EP2207572A2

EP2207572A2 - Method and application technology for the residue-free disinfection of pets, poultry barns and livestock sheds and other installations using ozone, electrolytically oxidative radicals, uv-c radiation, electrostatic spray technology, excess pressure ventilation and air-humidification technology

Info

Publication number: EP2207572A2
Application number: EP08800469A
Authority: EP
Inventors: Hanspeter Steffen
Original assignee: Individual
Current assignee: Individual
Priority date: 2007-10-10
Filing date: 2008-10-09
Publication date: 2010-07-21
Also published as: WO2009046561A2; WO2009046561A3

Abstract

The invention relates to a method and application technology for the residue-free disinfection of persons, pets, poultry barns and livestock sheds and other installations using ozone, electrolytically oxidative radicals, UV-C radiation, electrostatic spray technology, excess pressure ventilation and air-humidification technology. Preferably, the method contains the following steps: 1. Disinfection of humans, animals and objects by showering with electrolytically produced oxidative radicals in electrolytically produced oxidative water before entering the shed and in the sterile zones. (Fig. 2) 2. Disinfection of humans, animals and objects using ozone, electrolytically oxidative radicals, UV-C radiation, electrostatic spray technology, excess pressure ventilation and air-humidification technology in the sheds for the electrostatic spray disinfection of animals by means of a spray bar (fig. 1), for the disinfection of drinking water, for hoof and talon disinfection, for feed disinfection in silos and at feeding sites, for controlling flies and vermin, for regulating humidity and for air circulation, air purification and air sterilisation (fig. 3) and for preventing the entry of bacteria and pathogens through doors and windows during the transfer of the animals to the barn or shed. 3. Disinfection of humans, animals and objects using ozone, electrolytically oxidative radicals, UV-C radiation and electrostatic spray technology for disinfection before and after the transfer of the animals to the barn or shed, in order to prevent the transmission of infection and diseases as a quarantine measure.

Description

Process and application technology for residue-free disinfection, of pets, poultry and cattle sheds and other facilities with ozone, electrolytic oxidative radicals, UV-C radiation, electrostatic spray technology, overpressure ventilation and air humidification technology.

Technical area

The invention relates to a novel disinfecting, sanitizing and disease prevention method for disinfecting, sanitizing and preventing disease of domestic animals and individuals, poultry and cattle sheds, and other private and public facilities and buildings using ozone, ozonated water, electrolytic water prepared oxidative radicals, direct and indirect UV-C light irradiation, using air assisted electrostatic spray technology and overpressure ventilation and humidification technique for carrying out the method according to the preamble of the independent claims.

ERa * ff ^| f ^| £ β (rAKFp € £ £ fca] 26) State of the art

For disinfection, sanitation and disease prevention of pets and persons, poultry and cattle sheds and other private and public facilities and buildings are used to date mostly toxic chemicals that have toxic effects on animals, people and the environment and pathogens, bacteria, viruses, Molds, fungi, yeasts and insects, among other things in long-term use, cause resistance and often leave behind toxic residues after use.

The use of toxic and pathogen resistant chemicals is therefore highly controversial, as they no longer guarantee complete disinfection and are often harmful to animals and humans and the environment. Moreover, to date it has been difficult and virtually impossible to provide an all-encompassing and integrated decontamination, disinfection and infection prevention system using uniform disinfection and decontamination technology that meets all requirements, requirements and parameters for efficient and sustainable disinfection and disinfection could guarantee efficient infection prevention.

With the worldwide spread of viruses and bacterioses, e.g. SARS and the bird flu virus N5H1 etc., which can degenerate into dreaded pandemics, are impelling safe methods for the simultaneous infection prevention, disinfection, sanitation, quarantine remediation and propagation prevention of pandemic pathogens.

The today known disinfection techniques with ozone gas and ozonated water or direct and indirect UV-C radiation (wave range 254nm) in sole application have not shown sufficient disinfection results in practice for surface and room disinfections.

In practice, pathogenic microbes can only be reduced by a factor of 2-3 log.

Problems have been found especially when applying the ozone, - on the one hand in the gas application because of low humidity during use, on the other hand in the

Application by pressure nozzles with more than 2atm pressure, where the ozone dissolved in the water outgasses and is no longer available for the disinfection.

Own research studies in the last 10 years have clearly shown that the sole disinfection with ozone, electrolytic water-produced oxidative radicals, or UV-C irradiation alone showed unsatisfactory disinfection results, while in combination with ozone, electrolytically from water produced oxidative radicals, UV-C radiation and suitable air humidification technology, combined with the appropriate spray and application technologies excellent disinfection results up to an elimination rate of 99.99% can be achieved with certainty.

With the new invention in the combined disinfection and sanitizing application of ozone, ozonated water, water-borne oxidative free radicals, direct and indirect UV-C light irradiation and using air-assisted electrostatic spray technology and over-pressure ventilation and humidification Technique can prevent all types of bacterial, viral and other exogenous pathogens caused diseases in humans and animals and sanitize contaminated items.

The new disinfection-sanitization-decontamination and disease prevention technology is clean, significantly cheaper, efficient, residue-free and sustainable, and above all friendly to the environment, and in particular does not lead to resistance formation in pathogenic pathogens and additionally guarantees the decontamination of harmful toxins.

Over the course of several years, the optimal concentrations of ozone, UV-C radiation and oxidative radicals in the water and treatment times have been determined in order to achieve a perfect disinfection of animals, persons and equipment.

In several years of research and development work in the laboratory and in practical use, the inventor has tested and perfected the new method and achieved an efficiency of close to 100%.

To the knowledge of the inventor are to date no scientific work in the field of disinfection and cleaning of animals, people, stables and others Objects using the combination of ozone gas, ozonated water and electrolytically generated from water oxidative radicals and UV-C light as biocides against dangerous

Health-damaging bacteria, viruses, fungi, molds and pests such as ticks, lice, bedbugs, worms and worm eggs, etc. and with the combined application techniques of fumigation and electrostatic spray technology for disinfection, sanitation and disease prevention and purification of animals, persons, stables, milking parlors, milking crockery, drinking water, feeding equipment and other objects have been published in this combined form, nor is a similar combined technology used for the same purposes anywhere today.

Presentation of the invention

The object of the invention is to provide a new, low-cost, environmentally friendly and sustainable biological method for disinfection, sanitation and disease prevention by the elimination of bacteria, viruses, fungi, molds, yeasts, insects and pathogens in poultry and livestock and manure and other private and public facilities and for the quarantine decontamination and sanitation of pets, pet owners, objects, water for drinking, private and public vehicles and other relevant contaminated objects and surfaces such as, inter alia, in hospitals, playgrounds, silos and food warehouses etc. Aid of gaseous ozone, ozonated water, oxidative radicals produced electrolytically from water and direct and indirect UV-C radiation, using air assisted electrostatic spray technology and overpressure ventilation and humidification technology.

Presentation of the process components

The procedure includes the following technical aids and process steps:

1. ozone generator, preferably with cathode discharge, consisting of air compressor, dehumidifier, oxygen generator, ozone probe, ozone alarm for ozone in air, ozone gas compressor, ozone gas pressure tank (15 atm) and associated supply and

Discharges, Gas Flow Meters, Pressure Gauges Electrical Control, Ozone Concentration Meter.

2. Ozone emitting UV-C lamps in the wavelength range of 185 nm in sufficient number to achieve an ozone gas concentration of preferably 0.1-10 ppm per liter of air or more.

3. Automatically electronically controlled humidifier with preferably an air-jet nozzle with fan for atomizing ozone water or EOW (electrolytically produced oxidative water), controlled by an electronically switchable hygrometer to control the humidity as needed and application.

4. Electrolysis plant for the production of oxidative radicals in water, which either work with both diamond and other electrode types of platinum or alloys, or are made of other suitable materials.

Electrolysis equipment operating on diamond coated electrodes in an electrolytic reaction chamber or electrolytic cylinder reactors with diaphragm and platinum coated electrodes can be used.

5. Control unit for automatic or manual control and synchronization of disinfection - Process with ozonated water, ozone gas, water mist with oxidative radicals, UV-C direct and indirect irradiation in the wavelengths 185 nm (ozone generating) and 254 nm (biocide in direct and indirect irradiation).

6. Electrical supply system with generator and / or solar panels, and / or with electrical mains supply preferably with a power requirement of 150 KVA or matched to project size. 7. Plastic tanks with ventilation of sufficient size and pressure resistance up to 4 bar for the uptake and production of ozonated water, and for the electrolyzed oxidative water including mixing systems via venturi, vortex and bubble mixers, and catalytic, thermal or chemical residues Ozone, Chlorine Gas and Hydrogen Destroyer.

8. Drinking bowls and drinking lines with nipples.

9. Mobile beam spray system with electrostatic, air assisted nozzles, equipped with bottom mounted UV-C lamps (with 254 nm radiation wavelength).

10. One or more electrostatic spray nozzles with low pressure and large volume air support by means of air compressor, for the production of fine droplets and built-in

Electrode for the inductive charging of spray drops with a drop size of ideally not more than 50 microns, which allows a charge of the microdroplets of about 600 V or 3-5 mOhm (milli-ohms) per liter, including the corresponding electronics for generating the DC - Charge current of the electrodes and automatic or manual control to activate or deactivate the electrodes or other suitable nozzle types.

11. Footbath for persons and animals filled with electrolysed oxidative water (EOW).

12. High-pressure cleaner operated with oxidative water (EOW).

13. Ozone and EOW water showers (EOW = Electrolyzed oxidative water) for animal, body and udder care.

14. Washing plant for milking plant and milking equipment with oxidative radicals in water, with acidic and / or alkaline rinsing - options for implementing the CIP cleaning method (cleaning in place)

15. Air fans for generating an overpressure and for ventilation in a stable or in enclosed spaces, with heating or cooling elements. 16. Solar panels for the production of electricity and heat by means of solar heat collectors and heat pumps.

Presentation of the biocidal and reactive process components

ozone

Ozone, 03, is the 3-atom form of oxygen. Ozone is highly reactive and the strongest known oxidation agent. It is 51 times more reactive than chlorin and 3125 times faster in the destruction of microorganisms.

Ozone is a highly unstable molecule in gaseous form, which decomposes again into oxygen = 2 in a short time (about 20 minutes).

Ozone is generated by UV-C radiation (185 nm) or by corona cathode discharge at approximately 7000 volts, or produced electrolytically from water.

Ozone is better soluble in water than oxygen.

Ozone is gaseous, bluish in color, strongly odorous and harmless at 0.1 mg per liter of air in permanent exposure. Ozone works by splitting off an oxygen atom on contact with organic or inorganic compounds and, under the influence of moisture, <65% RH, leads to oxidation in part by the formation of highly reactive oxidative radicals.

Such cell membrane membrane oxidation results in lysis of cell walls and membranes of eukaryotes leading to the destruction of all fungi, bacteria, viruses, yeasts and their spores, as well as insects and their habitats.

Ozone can not dissolve the multi-layered cell wall structures of humans, higher animals and plants at short exposure times.

Ozone acts in short contact principle and leaves no residue, because it decomposes into oxygen in a short time.

Ozone leaves no damage on humans higher plants and plants with a short exposure time. Also, ozone does not cause resistance to microbes or pathogens.

Ozone is therefore an extremely effective biocide against all fungi, bacteria, viruses, yeasts, biofilms, protozoa and higher organisms such as small insects, worms, spider mites and other harmful parasites.

approvals

Ozone has been approved by the US Food and Drug Administration (FDA) since June 26, 2001 as an additive in direct contact with food.

Also, the use of ozone in agriculture was approved by the USDA (United States Department of Agriculture) in 2002.

Ozone is also permitted as a disinfectant by the EPA (Environmental Protection Agency) in the US.

UV-C light

UV-C light, as direct electromagnetic radiation in the wave range of 254 nm (nanometers) has optimal biocidal activity against bacteria, viruses, yeasts and insects.

In the case of microorganisms, the UV-C radiation primarily causes the damage caused by photon absorption of RNA (ribonucleic acid) and DNA (deoxyribonucleic acid) in the helix strand of the nuclear genome by bonding and cementing of the DNA helix base end pairs and thus makes information impossible - Duplication for cell division and secondarily it destroys molecular bonds in cell membranes in pathogenic microbes.

In the wave range of 185 nm (nanometers), UV-C radiation generates ozone, which under high humidity generates highly oxidative labile radicals ie hydroxyl compounds also called AOS (Advanced Oxidation Species), which significantly enhance the effect of ozone as a biocide (microbial hurdle principle). , admission

UV-C irradiation of living beings and food and surfaces and rooms has been approved by the FDA in the US since 1997 and also in the German Radiation Protection Ordinance.

For the efficiency of UV-C radiation, the radiation dose is decisive, which is stated in nϊW / sec / cm2 (milli watt per second per square centimeter of irradiated area).

The dose for elimination of microorganisms is preferably 4 to 20 mW / sec / cm 2 (depending on the species)

For noxious insects approx. 50 to 150 mW / sec / cm2 (depending on species)

Electrostatic spray technology

An electrostatic spray nozzle acc. Figure Annex 10 contains a ceramic embedded steel electrode and a supply of air, a supply for the spray liquid and a supply in the form of a cable for the current.

An electrostatic spray unit includes one or more electrostatic spray nozzles with low pressure and high volumetric air support for fine droplet generation and built-in electrode for inductive charging of the spray droplets with a drop size of ideally not more than 50 microns, charging the microdrops of about 600 V or 3-5 mOhm (milli-ohms) per liter, including the appropriate electronics for

Generation of the DC charge current of the electrodes and automatic or manual control for activating or deactivating the electrodes.

Electrolytic Oxidative Water (EOW)

Electrolytic oxidative water (EOW) or chemically active water destroys germs, fungi, and insects by oxidative radicals not chemically, but physically.

Because of its high oxidative reduction potential (ORP), "active water" damages the cell wall membranes of pathogens. The pathogen is compressed, resulting in osmotic or hydrogen overload inside the cell.

The damaged cell membranes allow for increased water transfer between the cell membranes, resulting in a hydrogenous flooding of the cells and filling them faster than the cells can dispose of the water.

This fact leads to a bursting of the cells, respectively to cell death by pressure explosion in a few seconds.

Since it is a physical destruction principle, there is no proven resistance to pathogens.

Principle of electrolysis (see picture Annex P

Example of an electrolysis with a zinc iodide solution (electrode material arbitrary)

When connecting two metal plates (electrodes) each with a cable and a device which generates direct current, e.g. A battery or a rectifier - and transfers these platelets in a beaker with aqueous solution (arbitrary ions) and now creates a voltage, so formed on both metal plates, a substance whose ions are present in the solution.

The voltage source causes an electron deficiency in the electrode connected to the positive pole (anode) and an excess of electrons in the other electrode connected to the negative pole (cathode). The aqueous solution between the cathode and anode contains electrolytes, which are positively or negatively charged ions. The positively charged cations in an electrolytic cell migrate by applying a voltage to the negatively charged cathode (attraction of opposite charges). At the cathode, they absorb one or more electrons and are thereby reduced.

At the anode, the opposite process takes place. There, the negatively charged anions emit electrons, that is, they are oxidized. The number of electrons consumed by the reduction at the cathode corresponds to the electrons picked up by the anode. In the electrolysis of aqueous saline solution, the same volume is produced Hydrogen gas such as chlorine gas. In the electrolysis of water twice as much hydrogen gas as oxygen gas, since the two positively charged protons of a water molecule migrate to the cathode and there each have to take an electron so that hydrogen forms, while the doubly negatively charged oxygen anion at the anode must give off two electrons to connect to the oxygen molecule.

The voltage which must at least be applied to the electrolysis, is called the deposition potential, in the electrolysis of water or in aqueous salt solutions, one speaks of the decomposition voltage. This voltage (or a higher voltage) must be applied so that the electrolysis takes place at all. For each substance, for each conversion of ions to two or polyatomic molecules, the decomposition voltage, the deposition potential can be determined on the basis of the redox potential. From the redox potential, one obtains many other important indications for the electrolysis, for example for the electrolytic decomposition of metal electrodes in acid or for the reduction of decomposition voltage by altering pH values.

For example, it can be calculated by the redox potential that the formation of oxygen at the anode during the electrolysis of water in basic solution (decomposition voltage: 0.401 V) takes place under lower voltage than in acidic (decomposition voltage: 1.23 V) or neutral (decomposition voltage: 0.815 V) solution, at the cathode, however, forms lighter hydrogen under acidic conditions, than under neutral or basic conditions).

If several reducible cations are present in an electrolyte solution, then after the redox series the cations are first reduced at the cathode, which have a more positive (weaker negative) potential in the redox series (voltage series), that is as close as possible to the potential of the proton hydrogen electrode voltage come. In the electrolysis of an aqueous saline solution forms at the cathode usually hydrogen and not sodium. Even in the presence of several types of anions that can be oxidized, first those come into play that have in the redox series as close as possible to the voltage zero point, ie a weaker positive redox potential. Normally, the electrolysis of aqueous NaCl at the anode produces oxygen and not chlorine. When the decomposition voltage is exceeded, the current strength increases proportionally with the voltage difference. According to Faraday, the amount by weight of an electrolytically formed substance is proportional to the amount of current flow (current multiplied by time). For the Formation of 1 g of hydrogen (about 11.2 liters, in the formation of a hydrogen molecule, two electrons are required) from aqueous solution, a current amount of 96485 C (As) = lFaraday is required. At a current of 1 A between the electrodes, the formation of 11.2 liters of hydrogen takes 26 hours and 48 minutes.

In addition to the redox potential, the overpotential (the overpotential) is also important. Due to kinetic inhibitions on electrodes, one often requires a significantly higher voltage than calculated from the calculation of the redox potentials. Depending on the material properties of the electrodes, the overpotential effects can also change the ORP series, so that other ions are oxidized or reduced than would have been expected after the redox potential. Shortly after switching off an electrolysis can be determined with an ammeter a current swing in the other direction. In this short phase, the reverse process of electrolysis, the formation of a galvanic cell. In this case, power is not consumed for the implementation, but it is briefly generated electricity; This principle is used in fuel cells.

If one forces a separation of individual molecules or bonds by an electrolysis, a galvanic element acts at the same time, the voltage of which counteracts the electrolysis. This voltage is also called the polarization voltage.

electrodes

There are only a few anode electrodes that remain inside during the electrolysis - so do not go into solution at all. Platinum, coal resp. Diamond are materials that do not dissolve at all during an electrolysis. There are also metals that do not dissolve despite strongly negative redox potential. This is called "passivity." An iron anode treated with concentrated nitric acid does not dissolve, and no ferrous or ffl cations go into solution, and it has "passivity."

Inhibition phenomena at the anode, which lead to an overvoltage during the oxygen formation, are observed with diamond and platinum anodes (overvoltage: 0.44 V). In these, the electrolysis of aqueous saline solution produces chlorine instead of oxygen. At zinc, lead (overvoltage: 0.78 V) and especially mercury cathodes (0.80 V), hydrogen protons show a considerable overvoltage and the formation of hydrogen occurs only at a much higher voltage. The significant overvoltage of hydrogen at the Mercury cathode, in which the sodium is bound as amalgam and therefore deprived of equilibrium, is used for the technical production of caustic soda. Due to the significant overvoltage at this electrode in the formation of hydrogen, the redox series changes and instead of hydrogen protons now migrate sodium cations to the mercury cathode.

Electrolysis of water

The electrolysis of water consists of two partial reactions, which take place at the two electrodes. The electrodes are immersed in water, which is rendered more conductive by the addition of some common salt, and then chlorine is recovered instead of oxygen.

Positively charged hydronium ions (H3O +) migrate in the electric field to the negatively charged electrode (cathode), where they each receive an electron. Hydrogen atoms are formed, which combine with another H atom formed by reduction to form a hydrogen molecule. Remain water molecules.

2 H3O + + 2 e- → H2 + 2 H2O

The separated, gaseous rises at the cathode.

The negatively charged hydroxide ions migrate to the positively charged electrode (anode).

Each hydroxide ion releases an electron to the plus pole, so that oxygen atoms are formed which combine to form oxygen molecules. with NaCl addition to chlorine molecules.

The remaining H + ions are immediately neutralized by hydroxide ions to water molecules.

4 OH → O ₂ + 2 H ₂ O + 4 e-

Here, too, the separated oxygen rises as a colorless gas at the anode. The overall reaction equation of the electrolysis of water is:

4 H ₃ O + + 4 OH - → 2 H ₂ + O ₂ + 6 H ₂ O

The hydronium and hydroxide ions on the left originate from the autoprotolysis of the water: 8 H ₂ O → 4 H ₃ O + + 4 OH

The electrolysis equation can therefore also be written as follows:

8H ₂ O → 2H ₂ + O ₂ + 6H ₂ O

or after shortening the water:

2H ₂ O → 2H ₂ + O ₂

hydroxide

The hydroxide ion is a negatively charged ion that forms when bases react with water. Its chemical formula is OH-.

A general base B reacts with water according to the following scheme:

-I- H ₂ O ^ v + H OH ^"

Based on the concentration of the hydroxide ions can be determined the pH of the resulting solution. To do this, first calculate the so-called pOH value.

pOH = -hg c (OH ^" )

And from this the pH value:

pH = k - pOH

There is one k for each temperature.

Under standard conditions, k = -14.

Hydroxide ions are also contained in pure water at 2O ⁰ C in a concentration of 10 ^"7 mol • l ^{" 1} . This is related to the autoprotolysis of water according to the following reaction equation:

H ₂ O + H ₂ O ^ H _Ä 0 ⁺ + OH ^" admission

The innovative use of diamond electrode technology in electrolysis has recently received much attention from numerous university research teams for use in the surface disinfection of poultry, fish and meat, fruits and vegetables in the processing industry.

Early in-house trials and test results led to submission of grant applications to the Food and Drug Administration (USA), which granted approval for the new technology in December 2002 and was awarded the status of "GRAS" (Generally Regarded as Safe).

Electrolysed oxidative water has been approved by the United States Food and Drug Administration (USDA) and the US Environmental Protection Agency (EPA) for general food applications, food surface disinfection, dairy and meat applications - and restaurant - technical applications.

The corresponding pages of FDA and USDA approval numbers are 21 CFR 173, 178, 182, 184 & 198.

The EPA Grant and Publication Page is 40 CFR 180,940 and the National Organic Program is 21 CFR 178.1010.

Ozonated water

The ozone generated by the ozone generator is by means of various mixing systems such as a venturi valve, a vortex or cyclone mixer, a

Fine bubble mixer (bubble blender) in a preferably cylindrical reaction tank made of stainless steel or other ozone-resistant material mixed at preferably 4.4 bar pressure. Depending on the water quality, a concentration of ozone in the water of approx. 8 - 35 ppm or approx. 8-35 mg ozone per liter of water can be achieved. This ozone-water mixture is very labile and the ozone quickly changes back into oxygen.

Therefore, ozone water for disinfection in hygienic applications must always be freshly prepared. Humidification by micro-atomization

Micro-atomization of ozone water or EOW water (electrolytically produced oxidative radicals from water) consists of one or more air-assisted micro-spray nozzles and an air fan by means of rotors. The humidification distance of such a fan can reach up to 30 meters and more.

Micro humidifier humidification is automatically controlled by an electronically controlled hygrometer and can be programmed from 0 to 100 relative humidity of ambient air, depending on the application needs.

Overpressure ventilation to prevent the penetration of pathogens into the sterile zones

In order to prevent bacteria, viruses, insects and contaminated water droplets or contaminated water microdroplets from penetrating into a hygiene area, such as a stable, room or building from outside, the hygiene zone must be sealed very well, especially on window frames and windows Doors or gates.

The overpressure is generated by a ventilation fan, the filtered outside air, which is not only cleaned with dust and bacteria filters, but also conditioned as needed heat and humidity.

The blown-in conditioned air creates an overpressure in the room, which can escape via an automatic air-discharge valve. When a window or door is opened in the room, air now escapes at a minimum speed of 1.5-2 meters per second. This prevents that no bacteria, viruses, insects and contaminated dust or contaminated water microdrops can penetrate into a hygiene area, such as a stable, room or building from the outside.

Decontamination of vehicles

It is essential for the maintenance of a permanent hygiene in sterile areas that no cross-contamination can take place.

For this reason, transport vehicles for animal carers, visitors and animals themselves, each time before and after use and contact with the outside world and for animals before and after and to be cleaned and disinfected with EOW water at a minimum concentration of 250 ppm.

Decontamination of persons and animals

To prevent the introduction of germs into a sanitized barn or sterile area it is also essential that the animals are previously under the cattle or poultry shower and in the hoof bath with oz. Water of 8 ppm / liter or EOW water with a ROP (Redox potential) of at least 920 mV washed, cleaned and disinfected. This also applies to all persons who enter a stable, a hygiene zone or a sterile room, that they first have to shower and disinfect with ozone water.

Decontamination of material

The same conditions apply to all material that is brought into or out of a sanitary zone. With ozone water or EOW water, all utensils, boxes and materials are thoroughly cleaned with the high-pressure cleaner, if necessary, and at the same time disinfected using the CIP principle (cleaning in place).

Decontamination of inside and outside surfaces

All walls, floors, floors and other surfaces of table furniture, machinery and other equipment are washed and disinfected regularly with the high-pressure cleaner or other EOW tools. In order to ensure that this disinfection also takes place deep in places where conventional equipment can not reach, UV-C lamps with protective shield or in ventilation textile hoses are integrated, which during the night or during the day an ozone concentration of 0.1 ppm per liter of air can maintain. The number of lamps depends on the room volume. With a 330 W UV-C ozone-producing lamp one can expect that 1 lamp per 100 m3 is sufficient for this fumigation purpose.

Disinfection by washing

Care should be taken to ensure that all material, utensils, machinery and equipment are used regularly, ie once a day, and every 4 hours in food and pet food applications. Purifications and washes can be done with ozone water or EOW water.

Disinfection by fumigation

The disinfection of hygiene zones and sterile rooms, full and empty feed silos, also for

Feed disinfection, preferably by fumigation with ozone gas produced by cathode discharge, or by ozone-producing UV-C lamps.

It should be noted that the concentration of ozone gas is at least 300 ppm in order to achieve a complete disinfection even in cracks and crevices. In this process, it is important that using the fine mist atomizer with EOW water humidity in the

100% space can be achieved, which significantly improves the reaction efficiency of the ozone (1-2 log better germ reduction).

Disinfection by UV-C irradiation

The disinfection with UV-C irradiation is carried out with UV-C lamps in the radiation range of a wavelength of 254 nm. This method of disinfection is used primarily to drive by means of a beam spray and irradiation wagon on a livestock such as poultry or pigs to use the direct radiation to shower the animals in combination with ozone water or EOW water.

At the same time, the animals are supplied with sufficient sunlight or UV radiation, which is important for the calcium and vitamin C metabolism. Poultry, cattle and, above all, pigs respond positively to this treatment, as it guarantees optimal supply of calcium to the bones and therefore less leg and standing problems. In addition, this fact must be taken into account in the egg production of run-out hens, and brings significant advantages for egg-tray quality and laying performance.

SOLUTION OF THE INVENTION

The inventive solution to achieve and implement the parameters for residue-free disinfection, decontamination, sanitation and disease prevention of animals, persons and in poultry and cattle sheds and other facilities and for quarantine decontamination and sanitation of stables, animal owners, objects, Drinking water, vehicles and other relevant contaminated objects and surfaces are defined by the features of the independent claims.

According to the invention, a method for use in disinfection, the

Decontamination, sanitation and disease prevention for animals and persons in poultry and cattle sheds and other facilities and in the quarantine decontamination and sanitation of stables and livestock, objects, drinking water, vehicles,

Milking parlors and milking equipment and other relevant contaminated objects and

Surfaces against harmful microorganisms and insects the way the bioeids

(Ozone and UV-C radiation, electrolysed oxidative water EOW) and their manufacture on and the manner of application technology and aids in the correct

Process sequence for efficient use.

The invention provides an integrated system in which the technical components for ozone, UV-C production and production of electrolyzed oxidative water EOW and the application technology and the consistent tools in the form of air-assisted electrostatic spray technology and pressure-ventilation and humidification -Technique for implementing the method according to the preamble of the independent claims are integrated.

The focus of innovation is not only on the combination of ozone and UV-C radiation and electrolyzed oxidative water as a new application and hurdle technology for combating infections and contamination caused by microbes and insects, etc., but also in the combined new ones Application techniques and tools by means of air assisted electrostatic spray technology and overpressure ventilation and humidification technique for performing the method.

The new combined application technique is essential for the successful use of ozone and UV-C irradiation and electrolyzed oxidative water EOW and fulfills all the parameters for optimal operation of the new disinfection and decontamination process for sanitation and disease prevention of animals, individuals and in poultry and Cowsheds and other public and private facilities. Without the special application techniques, the effect of ozone water and UV radiation and electrolyzed oxidative

Water EOW unsatisfactory, since the duration of action of ozone is very volatile and only very short because of the high molecular instability.

Furthermore, the invention is innovative with respect to the process for ozonating the water by means of a venturi valve and subsequent vortex injection cyclone and the fine bubble mixer specifically

has been developed for this purpose and prevents the outgassing of the ozone from the water during the spray process.

With this new injection technique, the intimate mixing of ozone gas with the spray water, in combination with the special air assisted electrostatic low-pressure spray nozzles (<1 atm spray pressure), the ozone concentration in the spray and disinfectant water up to 15 ppm resp. 15 mg / liter of ozone water are kept, which favors the disinfection process and greatly improved. This allows the duration of disinfecting ozone gas in the water to be tripled (up to 1 hour). Without converting ozone gas into oxygen. Thus, the efficiency of ozone as a biolide and disinfectant can be significantly increased.

Embodiment of the invention

To carry out the process and to demonstrate the application techniques used for residue-free disinfection, of domestic animals, poultry and cattle sheds and other facilities with ozone, ozone water, electrolytic oxidative radicals, UV-C radiation, electrostatic spray technology, positive pressure ventilation and air humidification technology the use of the new holistic, residue-free disinfection technology will be demonstrated using the example of a large poultry mast with ground keeping.

The Masthalle for poultry

Dimensions: 60 mx 20 m, gable height, 2500 m3 The hall has 2 main gates at the front and rear.

The hall has a side tilt window with darkening on both lateral sides.

The front section of the hall houses the disinfection room, cloakroom and hygiene lock.

Also located in this zone on the one hand the engine room with all technical equipment and control and control boxes, as well as the 2 ventilation fans.

The room for the technical facilities contains the following equipment and facilities:

1. ozone generator, preferably with cathode discharge, consisting of air compressor, dehumidifier, oxygen generator, ozone probe, ozone alarm for ozone in

Air, ozone gas compressor, ozone gas pressure tank (15 atm) and associated inlets and outlets, gas flow meters, pressure gauges, electrical control, ozone concentration meter.

2. Electrolysis plant for the production of oxidative radicals in water, either with diamond as well as with other electrode types of platinum or

Alloys work or are made of other suitable materials.

3. Control unit for automatic or manual control and synchronization of disinfection - Process with ozonated water, ozone gas, water mist with oxidative radicals, UV-C direct and indirect irradiation in the wavelengths 185 nm (ozone generating) and 254 nm (biocide in direct and indirect irradiation).

4. Electrical supply system with generator and / or solar panels, and / or with electrical mains supply preferably with a power requirement of 150 KVA or on project size matched. 5. 2 plastic tanks with ventilation of sufficient size and pressure resistance up to 4 bar for the uptake and production of ozonated water, and for the electrolyzed oxidative water including mixing systems via venturi, vortex and bubble mixers, and catalytic, thermal or chemical Residual ozone, chlorine gas and hydrogen destroyers.

6. Washing equipment for feeding utensils, other objects and transport cages with oxidative radicals in the water, with acidic and / or alkaline rinsing - Options for implementing the CIP cleaning method (Cleaning in Place)

7. Air fans for generating an overpressure and for ventilation in a stable or in enclosed spaces, with heating or cooling elements.

8. Air compressors - Plant for 20 m3 / min power

The mast hall houses the following facilities and equipment:

1. ozone emitting UV-C lamps in the wavelength range of 185 nm in sufficient number to achieve an ozone gas concentration of preferably 0.1 to 10 ppm per liter of air or more.

2. 2 Electronically controlled humidifiers with preferably 8 air-jet nozzles with fans for atomizing ozone water or EOW (electrolytically produced oxidative water), controlled by electronically switchable hygrometers to control the humidity as needed, temperature, meteorology and application.

3. 1 Mobile beam spray system with electrostatic, air assisted nozzles fitted with bottom mounted UV-C lamps (with 254 nm radiation wavelength).

4. 80 electrostatic spray nozzles with low pressure and large volume air support by means of air compressor, for fine droplet generation and built-in electrode for inductive charging of the spray droplets with a drop size of ideally not more than 50 microns, the charge of the microdrops of about 600 V or 3 5 mOhm (milli-ohms) per liter allowed, including the corresponding electronics for generation the DC charge current of the electrodes and automatic or manual control to activate or deactivate the electrodes.

5. Ozone emitting UV-C lamps in the 185 nra wave range in sufficient number to achieve an ozone gas concentration of preferably 0.1-10 ppm per liter of air or more.

6. Drinking bowls and drinking lines with nipples.

7. Footbath for persons and animals filled with electrolysed oxidative water (EOW).

8. High-pressure cleaner operated with oxidative water (EOW).

9. 6 chimney ventilation shafts

10. 6 Overpressure dampers for overpressure ventilation

11. Illumination lamps and heat lamps

Description of the fattening farm with special consideration of the hygiene and disinfection aspects and the disease prevention and the general well-being of the fattening chickens

1. Before the stable can be equipped with fattening chicken, an intensive house cleaning with subsequent disinfection of all parts and facilities must be carried out.

This is done first with a rough cleaning, which corresponds to a broom pure state.

Then all walls, side panels, windows, floorboards, floors and all equipment and objects are washed off with EOW water of at least 250 ppm of dissolved radicals per liter of water at 10 bar pressure. The disinfection is completed after a contact time of 10 minutes.

2. Finally, fumigation is carried out using pure ozone gas, which lasts 24-48 hours. The concentration of ozone in the air is in the process for this process Minimum 300 ppm and the ambient air must always be kept at 100% with the humidifiers.

3. After this successful fumigation the smear results after the test, germ count must be checked massively, the results of the smears must not exceed 10'0OO total germs.

4. Before the litter of sawdust is brought into the barn, it must be fumigated with ozone under a plastic blanket for 48 hours with ozone gas.

5. If the microbiological samples meet the requirements, the house may be covered with chicks.

6. During occupancy, an ozone concentration in the barn of 0.2 ppm is aimed for in the first 2 days. For this purpose, ozone from the ozone pressure vessel is preferably via a Teflon pipe, which is mounted on preferably about 2.50 -3 meters above the ground over the entire length of the house. Every 2 to 5 meters, the pipe has a micro-opening of preferably 0.5 mm, where the ozone gas can flow out and mix with the surrounding air. The line has a pressure of preferably 4 atm.

Also, ozone generating UV-C lamps can be used.

7. This measure avoids that the young fattening mosquitoes become infected and become ill by viruses and bacteria. After 2-3 days, the ozone concentration in the air is reduced to 0.1 ppm per liter of ambient air.

8. The drinking water is mixed with EOW water using a dosing pump so that the drinking water contains a concentration of preferably 0.4 - 0.6 ppm oxidative radicals, which lead to a total disinfection of drinking water and also to prevent algae formation and bacterial microfilm formation.

9. After preferably 10 days, the mast chicks are sprayed for the first time with the beam sprayer by means of the electrostatic nozzles with EOW water. The speed is preferably o.3 meters per second with a flow rate per nozzle of preferably 80-120 ml per minute. 10. The humidification system in the fattening shed will switch off automatically when the bar spray system is put into operation. The heat lamps are also switched on automatically so that the mast chicks dry quickly and do not catch cold.

11. The spray process is repeated per day as needed, preferably 2-3 times.

12. This treatment in the form of a micro-shower not only fulfills a kind of equitable water shower for the poultry, but also serves for disinfection and body and feather cleansing and thus also prevents the infestation of poultry vermin.

13. These measures reduce the mortality rate of young poultry by 80% and significantly increase the welfare of the animals, leading to improved feed intake of up to 30%.

14. Disinfected drinking water also prevents diarrhea and other intestinal diseases caused by parasites.

15. After a fattening period of 45 to 60 days, the fattening chicks are attained with a carcass weight of 1200 to 1500 gr. The fattening chicks are clean and sanitized when prepared for shipping in the battle boxes.

16. Arrived in the slaughterhouse, the animals are clean and thus guarantee a particularly hygienic processing.

17. After the mast, the mast hall is de-mended and swept clean and then washed again with EOW water with preferably 500 ppm concentration of oxidative radicals per liter of water with a high-pressure cleaner and disinfected with ozone and a concentration of min. Outgassed 300 ppm per liter of air.

18. Manhole entrances and equipment equipped with disinfection basins are filled with EOW water, which is continuously renewed in the pumping circuit. 19. All equipment and cloakroom rooms are preferably fumigated twice a day with ozone gas, and ozone-producing UV-C lamps (185 nm in length) maintain a constant ozone concentration of 0.2 ppm.

The showers for the operating staff are also operated with EOW water. Before taking up work in the barn, showering is mandatory for the operating staff.

Hand wash basins are also powered by EOW water.

20. Thanks to the overpressure ventilation, germs do not enter the hygiene zones and the solid from the outside.

21. Due to the constant maintenance of an ozone concentration of 0.1 ppm by ozone producing UV-C lamps (wave range 185 nm) also become bad

Smells of ammonia and sulfur compounds eliminated, which greatly contributes to the overall well-being of the animals and thus also contributes to the rest in the stable.

In addition, the radiation of the UV lamps in the UV range from 250 nm to 850 nm wavelength, in the UV-A and UV-B range in conjunction with the vitamin D contributes to an optimal calcium metabolism and thus also to a solid bone formation.

21. The feed silos are cleaned prior to stocking with animals using EOW water and high-pressure cleaners and fumigated with ozone gas for 24 hours before being filled with fresh feed.

The feed silos are then every 7 days for 8 hours with ozone, with a

Concentration of min. Fumigated 300ppm per liter of air to prevent infection and to prevent the formation of toxic substances derived from mold fungi.

22. Solar panels, preferably mounted on the stable roof, are used to generate energy to regulate the stall temperature and reduce the total

Energy consumption.

Claims

claims

1. A method and application technique for residue-free disinfection, of persons, pets, poultry and cattle sheds and other facilities with ozone, ozonated water, electrolytic oxidative radicals, UV-C radiation, electrostatic spray technology, positive pressure ventilation and air humidification technique individually and in combined application.

2. Method and application technique for residue-free disinfection, of persons, domestic animals, poultry and cattle houses and other facilities with ozone, ozonated water-electrolytic oxidative radicals, UV-C irradiation, electrostatic spray technology, over-pressure ventilation and air humidification technology, according to

Claim 1, characterized in that ozone, ozonated water, electrolytic oxidative radicals in water, UV-C irradiation, electrostatic spray technology, overpressure ventilation and air humidification technique are used together in synergetic combination or individually to achieve a residue-free disinfection.

3. Method and application technique for residue-free disinfection, of persons, pets, poultry and cattle sheds and other facilities with ozone, electrolytic oxidative radicals, UV-C radiation, electrostatic spray technology, over-pressure ventilation and air humidification technique, according to claim 1 and 2 characterized in that the method preferably includes the following technical aids:

1. ozone generator, preferably with cathode discharge, consisting of air compressor,

Dehumidifier, oxygen generator, ozone probe, ozone alarm for ozone in air, ozone compressor, ozone gas pressure tank (15 atm) and associated inlets and outlets, gas flow meters, pressure gauges electrical control,

Ozone concentration measuring device.

6. Electrical supply system with generator and / or solar panels, and / or with electrical mains supply preferably with a power requirement of 150 KVA or on project size matched

7. Plastic tanks with ventilation of sufficient size and pressure resistance up to 4 bar for the uptake and production of ozonated water, and for the electrolyzed oxidative water including mixing systems via venturi, vortex and bubble mixers, and catalytic, thermal or chemical residues -Ozone,

Chlorine gas and hydrogen destroyers.

8. Drinking bowls and drinking lines with nipples.

10. One or more electrostatic spray nozzles with low pressure and large-volume air support by means of air compressor, for fine droplet generation and built-in electrode for inductive charging of spray drops with a drop size of ideally not more than 50 microns, a charge of the microdrops of about 600 V or 3-5 mOhms (milli-ohms) per liter, including the appropriate electronics for generating the DC charge current of the electrodes and automatic or manual control for activating or deactivating the electrodes or other suitable nozzle types.

12. High-pressure cleaner operated with oxidative water (EOW).

14. Washing plant for milking plant and milking equipment with oxidative radicals in the water, with acidic and / or alkaline rinsing - options for implementing the CIP

Putz Method (Cleaning in Place)

15. Air fans for generating overpressure and for ventilation in stables or confined spaces, with heating or cooling elements.

16. Solar panels for the production of electricity and heat by means of solar heat collectors and heat pumps.

4. Method and application technique for residue-free disinfection of persons, pets, poultry and cattle sheds and other facilities with ozone, electrolytic oxidative radicals, UV-C radiation, electrostatic spray technology, over-pressure ventilation and air humidification technology, according to claim 1 and 2 and 3 characterized in that the method preferably comprises the following process steps:

1. Disinfection of humans, animals and objects by showering with electrolytically produced oxidative radicals in the water EOW before entering the barn and into the sterile zones. (Drawing 2)

2. Disinfection of humans, animals and objects by means of ozone, electrolytic oxidative radicals, UV-C radiation, electrostatic spray technology, overpressure ventilation and air humidification technology in the stable area for the electrostatic spray disinfection of the animals by means of a spray bar (drawing 1) , for drinking water disinfection, for hoof and claw disinfection, for

Feed disinfection in the silo and at the feeding place, for fly and vermin control, for damp regulation and air circulation and air purification and air sterilization (drawing 3) and for prevention of entry of germs and pathogens through doors and windows during the installation period of the animals. 3. Disinfection of humans, animals and objects by means of ozone, electrolytic oxidative radicals, UV-C irradiation, and electrostatic spray technology, especially for stall disinfection before and after the animals come to prevent infection and disease transmission as a quarantine measure.