JP2010163189A - High polymer film rolled packaging member - Google Patents

High polymer film rolled packaging member Download PDF

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Publication number
JP2010163189A
JP2010163189A JP2009007117A JP2009007117A JP2010163189A JP 2010163189 A JP2010163189 A JP 2010163189A JP 2009007117 A JP2009007117 A JP 2009007117A JP 2009007117 A JP2009007117 A JP 2009007117A JP 2010163189 A JP2010163189 A JP 2010163189A
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film
moisture
high polymer
polymer film
packaging member
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JP2009007117A
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Japanese (ja)
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Toshiaki Iwata
俊明 岩田
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Mitsubishi Plastics Inc
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Mitsubishi Plastics Inc
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Priority to JP2009007117A priority Critical patent/JP2010163189A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a high polymer film rolled packaging member in which an end part of the roll having a film composed of high polymer of high moisture absorbing characteristic such as polyester or polyamide is prevented from absorbing moisture in atmosphere and being bulged out and the trouble of frill-like looseness generated due to a more elongation of the end part of the film as compared with that of its central part is improved. <P>SOLUTION: There is provided a high polymer film rolled packaging member, wherein the high polymer film roll wound on a paper mandrel with a water content being less than 0.5 wt.% is packaged with a moisture-releasing film. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、ポリエステルやポリアミドなどのように吸湿性の高い高分子からなるフィルムを巻き芯に巻き付けてロール形態としたものの梱包体に関するものである。   The present invention relates to a package in which a film made of a highly hygroscopic polymer such as polyester or polyamide is wound around a winding core to form a roll.

ポリエステルやポリアミドなど比較的吸湿性の高い高分子からなるフィルムをロール形態に巻き上げた際、端部が雰囲気中の水分を吸収し膨張するため、水分を吸収していない中央部に比べ長くなるためフリル状に弛むトラブルを生じることがある。このため、アルミニウム箔あるいはアルミニウム蒸着層を有する防湿フィルムをフィルムロールに巻き付けて、湿気の侵入を防ぐ方法が一般に採られているが、近年、フィルムの弛みがないことが強く要求されるようになり、防湿フィルムで包み込まれた内部の空間の水分によるフィルムの弛みレベルをも問題にされるようになってきている
そこで、吸湿剤を防湿フィルムの内側に備え、フィルム内部の水分を除去し弛みを改良する方法が提案されているが、光学用途、電子部材用途のように極端に異物を嫌う用途においては、これら吸湿剤が異物の原因となる可能性があるため、多量の吸湿剤を適用することができず、十分な効果を発揮し得なかった。
When a film made of a relatively hygroscopic polymer such as polyester or polyamide is rolled up into a roll, the end part absorbs moisture in the atmosphere and expands, making it longer than the central part that does not absorb moisture May cause troubles that fluffy. For this reason, a method of preventing moisture intrusion by winding a moisture-proof film having an aluminum foil or an aluminum vapor deposition layer around a film roll is generally adopted, but in recent years, there has been a strong demand for the film not to be loose. Therefore, the level of looseness of the film due to moisture in the space enclosed by the moisture-proof film is also becoming a problem. Therefore, a moisture absorbent is provided on the inside of the moisture-proof film to remove moisture inside the film. Although a method for improving it has been proposed, in applications where the use of foreign substances is extremely hated, such as optical applications and electronic parts, these hygroscopic agents may cause foreign substances, so a large amount of hygroscopic agent is applied. It was not possible to achieve a sufficient effect.

フィルムをロール状に形態した後、加工前に乾燥工程を設けてフィルム内部の水分を除去する方法も提案されているが、乾燥工程を要する分、製造コストが高くなるという門外がある。   There has also been proposed a method in which a film is formed into a roll and then provided with a drying step before processing to remove moisture inside the film.

特開昭53−109806号公報JP-A-53-109806

本発明は、上記実情に鑑みなされたものであり、その解決課題は、異物の要因となる吸湿剤を使用せず、また事前のフィルム乾燥を経ることなく、ポリエステルやポリアミドなどのように吸湿性の高い高分子からなるフィルムを巻き上げたロールの端部が雰囲気中の水分を吸収して膨張することを防止し、フィルムの端部が中央部に比べ長くなるために発生するフリル状の弛みトラブルを改良した高分子フィルムロール梱包体を提供することにある。   The present invention has been made in view of the above circumstances, and its solution is to use a hygroscopic material such as polyester or polyamide without using a hygroscopic agent that causes foreign matter and without prior film drying. The frill-like slack trouble that occurs because the end of the roll wound with a film made of a high polymer film absorbs moisture in the atmosphere and prevents it from expanding, and the end of the film is longer than the center. It is providing the polymer film roll package which improved this.

本発明者は、上記課題に鑑み鋭意検討した結果、特定の構成を採用することによれば、上記課題を容易に解決できることを見いだし、本発明を完成するに至った。   As a result of intensive studies in view of the above problems, the present inventor has found that the above problems can be easily solved by adopting a specific configuration, and the present invention has been completed.

すなわち、本発明の要旨は、含水率が0.5重量%以下である紙製の巻芯に巻き上げられた高分子フィルムロールを、放湿性のフィルムで包装してなることを特徴とする高分子フィルムロール梱包体に存する。   That is, the gist of the present invention is a polymer comprising a polymer film roll wound up on a paper core having a moisture content of 0.5% by weight or less and wrapped with a moisture-releasing film. It exists in a film roll package.

以下、本発明を詳細に説明する。
本発明に使用するフィルムロールの巻き芯には、乾燥された紙製の管を巻芯として使用する。巻芯の含水率は、0.5重量%以下であり、好ましくは0.4重量%以下、さらに好ましくは0.3重量%以下である。巻芯の含水率が0.5重量%を超えると、フィルムに発生するフリル状の弛みを防止することができない。
Hereinafter, the present invention will be described in detail.
For the core of the film roll used in the present invention, a dried paper tube is used as the core. The moisture content of the core is 0.5% by weight or less, preferably 0.4% by weight or less, and more preferably 0.3% by weight or less. If the moisture content of the core exceeds 0.5% by weight, the frill-like slack that occurs in the film cannot be prevented.

紙管は、異物の原因ともなりうる毛羽立ちの少ない、防塵処理紙管を使用することが望ましい。   As the paper tube, it is desirable to use a dust-proof treated paper tube with less fuzz that may cause foreign matters.

本発明では、紙管が一種の吸湿剤として機能するため、想定される防湿フィルム内部の空気量に対して、紙管の含水容量について留意する必要があるが、紙管の密度等によっても代わるため適宜選択する。なお、巻き芯の内径と巻き芯の長さは必ずしも自由に選択できないため、紙管体積を増やして含水容量を増す必要がある時には、紙管の肉厚を増やすことで必要な含水容量を確保することが推奨される。   In the present invention, since the paper tube functions as a kind of hygroscopic agent, it is necessary to pay attention to the moisture content of the paper tube with respect to the assumed amount of air inside the moisture-proof film. Therefore, it chooses suitably. Note that the inner diameter of the core and the length of the core cannot always be freely selected, so when it is necessary to increase the water content by increasing the paper tube volume, the necessary water content can be secured by increasing the thickness of the paper tube. It is recommended to do.

紙管の乾燥方法は、特に限定されないが、例えば、乾燥熱風で熱処理する方法やクーラーや吸湿剤等で乾燥雰囲気に制御された保管スペースで数日〜数ヶ月保管する方法など、が挙げられる。   The method for drying the paper tube is not particularly limited, and examples thereof include a method of heat-treating with dry hot air and a method of storing for several days to several months in a storage space controlled in a dry atmosphere with a cooler, a hygroscopic agent, or the like.

本発明でいう、防湿性のフィルムとは、アルミニウム箔をラミネートしたものや、アルミニウム蒸着が施されたポリエチレンフィルムなど、透湿の極めて少ないフィルムを指す。   The moisture-proof film referred to in the present invention refers to a film having extremely low moisture permeability, such as a laminate of aluminum foil and a polyethylene film on which aluminum is deposited.

本発明によれば、異物の要因となる吸湿剤を使用することなく、また事前のフィルム乾燥を経なくても、フィルム中の水分に起因するフィルムのフリルを回避することができ、本発明の工業的価値は高い。   According to the present invention, the frills of the film due to moisture in the film can be avoided without using a hygroscopic agent that causes foreign matter and without undergoing prior film drying. Industrial value is high.

以下、本発明を実施例により詳細に説明するが、本発明は、以下の例に限定されるものではない。なお、本発明のおける測定方法・評価方法は、以下に示すとおりである。   EXAMPLES Hereinafter, although an Example demonstrates this invention in detail, this invention is not limited to the following examples. In addition, the measuring method and evaluation method in the present invention are as follows.

(1)紙管の含水率
株式会社ケツト製紙水分科学研究所計(PM−80)を用いて、紙管の含水量を測定する。
(1) Moisture content of paper tube The moisture content of the paper tube is measured using a Ketto Paper Moisture Science Laboratory meter (PM-80).

(2)端部弛み個数
梱包後のフィルムロール梱包体を、23℃50RH%の環境下で30日間保管後、最表層フィルムを3m巻き出して採取し、平坦な台上に広げて端部に発生したフリル状の凹凸の個数を数える。
(2) Number of slack edges The film roll package after packing is stored for 30 days in an environment of 23 ° C and 50RH%, then the outermost layer film is unwound and collected, spread on a flat table and spread on the edge. Count the number of frill-shaped irregularities that occurred.

(3)フィルムの含水率
フィルムの含水率測定は、カールフィッシャー水分計を用いて、フィルムを15mm幅のサイズに切り出し、重量が約1gになるように必要な長さだけ切り取る。切り取ったサンプルを小さく丸めてクリップで止め、測定を行う。
(3) Moisture content of the film The moisture content of the film is measured by using a Karl Fischer moisture meter, cutting the film into a 15 mm wide size, and cutting out the necessary length so that the weight is about 1 g. The cut sample is rounded down and stopped with a clip and measured.

実施例1:
紙管Gコア(肉厚15mm、内径6インチ、長さ1200m、含水分率7.8±1.5%)を、熱風オーブンも用いて、窒素気流下、110℃で1時間の乾燥を行い、窒素雰囲気のまま室温まで冷却した後、含水率0.3重量%の巻き芯を得た。この紙管に、厚さ188μmの二軸延伸ポリエステルフィルムであるダイアホイルT100−188(三菱樹脂社製 サイズ 1060mm×1200m)を、巻き上げてフィルムロールとした。なお、巻き上げ条件は、張力520N、速度150m/分とした。巻き上げ後、村角社製防湿フィルムアルミラミ紙(OPP/アルミニウムラミネートフィルム)で包み、さらにポリエチレンフィルムで包んで梱包した。
Example 1:
Paper tube G core (thickness 15 mm, inner diameter 6 inches, length 1200 m, moisture content 7.8 ± 1.5%) is dried for 1 hour at 110 ° C. in a nitrogen stream using a hot air oven. After cooling to room temperature in a nitrogen atmosphere, a winding core having a water content of 0.3% by weight was obtained. Diafoil T100-188 (Mitsubishi Resin Co., Ltd. size 1060 mm × 1200 m), which is a biaxially stretched polyester film having a thickness of 188 μm, was rolled up on this paper tube to form a film roll. The winding conditions were a tension of 520 N and a speed of 150 m / min. After winding up, it was wrapped in a moisture-proof film aluminum laminated paper (OPP / aluminum laminate film) manufactured by Murakaku Co., Ltd., and further wrapped in a polyethylene film and packed.

比較例1:
紙管を乾燥しないほかは実施例1と同様にして製品を得た。
Comparative Example 1:
A product was obtained in the same manner as in Example 1 except that the paper tube was not dried.

比較例2:
ポリエチレンフィルムを使用しないこと以外は、実施例1と同様にして製品を得た。
Comparative Example 2:
A product was obtained in the same manner as in Example 1 except that no polyethylene film was used.

以上、得られた結果をまとめて下記表1に示す。   The obtained results are summarized in Table 1 below.

Figure 2010163189
Figure 2010163189

本発明は、例えば、ポリエステルフィルムややポリアミドなどのように吸湿性の高い高分子からなるフィルムの梱包として好適に利用することができる。   The present invention can be suitably used as a package of a film made of a highly hygroscopic polymer such as a polyester film or polyamide.

Claims (1)

含水率が0.5重量%以下である紙製の巻芯に巻き上げられた高分子フィルムロールを、放湿性のフィルムで包装してなることを特徴とする高分子フィルムロール梱包体。 A polymer film roll package comprising a polymer film roll wound up on a paper core having a water content of 0.5% by weight or less and a moisture-releasing film.
JP2009007117A 2009-01-16 2009-01-16 High polymer film rolled packaging member Pending JP2010163189A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014019056A (en) * 2012-07-18 2014-02-03 Konica Minolta Inc Film roll package and method of manufacturing the same
JP2018035315A (en) * 2016-09-02 2018-03-08 三菱瓦斯化学株式会社 Industrial polyamide film storage method
JPWO2017164352A1 (en) * 2016-03-24 2019-01-31 味の素株式会社 Film roll package and manufacturing method thereof
JP2019177645A (en) * 2018-03-30 2019-10-17 東洋製罐グループホールディングス株式会社 Barrier film for electronic device

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014019056A (en) * 2012-07-18 2014-02-03 Konica Minolta Inc Film roll package and method of manufacturing the same
JPWO2017164352A1 (en) * 2016-03-24 2019-01-31 味の素株式会社 Film roll package and manufacturing method thereof
JP2018035315A (en) * 2016-09-02 2018-03-08 三菱瓦斯化学株式会社 Industrial polyamide film storage method
JP7211692B2 (en) 2016-09-02 2023-01-24 三菱瓦斯化学株式会社 How to store industrial polyamide film
JP2019177645A (en) * 2018-03-30 2019-10-17 東洋製罐グループホールディングス株式会社 Barrier film for electronic device
KR20200135468A (en) * 2018-03-30 2020-12-02 도요세이칸 그룹 홀딩스 가부시키가이샤 Barrier film for electronic devices
US11479018B2 (en) 2018-03-30 2022-10-25 Toyo Seikan Group Holdings, Ltd. Barrier film for electronic devices
KR102575857B1 (en) 2018-03-30 2023-09-07 도요세이칸 그룹 홀딩스 가부시키가이샤 Barrier film for electronic devices

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