JP2017074999A - Storage method and transport method of package of polyvinyl alcohol-based polymer film - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a package where water derived from dew condensation is hardly immersed into the package even when dew condensation occurs on the surface of the package such as the inner peripheral surface of a cylindrical core and the like and to provide a storage method and a transport method of the package using the package.SOLUTION: In a package where a roll wound with a PVA film (3, 24) on a cylindrical core (2, 21) is packaged by a packaging material (11, 25), a projection projecting both ends of the core (2, 21) from roll end surfaces is formed and at least a part of the end of the packaging material (11, 25) is fixed on the outer peripheral surface (22) of the projection for making the immersion of water derived from dew condensation into the package difficult even when dew condensation occurs on the inner surface of the core (2, 21) and the like.SELECTED DRAWING: Figure 3

Description

  The present invention relates to a package formed by packaging a roll in which a polyvinyl alcohol polymer film is wound around a cylindrical core with a packaging material, and a method for storing or transporting the package.

  The plastic film is usually stored or transported in the form of a package formed by wrapping a roll formed on a cylindrical core with a packaging material. By setting it as a package, the deterioration of the external appearance by the adhesion of water to the roll surface can be prevented, or the adverse effect on film properties due to moisture absorption can be prevented. In particular, in the case of a plastic film having a high hygroscopic property, such as a polyvinyl alcohol polymer (hereinafter, “polyvinyl alcohol polymer” may be abbreviated as “PVA”), which is a raw material of the polarizing film, the inside of the packaging body. Due to the ingress of moisture, the quality of the film changes due to an increase in the moisture content of the film and the occurrence of moisture spots, resulting in a problem that the processability when processing into a secondary product such as a polarizing film is not stable and the productivity is reduced. Arise. For this reason, in a plastic film or the like where quality deterioration due to moisture absorption is a concern, it is important in storage or transportation to improve the protection from moisture caused by condensation or moisture.

Several packaging methods for packaging plastic film rolls with moisture-proof packaging materials have been known.
For example, a method is known in which a PVA film is wound around a specific core to form a film roll, which is packaged with a packaging film having a moisture permeability of 10 g / m ² / day or less and stored or transported (see Patent Document 1). ). Patent Document 1 describes a method of wrapping a film roll with a wrapping film and pushing a remaining portion in the width direction into a core.

  Moreover, it is known to wind up a hygroscopic film around a core material and wrap it with a packaging material containing a specific film (see Patent Document 2). Patent Document 2 relates to a packaging method, in which after a width direction end portion of a packaging film (packaging material) is pushed into a hollow portion of a tubular core material, a suspension cap is inserted into the hollow portion of the core material. Have been described.

Further, a film roll in which a long film member is wound around the core while leaving both ends of the core, a packaging sheet that covers the film roll, and both side edges of the packaging sheet that wraps the film roll are connected to the core. A film roll package (see Patent Document 3) having a specific packaging rubber band fixed to both ends is known. In Patent Document 3, both side edges (both ends) refer to portions when the packaging sheet is viewed macroscopically, and the packaging sheet is sufficiently fixed even when the packaging rubber band moves in the length direction of the core. Thus, the rubber band for packaging is arrange | positioned in the part away from the edge of the packaging sheet. Therefore, in Patent Document 3, the end of the packaging sheet is a free end without being fixed to both ends of the core.

JP 2001-315895 A JP 2002-308343 A JP 2010-179922 A

  Recently, with PVA film, which is a raw material for polarizing films for liquid crystal displays, as the size of liquid crystal displays increases, wider PVA films are required, and in order to improve workability and productivity of polarizing films, Long PVA films are also desired. With the increase in the width and lengthening of such PVA film, the weight of the roll has increased, so that when the roll is loaded and unloaded and moved onto the gantry or processing apparatus, a support rod is inserted into the core for handling. Methods have come to be used extensively. Therefore, to facilitate the insertion of the support rod into the core, the cylindrical core is opened without closing both ends with a cap or the like, and the roll is transported or stored with the core exposed to the outside air. Has increased. In addition, as for the material of the cylindrical core, a metal having a high strength (such as bending rigidity), carbon fiber reinforced plastic, or a composite material thereof has been used.

  By the way, in a cold district in winter, when a package is carried from a storage place that is not air-conditioned to an air-conditioned processing place, condensation may occur on the surface of the package. In particular, recently, as the weight of the roll has increased as described above, dew condensation is more likely to occur due to the increase in the heat capacity of the roll and the accompanying decrease in the temperature change rate of the entire roll. In addition, as described above, metal cores and carbon fiber reinforced plastic cores have come to be used with increasing roll weight, but metal or plastic cores can be used as paper cores. Condensation is likely to occur. Such condensation is particularly likely to occur on the inner peripheral surface of the cylindrical core that is susceptible to the temperature of the PVA film. Therefore, when adopting a method of pushing a surplus portion in the width direction of the packaging material into the core as described in Patent Document 1, dew condensation occurs on the surface of the package, such as the inner peripheral surface of the cylindrical core. When this occurs, there arises a problem that water derived from condensation enters the inside of the package from between the pressed packaging material and the inner peripheral surface of the core. On the other hand, in the method of penetrating the suspension cap into the hollow portion of the core material as described in Patent Document 2, condensation on the inner peripheral surface of the core is prevented while the suspension cap is attached, In addition, water derived from condensation other than on the inner peripheral surface of the core is difficult to enter the package, but when the suspension cap is removed to insert the support rod into the core, the inside of the core Condensation occurs on the peripheral surface, or water derived from condensation other than on the inner peripheral surface of the core moves on the surface of the packaging material, causing water to flow between the packaging material and the inner peripheral surface of the core. The problem of intrusion into the packaging body still arises.

  Accordingly, the present invention provides a packaging body in which water derived from dew condensation hardly enters the packaging body even when condensation occurs on the surface of the packaging body, such as an inner peripheral surface of a cylindrical core, and the packaging The object is to provide a method for storing or transporting a package using the body.

  As a result of intensive studies to achieve the above-mentioned object, the present inventors have packed water by fixing the end of the packaging material on the outer peripheral surface of the protruding portion of the core when packaging the roll with the packaging material. It was found that the intrusion into the body was effectively prevented and the above-mentioned object was achieved, and further studies were made based on this finding to complete the present invention.

That is, the present invention
[1] A package in which a roll in which a PVA film is wound around a cylindrical core is wrapped with a packaging material, and both end portions of the core form protrusions protruding from the roll end surface, A packaging body in which at least a part of an end of the packaging material is fixed on an outer peripheral surface of the protruding portion;
[2] The package of the above [1], wherein at least a part of the surface of the core is made of metal and / or plastic.
[3] The package according to [1] or [2], wherein an inner peripheral surface of the core is exposed to outside air in the package.
[4] The package according to any one of the above [1] to [3], wherein the width of the PVA film is 2.1 m or more,
[5] The package according to any one of [1] to [4], wherein the roll has a mass of 0.5 t or more.
[6] The above [1] to [5], in which the end of the packaging material fixed on the outer peripheral surface of the projecting part substantially circulates the outer periphery of the projecting part in each of the projecting parts. Any one package,
[7] The adhesive tape is wound around the outer periphery of the protruding portion so that the adhesive surface of the adhesive tape is in contact with both the packaging material and the outer peripheral surface of the protruding portion in each of the two protruding portions. 1]-[6] any one package,
[8] In each of the two protruding portions, the protruding portion is tightened along the outer periphery of the protruding portion via the packaging material in which at least a part of the end is fixed on the outer peripheral surface of the protruding portion by the fastening member. The package according to any one of the above [1] to [7],
[9] The packaging material is less of a film water vapor permeability of ^5g / m 2 / 24h, the [1] to any one of the package of [8],
[10] A method of storing a package, wherein the package of any one of [1] to [9] is stored at 10 ° C. or lower.
[11] A method for transporting a package, wherein the package is transported in a state where a support rod is put inside the core of any one of the above [1] to [9].
About.

  According to the packaging body of the present invention, even when condensation occurs on the surface of the packaging body, such as the inner peripheral surface of the cylindrical core, it is difficult for water derived from condensation to enter the interior of the packaging body.

It is the schematic which shows an example of the roll used in this invention. It is the schematic which shows an example of the packaging method at the time of packaging a roll with a sheet-like packaging material. It is the schematic which shows an example of the cross section of the protrusion part vicinity of the package body by which the edge of the packaging material is being fixed on the outer peripheral surface of the protrusion part by the adhesive tape.

Hereinafter, the present invention will be described in detail.
The roll used in the present invention is formed by winding a PVA film around a cylindrical core. And the both ends of the said core form the protrusion part which protrudes from a roll end surface. FIG. 1 is a schematic view showing an example of a roll used in the present invention. In FIG. 1, a roll 1 is formed by winding a PVA film 3 around a cylindrical core 2. Each of both end portions 4 of the cylindrical core 2 forms a protruding portion 6 that protrudes outward from the roll end surface 5 in the length direction of the core.

  There is no restriction | limiting in particular in the kind of said cylindrical core, For example, a metal thing, a plastic thing, a paper thing, a wooden thing etc. are mentioned. It is also possible to use a core in the form of a composite, such as one using both metal and plastic, one using both metal and paper, and one using both plastic and paper. Among these, a metal and / or plastic core is preferable because it has high strength and the effects of the present invention are more prominent, and is not easily affected by wear or the like even when used repeatedly. The core is more preferable. The proportion of the mass of the metal and plastic with respect to the total mass of the cylindrical core is preferably 50% by mass or more, more preferably 80% by mass or more, and further preferably 95% by mass or more. The amount is preferably 100% by mass.

  Examples of the metal include iron, stainless steel, and aluminum. One of these may be used alone, or two or more may be used in combination. Among these, aluminum is preferable from the viewpoint of strength, lightness, price, and the like.

  Examples of the plastic include polyvinyl chloride, polyvinylidene chloride, polyester, polycarbonate, polyamide, epoxy resin, polyurethane, polyurea, and silicone resin. One of these is used alone. Moreover, you may use 2 or more types together. Of these, polyvinyl chloride is preferred. The plastic is also preferably a fiber reinforced plastic (FRP) such as a carbon fiber reinforced plastic from the viewpoint of strength and the like.

  In the present invention, water derived from condensation is packaged even when a core where condensation is likely to occur such as at least a part of the material of the surface of the cylindrical core is metal and / or plastic. Difficult to penetrate inside the body. Therefore, when such a core is used, the effect of the present invention is more remarkably exhibited. The cylindrical core has at least a part of its inner peripheral surface (preferably 50% or more of the area of the inner peripheral surface, more preferably the area of the inner peripheral surface because the effects of the present invention are more remarkably exhibited. 80% or more) is preferably a metal and / or plastic, more preferably the entire inner peripheral surface is a metal and / or plastic, and the entire surface of the cylindrical core is a metal. More preferably, it is plastic.

  The length of the cylindrical core is longer than the width of the PVA film so that both ends of the cylindrical core can form protrusions protruding from the roll end surface. The length of the cylindrical core is preferably longer in the range of 5 to 100 cm and more preferably longer in the range of 10 to 45 cm than the width of the PVA film described later from the viewpoint of handleability and the like. More preferably, it is longer within the range of 15 to 30 cm.

The diameter of the cylindrical core is not particularly limited, but the outer diameter is preferably in the range of 50 to 800 mm, more preferably in the range of 80 to 500 mm, from the viewpoint of strength, handleability, and the like. More preferably, it is in the range of 100 to 300 mm, and particularly preferably in the range of 150 to 250 mm.
In addition, the thickness of the cylindrical core is preferably in the range of 2 to 50 mm, more preferably in the range of 3 to 20 mm, from the viewpoint of strength, handleability, and the like, and in the range of 4 to 10 mm. More preferably, it is within.

  The roll used in the present invention is formed by winding a PVA film around a cylindrical core. Since the PVA film is greatly deteriorated in quality due to moisture absorption, the effects of the present invention are remarkably exhibited.

  As PVA which comprises a PVA film, what was manufactured by saponifying the vinyl ester polymer obtained by superposing | polymerizing a vinyl ester monomer can be used. Examples of vinyl ester monomers include vinyl formate, vinyl acetate, vinyl propionate, vinyl valerate, vinyl laurate, vinyl stearate, vinyl benzoate, vinyl pivalate, vinyl versatate, and the like. Among these, vinyl acetate is preferable.

  The degree of polymerization of PVA constituting the PVA film is preferably in the range of 500 to 9000, more preferably in the range of 1500 to 7000, more preferably in the range of 1800 to 5000, depending on the use of the PVA film. More preferably, it is in the range, and particularly preferably in the range of 2000 to 3000. In addition, the polymerization degree of PVA as used in this specification means the average polymerization degree measured according to description of JISK6726-1994.

  Moreover, although the saponification degree of PVA which comprises a PVA film is based also on the use of a PVA film, it is preferable that it is 75 mol% or more, it is more preferable that it is 85 mol% or more, and it is 95 mol% or more. More preferably, it is 99 mol% or more. In this specification, the degree of saponification of PVA refers to the total number of moles of structural units (typically vinyl ester units) that can be converted into vinyl alcohol units by saponification and the vinyl alcohol units of PVA. The proportion (mol%) occupied by the number of moles of vinyl alcohol units. The degree of saponification can be measured according to the description of JIS K6726-1994.

  You may make a PVA film contain a plasticizer, surfactant, dichroic dye, etc. as needed. There is no restriction | limiting in particular in the manufacturing method of a PVA film, The PVA film formed by well-known methods, such as a solution film forming method and a melt film forming method, can be used preferably.

  The thickness of the PVA film is not particularly limited, but is preferably in the range of 5 to 500 μm, more preferably in the range of 15 to 300 μm, and still more preferably in the range of 20 to 100 μm.

The width of the PVA film is not particularly limited, but is preferably 2.1 m or more, more preferably 2.3 m or more, further preferably 2.6 m or more, and particularly preferably 3 m or more. Most preferably, it is 3.3 m or more. When a PVA film having such a width is used, the length of the cylindrical core is further longer than the width of the PVA film, and a large amount of water derived from condensation is likely to be generated. Since it is difficult for water derived from condensation to enter the inside of the package, the effect of the present invention is more remarkably exhibited when a PVA film having the above-described width is used. Moreover, when the film width is less than 2.1 m, the ratio of the width of the trim to the film width increases during the secondary processing of the PVA film, which may lead to a decrease in productivity. Here, the trim refers to a portion that cannot be used as a product, in which both ends of the PVA film are cut by a certain width during processing.
On the other hand, if the width of the PVA film is too wide, the handleability may be lowered. Therefore, the width of the PVA film is preferably 8 m or less.

  The length of the PVA film wound around the cylindrical core is not particularly limited, but is preferably 1000 m or more, more preferably 2000 m or more, and further preferably 3000 m or more. If it is less than 1000 m, it may not be economical because the ratio of the loss generated at the beginning / end of winding of the roll to the whole becomes large. On the other hand, the upper limit of the length of the PVA film is not particularly limited, but if it is too long, the mass and diameter of the roll become excessive, and the handling thereof tends to be difficult when loading and unloading and moving to a gantry or processing apparatus. Therefore, the length of the PVA film is preferably 10,000 m or less.

  The mass of the roll used in the present invention is preferably 0.5 t or more, more preferably 1.5 t or more, and further preferably 2.5 t or more. In the present invention, even if the roll has a larger mass and condensation is likely to occur, it is difficult for water derived from condensation to enter the inside of the package. Therefore, when the roll as described above is used, the effect of the present invention is more remarkably exhibited. However, if the mass of the roll is too large, the handleability and the like may be deteriorated. Therefore, the mass of the roll is preferably 5 t or less.

  The package of the present invention is obtained by packaging the above roll with a packaging material. The type of the packaging material is not particularly limited. For example, a laminated film in which aluminum is vapor-deposited on polyethylene terephthalate, a laminated film of polyester and aluminum foil and polyethylene, a laminated film of aluminum-deposited polyester and polyethylene, an alumina-deposited polyester and polyethylene Examples include laminated films, laminated films of glass-deposited polyester and polyethylene, laminated films of polyvinylidene chloride-coated polypropylene and polyethylene, polypropylene films, high-density polyethylene films, and low-density polyethylene films. These packaging materials may be used individually by 1 type, or may use 2 or more types together, However, It is preferable to use together 2 or more types of packaging materials which have a different function. As an aspect in the case of using 2 or more types together, the aspect which wraps a roll with one packaging material, and is further packaged with another packaging material from it, for example is mentioned. In this case, as the packaging material that does not come into contact with the roll surface, a material having excellent mechanical strength is preferably used, and specifically, a high-density polyethylene film resistant to dirt and rubbing can be preferably used. The thickness of the packaging material that does not come into contact with the roll surface is preferably in the range of 20 to 60 μm from the viewpoint of handleability.

  On the other hand, as a packaging material in the case of using one kind of packaging material alone, or a packaging material in contact with the roll surface in the case of using two or more kinds of packaging materials, a laminated film in which aluminum is vapor-deposited on polyethylene terephthalate Polyester, aluminum foil and polyethylene laminated film, aluminum vapor deposited polyester and polyethylene laminated film, alumina vapor deposited polyester and polyethylene laminated film, and glass vapor deposited polyester and polyethylene laminated film are preferred because of their excellent moisture resistance. The thickness of the packaging material in contact with the roll surface is preferably in the range of 5 to 60 μm, and more preferably in the range of 10 to 20 μm, from the viewpoint of handleability and the like.

Packaging material, packaging material preferably in contact with the roll surface, since it is possible to prevent the influence of water on the PVA film more effectively, it is preferable that water vapor permeability of not more than the film 5g / m 2 / ^24h , more preferably a film of less ^3g / m 2 / 24h, further preferably less film 1.5g ^/ m 2 ^/ 24h. In addition, in this specification, water vapor permeability means water vapor permeability measured according to the infrared sensor method (40 ° C., 90% RH) described in JIS K7129: 2008.

  There is no particular limitation on the packaging method when packaging the roll with the packaging material. For example, after winding the sheet-like packaging material (for example, rectangular shape) that has not been three-dimensionally processed around the outer periphery of the roll, A method of squeezing the packaging material protruding outward in the length direction of the core, and then fixing the end of the squeezed packaging material on the outer peripheral surface of the protruding portion of the core; For example, a method of squeezing the packaging material protruding outward from the roll end surface in the length direction of the core and then fixing the end of the squeezed packaging material on the outer peripheral surface of the protruding portion of the core may be used. In these methods, after the squeezed packaging material is squeezed, the end of the squeezed packaging material is cut off, and the end of the newly generated wrapping material is fixed on the outer peripheral surface of the core projection. It is preferable because it is easy to fix the end of the packaging material at the desired position on the outer peripheral surface, but after squeezing the protruding packaging material, the end of the packaging material is squeezed as it is without cutting the end, and the outer periphery of the protruding portion of the core It may be fixed on the surface. When two or more types of packaging materials are used in combination, the protruding portion of the first type of packaging material is squeezed, and then the end of the squeezed first type of packaging material is fixed on the outer peripheral surface of the protruding portion of the core. The protruding part of the second type of packaging material may be squeezed, and then the end of the second type of packaging material that has been squeezed may be fixed on the outer peripheral surface of the protruding portion of the core, or multiple types of packaging material may protrude The portions may be squeezed together and then the end of the squeezed packaging material may be secured on the outer peripheral surface of the core protrusion.

Among the above wrapping methods, from the viewpoint of workability and the like, after wrapping the sheet-shaped packaging material along the outer periphery of the roll, the packaging material that protrudes outward in the length direction of the core from the roll end face is then squeezed, A method of fixing the end of the squeezed packaging material on the outer peripheral surface of the protruding portion of the core is preferable. In this case, the number of windings of each packaging material is not particularly limited, and may be either single winding or multiple winding such as double winding. Even if it is damaged, its influence can be reduced, which is preferable. In addition, after winding the sheet-shaped packaging material along the outer periphery, the end substantially parallel to the length direction of the core is fixed using an adhesive tape such as a plastic tape, a cloth tape, a paper tape, or an adhesive, It is preferable that the packaging material is made cylindrical as a whole because water can be more effectively prevented from entering the inside of the package.

  In FIG. 2, the schematic of an example of the packaging method at the time of packaging a roll with a sheet-like packaging material is shown. In the example of FIG. 2, first, as shown in (1) to (2) of FIG. 2, the sheet-shaped packaging material 11 is wound along the outer periphery of the roll, and the end portion is substantially parallel to the length direction of the core. 14 is fixed with an adhesive tape or an adhesive (not shown) to form a cylinder. Next, as shown in FIGS. 2 (2) to (3), the portion 15 protruding outward in the length direction of the core from the roll end surface 12 of the packaging material is squeezed, and the packaging material is projected at both ends of the core. The end of the packaging material 11 is fixed on the outer peripheral surface of the protrusion 13 as described later. In addition, if the slack portion when the packaging material 11 is squeezed is bent and the end thereof is also fixed on the outer peripheral surface of the protruding portion, it is possible to more effectively prevent water from entering the inside of the packaging body. ,preferable.

When packaging a roll with a packaging material, it is preferable to place a washer inside the package and at a position adjacent to the end face of the roll in order to protect the PVA film from scratches and impacts. As said washer, a polystyrene washer, a urethane washer, etc. can be used, for example.
In addition, a washer should be placed outside the package and adjacent to the roll end surface so that the packaging material near the roll end surface is not damaged when the package is loaded on a transportation stand. Is preferred. As the washer, for example, a wooden washer or a cardboard washer can be used.

  In the packaging body according to the present invention, the inner peripheral surface of the cylindrical core is exposed to the outside air. It is preferable that the support rod can be inserted into the core and can be handled, and since the support rod can be penetrated into the core, it is more preferable that the package has penetrated in the length direction of the cylindrical core. The inner peripheral surface of the cylindrical core may not be exposed to the outside air.

In the present invention, it is important that at least a part of the end of the packaging material is fixed on the outer peripheral surface of the protruding portion. Like the method of fixing with a rubber band for packaging described in Patent Document 3, when the end of the packaging material is a free end without being fixed, water stays near the end of the packaging material for a long time, Capillary phenomenon easily penetrates into the package from between the packaging material and the protrusion. In the present invention, when the edge of the packaging material is fixed on the outer peripheral surface of the protruding portion, water derived from condensation generated on the inner peripheral surface of the core has moved to the outer peripheral surface of the protruding portion. However, it can flow away without staying in the vicinity of the end of the packaging material for a long time, so that it can quickly leave the packaging body, and water can be effectively prevented from entering the packaging body.
The end of the packaging material fixed on the outer peripheral surface of the protruding portion (hereinafter sometimes referred to as “fixed end on the outer peripheral surface”) may be fixed in direct contact with the outer peripheral surface of the protruding portion. It may be fixed without contact. Examples of aspects that are fixed without direct contact include, for example, an aspect that is fixed via an adhesive that will be described later, and a case where the end of the slack portion of the packaging material is fixed on the outer peripheral surface of the protruding portion. Thus, the aspect etc. which are being fixed via the packaging material are mentioned.

  Even if the fixed end on the outer peripheral surface exists only in a part of the outer periphery of the protruding portion, the inner peripheral surface of the core is arranged by arranging the package with the fixed end on the outer peripheral surface facing downward. It can suppress that the water derived from the dew condensation which generate | occur | produced in this penetrate | invades in the inside of a package. However, in each of both protrusions, if the fixed end on the outer peripheral surface is fixed so as to circulate substantially continuously around the outer periphery of each protrusion, there is no need to consider the orientation of the package, It is preferable because water can be effectively prevented from entering the inside of the package. Here, “around substantially continuously” means that the outer periphery is substantially continuously rotated. For example, in the slack portion of the packaging material, the portion where the fixed end on the outer peripheral surface is not continuous is slightly. May be present. In the outer periphery of the protruding portion where the fixed end on the outer peripheral surface circulates substantially continuously, the length along the outer periphery of the portion where the fixed end on the outer peripheral surface does not exist with respect to the length of the outer periphery (when there are multiple locations) Is preferably 10% or less, more preferably 5% or less, still more preferably 1% or less, and particularly preferably 0%.

  There is no particular limitation on the manner of fixing the fixed end on the outer peripheral surface on the outer peripheral surface of the protrusion, for example, an embodiment in which it is fixed with an adhesive tape; an embodiment in which it is fixed with an adhesive; Aspect that is fixed by a fastening member such as a rubber band; In the case of using a core that is tapered so that the diameter of the end is smaller than the diameter other than the end, between the tapered part and the washer The fixed end on the outer peripheral surface is sandwiched between the outer peripheral surface and the like, and since the penetration of water into the inside of the package is more effectively prevented, the aspect and / or the adhesive fixed by the adhesive tape. The aspect fixed by is preferable, and the aspect fixed with the adhesive tape from a viewpoint of operativity or economical efficiency is more preferable. As a specific example of the aspect fixed by the adhesive tape, for example, the adhesive tape protrudes so that the adhesive surface of the adhesive tape is in contact with both the packaging material and the outer peripheral surface of the protrusion in each of the protruding portions. The aspect currently wound along the outer periphery of a part is mentioned. In this case, it is preferable that the adhesive tape is wound one or more times along the outer periphery of the protruding portion.

As said adhesive tape, what is rich in a softness | flexibility and a stretching property, and the thing which sticks the edge vicinity of a packaging material on the outer peripheral surface of a protrusion part and fixes it is preferable. Adhesive tapes include paper adhesive tapes, cloth adhesive tapes, film adhesive tapes, special adhesive tapes, etc. Specifically, cellophane tape, craft adhesive tape, cloth adhesive tape, OPP adhesive tape, aluminum Examples thereof include a tape, a vinyl tape, a polyester tape, a polyethylene tape, a polypropylene tape, a polyimide tape, a gum tape, or a composite tape processed by combining two or more of these. Among these, an adhesive tape having a multilayer structure of polyethylene and polypropylene is particularly preferable because it is excellent in waterproofness and durability. Moreover, an adhesive tape may be used individually by 1 type, or may use 2 or more types together.
Although there is no restriction | limiting in particular in the width | variety of an adhesive tape, From viewpoints, such as handleability, it is preferable to exist in the range of 2-15 cm, and it is more preferable to exist in the range of 5-10 cm.

  According to the packaging body of the present invention, in each of the two projecting portions, the projecting portion is fixed by the fastening member, and at least a part of the end is fixed on the outer peripheral surface of the projecting portion. It is preferable that it is tightened along. By tightening with the fastening member, the end of the packaging material is more firmly fixed on the outer peripheral surface, and even if water enters from between the end of the packaging material and the outer peripheral surface of the protruding portion, it contacts the roll Can be suppressed. In addition, before fixing the end of the packaging material on the outer peripheral surface of the protruding portion, and further before cutting the end of the squeezed packaging material, if fastening with a fastening member is performed in advance, the operation of fixing and cutting these Becomes easier. In each protrusion, only one fastening member may be used, or two or more fastening members may be used.

  There is no restriction | limiting in particular in the kind of said fastening member, What is called a binding tool can be used, For example, a metal or plastic binding band and an elastic band are mentioned. Of these, a ring-shaped elastic band is preferable from the viewpoint of workability.

There are no particular restrictions on the material of the elastic band, and examples thereof include those showing the properties of rubber, and specific examples include natural rubber, silicone rubber, acrylonitrile butadiene rubber, and the like. The inner diameter of the elastic band is not particularly limited, but the inner diameter when tightened is preferably 1.5 times or more compared with the inner diameter when normal (when not tightened) (inner diameter when circular). 2.0 times or more, more preferably 2.5 times or more. If the inner diameter when tightened is less than 1.5 times the normal inner diameter, the tightening force tends to be weakened. On the other hand, if the inner diameter when tightening exceeds 95% of the stretchable limit diameter of the elastic band, the tightening force tends to be uneven or break due to slight impact. Is preferably 95% or less of the stretch limit diameter of the elastic band.
The thickness of the elastic band is not particularly limited, but is preferably in the range of 0.5 to 3 mm, more preferably in the range of 0.7 to 2 mm, and in the range of 1 to 1.5 mm. More preferably. When the thickness is less than 0.5 mm, there is a tendency to break due to a slight impact at the time of extension, and when the thickness exceeds 3 mm, the economy tends to deteriorate.
Although the width | variety of an elastic band is not specifically limited, It is preferable to exist in the range of 10-30 mm, and it is more preferable to exist in the range of 15-20 mm. When the width is less than 10 mm, there is a tendency to break due to a slight impact at the time of extension, and when the width exceeds 30 mm, the economy tends to deteriorate.

  FIG. 3 is a schematic view showing an example of a cross section in the vicinity of the protruding portion of the packaging body in which the end of the packaging material is fixed on the outer peripheral surface of the protruding portion by an adhesive tape. In FIG. 3, the ends of the packaging materials 25 a and 25 b that are double-rolled on the outer peripheral surface 22 of the protruding portion of the cylindrical core 21 are fixed by an adhesive tape 26. In FIG. 3, the ends of the slack portions (25'a and 25'b) when the packaging material is squeezed are also fixed on the outer peripheral surface 22 of the protruding portion by the same adhesive tape 26. The adhesive surface 27 of the adhesive tape 26 is in contact with both the packaging material (25b and 25′b) and the outer peripheral surface 22 of the protruding portion of the cylindrical core 21, and on the outer periphery of the protruding portion of the cylindrical core 21. It is wound around. The adhesive tape 26 can be multiplex-wound. In FIG. 3, the adhesive tape 26 has a double-winding portion in which an adhesive tape (first) 26a and an adhesive tape (double) 26b overlap. Further, in FIG. 3, the projecting portion of the cylindrical core 21 is tightened along the outer periphery of the projecting portion by the fastening member 28 via the packaging materials 25a and 25b whose ends are fixed on the outer peripheral surface of the projecting portion. It has been. In FIG. 3, a urethane washer 29 is disposed at a position inside the package and adjacent to the roll end surface, and a cardboard washer 30 is disposed at a position outside the package and adjacent to the roll end surface. . FIG. 3 is an example of a package using one packaging material alone, but two or more types of packaging materials may be used in combination as described above.

Although there is no restriction | limiting in particular in the storage conditions at the time of storing the package of this invention, As storage temperature, it is preferable that it is in the range of -20-50 degreeC, and it is in the range of -10-40 degreeC. More preferably, it is further in the range of −5 to 30 ° C. In addition, even if the package of the present invention is stored at a low temperature of 10 ° C. or less (for example, 5 ° C. or less, or even 0 ° C. or less), it occurs when the package is carried into a processing place after storage. The effect of the present invention is more remarkably exhibited when stored at such a low temperature because the water derived from the condensation that may occur does not easily enter the package.
The storage humidity is preferably 80% RH or less, and more preferably 50% RH or less.

  There is no restriction | limiting in particular also in the storage period at the time of storing a package, For example, it is preferable to exist in the range of 1 day-1 year, and it is more preferable that it is in the range of 2 days-6 months.

  The package of the present invention is preferably transported in a state where a support bar is placed inside the core. In the present invention, even if the inner peripheral surface of the core is exposed to the outside air so that the support rod can be put inside the core, water derived from condensation generated on the inner peripheral surface of the core Intrusion into the package can be suppressed.

  When the package is transported in a state where the support bar is placed inside the core, it is preferable to transport the package by lifting the support bar with a transport machine such as a hoist crane. Lifting the support bar makes it difficult for the core to bend due to the strength of the support bar, so that damage to the PVA film due to the core bend can be prevented, and handling is also improved.

EXAMPLES The present invention will be specifically described below with reference to examples and the like, but the present invention is not limited to these examples. In addition, each evaluation or measuring method of the dew condensation on the inner peripheral surface of the core, the appearance of the roll, and the amount of change in the average moisture content employed in the following examples and comparative examples is shown below.

Condensation on the inner peripheral surface of the core Condensation on the inner peripheral surface of the core was evaluated according to the following criteria.
○: No condensation (water droplets) is observed.
X: Condensation (water droplets) is observed.

Appearance of the roll The outer peripheral surface of the roll was evaluated according to the following criteria.
(Double-circle): A moisture absorption trace is not recognized.
○: Although there is a moisture absorption trace locally (less than half of the outer peripheral surface of the roll), there is no practical problem.
X: There is a moisture absorption trace in more than half of the outer peripheral surface of the roll.

A sample of 10 × 10 cm square (one layer) was continuously cut out in the width direction from the surface layer film of the roll whose average moisture content was to be measured. Each of the obtained samples was left to dry in a dryer at 125 ° C. for 8 hours, and the moisture difference of each sample was calculated by dividing the mass difference before and after drying by the mass of the sample before drying. Next, the moisture content of the obtained sample was averaged to obtain the average moisture content of the roll. The same operation as described above was performed in advance for the roll before packaging, and the amount of change in the average moisture content was determined by subtracting the average moisture content of the roll before packaging from the average moisture content of the roll to be measured.

[Example 1]
A PVA film having a film width of 2.8 m, a thickness of 75 μm, and a length of 4000 m (PVA polymerization degree 2400, PVA saponification degree 99.9 mol%) made of aluminum, length 3.1 m, outer diameter 153 mm, wall thickness A roll was wound around the center of a 7 mm cylindrical core. The mass of this roll was 1.2 t.

Then, the laminated film obtained by depositing aluminum on a polyethylene terephthalate (thickness 12 [mu] m, water vapor permeability 1.5g / m 2 / ^24h. Hereinafter sometimes abbreviated as "deposition film".) Passed along the outer periphery of the roll two Heavy winding was performed, and the end portion substantially parallel to the length direction of the core was fixed with a paper tape to form a cylinder. Further, a high-density polyethylene film (thickness 20 μm) was double-rolled along the outer periphery of the roll from above, and the end substantially parallel to the length direction of the core was fixed with a paper tape to form a cylinder. Next, a set of urethane washers are arranged so as to be adjacent to each roll end face, and then the vapor-deposited film and the high-density polyethylene film protruding outward from the both roll end faces in the length direction of the core are collectively squeezed. The end of the slack portion is bent along the outer periphery of each protruding portion, and each protruding portion of the core is further bent by a ring-shaped rubber band (ordinary inner diameter 76 mm, thickness 1.1 mm, width 18 mm). It clamped along the outer periphery of a protrusion part via a density polyethylene film. Thereafter, the ends of the vapor-deposited film and the high-density polyethylene film including the end of the slack portion are fixed on the outer peripheral surface of each protruding portion with an adhesive tape (adhesive tape having a multilayer structure of polyethylene and polypropylene; width 5 cm), and PVA The film was sealed. At this time, the adhesive tape was wound along the outer periphery of each protrusion so that the adhesive surface of the adhesive tape was in contact with both the high-density polyethylene film and the outer peripheral surface of the protrusion. Furthermore, a set of corrugated cardboard washers was disposed from the top of the high-density polyethylene film at a position adjacent to each roll end face to obtain a package.

The package obtained as described above was stored in an atmosphere of −5 ° C. and 10% RH for 3 days, then moved to an atmosphere of 20 ° C. and 40% RH, left for 3 hours, and then subjected to the above method. The condensation on the inner peripheral surface of the core was evaluated.
Next, assuming that a large amount of dew condensation occurred, 100 ml of water was allowed to flow inside the cylindrical core, and shaking was assumed assuming shaking during transportation. And after wiping off the water in the vicinity of the end of the core so that the water does not contact the PVA film at the time of opening, the package is opened, and the appearance evaluation of the roll and the change in the average moisture content are measured by the above method. It was. The results are shown in Table 1.

[Example 2]
In Example 1, a package was obtained in the same manner as in Example 1 except that tightening with a rubber band was not performed.
About this packaging body, it carried out similarly to Example 1, and performed each evaluation or measurement of the dew condensation in the internal peripheral surface of a core, the external appearance of a roll, and the variation | change_quantity of an average moisture content. The results are shown in Table 1.

[Comparative Example 1]
In Example 1, a package was obtained in the same manner as in Example 1 except that the end of the packaging material was not fixed with an adhesive tape.
About this packaging body, it carried out similarly to Example 1, and performed each evaluation or measurement of the dew condensation in the internal peripheral surface of a core, the external appearance of a roll, and the variation | change_quantity of an average moisture content. The results are shown in Table 1.

[Comparative Example 2]
Example 1 is the same as Example 1 except that the packaging material remaining in the width direction is pushed into the core without fixing the end of the packaging material with an adhesive tape or tightening with a rubber band. Thus, a package was obtained.
About this packaging body, it carried out similarly to Example 1, and performed each evaluation or measurement of the dew condensation in the internal peripheral surface of a core, the external appearance of a roll, and the variation | change_quantity of an average moisture content. The results are shown in Table 1.

  According to the present invention, even when condensation occurs on the surface of the packaging body, such as the inner peripheral surface of the cylindrical core, condensation occurs because water derived from condensation does not easily enter the interior of the packaging body. The quality of the PVA film can be maintained even in an easy environment, for example, in transportation conditions such as aircraft and ships where temperature changes drastically, or in a use environment after storage in a warehouse exposed to low temperatures.

DESCRIPTION OF SYMBOLS 1 Roll 2, 21 Cylindrical core 3, 24 PVA film 4 End part of core 5, 12 Roll end surface 6, 13 Protruding part 7, 22 Outer peripheral surface 8, 23 Protruding part inner peripheral surface 11 Sheet-like Packaging material 14 End portion substantially parallel to the length direction of the core 15 Extruded portion 25a Packaging material (first layer)
25b Packaging material (double eye)
25'a Loose part of packaging material (single) 25'b Loose part of packaging material (double) 26 Adhesive tape 26a Adhesive tape (single)
26b Adhesive tape (double eye)
27 Adhesive surface of adhesive tape 28 Tightening member 29 Urethane washer 30 Cardboard washer

That is, the present invention
[1] A method for storing a package, in which a roll in which a PVA film is wound around a cylindrical core is packaged with a packaging material ;
The width of the PVA film is 2.1 m or more,
The material of at least a part of the surface of the core is metal and / or plastic,
The roll has a mass of 0.5 t or more,
Both end portions of the core form a protruding portion that protrudes from a roll end surface, and at least a part of the end of the packaging material is fixed on the outer peripheral surface of the protruding portion ,
In each of the two protruding portions, the adhesive tape is wound along the outer periphery of the protruding portion so that the adhesive surface of the adhesive tape is in contact with both the packaging material and the outer peripheral surface of the protruding portion,
In each of the two protruding portions, the protruding portion is tightened along the outer periphery of the protruding portion by the tightening member via the packaging material in which at least a part of the end is fixed on the outer peripheral surface of the protruding portion. ,And
A method for storing a package, the package having an inner peripheral surface of the core exposed to the outside air, stored at 10 ° C. or lower ;
[2] The storage method according to the above [1] , wherein the end of the packaging material fixed on the outer peripheral surface of the projecting part substantially circulates the outer periphery of the projecting part in each of the projecting parts.
[3] The method storage of the packaging material is less of a film water vapor permeability of ^{5 g} / m 2 / 24h, the above-mentioned [1] or [2],
[4] A method for transporting a package, in which the package is transported in a state where a support rod is placed inside the core of the package stored by any one of the above storage methods [1] to [3] .
About.

[ Comparative Example 3 ]
In Example 1, a package was obtained in the same manner as in Example 1 except that tightening with a rubber band was not performed.
About this packaging body, it carried out similarly to Example 1, and performed each evaluation or measurement of the dew condensation in the internal peripheral surface of a core, the external appearance of a roll, and the variation | change_quantity of an average moisture content. The results are shown in Table 1.

Claims (11)

  A packaging body in which a roll obtained by winding a polyvinyl alcohol polymer film on a cylindrical core is wrapped with a packaging material, and both end portions of the core form protrusions protruding from the roll end surface The packaging body in which at least a part of the end of the packaging material is fixed on the outer peripheral surface of the protruding portion.   The packaging body according to claim 1, wherein a material of at least a part of the surface of the core is metal and / or plastic.   The package according to claim 1 or 2, wherein an inner peripheral surface of the core is exposed to outside air in the package.   The package of any one of Claims 1-3 whose width | variety of the said polyvinyl alcohol-type polymer film is 2.1 m or more.   The package of any one of Claims 1-4 whose mass of the said roll is 0.5 t or more.   In each of both said protrusion parts, the edge of the said packaging material fixed on the outer peripheral surface of a protrusion part is carrying out the circumference | surroundings of the protrusion part substantially continuously in any one of Claims 1-5. The package described.   In each of both said protrusion parts, the adhesive tape is wound along the outer periphery of a protrusion part so that the adhesive surface of an adhesive tape may contact both the packaging material and the outer peripheral surface of a protrusion part. The package according to any one of the above.   In each of the two protruding portions, the protruding portion is clamped along the outer periphery of the protruding portion by the fastening member via the packaging material in which at least a part of the end is fixed on the outer peripheral surface of the protruding portion. The package according to any one of claims 1 to 7. It said packaging material is a less film water vapor permeability of ^5g / m 2 / 24h, packaging according to any one of claims 1-8.   The storage method of a package body which stores the package body of any one of Claims 1-9 at 10 degrees C or less. The transport method of a package body which transports a package body in the state which put the support rod inside the said core of the package body of any one of Claims 1-9.

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