JP2018028015A - Heat-shielding coating material, heat-shielding laminated coating film, and coated product - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a heat-shielding coating material and the like, excellent in heat shielding and masking effect.SOLUTION: A heat-shielding coating material comprises large-diameter titanium oxide having a particle diameter of 0.4 to 2.5 μm and small-diameter titanium oxide having a particle diameter of 0.15 μm or more and less than 0.4 μm at a weight ratio of 4:6 to 6:4. Preferably, the coating material further contains hollow particles having a particle diameter of 30 to 300 μm. Preferably, the hollow particles for use are made of acrylonitrile resin, and the content thereof is 0.2 to 5 wt% in the solid content of the coating material. From the viewpoint of weather resistance, preferably an acrylic silicone resin is used as binder resin.SELECTED DRAWING: None

Description

  The present invention relates to a thermal barrier paint, a thermal barrier laminate coating film, and a coated article.

  Various paintings are applied to buildings. For example, in the interior and exterior, various coatings are applied to form a coating film to frequently protect the casing and improve the design.

  In recent years, the demand for thermal barrier coatings is increasing from the viewpoint of energy saving, such as reduction of air conditioning costs, as coatings used for roofs and outer walls of buildings.

  Such a thermal barrier coating enhances the thermal barrier performance by providing a prescription that hardly absorbs near-infrared rays of sunlight, which is a heat source, or imparting thermal insulation performance. As a paint excellent in heat-shielding property, for example, there is “building roof material repair paint” described in Patent Document 1 proposed by Ohashi Chemical Industry Co., Ltd., one of the present applicants.

Japanese Patent Laid-Open No. 11-21509

  However, in recent years, from the viewpoint of further energy saving, there has been a demand for a thermal barrier coating having a higher thermal barrier than ever before.

  The present invention has been made in consideration of the above-described matters, and an object of the present invention is to provide a heat-shielding paint and a heat-shielding laminated coating film excellent in heat-shielding property and concealing property.

  In order to solve the above problems, a large-diameter titanium oxide having a particle diameter of 0.4 to 2.5 μm and a small-diameter titanium oxide having a particle diameter of 0.15 μm or more and less than 0.4 μm are used in a weight ratio of 4: 6-6. : It was set as the thermal-insulation coating material included in the ratio of 4.

  This thermal barrier paint has excellent thermal barrier properties and concealment properties by containing large-diameter titanium oxide and small-diameter titanium oxide in a predetermined ratio.

Small-diameter titanium oxide having a particle size of 0.15 μm or more and less than 0.4 μm is a pigment-grade titanium oxide generally used as a white pigment, and is excellent in visible light reflection or scattering action. Moreover, large-diameter titanium oxide having a particle size of 0.4 to 2.5 μm is excellent in infrared reflection or scattering action.
It is preferable that the large-diameter titanium oxide and the small-diameter titanium oxide are contained in a paint solid content of 20 to 60% by weight in a weight ratio of 4: 6 to 6: 4. The content in the solid content of the combined paint is more preferably 30 to 50% by weight, and most preferably 35 to 45% by weight.

  It can be set as the thermal-insulation coating material which further contains the hollow particle whose particle diameter is 30-300 micrometers.

  This thermal barrier coating has a better thermal barrier. Since the hollow particles have characteristics as a heat insulating material, they impart heat insulating properties to the coating film. As the hollow particles, those made of acrylonitrile resin are preferably used.

  At this time, it is preferable to use a heat-shielding paint containing 0.2 to 5% by weight of hollow particles in the solid content of the paint.

  This thermal barrier paint has better thermal barrier properties and good application workability.

  It can also be set as the thermal-insulation coating material which used the acrylic silicone type resin as binder resin.

  This thermal barrier paint can form a coating film excellent in weather resistance.

  In the coated article formed with the thermal barrier coating, the temperature rise is suppressed by the thermal barrier effect of the thermal barrier coating formed. In addition to building roofs and exterior walls, objects to be coated with thermal barrier coatings, such as outdoor equipment installed in cubicles, outdoor tanks including chemical tanks, asphalt roads, etc. Examples include buildings, equipment and machines that are exposed to sunlight, such as roadbeds, automobiles and ships. Applying the thermal barrier coating to these films to form a film contributes to a reduction in air-conditioning energy, a reduction in running costs, stability of contents, and elimination of loss. Examples of the material of the object to be coated include various metals such as galvalume steel plate and tin, ceramic materials such as slate and concrete, and composite materials such as FRP.

  Moreover, the said subject is equipped with the 1st coating film formed on the surface of a base material, and the 2nd coating film formed on the surface of this 1st coating film, Said 1st coating film and The second coating film has a 4: 6 to 6: 4 weight ratio of a large diameter titanium oxide having a particle size of 0.4 to 2.5 μm and a small diameter titanium oxide having a particle size of 0.15 μm or more and less than 0.4 μm. It is also solved by the heat-shielding laminated coating film contained at a ratio of

  Here, the first coating film can be a heat-shielding laminated coating film containing hollow particles having a particle diameter of 30 to 300 μm.

  This heat-shielding laminated coating film further improves the heat-shielding performance.

  At this time, it is preferable that the second coating film is a heat-shielding laminated coating film that does not contain hollow particles.

  This heat-shielding laminated coating film further improves the heat-shielding performance. When the second coating film (upper layer) contains hollow particles in a specific particle size range, the solar reflectance tends to be small. That is, as a constitution of the heat-shielding laminated coating film, the first coating film (lower layer) located on the substrate side contains hollow particles only, and the second coating film (upper layer) located outside contains hollow particles. It is preferable that the heat shielding performance is further improved.

  Furthermore, the above-mentioned problem comprises a first coating film formed on the surface of a substrate and a second coating film formed on the surface of the first coating film, wherein the first coating film and The second coating film has a 4: 6 to 6: 4 weight ratio of a large-diameter titanium oxide having a particle diameter of 0.4 to 2.5 μm and a small-diameter titanium oxide having a particle diameter of 0.15 μm or more and less than 0.4 μm. The first coating film comprises 0.2% to 5% by weight of hollow particles made of acrylonitrile-based resin and having a particle size of 30 to 300 μm, and the second coating film includes hollow particles. It is also solved by a heat-shielding laminated coating film that does not contain.

  In the coated article formed with these heat-shielding laminated coating films, the temperature rise is suppressed by the heat-shielding effect of the heat-shielding laminated coating films.

  According to the present invention, it is possible to provide a heat-shielding paint, a heat-shielding laminated coating film and a coated article excellent in heat-shielding property and concealing property.

It is a side view for demonstrating a heat-shielding laminated coating film. It is a figure which shows the sample for thermal-insulation test evaluation. It is a graph which shows a weather resistance test result.

Hereinafter, embodiments of the present invention will be described by way of example. The thermal barrier paint of the present invention contains large-diameter titanium oxide and small-diameter titanium oxide in a weight ratio within a predetermined range. Moreover, the heat-shielding laminated coating film of the present invention contains large-diameter titanium oxide and small-diameter titanium oxide in a specific range weight ratio in the first coating film and the second coating film.
The present invention is not limited to the following embodiments.

1. Thermal barrier coating The thermal barrier coating is a 4: 6-6 by weight ratio of a large-diameter titanium oxide having a particle size of 0.4 to 2.5 μm and a small-diameter titanium oxide having a particle size of 0.15 μm or more and less than 0.4 μm. : 4 is included.

(A) Large-diameter titanium oxide Large-diameter titanium oxide is titanium oxide having a particle diameter of 0.4 to 2.5 μm, and has a particle diameter larger than that of titanium oxide (pigment grade titanium oxide) generally used as a white pigment. It is a big one of several times to about ten times. Such a large-diameter titanium oxide has an excellent infrared reflection or scattering action.

  The large-diameter titanium oxide includes titanium oxide called acicular titanium oxide or rod-like titanium oxide. Examples of needle-like or rod-like titanium oxide include “PFR-404” manufactured by Ishihara Sangyo Co., Ltd. Moreover, as a large diameter titanium oxide, for example, “Titanics JR-1000” manufactured by Teika Co., Ltd. may be mentioned. Moreover, what gave surface treatments, such as an alumina treatment, can be used for a large diameter titanium oxide.

  Here, when the particle diameter of the large-diameter titanium oxide is less than 0.4 μm, it is difficult to obtain sufficient heat shielding performance. On the other hand, when the particle diameter of the large-diameter titanium oxide exceeds 2.5 μm, the dispersibility in the paint tends to be lowered. The particle diameter of the large-diameter titanium oxide is preferably 0.4 to 2.5 μm, more preferably 0.5 to 1.5 μm.

  In the present invention, the particle diameter of titanium oxide is obtained by taking a photograph with a transmission electron microscope and measuring the volume-based horizontal equivalent diameter with an automatic image processing analyzer. A commercially available product can be used as the measuring device.

(B) Small-diameter titanium oxide Small-diameter titanium oxide is titanium oxide having a particle size of 0.15 μm or more and less than 0.4 μm, and is titanium oxide (pigment grade titanium oxide) generally used as a white pigment. Such small-diameter titanium oxide is excellent in the reflection or scattering effect of visible light.

  The small-diameter titanium oxide is preferably subjected to alumina-zirconia treatment from the viewpoint of high weather resistance. An example of such a small-diameter titanium oxide is “Titanics JR-901” manufactured by Teika Corporation.

  The particle diameter of the small diameter titanium oxide is preferably 0.2 to 0.3 μm. When the particle size of the small-diameter titanium oxide is less than 0.15 μm, the visible light reflection or scattering effect is diminished.

(C) Mixing ratio of large-diameter titanium oxide and small-diameter titanium oxide And by using a large-diameter titanium oxide and a small-diameter titanium oxide in combination, it becomes possible to ensure high heat shielding properties. The ratio of the large diameter titanium oxide and the small diameter titanium oxide is from 4: 6 to 6: 4 in weight ratio. The ratio of the large-diameter titanium oxide and the small-diameter titanium oxide is preferably 5.5: 4.5 to 4.5: 5.5 by weight, more preferably about 5: 5 by weight.

(D) Binder resin The material and type of the binder resin used for the thermal barrier coating are not particularly limited. For example, an acrylic resin, an acrylic silicone resin, a urethane resin, or the like can be used. In consideration of weather resistance, it is preferable to use various modified silicone resins. Among these, acrylic silicone resins such as acrylic silicone resins and ceramic modified acrylic silicone resins are suitable. Examples of the acrylic silicone resin include “Polydurex H-7650” manufactured by Asahi Kasei Corporation.
As the binder resin, it is preferable to use an aqueous emulsion type having a lower environmental load than that of a solvent, but a solvent type can also be used.

(E) Hollow particles Hollow particles having a particle diameter of 30 to 300 μm can be blended in the heat-shielding paint. It is preferable to use a hollow particle in which pores existing inside are filled with a gas and there is no defect such that the inside gas is in contact with outside air. The particle diameter of the hollow particles is more preferably 40 to 150 μm, and most preferably 50 to 100 μm. In the present invention, the particle diameter of the hollow particles is measured by a laser diffraction scattering method. A commercial item can be used as a measuring device.

  By mix | blending the said hollow particle with a thermal-insulation coating material, heat insulation performance improves, As a result, the temperature rise (room temperature rise etc.) of a to-be-coated object can be suppressed.

As a hollow particle, when pursuing heat insulation performance, it is advantageous that the specific gravity is small. In order to maintain the structure of the hollow particles, it is desirable that the organic system has flexibility with respect to external force. The organic material can be selected from polymers composed of one or more of monomers such as acrylonitrile, vinyl chloride, vinylidene chloride, styrene, vinyl acetate, and methacrylate. In particular, the resin is preferably made of an acrylonitrile resin from the viewpoint of the barrier property of the gas filled in the hollow. The high barrier property of the gas filled in the hollow is advantageous in that the structure of the hollow particles is maintained.
For easier handling, an inorganic compound such as calcium carbonate may be supported on the surface of the organic hollow particles. Examples of such organic hollow particles include Matsumoto Yushi Seiyaku Co., Ltd. “Matsumoto Microsphere F-65DE”.

  The blending amount of the hollow particles is preferably 0.2 to 5% by weight in the solid content of the paint. When the blending amount of the hollow particles is less than 0.2% by weight, it is difficult to obtain a heat insulating effect by blending. On the other hand, when the blending amount of the hollow particles exceeds 5% by weight, problems such as coating separation and deterioration in coating workability are likely to occur. The blending amount of the hollow particles is more preferably 0.5 to 4% by weight in the solid content of the paint.

(F) Preparation of thermal barrier coating The thermal barrier coating can be prepared by blending the above materials and using a dispersing means such as a disper. In addition to the above materials, a film-forming aid, a solvent, a thickener, an antifoaming agent, a dispersing agent and the like may be added as necessary.
In the dispersion step, when hollow particles having low elasticity are used, it is preferable to take care not to destroy the structure. For example, two types of titanium oxide can be sufficiently dispersed in the binder resin by applying a large shearing force, and then hollow particles can be added thereto to perform mild dispersion.
The manufacturing process of the thermal barrier coating is a 4: 6 to 6 by weight ratio of large-diameter titanium oxide having a particle diameter of 0.4 to 2.5 μm and small-diameter titanium oxide having a particle diameter of 0.15 μm or more and less than 0.4 μm. : The process of mix | blending with binder resin in the ratio of 4 is included. Here, it is preferable to mix 20 to 60% by weight of the large-diameter titanium oxide and the small-diameter titanium oxide in the paint solid content. The blending amount in the solid content of the paint combined with each other is more preferably 30 to 50% by weight, and most preferably 35 to 45% by weight.

2. Thermal barrier laminate film A thermal barrier laminate film can be formed using the thermal barrier paint. As illustrated in FIG. 1, the heat-shielding laminated coating film is formed on the surface of the first coating film 2 (lower layer) 2 formed on the surface of the substrate 1 (the object to be coated) and the surface of the first coating film 2. And a formed second coating film (upper layer) 3. The first coating film and the second coating film are composed of a large-diameter titanium oxide having a particle diameter of 0.4 to 2.5 μm and a small-diameter titanium oxide having a particle diameter of 0.15 μm or more and less than 0.4 μm in a weight ratio. It is included at a ratio of 4: 6 to 6: 4.

  Here, the first coating film may be formed on the primer layer formed on the surface of the substrate. As a primer layer, it can select from an epoxy resin type, a urethane resin type, an acrylic resin type, a chlorinated rubber type etc. as needed. The method for applying the thermal barrier paint is not particularly limited. Moreover, you may give topcoats, such as a photocatalyst coating material, in order to provide antifouling property on the surface of a 2nd coating film.

  And it is preferable that a 1st coating film (lower layer) contains the hollow particle whose particle diameter is 30-300 micrometers. Thereby, the heat shielding performance is improved. The hollow particles preferably contain 0.2 to 5% by weight of an acrylonitrile-based resin.

  At this time, it is preferable that the second coating film (upper layer) does not contain hollow particles. This further improves the heat shielding performance.

  Hereinafter, the contents of the present invention will be described more specifically with reference to study examples.

[Examination example 1]
This examination example 1 is for clarifying the influence which the mixing | blending ratio of a large diameter titanium oxide and a small diameter titanium oxide has on heat insulation performance.

An aqueous emulsion resin was used as the binder resin. Specifically, an acrylic silicone resin (polydurex H-7650 manufactured by Asahi Kasei Corporation) having a solid content of 40.5% was used.
And as a large diameter titanium oxide, a particle diameter of 0.5-1.5 micrometers (Titanics Corporation Titanics JR-1000), as a small diameter titanium oxide (pigment grade titanium oxide), a particle diameter is 0.2-. A 0.3 μm one (Titanics JR-901 manufactured by Teika Co., Ltd.) was used.

  Then, a plurality of thermal barrier coatings were prepared by changing the blending ratio of large diameter titanium oxide and small diameter titanium oxide. The proportion of titanium oxide (large-diameter titanium oxide + small-diameter titanium oxide) in the solid content of the thermal barrier coating is uniform in each example and each comparative example (42.3 wt%).

Each obtained heat-shielding paint was applied twice to a base material (Galvanium steel sheet (registered trademark) thickness 0.8 mm, manufactured by JFE Steel Corporation) to form a heat-shielding laminated coating film. Specifically, each thermal barrier coating is applied to the surface of the base material (application amount 0.2 kg / m ² ) to form a first coating film, and then each thermal barrier coating is formed on the first coating film. Was applied again (application amount: 0.2 kg / m ² ) to form a second coating film, which was a heat-shielding laminated coating film composed of the first coating film and the second coating film. And the base material in which the heat-shielding laminated coating film was formed was made into the evaluation sample, and the solar reflectance evaluation and the heat-shielding test were done.

The solar reflectance was evaluated by two methods: (1) JIS K5675 and (2) a method according to the Tokyo Cool Roof Promotion Project. The measuring instrument used was “UV-3100PC” manufactured by Shimadzu Corporation, owned by Okayama Prefectural Industrial Technology Center.
Among the evaluations of solar reflectance, (2) the method according to the Tokyo Metropolitan Cool Roof Promotion Project is as follows. Spectral reflectance was measured using a test plate coated with each paint, using barium sulfate as a white standard, and the weighted average multiplied by the weight coefficient shown in Table 2 of JIS R3102 was integrated and calculated.

The evaluation procedure of the heat shielding test by lamp irradiation is as follows. Irradiate light from a light source (halogen projector “CHT-500S” manufactured by Caster Lighting Japan Co., Ltd.) for 30 minutes at a distance of 30 cm from the surface of the base material (30 cm × 20 cm) coated with a thermal barrier paint. Was stopped for 30 minutes. 2 was measured with a thermometer (SD card type 12-channel temperature recorder “BTM-4208SD” manufactured by FUSO Corporation). The average temperature for 90 minutes at which the temperature was measured was calculated, and this temperature was compared as the back surface temperature. The series of operations described above was performed in a room where the temperature was set to 23 ° C.
Table 1 shows the paint formulation and evaluation results of Study Example 1. In the table, ← indicates the same numerical value as in the left column.

From Table 1 above, the backside temperature in the heat-shielding test shows a relatively low temperature when the mixing ratio of large-diameter titanium oxide and small-diameter titanium oxide is in the range of 6: 4 to 4: 6 by weight ratio, and the heat-shielding performance. Was found to improve.
In addition, although it is a little, the solar reflectance (JIS) becomes higher as the blending ratio of large diameter titanium oxide is higher, and the solar reflectance (Tokyo) tends to be higher as the blending ratio of small diameter titanium oxide is higher. It was done.

[Examination example 2]
This examination example 2 is for clarifying the influence which the mixing | blending of various fillers, such as a hollow particle, has on heat-shielding performance.

  In addition to the binder resin (aqueous emulsion resin), large-diameter titanium oxide, and small-diameter titanium oxide, the same film-forming auxiliary, solvent, thickener, antifoaming agent, and dispersant as those in the above-mentioned Study Example 1 were used.

  As the various fillers, there are three types of organic hollow particles (acrylonitrile-based resin made of different particle diameters, all spherical), inorganic hollow particles (“Winlight MSB-5011” manufactured by Axes Chemical Co., Ltd.), and heat radiation filler ( "TCM-002" manufactured by Teika Co., Ltd.) and calcium carbonate were used. Except for Example 1 in which no filler was blended, the blending amount of the filler was uniform at 0.5% by weight in the solid content of the paint. In the system in which the filler is blended, the ratio of titanium oxide (large diameter titanium oxide + small diameter titanium oxide) in the solid content of the thermal barrier coating is 42% by weight.

And like the said examination example 1, after producing the thermal-insulation coating material of each Example and a comparative example, it apply | coats to a base material twice, respectively (coating amount: 0.2 kg / of both a 1st coating film and a 2nd coating film) m ² ) to form a heat-shielding laminated coating film, and evaluation of solar reflectance and a heat-shielding test were conducted.
Table 2 shows the paint formulation and evaluation results of Study Example 2.

From Table 2 above, by blending organic hollow particles having a particle diameter of 60 to 70 μm or organic hollow particles having a particle diameter of 140 μm, the solar reflectance tends to decrease, but the backside temperature of the heat shielding test decreases. It was found that the heat shielding performance was improved. In particular, when organic hollow particles having a particle diameter of 60 to 70 μm are added (Example 4), the heat shielding performance is high.
Organic hollow particles having a particle size of 15 to 30 μm do not have a decrease in reflectivity, but do not have a decrease in back surface temperature. The reason why the reflectance is not decreased as compared with particle diameters of 60 to 70 μm and 140 μm is considered to be because the particle diameter is small and not exposed to the coating film surface.
In addition, what added the inorganic hollow particle, the thermal radiation filler, and calcium carbonate did not have a significant change in the back surface temperature of a heat-shielding test, and the superiority of using an organic hollow particle was supported.

[Examination example 3]
This examination example 3 clarifies the relationship between the blending amount and the heat shielding performance using organic hollow particles having a particle diameter of 60 to 70 μm, which has been confirmed to have a high effect of improving the heat shielding performance in the examination example 2. Is for.

  In addition to the binder resin (aqueous emulsion resin), large-diameter titanium oxide, and small-diameter titanium oxide, the same film-forming auxiliary, solvent, thickener, antifoaming agent, and dispersant as those in the above-mentioned Study Example 1 were used.

The organic hollow particles are made of an acrylonitrile-based resin, have a spherical shape with a particle diameter of 60 to 70 μm as described above, and have a true specific gravity of 0.02 to 0.1 g / cm ³ . About this organic hollow particle, the heat-shielding coating material was created by the mixing | blending of seven levels including the combination.

And like the said examination example 1, after producing the thermal-insulation coating material of each Example and a comparative example, it apply | coats to a base material twice, respectively (coating amount: 0.2 kg / of both a 1st coating film and a 2nd coating film) m ² ) to form a heat-shielding laminated coating film, and evaluation of solar reflectance and a heat-shielding test were conducted.
Table 3 shows the paint formulation and evaluation results of Study Example 3.

From Table 3 above, when organic hollow particles (particle size: 60 to 70 μm) are blended in the solid content of the paint in an amount of 0.25 to 4.83 wt%, the back surface temperature of the heat insulation test is lowered and the heat insulation performance is improved. Confirmed to do.
When organic hollow particles (particle diameter: 60 to 70 μm) were blended in the solid content of the paint in an amount exceeding 5% by weight, problems such as separation of the paint and deterioration of workability of the paint occurred.

[Study Example 4]
The present study example 4 is a study on the configuration of the heat-shielding laminated coating film. Specifically, in the heat-shielding laminated coating film composed of the first coating film and the second coating film, which coating film should preferably contain organic hollow particles (spherical with a particle diameter of 60 to 70 μm)? It has been studied.

  In addition to the binder resin (aqueous emulsion resin), large-diameter titanium oxide, and small-diameter titanium oxide, the same film-forming auxiliary, solvent, thickener, antifoaming agent, and dispersant as those in the above-mentioned Study Example 1 were used.

And like the said examination example 1, after producing the thermal-insulation coating material of each Example and a comparative example, it apply | coats to a base material twice, respectively (coating amount: 0.2 kg / of both a 1st coating film and a 2nd coating film) m ² ) to form a heat-shielding laminated coating film, and evaluation of solar reflectance and a heat-shielding test were conducted.
Table 4 shows the paint formulation and evaluation results of Study Example 4. The coating film example No of the first coating film (lower layer) is the first digit, and the coating film example No. of the second coating film (upper layer) is the second digit. For example, in Example 14 of the laminated coating film, the coating material of the coating example 4 is used for the first coating film (lower layer) and the coating material of the coating example 1 is used for the second coating film (upper layer).

  From Table 4 above, it was found that when the organic hollow particles were blended in the first coating film (lower layer), the back surface temperature of the heat shielding test was lowered and the heat shielding performance was improved.

Surprisingly, it has also been found that heat shielding performance is further improved when the organic hollow particles are blended only in the first coating film (lower layer) (not blended in the upper layer) (Laminated coating film example 14). .
Although the details of the mechanism by which such phenomenon occurs are unknown, it has been confirmed that when organic hollow particles are blended with the second coating film, the solar reflectance decreases. It is assumed that the backside temperature is raised by the infrared rays entering the organic hollow particles passing through the inside of the organic hollow particles and passing through the backside rather than the atmosphere side without being reflected or scattered. .

[Study Example 5]
This examination example 5 is a comparative evaluation of a heat-shielding laminated coating film using the heat-shielding paint of the present invention and a laminated coating film using various commercially available products.

From Table 5 above, the heat-insulating laminated coating film of Example 14, which is a developed product, has a low back-surface temperature in the heat-insulating test as compared with the heat-shielding paints currently on the market for general purposes, and has a heat-insulating performance. It was confirmed to be excellent.
Moreover, the weather resistance test which used the metal weather (registered trademark of Dainippon Plastics Co., Ltd.) was implemented about the heat-shielding laminated coating film of Example 14 which is a developed product. The result is shown in FIG. From this figure, the developed heat-shielding laminated coating film maintains a high gloss retention even in 1250 hours (integrated light quantity 1700 MJ / m ² ), and the color difference change is as small as 0.8 or less, thus confirming high weather resistance. It was.

As described above with examples, the inventor of the present application diligently studied to enhance the heat shielding performance of the heat shielding paint, and found an effective composition of the reflector and the heat insulating material and a layer structure that enhances the effect.
In thermal barrier coatings, infrared reflection affects the superiority or inferiority of performance. The inventor of the present application provides a coating film having a high solar reflectance from visible light to infrared by mixing an appropriate amount of titanium oxide having a particle size approximately equal to the wavelength of visible light and infrared light in two sizes, large and small. I found that I can do it.
This is thought to be due to the fact that small-diameter titanium oxide enters the gaps between the large-diameter titanium oxides, the gaps between the titanium oxides are reduced to a state close to so-called close-packing, and the concealment is increased, which is a cause of high reflection.
Moreover, it is considered that the scattering of light to be reflected is increased by setting the diameter to be approximately the same as the wavelength to be reflected.
Furthermore, spherical hollow balloons (hollow particles) with high heat insulation properties were blended in order to enhance the heat insulation performance. Surprisingly, it has been found that the heat shielding performance is enhanced by using the non-mixed layer as the upper layer and the mixed layer as the lower layer.
This is presumably because when the hollow particles are blended on the upper surface that receives direct sunlight, the reflection performance of the hollow particles is lower than that of titanium oxide, so that more infrared rays are transmitted through the hollow particles.
In other words, if the upper layer is composed of a reflective layer in which titanium oxide is mixed, and the lower layer is composed of a heat insulating layer in which hollow particles are mixed, the upper layer effectively reflects infrared rays, and the heat transmitted through the coating film cannot be reflected in the lower layer. It has been found that the effect of heat insulation occurs and the heat shielding performance is enhanced.

  The present invention has been described above with reference to specific embodiments and examples. However, the present invention is not limited to the above-described embodiments and the like, and is attached to the application for this application by those skilled in the art. Various changes and modifications can be made without departing from the scope of the appended claims.

1 Substrate 2 First coating (lower layer)
3 Second coating (upper layer)

P measuring point

Claims (11)

A large-diameter titanium oxide having a particle size of 0.4 to 2.5 μm;
A small diameter titanium oxide having a particle size of 0.15 μm or more and less than 0.4 μm,
In a weight ratio of 4: 6 to 6: 4,
Thermal barrier paint.
Further comprising hollow particles having a particle size of 30 to 300 μm,
The thermal barrier paint according to claim 1.
Containing hollow particles in a solid content of 0.2 to 5% by weight,
The thermal barrier paint according to claim 2.
The hollow particles are made of acrylonitrile resin,
The thermal barrier paint according to claim 2 or 3.
Using acrylic silicone resin as binder resin,
The thermal-insulation coating material in any one of Claims 1-4.
The thermal barrier paint according to claim 1 is formed into a film.
Painted article.
A first coating film formed on the surface of the substrate;
A second coating film formed on the surface of the first coating film,
The first coating film and the second coating film are
Including a large-diameter titanium oxide having a particle diameter of 0.4 to 2.5 μm and a small-diameter titanium oxide having a particle diameter of 0.15 μm or more and less than 0.4 μm in a weight ratio of 4: 6 to 6: 4,
Thermal barrier laminated coating.
The first coating film further includes hollow particles having a particle diameter of 30 to 300 μm.
The heat-shielding laminated coating film according to claim 7.
The second coating does not contain hollow particles,
The heat-shielding laminated coating film according to claim 8.
A first coating film formed on the surface of the substrate;
A second coating film formed on the surface of the first coating film,
The first coating film and the second coating film are
Including a large-diameter titanium oxide having a particle diameter of 0.4 to 2.5 μm and a small-diameter titanium oxide having a particle diameter of 0.15 μm or more and less than 0.4 μm in a weight ratio of 4: 6 to 6: 4,
The first coating film is
0.2% to 5% by weight of hollow particles made of acrylonitrile resin and having a particle size of 30 to 300 μm,
The second coating film is
Does not contain hollow particles,
Thermal barrier laminated coating.
The heat-shielding laminated coating film according to any one of claims 7 to 10, is formed.
Painted article.