CN207630629U - A kind of compliant conductive fabric with fire-retardant hydrophobic effect - Google Patents
A kind of compliant conductive fabric with fire-retardant hydrophobic effect Download PDFInfo
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Abstract
本实用新型公开了一种具有阻燃疏水作用的柔性导电织物,由上至下依次为阻燃疏水织物层、柔性导电织物层及舒适透气织物层,上述三层粘结在一起,所述柔性导电织物层由至少一个条状的包含掺杂石墨烯的化学纤维织物的柔性导电织物构成,所述掺杂石墨烯的化学纤维织物的表面覆盖聚乙撑二氧噻吩层,本实用新型使织物电导率得到极大提高。
The utility model discloses a flexible conductive fabric with flame-retardant and hydrophobic effects, which are a flame-retardant hydrophobic fabric layer, a flexible conductive fabric layer and a comfortable and breathable fabric layer from top to bottom, the above three layers are bonded together, and the flexible The conductive fabric layer is composed of at least one strip-shaped flexible conductive fabric containing graphene-doped chemical fiber fabrics, the surface of the graphene-doped chemical fiber fabrics is covered with a polyethylenedioxythiophene layer. The utility model makes the fabric The conductivity is greatly improved.
Description
技术领域technical field
本实用新型涉及功能纺织品领域,具体涉及一种具有阻燃疏水作用的柔性导电织物。The utility model relates to the field of functional textiles, in particular to a flexible conductive fabric with flame-retardant and hydrophobic functions.
背景技术Background technique
早在60年前,摆脱天然纤维的各种新型纤维不断被开发,其中导电纤维因其导电性受到了极大的关注。根据导电纤维的特点,可将其分为金属系导电纤维,炭黑系导电纤维、导电高分子型纤维、金属化合物型导电纤维。导电织物是由导电纤维与服用纤维混纺而成或者以服用织物为基底在其上负载导电材料。导电织物作为一种功能性面料,可广泛应用于抗静电纺织品、屏蔽电磁波纺织品、反侦察伪装材料和智能可穿戴纺织品等领域,极大地拓展了纺织服装的应用领域。As early as 60 years ago, various new fibers free from natural fibers were continuously developed, among which conductive fibers received great attention because of their electrical conductivity. According to the characteristics of conductive fibers, it can be divided into metal-based conductive fibers, carbon black-based conductive fibers, conductive polymer fibers, and metal compound-based conductive fibers. Conductive fabrics are made by blending conductive fibers and clothing fibers or carrying conductive materials on the basis of clothing fabrics. As a functional fabric, conductive fabric can be widely used in antistatic textiles, electromagnetic wave shielding textiles, anti-reconnaissance camouflage materials and smart wearable textiles, which greatly expands the application fields of textiles and clothing.
虽然导电纤维得到了长足的发展,但也存在着一定的问题,如金属系导电纤维手感不好,抱合差,自重过大且不易混纺;炭黑系导电纤维耐冲击性差,易折损;导电高分子型纤维刚度过大,难溶,难熔,不易成型;金属化合物型导电纤维手感粗糙,舒适性较差。因此由导电纤维和服用纤维混纺而成的导电织物拥有各种缺陷,而以服用纺织品为基底在其上负载导电材料的研究更加广泛。Although conductive fibers have been greatly developed, there are still certain problems, such as metal-based conductive fibers have a bad hand feel, poor cohesion, excessive weight and are not easy to blend; carbon black-based conductive fibers have poor impact resistance and are easy to break; Polymer fibers are too rigid, insoluble, infusible, and difficult to form; metal compound-type conductive fibers feel rough and have poor comfort. Therefore, the conductive fabric blended with conductive fiber and clothing fiber has various defects, and the research on loading conductive materials on the clothing textile as the base is more extensive.
随着社会的发展,人们对多功能防护服的需求越来越多,如抗菌/抗静电织物,抗静电/疏水疏油织物等。但是目前各类功能整理剂的作用较为单一,且单一功能整理剂之间存在相容性问题,有的难以同浴使用,有的即使分步处理也难以达到相应的要求。目前关于兼具阻燃疏水作用的柔性导电织物的研究仍较少。With the development of society, people have more and more demands for multifunctional protective clothing, such as antibacterial/antistatic fabrics, antistatic/hydrophobic and oleophobic fabrics, etc. However, at present, the functions of various functional finishing agents are relatively single, and there are compatibility problems among the single-functional finishing agents. Some are difficult to use in the same bath, and some are difficult to meet the corresponding requirements even if they are treated step by step. At present, there are still few studies on flexible conductive fabrics with flame-retardant and hydrophobic properties.
实用新型内容Utility model content
为了克服现有技术存在的缺点与不足,本实用新型提供一种具有阻燃疏水作用的柔性导电织物。In order to overcome the shortcomings and deficiencies of the prior art, the utility model provides a flexible conductive fabric with flame-retardant and hydrophobic functions.
本实用新型采用如下技术方案:The utility model adopts the following technical solutions:
一种具有阻燃疏水作用的柔性导电织物,由上至下依次为阻燃疏水织物层、柔性导电织物层及舒适透气织物层,上述三层粘结在一起,所述柔性导电织物层由至少一个条状的包含掺杂石墨烯的化学纤维织物的柔性导电织物构成,所述掺杂石墨烯的化学纤维织物的表面覆盖聚乙撑二氧噻吩层。A flexible conductive fabric with flame-retardant and hydrophobic effects, which is a flame-retardant hydrophobic fabric layer, a flexible conductive fabric layer, and a comfortable and breathable fabric layer from top to bottom. The above three layers are bonded together, and the flexible conductive fabric layer is composed of at least A strip-shaped flexible conductive fabric containing graphene-doped chemical fiber fabric is formed, and the surface of the graphene-doped chemical fiber fabric is covered with a polyethylenedioxythiophene layer.
上述三层的纤维克重为20-300克/平方米。The fiber weight of the above three layers is 20-300 g/m2.
所述舒适透气织物层为棉、麻、毛、丝、天丝及其混纺织物中的一种。The comfortable and breathable fabric layer is one of cotton, hemp, wool, silk, tencel and their blended fabrics.
所述石墨烯掺杂的化学纤维织物中的石墨烯质量百分比为0.1%~5%;The mass percentage of graphene in the graphene-doped chemical fiber fabric is 0.1%~5%;
所述化学纤维织物为涤纶、锦纶、腈纶、氯纶、氨纶及其混纺织物中的一种;所述石墨烯掺杂的化学纤维织物的掺杂方式为纺丝溶液掺杂或者纺丝熔融体掺杂。The chemical fiber fabric is one of polyester, nylon, acrylic fiber, polyvinyl chloride, spandex and blended fabrics thereof; the doping method of the graphene-doped chemical fiber fabric is spinning solution doping or spinning melt doping.
本实用新型的有益效果:The beneficial effects of the utility model:
(1)掺杂剂石墨烯与原位聚合的导电聚乙撑二氧噻吩的相互协同作用使织物电导率得到极大提高,能够满足导电织物对高导电性的要求,而且掺杂剂石墨烯的加入能够有效改善导电涂层与织物的结合力,且提供一定的抗菌性、远红外发热功能。(1) The synergistic effect of the dopant graphene and the in-situ polymerized conductive polyethylenedioxythiophene greatly improves the electrical conductivity of the fabric, which can meet the high conductivity requirements of the conductive fabric, and the dopant graphene The addition of the conductive coating can effectively improve the bonding force between the conductive coating and the fabric, and provide certain antibacterial properties and far-infrared heating functions.
(2)通过采用三层织物叠合的结构,不仅可以满足高导电性的要求还提供了阻燃疏水功能,同时满足服装对舒适透气性的要求。这种设计解决了市场对多功能服装的需求与各类功能整理剂的作用较为单一,且单一功能整理剂之间存在相容性问题,有的难以同浴使用,有的即使分步处理也难以达到相应的要求这一问题。(2) By adopting a three-layer fabric superimposed structure, it can not only meet the requirements of high conductivity, but also provide flame-retardant and hydrophobic functions, and at the same time meet the requirements of clothing for comfort and breathability. This design solves the market's demand for multi-functional clothing and the effect of various functional finishing agents is relatively single, and there are compatibility problems between single-functional finishing agents, some are difficult to use in the same bath, and some are difficult to use even if they are processed step by step. It is difficult to meet the corresponding requirements.
(3)三层织物都保持了原有织物的柔性,穿着舒适。(3) The three layers of fabrics all keep the flexibility of the original fabrics and are comfortable to wear.
(4)所述掺杂石墨烯的化学纤维织物的表面覆盖聚乙撑二氧噻吩层使织物电导率得到极大提高,所以可以使用条状的柔性导电织物粘贴在舒适透气织物层,任意形状设置,实现导电功能,节约材料。(4) The surface of the chemical fiber fabric doped with graphene is covered with a polyethylenedioxythiophene layer so that the electrical conductivity of the fabric is greatly improved, so strip-shaped flexible conductive fabrics can be used to stick to the comfortable and breathable fabric layer, in any shape setting, realize the conductive function, and save materials.
附图说明Description of drawings
图1是本实用新型的结构示意图;Fig. 1 is a structural representation of the utility model;
图2是图1中柔性导电织物的纤维横截面图。Fig. 2 is a fiber cross-sectional view of the flexible conductive fabric in Fig. 1 .
具体实施方式Detailed ways
下面结合实施例及附图,对本实用新型作进一步地详细说明,但本实用新型的实施方式不限于此。The utility model will be described in further detail below in conjunction with the embodiments and accompanying drawings, but the implementation of the utility model is not limited thereto.
实施例Example
如图1所示,一种具有阻燃疏水作用的柔性导电织物,包括三层结构,上层为阻燃疏水织物层1,中间层为柔性导电织物层2,下层为舒适透气织物层3,所述柔性导电织物层由包含乙撑二氧噻吩纤维及掺杂石墨烯的纤维织物5的柔性导电织物构成,上述三层粘结在一起,所述柔性导电织物层包括至少一个条状的柔性导电织物,所述条状的宽度及长度根据实际情况及导电性能确定,如图2所示,所述掺杂石墨烯的化学纤维织物的表面覆盖聚乙撑二氧噻吩层4,也就是聚乙撑二氧噻吩层包裹在掺杂石墨烯的化学纤维织物的外表面。As shown in Figure 1, a flexible conductive fabric with flame-retardant and hydrophobic effects includes a three-layer structure, the upper layer is a flame-retardant hydrophobic fabric layer 1, the middle layer is a flexible conductive fabric layer 2, and the lower layer is a comfortable and breathable fabric layer 3. The flexible conductive fabric layer is made of a flexible conductive fabric comprising ethylenedioxythiophene fibers and fiber fabrics 5 doped with graphene, the above three layers are bonded together, and the flexible conductive fabric layer includes at least one strip-shaped flexible conductive fabric Fabric, the width and length of the strip are determined according to the actual situation and electrical conductivity, as shown in Figure 2, the surface of the chemical fiber fabric doped with graphene covers the polyethylenedioxythiophene layer 4, that is, polyethylene dioxythiophene layer 4. The dioxythiophene layer is wrapped on the outer surface of the chemical fiber fabric doped with graphene.
上述三层的纤维克重为20-300克/平方米。The fiber weight of the above three layers is 20-300 g/m2.
所述舒适透气织物层为棉、麻、毛、丝、天丝及其混纺织物中的一种。The comfortable and breathable fabric layer is one of cotton, hemp, wool, silk, tencel and their blended fabrics.
所述石墨烯掺杂的化学纤维织物中的石墨烯质量百分比为0.1%~5%;The mass percentage of graphene in the graphene-doped chemical fiber fabric is 0.1%~5%;
所述化学纤维织物为涤纶、锦纶、腈纶、氯纶、氨纶及其混纺织物中的一种;所述石墨烯掺杂的化学纤维织物的掺杂方式为纺丝溶液掺杂或者纺丝熔融体掺杂。The chemical fiber fabric is one of polyester, nylon, acrylic, polyvinyl chloride, spandex and blended fabrics thereof; the doping method of the graphene-doped chemical fiber fabric is spinning solution doping or spinning melt doping.
将上层阻燃疏水织物、中间层柔性导电织物、下层棉织物叠合即得兼具阻燃疏水作用的柔性导电织物。A flexible conductive fabric with both flame-retardant and hydrophobic effects is obtained by superimposing the upper layer of flame-retardant and hydrophobic fabric, the middle layer of flexible conductive fabric, and the lower layer of cotton fabric.
上述实施例为本实用新型较佳的实施方式,但本实用新型的实施方式并不受所述实施例的限制,其他的任何未背离本实用新型的精神实质与原理下所作的改变、修饰、替代、组合、简化,均应为等效的置换方式,都包含在本实用新型的保护范围之内。The above-mentioned embodiment is a preferred implementation mode of the present utility model, but the implementation mode of the present utility model is not limited by the described embodiment, and any other changes, modifications, modifications, Substitution, combination, and simplification should all be equivalent replacement methods, and are all included in the protection scope of the present utility model.
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| CN114934336A (en) * | 2022-05-10 | 2022-08-23 | 陕西锦澜科技有限公司 | Conductive blended yarn, flame-retardant conductive fabric and flexible intelligent wearable device |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114934336A (en) * | 2022-05-10 | 2022-08-23 | 陕西锦澜科技有限公司 | Conductive blended yarn, flame-retardant conductive fabric and flexible intelligent wearable device |
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