JP2018135625A - Method of manufacturing a woolen yarn and sweater not generating static electricity using fiber not generating static electricity - Google Patents

Method of manufacturing a woolen yarn and sweater not generating static electricity using fiber not generating static electricity Download PDF

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JP2018135625A
JP2018135625A JP2017043270A JP2017043270A JP2018135625A JP 2018135625 A JP2018135625 A JP 2018135625A JP 2017043270 A JP2017043270 A JP 2017043270A JP 2017043270 A JP2017043270 A JP 2017043270A JP 2018135625 A JP2018135625 A JP 2018135625A
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fiber
static electricity
sweater
conductive
friction
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正仁 櫨田
Masahito Utsugida
正仁 櫨田
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Abstract

PROBLEM TO BE SOLVED: To provide a method of not generating static electricity of high voltage which causes blackening of a fabric that a natural fiber and an artificial synthetic fiber inevitably generate by an electrostatic charge caused by friction, and by which a person lightly receives electric shock with sparking.SOLUTION: A fiber produced from a conductive polymer having a double covalent bond at a carbon skeleton part of a molecular structure such as polyacetylene added with iodine, DMcT, poly-p-phenylene, poly-p-phenylenevinylene, polythiophene, polypyrrole, and polyaniline is mix-spinning with an acrylic fiber, a polyester fiber, and the like for making a sweater and a woolen knitting yarn as a conductive fiber for removing static electricity to produce a woolen knitting yarn to knit a sweater, and the like. Even if the acrylic fiber and the polyester fiber are charged by friction, electrons are supplied from the mixed conductive fiber so that the charge of the charged acrylic fiber and the polyester fiber completely diminishes without acquiring static electricity on the woolen knitting yarn and the sweater. All that is required is selection of a conductive polymer easy to make a fiber, a mixing ratio of the conductive fiber to the extent that a fabric itself dose not charge even if the acrylic fiber charges by friction, and the like.

Description

この発明は、有機化学分野に関する物である。  The present invention relates to the field of organic chemistry.

この発明は、静電気の起き易い毛糸やセーターを静電気が起きない繊維を使う事に依って、全く静電気の起きない毛糸やセーター、布を織る為の繊維を作る方法である。  The present invention is a method for producing fibers for weaving yarns, sweaters, and fabrics that do not generate static electricity at all by using fibers that do not generate static electricity for yarns and sweaters that are susceptible to static electricity.

自然界に在る天然繊維、綿や羊毛、絹、人工的に合成された繊維、66ナイロン、アクリル、ポリエステル、レーヨン、ポリウレタン等は、化学的にはモノマーが多数つながった高分子であり、物理的には炭素を骨格として共有結合をしている絶縁体であり、対電子に依る1本鎖の共有結合をしている為に、共有結合している電子が隣の炭素原子等に移動する事が出来ず、摩擦等に因って炭素原子や酸素原子、水素原子、窒素原子等から電子が奪われると天然繊維も人工合成繊維も必ず帯電して、乾燥した湿度の低い冬等には毛糸で編んだセーターや絹、羊毛は帯電して高電圧を発生して、周囲の細かい埃を吸い寄せて生地が黒ずんだり、セーターを脱ぐ時には火花が飛んで、人が軽く感電する程に静電気を帯びる。  Natural fibers in the natural world, cotton, wool, silk, artificially synthesized fibers, 66 nylon, acrylic, polyester, rayon, polyurethane, etc. are polymers that are chemically linked to a large number of monomers. Is an insulator having a covalent bond with carbon as the skeleton, and since the single-chain covalent bond is based on a counter electron, the covalently bonded electron moves to the adjacent carbon atom, etc. If natural or artificial synthetic fibers are charged when carbon, oxygen, hydrogen, or nitrogen atoms are deprived due to friction, etc., natural fibers and artificial synthetic fibers are always charged. Sweaters, silk, and wool knitted in are charged, generating high voltage, sucking up fine dust around them and darkening the fabric, and when you take off the sweater, sparks fly, and people are lightly electrocuted .

摩擦等に因って帯電して、天然繊維や人工合成繊維が必ず起こす静電気に依って起こる生地の黒ずみや火花が飛んで人が軽く感電する程の高電圧の静電気を完全に発生しない様にする方法。  Do not completely generate high-voltage static electricity that is charged due to friction, etc., and that causes darkness or sparks in the fabric caused by static electricity caused by natural fibers or artificial synthetic fibers to fly and lightly cause human shock. how to.

この為、この発明に於いては、ヨウ素を添加したポリアセチレンやDMcT、ポリ−p−フェニレン、ポリ−p−フェニレンビニレン、ポリチオフェン、ポリピロール、ポリアニリン等の、分子構造の炭素骨格部に二重共有結合を持っている導電性高分子を繊維にして、セーターや毛糸を作るアクリル繊維やポリエステル繊維等に「静電気を除去する導電性繊維」として混ぜ込んで混紡とし、この糸で毛糸を作り、セーター等を編む。摩擦に因ってアクリル繊維やポリエステル繊維が帯電しても混紡してある導電性繊維から電子が供給されて、帯電したアクリル繊維やポリエステル繊維の帯電は完全に消えて、毛糸やセーターは静電気を帯びる事は無い。必要なのは、繊維にし易い導電性高分子の選択と導電性繊維とした場合に、摩擦でアクリル繊維などが帯電しても生地自体が静電気を帯びない程度の導電性繊維の混紡の割合などである。  Therefore, in the present invention, double covalent bonds are attached to the carbon skeleton of the molecular structure, such as polyacetylene doped with iodine, DMcT, poly-p-phenylene, poly-p-phenylene vinylene, polythiophene, polypyrrole, polyaniline, etc. Make a sweater or yarn by making a conductive polymer with fiber into acrylic fiber or polyester fiber as "conductive fiber to remove static electricity" to make a blend, make yarn with this yarn, sweater etc. Knit. Even if the acrylic fiber or polyester fiber is charged due to friction, electrons are supplied from the conductive fibers that are blended, the charged acrylic fiber or polyester fiber is completely uncharged, and the yarn and sweater are charged with static electricity. There is nothing to take on. What is needed is a ratio of conductive fiber blends that, when selected as a conductive polymer that is easy to make into fibers, and conductive fibers, even if acrylic fibers are charged due to friction, the fabric itself is not charged with static electricity. .

この発明に依り、毛糸やその毛糸で編んだセーター等に静電気が起こらず、乾燥した冬場に火花が飛んで、人が感電する程の高電圧の静電気が発生する事や、周囲の細かい埃を吸い付ける事に依って絹などの生地が黒ずむ事は無くなる。  According to this invention, static electricity does not occur in the yarn and the sweater knitted with the yarn, sparks fly in the dry winter, and high-voltage static electricity is generated to the extent that humans can get an electric shock, and fine dust around the The cloth such as silk does not darken due to the sucking.

Claims (1)

静電気の起きない繊維を使って、静電気の起きない毛糸やセーターを作る方法  How to make static yarns and sweaters using static-free fibers
JP2017043270A 2017-02-20 2017-02-20 Method of manufacturing a woolen yarn and sweater not generating static electricity using fiber not generating static electricity Pending JP2018135625A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111455654A (en) * 2020-04-29 2020-07-28 上海工程技术大学 Preparation method of polypyrrole composite wool conductive fabric
CN111636126A (en) * 2020-05-30 2020-09-08 江苏浩业纤维科技有限公司 Superfine denier acrylic fiber and wool blended yarn and preparation method thereof
CN113122980A (en) * 2021-04-14 2021-07-16 江苏浩业纤维科技有限公司 Anti-tearing wool-stretch yarn blended yarn and preparation method thereof
CN113564767A (en) * 2021-07-14 2021-10-29 北京航空航天大学 Conductive spiral yarn self-powered sensor with surface spacing structure and preparation method thereof

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JP2006104588A (en) * 2004-10-01 2006-04-20 Mitsubishi Rayon Co Ltd Electroconductive acrylic fiber and method for producing electroconductive acrylic fiber
JP2007521405A (en) * 2003-11-03 2007-08-02 アルバニー インターナショナル コーポレイション Durable highly conductive synthetic fabric structure
JP2008081881A (en) * 2006-09-27 2008-04-10 Toray Ind Inc Antistatic conjugate fiber
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JPS5580517A (en) * 1978-12-06 1980-06-17 Toray Ind Inc Antistatic synthetic fiber
JPH0967728A (en) * 1995-08-31 1997-03-11 Mitsubishi Rayon Co Ltd Antistatic spun yarn
JPH09228148A (en) * 1996-02-14 1997-09-02 Mitsubishi Rayon Co Ltd Electroconductive fiber
JP2004277912A (en) * 2003-03-14 2004-10-07 Toray Ind Inc Antistatic polyester-based conjugate fiber and method for producing the same
JP2005054286A (en) * 2003-08-07 2005-03-03 Toray Ind Inc Antistatic composite yarn and woven or knitted fabric comprising the same
JP2007521405A (en) * 2003-11-03 2007-08-02 アルバニー インターナショナル コーポレイション Durable highly conductive synthetic fabric structure
JP2006104588A (en) * 2004-10-01 2006-04-20 Mitsubishi Rayon Co Ltd Electroconductive acrylic fiber and method for producing electroconductive acrylic fiber
JP2008081881A (en) * 2006-09-27 2008-04-10 Toray Ind Inc Antistatic conjugate fiber
JP2009102770A (en) * 2007-10-23 2009-05-14 Kurabo Ind Ltd Natural fiber sliver subjected to electroconductive finishing, method for producing the same, electroconductive spun yarn obtained from the sliver, and fiber product using the electroconductive spun yarn
JP2010059589A (en) * 2008-09-08 2010-03-18 Kb Seiren Ltd Conjugated conductive fiber

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111455654A (en) * 2020-04-29 2020-07-28 上海工程技术大学 Preparation method of polypyrrole composite wool conductive fabric
CN111636126A (en) * 2020-05-30 2020-09-08 江苏浩业纤维科技有限公司 Superfine denier acrylic fiber and wool blended yarn and preparation method thereof
CN111636126B (en) * 2020-05-30 2021-05-04 江苏浩业纤维科技有限公司 Superfine denier acrylic fiber and wool blended yarn and preparation method thereof
CN113122980A (en) * 2021-04-14 2021-07-16 江苏浩业纤维科技有限公司 Anti-tearing wool-stretch yarn blended yarn and preparation method thereof
CN113564767A (en) * 2021-07-14 2021-10-29 北京航空航天大学 Conductive spiral yarn self-powered sensor with surface spacing structure and preparation method thereof
CN113564767B (en) * 2021-07-14 2022-10-28 北京航空航天大学 Conductive spiral yarn self-powered sensor with surface spacing structure and preparation method thereof

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