JP2017535518A5 - - Google Patents
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- Publication number
- JP2017535518A5 JP2017535518A5 JP2017515103A JP2017515103A JP2017535518A5 JP 2017535518 A5 JP2017535518 A5 JP 2017535518A5 JP 2017515103 A JP2017515103 A JP 2017515103A JP 2017515103 A JP2017515103 A JP 2017515103A JP 2017535518 A5 JP2017535518 A5 JP 2017535518A5
- Authority
- JP
- Japan
- Prior art keywords
- borate
- tetrakis
- diisopropylbenzamidinate
- formula
- metal complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 21
- -1 tert-butylcyclopentadienyl Chemical group 0.000 claims description 11
- 239000012190 activator Substances 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims description 3
- 229910000085 borane Inorganic materials 0.000 claims description 2
- 239000002516 radical scavenger Substances 0.000 claims description 2
- 150000004696 coordination complex Chemical class 0.000 claims 4
- 239000000178 monomer Substances 0.000 claims 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 239000005977 Ethylene Substances 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- 239000003446 ligand Substances 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000002879 Lewis base Substances 0.000 claims 1
- 239000005922 Phosphane Substances 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 150000002466 imines Chemical class 0.000 claims 1
- 150000002527 isonitriles Chemical class 0.000 claims 1
- 150000007527 lewis bases Chemical class 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 229910000064 phosphane Inorganic materials 0.000 claims 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphane group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 claims 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 17
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 150000001639 boron compounds Chemical class 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000013543 active substance Substances 0.000 description 2
- BOXSCYUXSBYGRD-UHFFFAOYSA-N cyclopenta-1,3-diene;iron(3+) Chemical compound [Fe+3].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 BOXSCYUXSBYGRD-UHFFFAOYSA-N 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-O dimethyl(phenyl)azanium Chemical compound C[NH+](C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-O 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 2
- 239000012041 precatalyst Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- OJJVPGJEBAZOIF-UHFFFAOYSA-N (2,3,4,5-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=CC(F)=C(F)C(F)=C1F OJJVPGJEBAZOIF-UHFFFAOYSA-N 0.000 description 1
- OUHOZBRDLAZZLQ-UHFFFAOYSA-N (2,3,5,6-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=CC(F)=C1F OUHOZBRDLAZZLQ-UHFFFAOYSA-N 0.000 description 1
- 125000004361 3,4,5-trifluorophenyl group Chemical group [H]C1=C(F)C(F)=C(F)C([H])=C1* 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 125000005131 dialkylammonium group Chemical group 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-O dicyclohexylazanium Chemical compound C1CCCCC1[NH2+]C1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-O 0.000 description 1
- GGSUCNLOZRCGPQ-UHFFFAOYSA-O diethyl(phenyl)azanium Chemical compound CC[NH+](CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-O 0.000 description 1
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- RIOQSEWOXXDEQQ-UHFFFAOYSA-O triphenylphosphanium Chemical compound C1=CC=CC=C1[PH+](C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-O 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- COIOYMYWGDAQPM-UHFFFAOYSA-N tris(2-methylphenyl)phosphane Chemical compound CC1=CC=CC=C1P(C=1C(=CC=CC=1)C)C1=CC=CC=C1C COIOYMYWGDAQPM-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14185359.8 | 2014-09-18 | ||
| EP14185359 | 2014-09-18 | ||
| PCT/EP2015/070498 WO2016041818A1 (en) | 2014-09-18 | 2015-09-08 | Metal complex comprising amidine and substituted cyclopentadienyl ligands |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017535518A JP2017535518A (ja) | 2017-11-30 |
| JP2017535518A5 true JP2017535518A5 (https=) | 2020-08-06 |
| JP6767363B2 JP6767363B2 (ja) | 2020-10-14 |
Family
ID=51582269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017515103A Active JP6767363B2 (ja) | 2014-09-18 | 2015-09-08 | アミジンおよび置換されたシクロペンタジエニル配位子を含む金属錯体 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10472431B2 (https=) |
| EP (1) | EP3194412B1 (https=) |
| JP (1) | JP6767363B2 (https=) |
| KR (1) | KR102506178B1 (https=) |
| CN (1) | CN106687468B (https=) |
| WO (1) | WO2016041818A1 (https=) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11390704B2 (en) | 2017-06-14 | 2022-07-19 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
| WO2019132687A1 (en) * | 2017-12-25 | 2019-07-04 | Arlanxeo Netherlands B.V. | Metal complex comprising amidine and thiophene fused cyclopentadienyl ligands |
| WO2019203676A1 (en) * | 2018-04-16 | 2019-10-24 | Arlanxeo Netherlands B.V. | Metal complex comprising amidine and indole fused cyclopentadienyl ligands |
| WO2020058267A1 (en) | 2018-09-18 | 2020-03-26 | Arlanxeo Netherlands B.V. | Catalyst mixture |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4204937B2 (ja) * | 2002-09-30 | 2009-01-07 | 出光興産株式会社 | オレフィン系グラフト共重合体組成物の製造方法 |
| CN1934145B (zh) | 2004-03-17 | 2011-01-19 | 帝斯曼知识产权资产管理有限公司 | 包括脒配体的聚合催化剂 |
| DE102005044549B4 (de) * | 2005-09-17 | 2008-04-17 | Eads Deutschland Gmbh | Flugzeugflügel mit ausfahrbarer Nasenklappe |
| EP2336204A1 (en) * | 2009-12-21 | 2011-06-22 | DSM IP Assets B.V. | Borane activated ti catalyst system comprising amidine and diene ligand |
| EP2336205A1 (en) * | 2009-12-21 | 2011-06-22 | DSM IP Assets B.V. | TI catalyst system comprising substituted cyclopentadienyl, amidine and diene ligand |
| JP5797979B2 (ja) | 2011-08-31 | 2015-10-21 | 太陽誘電株式会社 | 弾性波デバイス |
| JP2013155371A (ja) * | 2012-01-06 | 2013-08-15 | Japan Polyethylene Corp | オレフィン系重合体の製造方法 |
| CA2877754C (en) | 2012-08-03 | 2018-12-11 | Exxonmobil Chemical Patents Inc. | Catalysts comprising salan ligands |
-
2015
- 2015-09-08 WO PCT/EP2015/070498 patent/WO2016041818A1/en not_active Ceased
- 2015-09-08 KR KR1020177007116A patent/KR102506178B1/ko active Active
- 2015-09-08 US US15/511,358 patent/US10472431B2/en active Active
- 2015-09-08 EP EP15759472.2A patent/EP3194412B1/en active Active
- 2015-09-08 CN CN201580049929.6A patent/CN106687468B/zh active Active
- 2015-09-08 JP JP2017515103A patent/JP6767363B2/ja active Active
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