JP2017066140A - Oil-in-water type emulsion cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an oil-in-water type emulsion cosmetic capable of suppressing stickiness and achieving a high SPF value while maintaining a fresh or spreadable sense of use.SOLUTION: An oil-in-water type emulsion cosmetic comprises a solid oil and/or a semisolid oil, a powder and an emulsifying agent, wherein the solid oil and/or the semisolid oil are one selected from a hydrocarbon oil, a silicone oil and an ester oil and have a viscosity of 1500 mPa s or less at 25°C, the blending amount is 2 to 25 mass% based on the total amount of the oil phase and the amount of the oil phase is 40 mass% or less based on the total mass of the cosmetic.SELECTED DRAWING: None

Description

  The present invention relates to an oil-in-water emulsified cosmetic.

  Sunscreen cosmetics are intended to cut the ultraviolet rays in the sun rays and protect the skin from the harmful effects of ultraviolet rays. Examples of the bases include emulsifying types, lotion types, oil types, etc. Are roughly classified into oil-in-water emulsified cosmetics with an aqueous component as an outer phase (continuous phase) and water-in-oil emulsified cosmetics with an oily component as an outer phase (continuous phase). Conventional sunscreen cosmetics are required to have a fresh feeling of use, and among oil-in-water emulsified cosmetics, oil-in-water emulsified cosmetics emulsified with a hydrophobized UV scattering agent suppress stickiness. Therefore, it is possible to realize a fresh feeling of use (for example, Patent Document 1).

  On the other hand, in order to block the ultraviolet irradiation to the skin and obtain a high SPF (Sun Protection Factor) value, it is necessary to add a high amount of a solid ultraviolet absorber or an ultraviolet scattering agent to the sunscreen cosmetic. In order to blend a solid ultraviolet absorber or ultraviolet scattering agent, it is necessary to blend a high amount of oil, but sticking cannot be suppressed if the amount of oil is high.

  In water-in-oil type emulsified cosmetics with different emulsification types, Patent Document 2 achieves a high SPF value without blending a UV scatterer by blending dextrin fatty acid ester and / or sucrose fatty acid ester with oil. In addition, it is described that oiliness and stickiness can be reduced.

JP 2014-101335 A JP 2011-126732 A

  It is necessary to reduce the oil content in order to achieve freshness and good elongation, but ester oil must be included as an essential component in order to dissolve the solid ultraviolet absorber and blend the ultraviolet scattering agent. However, when it does so, since the ratio of the ester oil in the total oil amount becomes high, stickiness peculiar to the ester oil will occur. Thus, in oil-in-water emulsified cosmetics, there is a trade-off between the freshness and good elongation required for the feeling of use and the realization of the high SPF value required as the original function of sunscreen cosmetics. Conventionally, a smooth feeling was given by adding a powder that improves usability to the aqueous phase, but there was a problem that scumming occurred when applied to the skin. In addition, in an emulsification system in which a hydrophobicized powder is blended in the internal phase (oil phase), the emulsification tends to be unstable. Therefore, a fatty acid ester as described in Patent Document 2 is added to the oil phase. When blended, the emulsified particles are destroyed, and it is difficult to obtain a sufficiently stable base.

  The present invention has been made in view of the above circumstances, and seeks oil-in-water emulsified cosmetics by blending a predetermined amount of solid oil and / or semi-solid oil and keeping the total amount of oil phase below a certain level. An object of the present invention is to provide an oil-in-water emulsified cosmetic that can suppress stickiness and can achieve a high SPF value while maintaining a feeling of use that is refreshing and stretchable.

The oil-in-water emulsified cosmetic of the present invention is an oil-in-water emulsified cosmetic containing solid oil and / or semi-solid oil, powder, and emulsifier,
The solid oil and / or semi-solid oil is at least one selected from hydrocarbon oil, silicone oil and ester oil, the viscosity at 25 ° C. is 1500 mPa · s or less, and the blending amount is based on the total amount of the oil phase. 2 to 25% by mass,
An oil phase is 40 mass% or less with respect to cosmetics whole quantity.

The solid oil and / or semi-solid oil is preferably a sucrose fatty acid ester.
The fatty acid of the sucrose fatty acid ester is preferably a linear or branched chain having 12 to 22 carbon atoms.

  The solid oil and / or semi-solid oil is preferably an alkylmethylsiloxane wax.

The emulsifier is preferably an amphiphilic polymer.
The emulsifier is preferably an alkyl-modified polysaccharide.
The emulsifier is preferably a hydrophobically modified alkyl cellulose.

It is preferable that the compounding quantity of solid oil and / or semi-solid oil is 0.5-5 mass% with respect to cosmetics whole quantity.
The ratio of the amount of emulsifier to the amount of solid oil and / or semi-solid oil is preferably 0.04 to 0.4.

It is preferable that the compounding quantity of a powder is 3-10 mass% with respect to cosmetics whole quantity.
The powder is preferably a hydrophobic powder.

A thickener is further included, and the thickener is preferably at least one selected from polyacrylamide compounds, anionic polymers, and polysaccharides.
The thickener is (dimethylacrylamide / acryloyldimethyltaurine sodium) crosspolymer, vinylpyrrolidone / 2-acrylamido-2-methylpropanesulfonic acid (salt) copolymer, sodium acrylate / 2-acrylamido-2-methylpropanesulfone. Acid (salt) copolymer, acrylamide / 2-acrylamido-2-methylpropanesulfonic acid sodium salt copolymer, acrylamide / 2-acrylamido-2-methylpropanesulfonic acid (salt), 2-acrylamido-2-methylpropane It is preferably at least one selected from a homopolymer of sodium sulfonate, dimethylacrylamide / 2-acrylamide-2-methylpropanesulfonic acid, carboxyvinyl polymer, and xanthan gum.

  The oil phase preferably contains an ultraviolet absorber.

  The oil-in-water emulsified cosmetic of the present invention is an oil-in-water emulsified cosmetic containing a solid oil and / or a semisolid oil, a powder, and an emulsifier, wherein the solid oil and / or the semisolid oil is a hydrocarbon. At least one selected from oil, silicone oil and ester oil, the viscosity at 25 ° C. is 1500 mPa · s or less, and the blending amount is 2 to 25% by mass with respect to the total amount of the oil phase. Since it is 40% by mass or less with respect to the total amount of the cosmetic, it is possible to suppress stickiness as a prescription that can realize a high SPF value while maintaining the freshness and good feeling of use required for an oil-in-water emulsified cosmetic. it can.

Hereinafter, the oil-in-water emulsified cosmetic of the present invention will be described in detail.
The oil-in-water emulsified cosmetic of the present invention is an oil-in-water emulsified cosmetic containing a solid oil and / or a semisolid oil, a powder, and an emulsifier, wherein the solid oil and / or the semisolid oil is a hydrocarbon. At least one selected from oil, silicone oil and ester oil, the viscosity at 25 ° C. is 1500 mPa · s or less, and the blending amount is 2 to 25% by mass with respect to the total amount of the oil phase. It is 40 mass% or less with respect to cosmetics whole quantity.
Hereinafter, each component will be described in detail.

<Solid oil and / or semi-solid oil>
The solid oil and / or semi-solid oil has a viscosity at 25 ° C. of 1500 mPa · s or less, more preferably 1000 mPa · s or less, and further preferably 500 mPa · s or less. Here, the viscosity is a value measured by a B-type viscometer at 25 ° C., and in detail, a VDA type viscometer (Shibaura System Co., Ltd., DIGITAL VISMETRON VDA), rotor No. 1, rotor no. 2 or rotor no. 3 is a value measured under conditions of 12 rpm and 1 minute.

Here, a solid oil means an oil that is solid at 25 ° C., and a semi-solid oil means an oil that is half solid at 25 ° C.
The melting point (mp) of the solid oil and / or semi-solid oil is preferably in the range of 44 ° C to 90 ° C. When the melting point is within this range, it is possible to provide a feeling of use that is not sticky after coating.

The solid oil and / or semi-solid oil of the present invention is at least one selected from hydrocarbon oil, silicone oil and ester oil.
Examples of the hydrocarbon oil include microcrystalline wax and synthetic hydrocarbon wax. From the viewpoint of usability and high SPF, microcrystalline wax can be preferably used.

As the silicone oil, alkylmethylsiloxane wax can be used.
As the ester oil, for example, hardened oil, sucrose fatty acid ester, myristyl myristate (Croda Japan Co., Ltd.) and the like can be preferably used. Examples of the hardened oil (a kind of processed oil and fat) include white solid fat obtained by adding hydrogen to fish oil, whale oil, rapeseed oil, soybean oil and the like. As a commercial item, "Triphat PS-45H" (Nikko Chemicals Co., Ltd.) etc. can be mentioned preferably, for example.
From the viewpoints of emulsion stability and versatility, sucrose fatty acid esters and alkylmethylsiloxane waxes are particularly preferred.

As the sucrose fatty acid ester, linear or branched, saturated or unsaturated, having 12 to 22 carbon atoms can be preferably used. Specifically, sucrose caprylate, sucrose caprate, sucrose laurate, sucrose myristic ester, sucrose palmitate, sucrose stearate, sucrose oleate, sucrose elca Acid ester etc. are illustrated and these can be used 1 type or in combination of 2 or more types. For example, “sugar wax A-10E” (sucrose mixed fatty acid ester), “cosmelike SA-10” (acetic acid stearic acid scroll), “cosmelike MX-10” (sucrose mixed fatty acid ester) Kogyo Seiyaku Co., Ltd.), "Crodesta 4-IS" (Claude Japan Co., Ltd.) (tetraisostearic acid sucrose) and other commercial products can be preferably used in the present invention.
These sucrose fatty acid esters can be used alone or in combination of two or more.

  Examples of the alkylmethylsiloxane wax include alkyl (C30-40) methicone C30-C45 olefin and alkyl (C30-45) dimethylsilylpolypropylsilsesquioxane. Specifically, “AMS-C30 COSMETIC WAX” “SW -8005 C30 Resin Wax "(Toray Dow Corning Co., Ltd.) and the like can be preferably used.

  The blending amount of the solid oil and / or semi-solid oil is 2 to 25% by mass, preferably 2 to 20% by mass, based on the total amount of the oil phase. The blending amount of the solid oil and / or the semi-solid oil is in the range of 2 to 25% by mass with respect to the total amount of the oil phase, so that the emulsion stability can be ensured, and the feeling of freshness and good elongation can be obtained. Stickiness can be suppressed as a prescription that can achieve a high SPF value while maintaining.

  The blending amount of the solid oil and / or semi-solid oil is preferably 0.5 to 5% by mass and more preferably 1 to 5% by mass with respect to the total amount of the cosmetic. A high SPF value can be realized while maintaining a feeling of freshness and good elongation by setting the blending amount of the solid oil and / or semi-solid oil in the range of 0.5 to 5% by mass with respect to the total amount of the cosmetic. Stickiness can be suppressed as a prescription.

<Powder>
The powder used in the present invention can be used as it is, but the surface of the inorganic powder particles is, for example, silicones such as methylhydrogenpolysiloxane and dimethylpolysiloxane, dextrin fatty acid ester, higher fatty acid, higher alcohol, fatty acid. Use hydrophobic powders obtained by hydrophobizing hydrocarbons such as esters, metal soaps, alkyl phosphate ethers, fluorine compounds, or squalane, paraffin, etc. by wet methods using solvents, gas phase methods, mechanochemical methods, etc. Is preferred.

  As the inorganic powder, those that can be usually blended in cosmetics and external preparations for skin can be used, such as titanium oxide, zinc oxide, talc, mica, sericite, kaolin, titanium mica, black iron oxide, yellow iron oxide, bengara, Ultramarine blue, bitumen, chromium oxide, chromium hydroxide, and the like. In the case of a sunscreen cosmetic, it is preferable to use an ultraviolet scattering agent such as fine particle titanium oxide or fine particle zinc oxide having an average primary particle size of less than 100 μm.

  The blending amount of the powder may be set according to the purpose, but in sunscreen cosmetics and the like, it may be blended at 1% by mass or more, typically 3% by mass or more with respect to the total amount of the oil-in-water emulsified cosmetic. preferable. The upper limit is not particularly limited. However, when the blending amount increases, the blending amount of the oil phase, which is a dispersion medium, inevitably increases, and the blending of other components is limited. It is preferable that the amount be 10% by mass or less, typically 10% by mass or less.

<Emulsifier>
As the emulsifier, a nonionic surfactant or an amphiphilic polymer can be used, and an amphiphilic polymer is more preferable. More preferred are alkyl-modified polysaccharides. When an amphiphilic polymer is used as the emulsifier, the molecular weight is preferably 100,000 or more. Furthermore, it is preferable to set it as 400000-600000. More specifically, an (acrylates / steareth-20 methacrylate) copolymer or a hydrophobically modified alkyl cellulose such as stearoxyhydroxypropyl cellulose may be used, or a commercially available product thereof may be used. For example, Sangelose 90L (display name: hydrophobized hydroxypropyl methylcellulose; manufactured by Daido Kasei Kogyo Co., Ltd.), Natrosol Plus 330cs (manufactured by Ashland), Polysurf 67cs (manufactured by Ashland), and the like. Particularly preferred is hydrophobically modified alkyl cellulose.

It is preferable that the compounding quantity of an emulsifier is 0.1-0.5 mass% with respect to cosmetics whole quantity. By setting the blending amount of the emulsifier in the range of 0.1 to 0.5% by mass with respect to the total amount of the cosmetic, a stable emulsion can be obtained and a light feel can be obtained at the time of application.
The ratio of the emulsifier blending amount [the emulsifier blending amount / (solid oil and / or semisolid oil blending amount)] to the blending amount of the solid oil and / or semisolid oil is 0.04 to 0.4. It is preferable. By making the ratio of the blending amount of the emulsifier with respect to the blending amount of the solid oil and / or semi-solid oil within this range, a fresher feel can be obtained.

<Thickener>
The oil-in-water emulsified cosmetic of the present invention preferably contains a thickener. The thickener is more preferably at least one selected from polyacrylamide compounds, anionic polymers and polysaccharides. Specifically, vinylpyrrolidone / 2-acrylamide-2-methylpropanesulfonic acid (salt) copolymer, dimethylacrylamide / 2-acrylamide-2-methylpropanesulfonic acid (salt) copolymer, acrylamide / 2-acrylamide 2-methylpropanesulfonic acid copolymer, (dimethylacrylamide / acryloyldimethyltaurine sodium) crosspolymer, dimethylacrylamide / 2-acrylamido-2-methylpropanesulfonic acid crosspolymer cross-linked with methylenebisacrylamide, polyacrylamide And sodium acrylate, sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer, hydroxyethyl acrylate / 2-acrylamido-2-methyl Polyacrylamide compounds such as lopansulfonic acid (salt) copolymers, anionic polymers such as ammonium polyacrylate, polyacrylamide / ammonium acrylate copolymers, acrylamide / sodium acrylate copolymers, polysaccharides such as xanthan gum Preferable examples can be given. However, it is not limited to these examples.
In the above, as the salt, an alkali metal salt (for example, calcium salt, magnesium salt, etc.), an ammonium salt, an organic amine salt (for example, monoethanolamine salt, diethanolamine salt, triethanolamine salt, etc.) is suitable. Can be mentioned. These thickeners can be used alone or in combination of two or more.

  A commercially available product can be suitably used as the thickener. For example, as (dimethylacrylamide / acryloyldimethyltaurine sodium) crosspolymer, “SU-GEL” (manufactured by Toho Chemical Co., Ltd.), vinylpyrrolidone / 2-acrylamido-2-methylpropanesulfonic acid (salt) copolymer, , “ARISTOFLEX AVC” (manufactured by Clariant), sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid (salt) copolymer, “SIMULGEL EG” (manufactured by SEPIC), “SIMULGEL EPG” (SEPIC) As the acrylamide / 2-acrylamido-2-methylpropanesulfonic acid sodium salt copolymer, “SIMULGEL 600” (manufactured by SEPIC), acrylamide / 2-acrylamido-2-methylprop As the sulfonic acid (salt), “SEPICEL 305” (manufactured by SEPIC), “SEPIGEL 501” (manufactured by SEPIC), and 2-acrylamide-2-methylpropanesulfonic acid sodium salt as a homopolymer, “Hostacerin AMPS” (Manufactured by Clariant), “SIMULGEL 800” (manufactured by SEPIC), and the like. As dimethylacrylamide / 2-acrylamido-2-methylpropanesulfonic acid, “SU-POLYMER G-1” (Toho Chemical Co., Ltd.) And the like).

  It is preferable that the compounding quantity of a thickener is 0.1-0.5 mass% with respect to cosmetics whole quantity. By setting the blending amount of the thickener in the range of 0.1 to 0.5% by mass with respect to the total amount of the cosmetic, a stable emulsion can be obtained, and a light feel can be obtained during application.

<Ultraviolet absorber>
The oil-in-water emulsified cosmetic of the present invention preferably contains an ultraviolet absorber. Although it does not specifically limit as an ultraviolet absorber, It is preferable to select from the ultraviolet absorber which is insoluble in water and hardly soluble in oil. Specifically, as the ultraviolet absorber, benzoic acid-based ultraviolet absorbers (for example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy) PABA ethyl ester, N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, etc.); anthranilic acid-based UV absorber (for example, homomenthyl-N-acetylanthranilate, etc.); salicylic acid-based UV absorber ( For example, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, etc .; cinnamic acid UV absorbers (for example, octylmethoxycinnamate) (Ethyl hexyl paramethoxycinnamate), ethyl-4-isopropylcinnamate, methyl-2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p- Methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate, Cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethylhexanoyl-diparamethoxycinnamate, etc. ); Benzophenone ultraviolet absorbers (for example, 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4) , 4′-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4′-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone 2-ethylhexyl-4′-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc.); 3- (4′-methylbenzylidene)- d, l-camphor, 3-benzylide 2-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2′-hydroxy-5-methylphenylbenzotriazole; 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole 2- (2′-hydroxy-5′-methylphenylbenzotriazole; dibenzalazine; dianisoylmethane; 4-methoxy-4′-tert-butyldibenzoylmethane; 5- (3,3-dimethyl-2-norbornylidene); Preferred are -3-pentan-2-one and dimorpholinopyridazinone.

Also, triazine derivatives, specifically 2,4-bis-{[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl)-(1,3,5 ) -Triazine (Tinosorb S), 2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] 1,3,5-triazine (ubinal T150) and the like are preferable.
Furthermore, preferred examples of the dibenzoylmethane derivative include 4-tert-butyl-4′-methoxydibenzoylmethane (for example, “Pulsol 1789”).

<Oil phase>
The oil phase can contain any component selected from hydrocarbon oils other than the above solid oil and / or semi-solid oil, silicone oil, ester oil, higher fatty acid, higher alcohol, etc. Unless it impairs, it will not specifically limit.
Examples of liquid oils include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, southern castor oil, castor oil, linseed oil , Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin and the like.

  Examples of the higher fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, toluic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid ( DHA) and the like.

  Examples of higher alcohols include linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol); branched chain alcohols (eg, monostearyl glycerin ether (batyl alcohol) ), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyl decanol, isostearyl alcohol, octyldodecanol and the like.

  As ester oil, you may mix | blend the ester oil whose viscosity in 25 degreeC is higher than 1500 mPa * s in the range which does not affect the effect of this invention.

  As a silicone oil, you may mix | blend the silicone oil whose viscosity in 25 degreeC is higher than 1500 mPa * s in the range which does not affect the effect of this invention.

  The oil phase is 40% by mass or less, preferably 20 to 30% by mass with respect to the total amount of the cosmetic. When the oil phase is 40% by mass or less based on the total amount of the cosmetic, stickiness can be suppressed while ensuring the emulsion stability.

In the oil-in-water emulsified cosmetic of the present invention, various components usually used in cosmetics, such as a humectant, a pH adjuster, a neutralizer, an antioxidant, an antiseptic, an antibacterial agent, as long as the effect is not impaired. Agents, drugs, extracts, fragrances, pigments, etc. can be blended.
Examples of the humectant include polyhydric alcohols such as glycerin, diethylene glycol, butylene glycol, and polyethylene glycol, amino acids, nucleic acids, proteins such as collagen and elastin, mucopolysaccharides such as hyaluronic acid and chondroitin sulfate, and the like.
Examples of the pH adjuster include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, potassium carbonate, sodium hydrogen carbonate, ammonium hydrogen carbonate and the like.

Examples of the antioxidant include ascorbic acid, α-tocopherol, dibutylhydroxytoluene, butylhydroxyanisole and the like.
Examples of preservatives and antibacterial agents include paraoxybenzoic acid esters, phenoxyethanol, benzoic acid, salicylic acid, carboxylic acid, sorbic acid, parachloromethcresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, and photosensitizers. Can be mentioned.

  The form of the oil-in-water emulsified cosmetic of the present invention is not particularly limited, and basic cosmetics such as lotion, milky lotion, cream, facial cleanser, gel, essence (beauty serum), pack, etc., lipstick, eye shadow, eyeliner, mascara Any form of cosmetics such as foundations, sunscreens, makeup cosmetics, oral cosmetics, aromatic cosmetics, hair cosmetics, body cosmetics, etc. can be widely applied.

EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited to these Examples. Moreover, the compounding quantity in a following example etc. shows the mass% unless there is particular notice.
The oil-in-water emulsified cosmetics having the compositions listed in Tables 1 and 2 below were prepared by a conventional method, and the following measurements and evaluations were performed.

(UV protection effect)
The ultraviolet protection effect was performed using a highly accurate in vitro SPF measurement system described in JP-A-7-167781.
Specifically, a solar simulator (Solar Ultraviolet Simulator Model 600: Solar Light Co.) was used as the light source. A sample was uniformly applied to a transpore tape TM (3M Co.) used as an application body at an application amount of 2.0 mg / cm ² , dried for 15 minutes, and then irradiated with ultraviolet rays. And the calculation process of the transmitted ultraviolet spectrum was performed, and SPF value was computed.
The SPF values of the cosmetics of Examples and Comparative Examples calculated by the above method are normalized with the SPF value of the solid oil and / or semisolid oil-free sample, and the solid oil and / or semisolid oil-free formula is used. 1 was evaluated, and a value of 1 or less was evaluated as B, and 1 or more was evaluated as A.

(Immediate dispersibility)
The state immediately after manufacturing the obtained cosmetic was visually observed and evaluated according to the following criteria.
A: Evenly dispersed B: Undispersed part is slightly seen C: Undispersed part is seen

(Stability over time)
The state of the obtained cosmetics after 2 weeks at room temperature was visually observed and evaluated according to the following criteria.
A: Separation is not observed B: Separation of oil is slightly observed C: Part of oil is separated

Moreover, the following criteria were evaluated about the feeling of use of the obtained cosmetics.
(Mizumizushi)
Ten women-specialized panel members applied cosmetics to their skin and asked them to evaluate their freshness during application.
A: Eight or more panel members felt freshness during application B: Three to seven panelists felt freshness during application C: Two or less panelists felt freshness during application

(Stickiness)
Ten women-specialized panels were asked to apply cosmetics to their skin and evaluate their stickiness after application.
A: Eight or more panel members recognized that there was no stickiness after application B: Three to seven panel members recognized that there was no sticky feeling after application C: Two or less panels did not feel sticky after application recognized

  As shown in Tables 1 and 2, the oil-in-water emulsified cosmetic of the present invention is sticky as a prescription that can achieve a high SPF value while maintaining the freshness required for oil-in-water emulsified cosmetics. I was able to suppress it. On the other hand, in Comparative Example 1 which does not contain solid oil and / or semi-solid oil, there is a freshness, but even if it contains sticky, solid oil and / or semi-solid oil, its blending amount is more than 25% by mass with respect to the total amount of the oil phase. Although the stickiness was suppressed in the high comparative example 2, the freshness required for the oil-in-water emulsified cosmetic was lost. Moreover, even if the compounding quantity of solid oil and / or semi-solid oil is 2-25 mass% with respect to the total amount of oil phase, it will be shown in Comparative Example 3 if the oil phase exceeds 40 mass% with respect to the total amount of cosmetics. Emulsification failure occurred. In Comparative Example 3, because the emulsion breakage occurred, measurement of the SPF value and sensory evaluation were not performed. Furthermore, as shown in Comparative Example 4, in the case of dextrin palmitate, the viscosity was high as shown in Table 3, and thus stickiness could not be suppressed. Comparative Example 5 was an example using palmitic acid, and Comparative Example 6 was a higher alcohol. In these cases, stability over time, which is important as a cosmetic, was poor.

(Viscosity measurement)
Samples obtained by warming and dissolving each solid oil and / or semi-solid oil, fatty acid, and higher alcohol 2% using diisopropyl sebacate 98% as a solvent were allowed to stand for 1 day, and then B type viscometer, VDA type viscometer ( Shibaura System Co., Ltd. DIGITAL VISMETRON VDA) 2. Measurement was performed under conditions of 12 rpm for 1 minute. Table 3 shows the measurement results.

(Prescription example)
Below, the formulation example of the oil-in-water type emulsion cosmetics of this invention is given. The present invention is not limited by this formulation example. In addition, all compounding quantities are represented by the mass% with respect to the product whole quantity.

Formulation Example 1: Sunscreen emulsion macadamia nut oil fatty acid phytosteryl 0.5
Diisopropyl sebacate 10
Sorbitan sesquiisostearate 0.5
2-Ethylhexyl paramethoxycinnamate 7.5
Sodium hydroxymethoxybenzophenone sulfonate 3
Dimethylacrylamide / acryloyldimethyltaurine Na crosspolymer
0.5
Triethanolamine 1.8
Hydrophobized titanium oxide 4
Concentrated glycerin 4
Polyethylene glycol 300 8
Ethanol 10
Phenoxyethanol 0.3
Ion exchange water

Formulation Example 2: Sunscreen Emulsion Vaseline 1
Diisopropyl sebacate 10
Sorbitan sesquiisostearate 0.5
2-Ethylhexyl paramethoxycinnamate 7.5
2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] 1,3,5-triazine
1.5
Stearoxyhydroxypropylmethylcellulose 0.5
Hydrophobized titanium oxide 4
Concentrated glycerin 4
Polyethylene glycol 300 8
Ethanol 10
Ion exchange water

Formulation Example 3: Sunscreen Emulsion Vaseline 1
Diisopropyl sebacate 10
Sorbitan sesquiisostearate 0.5
2-Ethylhexyl paramethoxycinnamate 1.5
2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] 1,3,5-triazine
1.5
Oxybenzone 1
Polysilicone-15 2.0
Octocrylene 2.0
Tylene bisbenzotriazolyl tetramethylbutylphenol 2.0
2- [4- (Diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester 1.0
Stearoxyhydroxypropylmethylcellulose 0.5
Xanthan gum 0.1
Tranexamic acid 2.0
Dipotassium glycyrrhizinate 0.05
4-methoxysalicylic acid potassium salt 2.0
Hydrophobized titanium oxide 4
Concentrated glycerin 4
Polyethylene glycol 300 8
Ethanol 10
Ion exchange water

Formulation Example 4: Sunscreen emulsion sucrose stearate 1
Diisopropyl sebacate 10
2-ethylhexyl succinate 5
Methyl polysiloxane 1
Sorbitan sesquiisostearate 0.5
2-Ethylhexyl paramethoxycinnamate 7.5
Sodium hydroxymethoxybenzophenone sulfonate 3
Dimethylacrylamide / acryloyldimethyltaurine Na crosspolymer
0.5
Triethanolamine 1.8
Hydrophobized titanium oxide 4
Concentrated glycerin 4
Polyethylene glycol 300 8
Ethanol 10
Phenoxyethanol 0.3
Ion exchange water

Formulation Example 3: Sunscreen Emulsion Vaseline 1
Diisopropyl sebacate 10
Sorbitan sesquiisostearate 0.5
2-Ethylhexyl paramethoxycinnamate 1.5
2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] 1,3,5-triazine
1.5
Oxybenzone 1
Polysilicone-15 2.0
Octocrylene 2.0
Main Ji Ren bis-benzotriazolyl tetramethylbutylphenol 2.0
2- [4- (Diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester 1.0
Stearoxyhydroxypropylmethylcellulose 0.5
Xanthan gum 0.1
Tranexamic acid 2.0
Dipotassium glycyrrhizinate 0.05
4-methoxysalicylic acid potassium salt 2.0
Hydrophobized titanium oxide 4
Concentrated glycerin 4
Polyethylene glycol 300 8
Ethanol 10
Ion exchange water

Claims (14)

An oil-in-water emulsified cosmetic comprising a solid oil and / or semi-solid oil, a powder, and an emulsifier,
The solid oil and / or semi-solid oil is at least one selected from hydrocarbon oils, silicone oils and ester oils, has a viscosity at 25 ° C. of 1500 mPa · s or less, and the blending amount is the total amount of the oil phase. 2 to 25% by mass with respect to
An oil-in-water emulsified cosmetic in which the oil phase is 40% by mass or less based on the total amount of the cosmetic.   The oil-in-water emulsified cosmetic according to claim 1, wherein the solid oil and / or semi-solid oil is a sucrose fatty acid ester.   The oil-in-water emulsified cosmetic according to claim 2, wherein the fatty acid of the sucrose fatty acid ester is a linear or branched chain having 12 to 22 carbon atoms.   The oil-in-water emulsified cosmetic according to claim 1, wherein the solid oil and / or semi-solid oil is an alkylmethylsiloxane wax.   The oil-in-water emulsified cosmetic according to any one of claims 1 to 4, wherein the emulsifier is an amphiphilic polymer.   The oil-in-water emulsified cosmetic according to any one of claims 1 to 5, wherein the emulsifier is an alkyl-modified polysaccharide.   The oil-in-water emulsified cosmetic according to claim 6, wherein the emulsifier is a hydrophobically modified alkyl cellulose.   The oil-in-water emulsified cosmetic according to any one of claims 1 to 7, wherein a blending amount of the solid oil and / or semi-solid oil is 0.5 to 5% by mass based on the total amount of the cosmetic.   The oil-in-water emulsified cosmetic according to claim 8, wherein a ratio of the amount of the emulsifier to the amount of the solid oil and / or semi-solid oil is 0.04 to 0.4.   The oil-in-water emulsified cosmetic according to any one of claims 1 to 9, wherein a blending amount of the powder is 3 to 10% by mass with respect to a total amount of the cosmetic.   The oil-in-water emulsified cosmetic according to any one of claims 1 to 10, wherein the powder is a hydrophobic powder.   The oil-in-water emulsion cosmetic according to any one of claims 1 to 11, further comprising a thickener, wherein the thickener is at least one selected from polyacrylamide compounds, anionic polymers and polysaccharides. Fee.   The thickener is (dimethylacrylamide / acryloyldimethyltaurine sodium) crosspolymer, vinylpyrrolidone / 2-acrylamido-2-methylpropanesulfonic acid (salt) copolymer, sodium acrylate / 2-acrylamido-2-methylpropane Sulfonic acid (salt) copolymer, acrylamide / 2-acrylamido-2-methylpropanesulfonic acid sodium salt copolymer, acrylamide / 2-acrylamido-2-methylpropanesulfonic acid (salt), 2-acrylamido-2-methyl The water according to claim 12, which is at least one selected from a homopolymer of sodium propanesulfonate, dimethylacrylamide / 2-acrylamido-2-methylpropanesulfonic acid, carboxyvinyl polymer, and xanthan gum. Oil type emulsified cosmetic.   The oil-in-water emulsified cosmetic according to any one of claims 1 to 13, wherein the oil phase contains an ultraviolet absorber.