JP2018176444A - Method of molding fiber-reinforced thermoplastic resin molded article - Google Patents

Method of molding fiber-reinforced thermoplastic resin molded article Download PDF

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JP2018176444A
JP2018176444A JP2017074578A JP2017074578A JP2018176444A JP 2018176444 A JP2018176444 A JP 2018176444A JP 2017074578 A JP2017074578 A JP 2017074578A JP 2017074578 A JP2017074578 A JP 2017074578A JP 2018176444 A JP2018176444 A JP 2018176444A
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thermoplastic resin
reinforced thermoplastic
fiber
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plan
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JP6753351B2 (en
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吉宏 岩野
Yoshihiro Iwano
吉宏 岩野
康介 櫻井
Kosuke Sakurai
康介 櫻井
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Toyota Motor Corp
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Abstract

PROBLEM TO BE SOLVED: To obtain a method of molding a fiber-reinforced thermoplastic resin molded article for precisely molding into a rectangular shape in plan view.SOLUTION: A method for forming a fiber-reinforced thermoplastic resin molded article 10 comprises a projecting portion forming step of forming a projecting portion 18 projecting outwardly at each corner portion 16 of the fiber reinforced thermoplastic resin material 14 formed in a rectangular shape in plan view, while maintaining a temperature higher than a melting point of the fiber-reinforced thermoplastic resin material 14, and a molding step of placing the fiber reinforced thermoplastic resin material 14 on which the projecting portion 18 is formed, on a molding mold 20 having a rectangular cavity 24 in a plan view to press mold it, and forming each corner portion 12 of the fiber-reinforced thermoplastic resin molded body 10 having a rectangular shape in plan view with the projecting portion 18.SELECTED DRAWING: Figure 1

Description

本発明は、繊維強化熱可塑性樹脂成形体の成形方法に関する。   The present invention relates to a method of molding a fiber-reinforced thermoplastic resin molded article.

成形体のベース部分を構成するための第1の材料と3次元形状部分を構成するための第2の材料とを加熱し、プレス成形時において、第1の材料と第2の材料とを成形型のキャビティ内で一体成形することにより、ベース部分上に3次元形状部分を有する繊維強化熱可塑性樹脂成形体を製造する方法は、従来から知られている(例えば、特許文献1参照)。   The first material for forming the base portion of the formed body and the second material for forming the three-dimensional shape portion are heated, and the first material and the second material are formed at the time of press forming. A method for producing a fiber-reinforced thermoplastic resin molded product having a three-dimensional shaped portion on a base portion by integral molding in a mold cavity is conventionally known (see, for example, Patent Document 1).

特開2014−188831号公報JP, 2014-188831, A

しかしながら、繊維強化熱可塑性樹脂材料を平面視で矩形状にプレス成形する場合、その繊維強化熱可塑性樹脂材料の流動性を考慮すると、所望とする矩形状に精度良く成形することは難しい。すなわち、平面視で矩形状となる繊維強化熱可塑性樹脂成形体の各角部までを精度良く成形することは難しく、各角部までを精度良く成形できる成形方法の確立が望まれている。   However, when the fiber-reinforced thermoplastic resin material is press-formed into a rectangular shape in plan view, it is difficult to accurately form the desired rectangular shape in consideration of the flowability of the fiber-reinforced thermoplastic resin material. That is, it is difficult to precisely form up to each corner of the fiber-reinforced thermoplastic resin molded product which is rectangular in plan view, and establishment of a molding method capable of forming up to each corner precisely is desired.

そこで、本発明は、平面視で矩形状に精度良く成形できる繊維強化熱可塑性樹脂成形体の成形方法を得ることを目的とする。   Then, an object of this invention is to obtain the formation method of the fiber reinforced thermoplastic resin molded object which can be shape | molded precisely in rectangular shape by planar view.

上記の目的を達成するために、本発明に係る請求項1に記載の繊維強化熱可塑性樹脂成形体の成形方法は、繊維強化熱可塑性樹脂材料の融点よりも高い温度を保ちつつ、平面視で矩形状に形成された前記繊維強化熱可塑性樹脂材料の各角部に外方へ向けて突出する突出部を形成する突出部形成工程と、前記突出部が形成された前記繊維強化熱可塑性樹脂材料を平面視で矩形状のキャビティを有する成形型に配置してプレス成形し、平面視で矩形状とされる繊維強化熱可塑性樹脂成形体の各角部を前記突出部で形成する成形工程と、を含む。   In order to achieve the above object, the molding method of a fiber-reinforced thermoplastic resin molded article according to claim 1 of the present invention maintains a temperature higher than the melting point of the fiber-reinforced thermoplastic resin material, in plan view A protrusion forming step of forming a protrusion projecting outward on each corner of the rectangular fiber-reinforced thermoplastic resin material, and the fiber-reinforced thermoplastic resin material having the protrusion formed thereon Forming the respective corners of the fiber-reinforced thermoplastic resin molded product which is disposed in a mold having a rectangular cavity in a plan view and is press-formed, and forming the corners of the fiber-reinforced thermoplastic resin molded body having a rectangular shape in a plan view including.

請求項1に記載の発明によれば、平面視で、繊維強化熱可塑性樹脂材料の各角部に、外方へ向けて突出する突出部が形成され、プレス成形時に、その突出部で繊維強化熱可塑性樹脂成形体の各角部が形成される。したがって、繊維強化熱可塑性樹脂成形体が、平面視で矩形状に精度良く成形される。   According to the invention as set forth in claim 1, in a plan view, projecting portions which project outward are formed at respective corner portions of the fiber reinforced thermoplastic resin material, and at the time of press molding, the fiber reinforcing is carried out by the projecting portions. Each corner of the thermoplastic resin molding is formed. Therefore, the fiber-reinforced thermoplastic resin molded article is accurately formed into a rectangular shape in plan view.

以上のように、本発明によれば、繊維強化熱可塑性樹脂成形体を平面視で矩形状に精度良く成形することができる。   As described above, according to the present invention, a fiber-reinforced thermoplastic resin molded article can be accurately formed into a rectangular shape in plan view.

(A)プレス成形する前の本実施形態に係る繊維強化熱可塑性樹脂材料を示す平面図である。(B)プレス成形した後の本実施形態に係る繊維強化熱可塑性樹脂成形体を示す平面図である。(A) It is a top view which shows the fiber reinforced thermoplastic resin material which concerns on this embodiment before press-molding. (B) It is a top view which shows the fiber reinforced thermoplastic resin molded object which concerns on this embodiment after press-molding. (A)〜(C)本実施形態に係る繊維強化熱可塑性樹脂材料を成形型でプレス成形して本実施形態に係る繊維強化熱可塑性樹脂成形体を成形する工程を示す説明図である。(A)-(C) It is explanatory drawing which shows the process of press-molding the fiber reinforced thermoplastic resin material which concerns on this embodiment with a shaping | molding die, and shape | molding the fiber reinforced thermoplastic resin molded object which concerns on this embodiment. (A)プレス成形する前の比較例に係る繊維強化熱可塑性樹脂材料を示す平面図である。(B)プレス成形した後の比較例に係る繊維強化熱可塑性樹脂成形体を示す平面図である。(A) It is a top view which shows the fiber reinforced thermoplastic resin material which concerns on the comparative example before pressing. (B) It is a top view which shows the fiber reinforced thermoplastic resin molded object which concerns on the comparative example after press-molding.

以下、本発明に係る実施の形態について、図面を基に詳細に説明する。なお、説明の便宜上、各図において適宜示す矢印UPを成形型20の上方向、矢印FRを成形型20の前方向、矢印LEを成形型20の左方向とするが、これらの各方向に特に限定されるものではない。   Hereinafter, embodiments according to the present invention will be described in detail based on the drawings. For convenience of explanation, the arrow UP shown in each drawing as appropriate in the drawings is the upward direction of the mold 20, the arrow FR is the forward direction of the mold 20, and the arrow LE is the left direction of the mold 20. It is not limited.

また、本実施形態における成形方法は、平面視で矩形状となる繊維強化熱可塑性樹脂成形体(以下、単に「成形体」という)10を成形する方法である。したがって、以下においては、矩形状の一例として、長方形状となる成形体10について説明するが、成形体10は、例えば正方形状であっても同様である。   In addition, the molding method in the present embodiment is a method of molding a fiber-reinforced thermoplastic resin molded body (hereinafter, simply referred to as a “molded body”) 10 which is rectangular in plan view. Therefore, although the molded object 10 which becomes rectangular shape is demonstrated as an example of rectangular shape below, the same may be said even if the molded object 10 is square shape, for example.

更に、混練機(図示省略)により、熱可塑性樹脂と強化繊維とを混ぜ合わせて、熱可塑性樹脂中に強化繊維がランダムに配向された繊維強化熱可塑性樹脂材料(以下、単に「樹脂材料」という)14を生成するが、本実施形態において、樹脂材料14に含まれる強化繊維の含有率は、5質量%〜50質量%が好ましく、10質量%〜50質量%がより好ましい。   Furthermore, a fiber reinforced thermoplastic resin material (hereinafter simply referred to as "resin material") in which a thermoplastic resin and reinforcing fibers are mixed together by a kneader (not shown), and reinforcing fibers are randomly oriented in the thermoplastic resin. Although 14 is produced, in this embodiment, 5 mass%-50 mass% are preferable, and, as for the content rate of the reinforcing fiber contained in the resin material 14, 10 mass%-50 mass% are more preferable.

熱可塑性樹脂としては、例えばポリカーボネート(PC)樹脂、ポリアミド(PA)樹脂、ポリウレタン(PU)樹脂、ポリ塩化ビニル樹脂、アクリロニトリル−ブタジエン−スチレン共重合体(ABS)樹脂及びポリプロピレン(PP)樹脂などが挙げられ、特にPA樹脂及びPP樹脂が好適であるが、これらのものに限定されるものではない。   As a thermoplastic resin, for example, polycarbonate (PC) resin, polyamide (PA) resin, polyurethane (PU) resin, polyvinyl chloride resin, acrylonitrile-butadiene-styrene copolymer (ABS) resin, polypropylene (PP) resin, etc. Particularly preferred are PA resin and PP resin, but not limited thereto.

強化繊維としては、例えばアラミド繊維、セルロース繊維、ナイロン繊維、ビニロン繊維、ポリエステル繊維、ポリオレフィン繊維、レーヨン繊維等の樹脂繊維、炭素繊維(CF)、ガラス繊維(GF)及び金属繊維などが挙げられ、特に高い機械的強度を実現可能な炭素繊維が好適であるが、これらのものに限定されるものではない。強化繊維は、目的に応じて公知の各種繊維が使用されればよい。   Examples of reinforcing fibers include aramid fibers, cellulose fibers, nylon fibers, vinylon fibers, polyester fibers, polyolefin fibers, resin fibers such as rayon fibers, carbon fibers (CF), glass fibers (GF), metal fibers, etc. In particular, carbon fibers capable of achieving high mechanical strength are suitable, but not limited thereto. As the reinforcing fibers, various known fibers may be used depending on the purpose.

まず、本実施形態におけるプレス機の成形型20について説明する。図2に示されるように、成形型20は、固定側である下型22と、下型22に対して昇降移動する可動側である上型26と、を有している。下型22には、成形体10を成形するための平面視長方形状(矩形状)の凹部であるキャビティ24が形成されており、上型26には、キャビティ24に嵌合する底面視長方形状(矩形状)の凸部であるコア28が形成されている。   First, the molding die 20 of the press in the present embodiment will be described. As shown in FIG. 2, the molding die 20 has a lower die 22 which is a fixed side, and an upper die 26 which is a movable side which moves up and down with respect to the lower die 22. The lower mold 22 is formed with a cavity 24 which is a concave portion in a rectangular shape (rectangular shape) in plan view for molding the molded body 10, and the upper mold 26 is a rectangular shape in a bottom view fitted with the cavity 24. A core 28 which is a (rectangular) convex portion is formed.

したがって、図2(A)に示されるように、下型22のキャビティ24内における底面24Bの中央部上に、後述する樹脂材料14を配置し、図2(B)、図2(C)に示されるように、上型26を下降させつつ、そのコア28の下面28Aで樹脂材料14をプレス成形する(キャビティ24の底面24Bとコア28の下面28Aとで挟持押圧する)ことにより、成形体10が成形(製造)されるようになっている。   Therefore, as shown in FIG. 2A, the resin material 14 described later is disposed on the central portion of the bottom surface 24B in the cavity 24 of the lower mold 22, as shown in FIGS. 2B and 2C. As shown, while the upper die 26 is lowered, the resin material 14 is press-formed on the lower surface 28A of the core 28 (sandwich is pressed between the bottom surface 24B of the cavity 24 and the lower surface 28A of the core 28). 10 is to be molded (manufactured).

次に、以上のような成形型20を用いて成形体10を成形(製造)する成形方法について説明する。   Next, a molding method for molding (manufacturing) the molded body 10 using the molding die 20 as described above will be described.

まず、図3に示される比較例に係る繊維強化熱可塑性樹脂成形体(以下、単に「成形体」という)30について説明する。図3(A)に示されるように、この比較例に係る成形体30を成形(製造)するための繊維強化熱可塑性樹脂材料(以下、単に「樹脂材料」という)34は、平面視で略長方形状に形成されている。   First, a fiber-reinforced thermoplastic resin molded body (hereinafter, simply referred to as a “molded body”) 30 according to a comparative example shown in FIG. 3 will be described. As shown in FIG. 3 (A), a fiber-reinforced thermoplastic resin material (hereinafter simply referred to as “resin material”) 34 for molding (manufacturing) the molded body 30 according to this comparative example is substantially in plan view. It is formed in a rectangular shape.

この樹脂材料34を、成形型20の下型22のキャビティ24内における底面24Bの中央部上にロボットアーム等の供給手段(図示省略)により配置し、図2で示した上型26を下降させて、そのコア28の下面28Aでプレス成形する。すると、図3(B)に示されるように、樹脂材料34は、平面視で外方(上下方向と直交する方向であり、矢印で示す前後方向や左右方向など)に向かって流動する。   The resin material 34 is disposed on the central portion of the bottom surface 24B in the cavity 24 of the lower mold 22 of the mold 20 by a supply means (not shown) such as a robot arm, and the upper mold 26 shown in FIG. The lower surface 28A of the core 28 is pressed. Then, as shown in FIG. 3B, the resin material 34 flows outward (in a direction perpendicular to the vertical direction, such as a front-rear direction or a horizontal direction indicated by an arrow) in a plan view.

ここで、この樹脂材料34は、各コーナー部36において、その流動速度が他の部位よりも遅い(圧力分布が相対的に低い)。したがって、図示のように、プレス成形されつつ、融点を下回るまで成形型20で冷却された(固化された)成形体30の各コーナー部32は、その流動長が短いことから、平面視で外方側へ凸となる円弧状に(角が欠損した形状に)形成され、全体として成形体30が所望とする長方形状に形成されない(全体として成形体30が略楕円形状に形成されてしまう)。   Here, in each corner portion 36, the resin material 34 has a flow velocity slower than that of other portions (the pressure distribution is relatively low). Therefore, as shown in the drawing, each corner portion 32 of the compact 30 cooled (solidified) by the mold 20 while being press-formed and having a temperature lower than the melting point is short in flow length, It is formed in the shape of a circular arc that is convex toward the side (in the shape with missing corners), and the formed body 30 is not formed in the desired rectangular shape as a whole (the formed body 30 is formed in a substantially elliptical shape as a whole) .

換言すれば、樹脂材料34の各コーナー部36は、キャビティ24内における平面視直角形状の各角部24Aまで到達せず(行き渡らず)、成形体30の各コーナー部32における平面視円弧状の外縁部32Aとキャビティ24内における各角部24Aとの間で、平面視略直角三角形状となる空間部Sが形成されてしまい、成形体30の各コーナー部32が平面視で略直角形状にならない(角部にならない)。   In other words, each corner portion 36 of the resin material 34 does not reach (does not reach) each corner portion 24A of the rectangular shape in plan view in the cavity 24, and is arc-shaped in plan view in each corner portion 32 of the molded body 30. Between the outer edge 32A and each corner 24A in the cavity 24, a space S having a substantially right-angled triangular shape in plan view is formed, and each corner 32 of the molded body 30 has a substantially right-angled shape in plan view. It does not (it does not become a corner).

これに対し、本実施形態に係る成形体10は、次のようにして成形(製造)される。まず、図1(A)に示されるように、成形型20とは別のプリフォーム用のプレス機の成形型(図示省略)により、樹脂材料14の融点よりも高い温度を保ちつつ、平面視で略長方形状に形成された樹脂材料14の各角部16(仮想線にて示す)に、外方へ向けて突出(延長)する突出部18を一体に形成する(突出部形成工程)。   On the other hand, the molded object 10 which concerns on this embodiment is shape | molded (manufactured) as follows. First, as shown in FIG. 1 (A), a temperature higher than the melting point of the resin material 14 is maintained by a forming die (not shown) of a press for preform different from the forming die 20, and a plan view is obtained. In the respective rectangular portions 16 (shown by imaginary lines) of the resin material 14 formed into a substantially rectangular shape, projecting portions 18 projecting (extending) outward are integrally formed (protrusion portion forming step).

突出部18は、平面視で略楕円形状に突出されており、長径を対称の軸として略線対称形状に形成されている。なお、突出部18の形状は、図示の平面視略楕円形状に限定されるものではなく、各角部16の流動長の短さを補える形状であれば、例えば平面視略菱形形状等に形成されていてもよいし、略線対称形状に形成されていなくてもよい。また、この樹脂材料14の体積は、突出部18を形成しても、比較例に係る樹脂材料34の体積と同等になっており、図2(A)に示されるように、この樹脂材料14は、突出部18まで同じ高さに形成されている。   The protrusion 18 protrudes in a substantially elliptical shape in a plan view, and is formed in a substantially line symmetrical shape with the major axis as the axis of symmetry. The shape of the projecting portion 18 is not limited to the substantially elliptical shape in plan view in the drawing, and it may be formed in, for example, a substantially rhombus shape in plan view as long as it can compensate for the short flow length of each corner portion 16. It may or may not be formed in a substantially line symmetrical shape. Further, the volume of the resin material 14 is equivalent to the volume of the resin material 34 according to the comparative example, even if the protrusion 18 is formed, and as shown in FIG. Are formed at the same height up to the projection 18.

樹脂材料14の各角部16に突出部18を一体に形成したら(樹脂材料14を平面視略「X」字状に形成したら)、図2(A)、図1(B)に示されるように、その樹脂材料14を、成形型20の下型22のキャビティ24内における底面24Bの中央部上にロボットアーム等の供給手段により配置する。そして、図2(B)に示されるように、成形型20の上型26のコア28を、下型22のキャビティ24内に向けて下降させ、そのコア28の下面28Aで樹脂材料14をプレス成形する(成形工程)。   As shown in FIG. 2A and FIG. 1B, when the protrusion 18 is integrally formed on each corner 16 of the resin material 14 (when the resin material 14 is formed in a substantially “X” shape in plan view), The resin material 14 is placed on the central portion of the bottom surface 24B in the cavity 24 of the lower mold 22 of the mold 20 by a supply means such as a robot arm. Then, as shown in FIG. 2B, the core 28 of the upper mold 26 of the mold 20 is lowered into the cavity 24 of the lower mold 22, and the resin material 14 is pressed by the lower surface 28A of the core 28. Molding (molding process).

すると、その成形工程により、図2(C)、図1(B)に示されるように、樹脂材料14(突出部18を含む)が、平面視で外方(上下方向と直交する方向であり、矢印で示す前後方向や左右方向など)に向かって流動しつつ、融点を下回るまで成形型20で冷却され(固化され)、平面視で所望の略長方形状となる成形体10が精度良く成形(製造)される(上記の欠損が低減された形状に形成される)。   Then, as shown in FIG. 2 (C) and FIG. 1 (B), the resin material 14 (including the projecting portion 18) is outward (in a direction perpendicular to the vertical direction) in plan view by the molding process. The molded body 10 is cooled (solidified) by the mold 20 until it falls below the melting point while flowing in the front-rear direction, the left-right direction, etc. (Manufacturing) (The above-mentioned defects are formed in a reduced shape).

つまり、樹脂材料14の各角部16に突出部18を形成することにより、流動速度が他の部位よりも遅い(圧力分布が相対的に低い)角部16であっても、その流動長の短さを補うことができ、上記した空間部Sを埋めるように(キャビティ24内の各角部24Aに到達するまで)樹脂材料14(突出部18を含む)を効率よく流動させる(行き渡らせる)ことができる。よって、成形体10の各角部12を平面視で略直角形状に精度良く成形することができる。   That is, by forming the projecting portion 18 at each corner portion 16 of the resin material 14, even if the corner portion 16 has a flow velocity slower than that of other portions (the pressure distribution is relatively low), the flow length The shortness can be compensated, and the resin material 14 (including the projecting portion 18) is efficiently flowed (spread) so as to fill the above-mentioned space portion S (until reaching each corner 24A in the cavity 24). be able to. Therefore, each corner 12 of the molded body 10 can be accurately formed into a substantially right-angled shape in plan view.

以上、本実施形態に係る繊維強化熱可塑性樹脂成形体10の成形方法について、図面を基に説明したが、本実施形態に係る繊維強化熱可塑性樹脂成形体10の成形方法は、図示のものに限定されるものではなく、本発明の要旨を逸脱しない範囲内において、適宜設計変更可能なものである。例えば、樹脂材料14には、熱可塑性樹脂及び強化繊維以外に、添加剤、フィラー、着色剤などのその他の成分が必要に応じて含まれていてもよい。   As mentioned above, although the shaping | molding method of the fiber reinforced thermoplastic resin molded object 10 which concerns on this embodiment was demonstrated based on drawing, the molding method of the fiber reinforced thermoplastic resin molded object 10 which concerns on this embodiment is a thing of illustration. The present invention is not limited to the above, and design changes can be made as appropriate without departing from the scope of the present invention. For example, in addition to the thermoplastic resin and the reinforcing fiber, the resin material 14 may contain other components such as an additive, a filler, and a colorant as required.

10 繊維強化熱可塑性樹脂成形体
12 角部
14 繊維強化熱可塑性樹脂材料
16 角部
18 突出部
20 成形型
24 キャビティ
DESCRIPTION OF SYMBOLS 10 fiber reinforced thermoplastic resin molded object 12 corner | angular part 14 fiber reinforced thermoplastic resin material 16 corner | angular part 18 protrusion part 20 shaping | molding die 24 cavity

Claims (1)

繊維強化熱可塑性樹脂材料の融点よりも高い温度を保ちつつ、平面視で矩形状に形成された前記繊維強化熱可塑性樹脂材料の各角部に外方へ向けて突出する突出部を形成する突出部形成工程と、
前記突出部が形成された前記繊維強化熱可塑性樹脂材料を平面視で矩形状のキャビティを有する成形型に配置してプレス成形し、平面視で矩形状とされる繊維強化熱可塑性樹脂成形体の各角部を前記突出部で形成する成形工程と、
を含む繊維強化熱可塑性樹脂成形体の成形方法。
A protrusion forming an outwardly projecting protrusion on each corner of the fiber-reinforced thermoplastic resin material formed in a rectangular shape in plan view while maintaining a temperature higher than the melting point of the fiber-reinforced thermoplastic resin material Part formation process,
A fiber-reinforced thermoplastic resin molded article in which the fiber-reinforced thermoplastic resin material in which the projecting portion is formed is disposed in a mold having a rectangular cavity in a plan view and press-molded to have a rectangular shape in a plan view A forming step of forming each corner with the projection;
And a method of molding a fiber-reinforced thermoplastic resin molded article.
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Citations (5)

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JP2002373671A (en) * 2001-06-14 2002-12-26 Honda Motor Co Ltd Manufacturing method of separator for fuel cell
JP2004106399A (en) * 2002-09-19 2004-04-08 Canon Inc Method for molding optical element, apparatus for manufacturing it, and optical screen
JP2005324340A (en) * 2004-05-12 2005-11-24 Honda Motor Co Ltd Fiber reinforced plastic and its manufacturing method
JP2009286817A (en) * 2008-05-27 2009-12-10 Toray Ind Inc Laminated substrate, fiber-reinforced plastic, and methods for producing them
JP2016022671A (en) * 2014-07-22 2016-02-08 アピックヤマダ株式会社 Resin molding method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002373671A (en) * 2001-06-14 2002-12-26 Honda Motor Co Ltd Manufacturing method of separator for fuel cell
JP2004106399A (en) * 2002-09-19 2004-04-08 Canon Inc Method for molding optical element, apparatus for manufacturing it, and optical screen
JP2005324340A (en) * 2004-05-12 2005-11-24 Honda Motor Co Ltd Fiber reinforced plastic and its manufacturing method
JP2009286817A (en) * 2008-05-27 2009-12-10 Toray Ind Inc Laminated substrate, fiber-reinforced plastic, and methods for producing them
JP2016022671A (en) * 2014-07-22 2016-02-08 アピックヤマダ株式会社 Resin molding method

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