JP2017523290A - 洗濯洗剤組成物 - Google Patents
洗濯洗剤組成物 Download PDFInfo
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- JP2017523290A JP2017523290A JP2017504735A JP2017504735A JP2017523290A JP 2017523290 A JP2017523290 A JP 2017523290A JP 2017504735 A JP2017504735 A JP 2017504735A JP 2017504735 A JP2017504735 A JP 2017504735A JP 2017523290 A JP2017523290 A JP 2017523290A
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- surfactant
- laundry detergent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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Abstract
Description
−線状アルキルベンゼンスルホネートを含む、アニオン性界面活性剤と、
−エトキシ化アルコール非イオン性界面活性剤と、
−この組成物の5重量%を超える水と、を含み、
全アニオン性界面活性剤:非イオン性界面活性剤の重量比が、5:1〜23:1であり、線状アルキルベンゼンスルホネート:非イオン性界面活性剤の重量比が、5:1〜10:1であり、全界面活性剤の水に対する重量比が、3:1〜20:1である。
本発明の組成物は、液体洗濯洗剤組成物である。「液体洗濯洗剤組成物」という用語は、家庭用洗濯機内で、布地を濡らし、処理すること、例えば、衣類を洗浄することが可能な液体を含む、任意の洗濯洗剤組成物を意味し、限定するものではないが、液体、ゲル、ペースト、分散液などが挙げられる。液体組成物は、固体又は気体を適宜分割された形態で含み得るものであるが、液体組成物としては、錠剤又は顆粒などの、全体として非流動性の形態は除外する。
本発明はまた、水溶性フィルムと、本発明による液体洗濯洗剤組成物と、を含む、水溶性単位用量物品である。
予め秤量した400mLビーカーに、50グラム±0.1グラムのフィルム材料を入れ、245mL±1mLの蒸留水を添加する。これを、600rpmに設定した磁気撹拌機上で30分間激しく撹拌する。その後、混合物を、上記で定義した孔径(最大20マイクロメートル)の折り畳んだ定性分析用焼結ガラス濾紙で濾過する。回収した濾液から任意の従来の方法によって水を乾燥させ、残った材料の重量を測定する(これが溶解又は分散画分である)。その後、溶解度(%)又は分散度(%)を計算することができる。
アニオン性界面活性剤は、線状アルキルベンゼンスルホネート、アルキルエトキシレートサルフェート及びこれらの組み合わせから選択され得る。
エトキシ化非イオン性界面活性剤は、例えば、一級及び二級アルコールエトキシレート、特にアルコール1モル当たり平均1〜50モル又は更に20モルのエチレンオキシドでエトキシ化されたC8〜C20脂肪族アルコール、より特にアルコール1モル当たり平均1〜10モルのエチレンオキシドでエトキシ化されたC10〜C15一級及び二級脂肪族アルコールであってよい。非エトキシ化アルコール非イオン性界面活性剤としては、アルキルポリグリコシド、グリセロールモノエーテル、及びポリヒドロキシアミド(グルカミド)が挙げられる。
洗濯用洗剤補助剤成分は、漂白剤、漂白触媒、染料、色相剤、洗浄ポリマー、アルコキシル化ポリアミン、ポリエチレンイミン、アルコキシル化ポリエチレンイミン、汚れ放出ポリマー、両親媒性グラフトポリマー、界面活性剤、溶媒、移染阻害剤、キレート剤、酵素、香料、カプセル化香料、香料送達剤、抑泡剤、増白剤、ポリカルボキシレート、構造剤、酸化防止剤、付着助剤及びこれらの混合物から選択され得る。
任意の好適なプロセスを使用して、本発明の組成物を製造することができる。当業者であれば、当該技術分野にて既知の好適なプロセスを知っているであろう。
本発明の組成物又は単位用量物品は、洗濯物が既に存在しているか、又は洗濯物が加えられる洗浄液に加えることができる。自動洗濯機操作にて使用し、ドラム又は投入引き出しに直接添加してもよい。柔軟仕上げ剤又は染み除去剤などの他の洗濯洗剤組成物と組み合わせて使用してもよい。洗浄液に加える前の染み前処理組成物として使用してもよい。
%SRI=(色新しい染み−色洗浄後の染み)/(色新しい染み)*100%
AB間の染み除去の差を算出するために、%SRIB−%SRIAを計算した。正値は、Bの染み除去性能がより優れていることを示す。
Claims (15)
- 液体洗濯洗剤組成物であって、
線状アルキルベンゼンスルホネートを含む、アニオン性界面活性剤と、
エトキシ化アルコール非イオン性界面活性剤と、
前記組成物の5重量%を超える水と、
を含み、
全アニオン性界面活性剤:非イオン性界面活性剤の重量比が、5:1〜23:1であり、
線状アルキルベンゼンスルホネート:非イオン性界面活性剤の重量比が、5:1〜10:1であり、
全界面活性剤の水に対する重量比が、3:1〜20:1であり、
ここで、「全アニオン性界面活性剤」とは、前記液体洗濯洗剤組成物中に存在する全てのアニオン性界面活性剤の合計を意味し、「全界面活性剤」とは、全てのアニオン性、非イオン性及びカチオン性界面活性剤を含むがこれらに限定されない、前記液体洗濯洗剤組成物中に存在する全ての界面活性剤の濃度を意味し、「界面活性剤」は、脂肪酸又はその中和された等価物を含まない、液体洗濯洗剤組成物。 - 全アニオン性界面活性剤:非イオン性界面活性剤の前記重量比が、7:1〜23:1である、請求項1に記載の組成物。
- 線状アルキルベンゼンスルホネート:非イオン性界面活性剤の前記重量比が、6:1〜10:1である、請求項1又は2に記載の組成物。
- 20〜42重量%、又は更に25〜40重量%、又は更に30〜40重量%のアニオン性界面活性剤を含む、請求項1〜3のいずれか一項に記載の組成物。
- 前記アニオン性界面活性剤がアルキルエトキシレートサルフェートを含む、請求項1〜4のいずれか一項に記載の組成物。
- 15重量%〜25重量%の線状アルキルベンゼンスルホネートを含む、請求項1〜5のいずれか一項に記載の組成物。
- 0.5重量%〜7.5重量%、又は更に1重量%〜5重量%の非イオン性界面活性剤を含む、請求項1〜6のいずれか一項に記載の組成物。
- 前記非イオン性界面活性剤が、式R(EO)n(式中、Rは、4〜30個の炭素原子のアルキル鎖を表し、(EO)は、1単位のエチレンオキシドモノマーを表し、nは、0.5〜20の平均値を有する)の脂肪アルコールエトキシレートを含む、請求項1〜7のいずれか一項に記載の組成物。
- 5重量%〜15重量%の脂肪酸、又は更に8重量%〜15重量%の脂肪酸を含む、請求項1〜8のいずれか一項に記載の組成物。
- 5.5重量%〜20重量%の水を含む、請求項1〜9のいずれか一項に記載の組成物。
- 洗濯用洗剤補助剤成分を含み、前記洗濯用洗剤補助剤成分が、漂白剤、漂白触媒、染料、色相剤、洗浄ポリマー、アルコキシル化ポリアミン、ポリエチレンイミン、アルコキシル化ポリエチレンイミン、汚れ放出ポリマー、両親媒性グラフトポリマー、界面活性剤、溶媒、移染阻害剤、キレート剤、酵素、香料、カプセル化香料、香料送達剤、抑泡剤、増白剤、ポリカルボキシレート、構造剤、酸化防止剤、付着助剤及びこれらの混合物から選択される、請求項1〜10のいずれか一項に記載の組成物。
- アルコール、ジオール、モノアミン誘導体、グリコール又はこれらの混合物から選択される溶媒を含み、全溶媒の全界面活性剤に対するモル比は、1:1〜1:3、又は更に1:4〜1:2.5である、請求項1〜11のいずれか一項に記載の組成物。
- 水溶性フィルムと、請求項1〜12のいずれか一項に記載の液体洗濯洗剤組成物と、を含む、水溶性単位用量物品。
- 少なくとも2つ又は更に少なくとも3つの区画を含む、請求項13に記載の水溶性単位用量物品。
- 前記区画が、重なり合った向き又は並んだ向きに配置される、請求項14に記載の水溶性単位用量物品。
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