT / PTT two-component conjugate yarn yarn of Example 2. The raw machine had a warp density of 135 / 吋 and a weft density of 96 / 吋. The warp density of the obtained woven fabric was 149 yarns / 吋, and the weft density was 100 yarns / 吋. Cellulose mixing ratio is 80%, weft elongation is 6.4%, friction band voltage is 205V (official moisture content is 9.1%), dimensional change rate is -0.3 / -0.5, stitch slippage is 1.0 / It was found that it was 1.4 and the W & W property was 3.6 grade, and it was excellent in wearing comfort and washing with home washing.

〔実施例5〕
実施例2のPTT/PTT2成分系コンジュゲート糸原糸の替わりに丸断面形状のポリエチレンテレフタレート加工糸56dtex/30fを用いた以外は実施例2と同様の方法で裏地を作成した。生機の経糸密度は135本/吋、緯糸密度は97本/吋であった。
得られた織物の経糸密度は152本/吋、緯糸密度100本/吋であった。また、セルロース混率は80%、緯伸びは5.9%、摩擦帯電圧260V(公定水分率9.1%)、寸法変化率―0.1/−0.8、縫目滑脱1.6/1.1、且つ、W&W性も3.6級で着用快適性と家庭水洗い洗濯対応に優れていることが判った。
Example 5
A lining was prepared in the same manner as in Example 2 except that 56 dtex / 30f of a polyethylene terephthalate-processed yarn having a round cross-section was used instead of the PTT / PTT two-component conjugate yarn base yarn of Example 2. The raw machine had a warp density of 135 yarns / 吋 and a weft density of 97 yarns / 吋.
The warp density of the obtained woven fabric was 152 yarns / 吋 and the weft density was 100 yarns / 吋. Cellulose mixing ratio is 80%, weft elongation is 5.9%, frictional voltage is 260V (official moisture content is 9.1%), dimensional change is -0.1 / -0.8, seam slipping is 1.6 / 1.1 and the W & W property was 3.6 grade, and it was found that it was excellent in wearing comfort and washing with home washing.

本発明のセルロース系交織織物は、適度なストレッチ性を有するので着用時の運動追従性が高く、滑脱等の耐久性にも優れる。また、セルロース混率が高い織物である為、吸湿性や制電性能にも優れる。更にはW&W性に優れており、家庭で充分水洗い洗濯が可能なイージーケア性を有する交織織物を提供することができる。特に裏地に好適である。   Since the cellulosic union woven fabric of the present invention has an appropriate stretch property, it has a high movement follow-up property when worn and is excellent in durability such as slipping. Moreover, since it is a woven fabric with a high cellulose mixing ratio, it has excellent hygroscopicity and antistatic performance. Furthermore, it is excellent in W & W property, and can provide the unwoven fabric which has the easy care property which can be washed in water sufficiently at home. It is particularly suitable for lining.

Claims (6)

経糸がセルロース繊維、緯糸がセルロース繊維と合成繊維から構成される交織織物において、該交織織物が樹脂加工時にエポキシ変性シリコーンで処理されてなる織物であって、かつ、下記(1)〜(3)の特性を満たすことを特徴とするセルロース系交織織物。
(1)W&W性が3.5級以上
(2)緯方向のストレッチ率が5%以上
(3)吸湿性が7.5%以上
In the union woven fabric in which the warp is composed of cellulose fibers and the weft is composed of cellulose fibers and synthetic fibers, the unwoven fabric is a woven fabric obtained by treatment with epoxy-modified silicone during resin processing, and the following (1) to (3) Cellulosic union woven fabric characterized by satisfying the above characteristics.
(1) W & W property is 3.5 or higher (2) Stretch rate in the weft direction is 5% or higher (3) Hygroscopicity is 7.5% or higher
前記セルロース繊維が再生セルロース繊維であることを特徴とする請求項1記載のセルロース系交織織物。   The cellulosic interwoven fabric according to claim 1, wherein the cellulose fiber is a regenerated cellulose fiber. 前記合成繊維がポリエステル系繊維であることを特徴とする請求項1または2記載のセルロース系交織織物。   The cellulosic interwoven fabric according to claim 1 or 2, wherein the synthetic fiber is a polyester fiber. ポリエステル系繊維がポリトリメチレンテレフタレートの加工糸であることを特徴とする請求項3記載のセルロース系交織織物。   The cellulosic interwoven fabric according to claim 3, wherein the polyester fiber is a processed yarn of polytrimethylene terephthalate. セルロース繊維の混率が70%以上であることを特徴とする請求項1〜4のいずれかに記載のセルロース系交織織物。   The cellulosic interwoven fabric according to any one of claims 1 to 4, wherein a mixing ratio of the cellulose fibers is 70% or more. 請求項1〜5のいずれかに記載のセルロース系交織織物からなることを特徴とするセルロース系交織裏地。   A cellulosic union lining comprising the cellulosic union woven fabric according to any one of claims 1 to 5.
JP2004370706A 2004-12-22 2004-12-22 Cellulosic interwoven fabric Expired - Fee Related JP4518936B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2004370706A JP4518936B2 (en) 2004-12-22 2004-12-22 Cellulosic interwoven fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2004370706A JP4518936B2 (en) 2004-12-22 2004-12-22 Cellulosic interwoven fabric

Publications (2)

Publication Number Publication Date
JP2006176916A true JP2006176916A (en) 2006-07-06
JP4518936B2 JP4518936B2 (en) 2010-08-04

Family

ID=36731273

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004370706A Expired - Fee Related JP4518936B2 (en) 2004-12-22 2004-12-22 Cellulosic interwoven fabric

Country Status (1)

Country Link
JP (1) JP4518936B2 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103396654A (en) * 2013-08-19 2013-11-20 南京林业大学 Cellulose nano-fibril/epoxy resin composite film preparation method
CN107299442A (en) * 2017-05-31 2017-10-27 魏桥纺织股份有限公司 The preparation method of weaving man's spun articles
EP3467163A1 (en) * 2017-10-06 2019-04-10 Lenzing Aktiengesellschaft Lyocell filament lining fabric
JP2019189996A (en) * 2019-08-09 2019-10-31 日清紡テキスタイル株式会社 Textile product
US10876197B2 (en) 2011-05-20 2020-12-29 University Of Central Florida Research Foundation, Inc. Surface modified materials for tailoring responses to electromagnetic fields
CN115341387A (en) * 2021-11-11 2022-11-15 创姿服饰(上海)有限公司 Comfortable wear-resistant fabric and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08311777A (en) * 1995-05-12 1996-11-26 Asahi Chem Ind Co Ltd Shrink-proof processing for cellulose fiber-containing cloth
WO1999031309A1 (en) * 1997-12-17 1999-06-24 Asahi Kasei Kogyo Kabushiki Kaisha Lining cloth and method for producing the same
JP2001064844A (en) * 1999-08-25 2001-03-13 Asahi Chem Ind Co Ltd Woven fabric
JP2003313748A (en) * 2002-04-19 2003-11-06 Asahi Kasei Corp Woven fabric

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08311777A (en) * 1995-05-12 1996-11-26 Asahi Chem Ind Co Ltd Shrink-proof processing for cellulose fiber-containing cloth
WO1999031309A1 (en) * 1997-12-17 1999-06-24 Asahi Kasei Kogyo Kabushiki Kaisha Lining cloth and method for producing the same
JP2001064844A (en) * 1999-08-25 2001-03-13 Asahi Chem Ind Co Ltd Woven fabric
JP2003313748A (en) * 2002-04-19 2003-11-06 Asahi Kasei Corp Woven fabric

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10876197B2 (en) 2011-05-20 2020-12-29 University Of Central Florida Research Foundation, Inc. Surface modified materials for tailoring responses to electromagnetic fields
CN103396654A (en) * 2013-08-19 2013-11-20 南京林业大学 Cellulose nano-fibril/epoxy resin composite film preparation method
CN107299442B (en) * 2017-05-31 2019-12-06 魏桥纺织股份有限公司 Method for manufacturing one-step woven and formed home textile product
CN107299442A (en) * 2017-05-31 2017-10-27 魏桥纺织股份有限公司 The preparation method of weaving man's spun articles
CN111148865A (en) * 2017-10-06 2020-05-12 连津格股份公司 Lyocell filament lined fabric
WO2019068468A1 (en) * 2017-10-06 2019-04-11 Lenzing Aktiengesellschaft Lyocell filament lining fabric
AU2018344310B2 (en) * 2017-10-06 2020-12-17 Lenzing Aktiengesellschaft Lyocell filament lining fabric
EP3467163A1 (en) * 2017-10-06 2019-04-10 Lenzing Aktiengesellschaft Lyocell filament lining fabric
RU2746092C1 (en) * 2017-10-06 2021-04-06 Ленцинг Актиенгеселльшафт Lyocell fiber lining
TWI767063B (en) * 2017-10-06 2022-06-11 奧地利商藍晶股份公司 Lyocell filament lining fabric
US11686016B2 (en) 2017-10-06 2023-06-27 Lenzing Aktiengesellschaft Lyocell filament lining fabric
JP2019189996A (en) * 2019-08-09 2019-10-31 日清紡テキスタイル株式会社 Textile product
CN115341387A (en) * 2021-11-11 2022-11-15 创姿服饰(上海)有限公司 Comfortable wear-resistant fabric and preparation method thereof

Also Published As

Publication number Publication date
JP4518936B2 (en) 2010-08-04

Similar Documents

Publication Publication Date Title
TWI523981B (en) Polyester fiber and its manufacturing method and fabric and fiber product and polyester molded article
JP3902007B2 (en) Weft knitted fabric
KR100386006B1 (en) Lining cloth and method for producing the same
MXPA02007495A (en) Woven stretch fabric.
JP2013147762A (en) Woven fabric product
JP4819123B2 (en) Weft stretch lining and its manufacturing method
KR20030020943A (en) Stretchable high-density woven fabric
JP2015108204A (en) Woven fabric made of composite spun yarn
JP2006214056A (en) Woven fabric
RU2747298C1 (en) Clothing made of silk-like fabric containing or consisting of lyocell fibers
JP4518936B2 (en) Cellulosic interwoven fabric
JP2005105420A (en) Sportswear
JP2007270358A (en) Thick woven fabric and denim product excellent in wearing comfortability
JP5600270B2 (en) Cellulosic fabric with excellent washing durability
JP7264996B2 (en) textiles and clothing
JP2541661B2 (en) Adhesive interlining
JP2003119638A (en) Doubly covered elastic yarn and method for producing the same
JP5290840B2 (en) Stretch short fiber fabric and women&#39;s pants
CN211518759U (en) Meshbelt that shrinkage is low
JP7283959B2 (en) textiles and clothing
JP2005105455A (en) Woven fabric
JP7315306B2 (en) clothing
JP2006161204A (en) Polyester woven fabric
JP2004183193A (en) Woven fabric
JP5036649B2 (en) Interlining fabric and method for producing the same

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20071101

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20100217

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20100223

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20100422

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20100518

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20100518

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130528

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Ref document number: 4518936

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130528

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140528

Year of fee payment: 4

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313111

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

LAPS Cancellation because of no payment of annual fees