JP2017200887A - Surface-coated powder and cosmetics containing the same - Google Patents
Surface-coated powder and cosmetics containing the same Download PDFInfo
- Publication number
- JP2017200887A JP2017200887A JP2016093122A JP2016093122A JP2017200887A JP 2017200887 A JP2017200887 A JP 2017200887A JP 2016093122 A JP2016093122 A JP 2016093122A JP 2016093122 A JP2016093122 A JP 2016093122A JP 2017200887 A JP2017200887 A JP 2017200887A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- coated
- titanium oxide
- skin
- red
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000843 powder Substances 0.000 title claims abstract description 51
- 239000002537 cosmetic Substances 0.000 title claims abstract description 19
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 16
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 9
- 238000000576 coating method Methods 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 9
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 11
- 230000000052 comparative effect Effects 0.000 description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- -1 foundations Substances 0.000 description 7
- 239000000049 pigment Substances 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 2
- 210000000245 forearm Anatomy 0.000 description 2
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052627 muscovite Inorganic materials 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 229910052628 phlogopite Inorganic materials 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000000475 sunscreen effect Effects 0.000 description 2
- 239000000516 sunscreening agent Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- 229940043375 1,5-pentanediol Drugs 0.000 description 1
- GNCOVOVCHIHPHP-UHFFFAOYSA-N 2-[[4-[4-[(1-anilino-1,3-dioxobutan-2-yl)diazenyl]-3-chlorophenyl]-2-chlorophenyl]diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC(C(=C1)Cl)=CC=C1C(C=C1Cl)=CC=C1N=NC(C(C)=O)C(=O)NC1=CC=CC=C1 GNCOVOVCHIHPHP-UHFFFAOYSA-N 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- OENHQHLEOONYIE-UKMVMLAPSA-N all-trans beta-carotene Natural products CC=1CCCC(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C OENHQHLEOONYIE-UKMVMLAPSA-N 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- UHHXUPJJDHEMGX-UHFFFAOYSA-K azanium;manganese(3+);phosphonato phosphate Chemical compound [NH4+].[Mn+3].[O-]P([O-])(=O)OP([O-])([O-])=O UHHXUPJJDHEMGX-UHFFFAOYSA-K 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 229910052916 barium silicate Inorganic materials 0.000 description 1
- HMOQPOVBDRFNIU-UHFFFAOYSA-N barium(2+);dioxido(oxo)silane Chemical compound [Ba+2].[O-][Si]([O-])=O HMOQPOVBDRFNIU-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000011648 beta-carotene Substances 0.000 description 1
- 235000013734 beta-carotene Nutrition 0.000 description 1
- TUPZEYHYWIEDIH-WAIFQNFQSA-N beta-carotene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C)C=CC=C(/C)C=CC2=CCCCC2(C)C TUPZEYHYWIEDIH-WAIFQNFQSA-N 0.000 description 1
- 229960002747 betacarotene Drugs 0.000 description 1
- 229910052626 biotite Inorganic materials 0.000 description 1
- 229940073609 bismuth oxychloride Drugs 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- HRBZRZSCMANEHQ-UHFFFAOYSA-L calcium;hexadecanoate Chemical compound [Ca+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O HRBZRZSCMANEHQ-UHFFFAOYSA-L 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- JBTHDAVBDKKSRW-UHFFFAOYSA-N chembl1552233 Chemical compound CC1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 JBTHDAVBDKKSRW-UHFFFAOYSA-N 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 1
- 229910000152 cobalt phosphate Inorganic materials 0.000 description 1
- LFSBSHDDAGNCTM-UHFFFAOYSA-N cobalt(2+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[Ti+4].[Co+2] LFSBSHDDAGNCTM-UHFFFAOYSA-N 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 229940113120 dipropylene glycol Drugs 0.000 description 1
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
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- 238000001694 spray drying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229940105125 zinc myristate Drugs 0.000 description 1
- GBFLQPIIIRJQLU-UHFFFAOYSA-L zinc;tetradecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O GBFLQPIIIRJQLU-UHFFFAOYSA-L 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
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Abstract
Description
本発明は、ファンデーションなどのメイクアップ化粧料、サンスクリーン化粧料又は乳液などの化粧料に配合して好適な表面被覆粉体、及びその粉体を配合した化粧料に関するものである。 The present invention relates to a surface coating powder suitable for blending into makeup cosmetics such as foundations, cosmetics such as sunscreen cosmetics or emulsions, and cosmetics blended with the powders.
従来、ファンデーション、アイシャドー、ほほ紅などのメイクアップ化粧料や、サンスクリーン化粧料や、乳液などに配合される粉体は、肌への付着性や、粉体の感触を良くするなどの目的で、顔料粉体の表面に各種の化合物を被覆させた表面被覆粉体が用いられている。 Traditionally, makeup cosmetics such as foundations, eye shadows, and cheeks, sunscreen cosmetics, and powders blended into emulsions are intended to improve skin adhesion and powder feel. Thus, surface-coated powders in which various compounds are coated on the surface of the pigment powder are used.
表面被覆粉体としては、シリコーン処理（特許文献１）、金属石鹸処理等の疎水化処理粉体（特許文献２）、ヒアルロン酸処理（特許文献３）、アミノ酸処理（特許文献４）等の親水化処理粉体等が知られている。 Examples of the surface coating powder include hydrophilicity such as silicone treatment (Patent Document 1), hydrophobized powder such as metal soap treatment (Patent Document 2), hyaluronic acid treatment (Patent Document 3), and amino acid treatment (Patent Document 4). Chemically treated powders and the like are known.
従来の処理粉体は皮膚が乾燥しやすい、ムラ付きしやすい等の課題があった。 Conventional processed powders have problems such as easy skin drying and unevenness.
本発明は、前述のような問題点に鑑みてなされたもので、粉体にスキンケア効果を付与するとともに、肌に均一に塗布することができ、くすみや色ムラが少ない表面被覆粉体を提供することを目的とするものである。 The present invention has been made in view of the above-mentioned problems, and provides a surface-coated powder that imparts a skin care effect to the powder and can be uniformly applied to the skin with less dullness and color unevenness. It is intended to do.
本発明者らは、かかる課題について鋭意検討した結果、本発明を完成するにいたった。すなわち本発明は、表面を多価アルコールで被覆した表面被覆粉体、及びかかる表面被覆粉体を配合した化粧料に関する。 As a result of intensive studies on such problems, the present inventors have completed the present invention. That is, the present invention relates to a surface-coated powder whose surface is coated with a polyhydric alcohol, and a cosmetic containing such a surface-coated powder.
本発明の表面被覆粉体は、粉体にスキンケア効果を付与するとともに、肌に均一に塗布することができ、くすみや色ムラが少ないという効果を発揮する。 The surface-coated powder of the present invention imparts a skin care effect to the powder, can be uniformly applied to the skin, and exhibits the effect of less dullness and uneven color.
以下、本発明を実施するための形態について詳細に説明する。ただし、本発明は以下の実施形態に限定されるものではない。 Hereinafter, embodiments for carrying out the present invention will be described in detail. However, the present invention is not limited to the following embodiments.
粉体の表面を被覆する多価アルコールとしては特に限定されないが、グリセリン、ジグリセリン、１，３−ブチレングリコール、ジプロピレングリコール、ペンチレングリコール、ヘキシレングリコールから選択される１種を単独で、若しくは２種以上を併用して用いることが好ましい。これらの多価アルコールの中でも特にグリセリンのみを用いることが、効果と価格の面から好ましい。 Although it does not specifically limit as polyhydric alcohol which coat | covers the surface of powder, One type selected from glycerol, diglycerol, 1, 3- butylene glycol, dipropylene glycol, pentylene glycol, hexylene glycol alone, Or it is preferable to use 2 or more types in combination. Among these polyhydric alcohols, it is particularly preferable to use only glycerin from the viewpoint of effect and price.
本発明により表面を被覆処理される粉体としては、特に限定されないが、特に化粧料用の粉体を用いることが好ましい。かかる粉体としては、、酸化チタン、ベンガラ、黄酸化鉄、黒酸化鉄、酸化亜鉛、酸化セリウム、マンガンバイオレット、コバルトバイオレット、酸化クロム、水酸化クロム、チタン酸コバルト、群青、紺青、酸化マグネシウム、酸化ジルコニウム、タルク、カオリン、絹雲母（セリサイト）、白雲母、金雲母、合成雲母、紅雲母、黒雲母、パーミキュライト、シリカ、炭酸カルシウム、炭酸マグネシウム、ケイ酸マグネシウム、ケイ酸アルミニウム、ケイ酸バリウム、ケイ酸カルシウム、硫酸バリウム、硫酸カルシウム、リン酸カルシウム、ヒドロキシアパタイト、窒化ホウ素、パール顔料、オキシ塩化ビスマスなどの無機顔料や、赤色３号、赤色１０号、赤色１０６号、赤色２０１号、赤色２０２号、赤色２０４号、赤色２０５号、赤色２２０号、赤色２２６号、赤色２２７号、赤色２２８号、赤色２３０号、赤色４０１号、赤色４０５号、赤色５０５号、黄色４号、黄色５号、黄色２０２号、黄色２０３号、黄色２０５号、黄色４０１号、橙色２０１号、橙色２０３号、橙色２０４号、橙色２０５号、橙色２０６号、橙色２０７号、青色１号、青色２号、青色２０１号、青色４０４号、緑色３号、緑色２０１号、緑色２０４号、緑色２０５号などの有機色素や、クロロフィルやβ−カロチンなどの天然色素や、ミリスチン酸亜鉛、パルミチン酸カルシウム、ステアリン酸アルミニウムなどの金属石鹸や、ナイロンパウダー、セルロースパウダー、ポリエチレンパウダー、ポリメタクリル酸メチルパウダー、ポリスチレンパウダー、アクリルパウダー、シリコンパウダー等の有機粉体等が例示される。 The powder whose surface is coated according to the present invention is not particularly limited, but it is particularly preferable to use a powder for cosmetics. Such powders include titanium oxide, red iron oxide, yellow iron oxide, black iron oxide, zinc oxide, cerium oxide, manganese violet, cobalt violet, chromium oxide, chromium hydroxide, cobalt titanate, ultramarine, bitumen, magnesium oxide, Zirconium oxide, talc, kaolin, sericite, muscovite, phlogopite, synthetic mica, sauroite, biotite, permiculite, silica, calcium carbonate, magnesium carbonate, magnesium silicate, aluminum silicate, barium silicate , Calcium silicate, barium sulfate, calcium sulfate, calcium phosphate, hydroxyapatite, boron nitride, pearl pigment, inorganic pigments such as bismuth oxychloride, red 3, red 10, red 106, red 201, red 202 , Red 204, red 205, red No. 20, Red 226, Red 227, Red 228, Red 230, Red 401, Red 405, Red 505, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Yellow 205 , Yellow 401, Orange 201, Orange 203, Orange 204, Orange 205, Orange 206, Orange 206, Orange 207, Blue 1, Blue 2, Blue 201, Blue 404, Green 3, Green Organic dyes such as 201, green 204 and green 205, natural dyes such as chlorophyll and β-carotene, metal soaps such as zinc myristate, calcium palmitate and aluminum stearate, nylon powder, cellulose powder, Organics such as polyethylene powder, polymethyl methacrylate powder, polystyrene powder, acrylic powder, silicon powder Examples thereof include powder.
粉体としては、本発明のスキンケア効果の点から、酸化チタン、酸化亜鉛、ベンガラ、黄酸化鉄、黒酸化鉄、酸化亜鉛、タルク、カオリン、絹雲母、白雲母、金雲母、合成雲母から選択される１種又は２種以上の粉体が好ましく、さらには、酸化チタン、特に顔料級酸化チタンが好ましい。 From the viewpoint of the skin care effect of the present invention, the powder is selected from titanium oxide, zinc oxide, bengara, yellow iron oxide, black iron oxide, zinc oxide, talc, kaolin, sericite, muscovite, phlogopite, and synthetic mica. One or two or more kinds of powders are preferable, and titanium oxide, particularly pigment grade titanium oxide is more preferable.
粉体の表面被覆処理に用いられる多価アルコールの質量比は、処理される粉体に対して０.１〜５０質量部とするのが好ましい。前記質量比が０．１質量部未満であると肌への均一な付着性が充分でない場合がある。５０質量部を越えると粉体が凝集しやすくなるため、化粧料としては適さない場合がある。 The mass ratio of the polyhydric alcohol used for the powder surface coating treatment is preferably 0.1 to 50 parts by mass with respect to the powder to be treated. If the mass ratio is less than 0.1 parts by mass, uniform adhesion to the skin may not be sufficient. If it exceeds 50 parts by mass, the powder tends to agglomerate and may not be suitable as a cosmetic.
次に、本発明の表面被覆粉体の製造方法について説明する。表面被覆方法としては特に限定されず常法により表面被覆することができる。例えば、表面被覆される顔料粉体を適切なミキサー中で撹拌し、多価アルコールをそのまま、若しくはエタノール、イソプロピルアルコール、イソブタノール等のアルコール類、トルエン、ｎ−ヘキサン、シクロヘキサン等の炭化水素系有機溶剤、アセトン、酢酸エチル、酢酸ブチル等の極性有機溶剤などに溶解した溶液を、液滴下又はスプレー噴霧にて加え撹拌した後、必要に応じて有機溶剤を完全に蒸発除去し、その後、粉体を粉砕した後、８０〜２００℃に加熱熟成させることによって、表面被覆処理を行うことができる。 Next, the manufacturing method of the surface coating powder of this invention is demonstrated. The surface coating method is not particularly limited, and the surface coating can be performed by a conventional method. For example, the pigment powder to be surface-coated is stirred in a suitable mixer, and the polyhydric alcohol is used as it is, or alcohols such as ethanol, isopropyl alcohol, and isobutanol, and hydrocarbon-based organic materials such as toluene, n-hexane, and cyclohexane. A solution dissolved in a polar organic solvent such as solvent, acetone, ethyl acetate, butyl acetate or the like is added under a drop or spray spraying and stirred, and then the organic solvent is completely evaporated and removed as necessary. After crushing, the surface coating treatment can be performed by heating and aging at 80 to 200 ° C.
粉体の混合分散に用いる機器としては、溶液の濃度や粘度などに応じて適切な方法を選択することができる。好適な例としては、撹拌羽根を有した反応槽や、ディスパー、ヘンシェルミキサー、レディゲミキサー、ニーダー、Ｖ型混合機、ロールミル、ビーズミル、２軸混練機等のブレンダーによる方法や、水溶液と顔料を加熱空気中に噴霧して水分を一気に除去するスプレードライの方法などを選択することができる。また、粉砕を行う場合においては、ハンマーミル、ボールミル、サンドミル、ジェットミル等の通常の粉砕機を用いることができる。これらいずれの粉砕機によっても同等の品質のものが得られるため、特に限定されるものではない。 As an apparatus used for mixing and dispersing the powder, an appropriate method can be selected according to the concentration and viscosity of the solution. Suitable examples include a reaction vessel having a stirring blade, a method using a blender such as a disper, a Henschel mixer, a Redige mixer, a kneader, a V-type mixer, a roll mill, a bead mill, a biaxial kneader, an aqueous solution and a pigment. A spray drying method in which moisture is removed at once by spraying into heated air can be selected. When pulverization is performed, a normal pulverizer such as a hammer mill, a ball mill, a sand mill, or a jet mill can be used. Since any of these pulverizers can obtain the same quality, it is not particularly limited.
本発明の表面被覆粉体の化粧料への配合量としては、０．５〜９０質量％が好ましい。この配合量が０．５質量％未満では、表面被覆粉体のスキンケア効果が発揮されにくくなる傾向がある。一方、９０質量％を超える複合粉体を配合すると、製剤化が困難になる傾向がある。 As a compounding quantity to the cosmetics of the surface coating powder of this invention, 0.5-90 mass% is preferable. When the blending amount is less than 0.5% by mass, the skin care effect of the surface coating powder tends to be difficult to be exhibited. On the other hand, when a composite powder exceeding 90% by mass is blended, formulation tends to be difficult.
本発明の化粧料の形態としては、ルースパウダー状、プレスパウダー状、スティック状、クリーム状、乳液状、液状、多層分離状のいずれの剤型でも採用できる。 As the form of the cosmetic of the present invention, any dosage form of loose powder, press powder, stick, cream, emulsion, liquid, and multilayer separation can be employed.
本発明の化粧料には通常化粧料に用いられる成分を配合することができる。かかる成分としては、粉体、界面活性剤、油剤、高分子、水性成分、防腐剤、美容成分、香料等が挙げられる。 In the cosmetic of the present invention, components usually used in cosmetics can be blended. Examples of such components include powders, surfactants, oils, polymers, aqueous components, preservatives, cosmetic ingredients, and fragrances.
以下、実施例を挙げて本発明についてより具体的に説明する。ただし、本発明は以下の実施例に限定されるものではない。 Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to the following examples.
［実施例１］
顔料級酸化チタン１０００質量部をブレンダーに投入する。続いてイソプロピルアルコール１００質量部にグリセリンを１１１．１質量部を溶解した溶液を滴下混合し、酸化チタンとよく混合した。その後、ブレンダー内を加熱及び減圧し、イソプロピルアルコールを除去した。被覆された粉体をブレンダーから取り出し、粉砕して加熱処理を行い、グリセリンを１０質量％被覆した酸化チタンを得た。
[Example 1]
1000 parts by mass of pigment grade titanium oxide is put into a blender. Subsequently, a solution in which 111.1 parts by mass of glycerin was dissolved in 100 parts by mass of isopropyl alcohol was added dropwise and mixed well with titanium oxide. Thereafter, the inside of the blender was heated and decompressed to remove isopropyl alcohol. The coated powder was taken out of the blender, pulverized, and heat-treated to obtain titanium oxide coated with 10% by mass of glycerin.
［比較例１］
市販の２％ジメチコン処理酸化チタン（商品名ＳＡ−チタン ＣＲ−５０（１００％）、三好化成製）を比較例１として用いた。
[Comparative Example 1]
A commercially available 2% dimethicone-treated titanium oxide (trade name: SA-titanium CR-50 (100%), manufactured by Miyoshi Kasei) was used as Comparative Example 1.
［比較例２］
市販の未処理顔料級酸化チタン（商品名酸化チタンＣＲ−５０、石原産業製）を比較例２として用いた。
[Comparative Example 2]
Commercially available untreated pigment grade titanium oxide (trade name titanium oxide CR-50, manufactured by Ishihara Sangyo) was used as Comparative Example 2.
［スキンケア効果評価］
前腕内側に、実施例１、比較例１をそれぞれ２ｍｇ／ｃｍ2となるように塗布し、塗布前、塗布直後、塗布３０分後の経皮水分損失（ＴＥＷＬ）をＶａｐｏｍｅｔｅｒ（Ｄｅｌｆｉｎ ｔｅｃｈｎｏｌｏｇｉｅｓ製）を用いて測定した。測定は３か所測定した平均値で示した。塗布前を１００とした相対値にて結果を算出し、表１に示した。
[Skin care effect evaluation]
Example 1 and Comparative Example 1 were applied to the inner side of the forearm so as to be 2 mg / cm 2 , respectively, and Vapometer (manufactured by Delfin technologies) was used to measure transdermal water loss (TEWL) 30 minutes after application, immediately after application, and 30 minutes after application. And measured. The measurement was shown as an average value measured at three locations. The results were calculated as relative values with the value before application as 100 and are shown in Table 1.
表１に示した通り、比較例１塗布群においては、塗布によりＴＥＷＬへの影響は認められなかった。これに対し実施例１塗布群では、塗布直後からＴＥＷＬの低下が認められ、３０分後には顕著にＴＥＷＬが減少していた。ＴＥＷＬは、肌荒れの改善状態を示す指標（化粧品事典第４３９ページ、丸善出版、２００３年発行）であり、ＴＥＷＬの低下は肌荒れ状態が改善されたことを示すものである。従って、本発明の実施例は、肌荒れ改善効果、すなわち高いスキンケア効果を発揮するものである。 As shown in Table 1, in the application group of Comparative Example 1, no effect on TEWL was observed by application. In contrast, in the application group of Example 1, a decrease in TEWL was observed immediately after the application, and the TEWL was significantly decreased after 30 minutes. TEWL is an index (Cosmetics Encyclopedia page 439, Maruzen Publishing, published in 2003) indicating an improved state of rough skin, and a decrease in TEWL indicates that the rough skin state has been improved. Therefore, the Example of this invention exhibits the rough skin improvement effect, ie, the high skin care effect.
［付着性評価］
前腕内側に実施例１、比較例１をそれぞれ２ｍｇ／ｃｍ2となるように塗布し、塗布状態をマイクロスコープで観察した。その結果、比較例１は、皮膚に塗布すると、皮溝に極在した状態で塗布されていたのに対し、実施例１は、皮丘にとどまり均一に塗布されていた。
[Adhesion evaluation]
Example 1 and Comparative Example 1 were each applied to the inner side of the forearm so as to be 2 mg / cm 2, and the application state was observed with a microscope. As a result, when Comparative Example 1 was applied to the skin, it was applied in a state of being extremely present in the skin groove, whereas Example 1 remained uniformly on the skin and applied uniformly.
［反射特性評価］
肌色の人工皮革の表面に実施例１、比較例１、２を塗布し、変角測色計（型番ＧＣ５０００、日本電色工業製）を用いて反射特性の評価を行った。その結果、図１に示した通り、本発明の実施例１は比較例１、２より彩度が高く、くすみやムラが少ないことが示された。
[Evaluation of reflection characteristics]
Carried on the surface of the skin color of the artificial leather Example 1, Comparative Examples 1 and 2 was applied and evaluated for reflection characteristics using a variable angle colorimeter (Model GC5000, Nippon Denshoku Kogyo). As a result, as shown in FIG. 1, Example 1 of the present invention showed higher saturation than Comparative Examples 1 and 2, and less dullness and unevenness.
本発明の実施例１を配合した化粧料の実施例を表２に示す。 Table 2 shows examples of cosmetics formulated with Example 1 of the present invention.
Claims (4)
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| JPS5817433A (en) * | 1981-07-24 | 1983-02-01 | Fuji Photo Film Co Ltd | Manufacture of resin coated paper for photography |
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