JP2017189119A - Fruit juice-containing beverage having suppressed photodegradation - Google Patents
Fruit juice-containing beverage having suppressed photodegradation Download PDFInfo
- Publication number
- JP2017189119A JP2017189119A JP2016079042A JP2016079042A JP2017189119A JP 2017189119 A JP2017189119 A JP 2017189119A JP 2016079042 A JP2016079042 A JP 2016079042A JP 2016079042 A JP2016079042 A JP 2016079042A JP 2017189119 A JP2017189119 A JP 2017189119A
- Authority
- JP
- Japan
- Prior art keywords
- fruit juice
- beverage
- beverages
- containing beverage
- photodegradation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000013361 beverage Nutrition 0.000 title claims abstract description 180
- 235000015203 fruit juice Nutrition 0.000 title claims abstract description 108
- 238000001782 photodegradation Methods 0.000 title claims abstract description 35
- JMGZEFIQIZZSBH-UHFFFAOYSA-N Bioquercetin Natural products CC1OC(OCC(O)C2OC(OC3=C(Oc4cc(O)cc(O)c4C3=O)c5ccc(O)c(O)c5)C(O)C2O)C(O)C(O)C1O JMGZEFIQIZZSBH-UHFFFAOYSA-N 0.000 claims abstract description 47
- IVTMALDHFAHOGL-UHFFFAOYSA-N eriodictyol 7-O-rutinoside Natural products OC1C(O)C(O)C(C)OC1OCC1C(O)C(O)C(O)C(OC=2C=C3C(C(C(O)=C(O3)C=3C=C(O)C(O)=CC=3)=O)=C(O)C=2)O1 IVTMALDHFAHOGL-UHFFFAOYSA-N 0.000 claims abstract description 46
- FDRQPMVGJOQVTL-UHFFFAOYSA-N quercetin rutinoside Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC=2C(C3=C(O)C=C(O)C=C3OC=2C=2C=C(O)C(O)=CC=2)=O)O1 FDRQPMVGJOQVTL-UHFFFAOYSA-N 0.000 claims abstract description 46
- 235000005493 rutin Nutrition 0.000 claims abstract description 46
- IKGXIBQEEMLURG-BKUODXTLSA-N rutin Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@@H]1OC[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](OC=2C(C3=C(O)C=C(O)C=C3OC=2C=2C=C(O)C(O)=CC=2)=O)O1 IKGXIBQEEMLURG-BKUODXTLSA-N 0.000 claims abstract description 46
- ALABRVAAKCSLSC-UHFFFAOYSA-N rutin Natural products CC1OC(OCC2OC(O)C(O)C(O)C2O)C(O)C(O)C1OC3=C(Oc4cc(O)cc(O)c4C3=O)c5ccc(O)c(O)c5 ALABRVAAKCSLSC-UHFFFAOYSA-N 0.000 claims abstract description 46
- 229960004555 rutoside Drugs 0.000 claims abstract description 46
- 235000020971 citrus fruits Nutrition 0.000 claims abstract description 42
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims abstract description 41
- 102000004190 Enzymes Human genes 0.000 claims abstract description 35
- 108090000790 Enzymes Proteins 0.000 claims abstract description 35
- 229930003799 tocopherol Natural products 0.000 claims abstract description 34
- 239000011732 tocopherol Substances 0.000 claims abstract description 34
- 235000010384 tocopherol Nutrition 0.000 claims abstract description 33
- 229960001295 tocopherol Drugs 0.000 claims abstract description 33
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 claims abstract description 19
- 241000207199 Citrus Species 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 35
- 235000012680 lutein Nutrition 0.000 claims description 34
- KBPHJBAIARWVSC-RGZFRNHPSA-N lutein Chemical compound C([C@H](O)CC=1C)C(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\[C@H]1C(C)=C[C@H](O)CC1(C)C KBPHJBAIARWVSC-RGZFRNHPSA-N 0.000 claims description 34
- 229960005375 lutein Drugs 0.000 claims description 34
- ORAKUVXRZWMARG-WZLJTJAWSA-N lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C ORAKUVXRZWMARG-WZLJTJAWSA-N 0.000 claims description 34
- 239000001656 lutein Substances 0.000 claims description 34
- KBPHJBAIARWVSC-XQIHNALSSA-N trans-lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C KBPHJBAIARWVSC-XQIHNALSSA-N 0.000 claims description 34
- FJHBOVDFOQMZRV-XQIHNALSSA-N xanthophyll Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C=C(C)C(O)CC2(C)C FJHBOVDFOQMZRV-XQIHNALSSA-N 0.000 claims description 34
- 238000006731 degradation reaction Methods 0.000 claims description 26
- 230000015556 catabolic process Effects 0.000 claims description 24
- 239000003112 inhibitor Substances 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 230000002401 inhibitory effect Effects 0.000 claims description 13
- 238000009826 distribution Methods 0.000 abstract description 11
- 229940088598 enzyme Drugs 0.000 abstract description 9
- 230000001629 suppression Effects 0.000 abstract description 7
- 238000002156 mixing Methods 0.000 abstract description 3
- 238000004321 preservation Methods 0.000 abstract description 2
- 230000006866 deterioration Effects 0.000 description 56
- 239000000796 flavoring agent Substances 0.000 description 55
- 235000019634 flavors Nutrition 0.000 description 50
- 235000019645 odor Nutrition 0.000 description 13
- 239000000284 extract Substances 0.000 description 12
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 11
- 238000003860 storage Methods 0.000 description 11
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 10
- 229940043350 citral Drugs 0.000 description 10
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 10
- QAIPRVGONGVQAS-DUXPYHPUSA-N trans-caffeic acid Chemical compound OC(=O)\C=C\C1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-DUXPYHPUSA-N 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 235000013399 edible fruits Nutrition 0.000 description 8
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 7
- 239000003963 antioxidant agent Substances 0.000 description 7
- 230000003078 antioxidant effect Effects 0.000 description 7
- 235000006708 antioxidants Nutrition 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- PZIRUHCJZBGLDY-UHFFFAOYSA-N Caffeoylquinic acid Natural products CC(CCC(=O)C(C)C1C(=O)CC2C3CC(O)C4CC(O)CCC4(C)C3CCC12C)C(=O)O PZIRUHCJZBGLDY-UHFFFAOYSA-N 0.000 description 6
- REFJWTPEDVJJIY-UHFFFAOYSA-N Quercetin Chemical compound C=1C(O)=CC(O)=C(C(C=2O)=O)C=1OC=2C1=CC=C(O)C(O)=C1 REFJWTPEDVJJIY-UHFFFAOYSA-N 0.000 description 6
- -1 camferol Chemical compound 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- ACEAELOMUCBPJP-UHFFFAOYSA-N (E)-3,4,5-trihydroxycinnamic acid Natural products OC(=O)C=CC1=CC(O)=C(O)C(O)=C1 ACEAELOMUCBPJP-UHFFFAOYSA-N 0.000 description 5
- KSEBMYQBYZTDHS-HWKANZROSA-M (E)-Ferulic acid Natural products COC1=CC(\C=C\C([O-])=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-M 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 5
- 235000004883 caffeic acid Nutrition 0.000 description 5
- 229940074360 caffeic acid Drugs 0.000 description 5
- QAIPRVGONGVQAS-UHFFFAOYSA-N cis-caffeic acid Natural products OC(=O)C=CC1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-UHFFFAOYSA-N 0.000 description 5
- 235000001785 ferulic acid Nutrition 0.000 description 5
- KSEBMYQBYZTDHS-UHFFFAOYSA-N ferulic acid Natural products COC1=CC(C=CC(O)=O)=CC=C1O KSEBMYQBYZTDHS-UHFFFAOYSA-N 0.000 description 5
- KSEBMYQBYZTDHS-HWKANZROSA-N ferulic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-N 0.000 description 5
- 229940114124 ferulic acid Drugs 0.000 description 5
- 235000013305 food Nutrition 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- QURCVMIEKCOAJU-UHFFFAOYSA-N trans-isoferulic acid Natural products COC1=CC=C(C=CC(O)=O)C=C1O QURCVMIEKCOAJU-UHFFFAOYSA-N 0.000 description 5
- CWVRJTMFETXNAD-FWCWNIRPSA-N 3-O-Caffeoylquinic acid Natural products O[C@H]1[C@@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-FWCWNIRPSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- CWVRJTMFETXNAD-KLZCAUPSSA-N Neochlorogenin-saeure Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O CWVRJTMFETXNAD-KLZCAUPSSA-N 0.000 description 4
- 229930003427 Vitamin E Natural products 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229940074393 chlorogenic acid Drugs 0.000 description 4
- 235000001368 chlorogenic acid Nutrition 0.000 description 4
- FFQSDFBBSXGVKF-KHSQJDLVSA-N chlorogenic acid Natural products O[C@@H]1C[C@](O)(C[C@@H](CC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O FFQSDFBBSXGVKF-KHSQJDLVSA-N 0.000 description 4
- CWVRJTMFETXNAD-JUHZACGLSA-N chlorogenic acid Chemical compound O[C@@H]1[C@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-JUHZACGLSA-N 0.000 description 4
- BMRSEYFENKXDIS-KLZCAUPSSA-N cis-3-O-p-coumaroylquinic acid Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)cc2)[C@@H]1O)C(=O)O BMRSEYFENKXDIS-KLZCAUPSSA-N 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 4
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 239000011709 vitamin E Substances 0.000 description 4
- 235000019165 vitamin E Nutrition 0.000 description 4
- 229940046009 vitamin E Drugs 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- ZVOLCUVKHLEPEV-UHFFFAOYSA-N Quercetagetin Natural products C1=C(O)C(O)=CC=C1C1=C(O)C(=O)C2=C(O)C(O)=C(O)C=C2O1 ZVOLCUVKHLEPEV-UHFFFAOYSA-N 0.000 description 3
- HWTZYBCRDDUBJY-UHFFFAOYSA-N Rhynchosin Natural products C1=C(O)C(O)=CC=C1C1=C(O)C(=O)C2=CC(O)=C(O)C=C2O1 HWTZYBCRDDUBJY-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000012675 alcoholic extract Substances 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 description 3
- 229930014626 natural product Natural products 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 238000004445 quantitative analysis Methods 0.000 description 3
- 235000005875 quercetin Nutrition 0.000 description 3
- 229960001285 quercetin Drugs 0.000 description 3
- 239000003352 sequestering agent Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 235000020238 sunflower seed Nutrition 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- PFTAWBLQPZVEMU-ZFWWWQNUSA-N (+)-epicatechin Natural products C1([C@@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-ZFWWWQNUSA-N 0.000 description 2
- WMBWREPUVVBILR-WIYYLYMNSA-N (-)-Epigallocatechin-3-o-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=C(O)C=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-WIYYLYMNSA-N 0.000 description 2
- PFTAWBLQPZVEMU-UKRRQHHQSA-N (-)-epicatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-UKRRQHHQSA-N 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- PFPQMWRASYNLMZ-LGIMBNBCSA-N 2-(3,4-dihydroxyphenyl)-3-[(2s,3r,4r,5s,6r)-3,4-dihydroxy-5-[(2r,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-6-[[(2r,3r,4r,5r,6s)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxymethyl]oxan-2-yl]oxy-5,7-dihydroxychromen-4-one Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1OC[C@@H]1[C@@H](O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@@H](O)[C@H](OC=2C(C3=C(O)C=C(O)C=C3OC=2C=2C=C(O)C(O)=CC=2)=O)O1 PFPQMWRASYNLMZ-LGIMBNBCSA-N 0.000 description 2
- COCYGNDCWFKTMF-UHFFFAOYSA-N 7,8-dihydroxyflavone Chemical compound OC=1C(O)=CC=C(C(C=2)=O)C=1OC=2C1=CC=CC=C1 COCYGNDCWFKTMF-UHFFFAOYSA-N 0.000 description 2
- 235000003826 Artemisia Nutrition 0.000 description 2
- 235000003261 Artemisia vulgaris Nutrition 0.000 description 2
- 235000004936 Bromus mango Nutrition 0.000 description 2
- 235000005881 Calendula officinalis Nutrition 0.000 description 2
- 244000248349 Citrus limon Species 0.000 description 2
- WMBWREPUVVBILR-UHFFFAOYSA-N GCG Natural products C=1C(O)=C(O)C(O)=CC=1C1OC2=CC(O)=CC(O)=C2CC1OC(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 235000014826 Mangifera indica Nutrition 0.000 description 2
- 240000007228 Mangifera indica Species 0.000 description 2
- 244000183278 Nephelium litchi Species 0.000 description 2
- 235000008673 Persea americana Nutrition 0.000 description 2
- 244000025272 Persea americana Species 0.000 description 2
- 235000003421 Plantago ovata Nutrition 0.000 description 2
- 244000134552 Plantago ovata Species 0.000 description 2
- 235000009827 Prunus armeniaca Nutrition 0.000 description 2
- 244000018633 Prunus armeniaca Species 0.000 description 2
- 239000009223 Psyllium Substances 0.000 description 2
- 235000009184 Spondias indica Nutrition 0.000 description 2
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 235000013334 alcoholic beverage Nutrition 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 244000030166 artemisia Species 0.000 description 2
- 235000009052 artemisia Nutrition 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 235000021466 carotenoid Nutrition 0.000 description 2
- 150000001747 carotenoids Chemical class 0.000 description 2
- RTIXKCRFFJGDFG-UHFFFAOYSA-N chrysin Chemical compound C=1C(O)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=CC=C1 RTIXKCRFFJGDFG-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- XMOCLSLCDHWDHP-IUODEOHRSA-N epi-Gallocatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-IUODEOHRSA-N 0.000 description 2
- 235000012734 epicatechin Nutrition 0.000 description 2
- LPTRNLNOHUVQMS-UHFFFAOYSA-N epicatechin Natural products Cc1cc(O)cc2OC(C(O)Cc12)c1ccc(O)c(O)c1 LPTRNLNOHUVQMS-UHFFFAOYSA-N 0.000 description 2
- 229940030275 epigallocatechin gallate Drugs 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 235000004515 gallic acid Nutrition 0.000 description 2
- 229940074391 gallic acid Drugs 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004128 high performance liquid chromatography Methods 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000419 plant extract Substances 0.000 description 2
- 235000021018 plums Nutrition 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- GWTUHAXUUFROTF-UHFFFAOYSA-N pseudochlorogenic acid Natural products C1C(O)C(O)C(O)CC1(C(O)=O)OC(=O)C=CC1=CC=C(O)C(O)=C1 GWTUHAXUUFROTF-UHFFFAOYSA-N 0.000 description 2
- 229940070687 psyllium Drugs 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 229920001864 tannin Polymers 0.000 description 2
- 235000018553 tannin Nutrition 0.000 description 2
- 239000001648 tannin Substances 0.000 description 2
- 235000013616 tea Nutrition 0.000 description 2
- YKFLAYDHMOASIY-UHFFFAOYSA-N γ-terpinene Chemical compound CC(C)C1=CCC(C)=CC1 YKFLAYDHMOASIY-UHFFFAOYSA-N 0.000 description 2
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 description 1
- LSHVYAFMTMFKBA-TZIWHRDSSA-N (-)-epicatechin-3-O-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=CC=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 LSHVYAFMTMFKBA-TZIWHRDSSA-N 0.000 description 1
- CWVRJTMFETXNAD-BMNNCGMMSA-N (1s,3r,4s,5r)-3-[(e)-3-(3,4-dihydroxyphenyl)prop-2-enoyl]oxy-1,4,5-trihydroxycyclohexane-1-carboxylic acid Chemical compound O[C@H]1[C@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-BMNNCGMMSA-N 0.000 description 1
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 description 1
- 239000001100 (2S)-5,7-dihydroxy-2-(3-hydroxy-4-methoxyphenyl)chroman-4-one Substances 0.000 description 1
- JPFCOVZKLAXXOE-XBNSMERZSA-N (3r)-2-(3,5-dihydroxy-4-methoxyphenyl)-8-[(2r,3r,4r)-3,5,7-trihydroxy-2-(4-hydroxyphenyl)-3,4-dihydro-2h-chromen-4-yl]-3,4-dihydro-2h-chromene-3,5,7-triol Chemical compound C1=C(O)C(OC)=C(O)C=C1C1[C@H](O)CC(C(O)=CC(O)=C2[C@H]3C4=C(O)C=C(O)C=C4O[C@@H]([C@@H]3O)C=3C=CC(O)=CC=3)=C2O1 JPFCOVZKLAXXOE-XBNSMERZSA-N 0.000 description 1
- WVXRAFOPTSTNLL-NKWVEPMBSA-N 2',3'-dideoxyadenosine Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@H]1CC[C@@H](CO)O1 WVXRAFOPTSTNLL-NKWVEPMBSA-N 0.000 description 1
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 1
- NYCXYKOXLNBYID-UHFFFAOYSA-N 5,7-Dihydroxychromone Natural products O1C=CC(=O)C=2C1=CC(O)=CC=2O NYCXYKOXLNBYID-UHFFFAOYSA-N 0.000 description 1
- WWGFXSLWIRYIBP-UHFFFAOYSA-N 7,8-dihydroxy-4H-chromen-4-one Natural products O1C=CC(=O)C=2C1=C(O)C(O)=CC=2 WWGFXSLWIRYIBP-UHFFFAOYSA-N 0.000 description 1
- 241000143060 Americamysis bahia Species 0.000 description 1
- 244000144725 Amygdalus communis Species 0.000 description 1
- 235000007119 Ananas comosus Nutrition 0.000 description 1
- 244000099147 Ananas comosus Species 0.000 description 1
- 244000003416 Asparagus officinalis Species 0.000 description 1
- 235000005340 Asparagus officinalis Nutrition 0.000 description 1
- 235000000832 Ayote Nutrition 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 1
- 235000017647 Brassica oleracea var italica Nutrition 0.000 description 1
- 240000003259 Brassica oleracea var. botrytis Species 0.000 description 1
- HFDJPVYMPCPGIZ-UHFFFAOYSA-N C=1C(O)=CC=C(C(C=2)=O)C=1OC=2C1=CC=CC=C1.C=1C(=O)C2=CC(O)=CC=C2OC=1C1=CC=CC=C1 Chemical compound C=1C(O)=CC=C(C(C=2)=O)C=1OC=2C1=CC=CC=C1.C=1C(=O)C2=CC(O)=CC=C2OC=1C1=CC=CC=C1 HFDJPVYMPCPGIZ-UHFFFAOYSA-N 0.000 description 1
- 240000001432 Calendula officinalis Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 241001672694 Citrus reticulata Species 0.000 description 1
- 240000000560 Citrus x paradisi Species 0.000 description 1
- 235000009917 Crataegus X brevipes Nutrition 0.000 description 1
- 235000013204 Crataegus X haemacarpa Nutrition 0.000 description 1
- 235000009685 Crataegus X maligna Nutrition 0.000 description 1
- 235000009444 Crataegus X rubrocarnea Nutrition 0.000 description 1
- 235000009486 Crataegus bullatus Nutrition 0.000 description 1
- 235000017181 Crataegus chrysocarpa Nutrition 0.000 description 1
- 235000009682 Crataegus limnophila Nutrition 0.000 description 1
- 235000004423 Crataegus monogyna Nutrition 0.000 description 1
- 240000000171 Crataegus monogyna Species 0.000 description 1
- 235000002313 Crataegus paludosa Nutrition 0.000 description 1
- 235000009840 Crataegus x incaedua Nutrition 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- LSHVYAFMTMFKBA-UHFFFAOYSA-N ECG Natural products C=1C=C(O)C(O)=CC=1C1OC2=CC(O)=CC(O)=C2CC1OC(=O)C1=CC(O)=C(O)C(O)=C1 LSHVYAFMTMFKBA-UHFFFAOYSA-N 0.000 description 1
- 235000009419 Fagopyrum esculentum Nutrition 0.000 description 1
- 240000008620 Fagopyrum esculentum Species 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000017048 Garcinia mangostana Nutrition 0.000 description 1
- 240000006053 Garcinia mangostana Species 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 102000051366 Glycosyltransferases Human genes 0.000 description 1
- 108700023372 Glycosyltransferases Proteins 0.000 description 1
- 235000005206 Hibiscus Nutrition 0.000 description 1
- 235000007185 Hibiscus lunariifolius Nutrition 0.000 description 1
- 244000284380 Hibiscus rosa sinensis Species 0.000 description 1
- 235000017309 Hypericum perforatum Nutrition 0.000 description 1
- 244000141009 Hypericum perforatum Species 0.000 description 1
- XMOCLSLCDHWDHP-UHFFFAOYSA-N L-Epigallocatechin Natural products OC1CC2=C(O)C=C(O)C=C2OC1C1=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-UHFFFAOYSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- RHGKLRLOHDJJDR-BYPYZUCNSA-N L-citrulline Chemical compound NC(=O)NCCC[C@H]([NH3+])C([O-])=O RHGKLRLOHDJJDR-BYPYZUCNSA-N 0.000 description 1
- 241000207923 Lamiaceae Species 0.000 description 1
- 241000245240 Lonicera Species 0.000 description 1
- 235000014837 Malpighia glabra Nutrition 0.000 description 1
- 240000003394 Malpighia glabra Species 0.000 description 1
- 235000014435 Mentha Nutrition 0.000 description 1
- 241001072983 Mentha Species 0.000 description 1
- 235000006679 Mentha X verticillata Nutrition 0.000 description 1
- 235000002899 Mentha suaveolens Nutrition 0.000 description 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
- RHGKLRLOHDJJDR-UHFFFAOYSA-N Ndelta-carbamoyl-DL-ornithine Natural products OC(=O)C(N)CCCNC(N)=O RHGKLRLOHDJJDR-UHFFFAOYSA-N 0.000 description 1
- 235000015742 Nephelium litchi Nutrition 0.000 description 1
- 241000219925 Oenothera Species 0.000 description 1
- 235000004496 Oenothera biennis Nutrition 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 235000003406 Polymnia sonchifolia Nutrition 0.000 description 1
- 244000134540 Polymnia sonchifolia Species 0.000 description 1
- 229920001991 Proanthocyanidin Polymers 0.000 description 1
- 240000005809 Prunus persica Species 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 241000508269 Psidium Species 0.000 description 1
- 244000294611 Punica granatum Species 0.000 description 1
- 235000014360 Punica granatum Nutrition 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- LUJAXSNNYBCFEE-UHFFFAOYSA-N Quercetin 3,7-dimethyl ether Natural products C=1C(OC)=CC(O)=C(C(C=2OC)=O)C=1OC=2C1=CC=C(O)C(O)=C1 LUJAXSNNYBCFEE-UHFFFAOYSA-N 0.000 description 1
- PUTDIROJWHRSJW-UHFFFAOYSA-N Quercitrin Natural products CC1OC(Oc2cc(cc(O)c2O)C3=CC(=O)c4c(O)cc(O)cc4O3)C(O)C(O)C1O PUTDIROJWHRSJW-UHFFFAOYSA-N 0.000 description 1
- 244000178231 Rosmarinus officinalis Species 0.000 description 1
- 235000011034 Rubus glaucus Nutrition 0.000 description 1
- 244000235659 Rubus idaeus Species 0.000 description 1
- 235000009122 Rubus idaeus Nutrition 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- 241000533293 Sesbania emerus Species 0.000 description 1
- 235000009337 Spinacia oleracea Nutrition 0.000 description 1
- 244000300264 Spinacia oleracea Species 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 240000000785 Tagetes erecta Species 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 description 1
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 description 1
- 102000004357 Transferases Human genes 0.000 description 1
- 108090000992 Transferases Proteins 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 240000008866 Ziziphus nummularia Species 0.000 description 1
- OXGUCUVFOIWWQJ-XIMSSLRFSA-N acanthophorin B Natural products O[C@H]1[C@H](O)[C@H](O)[C@H](C)O[C@H]1OC1=C(C=2C=C(O)C(O)=CC=2)OC2=CC(O)=CC(O)=C2C1=O OXGUCUVFOIWWQJ-XIMSSLRFSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 235000020224 almond Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 235000001046 cacaotero Nutrition 0.000 description 1
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 description 1
- 235000005487 catechin Nutrition 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 229940043370 chrysin Drugs 0.000 description 1
- 235000015838 chrysin Nutrition 0.000 description 1
- 229950001002 cianidanol Drugs 0.000 description 1
- 229960002173 citrulline Drugs 0.000 description 1
- 235000013477 citrulline Nutrition 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229940097362 cyclodextrins Drugs 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- DZYNKLUGCOSVKS-UHFFFAOYSA-N epigallocatechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3cc(O)c(O)c(O)c3 DZYNKLUGCOSVKS-UHFFFAOYSA-N 0.000 description 1
- 235000010350 erythorbic acid Nutrition 0.000 description 1
- 239000004318 erythorbic acid Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000019985 fermented beverage Nutrition 0.000 description 1
- 235000019225 fermented tea Nutrition 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- HVQAJTFOCKOKIN-UHFFFAOYSA-N flavonol Natural products O1C2=CC=CC=C2C(=O)C(O)=C1C1=CC=CC=C1 HVQAJTFOCKOKIN-UHFFFAOYSA-N 0.000 description 1
- 150000002216 flavonol derivatives Chemical class 0.000 description 1
- 235000011957 flavonols Nutrition 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 239000008369 fruit flavor Substances 0.000 description 1
- FODTZLFLDFKIQH-FSVGXZBPSA-N gamma-Oryzanol (TN) Chemical compound C1=C(O)C(OC)=CC(\C=C\C(=O)O[C@@H]2C([C@@H]3CC[C@H]4[C@]5(C)CC[C@@H]([C@@]5(C)CC[C@@]54C[C@@]53CC2)[C@H](C)CCC=C(C)C)(C)C)=C1 FODTZLFLDFKIQH-FSVGXZBPSA-N 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 229940065115 grapefruit extract Drugs 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- AIONOLUJZLIMTK-AWEZNQCLSA-N hesperetin Chemical compound C1=C(O)C(OC)=CC=C1[C@H]1OC2=CC(O)=CC(O)=C2C(=O)C1 AIONOLUJZLIMTK-AWEZNQCLSA-N 0.000 description 1
- 229960001587 hesperetin Drugs 0.000 description 1
- AIONOLUJZLIMTK-UHFFFAOYSA-N hesperetin Natural products C1=C(O)C(OC)=CC=C1C1OC2=CC(O)=CC(O)=C2C(=O)C1 AIONOLUJZLIMTK-UHFFFAOYSA-N 0.000 description 1
- 235000010209 hesperetin Nutrition 0.000 description 1
- 239000008123 high-intensity sweetener Substances 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- FTODBIPDTXRIGS-UHFFFAOYSA-N homoeriodictyol Natural products C1=C(O)C(OC)=CC(C2OC3=CC(O)=CC(O)=C3C(=O)C2)=C1 FTODBIPDTXRIGS-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229940026239 isoascorbic acid Drugs 0.000 description 1
- KRZBCHWVBQOTNZ-DLDRDHNVSA-N isochlorogenic acid Natural products O[C@@H]1[C@H](C[C@@](O)(C[C@H]1OC(=O)C=Cc2ccc(O)c(O)c2)C(=O)O)OC(=O)C=Cc3ccc(O)c(O)c3 KRZBCHWVBQOTNZ-DLDRDHNVSA-N 0.000 description 1
- WZNJWVWKTVETCG-UHFFFAOYSA-N kojic acid Natural products OC(=O)C(N)CN1C=CC(=O)C(O)=C1 WZNJWVWKTVETCG-UHFFFAOYSA-N 0.000 description 1
- BEJNERDRQOWKJM-UHFFFAOYSA-N kojic acid Chemical compound OCC1=CC(=O)C(O)=CO1 BEJNERDRQOWKJM-UHFFFAOYSA-N 0.000 description 1
- 229960004705 kojic acid Drugs 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- DCYOADKBABEMIQ-OWMUPTOHSA-N myricitrin Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1OC1=C(C=2C=C(O)C(O)=C(O)C=2)OC2=CC(O)=CC(O)=C2C1=O DCYOADKBABEMIQ-OWMUPTOHSA-N 0.000 description 1
- DCYOADKBABEMIQ-FLCVNNLFSA-N myricitrin Natural products O([C@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](C)O1)C1=C(c2cc(O)c(O)c(O)c2)Oc2c(c(O)cc(O)c2)C1=O DCYOADKBABEMIQ-FLCVNNLFSA-N 0.000 description 1
- 235000013615 non-nutritive sweetener Nutrition 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 235000019629 palatability Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- OEKUVLQNKPXSOY-UHFFFAOYSA-N quercetin 3-O-beta-D-glucopyranosyl(1->3)-alpha-L-rhamnopyranosyl(1->6)-beta-d-galactopyranoside Natural products OC1C(O)C(C(O)C)OC1OC1=C(C=2C=C(O)C(O)=CC=2)OC2=CC(O)=CC(O)=C2C1=O OEKUVLQNKPXSOY-UHFFFAOYSA-N 0.000 description 1
- QPHXPNUXTNHJOF-UHFFFAOYSA-N quercetin-7-O-beta-L-rhamnopyranoside Natural products OC1C(O)C(O)C(C)OC1OC1=CC(O)=C2C(=O)C(O)=C(C=3C=C(O)C(O)=CC=3)OC2=C1 QPHXPNUXTNHJOF-UHFFFAOYSA-N 0.000 description 1
- OXGUCUVFOIWWQJ-HQBVPOQASA-N quercitrin Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1OC1=C(C=2C=C(O)C(O)=CC=2)OC2=CC(O)=CC(O)=C2C1=O OXGUCUVFOIWWQJ-HQBVPOQASA-N 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- PCMORTLOPMLEFB-ONEGZZNKSA-N sinapic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC(OC)=C1O PCMORTLOPMLEFB-ONEGZZNKSA-N 0.000 description 1
- PCMORTLOPMLEFB-UHFFFAOYSA-N sinapinic acid Natural products COC1=CC(C=CC(O)=O)=CC(OC)=C1O PCMORTLOPMLEFB-UHFFFAOYSA-N 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 235000021012 strawberries Nutrition 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 235000014620 theaflavin Nutrition 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- CWVRJTMFETXNAD-NXLLHMKUSA-N trans-5-O-caffeoyl-D-quinic acid Chemical compound O[C@H]1[C@H](O)C[C@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-NXLLHMKUSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Alcoholic Beverages (AREA)
- Non-Alcoholic Beverages (AREA)
Abstract
Description
本発明は、容器詰め等の果汁含有飲料(ただし、柑橘系飲料を除く)において、果汁飲料成分の製造、流通、保存等における光劣化が抑制された果汁含有飲料、その製造方法、及び果汁含有飲料の光劣化抑制方法、そのための光劣化抑制剤に関する。 The present invention relates to a juice-containing beverage in which photodegradation in production, distribution, storage, etc. of fruit juice beverage components is suppressed in fruit juice-containing beverages (excluding citrus beverages) such as stuffed containers, a method for producing the same, and fruit juice-containing beverages The present invention relates to a method for suppressing light deterioration of beverages and a light deterioration suppressing agent therefor.
天然果汁のような果汁含有飲料は、その爽やかな香味、味覚から醸し出される嗜好性と、健康機能成分含有の期待から、近年、特に消費者ニーズが増大している飲料の一つである。果汁含有飲料は、天然果汁の香味、味覚、色調等が尊重される飲料であり、天然果実由来の各種香味成分や、味覚成分等を含有するところを特徴とする飲料であるが、一方で、該果汁成分には、温度や、光、酸化に対して劣化を生じ易い成分が多く含まれる。したがって、果汁含有飲料においては、飲料製造時、或いは、流通段階及び保存段階における香味成分や、味覚成分等の劣化に対しては、異常な注意が払われる。特に、昨今、流通、保存販売において、プラスチックやガラスビン等の透明容器の使用が盛んであり、かかる流通、販売における光による劣化が重要な問題となっている。 Fruit juice-containing beverages such as natural fruit juice are one of beverages whose consumer needs have been increasing in recent years because of their refreshing flavor and palatability derived from the taste and expectation of containing health functional ingredients. Fruit juice-containing beverages are beverages that respect the flavor, taste, color, etc. of natural fruit juice, and are beverages characterized by containing various flavor components derived from natural fruits, taste components, etc. The fruit juice component contains many components that easily deteriorate with respect to temperature, light, and oxidation. Therefore, in fruit juice-containing beverages, extraordinary attention is paid to deterioration of flavor components, taste components, and the like during beverage production or in the distribution stage and storage stage. In particular, recently, transparent containers such as plastics and glass bottles are widely used in distribution and storage sales, and deterioration due to light in such distribution and sales is an important problem.
果汁含有飲料等の光劣化等を防止する一般的な方法としては、例えばジブチルヒドロキシトルエン、ブチルヒドロキシアニソール、トコフェロール、アスコルビン酸、エリソルビン酸等の酸化防止剤を添加する方法や、低温での流通、保存を行う方法、或いは、光や外気を遮断した容器を使用する方法等が行なわれているが、対象とする果汁によっては、適用が難しかったり、或いは、香味や、味覚の劣化防止効果が十分でない等の問題があり、十分な結果を得るまでには至っていない。従来より、果汁飲料等の飲料の光劣化等の製造、流通、販売時の光や熱、酸化等による劣化を抑制する方法としては、各種の方法が開示されている。例えば、特許文献1には、クロロゲン酸、カフェー酸、及び、フェルラ酸から選ばれた少なくとも1種と、ビタミンC、ルチン、及び、ケルセチンから選ばれた少なくとも1種とを含有させることにより、保存中のフレーバー等の劣化を防止する方法が、特許文献2には、果実や果皮等から得られる天然精油等の天然物由来の香料組成物の光等の劣化の防止に、クロロゲン酸を含有させる方法が開示されている。 As a general method for preventing photodegradation and the like of fruit juice-containing beverages, for example, a method of adding an antioxidant such as dibutylhydroxytoluene, butylhydroxyanisole, tocopherol, ascorbic acid, erythorbic acid, distribution at low temperature, A method of storage or a method of using a container that blocks light and outside air is used, but depending on the target juice, it may be difficult to apply, or the effect of preventing deterioration of flavor and taste is sufficient There are problems such as not being able to obtain sufficient results. Conventionally, various methods have been disclosed as methods for suppressing deterioration due to light, heat, oxidation, and the like during manufacture, distribution, and sale of beverages such as fruit juice beverages. For example, Patent Document 1 preserves by containing at least one selected from chlorogenic acid, caffeic acid, and ferulic acid and at least one selected from vitamin C, rutin, and quercetin. Patent Document 2 discloses a method for preventing deterioration of flavors and the like in the inside, and chlorogenic acid is contained in prevention of deterioration of light and the like of a perfume composition derived from natural products such as natural essential oils obtained from fruits and fruit skins. A method is disclosed.
また、特許文献3には、果汁、果汁飲料等の光や、熱による香味の劣化防止に、ヒマワリの種子の水又は含水アルコール抽出物、或いは、該抽出物に金属封鎖剤を併用した香味劣化防止剤を含有せしめる方法が、特許文献4には、ヒマワリの種子の水又は含水アルコール抽出物に、フラボノール類を含有した香味劣化防止剤を含有せしめる方法が、特許文献5には、ヒマワリの種子の水又は含水アルコール抽出物に、カテキン類を含有した香味劣化防止剤を含有せしめる方法が開示されている。また、特許文献6には、金属封鎖剤とコーヒー豆の水又は含水アルコール抽出物を含有した香味劣化防止剤を含有せしめる方法が開示されている。 In addition, Patent Document 3 discloses a flavor deterioration by using a water or hydrous alcohol extract of sunflower seeds or a combination of a metal sequestering agent for preventing deterioration of flavor caused by light or heat of fruit juices, fruit juices, and the like. Patent Document 4 discloses a method of adding an inhibitor, Patent Document 4 discloses a method of adding a flavor degradation inhibitor containing flavonols to sunflower seed water or water-containing alcoholic extract, and Patent Document 5 discloses sunflower seeds. Has disclosed a method of adding a catechin-containing flavor deterioration inhibitor to the water or water-containing alcoholic extract. Patent Document 6 discloses a method of adding a sequestering agent containing a metal sequestering agent and coffee bean water or a water-containing alcoholic extract.
更に、特許文献7には、特に、透明ガラスビンや透明プラスチック容器入り飲料として、製造、流通、保存する容器詰め飲料の光や熱による香味の劣化の防止のために、イソクロロゲン酸、カフェー酸、クロロゲン酸、コウジ酸、ネオクロロゲン酸、フェルラ酸、プソイドクロロゲン酸、及び没食子酸の1種又は2種以上と、リンゴ抽出物とを含有する飲料用香味劣化防止剤を用いる方法が開示されている。また、特許文献8には、果汁等の熱や光による劣化の防止剤として、スイカズラ属(Lonicera)に属する植物の抽出物を劣化防止剤として用いる方法が開示されている。 Furthermore, in Patent Document 7, in order to prevent deterioration of flavor caused by light or heat of a container-packed beverage to be manufactured, distributed, and stored, particularly as a beverage in a transparent glass bottle or a transparent plastic container, isochlorogenic acid, caffeic acid, A method using a flavor deterioration inhibitor for beverages containing one or more of chlorogenic acid, kojic acid, neochlorogenic acid, ferulic acid, pseudochlorogenic acid, and gallic acid and an apple extract is disclosed. Yes. Patent Document 8 discloses a method in which an extract of a plant belonging to the genus Lonicera is used as an anti-degradation agent as an anti-degradation agent such as fruit juice due to heat or light.
果汁含有飲料の中で、レモンやグレープフルーツを代表とする柑橘系の香味を持つ清涼飲料水やアルコール飲料は、爽やかな香味が特徴で古くから多くの人々に支持を受けている飲料であるが、その一方で、柑橘系の香気成分は酸性環境下で不安定であり、熱や光によって劣化して、その特徴である爽やかな香気が減少すると同時にオフフレーバーが生じて商品価値を下げてしまうという問題がある。この劣化の原因のひとつとして、柑橘系香気の代表的な成分であるシトラールが光や熱によって変化することが挙げられる。詳細はまだ不明な点も多いが、シトラールからの熱劣化及び光劣化によるオフフレーバーの生成機構は、それぞれ異なることが知られている。 Among juice-containing beverages, soft drinks and alcoholic beverages with citrus flavors such as lemon and grapefruit are drinks that have been supported by many people for a long time, with a refreshing flavor. On the other hand, citrus fragrance components are unstable in an acidic environment and deteriorate due to heat and light, and the refreshing fragrance, which is the feature of the citrus fragrance components, is reduced, and at the same time, off-flavor is generated, reducing the commercial value. There's a problem. One of the causes of this deterioration is that citral, which is a typical component of citrus aroma, is changed by light or heat. Although many details are still unclear, it is known that the generation mechanisms of off-flavors due to thermal degradation and light degradation from citral are different.
近年、飲料が透明なペットボトルのような光透過性の容器に充填される機会が増え、更にコンビニエンスストアなど明るいショーケースの中で製品が陳列販売される機会も増えたことから、他の果汁飲料と同様、柑橘系飲料の光劣化に対する抑制技術の重要度が高まっており、特に、柑橘系飲料において、該柑橘系飲料の香気成分であるシトラール等の熱や光、酸化による劣化に起因する劣化臭の生成を抑制する方法については、従来より、数多くの方法が提案されている。 In recent years, beverages have been filled in light-transparent containers such as transparent plastic bottles, and the number of opportunities for products to be displayed and sold in bright display cases such as convenience stores has increased. As with beverages, the importance of suppression technology for light degradation of citrus beverages is increasing, especially in citrus beverages, due to deterioration due to heat, light, and oxidation of citral, which is an aroma component of the citrus beverages As a method for suppressing the generation of a deteriorated odor, many methods have been conventionally proposed.
特に、柑橘系飲料の香気成分であるシトラール等の熱や光、酸化による劣化に起因する劣化臭の生成を抑制する方法として、植物抽出物や、植物抽出成分を柑橘系飲料に添加する方法が開示されている。例えば、特許文献9には、飲食品用フレーバーの熱や光等の劣化の防止に、クロロゲン酸、カフェー酸、及びフェルラ酸から選択される抗酸化成分と、プロアントシアニジン少量体よりなる抗酸化成分とからなるフレーバー劣化防止剤を用いる方法が、特許文献10には、カリン、マンゴー、マンゴスチン、ミロバラン、ザクロ、またはカカオから溶媒抽出された抽出物と、エピカテキン、エピカテキンガレート、エピガロカテキンガレート、酵素処理ルチン、クエルセチン、フェルラ酸、カフエー酸、没食子酸から選択される成分をシトラール由来の劣化臭の生成抑制に用いる方法が開示されている。 In particular, as a method for suppressing the generation of odor caused by heat, light, and oxidative deterioration such as citral, which is an aroma component of citrus beverages, there is a method of adding plant extracts and plant extract components to citrus beverages. It is disclosed. For example, Patent Document 9 discloses that an antioxidant component selected from chlorogenic acid, caffeic acid, and ferulic acid and an antioxidant component consisting of a proanthocyanidin minor body for preventing deterioration of flavors for foods and drinks such as heat and light. Patent Document 10 discloses an extract obtained by solvent extraction from karin, mango, mangosteen, mylobaran, pomegranate or cacao, and epicatechin, epicatechin gallate, epigallocatechin gallate. In addition, a method is disclosed in which a component selected from enzyme-treated rutin, quercetin, ferulic acid, caffeic acid, and gallic acid is used to suppress the generation of a citral-derived deteriorated odor.
また、シトラール等由来の劣化臭の生成を抑制するために、特許文献11には、シソ科メンタ(Mentha)属ミントの溶媒抽出物、キク科アルテミシア(Artemisia)属ヨモギの溶媒抽出物、ミカン亜科シトラス(Citrus)属オレンジの溶媒抽出物、ミカン亜科シトラス(Citrus)属レモンの溶媒抽出物、ミカン亜科シトラス(Citrus)属グレープフルーツの溶媒抽出物、カフェー酸、フェルラ酸、シナピン酸、ロズマリン酸、ジカフェオイルキナ酸類、クマル酸類、α−グルコシルルチン(酵素処理ルチン)、クエルセチン、ミリシトリン、クエルシトリン、γ−オリザノール、カンフェロール、ヘスペレチン、クリシン、ルテオリン−7−グリコシド、6−ヒドロキシフラボン、7−ヒドロキシフラボン、プラトール及び7,8−ジヒドロキシフラボンからなる群より選ばれる成分を、特許文献12には、エピガロカテキン、エピガロカテキンガレート、エピカテキンを、特許文献13には、カキノキ科カキノキ属の果実又は未熟果由来のタンニン、該タンニン精製物を、特許文献14には、茶ポリフェノールを、特許文献15には、ヤーコン抽出物を、用いる方法が開示されている。 Moreover, in order to suppress the generation | occurrence | production of the deterioration odor derived from a citral etc., patent document 11 includes the solvent extract of the Labiatae Menta (Mentha genus) mint, the solvent extract of the Artemisia genus Artemisia, the mandarin orange Citrus orange extract, Citrus lemon extract, Citrus grapefruit extract, Caffeic acid, Ferulic acid, Sinapinic acid, Rosmarin Acids, dicaffeoylquinic acids, coumaric acids, α-glucosylrutin (enzyme-treated rutin), quercetin, myricitrin, quercitrin, γ-oryzanol, camferol, hesperetin, chrysin, luteolin-7-glycoside, 6-hydroxyflavone 7-hydroxyflavone, Ingredients selected from the group consisting of platol and 7,8-dihydroxyflavone, Patent Document 12 discloses epigallocatechin, epigallocatechin gallate, epicatechin, Patent Document 13 discloses fruit of the genus Oysteraceae, or immature Patent Document 14 discloses a method using fruit-derived tannin, purified tannin, Patent Document 14 uses tea polyphenol, and Patent Document 15 uses Yacon extract.
更に、特許文献16には、アシタバ、アボカド、オオバコ、発酵茶葉、半発酵茶葉、エビスグサ、サンザシの溶媒抽出物を、特許文献17には、テアフラビン類を、特許文献18には、杜仲葉、エンメイソウ、ハイビスカス、セイヨウオトギリソウ、ライチ種子、月見草種子、グァバ葉、マリーゴールド、ラズベリー葉の抽出物を、特許文献19には、アシタバ、アボカド、オオバコ等の溶媒抽出物を、特許文献20には、酸性条件下で、セリン、グリシン、アラニン及びシトルリンを用いる方法が開示されている。また、特許文献21には、シトラールとサイクロデキストリン類を所定の濃度及び比率で含む飲料とすることにより、殺菌、保存や光照射においてもシトラールが減少せず、シトラールの劣化によるオフフレーバーの発生を防止する方法が、特許文献22には、シトラール、リモネン、γ―テルピネンとα―テルピノレンを含有させたレモン風味飲料の熱や光に対する劣化を防止する方法が開示されている。 Further, Patent Document 16 discloses a solvent extract of Ashitaba, Avocado, Psyllium, Fermented tea leaves, Semi-fermented tea leaves, Shrimp and Hawthorn, Patent Document 17 discloses theaflavins, and Patent Document 18 discloses Tochu leaves and Enmeiso. , Hibiscus, Hypericum perforatum, Lychee seed, Evening primrose seed, Guava leaf, Marigold, Raspberry leaf extract, Patent Document 19, Solitary extract such as Ashitaba, Avocado, Psyllium, Patent Document 20 A method using serine, glycine, alanine and citrulline under conditions is disclosed. Further, in Patent Document 21, by making a beverage containing citral and cyclodextrins at a predetermined concentration and ratio, citral is not reduced even in sterilization, storage or light irradiation, and off-flavor is generated due to deterioration of citral. Patent Document 22 discloses a method for preventing deterioration of lemon-flavored beverages containing citral, limonene, γ-terpinene and α-terpinolene with respect to heat and light.
一方で、ルチンを飲食品等における加熱や光劣化に対する抗酸化剤として用いることが知られている(特許文献23、特許文献24)。ルチンを飲料等の劣化防止に使用する場合は、その水溶性等を増す目的で、ルチンに転移酵素を働かせて、糖を転移させ(特許文献25)、酵素処理ルチンとして用いられる(特許文献10、特許文献11)。ルチンを飲食品等における加熱や光劣化に対する劣化防止に用いる場合に、ルチンに、トコフェロール(ビタミンE)を配合することも開示されている(特許文献24、特許文献26:、特許文献27、特許文献28)。 On the other hand, it is known that rutin is used as an antioxidant against heating and photodegradation in foods and drinks (Patent Documents 23 and 24). When rutin is used for preventing deterioration of beverages and the like, it is used as enzyme-treated rutin by transferring a transferase to rutin to transfer sugar (Patent Document 25) for the purpose of increasing its water solubility and the like (Patent Document 25). And Patent Document 11). In the case where rutin is used for preventing deterioration of food and beverages against heating and light deterioration, it is also disclosed that tocopherol (vitamin E) is added to rutin (Patent Document 24, Patent Document 26 :, Patent Document 27, Patent). Reference 28).
以上のように、果汁含有飲料においては、飲料の香気成分の熱や光、酸化による劣化に対する劣化防止の方法として、各種成分の添加による劣化抑制、防止方法が開示されており、果汁含有飲料の中で、特に、柑橘系飲料のような飲料の香気成分の熱や光、酸化による劣化に対する劣化防止の方法も開示されているが、果汁含有飲料においては、天然の爽やかな香味を特徴とする飲料であるために、劣化抑制成分の添加による有効な劣化抑制効果と同時に、飲料自体の本来の香味への影響を極力回避し、かつ、有効な劣化抑制効果を有する劣化抑制方法の更なる開発が望まれるところである。特に、透明なペットボトルのような光透過性の容器に充填された製品状態での飲料の流通、販売のニーズが増大している昨今においては、香気に優れ、安定性の高い柑橘系飲料製品を提供するために、有効な劣化抑制方法の提供が何よりも必要とされるところである。 As described above, in juice-containing beverages, as methods for preventing deterioration due to heat and light of beverage aroma components, and deterioration due to oxidation, deterioration suppression and prevention methods by the addition of various components have been disclosed. Among them, in particular, a method for preventing deterioration of aroma components of beverages such as citrus beverages against deterioration due to heat, light, and oxidation has been disclosed, but fruit juice-containing beverages are characterized by a natural refreshing flavor. Further development of a degradation control method that has an effective degradation inhibitory effect while avoiding the influence on the original flavor of the beverage itself as much as possible, as well as an effective degradation inhibitory effect due to the addition of degradation inhibitory ingredients because it is a beverage Is desired. Especially in recent years when the needs for the distribution and sales of beverages filled in light-transparent containers such as transparent PET bottles are increasing, citrus beverage products with excellent aroma and high stability Therefore, the provision of an effective deterioration suppressing method is required above all.
本発明の課題は、光透過性容器詰め等の果汁含有飲料(ただし、柑橘系飲料を除く)において、果汁含有飲料の香味、味覚成分等の、製造、流通、保存等における光劣化を効果的に抑制し、しかも、果汁含有飲料の果汁自体の本来の香味である天然の爽やかな香味、味覚への影響を極力回避し、香味、味覚に優れ、安定性の高い果汁含有飲料を提供することにある。 The subject of this invention is effective in light degradation in manufacture, distribution, preservation | save, etc. of the flavor, taste component, etc. of a fruit juice containing drink in fruit juice containing drinks (however, except citrus-type drinks), such as a light transmissive container packing To provide a fruit juice-containing beverage that is excellent in flavor and taste and has high stability, avoiding as much as possible the influence of natural fresh flavor, which is the original flavor of the fruit juice itself, and taste. It is in.
本出願人は先に、植物由来の抗酸化作用を有する成分について、柑橘系飲料の保存中の光劣化に対して、安全に、かつ、有効に光劣化を抑制し、しかも柑橘系飲料が持つ、爽やかな香味を保持することが可能な光劣化抑制剤成分について鋭意探索する中で、トコフェロール(ビタミンE)、ルテイン、及び酵素処理ルチンを飲料に対して、特定濃度範囲で組み合わせて用いることにより、柑橘系飲料の保存中の光劣化に対して、有効に劣化を抑制し、しかも、添加成分による柑橘系飲料の香味への影響を回避して、香気に優れ、安定性の高い柑橘系飲料製品を提供することが可能であることを見出し、特許を出願するに至った(特願2015−222548号)。そこで、上記課題を解決すべく、上記トコフェロール(ビタミンE)、ルテイン、及び酵素処理ルチンからなる光劣化抑制剤成分を柑橘系飲料以外の果汁含有飲料について、光劣化の抑制効果を検証する中で、該光劣化抑制剤成分が、柑橘系飲料以外の果汁含有飲料にも有効に光劣化の抑制効果を有することを見出し、本発明を完成するに至った。 The present applicant first has to suppress the light deterioration safely and effectively against the light deterioration during storage of the citrus drink, and the citrus drink has a plant-derived antioxidant component. By eagerly searching for a photodegradation inhibitor component capable of maintaining a refreshing flavor, by using tocopherol (vitamin E), lutein, and enzyme-treated rutin in combination with a specific concentration range for beverages In addition to light degradation during storage of citrus beverages, it effectively suppresses degradation and avoids the influence of added components on the flavor of citrus beverages, and has excellent aroma and high stability. It was found that it was possible to provide a product, and a patent was filed (Japanese Patent Application No. 2015-222548). Then, in order to solve the said subject, in verifying the inhibitory effect of photodegradation about juice containing drinks other than a citrus drink, the photodegradation inhibitor component which consists of the said tocopherol (vitamin E), lutein, and an enzyme process rutin. The present inventors have found that the photodegradation inhibitor component effectively has an effect of inhibiting photodegradation in fruit juice-containing beverages other than citrus beverages, and have completed the present invention.
すなわち、本発明は、果汁含有飲料(ただし、柑橘系飲料を除く)において、飲料全量に対して、トコフェロールを0.00006〜0.03重量%、ルテインを0.0000005〜0.0005重量%、及び酵素処理ルチンを0.00002〜0.01重量%の含有割合となるように配合含有させたことを特徴とする、光劣化が抑制された果汁含有飲料からなる。本発明の果汁含有飲料は、上記配合割合の光劣化抑制剤成分の組み合わせを採用することにより、光透過性容器詰め等の果汁含有飲料の形態においても、有効に光劣化を抑制し、香気に優れ、安定性の高い果汁含有飲料製品を提供することを可能とする。 That is, the present invention is a fruit juice-containing beverage (excluding citrus beverages), tocopherol 0.00006-0.03% by weight, lutein 0.0000005-0.0005% by weight relative to the total amount of beverage, And a fruit juice-containing beverage in which photodegradation is suppressed, characterized in that the enzyme-treated rutin is blended and contained so as to have a content ratio of 0.00002 to 0.01% by weight. The fruit juice-containing beverage of the present invention effectively suppresses light degradation and aroma even in the form of fruit juice-containing beverages such as light-transparent containers by adopting a combination of the above-described blending ratio of the light degradation inhibitor component. It is possible to provide an excellent and stable fruit juice-containing beverage product.
本発明の光劣化抑制剤成分において、前記するように酵素処理ルチン、トコフェロール(ビタミンE)自体は、飲料の劣化抑制剤成分として知られているものであり、ルテイン(β,ε−カロテン−3,3´−ジオール)も、緑色野菜等由来のカロテノイドの一つであり、それ自体、天然物由来の抗酸化剤として知られているものである。本発明は、これらの成分を、特定濃度範囲で組み合わせて用いることにより、優れた光劣化抑制効果を得ることができることを見出したものである。 In the photodegradation inhibitor component of the present invention, as described above, the enzyme-treated rutin and tocopherol (vitamin E) itself are known as beverage degradation inhibitor components, and lutein (β, ε-carotene-3) , 3'-diol) is one of carotenoids derived from green vegetables and the like, and is itself known as an antioxidant derived from natural products. The present invention has been found that an excellent light deterioration suppressing effect can be obtained by using these components in combination in a specific concentration range.
本発明の光劣化が抑制された果汁含有飲料において、該果汁含有飲料は、非アルコール又はアルコール含有果汁含有飲料であることができる。本発明により、特に果汁含有飲料が、光透過性の容器詰め飲料であるような場合においても、その流通、保存における光劣化に対して、その光劣化を有効に抑制し、香気に優れ、安定性の高い果汁含有飲料製品を提供することができる。 In the fruit juice-containing beverage in which photodegradation of the present invention is suppressed, the fruit juice-containing beverage can be a non-alcohol or alcohol-containing fruit juice-containing beverage. According to the present invention, even when the fruit juice-containing beverage is a light-permeable container-packed beverage, the light degradation is effectively suppressed against light degradation during distribution and storage, and the aroma is excellent and stable. A highly fruitful beverage-containing beverage product can be provided.
本発明は、果汁含有飲料(ただし、柑橘系飲料を除く)の製造において、飲料全量に対して、トコフェロールを0.00006〜0.03重量%、ルテインを0.0000005〜0.0005重量%、及び酵素処理ルチンを0.00002〜0.01重量%の含有割合となるように配合含有させることを特徴とする、飲料の光劣化が抑制された果汁含有飲料の製造方法の発明を包含する。 In the production of fruit juice-containing beverages (excluding citrus beverages), the present invention comprises 0.00006-0.03% by weight of tocopherol, 0.0000005-0.0005% by weight of lutein, And the invention of a method for producing a fruit juice-containing beverage in which photodegradation of the beverage is suppressed, wherein the enzyme-treated rutin is blended and contained so as to have a content ratio of 0.00002 to 0.01% by weight.
更に、本発明は、果汁含有飲料(ただし、柑橘系飲料を除く)の製造において、飲料全量に対して、トコフェロールを0.00006〜0.03重量%、ルテインを0.0000005〜0.0005重量%、及び酵素処理ルチンを0.00002〜0.01重量%の含有割合となるように配合含有させることを特徴とする、果汁含有飲料の光劣化を抑制する方法の発明を包含する。 Furthermore, in the present invention, in the production of fruit juice-containing beverages (excluding citrus beverages), 0.00006-0.03% by weight of tocopherol and 0.0000005-0.0005% by weight of lutein relative to the total amount of beverage. %, And an enzyme-treated rutin in an amount of 0.00002 to 0.01% by weight. The invention includes a method for suppressing photodegradation of a fruit juice-containing beverage.
更に、本発明は、果汁含有飲料(ただし、柑橘系飲料を除く)の光劣化を抑制するための光劣化抑制剤において、請求項1に記載の光劣化が抑制された柑橘系飲料を製造するために用いるトコフェロール、ルテイン、及び酵素処理ルチンを配合した、果汁含有飲料の光劣化抑制剤の発明を包含する。 Furthermore, this invention manufactures the citrus drink by which the photodegradation of Claim 1 was suppressed in the photodegradation inhibitor for suppressing the photodegradation of fruit juice containing drinks (however, except a citrus drink). The invention of the photodegradation inhibitor for fruit juice-containing beverages containing tocopherol, lutein and enzyme-treated rutin used for the purpose is included.
すなわち、具体的には本発明は、[1]果汁含有飲料(ただし、柑橘系飲料を除く)において、飲料全量に対して、トコフェロールを0.00006〜0.03重量%、ルテインを0.0000005〜0.0005重量%、及び酵素処理ルチンを0.00002〜0.01重量%の含有割合となるように配合含有させたことを特徴とする、光劣化が抑制された果汁含有飲料や、[2]果汁含有飲料が、非アルコール又はアルコール含有柑橘系飲料であることを特徴とする前記[1]に記載の光劣化が抑制された果汁含有飲料や、[3]果汁含有飲料が、光透過性の容器詰め飲料であることを特徴とする前記[1]又は[2]に記載の光劣化が抑制された果汁含有飲料からなる。 That is, the present invention specifically relates to [1] fruit juice-containing beverages (excluding citrus beverages), wherein 0.00006 to 0.03% by weight of tocopherol and 0.0000005 of lutein relative to the total amount of beverage. -0.0005 wt%, and a fruit juice-containing beverage with reduced photodegradation, characterized in that the enzyme-treated rutin is mixed and contained so as to have a content ratio of 0.00002 to 0.01 wt%, [2] The juice-containing beverage with suppressed light degradation as described in [1] above, wherein the juice-containing beverage is a non-alcohol or alcohol-containing citrus beverage; It consists of a fruit juice-containing beverage in which photodegradation is suppressed as described in [1] or [2] above, which is a sexual container-packed beverage.
また、本発明は、[4]果汁含有飲料(ただし、柑橘系飲料を除く)の製造において、飲料全量に対して、トコフェロールを0.00006〜0.03重量%、ルテインを0.0000005〜0.0005重量%、及び酵素処理ルチンを0.00002〜0.01重量%の含有割合となるように配合含有させることを特徴とする、飲料の光劣化が抑制された果汁含有飲料の製造方法や、[5]果汁含有飲料(ただし、柑橘系飲料を除く)の製造において、飲料全量に対して、トコフェロールを0.00006〜0.03重量%、ルテインを0.0000005〜0.0005重量%、及び酵素処理ルチンを0.00002〜0.01重量%の含有割合となるように配合含有させることを特徴とする、果汁含有飲料の光劣化を抑制する方法や、[6]果汁含有飲料(ただし、柑橘系飲料を除く)の光劣化を抑制するための光劣化抑制剤において、前記[1]に記載の光劣化が抑制された果汁含有飲料を製造するために用いるトコフェロール、ルテイン、及び酵素処理ルチンを配合した、果汁含有飲料の光劣化抑制剤からなる。 The present invention also provides [4] juice-containing beverages (excluding citrus beverages), with 0.00006-0.03% by weight of tocopherol and 0.0000005-0 A method for producing a fruit juice-containing beverage in which the photodegradation of the beverage is suppressed, characterized in that the content is 0.00005 to 0.01% by weight, and the enzyme-treated rutin is contained in an amount of 0.00002 to 0.01% by weight. [5] In production of fruit juice-containing beverages (excluding citrus beverages), 0.00006-0.03% by weight of tocopherol, 0.0000005-0.0005% by weight of lutein, based on the total amount of beverage, And a method for suppressing photodegradation of a fruit juice-containing beverage, wherein the enzyme-treated rutin is mixed and contained so as to have a content ratio of 0.00002 to 0.01% by weight, [6] In order to produce a fruit juice-containing beverage in which the light deterioration according to the above [1] is suppressed in the light deterioration inhibitor for suppressing light deterioration of the fruit juice-containing beverage (excluding citrus beverages). It consists of a photodegradation inhibitor for fruit juice-containing beverages that contains tocopherol, lutein and enzyme-treated rutin used.
本発明は、光透過性容器詰め等の製品形態において、流通、販売が行われる果汁含有飲料においても、香気成分の光劣化が有効に抑制されて、保存後も天然のフレッシュな香味、味覚を有する容器詰めの果汁含有飲料を提供し、果汁含有飲料自体の本来の爽やかな香味、味覚を保持した、香気に優れ、安定性の高い柑橘系飲料製品を提供する。 In the product form such as light-transparent container packing, the present invention effectively suppresses the light deterioration of aroma components even in fruit juice-containing beverages that are distributed and sold, and maintains a natural fresh flavor and taste even after storage. A container-packed fruit juice-containing beverage is provided, and a citrus beverage product with excellent aroma and high stability that retains the original refreshing flavor and taste of the fruit juice-containing beverage itself is provided.
本発明は、果汁含有飲料(ただし、柑橘系飲料を除く)において、飲料全量に対して、トコフェロールを0.00006〜0.03重量%、ルテインを0.0000005〜0.0005重量%、及び酵素処理ルチンを0.00002〜0.01重量%の含有割合となるように配合含有させたことを特徴とする、光劣化が抑制された果汁含有飲料、その製造方法、及び該果汁含有飲料の光劣化抑制方法、そのための光劣化抑制剤からなる。 In the present invention, fruit juice-containing beverages (excluding citrus beverages), 0.00006-0.03% by weight of tocopherol, 0.0000005-0.0005% by weight of lutein and enzyme A juice-containing beverage with suppressed photodegradation, a method for producing the same, and the light of the juice-containing beverage, characterized in that treated rutin is mixed and contained so as to have a content ratio of 0.00002 to 0.01% by weight. It consists of a deterioration suppressing method and a light deterioration suppressing agent therefor.
<光劣化>
本発明は、果汁含有飲料において、その製造、流通、保存時における飲料の香味成分の光劣化を抑制する。ペットボトルのような光透過性の透明容器に充填された果汁含有飲料は、日光や蛍光灯の下に放置した場合、果汁の有するフレッシュな香気が低減して、代わりに樹脂、ビニール、化学薬品などを連想させるケミカル臭や、金属様臭又は酸化臭などのオフフレーバーが発生する。本発明における光劣化の防止効果は、該光による香味成分の劣化によるオフフレーバーの発生等を防止することからなる。
<Light degradation>
In the fruit juice-containing beverage, the present invention suppresses photodegradation of the flavor component of the beverage during production, distribution, and storage. Fruit juice-containing beverages filled in light-transparent transparent containers such as PET bottles, when left under sunlight or fluorescent light, reduce the fresh aroma of the juice, instead of resin, vinyl, chemicals Off-flavors such as chemical odors reminiscent of the above, metal-like odors, and oxidation odors occur. The effect of preventing light deterioration in the present invention consists in preventing the occurrence of off-flavor due to the deterioration of the flavor component due to the light.
<果汁含有飲料(柑橘系飲料を除く)>
本発明の果汁含有飲料とは、対象として、柑橘系飲料を除いた果汁含有飲料を対象とし、アンズ、モモ、スモモ、ウメ、サクランボ、アーモンド、ナツメ、マンゴー等の核果類、ナシ、ライチ(レイシ)、ブドウ、パイナップル、イチゴ、アセロラ等の果実から調製される果汁を含有する果汁含有飲料を対象とすることができる。当該果実の果汁を原料のひとつとして、或いは複数併せて使用することができる。
<Fruit juice-containing beverages (excluding citrus beverages)>
The fruit juice-containing beverage of the present invention is a fruit juice-containing beverage excluding citrus-based beverages, and includes fruits, fruits, apricots, peaches, plums, plums, cherries, almonds, jujube, mangoes, pears, litchis (Lacy) ), Fruit juice-containing beverages containing fruit juice prepared from fruits such as grapes, pineapples, strawberries, and acerola. The fruit juice can be used as one of raw materials or in combination.
本発明の果汁含有飲料のpHの範囲は限定されないが果汁含有飲料の香味特徴を活かすためには、pH2.0〜5.0、好ましくはpH2.5〜4.0に調整されていることが望ましい。pHの調整は、酸性の果汁を用いておこなわれる他、酸味料として一般に用いられるクエン酸、リンゴ酸、酒石酸、乳酸、コハク酸、酢酸などを用いて調整できるが、フルーツフレーバーとの相性の良さの点からは、クエン酸又はリンゴ酸が好ましく、クエン酸が最も好ましい。 The range of the pH of the fruit juice-containing beverage of the present invention is not limited, but in order to take advantage of the flavor characteristics of the fruit juice-containing beverage, it is adjusted to pH 2.0 to 5.0, preferably pH 2.5 to 4.0. desirable. The pH can be adjusted using acidic fruit juice, but it can also be adjusted using citric acid, malic acid, tartaric acid, lactic acid, succinic acid, acetic acid, etc., which are commonly used as acidulants. Good compatibility with fruit flavors From this point, citric acid or malic acid is preferable, and citric acid is most preferable.
本発明の果汁含有飲料は、非アルコール又はアルコール含有果汁飲料として調製することができる。本発明の果汁含有飲料において、アルコールを含有させ、アルコール含有果汁飲料として調製する場合において、その一例がいわゆるチューハイタイプのアルコール飲料である。果汁やフレーバーとともにアルコールを混合し、更に炭酸ガスを付与したものである。そのほかアルコール含有飲料としては、ビールタイプの飲料と果汁やフレーバーとを混合して調製する果汁香味のビールテイスト飲料や、果汁自体をアルコール発酵させて調製する果汁香味の醗酵飲料などが例示できる。アルコール含量は、用途に合わせて例えば0.1〜20容量%程度まで適宜選択できる。 The fruit juice-containing beverage of the present invention can be prepared as a non-alcohol or alcohol-containing fruit juice beverage. In the fruit juice-containing beverage of the present invention, when alcohol is contained and prepared as an alcohol-containing fruit juice beverage, an example thereof is a so-called Chu-Hi type alcoholic beverage. Alcohol is mixed with fruit juice and flavor, and carbon dioxide is added. In addition, examples of alcohol-containing beverages include beer-flavored beer-taste beverages prepared by mixing beer-type beverages with fruit juices and flavors, and fruit-flavored fermented beverages prepared by subjecting fruit juices themselves to alcohol fermentation. The alcohol content can be appropriately selected, for example, from about 0.1 to 20% by volume according to the application.
また、本発明の果汁含有飲料において、炭酸ガスを含ませて、非アルコールの炭酸ガス飲料としてもよい。この場合、炭酸ガス圧に限定はないが、通常0.1〜0.5MPa程度である。 Moreover, in the fruit juice containing drink of this invention, it is good also as a non-alcoholic carbon dioxide drink by containing carbon dioxide. In this case, the carbon dioxide pressure is not limited, but is usually about 0.1 to 0.5 MPa.
その他、本発明の果汁含有飲料においては、非アルコール含有、アルコール含有に関わらず、通常の果汁含有飲料で用いられる原料、すなわち、甘味料(高甘味度甘味料を含む)、酸味料、香料、色素、安定剤などはいずれも使用可能である。その中でもアスコルビン酸は果汁含有飲料の酸化防止効果も有するので本発明効果をより明確に発揮させる上で、添加することができる。 In addition, in the fruit juice-containing beverage of the present invention, regardless of non-alcohol content and alcohol content, raw materials used in ordinary fruit juice-containing beverages, that is, sweeteners (including high-intensity sweeteners), acidulants, flavors, Any of dyes and stabilizers can be used. Among them, ascorbic acid also has an antioxidant effect for fruit juice-containing beverages, and therefore can be added to demonstrate the effects of the present invention more clearly.
<光劣化抑制剤成分>
本発明において、果汁含有飲料の光劣化抑制の有効成分として用いられる光劣化抑制剤成分としては、トコフェロール、ルテイン、及び酵素処理ルチンを組み合わせて配合した成分が用いられる。トコフェロール、ルテイン、及び酵素処理ルチンは、植物等から、抽出、採取されるもので、それ自体は飲食品等に用いる抗酸化剤として知られているものであり、市販品等によって入手することができる。
<Light degradation inhibitor component>
In this invention, the component which mix | blended combining the tocopherol, lutein, and the enzyme process rutin is used as a photodegradation inhibitor component used as an active ingredient of light degradation suppression of a fruit juice containing drink. Tocopherol, lutein, and enzyme-treated rutin are extracted and collected from plants, etc., and are known per se as antioxidants used in foods and drinks, and can be obtained from commercial products. it can.
<トコフェロール>
本発明で使用するトコフェロールは、脂溶性ビタミンの一種である。化学合成されたものでも、大豆油、小麦胚芽油、パーム油などの植物原料由来の油脂から抽出、精製されたものであってもよい。前者は、通常dl体のα型であり、後者は、全て天然d体の、α、β、γ、δの各誘導型の混合物であるが、どちらも同じように使用できる。本発明は、dl体、d体、及びα、β、γ、δ各誘導型を区別せず、全てをトコフェロールとして扱う。
<Tocopherol>
Tocopherol used in the present invention is a kind of fat-soluble vitamin. It may be chemically synthesized or extracted and purified from oils and fats derived from plant materials such as soybean oil, wheat germ oil and palm oil. The former is usually the α form of the dl form, and the latter is an α, β, γ, and δ derivative mixture of all natural d forms, both of which can be used in the same manner. In the present invention, the dl-form, d-form, and α, β, γ, and δ induction types are not distinguished, and all are treated as tocopherols.
本発明におけるトコフェロールの添加量は、香味劣化抑制効果や飲料香味や外観などに与える影響の点で、果汁含有飲料中に、0.00006〜0.03重量%の範囲で含有させるが、好ましくは、0.00012〜0.015重量%、更に好ましくは0.0006〜0.0015重量%の範囲で含有させることができる。原料中及び飲料中のトコフェロールの定量分析は、食品添加物公定書に記載のHPLC法などによりおこなうことができる。 The addition amount of tocopherol in the present invention is contained in the range of 0.00006 to 0.03% by weight in the fruit juice-containing beverage in terms of influence on flavor deterioration suppressing effect, beverage flavor and appearance, etc. , 0.00012 to 0.015 wt%, more preferably 0.0006 to 0.0015 wt%. Quantitative analysis of tocopherol in raw materials and beverages can be performed by the HPLC method described in the Food Additives Official Document.
<ルテイン>
本発明で使用するルテインは、天然色素カロチノイドの一種であり、緑黄色野菜、例えば、ほうれん草や、かぼちゃ、ブロッコリーなどに多く含まれる。この緑黄色野菜などルテインを豊富に含む植物体などから抽出、精製したルテインも使用できるが、飲食品原料としてマリーゴールド由来のルテインが、天然物由来のルテインとして入手可能なので、これを用いればよい。一方、化学合成品のルテインも使用してもよい。
<Lutein>
Lutein used in the present invention is a kind of natural pigment carotenoid, and is abundant in green-yellow vegetables such as spinach, pumpkin, broccoli and the like. Lutein extracted and purified from a plant body rich in lutein such as green-yellow vegetables can also be used. However, marigold-derived lutein can be obtained as a natural product-derived lutein, and this can be used. On the other hand, chemically synthesized lutein may also be used.
本発明におけるルテインの添加量は、香味劣化抑制効果や飲料の香味や外観などに与える影響の点で、果汁含有飲料中に、0.0000005〜0.0005重量%範囲で含有させるが、好ましくは、0.000001〜0.00025重量%、更に好ましくは0.000005〜0.000012重量%の範囲で含有させることができる。原料中及び飲料中のルテインの定量分析は、一般財団法人日本食品分析センターのHPに掲載(http://www.jfrl.or.jp/bunsekiflow/files/179.pdf)のHPLC法などを用いて行うことができる。 In the present invention, the amount of lutein added is in the range of 0.0000005 to 0.0005% by weight in the fruit juice-containing beverage in terms of the effect on the flavor deterioration inhibiting effect and the flavor and appearance of the beverage. 0.000001 to 0.00025% by weight, more preferably 0.000005 to 0.000012% by weight. Quantitative analysis of lutein in raw materials and beverages uses the HPLC method published on the website of the Japan Food Research Center (http://www.jfrl.or.jp/bunsekiflow/files/179.pdf). Can be done.
<酵素処理ルチン>
本発明で使用する酵素処理ルチンは、ルチンを糖転移酵素で処理して水溶性を高めたルチンであり(特許文献25参照)、市販品ではαGルチンP(東洋製糖社製)が例示できる。ルチンは、ポリフェノール配糖体の一種であり、ソバの葉や、アスパラガス、柑橘類の果皮などに多く含まれている。
<Enzyme-treated rutin>
The enzyme-treated rutin used in the present invention is rutin obtained by treating rutin with glycosyltransferase to enhance water solubility (see Patent Document 25), and αG rutin P (manufactured by Toyo Sugar Co., Ltd.) can be exemplified as a commercial product. Rutin is a kind of polyphenol glycoside and is contained in a lot of buckwheat leaves, asparagus, and citrus peels.
本発明における酵素処理ルチンの添加量は、香味劣化抑制効果や飲料の香味や外観などの与える影響の点で、果汁含有飲料に、0.00002〜0.01重量%の範囲で含有させるが、好ましくは、0.00004〜0.005重量%、更に好ましくは0.0002〜0.0005重量%の範囲で含有させることができる。原料中及び飲料中の酵素処理ルチンの定量分析は食品衛生学雑誌 Vol.41(2000)No.1,p54−60に記載のHPLC法などにより行うことができる。 The addition amount of the enzyme-treated rutin in the present invention is contained in the fruit juice-containing beverage in the range of 0.00002 to 0.01% by weight in terms of effects such as the flavor deterioration inhibiting effect and the flavor and appearance of the beverage. Preferably, it can be contained in the range of 0.00004 to 0.005% by weight, more preferably 0.0002 to 0.0005% by weight. Quantitative analysis of enzyme-treated rutin in raw materials and beverages can be found in Food Hygiene Magazine Vol. 41 (2000) No. 1, p54-60.
<乳化>
本発明で使用する、トコフェロール、ルテイン、及び酵素処理ルチンのうち、前二者は非水溶性であるため、果汁含有飲料中には溶解しにくいため、飲料原料の調合時に、乳化剤を用いて溶解することができる。乳化剤としては、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、及びポリソルベートの一種又は二種以上を用いることができる。また、均質化処理機のような均質化処理手段を用いることができる。
<Emulsification>
Of the tocopherol, lutein, and enzyme-treated rutin used in the present invention, the former two are water-insoluble, so they are difficult to dissolve in fruit juice-containing beverages. can do. As the emulsifier, one or more of polyglycerin fatty acid ester, sucrose fatty acid ester, and polysorbate can be used. Moreover, a homogenization processing means such as a homogenization processor can be used.
更に、飲料製造の際のハンドリングの良さの点などから、予めこれら三成分と乳化剤を混合して製剤化しておくことが好ましい。製剤化は、各素材毎におこなうこともできるし、うち二者又は三者をまとめておこなうことができるが、三者ともまとめて製剤化しておくことがより好ましい。上記乳化剤を、水、多価アルコール又はそれらの混合物中に、溶解させた後、必要な量のトコフェロール、ルテイン、及び酵素処理ルチンを添加し、常法に従って乳化装置を用いて乳化することにより得られる。ここで、多価アルコールとは、分子内に2個以上の水酸基を持つ化合物の総称であり、グリセリン、プロピレングリコール、ソルビトール、マルチトールなどが例示できる。 Furthermore, it is preferable that these three components and an emulsifier are mixed and formulated in advance from the viewpoint of good handling during beverage production. Formulation can be performed for each material, and two or three of them can be performed together, but it is more preferable to formulate all three together. After the above emulsifier is dissolved in water, a polyhydric alcohol or a mixture thereof, the necessary amounts of tocopherol, lutein, and enzyme-treated rutin are added and emulsified using an emulsifier according to a conventional method. It is done. Here, the polyhydric alcohol is a general term for compounds having two or more hydroxyl groups in the molecule, and examples thereof include glycerin, propylene glycol, sorbitol, and maltitol.
<容器詰め果汁含有飲料の製造方法>
常法に従い、果汁含有飲料の原料を、トコフェロール、ルテイン、及び酵素処理ルチンを含めて他の原料と一緒に、混合して溶解する。この後、必要な殺菌をおこなった後容器に充填するか、容器に充填してから必要な殺菌をおこなう。容器は、通常の容器詰め飲料で使用する、缶容器、ペットボトル、ガラスビン、紙容器など、いずれも使用可能である。本発明の効果である、光劣化抑制効果を有効に活用するという点では、光透過性のある、透明なガラスビンやペットボトルなどの容器を使用することが望ましい。
<Method for producing container-packed fruit juice-containing beverage>
According to a conventional method, the ingredients of the fruit juice-containing beverage are mixed and dissolved together with other ingredients including tocopherol, lutein, and enzyme-treated rutin. Then, after performing necessary sterilization, the container is filled, or after filling the container, necessary sterilization is performed. As the container, any of cans, plastic bottles, glass bottles, paper containers, and the like used in ordinary container-packed beverages can be used. From the viewpoint of effectively utilizing the effect of suppressing light degradation, which is an effect of the present invention, it is desirable to use a transparent glass bottle or a plastic bottle such as a plastic bottle.
以下に実施例を示して、本発明を具体的に説明するが、本発明は、この実施例に限定されるものではない。 EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples.
<香味劣化抑制用製剤の調製例>
グリセリン76.95gにイオン交換水10gとデカグリセリンモノミリステート5.0gと酵素処理ルチン2.0gを添加し、60℃に加温して融解した。これにトコフェノール6.0gとルテイン0.05gを添加して、ホモミキサーで高速攪拌して乳化させ、香味劣化抑制用製剤100gを調製した。
<Preparation example of preparation for inhibiting flavor deterioration>
To 76.95 g of glycerin, 10 g of ion-exchanged water, 5.0 g of decaglycerin monomyristate and 2.0 g of enzyme-treated rutin were added and heated to 60 ° C. to melt. Tocophenol 6.0g and lutein 0.05g were added to this, it emulsified by high-speed stirring with a homomixer, and 100g of flavor deterioration suppression preparations were prepared.
<容器詰め果汁含有飲料1>
表1に示す原料(アンズ果汁)にイオン交換水を加え、合計1000mLの飲料調合液を調製した。なお、香味劣化抑制用製剤として、前記調製例に記載した香味劣化抑制用製剤を用いた。比較例1、比較例2は、香味劣化抑制用製剤の添加なし、比較例3、実施例1は、香味劣化抑制用製剤(トコフェロール:0.120%;ルテイン:0.001%;酵素処理ルチン:0.04%)を添加した。これらの調合液に対し更にそれぞれの調合液をUHT殺菌してから、透明なガラスビン容器に充填して、容器詰め果汁含有飲料を調製した。調製した果汁含有飲料のうち、サンプル2(比較例)及びサンプル4(実施例)を、3000ルクス(LX)の曝光下で、12日間の光照射を実施し、サンプル1(比較例)、サンプル3(比較例3)は、光照射を実施しなかった。結果を、熟練した社内パネラー3名により官能評価を実施した。
<Contained fruit juice-containing beverage 1>
Ion exchange water was added to the raw material (apricot juice) shown in Table 1 to prepare a total of 1000 mL of beverage preparation. In addition, the preparation for flavor deterioration suppression described in the said preparation example was used as a preparation for flavor deterioration suppression. Comparative Example 1 and Comparative Example 2 have no addition of a flavor deterioration inhibiting preparation, Comparative Example 3 and Example 1 have a flavor deterioration inhibiting preparation (tocopherol: 0.120%; lutein: 0.001%; enzyme-treated rutin) : 0.04%) was added. Each of these preparations was further UHT sterilized with respect to these preparations, and then filled into a transparent glass bottle container to prepare a container-packed fruit juice-containing beverage. Among the prepared fruit juice-containing beverages, Sample 2 (Comparative Example) and Sample 4 (Example) were subjected to light irradiation for 12 days under an exposure of 3000 lux (LX), and Sample 1 (Comparative Example) and Sample 3 (Comparative Example 3) was not irradiated with light. The results were subjected to sensory evaluation by three skilled in-house panelists.
(結果)
光劣化臭の抑制効果を◎○△×の4段階で絶対評価した。光劣化が感じられないものを◎、光劣化臭がほとんど感じられないものを○、光劣化臭をやや感じるものを△、光劣化臭をはっきりと感じるものを×として、パネラー3名の平均を求めた。その結果を、表1に示す。表1に示されるとおり、実施例1では、トコフェロール、ルテイン、酵素処理ルチンを所定濃度で含有させることにより、12日間の光照射を実施した後でも、光劣化臭がほとんど感じられず、果汁含有飲料の香味特徴が十分に感じられる飲料であった。
(result)
The effect of suppressing the photodegradation odor was absolutely evaluated in four stages of ◎ ○ △ ×. The average of three panelists was defined as ◎ for those that did not feel light deterioration, ○ for those that hardly felt light deterioration odors, △ for those that slightly felt light deterioration odors, and × for those that clearly felt light deterioration odors. Asked. The results are shown in Table 1. As shown in Table 1, in Example 1, by containing tocopherol, lutein, and enzyme-treated rutin at a predetermined concentration, even after 12 days of light irradiation, almost no photodegradation odor was felt and fruit juice contained It was a beverage that sufficiently felt the flavor characteristics of the beverage.
<容器詰め果汁含有飲料2>
表2に示す処方のようにトコフェロール、ルテイン、酵素処理ルチンの量を変化させ、果汁含有飲料のサンプルを調製した。比較例4は香味劣化抑制用製剤を添加せず、実施例2、実施例3、実施例4は表2の通り香味劣化抑制用製剤を添加した。比較例4、実施例2、実施例3、実施例4のそれぞれのサンプルをUHT殺菌をした後に透明なガラスビン容器に充填し、6000ルクスの曝光下で7日間の光照射を実施した。実施例1と同様に、熟練した社内パネラー6名により官能評価を実施した。
<Contained fruit juice-containing beverage 2>
Samples of fruit juice-containing beverages were prepared by changing the amounts of tocopherol, lutein, and enzyme-treated rutin as shown in Table 2. Comparative Example 4 did not add a flavor deterioration inhibiting formulation, and Example 2, Example 3, and Example 4 added flavor deterioration inhibiting formulations as shown in Table 2. Each sample of Comparative Example 4, Example 2, Example 3, and Example 4 was UHT sterilized, then filled into a transparent glass bottle container, and irradiated with light for 7 days under an exposure of 6000 lux. In the same manner as in Example 1, sensory evaluation was performed by six skilled in-house panelists.
(結果)
結果を表2に示す。表2に示される通り、トコフェロール、酵素処理ルチン、ルテインの量を調整することにより、光に曝露した後でも光劣化臭がほとんど感じられず、果汁含有飲料の香味特徴が十分に感じられる飲料であった。
(result)
The results are shown in Table 2. As shown in Table 2, by adjusting the amount of tocopherol, enzyme-treated rutin, and lutein, it is a beverage that can hardly feel a light-degraded odor even after exposure to light, and can sufficiently feel the flavor characteristics of a fruit juice-containing beverage. there were.
本発明は、光透過性容器詰め等の製品形態において、流通、販売が行われる果汁含有飲料(ただし、柑橘系飲料を除く)においても、香気成分の光劣化が有効に抑制されて、保存後もフレッシュな香味を有する容器詰めの果汁含有飲料を提供し、果汁含有飲料自体の本来の香味である爽やかな香味を保持した、香気に優れ、安定性の高い果汁含有飲料を提供する。 In the product form such as light transmissive container packing, the present invention effectively suppresses the light deterioration of the aroma component even in fruit juice-containing beverages that are distributed and sold (except for citrus beverages), and after storage. In addition, a container-packed fruit juice-containing beverage having a fresh flavor is provided, and a fruit juice-containing beverage with excellent aroma and high stability that retains the refreshing flavor that is the original flavor of the fruit juice-containing beverage itself.
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016079042A JP2017189119A (en) | 2016-04-11 | 2016-04-11 | Fruit juice-containing beverage having suppressed photodegradation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016079042A JP2017189119A (en) | 2016-04-11 | 2016-04-11 | Fruit juice-containing beverage having suppressed photodegradation |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2017189119A true JP2017189119A (en) | 2017-10-19 |
Family
ID=60084247
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016079042A Pending JP2017189119A (en) | 2016-04-11 | 2016-04-11 | Fruit juice-containing beverage having suppressed photodegradation |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2017189119A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020044912A1 (en) * | 2018-08-31 | 2020-03-05 | サントリーホールディングス株式会社 | Alcoholic beverage in selectively light-blocking container |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001097624A1 (en) * | 2000-06-20 | 2001-12-27 | Calpis Co., Ltd. | Acidic milky drink |
JP2002078447A (en) * | 2000-06-22 | 2002-03-19 | Riken Vitamin Co Ltd | Milk beverage packed in transparent container |
JP2010209240A (en) * | 2009-03-11 | 2010-09-24 | Toyo Seito Kk | Rutin derivative composition and method of producing the same and use of the same |
JP2012527897A (en) * | 2009-05-28 | 2012-11-12 | カーギル・インコーポレイテッド | Monatin sweetened beverage that can be stored at room temperature for a long time |
JP2013055891A (en) * | 2011-09-07 | 2013-03-28 | Riken Vitamin Co Ltd | Flavor deterioration inhibitor for food and drink containing fruit juice |
JP2014168401A (en) * | 2013-03-01 | 2014-09-18 | Calpis Co Ltd | White grape juice-containing beverage |
JP2017169500A (en) * | 2016-03-24 | 2017-09-28 | 太陽化学株式会社 | Emulsion composition for food and drinks containing fruit juice polyphenol |
-
2016
- 2016-04-11 JP JP2016079042A patent/JP2017189119A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001097624A1 (en) * | 2000-06-20 | 2001-12-27 | Calpis Co., Ltd. | Acidic milky drink |
JP2002078447A (en) * | 2000-06-22 | 2002-03-19 | Riken Vitamin Co Ltd | Milk beverage packed in transparent container |
JP2010209240A (en) * | 2009-03-11 | 2010-09-24 | Toyo Seito Kk | Rutin derivative composition and method of producing the same and use of the same |
JP2012527897A (en) * | 2009-05-28 | 2012-11-12 | カーギル・インコーポレイテッド | Monatin sweetened beverage that can be stored at room temperature for a long time |
JP2013055891A (en) * | 2011-09-07 | 2013-03-28 | Riken Vitamin Co Ltd | Flavor deterioration inhibitor for food and drink containing fruit juice |
JP2014168401A (en) * | 2013-03-01 | 2014-09-18 | Calpis Co Ltd | White grape juice-containing beverage |
JP2017169500A (en) * | 2016-03-24 | 2017-09-28 | 太陽化学株式会社 | Emulsion composition for food and drinks containing fruit juice polyphenol |
Non-Patent Citations (1)
Title |
---|
"Carotenoid pigments in acerola fruits (Malpighia emarginata DC.) and derived products", EUROPEAN FOOD RESEARCH & TECHNOLOGY, vol. 220, JPN6019045366, 28 October 2004 (2004-10-28), DE, pages 63 - 69, ISSN: 0004204084 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020044912A1 (en) * | 2018-08-31 | 2020-03-05 | サントリーホールディングス株式会社 | Alcoholic beverage in selectively light-blocking container |
JP2020031610A (en) * | 2018-08-31 | 2020-03-05 | サントリーホールディングス株式会社 | Alcoholic beverage in package that selectively suppresses light transmission |
JP7038028B2 (en) | 2018-08-31 | 2022-03-17 | サントリーホールディングス株式会社 | Alcoholic beverage in a selective light transmission suppression container |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2024063243A (en) | Container-packaged beverage | |
KR100768697B1 (en) | Acidic milky drink | |
JP6132594B2 (en) | White grape juice drink | |
JP6829935B2 (en) | Alcoholic beverage | |
JP3683880B2 (en) | Degradation preventive agent for flavor components | |
JP2018191581A (en) | Bitterness inhibitor | |
WO2004045309A1 (en) | Method of preventing flavor component from degradation | |
JP2004166632A (en) | Deterioration preventing agent for flavor component | |
JP4257022B2 (en) | Food flavor deterioration inhibitor and method | |
JP6886238B2 (en) | Citrus beverage with suppressed photodegradation | |
JP5820681B2 (en) | Bitter taste inhibitor | |
JP2017189119A (en) | Fruit juice-containing beverage having suppressed photodegradation | |
Silva et al. | Food additives used in non-alcoholic water-based beverages—A review | |
JP6684588B2 (en) | Beverage containing methoxyflavone | |
JP6429749B2 (en) | Beverage containing enzyme-treated isoquercitrin | |
JP2016198007A (en) | Carotenoid and flavor deterioration inhibitor for carotenoid-containing food | |
JP4605949B2 (en) | Degradation preventive agent for flavor components | |
JP2019136008A (en) | Artemisia absinthium extract | |
EP2987416A1 (en) | Flavor deterioration inhibitor | |
JP7282560B2 (en) | Composition for suppressing deterioration of flavor or flavor of food and drink, and method for suppressing deterioration | |
JP2004292778A (en) | Flavor deterioration inhibitor | |
JP2006340639A (en) | Agent for suppressing decrease of flavor | |
JP4912578B2 (en) | Anti-browning agent | |
JP7249764B2 (en) | LIQUID COMPOSITION CONTAINING POLYPHENOLS AND SUPPRESSED PRECIPITATION | |
JP4139969B2 (en) | Fading inhibitor |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20190206 |
|
A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A712 Effective date: 20190723 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20191115 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20191121 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20200116 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20200203 |