JP2018078223A - Lamination coil component and manufacturing method thereof - Google Patents

Lamination coil component and manufacturing method thereof Download PDF

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JP2018078223A
JP2018078223A JP2016220144A JP2016220144A JP2018078223A JP 2018078223 A JP2018078223 A JP 2018078223A JP 2016220144 A JP2016220144 A JP 2016220144A JP 2016220144 A JP2016220144 A JP 2016220144A JP 2018078223 A JP2018078223 A JP 2018078223A
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transition metal
body portion
nonmagnetic
coil component
conductor
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陽 佐々木
Akira Sasaki
陽 佐々木
吉田 則隆
Noritaka Yoshida
則隆 吉田
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Panasonic Intellectual Property Management Co Ltd
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Priority to CN201721372300.8U priority patent/CN207602315U/en
Publication of JP2018078223A publication Critical patent/JP2018078223A/en
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Abstract

PROBLEM TO BE SOLVED: To provide a lamination coil component capable of facilitating determination whether a formed conductor is defective or not in a visual inspection using images.SOLUTION: Disclosed lamination coil component includes: a non-magnetic material portion 11; and plural coils 15, 16 of conductors 14 constituted of Ag, which is formed in the non-magnetic material portion 11. The non-magnetic material portion 11 contains a transition metal. In the manufacturing method, the content of an oxide of the transition metal is controlled in a range of 0.1 to 5.0 wt.% with respect to an inorganic substance contained in the non-magnetic material.SELECTED DRAWING: Figure 1

Description

本発明は、デジタル機器やAV機器、情報通信端末等の各種電子機器に使用される小形で薄型の積層コイル部品およびその製造方法に関するものである。   The present invention relates to a small and thin laminated coil component used for various electronic devices such as digital devices, AV devices, and information communication terminals, and a method for manufacturing the same.

従来のこの種の積層コイル部品は、図4に示すように、非磁性体部1と、非磁性体部1内に埋設されAgで構成された導体からなる第1のコイル2、第2のコイル3と、非磁性体部1の上下に積層された磁性体部4とを備えていた。また、非磁性体部1は、フィラー、非晶質のガラスなどで構成された無機物と、溶剤、可塑剤などで構成された有機物とを配合し、焼成することで形成されていた。   As shown in FIG. 4, a conventional multilayer coil component of this type includes a non-magnetic body portion 1, a first coil 2 made of Ag embedded in the non-magnetic body portion 1, and a second coil 2. The coil 3 and the magnetic part 4 laminated on the top and bottom of the non-magnetic part 1 were provided. Moreover, the nonmagnetic part 1 was formed by blending an inorganic material composed of a filler, amorphous glass, and the like and an organic material composed of a solvent, a plasticizer, and the like, and baking the mixture.

なお、この出願の発明に関連する先行技術文献としては、例えば、特許文献1が知られている。   As a prior art document related to the invention of this application, for example, Patent Document 1 is known.

特開2014−179570号公報JP 2014-179570 A

上記した従来の積層コイル部品においては、非磁性体部1を構成するガラスセラミックス材料の色が白いため、Agで構成された導体と色調が近く、これにより、非磁性体部1と導体とが区別しにくくなるため、画像による外観検査において導体の形成不良の有無の確認をしようとしても形成不良かどうかの判断が困難であるという課題を有していた。   In the above-described conventional laminated coil component, since the color of the glass ceramic material constituting the non-magnetic body portion 1 is white, the color tone is close to that of the conductor made of Ag, whereby the non-magnetic body portion 1 and the conductor are separated. Since it becomes difficult to distinguish, there has been a problem that it is difficult to determine whether or not there is a poor formation of a conductor in an appearance inspection using an image even if it is attempted to check whether or not the conductor is defective.

本発明は上記従来の課題を解決するもので、画像による外観検査において導体が形成不良かどうかの判断が容易な積層コイル部品を提供することを目的とするものである。   SUMMARY OF THE INVENTION The present invention solves the above-described conventional problems, and an object of the present invention is to provide a laminated coil component in which it is easy to determine whether a conductor is poorly formed in an appearance inspection using images.

上記目的を解決するために本発明は、非磁性体部と、非磁性体部に形成されAgで構成された導体からなるコイルとを備え、非磁性体部に遷移金属を含有させた。   In order to solve the above-mentioned object, the present invention includes a non-magnetic part and a coil made of a conductor formed of Ag and formed in the non-magnetic part, and a transition metal is contained in the non-magnetic part.

本発明の積層コイル部品は、非磁性体部に含有された遷移金属によって非磁性体部に着色することができるため、非磁性体部の色と、Agで構成された導体の色の色調を遠ざけることができ、これにより、非磁性体部と導体とを容易に区別できるため、画像による外観検査において導体が形成不良かどうかの判断が容易になるという効果を奏するものである。   Since the laminated coil component of the present invention can be colored on the non-magnetic body part by the transition metal contained in the non-magnetic body part, the color tone of the color of the non-magnetic body part and the color of the conductor composed of Ag can be changed. As a result, it is possible to easily separate the non-magnetic material portion from the conductor, and thus it is possible to easily determine whether or not the conductor is poorly formed in the appearance inspection by the image.

本発明の一実施の形態におけるコモンモードノイズフィルタの断面図Sectional drawing of the common mode noise filter in one embodiment of this invention 同コモンモードノイズフィルタの斜視図Perspective view of the common mode noise filter 非磁性体部中の遷移金属酸化物の含有率と非磁性体部の絶縁抵抗の関係を示す図Diagram showing the relationship between the transition metal oxide content in the non-magnetic part and the insulation resistance of the non-magnetic part 従来のコモンモードノイズフィルタの断面図Cross section of a conventional common mode noise filter

図1は本発明の一実施の形態における積層コイル部品の一例としてのコモンモードノイズフィルタの断面図、図2は同コモンモードノイズフィルタの斜視図である。   FIG. 1 is a cross-sectional view of a common mode noise filter as an example of a laminated coil component according to an embodiment of the present invention, and FIG. 2 is a perspective view of the common mode noise filter.

本発明の一実施の形態におけるコモンモードノイズフィルタは、図1に示すように、非磁性体部11と、非磁性体部11を挟み込む第1の磁性体部12、第2の磁性体部13と、第1の非磁性体部11内に埋設されAgで構成された導体14と、導体14からなる第1のコイル15、第2のコイル16とを備えている。   As shown in FIG. 1, the common mode noise filter according to one embodiment of the present invention includes a nonmagnetic body portion 11, a first magnetic body portion 12 that sandwiches the nonmagnetic body portion 11, and a second magnetic body portion 13. And a conductor 14 embedded in the first nonmagnetic part 11 and made of Ag, and a first coil 15 and a second coil 16 made of the conductor 14.

上記構成において、前記非磁性体部11は、複数の非磁性体層を積層することによって設けられ、また、この非磁性体部11(複数の非磁性体層)は、非晶質のガラスと、結晶質のフィラーと、Agの拡散防止するため等に添加される添加剤と、Mnの酸化物を含有する非磁性材料を焼成することによって形成される。   In the above configuration, the nonmagnetic body portion 11 is provided by laminating a plurality of nonmagnetic body layers, and the nonmagnetic body portion 11 (a plurality of nonmagnetic body layers) is made of amorphous glass and It is formed by firing a nonmagnetic material containing a crystalline filler, an additive added to prevent diffusion of Ag, and the like, and an oxide of Mn.

さらに、複数の非磁性体層は、上記の無機物と、可塑剤、溶剤等の有機物とを混合して得られたスラリーを作製し、このスラリーをシート化し、焼成して得られる。焼成後には有機物は非磁性体部11内部にほとんど残留しない。また、非磁性体部11は、薄い茶色で着色される。   Further, the plurality of non-magnetic layers are obtained by preparing a slurry obtained by mixing the above-described inorganic material and an organic material such as a plasticizer and a solvent, forming the slurry into a sheet, and baking it. After firing, the organic matter hardly remains in the nonmagnetic part 11. Further, the non-magnetic body portion 11 is colored light brown.

また、前記第1の磁性体部12は、非磁性体部11の下面に積層され、シート状に構成されたNi−Cu−Znフェライト等の磁性材料からなる複数の磁性体層で構成されている。   The first magnetic body portion 12 is formed of a plurality of magnetic body layers made of a magnetic material such as Ni—Cu—Zn ferrite, which is laminated on the lower surface of the non-magnetic body portion 11 and configured in a sheet shape. Yes.

そして、前記第2の磁性体部13は、非磁性体部11の上面に積層され、すなわち、非磁性体部11を第1、第2の磁性体部12、13で挟み込んだ構成とし、そして、第2の磁性体部13も、シート状に構成されたNi−Cu−Znフェライト等の磁性材料からなる複数の磁性体層で構成されている。   The second magnetic body portion 13 is laminated on the upper surface of the nonmagnetic body portion 11, that is, the nonmagnetic body portion 11 is sandwiched between the first and second magnetic body portions 12 and 13, and The second magnetic body portion 13 is also composed of a plurality of magnetic layers made of a magnetic material such as Ni—Cu—Zn ferrite formed in a sheet shape.

さらに、前記第1のコイル15、第2のコイル16は、第1の非磁性体部11内に埋設され、それぞれ渦巻状導体と引出用導体からなる導体14で形成されている。また、第1のコイル15、第2のコイル16を構成する導体14は、それぞれ非磁性体層にめっきAgを転写するか、またはAgペーストを印刷することにより形成されている。そして、第1のコイル15と第2のコイル16とが互いに磁気結合するようになっている。   Further, the first coil 15 and the second coil 16 are embedded in the first non-magnetic body portion 11 and are each formed of a conductor 14 composed of a spiral conductor and a lead conductor. The conductors 14 constituting the first coil 15 and the second coil 16 are each formed by transferring plating Ag onto the nonmagnetic material layer or printing Ag paste. The first coil 15 and the second coil 16 are magnetically coupled to each other.

なお、第1のコイル15、第2のコイル16は、その一部を第1、第2の磁性体部12、13に接するようにしてもよく、また、第1の磁性体部12の下面、および第2の磁性体部13の上面にさらに別の非磁性体部を積層してもよい。   The first coil 15 and the second coil 16 may be partially in contact with the first and second magnetic body portions 12 and 13, and the lower surface of the first magnetic body portion 12. Further, another nonmagnetic body portion may be laminated on the upper surface of the second magnetic body portion 13.

そして、上記した構成により、図2に示すような積層体17が形成される。また、この積層体17の両端面には、4つの外部電極18が設けられ、そしてこの外部電極18はそれぞれ第1のコイル15、第2のコイル16の各両端部と接続されている。さらに、外部電極18は、積層体17の端面に銀ペーストを印刷して焼成するか、あるいは樹脂と銀からなるペーストを印刷することにより形成され、またこれらの表面にめっきによってニッケルめっき層を形成するとともに、このニッケルめっき層の表面にめっきによってすずやはんだ等の低融点金属めっき層を形成する。   And the laminated body 17 as shown in FIG. 2 is formed by the above-mentioned structure. Further, four external electrodes 18 are provided on both end surfaces of the laminate 17, and the external electrodes 18 are connected to both end portions of the first coil 15 and the second coil 16, respectively. Further, the external electrode 18 is formed by printing and baking a silver paste on the end face of the laminate 17 or printing a paste made of resin and silver, and a nickel plating layer is formed on these surfaces by plating. At the same time, a low melting point metal plating layer such as tin or solder is formed on the surface of the nickel plating layer by plating.

この積層体17は、着色された非磁性体部11と、非磁性体部11を挟む第1、第2の磁性体部12、13が積層される。   In this laminated body 17, a colored nonmagnetic body portion 11 and first and second magnetic body portions 12 and 13 sandwiching the nonmagnetic body portion 11 are laminated.

上記したように本発明の一実施の形態におけるコモンモードノイズフィルタにおいては、非磁性体部11に遷移金属であるMnを含有させているため、非磁性体部11を着色す
ることができ、これにより、非磁性体部11の色とAgで構成された導体14の色の色調を遠ざけることができるため、非磁性体部11と導体14とを容易に区別でき、この結果、画像による外観検査において、積層体17の端面に導体14が形成されていなかったり、その面積が小さかったりするような不良が発生したかどうかの判断を的確にできるという効果が得られるものである。
As described above, in the common mode noise filter according to the embodiment of the present invention, since the nonmagnetic body portion 11 contains Mn which is a transition metal, the nonmagnetic body portion 11 can be colored. Therefore, the color tone of the non-magnetic body portion 11 and the color of the conductor 14 made of Ag can be kept away from each other, so that the non-magnetic body portion 11 and the conductor 14 can be easily distinguished. In this case, it is possible to accurately determine whether the conductor 14 is not formed on the end face of the multilayer body 17 or the defect such that the area is small has occurred.

また、非磁性体部11に含有させる遷移金属は、非磁性体部11を着色することができるような遷移金属の酸化物であれば何でもよいが、例えば、Cr、Mn、Fe、Co、Ni、Cuなどが好適に用いられる。なかでも、遷移金属としてMnを使用すれば、電子部品としてありふれた薄い茶色に着色できるため、より好ましい。   The transition metal to be contained in the nonmagnetic part 11 may be any transition metal oxide that can color the nonmagnetic part 11, for example, Cr, Mn, Fe, Co, Ni Cu or the like is preferably used. Especially, if Mn is used as the transition metal, it is more preferable because it can be colored in a light brown color that is common for electronic parts.

ここで、非磁性体部11に遷移金属を含有させるには、まず、焼成前の非磁性材料に遷移金属の酸化物を含有させる必要がある。非磁性材料に遷移金属酸化物を含有させた後、その非磁性材料をシート化し、積層して形成される非磁性体部11と第1、第2の磁性体部12、13を積層して、積層体17を形成した後、焼成し、さらにその後、外部電極18を形成して積層コイル部品が得られる。焼成過程で遷移金属酸化物がガラスに取り込まれ、結果物の非磁性体部11には遷移金属が残ると考えられる。   Here, in order to contain the transition metal in the nonmagnetic body portion 11, it is necessary to first contain the transition metal oxide in the nonmagnetic material before firing. After the transition metal oxide is contained in the nonmagnetic material, the nonmagnetic material is made into a sheet, and the nonmagnetic body portion 11 and the first and second magnetic body portions 12 and 13 formed by stacking are stacked. After the laminated body 17 is formed, firing is performed, and then the external electrode 18 is formed to obtain a laminated coil component. It is considered that the transition metal oxide is taken into the glass during the firing process, and the transition metal remains in the resulting non-magnetic part 11.

このとき、焼成前の非磁性材料中の無機物のうちの、遷移金属酸化物の含有量を0.1wt%〜5.0wt%としている。   At this time, the content of the transition metal oxide in the inorganic material in the non-magnetic material before firing is set to 0.1 wt% to 5.0 wt%.

0.1wt%未満だと、着色による効果が得られない。一方、遷移金属酸化物の含有量を増やすと、電荷のキャリアとなる遷移金属イオンが、非磁性体部11の構成要素であるガラス中に多数存在することになり、絶縁性が悪化する。   If it is less than 0.1 wt%, the effect of coloring cannot be obtained. On the other hand, when the content of the transition metal oxide is increased, a large number of transition metal ions serving as charge carriers are present in the glass that is a constituent element of the non-magnetic body portion 11, and the insulating property is deteriorated.

ここで、図3に、焼成前の非磁性材料中の無機物に対する遷移金属酸化物の含有量と焼成後の積層体17の絶縁抵抗との関係を示す。   Here, FIG. 3 shows the relationship between the content of the transition metal oxide with respect to the inorganic substance in the nonmagnetic material before firing and the insulation resistance of the laminate 17 after firing.

図3から明らかなように、非磁性材料中の無機物に対する遷移金属酸化物の含有量が5.0wt%を超えると、絶縁抵抗が108Ωを下回るため、5.0wt%以下とするのが好ましい。 As is clear from FIG. 3, when the content of the transition metal oxide with respect to the inorganic substance in the nonmagnetic material exceeds 5.0 wt%, the insulation resistance is less than 10 8 Ω, so that it is 5.0 wt% or less. preferable.

なお、上記一実施の形態においては、ガラスとフィラーと添加剤と遷移金属酸化物といった無機物と、可塑剤、溶剤等の有機物とを混合、シート化した非磁性材料を焼成することによって非磁性体部11を得ているが、溶融によるガラスの製造段階であらかじめ遷移金属酸化物を添加しておくことで得られる遷移金属含有ガラスを用いても、同様の効果が達せられるものである。   In the above-described embodiment, the nonmagnetic material is obtained by baking a nonmagnetic material obtained by mixing an inorganic material such as glass, a filler, an additive, and a transition metal oxide, and an organic material such as a plasticizer or a solvent. Although the part 11 is obtained, the same effect can be achieved even when a transition metal-containing glass obtained by adding a transition metal oxide in advance in the glass production stage by melting is used.

また、上記本発明の実施の形態においては、積層コイル部品の一例としてコモンモードノイズフィルタについて説明したが、積層インダクタ、積層インダクタアレイ等の他の積層コイル部品についても適用できる。   In the embodiment of the present invention, the common mode noise filter has been described as an example of the laminated coil component. However, the present invention can also be applied to other laminated coil components such as a laminated inductor and a laminated inductor array.

本発明に係る積層コイル部品は、画像による外観検査において導体が形成不良かどうかの判断が容易になるという効果を有するものであり、特にデジタル機器やAV機器、情報通信端末等に使用されるコモンモードノイズフィルタ等において有用となるものである。   The multilayer coil component according to the present invention has an effect that it is easy to determine whether or not a conductor is poorly formed in an appearance inspection by an image, and is particularly used in digital devices, AV devices, information communication terminals, and the like. This is useful in a mode noise filter or the like.

11 非磁性体部
14 導体
15、16 第1、第2のコイル
11 Non-magnetic part 14 Conductor 15, 16 First and second coils

Claims (3)

非磁性体部と、前記非磁性体部に形成されAgで構成された導体からなるコイルとを備え、前記非磁性体部に遷移金属を含有させた積層コイル部品。 A laminated coil component comprising a non-magnetic body part and a coil made of a conductor formed of Ag formed in the non-magnetic body part, and a transition metal contained in the non-magnetic body part. 前記遷移金属をMnとした請求項1に記載の積層コイル部品。 The multilayer coil component according to claim 1, wherein the transition metal is Mn. 前記遷移金属の酸化物が含有された非磁性材料からなる前記非磁性体部に、Agで構成された前記導体からなる前記コイルを形成する積層コイル部品の製造方法であって、前記遷移金属の酸化物の含有量を、前記非磁性材料に含有された無機物に対して0.1wt%〜5.0wt%とした積層コイル部品の製造方法。 A method of manufacturing a laminated coil component in which the coil made of the conductor made of Ag is formed on the nonmagnetic body portion made of a nonmagnetic material containing the transition metal oxide, The manufacturing method of the laminated coil components which made content of an oxide 0.1 wt%-5.0 wt% with respect to the inorganic substance contained in the said nonmagnetic material.
JP2016220144A 2016-11-11 2016-11-11 Lamination coil component and manufacturing method thereof Pending JP2018078223A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0558718A (en) * 1991-07-18 1993-03-09 Aluminum Co Of America <Alcoa> Method and frit for obtaining colored ceramic body
JPH11297533A (en) * 1998-04-14 1999-10-29 Murata Mfg Co Ltd Inductor
JP2003282332A (en) * 2002-03-25 2003-10-03 Murata Mfg Co Ltd Ceramic electronic component and method of manufacturing the ceramic electronic component
JP2007194387A (en) * 2006-01-19 2007-08-02 Murata Mfg Co Ltd Electronic component and method of manufacturing the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0558718A (en) * 1991-07-18 1993-03-09 Aluminum Co Of America <Alcoa> Method and frit for obtaining colored ceramic body
JPH11297533A (en) * 1998-04-14 1999-10-29 Murata Mfg Co Ltd Inductor
JP2003282332A (en) * 2002-03-25 2003-10-03 Murata Mfg Co Ltd Ceramic electronic component and method of manufacturing the ceramic electronic component
JP2007194387A (en) * 2006-01-19 2007-08-02 Murata Mfg Co Ltd Electronic component and method of manufacturing the same

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