JP2017089306A - Multi-layered heat expansion packing for building material - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a multi-layered heat expansion packing for a building material having high mechanical strength and high adhesion between a heat expansion resin component layer and a thermoplastic resin component layer.SOLUTION: A multi-layered heat expansion packing for a building material includes a protrusion 10 and a body part 20 on a cross-section form based on a surface orthogonal to a longitudinal direction, and comprises two or more resin component layers including a heat expansion resin component layer and a thermoplastic resin component layer. Heat expansion resin components that form the heat expansion resin component layer contains a resin component and a heat expansion graphite. The resin component comprises a thermoplastic resin including a copolymer of ethylene-vinyl acetate, the copolymer of ethylene-vinyl acetate containing 20 wt.% or more of vinyl acetate.SELECTED DRAWING: Figure 2

Description

  The present invention relates to a thermally expandable multilayer packing for building materials.

  A molded body containing a thermally expandable resin composition expands when exposed to heat such as a fire to form a nonflammable expansion residue. Since this expansion residue can be used to prevent the spread of fire and the diffusion of smoke, molded articles containing a thermally expandable resin composition are widely used for building materials.

  As such a molded body, a thermally expandable multilayer packing for building materials such as a glazing channel provided with a thermally expandable resin composition layer and a plastic resin composition layer is disclosed. For example, Patent Document 1 discloses a thermally expandable multilayer packing for building materials that includes a protrusion and a main body in a cross-sectional shape with respect to a vertical plane with respect to the longitudinal direction, and includes a thermally expandable resin composition layer and a plastic resin The resin component comprised of the composition layer and contained in the thermally expandable resin composition is composed of at least one of a chlorinated polyvinyl chloride resin and EPDM having a chlorine content in the range of 60 to 72 wt. A heat-expandable multilayer packing for building materials is disclosed in which a resin composition layer and the resin composition layer are formed by co-extrusion using the heat-expandable resin composition and the resin composition, respectively. (Patent Document 1).

Patent No. 5347103

  By the way, in the thermally expandable multilayer packing for building materials such as glazing channels provided with the thermally expandable resin composition layer and the plastic resin composition layer, the resin component of the thermally expandable resin composition of the thermally expandable resin composition layer When ethylene is a vinyl acetate copolymer (EVA), the mechanical strength of the thermally expandable resin composition layer is low. Therefore, such a thermally expandable resin composition layer is generally made of polyvinyl chloride (PVC) or the like. A thermoplastic resin is integrally formed with a plastic resin composition layer containing a resin component. However, if the vinyl acetate content in EVA is low, there is a problem that polar resins such as polyvinyl chloride (PVC) have poor adhesion.

  An object of the present invention is to provide a heat-expandable multilayer packing for building materials that is excellent in mechanical strength and has high adhesion between the heat-expandable resin composition layer and the plastic resin composition layer.

  As a result of intensive studies by the present inventors in order to solve the above problems, the present inventors have determined that the content of vinyl acetate in EVA contained in the thermally expandable resin composition of the thermally expandable resin composition layer is 20 wt. In order to complete the present invention, the adhesiveness between the thermally expandable resin composition layer and the thermoplastic resin composition layer containing polyvinyl chloride (PVC) as the resin composition is improved. It came.

  That is, the present invention is as follows.

Item 1. A thermally expandable multi-layer packing for building materials including a projecting portion and a main body portion in a cross-sectional shape based on a vertical plane with respect to the longitudinal direction,
The building material thermally expandable multilayer packing comprises two or more resin composition layers including at least a thermally expandable resin composition layer and a thermoplastic resin composition layer,
The thermally expandable resin composition forming the thermally expandable resin composition layer contains a resin component and thermally expandable graphite, and the resin component contains a thermoplastic resin containing an ethylene-vinyl acetate copolymer, A thermally expandable multilayer packing for building materials, wherein the content of vinyl acetate in the ethylene-vinyl acetate copolymer is 20% by weight or more.

  Item 2. Item 2. The building material according to Item 1, wherein the thermoplastic resin composition forming the thermoplastic resin composition layer contains a polar resin selected from a polyvinyl chloride resin, a polychlorinated vinyl chloride resin, and a combination thereof. Thermally expandable multilayer packing.

  Item 3. Item 2. The thermally expandable multilayer packing for building materials according to Item 1, wherein the content of vinyl acetate in the ethylene-vinyl acetate copolymer is 25% by weight or more.

  Item 4. Item 4. The building material thermally expandable multilayer packing according to any one of Items 1 to 3, wherein the building material thermally expandable multilayer packing is a glazing channel.

  In addition to being excellent in mechanical strength, the thermally expandable multilayer packing for building materials of the present invention has high adhesiveness between the thermally expandable resin composition layer and the resin composition layer, so it is strong against mechanical external force and excellent in strength. Sealing properties such as airtightness and watertightness can be provided.

The schematic cross section for demonstrating the glazing channel which concerns on 1st Embodiment. The typical fragmentary perspective view for demonstrating the glazing channel of FIG. The typical fragmentary sectional view for demonstrating the state with which the glazing channel of FIG. 1 was mounted | worn with the glass panel. The schematic cross section for demonstrating the glazing channel which concerns on 2nd Embodiment. The schematic cross section for explaining the glazing channel concerning a 3rd embodiment. The schematic cross section for demonstrating the glazing channel which concerns on 4th Embodiment. The schematic cross section for demonstrating the glazing channel which concerns on 5th Embodiment. The schematic cross section for explaining the glazing channel concerning a 6th embodiment. The schematic cross section for demonstrating the glazing channel which concerns on 7th Embodiment. The schematic cross section for demonstrating the glazing channel which concerns on 8th Embodiment. The schematic cross section for demonstrating the glazing channel which concerns on 9th Embodiment. A schematic sectional view for explaining a glazing channel concerning a 10th embodiment. The schematic cross section for demonstrating the glazing channel which concerns on 11th Embodiment.

    First, the thermally expandable resin composition used in the present invention will be described.

  The expandable resin composition used in the present invention contains a resin component and thermally expandable graphite.

  The resin component contained in the expandable resin composition used in the present invention is made of a thermoplastic resin containing an ethylene-vinyl acetate copolymer (EVA).

The chemical formula of the ethylene-vinyl acetate copolymer (EVA) is as shown in the following formula (1), and the CH ₂ —CH (OCOCH ₃ ) moiety is a vinyl acetate moiety.

  Examples of the thermoplastic resin other than the ethylene-vinyl acetate copolymer include polyolefin resins such as polypropylene resin, polyethylene resin, poly (1-) butene resin, polypentene resin, polystyrene resin, and acrylonitrile-butadiene-styrene (ABS) resin. And synthetic resins such as polycarbonate resin, polyphenylene ether resin, (meth) acrylic resin, polyamide resin, polyvinyl chloride resin, novolac resin, polyurethane resin, and polyisobutylene.

  The resin component may also include thermosetting resins other than thermoplastic resins, rubber materials, and combinations thereof.

  Examples of the thermosetting resin include synthetic resins such as polyurethane, polyisocyanate, polyisocyanurate, phenol resin, epoxy resin, urea resin, melamine resin, unsaturated polyester resin, and polyimide.

  Rubber materials include natural rubber, isoprene rubber, butadiene rubber, 1,2-polybutadiene rubber, styrene-butadiene rubber, chloroprene rubber, nitrile rubber, butyl rubber, chlorinated butyl rubber, ethylene-propylene rubber, chlorosulfonated polyethylene, acrylic rubber And rubber materials such as epichlorohydrin rubber, polyvulcanized rubber, non-vulcanized rubber, silicon rubber, fluororubber, and urethane rubber.

  The ratio of the thermoplastic resin in the resin component is generally 50% by weight or more, 60% by weight or more, 70% by weight or more, 80% by weight or more, 90% by weight or 100% by weight. The proportion of vinyl acetate copolymer is generally 50% or more, 60% or more, 70% or more, 80% or more, 90% or more, or 100% by weight.

  In the present invention, the content of vinyl acetate in the ethylene-vinyl acetate copolymer is 20% by weight or more, more preferably 25% by weight or more based on the ethylene-vinyl acetate copolymer. When the content of vinyl acetate in the copolymer is less than 20% by weight, a thermally expandable resin composition layer formed from the thermally expandable resin composition and a thermoplastic resin composition formed from the thermoplastic resin composition Adhesion with the physical layer is reduced.

  Thermally expandable graphite is a conventionally known substance, and powders such as natural scaly graphite, pyrolytic graphite, and quiche graphite are mixed with inorganic acids such as concentrated sulfuric acid, nitric acid, and selenic acid, and concentrated nitric acid, perchloric acid, and perchlorine. A graphite intercalation compound is produced by treatment with a strong oxidizing agent such as acid salts, permanganates, dichromates and hydrogen peroxide. The heat-expandable graphite produced is a crystalline compound that maintains the layered structure of carbon.

  The heat-expandable graphite used in the present invention is obtained by neutralizing heat-expandable graphite obtained by acid treatment with ammonia, an aliphatic lower amine, an alkali metal compound, an alkaline earth metal compound, or the like. You can also.

  Examples of the aliphatic lower amine include monomethylamine, dimethylamine, trimethylamine, ethylamine, propylamine, and butylamine.

  Examples of the alkali metal compound and alkaline earth metal compound include hydroxides such as potassium, sodium, calcium, barium, and magnesium, oxides, carbonates, sulfates, and organic acid salts.

  Specific examples of the thermally expandable graphite include “CA-60S” manufactured by Nippon Kasei Co., Ltd., “GREP-EG” manufactured by Tosoh Corporation, “GRAFGUARD” manufactured by GRAFTECH, and the like.

  When the particle size of the thermally expandable graphite is 200 mesh or less, the degree of expansion of the graphite is sufficient to obtain an expanded heat insulating layer, and when the particle size is 20 mesh or more, it is added to the resin. The dispersibility at the time is good, and the mechanical properties of the obtained extruded product are good.

  For this reason, the particle size of the thermally expandable graphite is preferably in the range of 20 to 200 mesh.

  When the amount of thermally expansible graphite added decreases, the fire resistance and foamability tend to decrease. Moreover, when it increases, it will become difficult to extrusion-mold, the surface property of the obtained molded object will worsen, and there exists a tendency for a mechanical physical property to fall. For this reason, the addition amount of the thermally expandable graphite with respect to 100 parts by weight of the resin component is in the range of 3 to 350 parts by weight. The amount of thermally expandable graphite added is preferably 10 to 200 parts by weight.

  The thermally expandable resin composition may further contain an inorganic filler.

  If the said inorganic filler is an inorganic filler generally used when manufacturing a resin molding, there will be no limitation in particular. Specifically, for example, silica, diatomaceous earth, alumina, zinc oxide, titanium oxide, calcium oxide, magnesium oxide, iron oxide, tin oxide, antimony oxide, ferrites, calcium hydroxide, magnesium hydroxide, aluminum hydroxide, base Magnesium carbonate, calcium carbonate, magnesium carbonate, zinc carbonate, barium carbonate, dawnite, hydrotalcite, calcium sulfate, barium sulfate, gypsum fiber, calcium silicate, talc, clay, my strength, montmorillonite, bentonite, activated clay, Seviolite, imogolite, sericite, glass fiber, glass beads, silica balloon, aluminum nitride, boron nitride, silicon nitride, carbon black, graphite, carbon fiber, carbon balloon, charcoal powder, various metal powders, potassium titanate, Magnesium acid, titanate zirconium lead, zinc stearate, calcium stearate, aluminum borate, molybdenum sulfide, silicon carbide, stainless steel fiber, zinc borate, various magnetic powder, slag fibers, fly ash, and a dewatered sludge.

  Of these, calcium carbonate and water-containing inorganic substances such as calcium hydroxide, magnesium hydroxide, and aluminum hydroxide that are dehydrated during heating and have an endothermic effect are preferable. Antimony oxide is preferable because it has an effect of improving flame retardancy.

  The said inorganic filler can use 1 type, or 2 or more types.

  Among inorganic fillers, specific examples of aluminum hydroxide include, for example, aluminum hydroxide, “Hijilite H-31” (manufactured by Showa Denko) having a particle size of 18 μm, and “B325” (ALCOA) having a particle size of 25 μm. In the case of calcium carbonate, “Whiteon SB Red” (manufactured by Bihoku Flour Industry Co., Ltd.) having a particle size of 1.8 μm, “BF300” (manufactured by Bihoku Flour Industries Co., Ltd.) having a particle size of 8 μm and the like can be mentioned.

  When the amount of the inorganic filler added is small, the fire resistance tends to be lowered, and when it is increased, extrusion molding is difficult, the surface properties of the obtained molded article are deteriorated, and the mechanical properties tend to be lowered. For this reason, the addition amount of the said inorganic filler is the range of 3-400 weight part with respect to 100 weight part of resin components, Preferably it is 10-200 weight part.

  The thermally expandable resin composition may further contain a plasticizer.

If the said plasticizer is a plasticizer generally used when manufacturing a polyvinyl chloride resin molded object, it will not specifically limit. Specifically, for example, phthalate plasticizers such as di-2-ethylhexyl phthalate (DOP), dibutyl phthalate (DBP), diheptyl phthalate (DHP), diisodecyl phthalate (DIDP),
Fatty acid ester plasticizers such as di-2-ethylhexyl adipate (DOA), diisobutyl adipate (DIBA), dibutyl adipate (DBA),
Epoxidized ester plasticizers such as epoxidized soybean oil,
Polyester plasticizers such as adipic acid ester and adipic acid polyester,
Trimellitic acid ester plasticizers such as tri-2-ethylhexyl trimellitate (TOTM), triisononyl trimellitate (TINTM),
Phosphate ester plasticizers such as trimethyl phosphate (TMP), triethyl phosphate (TEP), phosphoric acid and land resil (TCP),
Examples include process oils such as mineral oil.

  One or more plasticizers can be used.

  When the amount of the plasticizer added is large, the flexibility becomes high, and when it is small, the extrusion moldability tends to be lowered. For this reason, although the addition amount of a plasticizer is not limited, It is preferable that the addition amount of a plasticizer is the range of 20-200 weight part with respect to 100 weight part of said resin components.

  In addition, the thermally expandable resin composition used in the present invention is generally used as necessary as a phosphorus compound, a heat stabilizer, a lubricant, and a processing aid as long as the physical properties are not impaired. One or two or more of an agent, a pyrolytic foaming agent, an antioxidant, an antistatic agent, a pigment, a crosslinking agent, a crosslinking accelerator, and the like may be added.

  The phosphorus compound is added in order to increase the strength of the expanded heat insulating layer and improve the fire prevention performance, and is not particularly limited. For example, red phosphorus; various phosphate esters excluding those that are the above plasticizers; phosphorus Examples thereof include metal phosphates such as sodium phosphate, potassium phosphate, and magnesium phosphate; ammonium polyphosphate; a compound represented by the following chemical formula (1), and the like.

In the chemical formula (1), R ¹ and R ³ represent hydrogen, a linear or branched alkyl group having 1 to 16 carbon atoms, or an aryl group having 6 to 16 carbon atoms. R ² is a hydroxyl group, a linear or branched alkyl group having 1 to 16 carbon atoms, a linear or branched alkoxyl group having 1 to 16 carbon atoms, an aryl group having 6 to 16 carbon atoms, or carbon. The aryloxy group of Formula 6-16 is represented.
As the heat stabilizer, for example, lead heat stabilizer such as tribasic lead sulfate, tribasic lead sulfite, dibasic lead phosphite, lead stearate, dibasic lead stearate,
Organotin heat stabilizers such as organotin mercapto, organotin malate, organotin laurate, dibutyltin malate,
Examples thereof include metal soap heat stabilizers such as zinc stearate and calcium stearate.

  One or more heat stabilizers can be used.

Examples of the lubricant include waxes such as polyethylene, paraffin, and montanic acid,
Various ester waxes,
Organic acids such as stearic acid, ricinoleic acid,
Organic alcohols such as stearyl alcohol,
Examples include amide compounds such as dimethylbisamide.

  One or more lubricants can be used.

  Examples of the processing aid include chlorinated polyethylene, methyl methacrylate-ethyl acrylate copolymer, and high molecular weight polymethyl methacrylate.

  Examples of the pyrolytic foaming agent include azodicarbonamide (ADCA), dinitrosopentamethylenetetramine (DPT), p, p-oxybisbenzenesulfonylhydrazide (OBSH), azobisisobutyronitrile (AIBN), and the like. Can be mentioned.

  As an antioxidant, a phenol compound etc. are mentioned, for example.

  As an antistatic agent, an amino compound etc. are mentioned, for example.

  Examples of the pigment include organic pigments such as azos, phthalocyanines, selenium, dye lakes, inorganic pigments such as oxides, molybdenum chromates, sulfides / selenides, ferrocyanides, and the like. It is done.

Examples of the cross-linking agent include sulfur. Examples of the crosslinking accelerator include tellurium diethyldithiocarbamate, N, N, N ′, N′-tetraethylthiuram disulfide, benzyl diethyldithiocarbamate, and the like.
[Specific Examples of Thermally Expandable Resin Composition]
Specific examples of the thermally expandable resin composition used in the present invention are as follows.
(A) Thermally expandable resin composition containing resin component and thermally expandable graphite (b) Thermally expandable resin composition containing resin component, thermally expandable graphite and inorganic filler (c) Resin component, thermal expansion Thermally Expandable Resin Composition Containing Expandable Graphite and Plasticizer (d) Resin Composition Composed of Resin Component, Thermally Expandable Graphite, Inorganic Filler, and Plasticizer (e) Any of (a) to (d) above For one resin composition, at least selected from the group consisting of a phosphorus compound, a heat stabilizer, a lubricant, a processing aid, a pyrolytic foaming agent, an antioxidant, an antistatic agent, a pigment, a crosslinking agent, and a crosslinking accelerator. Next, the thermoplastic resin composition used in the present invention will be described.

  The thermoplastic resin composition used in the present invention contains a polar resin (polar resin). Examples of the polar resin include ABS resin, acetal resin, methacrylic resin, polyvinyl chloride resin, polychlorinated vinyl chloride resin, and the like, preferably polyvinyl chloride resin (PVC), polychlorinated vinyl chloride resin ( CPVC), and combinations thereof.

Examples of the polyvinyl chloride resin include vinyl chloride homopolymers,
A copolymer of a vinyl chloride monomer and a monomer having an unsaturated bond copolymerizable with the vinyl chloride monomer;
Examples thereof include polymers other than vinyl chloride monomers or graft copolymers obtained by graft copolymerization of vinyl chloride with copolymers other than vinyl chloride monomers.

  The said polyvinyl chloride resin can use 1 type, or 2 or more types.

The monomer having an unsaturated bond copolymerizable with the vinyl chloride monomer is not particularly limited as long as it is copolymerizable with the vinyl chloride monomer. For example, α-olefins such as ethylene, propylene, butylene,
Vinyl esters such as vinyl acetate and vinyl propionate,
Vinyl ethers such as butyl vinyl ether and cetyl vinyl ether,
Acrylic esters such as methyl acrylate, ethyl acrylate, butyl acrylate,
Methacrylic acid esters such as methyl methacrylate, ethyl methacrylate, butyl methacrylate,
Aromatic vinyls such as styrene and α-methylstyrene,
N-substituted maleimides such as N-phenylmaleimide and N-cyclohexylmaleimide are exemplified.

  One or two or more monomers having an unsaturated bond copolymerizable with the vinyl chloride monomer can be used.

The polymer other than the vinyl chloride monomer or the copolymer other than the vinyl chloride monomer is not particularly limited as long as it is a graft polymer of vinyl chloride or a graft copolymer, and for example, an ethylene-vinyl acetate copolymer. ,
Ethylene-vinyl acetate-carbon monoxide copolymer, ethylene-ethyl acrylate copolymer, ethylene-butyl acrylate-carbon monoxide copolymer, ethylene-methyl methacrylate copolymer, ethylene-propylene copolymer, acrylonitrile-butadiene Copolymers, polyurethane, chlorinated polyethylene, chlorinated polypropylene and the like can be mentioned.

  These can use 1 type, or 2 or more types.

  The polyvinyl chloride resin and the chlorinated polyvinyl chloride resin are not particularly limited, and any conventionally known polyvinyl chloride resin can be used.

  The polyvinyl chloride resin composition used for the thermoplastic resin composition is conventionally known, and for example, those defined in the Japanese Industrial Standard (JIS) can be used.

  The polyvinyl chloride resin composition includes a soft polyvinyl chloride resin composition and a hard polyvinyl chloride resin composition.

  Usually, the soft polyvinyl chloride resin composition contains a plasticizer, and the hard polyvinyl chloride resin composition does not contain a plasticizer. As the plasticizer, the same plasticizer as described above can be used.

  In addition, as the soft polyvinyl chloride resin composition, for example, a soft polyvinyl chloride compound (JIS K6723) defined in Japanese Industrial Standard can be used.

  As the hard polyvinyl chloride resin composition, for example, unplasticized polyvinyl chloride-molding and extrusion materials (JIS K6740-1) defined in Japanese Industrial Standard can be used.

  Moreover, as said chlorinated polyvinyl chloride resin (CPVC), what chlorinated the polyvinyl chloride resin (PVC) demonstrated previously, etc. are mentioned, for example.

  When vinyl chloride resin, chlorinated polyvinyl chloride resin, and combinations thereof are selected as the resin component, the resulting thermally expandable multi-layer packing for building materials provides mechanical strength, flexibility, airtightness, watertightness, and strength. Excellent.

  The average degree of polymerization of the polyvinyl chloride resin is not particularly limited, but the average degree of polymerization of the polyvinyl chloride resin is preferably in the range of 600 to 1500 from the viewpoint of mechanical properties and melt extrusion molding.

  Moreover, as a resin component contained in the said thermoplastic resin composition, you may include said thermoplastic resins other than polar resin, said thermosetting resin, said rubber substance, and those combinations.

  The thermoplastic resin composition used in the present invention can be obtained by adding the above-described inorganic filler and plasticizer described above to the resin component contained in the thermoplastic resin composition.

  In the thermoplastic resin composition used in the present invention, a phosphorus compound as a flame retardant, a heat stabilizer, a lubricant, which is generally used at the time of extrusion molding, as long as the physical properties are not impaired. Processing aids, pyrolytic foaming agents, antioxidants, antistatic agents, pigments and the like may be added.

These specific examples are the same as those exemplified above.
[Specific examples of thermoplastic resin composition]
Specific examples of the thermoplastic resin composition used in the present invention are as follows.
(F) Thermoplastic resin composition containing resin component and inorganic filler (g) Thermoplastic resin composition containing resin component and plasticizer (h) Containing resin component, plasticizer and inorganic filler Thermoplastic resin composition (i) Phosphorus compound, thermal stabilizer, lubricant, processing aid, pyrolytic foaming agent, antioxidant for any one of the thermoplastic resin compositions (f) to (h) above A resin composition comprising at least one selected from the group consisting of an agent, an antistatic agent, a pigment, a crosslinking agent, and a crosslinking accelerator. By selecting a resin component to be used in the thermoplastic resin composition, the present invention Various functions can be imparted to the thermally expandable multilayer packing for building materials.

  Using the above-described thermally expandable resin composition and thermoplastic resin composition, any known method can be used to produce a thermally expandable multilayer packing for building materials. For example, the thermally expandable resin composition and the thermoplastic resin composition can be individually molded and then bonded, or a thermally expandable multilayer packing for building materials can be produced by extrusion molding. In the case of extrusion molding, using two resin compositions of a heat-expandable resin composition and a thermoplastic resin composition, according to a conventional method, at 130 to 170 ° C. with an extruder such as a single screw extruder or a twin screw extruder. By melting and co-extrusion at the same time, it is possible to obtain a long thermal expansion multilayer packing for building materials having a multilayer structure including at least a thermal expansion resin composition layer and a thermoplastic resin composition layer.

  In the thermally expandable multilayer packing for building materials of the present invention, the thermally expandable resin composition that forms the thermally expandable resin composition layer is the polar resin that the thermoplastic resin composition that forms the thermoplastic resin composition layer. Since it contains, it is excellent in the mechanical strength of the thermally expansible multilayer packing for building materials, and the adhesiveness between a thermally expansible resin composition layer and a thermoplastic resin composition layer is high.

  By cutting the long thermally expandable multilayer packing for building materials into an appropriate length according to the use, the thermally expandable multilayer packing for building materials of the present invention is obtained.

  Examples of the thermally expandable multilayer packing for building materials of the present invention include those used for building materials such as windows and doors. Specific examples of the thermally expandable multilayer packing for building materials include, for example, a glazing channel, a tight material, a gasket, or a glazing bead material.

Hereinafter, the present invention will be described in detail according to first to eleventh embodiments with reference to the drawings. The present invention is not limited to these embodiments.
(First embodiment)
[Structure of glazing channel 100]
FIG. 1 is a schematic cross-sectional view for explaining a glazing channel as a thermally expandable multilayer packing for building materials according to the first embodiment, and FIG. 1 is based on a vertical plane with respect to the longitudinal direction of the glazing channel according to the first embodiment. It shows a cross-sectional shape. FIG. 2 is a schematic partial perspective view for explaining the glazing channel according to the first embodiment. FIG. 3 is a schematic partial cross-sectional view for explaining a state in which the glazing channel according to the first embodiment is mounted on the glass panel.

  The glazing channel 100 according to the first embodiment is attached to a peripheral portion 610 of a glass panel 600 formed by stacking two or more glass plates. The glazing channel 100 includes a bottom wall portion 1 facing the end surface 601 of the glass panel 600 and a side wall portion 2 provided on both sides of the bottom wall portion 1 and covering the glass panel peripheral portion 610 along the longitudinal direction of the glass panel end surface 601. And have. The bottom wall portion 1 and the side wall portion 2 form the main body portion 10 of the glazing channel 100.

The bottom wall portion 1 and the side wall portion 2 included in the glazing channel 100 are formed of a hard vinyl chloride resin composition.

  A protrusion 20 is provided on the upper portion of the side wall 2. The protruding portion 20 has outer fin portions 21a and 21a and inner fin portions 21b and 21b protruding toward the inside, that is, the glass panel 600 side.

  Moreover, the protrusion part 20 has the groove parts 21c and 21c in the outer side, ie, the opposite side to the glass panel 600 side. The glazing channel 100 can be fixed to the sash 620 by inserting the end of the sash 620 into the grooves 21c and 21c.

The protrusion 20 is formed of a thermally expandable resin composition.
[Production example of glazing channel 100]
The glazing channel 100 according to the first embodiment can be manufactured by co-extrusion molding using a heat-expandable resin composition for the protrusion 20 and a thermoplastic resin for the main body 10.
[Operation of Grazing Channel 100]
A glazing channel 100 shown in FIG. 1 has a protrusion 20 made of a thermally expandable resin composition layer and a main body 10 made of a thermoplastic resin composition layer.

  Since the thermally expandable resin composition layer expands due to heat such as a fire, it has a fire resistance function.

  On the other hand, the thermoplastic resin composition layer functions as a protective layer that protects the glass panel 600 from an external impact.

  Thus, since the glazing channel 100 according to the first embodiment has two or more resin composition layers having different functions, a plurality of different functions can be imparted to one glazing channel 100.

  When the sash 620 provided with the glazing channel 100 and the glass panel 600 shown in FIG. 3 is exposed to heat such as a fire, the protrusion 20 made of the thermally expandable resin composition layer expands. The expansion residue generated by this expansion closes the gap between the glass panel 600 and the sash 620.

  Due to this expansion residue, it is possible to delay the entry of flames, smoke, etc. generated by a fire through the gap between the glass panel 600 and the sash 620 to the side where no fire is generated.

As described above, the sash 620 including the glazing channel 100 according to the first embodiment is excellent in fire resistance.
(Second Embodiment)
[Structure of glazing channel 110]
FIG. 4 is a schematic cross-sectional view for explaining a glazing channel according to the second embodiment.

  In the glazing channel 100 according to the first embodiment, the protrusion 20 is a thermally expandable resin composition layer, and the main body 10 is a thermoplastic resin layer.

  On the other hand, the glazing channel 110 according to the second embodiment is different in that the protrusion 20 is a thermoplastic resin layer and the main body 10 is a thermally expandable resin composition layer.

The glazing channel 110 obtained by co-extrusion molding is excellent in appearance.
[Production Example of Grazing Channel 110]
Similar to the glazing channel 100 of the first embodiment, the glazing channel 110 according to the second embodiment can be manufactured by co-extrusion molding. Hereinafter, the glazing channels 120 to 200 of the third to eleventh embodiments can also be manufactured by co-extrusion molding.
[Operation of Grazing Channel 110]
The glazing channel 110 shown in FIG. 4 has a projection 20 made of a thermoplastic resin composition layer and a main body 10 made of a thermally expandable resin composition layer.

  Since the thermally expandable resin composition layer expands due to heat such as a fire, it has a fire resistance function. On the other hand, since the projection part 20 which consists of a thermoplastic resin composition layer is formed from the soft polyvinyl chloride resin composition, it has a softness | flexibility and can be made to contact | adhere with the glass panel 600. FIG.

  For this reason, the protrusion 20 can prevent water or the like condensed on the glass panel 600 from entering the inside of the sash.

In the glazing channel 110 according to the second embodiment, the main body 10 made of a thermally expandable resin composition layer expands due to heat such as a fire. A gap between the glass panel 600 and the sash 620 can be closed by the expansion residue.
(Third embodiment)
[Structure of glazing channel 120]
FIG. 5 is a schematic cross-sectional view for explaining a glazing channel according to the third embodiment.

  In the glazing channel 100 according to the first embodiment, the protrusion 20 is a thermally expandable resin composition layer, and the main body 10 is a thermoplastic resin layer.

  In contrast, in the glazing channel 120 according to the third embodiment, the protrusion 20 and the main body 10 are a thermoplastic resin layer containing soft polyvinyl chloride, and the inner bottom wall 4 in contact with the main body 10 is a thermally expandable resin. The difference is that it is a composition layer. Therefore, the glazing channel 120 obtained by co-extrusion molding is excellent in appearance.

The inner bottom wall 4 is installed in contact with the bottom wall 1 and the side wall 2.
[Operation of Grazing Channel 120]
The glazing channel 120 shown in FIG. 5 has the protrusion part 20 and the main-body part 10 which consist of a thermoplastic resin composition layer, and the inner bottom wall part 4 which consists of a thermally expansible resin composition layer.

  Since the thermally expandable resin composition layer expands due to heat such as a fire, it has a fire resistance function.

  On the other hand, since the protrusion 20 and the main body 10 formed from the thermoplastic resin composition layer are formed from a resin composition containing soft polyvinyl chloride, they have flexibility and are brought into close contact with the glass panel 600. Easy to install.

For this reason, the protrusion 20 can prevent water or the like condensed on the glass panel 600 from entering the inside of the sash.
(Fourth embodiment)
[Structure of glazing channel 130]
FIG. 6 is a schematic cross-sectional view for explaining a glazing channel according to the fourth embodiment.

  In the glazing channel 100 according to the first embodiment, the protrusion 20 is a thermally expandable resin composition layer, and the main body 10 is a thermoplastic resin layer.

  On the other hand, in the glazing channel 130 according to the fourth embodiment, the protrusion 20 is made of a thermoplastic resin layer containing soft polyvinyl chloride, and the main body 10 is made of a thermoplastic resin layer containing hard polyvinyl chloride. The difference is that the inner bottom wall portion 4 in contact with 10 is made of a thermally expandable resin composition layer.

Note that the inner bottom wall portion 4 is installed in contact with the bottom wall portion 1 and the side wall portion 2 in the same manner as in the third embodiment.
[Operation of glazing channel 130]
The glazing channel 130 shown in FIG. 6 has the protrusion part 20 and the main-body part 10 which consist of a thermoplastic resin composition layer, and the inner bottom wall part 4 which consists of a thermally expansible resin composition layer.

  Since the thermally expandable resin composition layer expands due to heat such as a fire, it has a fire resistance function.

  On the other hand, since the thermoplastic resin composition layer of the protrusion 20 is formed of a resin composition containing soft polyvinyl chloride, the protrusion 20 of the glazing channel 130 has flexibility and is in close contact with the glass panel 600. And can be easily installed.

  For this reason, the protrusion 20 can prevent water or the like condensed on the glass panel 600 from entering the inside of the sash.

Moreover, since the thermoplastic resin composition layer of the main-body part 10 is formed from the resin composition containing hard polyvinyl chloride, the glass panel 600 can be hold | maintained.
(Fifth embodiment)
[Structure of glazing channel 140]
FIG. 7 is a schematic cross-sectional view for explaining a glazing channel according to the fifth embodiment.

  The glazing channel 140 according to the fifth embodiment is a modification of the glazing channel 130 according to the previous fourth embodiment.

  In the case of the glazing channel 130 according to the previous fourth embodiment, the inner bottom wall portion 4 made of the thermally expandable resin composition layer was installed in contact with the inside of the main body portion 10.

  On the other hand, the glazing channel 140 according to the fifth embodiment is different in that the outer bottom wall portion 5 made of a thermally expandable resin composition layer is installed in contact with the outside of the main body portion 10.

The rest is the same as in the case of the fourth embodiment.
(Sixth embodiment)
[Structure of glazing channel 150]
FIG. 8 is a schematic cross-sectional view for explaining a glazing channel according to the sixth embodiment.

  A glazing channel 150 according to the sixth embodiment is a modification of the glazing channel 130 according to the fourth embodiment.

  In the case of the glazing channel 130 according to the previous fourth embodiment, the inner bottom wall portion 4 made of the thermally expandable resin composition layer was installed in contact with the inside of the main body portion 10.

  In contrast, in the glazing channel 150 according to the sixth embodiment, the inner side wall portions 6 and 6 made of the thermally expandable resin composition layer are installed in contact with the inner side of the side wall portions 2 and 2 of the main body portion 10, respectively. Is different.

The rest is the same as in the case of the fourth embodiment.
(Seventh embodiment)
[Structure of glazing channel 160]
FIG. 9 is a schematic cross-sectional view for explaining a glazing channel according to the seventh embodiment.

  A glazing channel 160 according to the seventh embodiment is a modification of the glazing channel 130 according to the fourth embodiment.

  In the case of the glazing channel 130 according to the previous fourth embodiment, the inner bottom wall portion 4 made of the thermally expandable resin composition layer was installed in contact with the inside of the main body portion 10.

  In contrast, in the glazing channel 160 according to the seventh embodiment, the outer wall portions 7 and 7 made of a thermally expandable resin composition layer are installed in contact with the outer sides of the side wall portions 2 and 2 of the main body portion 10, respectively. Is different.

The rest is the same as in the case of the fourth embodiment.
(Eighth embodiment)
[Structure of glazing channel 170]
FIG. 10 is a schematic cross-sectional view for explaining a glazing channel according to the eighth embodiment.

  The glazing channel 170 according to the eighth embodiment is a modification of the glazing channel 110 according to the second embodiment.

  In the case of the glazing channel 110 according to the previous second embodiment, the projection 20 made of the thermoplastic resin layer and the main body 10 made of the thermally expandable resin composition layer were provided.

  In contrast, the glazing channel 170 according to the eighth embodiment includes an outer main body portion 8 made of a thermoplastic resin layer in contact with the main body portion 10 in addition to the configuration of the glazing channel 130 according to the second embodiment. Different.

The rest is the same as in the case of the second embodiment.
(Ninth embodiment)
[Structure of glazing channel 180]
FIG. 11 is a schematic cross-sectional view for explaining a glazing channel according to the ninth embodiment.

  The glazing channel 180 according to the ninth embodiment is a modification of the glazing channel 110 according to the second embodiment.

  In the case of the glazing channel 110 according to the previous second embodiment, the protrusion 20 made of a thermoplastic resin layer using a polyvinyl chloride resin composition containing soft polyvinyl chloride and a main body made of a thermally expandable resin composition layer Part 10.

  In contrast, in the glazing channel 180 according to the ninth embodiment, the bottom wall portion 1 is made of a thermally expandable resin composition layer, and the side wall portions 2 and 2 are made of a polyvinyl chloride resin composition containing hard polyvinyl chloride. The point which consists of the used thermoplastic resin layer differs.

The rest is the same as in the case of the second embodiment.
(10th Embodiment)
[Structure of glazing channel 190]
FIG. 12 is a schematic cross-sectional view for explaining a glazing channel according to the tenth embodiment.

  A glazing channel 190 according to the tenth embodiment is a modification of the glazing channel 110 according to the second embodiment.

  In the case of the glazing channel 110 according to the second embodiment, the thermally expandable resin composition layer and the thermoplastic resin composition layer in the cross section of the glazing channel 110 with respect to the plane perpendicular to the co-extrusion direction during production. Is a straight line (see FIG. 4).

  In contrast, the boundary line 15 between the thermally expandable resin composition layer and the thermoplastic resin composition layer in the cross section of the glazing channel 190 according to the tenth embodiment is a curved line (see FIG. 12).

  By making the boundary line 15 into a curve, the contact area between the thermally expandable resin composition layer and the thermoplastic resin composition layer in the cross section of the glazing channel 190 can be made larger than in the case of the second embodiment. it can.

Thus, even when an impact or the like is applied to the glazing channel 190 by increasing the contact area between the thermally expandable resin composition layer and the thermoplastic resin composition layer in the cross section of the glazing channel 190, the thermally expandable resin Peeling of the interface between the composition layer and the thermoplastic resin composition layer can be reduced.
(Eleventh embodiment)
[Structure of glazing channel 200]
FIG. 13 is a schematic cross-sectional view for explaining a glazing channel according to the eleventh embodiment.

  The glazing channel 200 according to the eleventh embodiment is a modification of the glazing channel 190 according to the previous tenth embodiment.

  In the case of the glazing channel 190 according to the tenth embodiment, the boundary line between the thermally expandable resin composition layer and the thermoplastic resin composition layer in the cross section of the glazing channel 190 with respect to the plane perpendicular to the co-extrusion direction. 15 was a curve.

  On the other hand, the boundary line 16 between the thermally expandable resin composition layer and the thermoplastic resin composition layer in the cross section of the glazing channel 200 is a broken line.

  The number of folding points forming the fold line is not limited, but is preferably in the range of 1-100, more preferably in the range of 1-20, and even more preferably in the range of 1-10.

  By making the boundary line 16 a broken line, the contact area between the thermally expandable resin composition layer and the thermoplastic resin composition layer in the cross section of the glazing channel 190 is increased as compared with the case of the second embodiment. Can do.

  In this way, even when an impact or the like is applied to the glazing channel 200 by increasing the contact area between the thermally expandable resin composition layer and the thermoplastic resin composition layer in the cross section of the glazing channel 200, the thermally expandable resin. Peeling of the interface between the composition layer and the thermoplastic resin composition layer can be reduced.

[Production Examples of Example 1, Example 2 and Comparative Example 1]
With the compositions shown in Table 1, laminates of Example 1, Example 2 and Comparative Example 1 consisting of two layers of a thermally expandable resin composition layer and a thermally expandable resin composition layer were produced. The units in the table are parts by weight.

  The acquisition place of each component of a thermally expansible resin composition is as follows.

  Ethylene-vinyl acetate copolymer (Mitsui Chemicals Co., Ltd.), thermally expandable graphite (“GREP-EG” manufactured by Tosoh Corporation), inorganic filler (zinc oxide), plasticizer (J Plus Co., Ltd. “DIDP”) ), Flame retardant (Nissan Chemical Industry Co., Ltd.).

  The source of each component of the thermoplastic resin composition is as follows.

  Polyvinyl chloride (Shin-Etsu Chemical Co., Ltd., polymerization degree 1000), inorganic filler (calcium carbonate), plasticizer (J Plus Co., Ltd. “DIDP”), flame retardant (Nissan Chemical Industry Co., Ltd.), Ca—Zn composite stable Agent (Mizusawa Chemical Co., Ltd. "NT-231"), calcium stearate (Sakai Chemical Industry Co., Ltd. "SC-100").

  The thermally expandable resin composition and the thermoplastic resin composition are supplied to a single screw extruder (Ikegai Machine Sales Co., Ltd., 65 mm extruder) and co-extruded at a speed of 1 m / hr, and the thermally expandable resin composition layer and Simultaneous coextrusion molding consisting of two layers of the thermoplastic resin composition layer was formed.

  The adhesion between the thermally expandable resin composition layer and the thermoplastic resin composition layer was evaluated by the adhesion between the two layers when the thermally expandable resin composition layer and the thermoplastic resin composition layer were peeled by hand. When the material of the heat-expandable resin composition layer is destroyed without being peeled at the interface with the thermoplastic resin composition layer when the heat-expandable resin composition layer is peeled off (that is, a part of the heat-expandable resin composition layer) Only partly peels off, and a part of the thermally expandable resin composition layer remains in the thermoplastic resin composition layer without peeling off), and the thermally expandable resin composition layer can be clearly separated from the thermoplastic resin composition layer. The case was marked with x.

  As a result, the laminates of Examples 1 and 2 had good adhesion between the two layers, and Comparative Example 1 had poor adhesion between the two layers.

Claims (4)

A thermally expandable multi-layer packing for building materials including a projecting portion and a main body portion in a cross-sectional shape based on a vertical plane with respect to the longitudinal direction,
The building material thermally expandable multilayer packing comprises two or more resin composition layers including at least a thermally expandable resin composition layer and a thermoplastic resin composition layer,
The thermally expandable resin composition forming the thermally expandable resin composition layer contains a resin component and thermally expandable graphite, and the resin component contains a thermoplastic resin containing an ethylene-vinyl acetate copolymer, A thermally expandable multilayer packing for building materials, wherein the content of vinyl acetate in the ethylene-vinyl acetate copolymer is 20% by weight or more.   The building material according to claim 1, wherein the thermoplastic resin composition forming the thermoplastic resin composition layer contains a polar resin selected from a polyvinyl chloride resin, a polychlorinated vinyl chloride resin, and a combination thereof. Thermally expandable multilayer packing.   The thermally expandable multilayer packing for building materials according to claim 1, wherein the content of vinyl acetate in the ethylene-vinyl acetate copolymer is 25% by weight or more. The thermally expandable multilayer packing for building materials according to any one of claims 1 to 3, wherein the thermally expandable multilayer packing for building materials is a glazing channel.