JP2017154992A - Liquid composition having action of controlling insect pest and method for producing the same, agent for controlling insect pest, and method for controlling insect pest - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a liquid composition exhibiting an action of controlling insect pests.SOLUTION: A method for producing a liquid composition includes: a mixture step of mixing mineral functional water containing mineral containing water (A) containing a mineral component eluted from a mineral imparting material (A) containing a plant raw material and a woody plant raw material and mineral containing water (B) containing a mineral component eluted from an inorganic mineral imparting material (B), and a saccharide solution containing a sugar component to obtain a mineral saccharide mixed solution; and an electrolysis step of inserting a positive electrode and a negative electrode into the mineral saccharide mixed solution, and applying a direct-current voltage to the positive electrode and the negative electrode to electrolyze the mineral saccharide mixed solution. The obtained liquid composition exhibits an excellent action of controlling insect pests, particularly, Diptera.SELECTED DRAWING: None

Description

  The present invention relates to a liquid composition having a pest control action, a method for producing the same, a pest control agent containing this as an active ingredient, and a pest control method.

  Conventionally, various pest control agents have been developed to control pests such as mosquitoes and flies (for example, Patent Documents 1 to 3). On the other hand, from the viewpoint of safety to humans and livestock and influence on the environment, attempts have been made to use natural raw materials as active ingredients of pest control agents, not synthetic compounds.

On the other hand, water containing mineral components may have effects such as soil improvement, plant growth, harmful chemical decomposition, deodorization, air purification, etc. Production facilities for mineral water and mineral water have been developed.
The inventor immerses the conductive wire and the mineral-imparting material (A) coated with an insulator in water, causes a direct current to flow through the conductive wire, and the water around the conductive wire has the same direction as the direct current. Means for forming a raw mineral aqueous solution (A) by applying ultrasonic vibration to the water, and irradiating the formed raw mineral aqueous solution (A) with far infrared rays to contain mineral-containing water (A) A mineral-containing water production apparatus (A) comprising a far-infrared light generating means for forming a water is developed (see Patent Document 4).
In addition, the present inventors communicate the mineral-containing water production apparatus (A), a plurality of water containers filled with different types of mineral imparting materials (B), and the plurality of water containers in series. A water supply path, a bypass water passage connected to the water supply path in parallel with each of the plurality of water flow containers, and a water flow switching valve provided at a branch portion of the water supply path and the bypass water path, respectively. Mineral functional water production equipment equipped with a mineral-containing water production apparatus (B) has been developed (see Patent Document 5). And if the said mineral functional water manufacturing facility is used, it has been reported that the mineral functional water (far infrared generation water) which has the function to generate | occur | produce the far infrared rays of a characteristic wavelength can be manufactured. Moreover, the present inventors used the mineral functional water manufacturing equipment disclosed by patent document 5, and as a result of repeating examination centering on the kind and compounding ratio of a mineral provision material, the mineral function manufactured on the specific condition. It has been reported that water exhibits an excellent control action against unicellular organisms and viruses (Patent Document 6).

Special table 2010-535230 gazette JP 2004-75657 A JP-A-9-175905 Japanese Patent No. 4817817 JP 2011-56366 A Japanese Patent No. 5864010

As mentioned above, various mineral-containing waters have been reported so far, but the effect of mineral-containing water has not been scientifically verified, and the true action of mineral-containing water has not been achieved yet. There are many parts that are not clarified. For this reason, some conventional mineral-containing water does not actually have an effect, while it has an effect, and even if it has an effect, it is insufficient for practical use or has a poor reproducibility. Not a few.
Even in the mineral functional water produced in the devices reported in Patent Documents 4 and 5, it could not be said that mineral functional water that expresses the target effective efficacy could be produced reliably. In particular, the mineral component materials used in the mineral-containing water production apparatuses (A) and (B) reported in Patent Document 5 are involved in a complicated manner and the mixing ratio of the mineral components (mineral-imparting materials). In fact, it was not always clear what kind of effect functional mineral water can be obtained by using. And until now, the control action on arthropods such as insects with mineral functional water has not been studied.

  Under such circumstances, an object of the present invention is to provide a liquid composition exhibiting a pest control action and a method for producing the same. Another object of the present invention is to provide a pest control agent and a pest control method using the same.

  As a result of intensive studies to solve the above problems, the present inventor is obtained by applying a direct current voltage to a mixed solution of mineral functional water produced by a specific production method and a sugar solution containing a sugar component. The present inventors have found that an excellent pest control action is expressed in the liquid composition and have reached the present invention.

That is, the present invention relates to the following inventions.
<1> The mineral-containing water (A) formed in the following step (1) and the mineral-containing water (B) formed in the following step (2) are 1: 7 to 1:12 (weight ratio). ) And a saccharide solution containing a saccharide component are mixed at a ratio of 5 to 20 parts by weight with respect to 1 part by weight of the mineral functional water, A mixing step for obtaining a carbohydrate mixed solution;
An electrolysis step of electrolyzing the mineral sugar mixed solution by inserting a positive electrode and a negative electrode into the mineral sugar mixed solution, applying a direct current voltage between the positive electrode and the negative electrode,
The manufacturing method of the liquid composition containing this.
Step (1):
Conductive wire covered with an insulator, a vegetation plant material composed of a plant of the family Asteraceae and a plant of the family Rosaceae, and a tree of a plant composed of at least one kind selected from maple, birch, pine and cedar Mineral-imparting material (A) containing a plant raw material is immersed in water, a direct current is conducted to the conductive wire, a water flow in the same direction as the direct current is generated in the water around the conductive wire, A process of forming a raw mineral aqueous solution (A) by applying ultrasonic vibration to water, and then irradiating the raw mineral aqueous solution (A) with far infrared rays (wavelength 6 to 14 μm) to form mineral-containing water (A). Because
The addition amount of the mineral-imparting material (A) with respect to water is 10 to 15% by weight, and the current value and voltage value in direct current conducted to the conductive wire are in the range of 0.05 to 0.1 A and 8000 to 8600 V, respectively. And
Mineral imparting material (A)
As the plant material, wild thistle (leaf, stem and flower): 8 to 12% by weight, mugwort (leaf and stem), and camellia (leaf and stem) are 8 to 12% by weight, respectively. A dried pulverized product of Asteraceae plants mixed in a proportion of 55 to 65% by weight and 27 to 33% by weight, dried and pulverized, and
17-23 wt%, 8-12 wt%, 65-75 wt% of Neubara (leaves, flowers), radish (leaves and stems), and raspberries (leaves, stems, and flowers), respectively Use a dry pulverized product of a rose family plant mixed and dried at a ratio of
A plant material (A1) obtained by mixing the dried pulverized product of the Asteraceae plant and the dried pulverized product of the Rosaceae plant at a ratio of 1: 0.8 to 1: 1.2 (weight ratio);
As the woody plant raw material, maple (leaves and stems), birch (leaves, stems and bark), cedar (leaves, stems and bark), 22 to 28% by weight, A woody plant raw material (A2) composed of a dried pulverized product mixed at a ratio of 22 to 28% by weight and 45 to 55% by weight, dried and pulverized,
The process which is a mineral provision material (A ') obtained by mixing so that it may become 1: 2.7-1: 3.3 by the weight ratio of a plant plant raw material (A1) and a woody plant raw material (A2). 2):
Mineral-containing water by passing water through six water-flowing containers from the first water-flowing container to the sixth water-flowing container that are filled with different types of inorganic mineral-imparting materials (B) and connected in series. Forming (B), comprising:
In the six water containers,
The mineral-providing material (B1) in the first water-container contains 65 to 75% by weight, 12.5 to 17.5% by weight, and 12.5 to 17.5% by weight of limestone, fossilized coral, and shell, respectively. blend,
The mineral-imparting material (B2) in the 2nd water flow container is 37-43 weight%, 12.5-17.5 weight%, 37-43 weight%, 2.5 limestone, a fossil coral, a shell, and activated carbon, respectively. A mixture comprising -7.5% by weight,
The mineral-imparting material (B3) in the third water container contains limestone, fossilized coral, and shell, respectively, 75 to 85% by weight, 12.5 to 17.5% by weight, and 2.5 to 7.5% by weight. blend,
The mineral-imparting material (B4) in the fourth water container contains 85 to 95% by weight, 2.5 to 7.5% by weight, and 2.5 to 7.5% by weight of limestone, fossilized coral, and shell, respectively. blend,
The mineral-providing material (B5) in the fifth water-container contains limestone, fossilized coral, and shell as 75 to 85% by weight, 7.5 to 12.5% by weight, and 7.5 to 12.5% by weight, respectively. blend,
A mixture in which the mineral-imparting material (B6) in the sixth water container contains 55 to 65 wt%, 27 to 33 wt%, and 7.5 to 12.5 wt% of limestone, fossilized coral, and shells,
<2> The method for producing a liquid composition according to <1>, wherein the functional mineral water is mineral functional water CAC-717 manufactured by Riken Techno System Co., Ltd.
<3> The method for producing a liquid composition according to <1> or <2>, wherein the carbohydrate solution contains at least glucose and fructose as a carbohydrate component.
<4> The liquid according to any one of <1> to <3>, wherein the carbohydrate solution contains a carbohydrate component obtained by adding an acid aqueous solution to a pulverized maple bark to hydrolyze it and separating it from lignin. A method for producing the composition.
<5> The method for producing a liquid composition according to <3> or <4>, which is a saccharide solution adjusted to pH 4 to 5.
<6> The method for producing a liquid composition according to any one of <1> to <5>, wherein in the electrolysis step, the positive electrode and the negative electrode are platinum electrode plates.
<7> The method for producing a liquid composition according to any one of <1> to <6>, wherein the applied voltage is DC 10 V or more.
<8> A liquid composition comprising a step of evaporating water and / or adding a monosaccharide to a liquid composition having a pH of 4 to 5 produced by any one of the methods <1> to <7> until the pH is 5 to 6. A method for concentrating the composition.

<9> A liquid composition produced by the method according to any one of <1> to <7> and having a pest control action, having a pH of 4 to 5.
<10> A pest control agent comprising the liquid composition according to <9> as an active ingredient.
<11> The control agent according to <10>, wherein the pest to be controlled is a diptera pest.
<12> A method for controlling pests, wherein the liquid composition according to <9> or the control agent according to <10> is applied to a pest or a pest habitat.
<13> The pest control method according to <12>, wherein the pest to be controlled is a diptera pest.

  ADVANTAGE OF THE INVENTION According to this invention, the liquid composition which has effective effects, such as a control effect with respect to a pest, is provided. The pest control agent containing the liquid composition or the liquid composition as an active ingredient exhibits an excellent control action against pests, particularly diptera.

It is a block diagram which shows schematic structure of a mineral functional water manufacturing facility. It is a schematic diagram of the mineral containing aqueous solution manufacturing means which makes a part of the mineral containing water (A) manufacturing apparatus which comprises the mineral functional water manufacturing equipment shown in FIG. FIG. 3 is a partially omitted cross-sectional view taken along line AA in FIG. 2. It is a perspective view which shows the storage container of the mineral provision material (A) used for the raw material mineral aqueous solution manufacturing means shown in FIG. It is a schematic diagram which shows the reaction state of the conductive wire vicinity in the raw material mineral aqueous solution manufacturing means shown in FIG. It is a schematic sectional drawing of the far infrared irradiation apparatus which makes a part of the mineral containing water (A) manufacturing apparatus which comprises the mineral functional water manufacturing equipment shown in FIG. It is a block diagram of the mineral containing water (B) manufacturing apparatus which comprises the mineral functional water manufacturing equipment shown in FIG. It is a front view which shows the mineral containing water (B) manufacturing apparatus which comprises the mineral functional water manufacturing equipment shown in FIG. It is a side view of the mineral containing water (B) manufacturing apparatus shown in FIG. It is a partially-omission perspective view which shows the structure of the mineral containing water manufacturing apparatus (B) shown in FIG. It is a side view of the water flow container which comprises the mineral containing water manufacturing apparatus (B) shown in FIG.

  Hereinafter, the present invention will be described in detail with reference to examples and the like, but the present invention is not limited to the following examples and the like, and can be arbitrarily modified and implemented without departing from the gist of the present invention. In the present specification, “to” is used as an expression including numerical values or physical quantities before and after.

<1. Method for producing liquid composition>
In the present invention, the mineral-containing water (A) formed in the following step (1) and the mineral-containing water (B) formed in the following step (2) are 1: 7 to 1:12 (weight). Ratio) and the mineral functional water contained at a ratio to be mixed with a sugar solution containing a sugar component at a ratio of 5 to 20 parts by weight with respect to 1 part by weight of the mineral functional water, A mixing step for obtaining a mineral sugar mixed solution, and an electrolysis step for electrolyzing the mineral sugar mixed solution by inserting a positive electrode and a negative electrode into the mineral sugar mixed solution and applying a DC voltage between the positive electrode and the negative electrode. When,
(Hereinafter referred to as “the production method of the liquid composition of the present invention” or simply “the production method of the present invention”).

Step (1):
Conductive wire covered with an insulator, a vegetation plant material composed of a plant of the family Asteraceae and a plant of the family Rosaceae, and a tree of a plant composed of at least one kind selected from maple, birch, pine and cedar Mineral-imparting material (A) containing a plant raw material is immersed in water, a direct current is conducted to the conductive wire, a water flow in the same direction as the direct current is generated in the water around the conductive wire, A process of forming a raw mineral aqueous solution (A) by applying ultrasonic vibration to water, and then irradiating the raw mineral aqueous solution (A) with far infrared rays (wavelength 6 to 14 μm) to form mineral-containing water (A). Because
The addition amount of the mineral-imparting material (A) with respect to water is 10 to 15% by weight, and the current value and voltage value in direct current conducted to the conductive wire are in the range of 0.05 to 0.1 A and 8000 to 8600 V, respectively. And
Mineral imparting material (A)
As the plant material, wild thistle (leaf, stem and flower): 8 to 12% by weight, mugwort (leaf and stem), and camellia (leaf and stem) are 8 to 12% by weight, respectively. A dried pulverized product of Asteraceae plants mixed in a proportion of 55 to 65% by weight and 27 to 33% by weight, dried and pulverized, and
17-23 wt%, 8-12 wt%, 65-75 wt% of Neubara (leaves, flowers), radish (leaves and stems), and raspberries (leaves, stems, and flowers), respectively Use a dry pulverized product of a rose family plant mixed and dried at a ratio of
A plant material (A1) obtained by mixing the dried pulverized product of the Asteraceae plant and the dried pulverized product of the Rosaceae plant at a ratio of 1: 0.8 to 1: 1.2 (weight ratio);
As the woody plant raw material, maple (leaves and stems), birch (leaves, stems and bark), cedar (leaves, stems and bark), 22 to 28% by weight, A woody plant raw material (A2) composed of a dried pulverized product mixed at a ratio of 22 to 28% by weight and 45 to 55% by weight, dried and pulverized,
The process which is a mineral provision material (A ') obtained by mixing so that it may become 1: 2.7-1: 3.3 by the weight ratio of a plant plant raw material (A1) and a woody plant raw material (A2).

Step (2):
Mineral-containing water by passing water through six water-flowing containers from the first water-flowing container to the sixth water-flowing container that are filled with different types of inorganic mineral-imparting materials (B) and connected in series. Forming (B), comprising:
In the six water containers,
The mineral-providing material (B1) in the first water-container contains 65 to 75% by weight, 12.5 to 17.5% by weight, and 12.5 to 17.5% by weight of limestone, fossilized coral, and shell, respectively. blend,
The mineral-imparting material (B2) in the 2nd water flow container is 37-43 weight%, 12.5-17.5 weight%, 37-43 weight%, 2.5 limestone, a fossil coral, a shell, and activated carbon, respectively. A mixture comprising -7.5% by weight,
The mineral-imparting material (B3) in the third water container contains limestone, fossilized coral, and shell, respectively, 75 to 85% by weight, 12.5 to 17.5% by weight, and 2.5 to 7.5% by weight. blend,
The mineral-imparting material (B4) in the fourth water container contains 85 to 95% by weight, 2.5 to 7.5% by weight, and 2.5 to 7.5% by weight of limestone, fossilized coral, and shell, respectively. blend,
The mineral-providing material (B5) in the fifth water-container contains limestone, fossilized coral, and shell as 75 to 85% by weight, 7.5 to 12.5% by weight, and 7.5 to 12.5% by weight, respectively. blend,
A mixture in which the mineral-imparting material (B6) in the sixth water container contains 55 to 65 wt%, 27 to 33 wt%, and 7.5 to 12.5 wt% of limestone, fossilized coral, and shells,
Is the process

  The mineral functional water and saccharide solution, which are the raw materials of the production method of the present invention, do not have a significant pest control action alone, but a direct current voltage is applied to the mineral saccharide mixed solution in which these are mixed at a predetermined ratio. By applying and electrolyzing the mineral sugar mixed solution, a significant pest control action is expressed.

  In the present invention, the “pest” means arthropods (including those other than insects) that cause harmful effects on humans, livestock, pets, agricultural products, buildings, and the like. For details, see <2. The use of the liquid composition will be described below.

  Hereinafter, the mixing step and the electrolysis step in the method for producing the liquid composition of the present invention will be described.

<1-1. Mixing process>
A mixing process is a process of mixing the mineral functional water and saccharide solution which are raw materials, and obtaining a mineral saccharide mixed solution.

<Mineral functional water>
“Mineral functional water” is a concept that means that contains a mineral component and expresses at least one effective effect. Hereinafter, in this specification, the mineral functional water used as a raw material of the manufacturing method of the liquid composition of this invention shall be described as "the mineral functional water of this invention", or just "mineral functional water." In addition, the said mineral functional water has at least one of a single cell organism control action and a virus control action as a beneficial effect.

In this specification, “mineral component” does not mean “inorganic component (including trace elements) excluding four elements (carbon, hydrogen, nitrogen, oxygen)”, which is a definition of mineral in a narrow sense, As long as it coexists with an inorganic component, it may contain the four elements (carbon, hydrogen, nitrogen, oxygen) excluded in the narrowly defined definition. Therefore, for example, “a plant-derived mineral component” is a concept including a case where a plant-derived organic component is included together with a plant-derived inorganic component such as calcium.
Moreover, as an inorganic component (composing a mineral component), for example, sodium, potassium, calcium, magnesium, phosphorus, and the like, and trace elements such as iron, zinc, copper, manganese, iodine, selenium, chromium, and molybdenum, respectively. Although it can illustrate, it is not limited to this.

  Moreover, in this specification, "mineral containing water" is the raw material water of the previous step in manufacturing mineral functional water, and mineral containing water also contains a mineral component. Details will be described later as the method for producing mineral functional water of the present invention. The mineral-containing water itself may or may not have an effective effect.

The mineral functional water that is the raw material of the production method of the present invention (the mineral functional water of the present invention) corresponds to the mineral functional water produced by the production method in Patent Document 6 (Patent No. 5864010). The mineral functional water of this invention can be manufactured by the method according to the method disclosed by the literature using the apparatus disclosed by the said patent document 5 (Unexamined-Japanese-Patent No. 2011-56366).
In addition, as a suitable example of the mineral functional water of this invention, the mineral functional water CAC-717 by Riken Techno System Co., Ltd. is mentioned.

  Hereinafter, a preferred embodiment of the method for producing mineral functional water of the present invention using the apparatus disclosed in Patent Document 5 (Japanese Patent Laid-Open No. 2011-56366) will be described with reference to the drawings.

  As shown in FIG. 1, the functional mineral water manufacturing facility 1 is manufactured with a mineral-containing water (A) manufacturing device 2, a mineral-containing water (B) manufacturing device 3, and a mineral-containing water (A) manufacturing device 2. A mixing tank 46 which is a mixing means for mixing the mineral-containing water (A) 44 with the mineral-containing water (B) 45 manufactured by the mineral-containing water (B) manufacturing apparatus 3 to form the mineral functional water 47. ing.

  The mineral-containing water (A) production apparatus 2 produces a raw mineral aqueous solution (A) 41 that forms raw mineral aqueous solution (A) 41 using raw water 11 supplied from water and a mineral-imparting material (A) 12 (see FIG. 4) described later as raw materials. Means 10 and a far infrared ray generating means 43 for irradiating the raw mineral water solution (A) 41 obtained by the raw material mineral aqueous solution production means 10 with far infrared rays to change to mineral-containing water (A) 44.

  The mineral-containing water (B) manufacturing device 3 forms mineral-containing water (B) 45 containing mineral components eluted from the mineral-imparting material by passing water W supplied from outside through the water containers 51 to 56. It has the function to do.

  Hereinafter, the mineral-containing water (A) manufacturing apparatus 2 and the mineral-containing water (B) manufacturing apparatus 3 will be described in detail.

(Mineral-containing water (A) production equipment)
Next, based on FIGS. 2-6, the mineral containing water (A) manufacturing apparatus 2 which comprises the mineral functional water manufacturing equipment 1 shown in FIG. 1 is demonstrated. As shown in FIG. 1, the mineral-containing water (A) production apparatus 2 is a raw mineral aqueous solution (A) 41 using water 11 supplied from water and a mineral-imparting material (A) 12 (see FIG. 4) described later as raw materials. The raw mineral water producing means 10 (see FIG. 2) for forming the water and the mineral-containing water (A) solution 41 obtained by the raw mineral aqueous solution producing means 10 are irradiated with far-infrared rays to change into mineral-containing water (A) 44. And far-infrared light generating means 43 (see FIG. 6).

  As shown in FIG. 2 and FIG. 3, the raw mineral aqueous solution production means 10 includes a reaction vessel 13 that can contain water 11 and a mineral-imparting material (A) 12, and a reaction vessel 13 that is covered with an insulator 14. A conductive wire 15 immersed in the water 11, an ultrasonic generator 16 for applying ultrasonic vibration to the water 11 in the reaction vessel 13, and a direct current power source device for conducting a direct current DC through the conductive wire 15. 17 and circulation paths 18a and 18b and a circulation pump P, which are means for generating a water flow R in the same direction as the direct current DC in the water 11 around the conductive wire 15. The DC power supply device 17, the ultrasonic wave generating means 16, and the circulation pump P are all operated by feeding from a general commercial power source.

  The reaction vessel 13 has an inverted conical cylinder shape with an open top surface, and a drain port 19 is provided at the bottom corresponding to the apex thereof. The drain port 19 has a circulation path 18a communicating with the suction port P1 of the circulation pump P. And an opening degree adjusting valve 20 for adjusting the amount of drainage to the circulation path 18a and a drainage valve 21 for discharging water in the reaction vessel 13 and the like.

  A base end portion of the circulation path 18 b is connected to the discharge port P <b> 2 of the circulation pump P, and a distal end portion of the circulation path 18 b is connected to the storage tank 22. Near the bottom of the outer periphery of the storage tank 22, a base end of a circulation path 18 c for feeding the water 11 in the storage tank 22 into the reaction container 13 is connected, and the distal end of the circulation path 18 c is an opening of the reaction container 13. It is piped at the position facing. The circulation path 18 c is provided with an opening degree adjusting valve 23 for adjusting the amount of water fed from the storage tank 22 to the reaction vessel 13.

  A drain pipe 24 having a drain valve 25 and a water temperature gauge 26 is connected to the bottom of the storage tank 22 in a hanging manner. If the drain valve 25 is opened as necessary, the water in the storage tank 22 can be discharged from the lower end of the drain pipe 24. At this time, the temperature of the water 11 passing through the drain pipe 24 is measured by the water thermometer 26. be able to.

  As shown in FIG. 5, the plurality of conductive cables 29 (29a to 29g) made of the conductive wire 15 and the insulator 14 covering the conductive wire 15 form an annular shape at a plurality of positions with different depths in the reaction vessel 13, respectively. These circular conductive cables 29 a to 29 g are wired and are arranged substantially coaxially with the reaction vessel 13. The inner diameter of each of the conductive cables 29a to 29g is reduced in a stepwise manner in accordance with the inner diameter of the inverted conical cylindrical reaction vessel 13, and has an inner diameter corresponding to each arrangement location. Since each of the conductive cables 29a to 29g is detachably connected to an insulating terminal 30 provided on the wall 13a of the reaction vessel 13, an annular portion can be removed from the terminal 30 as necessary. Can be attached.

  A portion of the reaction vessel 13 corresponding to the axial center is provided with a bottomed cylindrical storage container 31 formed of an insulating network, and the storage container 31 is filled with a mineral-imparting material (A) 12. Has been. The storage container 31 is detachably locked to the upper edge of the wall 13a of the reaction container 13 by a hook 31f provided on the upper part thereof.

  As shown in FIG. 2, conductive cables 29s and 29t are spirally wound around the outer circumferences of the circulation paths 18a and 18b, respectively, and a DC current DC is supplied from the DC power supply device 17 to these conductive cables 29s and 29t. The The direction of the direct current DC flowing through the conductive cables 29s and 29t is set so as to substantially coincide with the direction of the water flow flowing through the circulation paths 18a and 18b.

  In the raw mineral water aqueous solution manufacturing means 10, a predetermined amount of water 11 is placed in the reaction container 13 and the storage tank 22, and the storage container 31 filled with the mineral-imparting material (A) 12 is set in the center of the reaction container 13. Thereafter, the circulation pump P is operated, and the opening degree adjusting valve 20 at the bottom of the reaction vessel 13 and the opening degree adjusting valve 23 of the circulation path 18c are adjusted so that the drain port 19, the circulation path 18a, and the circulation pump P Then, the water 11 is circulated so as to return to the upper part of the reaction vessel 13 again via the circulation path 18b, the storage tank 22 and the circulation path 18c. Then, when the DC power supply device 17 and the ultrasonic wave generation means 16 are operated, the elution reaction of the mineral component from the mineral applying material (A) 12 in the storage container 31 to the water 11 starts.

The working conditions for producing the raw mineral aqueous solution (A) using the raw mineral aqueous solution production means 10 are not particularly limited, but in this embodiment, the raw mineral aqueous solution (A) was produced under the following working conditions. .
(1) A DC current DC having a voltage of 8000 to 8600 V and a current of 0.05 to 0.1 A was conducted to the conductive cables 29, 29s, and 29t. The insulator 14 constituting the conductive cable 29 and the like is made of polytetrafluoroethylene resin.
(2) The mineral-imparting material (A) 12 filled in the reaction vessel 13 is filled 10 to 15% by mass with respect to the water 11. Specific description of the mineral-imparting material (A) 12 will be described later.
(3) The water 11 should just contain an electrolyte so that direct current DC may act. For example, about 10 g of sodium carbonate, which is an electrolyte, is used for 100 liters of water. However, ground water can be used as it is.
(4) The ultrasonic wave generation means 16 generates an ultrasonic wave having a frequency of 30 to 100 kHz, and the ultrasonic vibration part (not shown) directly touches the water 11 in the reaction vessel 13 and vibrates. Ultrasonic wave generation means 16 is arranged.

  When the raw mineral water producing means 10 is operated under such conditions, a water flow R sucked into the drain port 19 while rotating in the left-handed direction is generated in the reaction vessel 13, and the water discharged from the drain port 19 is generated. 11 continues to return to the reaction vessel 13 again via the circulation paths 18a and 18b described above.

  Therefore, the mineral component from the mineral-imparting material (A) 12 is quickly brought into the water 11 by the stirring action by the water flow R, the action of the direct current flowing through the conductive cable 29 and the ultrasonic vibration applied to the water 11 by the ultrasonic wave generation means 16. The raw mineral aqueous solution (A) in which the required mineral components are appropriately dissolved can be efficiently produced.

  In the raw mineral aqueous solution production means 10, a plurality of annular conductive cables 29 a to 29 g are wired substantially coaxially in the reaction vessel 13, and a water flow R that rotates in the left-handed screw direction in the reaction vessel 13 is generated. ing. Therefore, a relatively dense electric energy field can be formed in the reaction container 13 having a constant volume, and the raw mineral aqueous solution (A) can be efficiently produced in the reaction container 13 having a relatively small volume. .

  In addition, since the reaction vessel 13 has an inverted conical cylindrical shape, the water flow R flowing along the plurality of annular conductive cables 29a to 29g can be generated relatively easily and stably, whereby the mineral component Is promoted. Further, since the flow rate of the water flow R flowing in the inverted conical cylindrical reaction vessel 13 increases toward the drain port 19 at the bottom of the reaction vessel 13, the contact frequency with the mineral imparting material (A) 12 also increases. It is possible to increase the amount of mineral that captures and ionizes the free electrons e present in the water 11.

  Further, since the storage tank 22 for discharging the water 11 while storing it is provided between the circulation paths 18b and 18c, the mineral elution reaction can be advanced while circulating the amount of water 11 exceeding the volume of the reaction vessel 13. Is possible. For this reason, raw material mineral aqueous solution (A) can be mass-produced efficiently.

  When the circulation pump P is continuously operated to continue these reactions, the raw mineral aqueous solution (A) from which the mineral components are eluted is finally generated. Depending on the size of the drain outlet 19 at the bottom of the reaction vessel 13, the amount of circulating water, the shape of the reaction vessel 13 (particularly, the angle γ formed between the axis C shown in FIG. 2 and the wall 13 a), etc. The appearance state of the electrons e can be controlled, and the water solubility of the mineral component is influenced by the action of the free electrons e on the mineral-imparting material (A) 12.

  If raw material mineral aqueous solution (A) is formed, this raw material mineral aqueous solution (A) 41 will be moved in the processing container 40 shown in FIG. In this case, the residue of the mineral-imparting material (A) 12 leaked from the storage container 31 in the reaction container 13 can be discharged from the drain valve 21 at the bottom of the reaction container 13. The raw mineral aqueous solution (A) 41 accommodated in the processing container 40 is irradiated with far-infrared rays by the far-infrared light generating means 43 disposed inside the processing container 40 while being slowly stirred by the stirring blade 42.

  The far-infrared light generating means 43 only needs to generate far-infrared light having a wavelength of about 6 to 14 μm, and any material or generating means may be used. However, it is desirable to have a radiation ratio of 85% or more with respect to black body radiation in the wavelength range of 6 to 14 μm at 25 ° C.

  In the raw material aqueous mineral solution manufacturing means 10 shown in FIG. 2, the mineral component contained in the mineral-imparting material (A) 12 is quickly brought about by the stirring action by the water flow R, the action of the direct current DC flowing through the conductive wire 15 and the ultrasonic vibration. By eluting into the water 11, the required mineral components are appropriately dissolved, and the mineral aqueous solution 41 can be produced efficiently.

  Then, in the far-infrared ray generating means 43 shown in FIG. 6, the mineral-containing water (A) 44 whose electronegativity is increased by irradiating the mineral aqueous solution 41 with far-infrared rays to fuse dissolved mineral components and water molecules. Is formed.

  In the mineral-containing water (A) production apparatus 2, the mineral-containing water (A) 44 formed by the above-described process is fed into the mixing tank 46 via the water supply path 57y as shown in FIG. In 46, it mixes with the mineral containing water (B) 45 sent from the mineral containing water (B) manufacturing apparatus 3. FIG.

Hereinafter, the mineral imparting material (A) will be described.
The mineral-imparting material (A) is a vegetative plant material consisting of a plant family of asteraceae and a plant family of rose family, and a vegetation plant material consisting of one or more kinds of tree plants selected from maple, birch, pine and cedar. Containing. As the site to be used, a site where mineral components such as leaves, stems, flowers, and bark are easy to elute is appropriately selected and may be used as it is, or may be used as a dried product.
In addition to other plant plants other than the Asteraceae and the Rosaceae, other plant plants may be included, but it is preferable that only the plants of the Asteraceae and Rose family are included. For example, for unknown reasons, the addition of cruciferous and pine family plants greatly reduces the control effect of single-cell organisms, which is one of the useful effects of the mineral functional water of the present invention.

An example of the mineral imparting material (A) is a mineral imparting material (A ′). Mineral-imparting material (A ') is a wild thistle (leaf part, stem part and flower part): 8 to 12% by weight, mugwort (leaf part and stem part), camellia (leave part and stem part) ), 8-12% by weight, 55-65% by weight, and 27-33% by weight, respectively, and dried and pulverized Asteraceae plants crushed after drying, and
17-23 wt%, 8-12 wt%, 65-75 wt% of Neubara (leaves, flowers), radish (leaves and stems), and raspberries (leaves, stems, and flowers), respectively Use a dry pulverized product of a rose family plant mixed and dried at a ratio of
A plant material (A1) obtained by mixing the dried pulverized product of the Asteraceae plant and the dried pulverized product of the Rosaceae plant at a ratio of 1: 0.8 to 1: 1.2 (weight ratio);
As the woody plant raw material, maple (leaves and stems), birch (leaves, stems and bark), cedar (leaves, stems and bark), 22 to 28% by weight, A woody plant raw material (A2) composed of a dried pulverized product mixed at a ratio of 22 to 28% by weight and 45 to 55% by weight, dried and pulverized,
It is the mineral provision material obtained by mixing so that it may become 1: 2.7-1: 3.3 by the weight ratio of a plant plant raw material (A1) and a woody plant raw material (A2).

Among the mineral-providing materials (A ′), in particular, as the plant plant material, field thistle (leaves, stems and flowers), mugwort (leaves and stems), and camellia (leaves and stems), 10% by weight, 60% by weight, and 30% by weight of each mixture, dried and pulverized Asteraceae plants crushed, dried roses (leaves, flowers), radish (leaves and leaves) Stem part), raspberry (leaf part, stem part and flower part) were mixed at a ratio of 20% by weight, 10% by weight and 70% by weight, respectively, dried and pulverized after drying, Plant and plant material (A1) obtained by mixing at 1: 1 (weight ratio);
As the woody plant material, maple (leaves and stems), birch (leaves, stems, and bark), and cedar (leaves, stems, and bark) are 25% by weight and 25% respectively. %, 50% by weight of the mixture, dried and pulverized, and then the woody plant material (A2) comprising the plant material (A1) and the woody plant material (A2) It is preferable that it is a mineral provision material obtained by mixing so that it may become 1: 3.
As such plant and plant material (A1), “P-100 (product number)” manufactured by Riken Techno System Co., Ltd., and “P-200 (product number)” manufactured by Riken Techno System Co., Ltd. as the tree plant material (A2). It can be preferably used.

(Mineral-containing water (B) production equipment)
Next, based on FIG. 1, FIG. 7, the structure of the mineral containing water (B) manufacturing apparatus 3, a function, etc. are demonstrated.
As shown in FIGS. 1 and 7, the mineral-containing water (B) manufacturing apparatus 3 includes first to sixth water flow containers 51 to 56 filled with different types of mineral-imparting materials (B), A water supply path 57 that connects the first water flow container 51 to the sixth water flow container 56 in series, and a detour connected to the water flow path 57 in parallel with the first water flow container 51 to the sixth water flow container 56, respectively. Water channels 51p to 56p, and water flow switching valves 51v to 56v provided at branch portions of the bypass water channels 51p to 56p and the water supply channel 57, respectively.

  The switching operation of the water flow switching valves 51v to 56v is executed by operating the six switching buttons 51b to 56b provided on the operation panel 58 connected to the water flow switching valves 51v to 56v by the signal cable 59. Can do. Since the six switching buttons 51b to 56b and the six water flow switching valves 51v to 56v correspond to each number, if one of the switching buttons 51b to 56b is operated, the water flow corresponding to that number is operated. The switching valves 51v to 56v are switched to change the water flow direction.

Here, the mineral-imparting materials (B) 51m to 56m can be preferably produced by mixing raw materials based on limestone, fossilized corals and shells.
First, components contained in limestone, fossil coral, and shells are analyzed, and the amounts of silicon dioxide, iron oxide, activated carbon, titanium nitride, calcium carbonate, magnesium carbonate, and calcium phosphate are evaluated. And based on content of each component, a limestone, a fossilized coral, and a shell are mixed and a mineral provision material (B) 51m-56m is manufactured.
In addition, although it is desirable to control the component contained according to the mixing ratio of limestone, fossil coral, and shells in the mineral imparting material (B) 51m to 56m, the limestone, fossil coral, and shells as raw materials are contained depending on the production area. Therefore, if necessary, silicon dioxide, iron oxide, activated carbon, titanium nitride, calcium carbonate, magnesium carbonate, and calcium phosphate may be added. In particular, activated carbon is usually added separately because it is hardly contained in limestone, fossilized coral, and shells.

As a mineral provision material (B) 51m-56m,
A mixture in which the mineral-imparting material (B1) in the first water flow container 51 contains limestone, fossilized coral, and shells by 70 wt%, 15 wt%, and 15 wt%, respectively;
A mixture in which the mineral-imparting material (B2) in the second water flow container 52 contains limestone, fossilized coral, shell, activated carbon, 40% by weight, 15% by weight, 40% by weight, and 5% by weight,
A mixture containing 80% by weight, 15% by weight, and 5% by weight of limestone, fossilized coral, and shell, respectively, in the mineral-imparting material (B3) in the third water flow container 53;
A mixture in which the mineral-imparting material (B4) in the fourth water flow container 54 contains limestone, fossilized coral, and shell, respectively 90% by weight, 5% by weight, and 5% by weight;
A mixture in which the mineral-imparting material (B5) in the fifth water flow container 55 contains limestone, fossilized coral, and shell, respectively 80% by weight, 10% by weight, and 10% by weight,
When the mineral-imparting material (B6) in the sixth water flow container 56 is a mixture containing 60% by weight, 30% by weight, and 10% by weight of limestone, fossilized coral, and shell, it is mixed with mineral-containing water (A). It is possible to obtain mineral-containing water (B) that exhibits an excellent control action when it is made to occur.

  In particular, limestone, fossilized corals, and shells used in the mineral-imparting materials (B1) to (B6) are preferably the following (1-1) to (1-3).

(1-1) Limestone:
About 3 cm of pebbles pulverized with limestone containing volcanic deposits containing the following components Calcium carbonate: 50% by weight or more Iron oxide: 3-9% by weight Iron Total of titanium oxide, titanium carbide, titanium nitride: 0 .8 wt% or more Magnesium carbonate: 7 to 10 wt%
As such limestone, “CC-200 (product number)” manufactured by Riken Techno System Co., Ltd. can be suitably used.

(1-2) Fossil coral:
The following two types of fossil corals are mixed at a weight ratio of 1: 9, and are granulated to 3 to 5 mm. Fossil corals produced from about 100 meters underground and modified in crystal composition by heavy pressure.
Fossilized coral from land near Okinawa Amami Oshima (including calcium carbonate, calcium phosphate and other trace elements)
As such fossilized coral, “CC-300 (product number)” manufactured by Riken Techno System Co., Ltd. can be suitably used.

(1-3) Shell:
A granular material obtained by mixing abalone, tocobushi and barnacle at the same weight and pulverizing them to 3 to 5 mm. As such a shell, "CC-400 (product number)" manufactured by Riken Techno System Co., Ltd. can be suitably used.

(1-4) Activated carbon Although what was manufactured from arbitrary raw materials can be used for activated carbon, Preferably activated carbon manufactured using coconut shells as a raw material is mentioned. For example, "CC-500 (product number)" manufactured by Riken Techno System Co., Ltd., which is made from Thai palm husk, is mentioned.

  If the switching buttons 51b to 56b of the operation panel 58 described above are operated to switch the water flow switching valves 51v to 56v to the water container side, the water flowing through the water supply path 57 is downstream from the operated water flow switching valve. If the water flows into the first water container 51 to the sixth water container 56 and the water flow switching valves 51v to 56v are switched to the detour water channel side, the water flowing through the water supply path 57 is supplied from the operated water flow switching valve. It flows into the detour water channels 51p to 56p on the downstream side. Therefore, by operating any one of the switching buttons 51b to 56b and selectively switching the water flow switching valves 51v to 56v, different mineral imparting materials (B) for each of the first water container 51 to the sixth water container 56. Mineral-containing water (B) 45 in which mineral components eluted from 51 m to 56 m are selectively dissolved can be formed.

  Next, based on FIGS. 8-11, the structure of the actual mineral containing water (B) manufacturing apparatus 3, a function, etc. are demonstrated. 8 to 10, the bypass water channels 51p to 56p, the water flow switching valves 51v to 56v, the operation panel 58, and the signal cable 59 described above are omitted.

  As shown in FIGS. 8 and 9, the mineral-containing water (B) production apparatus 3 includes a substantially cylindrical first water flow container 51 to a sixth water flow container 56 mounted on the gantry 60, and the first of these. A water supply path 57 that connects the water flow containers 51 to 6 in series, and a raw water tank 63 for storing the water W supplied from the water supply is disposed at the top of the gantry 60. . In the raw water tank 63, an inorganic porous body 64 having a function of adsorbing impurities in the water W is accommodated. A plurality of casters 61 and level adjusters 62 are provided at the bottom of the gantry 60. The first water flow container 51 to the sixth water flow container 56 each having a substantially cylindrical shape are mounted on a gantry 60 having a rectangular parallelepiped lattice structure in a state where the respective shaft centers 51c to 56c (see FIG. 9) are maintained in the horizontal direction. Yes. The first water container 51 to the sixth water container 56 can be attached to and detached from the gantry 60.

  As shown in FIG. 10, the first water flow container 51 to the sixth water flow container 56 all have the same structure, and the flange portions 51 f to 56 f provided at both ends of the cylindrical main body portions 51 a to 56 a are circular. An airtight structure is formed by attaching plate-like lids 51d to 56d. When the shaft centers 51c to 56c are in a horizontal state, a water inlet 57a communicating with the water supply path 57 is provided at a position located at the lowermost part of the main body portions 51a to 56a, and the lid bodies 51d to 56d far from the water inlet 57a are provided. A water outlet 57b communicating with the water supply path 57 is provided at the top, and a mesh strainer 57c is attached to the water outlet 57b. An automatic air valve 57d for releasing the air in the first water flow container 51 to the sixth water flow container 56 is attached to a portion directly above the water outlet 57b on the outer periphery of the main body portions 51a to 56a.

  The water supplied from the upstream water supply path 57 passes through the water inlet 57a and flows into the first water flow container 51 to the sixth water flow container 56, and the mineral-imparting material (B) filled in each of them. Since each mineral component elutes in water by contacting 51m-56m, it becomes the water containing the mineral component according to each mineral provision material (B) 51m-56m, and the downstream water supply path from the outlet 57b To 57.

  In the mineral-containing water (B) manufacturing apparatus 3 shown in FIGS. 8 to 10, any one of the switching buttons 51b to 56b of the operation panel 58 shown in FIG. Each of the mineral imparting materials (B) 51m to 56m filled in the sixth water flow container 56 from the first water flow container 51 by passing through one or more of the water flow containers 51 to the sixth water flow container 56, respectively. Mineral-containing water (B) 45 in which the characteristic mineral components contained therein are selectively dissolved can be formed.

  Moreover, in the mineral containing water (B) manufacturing apparatus 3, since the 1st water flow container 51-the 6th water flow container 56 are connected in series by the water supply path 57, water is continuously supplied to the said water supply path 57. By flowing, it is possible to mass-produce mineral-containing water (B) 45 in which the mineral components according to the mineral-imparting materials (B) 51 m to 56 m in the first to sixth water containers 51 to 56 are dissolved. .

  The mineral-containing water (B) 45 formed in the mineral-containing water (B) production apparatus 3 is sent into the mixing tank 46 via the water supply path 57x downstream from the sixth water flow container 56, and Inside, mineral functional water 47 is formed by being mixed with mineral-containing water (A) 44 manufactured by the mineral-containing water (A) manufacturing apparatus 2 shown in FIG.

The mixing ratio of the mineral-containing water (A) and the mineral-containing water (B) is appropriately determined in consideration of the types of raw materials contained in the mineral-containing water (A) and the mineral-containing water (B) and the concentration of components to be eluted. Is a weight ratio of mineral-containing water (A) and mineral-containing water (B) ([mineral-containing water (A)]: [mineral-containing water (B)]) in the range of 1: 5 to 1:20. Yes, preferably in the range of 1: 7 to 1:12, more preferably in the range of 1:10.
When there is too little mineral-containing water (A) (too much mineral-containing water (B)) and too much mineral-containing water (A) (too little mineral-containing water (B)), mineral functional water The active ingredient may be diluted and the intended action may be insufficient.

  As mentioned above, although suitable embodiment of the manufacturing method of the mineral functional water of this invention was described, the mineral functional water of this invention which has the structure mentioned above should just be manufactured, and various structures other than the said preferred embodiment are employ | adopted. Should be considered non-restrictive. In particular, in the embodiment disclosed this time, matters that are not explicitly disclosed, for example, operating conditions and operating conditions, various parameters, dimensions, weights, volumes, and the like of a component deviate from a range that a person skilled in the art normally performs. Instead, values that can be easily assumed by those skilled in the art are employed.

<Sugar solution>
The saccharide solution used as the raw material of the liquid composition of the present invention is a solution containing a saccharide component.
In the present specification, the “carbohydrate component” is a concept that means monosaccharides, disaccharides, polysaccharides, sugar alcohols and the like obtained by removing dietary fibers from carbohydrates, and the liquid composition of the present invention controls pests. As long as it has an effect | action, the carbohydrate component which can be used is not restrict | limited, You may use combining 1 type, or 2 or more types of carbohydrate components. In particular, monosaccharides are preferable as the carbohydrate component, and it is preferable to include at least glucose and fructose.

  The solvent of the saccharide solution is water, but may contain an organic solvent such as ethanol as long as the effects of the present invention are not impaired.

Moreover, the carbohydrate component obtained by hydrolyzing the bark containing a carbohydrate component and separating and removing insoluble dietary fiber can also be used as a raw material of the carbohydrate solution. Suitable bark includes maple bark.
The saccharide component obtained by adding an acid aqueous solution to the crushed maple bark and hydrolyzing the pulverized maple bark, which will be described later in the Examples, and separating lignin, which is an insoluble dietary fiber, is a saccharide in the present invention. Suitable as a raw material for the solution. As the acid aqueous solution, an aqueous solution of an inorganic acid such as hydrochloric acid, sulfuric acid or nitric acid is used, and an aqueous sulfuric acid solution of 30% or less is preferable.

  From the viewpoint of enhancing stability, the carbohydrate solution is preferably a carbohydrate solution adjusted to pH 4-5. When bark is hydrolyzed with acid, the pH is usually less than 4, so an alkali component is added to lower the acidity to make it weakly acidic. Examples of the alkali component include calcium hydroxide.

(Mixing of mineral functional water and carbohydrate solution)
The mineral functional water of the present invention and a saccharide solution are mixed to obtain a mineral saccharide mixed solution. The mixing ratio of the functional mineral water to the saccharide solution may be 5 to 20 parts by weight, 7 to 12 parts by weight, or 8 to 10 parts by weight with respect to 1 part by weight of the mineral functional water. it can.

  The mineral sugar mixed solution may contain an arbitrary component as long as the effects of the present invention are not impaired. The optional component is not particularly limited as long as it is an additive that does not impair the object of the present invention, and examples thereof include known pH adjusters and stabilizers. Further, the mixing ratio is arbitrary as long as the object of the present invention is not impaired.

The mineral sugar mixed solution can be produced by mixing mineral functional water and a sugar solution (and optional components as necessary) as constituent components by a known mixing method employed in liquid mixing. The mixing order is also arbitrary, and any two components or three or more components among the constituent components may be blended in advance, and then the remaining components may be mixed, or all may be mixed at once.
The mixing conditions are also arbitrary as long as there are no circumstances such as denaturation of components contained in the mineral sugar mixed solution.

<1-2. Electrolysis process>
The electrolysis step is a step of electrolyzing the mineral sugar mixed solution by inserting a positive electrode and a negative electrode into the mineral sugar mixed solution and applying a DC voltage between the positive electrode and the negative electrode.
In this process, “electrolyze” means a state in which bubbles are generated by electrolyzing water by applying a DC voltage to the mineral sugar mixed solution.

In the electrolysis process, a phenomenon that a pest control action is imparted to the mineral sugar mixed solution is recognized by applying a direct current voltage to the mineral sugar mixed solution and performing the electrolysis process. That is, the method for producing a liquid composition of the present invention has one of the characteristics in the electrolysis process.
On the other hand, there are still many unclear points about the effect of the electrolysis process on the mineral sugar mixed solution. However, the mineral component and carbohydrate component derived from mineral functional water can add amino groups and sugars to the sugar molecular structure by applying DC voltage. It has changed to a structure in which a carboxyl group or a hydroxy group is bonded, or a mineral component derived from functional mineral water and a carbohydrate component are mixed evenly at the molecular level and combined to contribute to the expression of pest control. there is a possibility.
In addition, as above-mentioned, mineral functional water and saccharide solution itself do not show a significant pest control action, and the mineral saccharide mixed solution (before electrolysis) which mixed these does not show a significant pest control action.

Hereinafter, the electrolysis process will be specifically described as a more preferred embodiment.
First, the mineral sugar mixed solution obtained in the mixing step and a predetermined container are put. The container to be used is not particularly limited as long as there is no special circumstance such as degeneration of the mineral sugar mixed solution.
In addition, you may throw in the ceramic made from cement which uses a basalt as an aggregate beforehand to a container. Basalt may act as a catalyst that works to make solutes more soluble.

  Next, the positive electrode and the negative electrode are inserted into the mineral sugar mixed solution. For the positive electrode and the negative electrode, materials that are not dissolved or modified by the applied voltage are selected. In particular, the positive electrode and the negative electrode are preferably platinum electrode plates.

The applied voltage only needs to be a voltage at which the mineral sugar mixed solution is electrolyzed, and is, for example, DC 10 V or more, although it depends on the amount of solution and the solution resistance. Moreover, although an upper limit does not have a restriction | limiting in particular, it is 20V or less.
In the present invention, “the state in which a mineral sugar mixed solution is electrolyzed (by applying a DC voltage between the positive electrode and the negative electrode)” means that the electric power of water is applied by applying a DC voltage between the positive electrode and the negative electrode. It refers to the state in which bubbles derived from decomposition are generated.
The voltage application may be continued until the mineral sugar mixed solution expresses a significant pest control action. When the electrode capacity is set to 10 to 20 V DC and the electrode capacity (100 mm × 100 mm) is used with respect to the solution capacity of 5 L, One hour or more is a standard.

You may concentrate the liquid composition obtained by passing through the said process for the maintenance of the quality in a preservation | save and the convenience of dilution use.
The produced liquid composition has a pH of 4 to 5, but can be concentrated by evaporating water and / or adding a monosaccharide until a pH of 5 to 6 is reached. Moisture evaporation is usually performed by heating the liquid composition. Suitable monosaccharides include glucose.
By such treatment, a concentrated solution having a high viscosity of 5 to 6 and having a concentration of about 20% by weight in total of the saccharide component and the mineral component is obtained.

  The pH value in the present specification is a numerical value of the pH measured with a pH meter. The pH meter is not limited to that shown in the examples.

<2. Application of liquid composition>
The liquid composition of the present invention produced by the above production method has a pest control action.
Moreover, it is weakly acidic with a pH of 4 to 5 (pH 5 to 6 for a concentrated solution), and is excellent in safety for humans and animals. Therefore, since there is no harm as in the conventional pest control composition of the mineral functional water of the present invention, there is no problem even if it sucks or adheres to the skin, so it is particularly necessary for protective equipment such as rubber gloves, goggles and masks. There is an advantage of not.

  Hereinafter, a pest control agent and a pest control method using a pest control action which is an effective effect of the liquid composition of the present invention will be described.

As described above, in the present invention, “pest” means arthropods (including insects other than insects) that cause harmful effects on humans and the like.
Although it illustrates below as a classification | category of a pest, it is not restricted to this.
Agricultural pests that eat and destroy crops (eg grasshoppers, planthoppers, stink bugs); Storage pests that eat and store stored grains (weevils); Sanitary pests related to human and animal diseases (mosquitoes, flies, fleas) Food pests that cause harm to food (roaches, flies, etc.); property pests that cause harm to property such as buildings and furniture (termites, cutworms, etc.); livestock Livestock pests that cause harm (abs, mosquitoes, ticks, etc.); unpleasant pests (such as cockroaches, flies, etc.) that are harmful to their appearance.

(2-1. Pest control agent)
The pest control agent of the present invention contains the liquid composition of the present invention as an active ingredient.

  As the pest control agent of the present invention, the liquid composition of the present invention may be used as it is, but it is used as a control agent containing the liquid composition of the present invention as an active ingredient.

  The pest control agent of the present invention has excellent efficacy in controlling pests, particularly diptera. Diptera pests include mosquitoes such as mosquitoes such as Chikaeka, Akaieka, Kogataaikaeka and Aedesia; Aedes such as Aedes aegypti and Aedes albopictus; , Fruit flies, flies, flea flies, flies, fly flies, and fly flies).

  The pest control agent of the present invention can also be used to control pests other than Diptera pests. Examples of such pests include planthoppers; lices; fleas; ticks; ants; termites; and the like. However, other pests are not limited to these pests as long as they exhibit a controlling effect.

The form of the pest control agent of the present invention is not limited as long as the pest control action of the liquid composition of the present invention is exhibited. Specific preparation forms of the pest control agent of the present invention include oil preparations, emulsions, wettable powders, suspensions in water, aerosols, carbon dioxide preparations, heat transpiration agents, and the like. These preparations can contain the liquid composition of the present invention and known ingredients in these preparations.
The amount of the liquid composition of the present invention contained in these preparations is determined within a range in which the control effect on the target pests is actually expressed, and depends on the target pests and the preparation form. When the total weight is 100% by weight, it is 0.01 to 100% by weight (in the case of 100% by weight, the liquid composition stock solution).

  The formulation method depends on the formulation form. For example, the liquid composition of the present invention is mixed with a known solid carrier, liquid carrier, gaseous carrier, bait, etc., and if necessary, a surfactant. The method of adding and processing other formulation adjuvants can be mentioned.

  The control agent of the present invention can be used together with other insecticides, insect repellents, fungicides, herbicides and the like.

(2-2: Pest control method)
The pest control method of the present invention is characterized in that an effective amount of the liquid composition of the present invention is applied to a pest to be controlled or a pest habitat (house, barn, animal body, soil, etc.). In addition, since it is the same as the said (2-1. Pest control agent) about the pest to be controlled, description is omitted.

  Since the liquid composition of the present invention has a pest control action, the pest can be controlled using this control action. Note that “having a pest control action” includes not only that the target pests are completely killed, but also that the pests are significantly reduced and the growth (including egg hatching) can be suppressed.

  On the other hand, in view of the fact that the mineral-containing water (A) or the mineral-containing water (B) constituting the liquid composition of the present invention alone does not exhibit a pest control action, It is clear that mixing the contained water (A) and the mineral containing water (B) exhibits a controlling action against pests.

The control method of the present invention is carried out by applying a liquid composition directly or a pesticide containing the liquid composition as an active ingredient to a pest to be controlled or a place where the pest lives. The liquid composition of the present invention is preferably applied so as to be in direct contact with pests (particularly Diptera pests).
The method of applying the liquid composition or the control agent containing the liquid composition as an active ingredient is not particularly limited, and includes spraying, spraying, coating, and the like, and can be appropriately selected according to each form, use place, etc. .
The application amount and application concentration of the liquid composition or the liquid composition containing the liquid composition as an active ingredient can be appropriately determined according to the form of the liquid control agent, the application time, the application place, the application method, the occurrence of pests, etc. .

  Examples of the space where the liquid composition or the control agent containing the liquid composition as an active ingredient is applied include, for example, the inside of a building (including toilets, bathhouses, storerooms, etc.), and in open outdoor spaces. It can also be applied.

Veterinary medicine when a liquid composition or a control agent containing the liquid composition as an active ingredient is used to control ectoparasites of cattle, horses, pigs, sheep, goats, chickens and other small animals such as dogs and cats It can be used for animals in a known manner.
In particular, when used for livestock, a method of spraying the liquid composition of the present invention so as to get wet on the body surface of livestock is one of the preferred methods. In addition, it is also effective to apply a sponge or the like to a site where pests are likely to occur, or to create a puddle on the scaffold and immerse it. Moreover, since the liquid composition of this invention is safe as mentioned above, there is also an advantage that it is not necessary to wash away even after spraying on livestock.

  Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to these examples.

<1. Production of liquid composition>
[Example]
[1] Mixing Step [1-1] Mineral Functional Water Mineral functional water CAC-717 (Tera Protect (trade name), CAC-717 (part number)), developed by Riken Techno System Co., Ltd., was developed as the mineral functional water used as a raw material. Product number CA-C-01) was used.
The mineral functional water CAC-717 was measured with a pH meter (glass electrode type hydrogen ion concentration indicator TPX-90 manufactured by Toko Chemical Laboratory), and it was pH 12.5.

The mineral functional water CAC-717 was produced using the mineral functional water production apparatus described in the above embodiment of the present invention by the production method described above using the following raw materials and methods. In addition, the said method is corresponded to the manufacturing method of the mineral functional water of Example 1 in patent 5864010.
1. Manufacture of mineral-containing water (A) As a raw material for the mineral imparting material (A), as a plant and plant material (A1), "P-100 (product number)" manufactured by Riken Techno System Co., Ltd., and as a woody plant material (A2), "P-200 (product number)" manufactured by Riken Techno System Co., Ltd. was used.
“P-100” is a plant and plant material (A1) obtained by mixing the following dry pulverized plant of Asteraceae and dry pulverized plant of Rosaceae at 1: 1 (weight ratio), and “P-200” is The woody plant raw material (A2) described below.

(A1) Plant and plant material (dried plant plant)
(A1-1) Dry ground product of Asteraceae Plants Thistle (leaf, stem and flower), mugwort (leaf and stem), and camellia (leaf and stem) are 10% by weight and 60%, respectively. Mixed in a ratio of 30% by weight and 30% by weight, dried and then pulverized.
(A1-2) Dry pulverized product of rose family plants Neubara (leaves, flower parts), radish (leaves and stems), raspberries (leaves, stems and flower parts), 20% by weight, 10 Mixed in a ratio of 70% by weight, and then pulverized after drying.

(A2) Woody plant raw material (dried woody plant)
Maple (leaves and stems), birch (leaves, stems, and bark) and cedar (leaves, stems, and bark) are 25%, 25%, and 50% by weight, respectively. Mixed in proportion, dried and then crushed.

  In the mineral-containing water (A) production apparatus 2 shown in FIG. 1, the mineral-imparting material (A) obtained by mixing the plant and plant material (A1) and the woody plant material (A2) at a ratio of 1: 3 (weight ratio), The raw mineral aqueous solution manufacturing means 10 (see FIG. 2) is placed at 10 to 15% by weight with respect to water, and a direct current (DC8300V, 100 mA) is conducted to the conductive wire of the raw mineral aqueous solution manufacturing means 10 so that A water flow in the same direction as the direct current was generated in the water around the water, and ultrasonic vibration (oscillation frequency 50 kHz, amplitude 1.5 / 1000 mm) was applied to the water to form a raw mineral aqueous solution (A). Subsequently, the mineral-containing water (A) of an Example was obtained by irradiating the far-infrared ray (wavelength 6-14 micrometers) to the raw material mineral aqueous solution (A) supplied to the far-infrared ray generation means 43 of the back | latter stage.

2. Production of Mineral-Containing Water (B) As a raw material for the mineral-imparting material (B), a mixture obtained by pulverizing and mixing limestone, fossil coral, shells and activated carbon was used. The raw materials for the mineral-imparting material (B) and the mixtures (mineral-imparting materials (B1) to (B6)) used in the first to sixth water-flow containers are as follows.

(1) Raw material (1-1) Limestone: “CC-200 (Part No.)” manufactured by Riken Techno System Co., Ltd.
About 3 cm of pebbles pulverized with limestone containing volcanic deposits containing the following components Calcium carbonate: 50% by weight or more Iron oxide: 3-9% by weight Iron Total of titanium oxide, titanium carbide, titanium nitride: 0 .8 wt% or more Magnesium carbonate: 7 to 10 wt%

(1-2) Fossil coral: “CC-300 (part number)” manufactured by Riken Techno System Co., Ltd.
The following two types of fossil corals are mixed at a weight ratio of 1: 9, and are granulated from 3 to 5 mm.
・ Fossil corals from the land near Okinawa Amami Oshima (including calcium carbonate, calcium phosphate and other trace elements)

(1-3) Shell: “CC-400 (Part No.)” manufactured by Riken Techno System Co., Ltd.
・ Abalone, Tokobushi, Barnacle mixed at the same weight and pulverized to 3-5mm

(1-4) Activated carbon (only the second water container is used): “CC-500 (product number)” manufactured by Riken Techno System Co., Ltd.
・ Thai palm activated carbon

(2) Use ratio in the 1st to 6th water-container / first water-container:
Mineral-imparting material (B1): A mixture of limestone, fossilized coral, and shells of 70%, 15%, and 15% by weight, respectively.
Mineral-imparting material (B2): Mixed limestone, fossilized coral, shell, activated carbon 40%, 15%, 40%, 5% by weight, respectively (equivalent to silicon dioxide and activated carbon)
・ Third water container:
Mineral-imparting material (B3): A mixture of limestone, fossilized coral and shell, 80% by weight, 15% by weight and 5% by weight, respectively.
Mineral-imparting material (B4): Mixed limestone, fossilized coral and shells by 90 wt%, 5 wt% and 5 wt%, respectively.
Mineral-imparting material (B5): A mixture of limestone, fossilized coral, and shell, 80% by weight, 10% by weight, and 10% by weight, respectively.
Mineral-imparting material (B6): Mixed limestone, fossilized coral and shell by 60%, 30% and 10% by weight, respectively.

  In the mineral functional water production facility 1 having the configuration shown in FIG. 1, mineral-containing water (B) is obtained by circulating water through the first to sixth water flow containers using the mineral-imparting materials (B1) to (B6). It was. Each of (B1) to (B6) was 50 kg (total 300 kg), the amount of water to be circulated was set at 1000 kg, and the flow rate was set at 500 mL / 40 s.

  Mineral-containing water (CAC-717) was obtained by mixing the mineral-containing water (A) and mineral-containing water (B) formed by the above method so that the ratio was 1:10 (weight ratio).

[1-2] Carbohydrate Solution As a saccharide solution, a saccharide solution “P-300 (product number)” manufactured by Riken Techno System Co., Ltd. was used. The manufacturing method of a carbohydrate solution (P-300) is as follows.

  First, the maple bark was appropriately crushed into small pieces to obtain a crushed maple bark. The crushed maple bark was put in an acid-resistant container, and 5 parts by weight of a 20% aqueous sulfuric acid solution was added to 1 part by weight of the crushed maple bark and stirred for hydrolysis. Then, the solution containing a carbohydrate component was separated from the lignin which is a bark component by pressing and filtration. Thereafter, calcium hydroxide was added to proceed with neutralization to obtain a saccharide solution having a reduced acidity and a stable pH of 4-5. After removing impurities by filtration, the intended sugar solution (sugar solution (P-300)) was obtained by heating and evaporation. The concentration of the saccharide component of the saccharide solution determined from the solid content remaining after heating and evaporating the water of the saccharide solution (P-300) was in the range of 1 wt% to 2 wt%.

[1-3] Mixing of mineral functional water and saccharide components As a mixing catalyst, 1 part by weight of mineral functional water (CAC-717) in a mixing container containing cement ceramic made of basalt aggregate, saccharide solution (P-300) It was added at a ratio of 9 parts by weight, and stirred well to obtain a mineral carbohydrate mixed solution.

[2] Electrolysis process Put the obtained mineral carbohydrate mixed solution (about 5L) into the container for electrolysis, and arrange 16 plates of platinum electrode (100mm x 100mm) as a positive electrode and a negative electrode facing each other. A DC voltage was applied during use. The voltage was controlled so as to be within the range of DC 10V to 20V and voltage application was performed for 1 hour to obtain a liquid composition of the intended example.

The obtained liquid composition of Example 1 was measured with a pH meter (glass electrode type hydrogen ion concentration indicator TPX-90, manufactured by Toko Chemical Laboratories) and found to have a pH of 4.5.
Further, the total concentration of the mineral component and the saccharide component, which was determined from the solid content remaining after heating and evaporating the moisture of the liquid composition of the example, was 2% by weight or less.

[3] Pest control test The following pest control test was conducted using the liquid compositions of the examples.

"Test Example 1: Chikaeka (adult)"
Ten test worms were placed in a plastic cup with a lid (caliber 11.5 cm × bottom diameter 9.5 cm × height 9.5 cm), mainly 10 each, and 14 to 17 only in the stock solution sprayed section. It was used.
The liquid composition (stock solution) of the example was diluted 50 times, 100 times, 250 times, and 500 times with water, and water was prepared as a control. 200 mL of each test solution was placed in a plastic trigger plate and sprayed twice from a distance of 30 cm above a cup (without lid) containing Chikaeka adults (spraying amount: 1.51 ± 0.28 mL / 9 cm: n = 5). Before spraying, the sample was lightly anesthetized with carbon dioxide in a cup with a lid, and when it started to awaken, the lid was opened and the test solution was sprayed quickly, and then the lid was covered with nylon goose. In addition, although many water picks of the sprayed test liquid adhered in the cup, the reaction was observed as it was without transferring the test insect to a new cup.
After spraying, the number of knockdowns was observed over time at room temperature of about 20 ° C. Knockdown was determined by confirming the inability to walk. The evaluation was repeated twice for each test solution. Based on the obtained knockdown rate and lethality rate, the Probit analysis program (Pri Ptobit ver.1.63: Sakuma 1998) was used to analyze the KT50 and LC50 values by the Finney method. Evaluated.

<Results and discussion>
Table 1 shows the results of the knockdown effect on the adult Chikaeka by direct spraying of the liquid composition of the example.
As shown in Table 1, the KT50 value (the time required for 50% of the individuals to knock down) is 240 minutes or more at 500-fold dilution, 22.3 minutes at 250-fold dilution, and higher than 100-fold dilution. It was less than 5 minutes. None of the knockdown individuals died without resuscitation.
In addition, the knockdown rate after 4 hours increased according to the concentration from the 500-fold dilution to the 100-fold dilution, but there was not much difference at a higher concentration than the 100-fold dilution. Some individuals survived. However, as for the chikaeka, individuals in contact with the water droplets of the test solution surely died while attached to the bottom or wall of the cup. In addition, in this test, many water droplets are scattered on the surface until 4 hours later in any cup, and individuals that survived 50-fold dilution or undiluted solution are individuals that are not in direct contact with the drug solution. Judged that there was.
Therefore, if the concentration is higher than 100-fold dilution, it is determined that 100% lethality can be achieved if the effective amount of the liquid composition is directly applied to the worm body.

"Test Example 2: Drosophila melanogaster (adult)"
In the same manner as in Test Example 1, except that the test insects were adult Drosophila melanogaster instead of 10 adults, and 10 each were placed in a plastic cup with a lid (caliber 8 cm × bottom diameter 7 cm × height 6.5 cm). The control test of Test Example 2 was performed.

Table 2 shows the results of the knockdown effect on adult Drosophila melanogaster by direct spraying of the liquid compositions of the examples.
As shown in Table 2, the KT50 value when sprayed directly against adult Drosophila melanogaster was 240 minutes or more at 50-fold dilution, 21.3 minutes at 250-fold dilution, and 16.3 minutes at 100-fold dilution. . Therefore, the KT50 value of the stock solution is considered to be 10 minutes or less.
The knockdown effect increased according to the concentration from 500-fold dilution to 100-fold dilution as in Test Example 1 (Chikaeka), and the knockdown rate after 2 hours became 100% after 100-fold dilution.
In both of the tests in which the stock solution was sprayed, many drops of the test solution were scattered in the cup after 4 hours, but the first time knocked down 100% in a short time, and the second time had almost the same environment. Many of them continued to survive. From this, it was suggested that it was one of the factors of the insecticidal effect that the test solution applied directly to the insect body.

“Test Example 3: Housefly (Egg)”
Housefly eggs were taken out of the culture medium on the same day and removed while adhering to a predetermined number (20-45) of the medium, and placed in a plastic cup (bore 7 cm × bottom 6 cm × height 3.5 cm). . The liquid composition (stock solution) of the example was diluted 50 times, 100 times, 250 times, and 500 times with water, and water was prepared as a control. 200 mL of each test solution was placed in a plastic trigger plate, and sprayed twice from a distance of 30 cm above the cup (without lid) containing each test insect (spray amount: 1.51 ± 0.28 mL / 9 cm: n = 5).
With regard to the housefly eggs, the material of the housefly eggs adhering to a small piece of the medium was placed in a cup and sprayed, and it was confirmed with a stereomicroscope that the drug solution was applied after the treatment. Thereafter, the number of larvae hatched after 2 days at 25 ° C. was measured. 20 or more house fly eggs were tested and tested once.

  As shown in Table 3, the egg-killing effect on the housefly eggs was not effective at a concentration of 250-fold dilution or less, and an egg-killing effect was observed at a concentration of 100-fold dilution or more. At concentrations higher than 100-fold dilution, a slight stickiness is observed in the residue of the test solution, which may be one of the causes of hatching inhibition.

  From the above test data, the LC50 value (50% lethal concentration of the test insect) and the LC100 value (100% lethal concentration of the test insect) of the test solution at a specific time are shown in Table 4.

(Reference test)
Mineral carbohydrate mixed solution (CAC-717), carbohydrate solution (P-300) and mineral functional water (CAC-717) 1 part by weight, carbohydrate solution (P-300) 9 parts by weight For the non-electrolytic treatment, the control action against pests was evaluated.
Evaluation was performed according to the above-mentioned “Test Example 1: Chikaeka (Adult)”, and Mineral Functional Water (CAC-717), Carbohydrate Solution (P-300), and Mineral Sugar against Chikaeka Adult (10) Each quality mixed solution (no electrolysis treatment) was sprayed, and the survival rate after 60 minutes was confirmed. As a result, there were 3 deaths in the functional mineral water (CAC-717), 2 in the carbohydrate solution (P-300), and 3 in the mineral carbohydrate mixed solution (no electrolysis treatment).
From these results, the mineral functional water (CAC-717), the sugar solution (P-300), and the mineral sugar mixed solution (no electrolysis treatment) died in comparison with the liquid composition of the present invention. The number of Chikaeka was obviously small, and it was judged that there was no significant control effect.

[4] Concentration of liquid composition Glucose was added to the liquid composition of the example while heating and evaporating water until the pH reached 5 to 6, thereby concentrating the liquid composition. The obtained concentrated liquid composition had improved viscosity as compared to before concentration. Further, the solid component concentration (mineral component + carbohydrate component (including added glucose)) obtained from the solid content remaining after heating and evaporating the moisture of the concentrated liquid composition was in the range of 20% by weight.
Water was added to the concentrated liquid composition, and the mixture was diluted to pH 4-5, and then diluted with the same container as the above “Test Example 1: Chikaieka (adult)” with respect to adult Chikaeka (5). When the concentrated liquid composition was sprayed, all five animals died after 60 minutes.
From this result, it was confirmed that the pest control action remains even if the liquid composition is concentrated and then diluted again.

  Since the liquid composition of the present invention can be used for pest control applications, it is promising from the viewpoint of hygiene of living environment and agricultural chemical countermeasures for agricultural products.

DESCRIPTION OF SYMBOLS 1 Mineral functional water manufacturing equipment 2 Mineral containing water (A) manufacturing apparatus 3 Mineral containing water (B) manufacturing apparatus 10 Raw material aqueous solution manufacturing means 11, W water 12 Mineral provision material (A)
DESCRIPTION OF SYMBOLS 13 Reaction container 13a Wall body 14 Insulator 15 Conductive wire 16 Ultrasonic wave generation means 17 DC power supply device 18a, 18b, 18c Circulation path 19 Drain port 20, 23 Opening control valve 21, 25 Drain valve 22 Containment tank 24 Drain pipe 26 Water temperature meter 29, 29a-29g, 29s, 29t Conductive cable 30 Terminal 31 Storage container 31f Hook 40 Processing container 41 Raw material mineral aqueous solution (A)
42 Stirrer blades 43 Far infrared ray generating means 44 Mineral-containing water (A)
45 Mineral-containing water (B)
46 Mixing tank 47 Mineral functional water 51 1st water container 52 2nd water container 53 3rd water container 54 4th water container 55 5th water container 56 6th water container 51a-56a Main-body part 51b- 56b Switching button 51c to 56c Axle 51d to 56d Lid 51f to 56f Flange 51m to 56m Mineral imparting material (B)
51p to 56p detour channel 51v to 56v water flow switching valve 57, 57x, 57y water supply route 57a water inlet 57b water outlet 57c mesh strainer 57d automatic air valve 58 operation panel 59 signal cable 60 mount 61 caster 62 level adjuster 63 raw water tank DC DC current DW Tap water R Water flow

Claims (13)

The mineral-containing water (A) formed in the following step (1) and the mineral-containing water (B) formed in the following step (2) become 1: 7 to 1:12 (weight ratio). Mineral functional water contained in a proportion and a saccharide solution containing a saccharide component are mixed at a ratio of 5 to 20 parts by weight of the saccharide solution with respect to 1 part by weight of the mineral functional water. A mixing step to obtain a solution;
An electrolysis step of electrolyzing the mineral sugar mixed solution by inserting a positive electrode and a negative electrode into the mineral sugar mixed solution, applying a direct current voltage between the positive electrode and the negative electrode,
The manufacturing method of the liquid composition characterized by including.

Step (1):
Conductive wire covered with an insulator, a vegetation plant material composed of a plant of the family Asteraceae and a plant of the family Rosaceae, and a tree of a plant composed of at least one kind selected from maple, birch, pine and cedar Mineral-imparting material (A) containing a plant raw material is immersed in water, a direct current is conducted to the conductive wire, a water flow in the same direction as the direct current is generated in the water around the conductive wire, A process of forming a raw mineral aqueous solution (A) by applying ultrasonic vibration to water, and then irradiating the raw mineral aqueous solution (A) with far infrared rays (wavelength 6 to 14 μm) to form mineral-containing water (A). Because
The addition amount of the mineral-imparting material (A) with respect to water is 10 to 15% by weight, and the current value and voltage value in direct current conducted to the conductive wire are in the range of 0.05 to 0.1 A and 8000 to 8600 V, respectively. And
Mineral imparting material (A)
As the plant material, wild thistle (leaf, stem and flower): 8 to 12% by weight, mugwort (leaf and stem), and camellia (leaf and stem) are 8 to 12% by weight, respectively. A dried pulverized product of Asteraceae plants mixed in a proportion of 55 to 65% by weight and 27 to 33% by weight, dried and pulverized, and
17-23 wt%, 8-12 wt%, 65-75 wt% of Neubara (leaves, flowers), radish (leaves and stems), and raspberries (leaves, stems, and flowers), respectively Use a dry pulverized product of a rose family plant mixed and dried at a ratio of
A plant material (A1) obtained by mixing the dried pulverized product of the Asteraceae plant and the dried pulverized product of the Rosaceae plant at a ratio of 1: 0.8 to 1: 1.2 (weight ratio);
As the woody plant raw material, maple (leaves and stems), birch (leaves, stems and bark), cedar (leaves, stems and bark), 22 to 28% by weight, A woody plant raw material (A2) composed of a dried pulverized product mixed at a ratio of 22 to 28% by weight and 45 to 55% by weight, dried and pulverized,
The process which is a mineral provision material (A ') obtained by mixing so that it may become 1: 2.7-1: 3.3 by the weight ratio of a plant plant raw material (A1) and a woody plant raw material (A2).

Step (2):
Mineral-containing water by passing water through six water-flowing containers from the first water-flowing container to the sixth water-flowing container that are filled with different types of inorganic mineral-imparting materials (B) and connected in series. Forming (B), comprising:
In the six water containers,
The mineral-providing material (B1) in the first water-container contains 65 to 75% by weight, 12.5 to 17.5% by weight, and 12.5 to 17.5% by weight of limestone, fossilized coral, and shell, respectively. blend,
The mineral-imparting material (B2) in the 2nd water flow container is 37-43 weight%, 12.5-17.5 weight%, 37-43 weight%, 2.5 limestone, a fossil coral, a shell, and activated carbon, respectively. A mixture comprising -7.5% by weight,
The mineral-imparting material (B3) in the third water container contains limestone, fossilized coral, and shell, respectively, 75 to 85% by weight, 12.5 to 17.5% by weight, and 2.5 to 7.5% by weight. blend,
The mineral-imparting material (B4) in the fourth water container contains 85 to 95% by weight, 2.5 to 7.5% by weight, and 2.5 to 7.5% by weight of limestone, fossilized coral, and shell, respectively. blend,
The mineral-providing material (B5) in the fifth water-container contains limestone, fossilized coral, and shell as 75 to 85% by weight, 7.5 to 12.5% by weight, and 7.5 to 12.5% by weight, respectively. blend,
A mixture in which the mineral-imparting material (B6) in the sixth water container contains 55 to 65 wt%, 27 to 33 wt%, and 7.5 to 12.5 wt% of limestone, fossilized coral, and shells,
Is the process   The method for producing a liquid composition according to claim 1, wherein the mineral functional water is mineral functional water CAC-717 manufactured by Riken Techno System Co., Ltd.   The method for producing a liquid composition according to claim 1 or 2, wherein the carbohydrate solution contains at least glucose and fructose as carbohydrate components.   The method for producing a liquid composition according to any one of claims 1 to 3, wherein the saccharide solution contains a saccharide component obtained by adding an acid aqueous solution to a pulverized maple bark to hydrolyze it and separating it from lignin. .   The method for producing a liquid composition according to claim 3 or 4, wherein the solution is a carbohydrate solution adjusted to pH 4-5.   The method for producing a liquid composition according to claim 1, wherein in the electrolysis step, the positive electrode and the negative electrode are platinum electrode plates.   The method for producing a liquid composition according to any one of claims 1 to 6, wherein the applied voltage is DC 10 V or more.   A method for concentrating a liquid composition comprising a step of evaporating water and / or adding a monosaccharide to a liquid composition having a pH of 4 to 5 produced by the method according to any one of claims 1 to 7 until the pH becomes 5 to 6. .   A liquid composition produced by the method of any one of claims 1 to 7 and having a pest control action, having a pH of 4 to 5.   A pest control agent comprising the liquid composition according to claim 9 as an active ingredient.   The pest control agent according to claim 10, wherein the pest to be controlled is a diptera pest.   A pest control method comprising applying the liquid composition according to claim 9 or the control agent according to claim 10 to a pest or a pest habitat.   The pest control method according to claim 12, wherein the pest to be controlled is a diptera pest.

Images