JP2017057503A - Aluminum alloy clad material and heat exchanger assembled with tube made by forming the clad material - Google Patents

Abstract

PURPOSE: To provide an aluminum alloy clad material which gives a tube for heat exchangers having excellent corrosion resistance of the outer surface when formed into a tube.CONSTITUTION: An aluminum alloy clad material comprises a three-layer structure in which an inner skin material is cladded on one side of a core and a sacrificial anode material is cladded on the other side. The core is composed of an Al-Mn-Cu alloy comprising 0.6-2.0% Mn, 0.03-1.0% Cu and remaining aluminum and unavoidable impurities. The sacrificial anode material is an Al-Zn-Cu alloy comprising 0.5-6.0% Zn, 0.03-0.3% Cu and remaining aluminum and unavoidable impurities. The inner skin material is an Al-Mn-Cu alloy comprising 0.6-2.0% Mn, 0.2-1.5% Cu and remaining aluminum and unavoidable impurities. The Cu amounts, %, of the core, the inner skin material and the sacrificial anode material meet the condition: (Cu% of the sacrificial anode material)≤(Cu% of the core)≤(Cu% of the inner skin material). The aluminum alloy clad material may have a two-layer structure consisting of the core and the sacrificial anode material.SELECTED DRAWING: None

Description

  The present invention relates to an aluminum alloy clad material, more specifically, an aluminum alloy clad material capable of obtaining a heat exchanger tube having excellent outer surface corrosion resistance when molded into a tube, and a heat assembled with the tube formed from the clad material. Regarding the exchanger.

  Conventionally, an aluminum alloy extruded tube or a tube formed by bending an aluminum alloy plate material is applied as a refrigerant passage tube of an aluminum heat exchanger that is joined and integrated by brazing. In order to improve the corrosion resistance of the outer surface (atmosphere side), these refrigerant passage tubes are subjected to Zn spraying on the extrusion tube on the outer surface side of the refrigerant passage tube, and Al− for the tube formed by bending the plate material. The Zn-based alloy is clad, and the design is aimed at the sacrificial anode effect by the Zn diffusion layer.

  In recent years, especially in automotive heat exchangers, it has been required to reduce the thickness of the constituent materials and increase the corrosion resistance, and to reduce the corrosion rate of the sacrificial anode layer and increase the sacrificial anode layer thickness by reducing the Zn content of the sacrificial anode material. It has been. However, in the conventional extruded tube, it is difficult to reduce the amount of Zn spray from the viewpoint of spraying efficiency, and even in a tube formed by bending a plate material, the potential of the sacrificial anode material is noble due to the influence of diffusion of Cu contained in the core material. Therefore, if the Zn content is reduced, a sufficient potential difference for obtaining the sacrificial anode effect cannot be secured, so it is difficult to reduce the Zn content of the sacrificial anode material, and the sacrificial anode layer thickness is increased. Also, it is difficult to increase the cladding rate from the viewpoint of manufacturing cost.

  A brazing sheet in which a larger amount of Cu than the core material is added to the brazing material on the inner surface side and a potential gradient is applied so that the electric potential becomes noble from the outer surface side toward the inner surface side after brazing, and the brazing material on the outer surface side Zn is added to the brazing material on the inner surface side, and Zn and Cu are added at a specific addition ratio, so that the potential is increased from the outer surface of the brazing sheet to the inner surface due to the concentration gradient of Zn and Cu. Although a brazing sheet designed to be noble has been proposed, the potential layer formed by Cu diffused from the brazing material is thin, and the potential difference between the noble layer and the core material is small, so that the core material is corroded by corrosion. In the state immediately before the through hole is generated, the effect of suppressing the generation of the through hole is not sufficient.

JP 2011-224656 A JP 2009-127121 A JP 2007-247021 A

In order to solve the above-mentioned problems, the inventors have tested a tube formed by bending an aluminum alloy plate material, the structure of the aluminum alloy clad material constituting the tube, and the relationship between the alloy composition of each layer of the clad material and the corrosion resistance. As a result of the examination, the structure of the aluminum alloy clad material constituting the tube is a two-layer structure of the core material and the sacrificial anode material, or the sacrificial anode material is clad on one surface of the core material, and the other surface is more than the core material. When the sacrificial anode material contains a small amount of Cu in the case of a three-layer structure in which a potential noble endothelial material is arranged, the corrosion rate of the sacrificial anode material is suppressed, and the sacrificial anode material remains for a long time. It has been found that the generation of holes can be suppressed, and the corrosion resistance of the outer surface (atmosphere side) is improved. In particular, in the three-layer structure, the core material exerts a sacrificial anode effect on the endothelial material, so that the sacrificial anode material and the core material become the sacrificial anode layer with respect to the endothelium material, resulting in an increase in the thickness of the sacrificial anode layer. Thus, it is possible to suppress the generation of through holes for a longer period.

  The present invention was made as a result of further testing and examination based on the above knowledge, and its purpose is to obtain a heat exchanger tube having excellent corrosion resistance on the outer surface when formed into a tube. An aluminum alloy clad material that can be produced, and a heat exchanger in which a tube formed with the clad material is assembled.

  An aluminum alloy clad material according to claim 1 for achieving the above object is an aluminum alloy clad material in which a sacrificial anode material is clad on one surface of a core material, and the core material has Mn: 0.6 to 2.0. %, Cu: 0.03 to 1.0%, Al—Mn—Cu alloy composed of the balance aluminum and inevitable impurities, and the sacrificial anode material is Zn: 0.5 to 6.0%, Cu : Al-Zn-Cu alloy containing 0.03 to 0.3%, the balance being aluminum and inevitable impurities, the Cu content of the core material and the sacrificial anode material (Cu content% of the sacrificial anode material) ≦ (Cu content% of core material) In the following description, all alloy percentages are indicated by mass%.

  An aluminum alloy clad material according to claim 2 is characterized in that, in claim 1, the core material further contains one or two of Si: 1.5% or less and Fe: 0.7% or less.

  An aluminum alloy clad material according to claim 3 is characterized in that, in claim 1 or 2, the core material further contains Ti: 0.01 to 0.3%.

  The aluminum alloy clad material according to claim 4 is an aluminum alloy clad material in which a core material is clad with an endothelial material on one surface and a sacrificial anode material is clad on the other surface, and the core material has Mn: 0.6-2. 0.0%, Cu: 0.03 to 1.0%, Al-Mn-Cu alloy consisting of the balance aluminum and inevitable impurities, and the endothelial material is Mn: 0.6 to 2.0%, It is an Al—Mn—Cu alloy containing Cu: 0.2 to 1.5%, and the balance being aluminum and inevitable impurities, and the sacrificial anode material is Zn: 0.5 to 6.0%, Cu: 0 Al-Zn-Cu alloy containing 0.03 to 0.3% and the balance aluminum and inevitable impurities, the Cu content of the core material, the endothelial material and the sacrificial anode material (Cu content% of the sacrificial anode material) ) ≤ (Cu content of core material%) ≤ Characterized in that a relation of the Cu content%) of the inner covering.

  The aluminum alloy clad material according to claim 5 is characterized in that, in claim 4, the core material further contains one or two of Si: 1.5% or less and Fe: 0.7% or less.

  An aluminum alloy clad material according to claim 6 is characterized in that, in claim 4 or 5, the core material further contains Ti: 0.01 to 0.3%.

  The aluminum alloy clad material according to claim 7 is the aluminum alloy clad material according to any one of claims 4 to 6, wherein the endothelial material further contains one or two of Si: 1.5% or less and Fe: 0.7% or less. It is characterized by that.

The aluminum alloy clad material according to claim 8 is characterized in that, in any one of claims 4 to 7, the endothelial material further contains Ti: 0.01 to 0.3%.

  The aluminum alloy clad material according to claim 9 is any one of claims 1 to 8, wherein the sacrificial anode material is further Si: 1.5% or less, Fe: 0.7% or less, Mn: 1.5% or less 1 type or 2 types or more are contained.

  A heat exchanger according to claim 10 is formed by forming the aluminum alloy clad material according to any one of claims 1 to 9 into a tube so that the endothelial material is on the refrigerant passage side and the sacrificial anode material is on the atmosphere side. It is characterized by being assembled by brazing aluminum fins.

  According to the present invention, when formed into a tube, the aluminum alloy clad material which is excellent in corrosion resistance of the outer surface and can be suitably used as a material of a heat exchanger, in particular, a heat exchanger tube for automobiles, and the aluminum alloy clad A heat exchanger is provided that incorporates a tube formed from a material.

It is sectional drawing which shows the Example of the tube for heat exchangers which shape | molded the aluminum alloy clad material of this invention. It is sectional drawing which shows the other Example of the tube for heat exchangers which shape | molded the aluminum alloy clad material of this invention.

  As described above, the aluminum alloy clad material of the present invention has a two-layer structure composed of a core material and a sacrificial anode material, or a sacrificial anode material disposed on one surface of the core material, and a potential higher than that of the core material on the other surface. Has a three-layer structure in which noble endothelial material is arranged, and the sacrificial anode material contains Cu, and is molded into a tube so that the endothelial material is on the refrigerant passage side and the sacrificial anode material is on the atmosphere side. When assembled in the exchanger, the rate of corrosion of the sacrificial anode material is suppressed, and the sacrificial anode effect of the sacrificial anode material lasts for a long period of time. Improved corrosion resistance is achieved. In particular, in the three-layer structure, the sacrificial anode material and the core material serve as a sacrificial anode layer with respect to the endothelium material because the core material serves as the endothelium material, resulting in an increase in the thickness of the sacrificial anode layer. Thus, it is possible to suppress the generation of through holes for a longer period.

  In the basic structure of the two-layer structure, Al—Mn—Cu containing Mn: 0.6 to 2.0%, Cu: 0.03 to 1.0%, and the balance aluminum and inevitable impurities as core materials As the alloy and sacrificial anode material, an Al—Zn—Cu alloy containing Zn: 0.5 to 6.0%, Cu: 0.03 to 0.3%, and the balance aluminum and inevitable impurities is applied. The However, the Cu content of the core material and the sacrificial anode material is set such that (Cu content% of the sacrificial anode material) ≦ (Cu content% of the core material).

  The core material can contain one or two of Si: 1.5% or less and Fe: 0.7% or less, and can contain Ti: 0.01 to 0.3%. In addition, the sacrificial anode material may contain one or more of Si: 1.5% or less, Fe: 0.7% or less, and Mn: 1.5% or less.

  In the basic structure of the three-layer structure, Al—Mn—Cu containing Mn: 0.6 to 2.0%, Cu: 0.03 to 1.0% as a core material, and remaining balance of aluminum and inevitable impurities Al-Mn-Cu alloy containing Mn: 0.6-2.0%, Cu: 0.2-1.5%, the balance aluminum and inevitable impurities, as sacrificial anode material , Zn: 0.5-6.0%, Cu: 0.03-0.3%, Al—Zn—Cu alloy consisting of the balance aluminum and inevitable impurities is applied. However, the Cu content of the core material, the endothelial material, and the sacrificial anode material is such that (Cu content% of the sacrificial anode material) ≦ (Cu content% of the core material) ≦ (Cu content% of the endothelium material). To do.

  The core material can contain one or two of Si: 1.5% or less and Fe: 0.7% or less, and can contain Ti: 0.01 to 0.3%. The endothelium material can contain one or two of Si: 1.5% or less and Fe: 0.7% or less, and Ti: 0.01 to 0.3%. In addition, the sacrificial anode material may contain one or more of Si: 1.5% or less, Fe: 0.7% or less, and Mn: 1.5% or less.

Hereinafter, the significance and reasons for limitation of the alloy components of the core material, the endothelial material, and the sacrificial anode material will be described.
(Sacrificial anode material)
Zn:
Zn in the sacrificial anode material functions to make the potential noble, and is contained for adjusting the potential balance with the core material and the endothelial material. The preferable content of Zn is in the range of 0.5 to 6.0%. If the content is less than 0.5%, the effect is not sufficient. If the content exceeds 6.0%, the self-corrosion rate increases and the corrosion resistance life is shortened. descend. A more preferable content range of Zn is 1.0 to 5.0%.

Cu:
Cu functions to suppress the corrosion rate of the sacrificial anode material. The preferable content of Cu is in the range of 0.03 to 0.3%. If it is less than 0.03%, a sufficient corrosion rate suppressing effect cannot be obtained, and if it exceeds 0.3%, the potential becomes noble. It becomes difficult to obtain the sacrificial anode effect. A more preferable content range of Cu is 0.03 to 0.2%.

Si:
Si functions to improve strength. The preferable content of Si is in the range of 1.5% or less, and when it exceeds 1.5%, the self-corrosion rate increases. The more preferable range of Si is 0.
5% or less.

Fe:
Fe functions to improve strength. The preferable content of Fe is in the range of 0.7% or less, and when it exceeds 0.7%, the self-corrosion rate increases.

Mn:
Mn functions to improve strength. The preferable content of Mn is in the range of 1.5% or less, and when it exceeds 1.5%, the self-corrosion rate increases. A more preferable content range of Mn is 0.5% or less. Even if the sacrificial anode material contains 0.3% or less of In, Sn, Ti, V, Cr, Zr and B, the effects of the present invention are not impaired.

(Heartwood)
Mn:
Mn functions to improve strength. The preferable content of Mn is in the range of 0.6 to 2.0%. If it is less than 0.6%, the effect is not sufficient, and if it exceeds 2.0%, rolling becomes difficult. A more preferable content range of Mn is 1.0 to 2.0%.

Cu:
Cu functions to make the potential of the core material noble, and is contained for adjusting the balance of the potential with the sacrificial anode material and the endothelial material. If the Cu content in the core material is less than the Cu content in the sacrificial anode material, a potential difference from the sacrificial anode material cannot be ensured, so the Cu content in the core material is preferably equal to or greater than the Cu content in the sacrificial anode material. . Further, since Cu in the core material diffuses into the sacrificial anode material during brazing heating and reduces the potential difference from the sacrificial anode material, the Cu content of the core material is preferably 1.5% or less. In the clad material with a three-layer structure, if the Cu content in the core material is equal to or higher than the Cu content in the endothelium material, a potential difference from the endothelium material cannot be secured, so the Cu content in the core material in the clad material with the three-layer structure The amount is preferably less than the Cu content in the endothelial material. A more preferable content range of Cu is 0.6% or less.

Si:
Si functions to improve strength. The preferable content of Si is in the range of 1.5% or less, and if it exceeds 1.5%, the melting point is lowered and it becomes easy to melt during brazing. A more preferable content range of Si is 0.8% or less.

Fe:
Fe functions to improve strength. The preferable content of Fe is in the range of 0.7% or less, and when it exceeds 0.7%, the self-corrosion rate increases.

Ti:
Ti is divided into a high-concentration region and a low region in the thickness direction of the core material, and the layers are alternately distributed. As a result, the low-concentration region is preferentially corroded as compared to the high region. This prevents the progress of corrosion in the thickness direction, thereby improving the corrosion resistance. The preferable content of Ti is in the range of 0.01 to 0.3%. If the content is less than 0.01%, the effect is not sufficient, and if it exceeds 0.3%, a huge crystallized product is formed and molded. Sex is harmed. In addition, even if the core material contains 0.3% or less of V, Cr, Zr and B, the effect of the present invention is not impaired.

(Endothelial material)
Mn:
Mn functions to improve strength. The preferable content of Mn is in the range of 0.6 to 2.0%. If it is less than 0.6%, the effect is not sufficient, and if it exceeds 2.0%, rolling becomes difficult. A more preferable content range of Mn is 1.0 to 2.0%.

Si:
Si functions to improve strength. The preferable content of Si is in the range of 1.5% or less, and if it exceeds 1.5%, the melting point is lowered and it becomes easy to melt during brazing.

Fe:
Fe functions to improve strength. The preferable content of Fe is in the range of 0.7% or less, and when it exceeds 0.7%, the self-corrosion rate increases.

Cu:
Cu functions to make the potential of the endothelial material noble and is contained for adjusting the balance of the potential with the core material. The preferable content of Cu is in the range of 0.2 to 1.5%, and in the range of (Cu content% of the core material) ≦ (Cu content% of the endothelium material), the melting point is over 1.5%. Decreases and becomes easier to melt during brazing. When the Cu content of the endothelial material is less than the Cu content of the core material, the core material does not act as a sacrificial anode material for the endothelial material, and therefore the corrosion resistance life is reduced. The more preferable content range of Cu in the endothelial material is 0.8% or less.

Ti:
Ti is divided into a high-concentration region and a low region in the plate thickness direction of the endothelium material, and they are layered alternately. As a result, the low-Ti concentration region corrodes preferentially compared to the high region, resulting in a corrosive form. It has the effect of layering, thereby preventing the progress of corrosion in the thickness direction and improving the corrosion resistance. The preferable content of Ti is in the range of 0.01 to 0.3%. If the content is less than 0.01%, the effect is not sufficient, and if it exceeds 0.3%, a huge crystallized product is formed and molded. Sex is harmed. In addition, even if 0.3% or less of V, Cr, Zr and B are contained in the endothelial material, the effect of the present invention is not impaired.

  As for the contents of Si and Fe in the sacrificial anode material, the core material and the endothelial material, the use of high-purity bullion causes an increase in manufacturing cost. Therefore, both the Si and Fe contents are less than 0.03%. Is not preferable.

  In the clad structure of the present invention, the clad rate of the sacrificial anode material is preferably 5 to 30%, and in the case of a three-layer structure, the clad rate of the endothelial material is preferably 5 to 30%. If the clad rate of the sacrificial anode material is less than 5%, the amount of Zn in the sacrificial anode material decreases due to diffusion during brazing, making it difficult to obtain a sufficient sacrificial anode effect. If the clad rate of the sacrificial anode material exceeds 30%, clad rolling becomes difficult. A more preferable sacrificial anode material has a cladding ratio of 10 to 30%. If the clad rate of the endothelial material is less than 5%, the Cu concentration in the endothelial material decreases due to diffusion during brazing, the potential difference from the core material becomes small, and the sacrificial anode effect of the core material becomes difficult to obtain. If the clad rate of the endothelial material exceeds 30%, clad rolling becomes difficult. A more preferable cladding ratio of the endothelial material is 10 to 30%.

  The aluminum alloy clad material of the present invention is formed into a tube so that the endothelial material is on the refrigerant passage side and the sacrificial anode material is on the atmosphere side (outside surface side), and on the outside surface side (atmosphere side) of this tube or on the outside surface side. Aluminum fins are assembled on the inner surface side (refrigerant flow path side) and brazed to form a heat exchanger.

  For example, as shown in FIG. 1, the tube material 1 is produced by forming an aluminum alloy clad material 2 into a tube, and then inserting inner fins 3 made of a brazing sheet with brazing material disposed on both sides, and connecting the tube joint 4 As shown in FIG. 2, a paste brazing 5 is applied to the sacrificial anode material side of the aluminum alloy clad material 2 in advance to form a tube, or as shown in FIG. After molding, a paste brazing 5 is applied, and the joint 4 is brazed and joined by the paste brazing 5.

  The aluminum alloy clad material of the present invention is molded into a tube so that the core material in the case of the two-layer structure is the refrigerant passage side and the sacrificial anode material is on the atmosphere side (outer surface side) in the three-layer structure. When an aluminum fin is assembled to this tube and brazed and heated at a temperature of 600 ° C. for 3 minutes, both are joined to produce a heat exchanger, the potential of the sacrificial anode material, core material and endothelial material in the assembled tube is , (Potential of sacrificial anode material) <(potential of core material) <(potential of endothelium material having a three-layer structure), and the sacrificial anode material exerts a sacrificial anode effect on the core material. The sacrificial anode material of the Al—Zn—Cu based alloy according to the present invention has a slower corrosion rate than the sacrificial anode material of a general Al—Zn based alloy, and the period during which the sacrificial anode effect acts increases, thereby improving the corrosion resistance. Can be achieved. In the case of the three-layer structure, the core material exerts a sacrificial anode effect on the endothelium material. As a result, the thickness of the sacrificial anode layer is increased, and both the sacrificial anode material and the core material are affected by corrosion. Even when most of the material is consumed, the presence of a noble endothelial material can suppress the generation of through-holes, thereby further improving the corrosion resistance of the outer surface (atmosphere side).

Examples of the present invention will be described below in comparison with comparative examples to demonstrate the effects. These examples show one embodiment of the present invention, and the present invention is not limited thereto.

Example 1
The alloy for sacrificial anode materials (S1 to S11) having the composition shown in Table 1 by semi-continuous casting, the alloy for core material and the alloy for endothelial material (C1 to C20) having the composition shown in Table 2 were obtained. Among the ingots, the alloy ingot for sacrificial anode material was homogenized at 500 ° C. for 8 hours, and then hot-rolled at a starting temperature of 500 ° C. to a predetermined thickness, and the alloy ingot for core material and endothelial material After performing a homogenization treatment at 500 ° C. for 8 hours, the core alloy ingot was chamfered, and the endothelium alloy ingot was hot-rolled at a starting temperature of 500 ° C. to a predetermined thickness.

  Next, after chamfering the hot rolled material of the sacrificial anode material alloy and the endothelial material alloy, each aluminum alloy was superposed in the combination shown in Table 3, and hot rolled to a thickness of 3 mm at a starting temperature of 500 ° C., Further, after cold rolling, intermediate annealing was performed at a temperature of 400 ° C., and then cold rolling was performed to obtain aluminum alloy clad plate materials (test materials 1 to 31) having a thickness of 0.2 mm.

Comparative Example 1
The alloy for sacrificial anode materials (S12 to S18) having the composition shown in Table 1 by semi-continuous casting, the alloy for core material and the alloy for endothelial material (C21 to C26) having the composition shown in Table 2 are further ingoted, and further implemented The alloy for sacrificial anode material (S1), the alloy for core material and the alloy for endothelium material (C1, C11) ingoted in Example 1 are used, and among these ingots, the alloy ingot for sacrificial anode material is 500 ° C. After performing a homogenization treatment for 8 hours at a starting temperature of 500 ° C. to obtain a predetermined thickness, the core material and the alloy ingot for endothelial material were subjected to a homogenization treatment at 500 ° C. for 8 hours, The core material alloy ingot was chamfered, and the endothelial material alloy ingot was hot-rolled at a starting temperature of 500 ° C. to a predetermined thickness. In Tables 1 and 2, those outside the conditions of the present invention are underlined.

  Next, after chamfering the hot rolled material of the sacrificial anode material alloy and the endothelial material alloy, each aluminum alloy was superposed in the combination shown in Table 4 and hot rolled to a thickness of 3 mm at a starting temperature of 500 ° C., Further, after cold rolling, intermediate annealing was performed at a temperature of 400 ° C., and then cold rolling was performed to obtain aluminum alloy clad plate materials (test materials 101 to 114) having a thickness of 0.2 mm.

About the obtained test material, after heating for 3 minutes at 600 degreeC equivalent to brazing heating, the potential measurement, the tension test, and the corrosion test were done with the following method. The results are shown in Tables 3-4.
(Potential measurement)
The potential of the test material was measured at room temperature in a 5% NaCl aqueous solution adjusted to pH 3 with acetic acid. The potential of the sacrificial anode material was measured by masking other than the sacrificial anode material side surface, and the potential of the endothelial material was measured by masking the surface other than the endothelial material side surface. Further, the potential of the core material was measured by grinding the test material from the sacrificial anode material surface side to the center of the core material thickness and masking other than the ground surface.

(Tensile test)
The test material was formed into a JIS-5 test piece, and a tensile test was performed in accordance with JIS Z2241, and a 3003 alloy having a tensile strength equal to or higher than the O-material equivalent strength (95 MPa) was regarded as acceptable.

(Corrosion test)
For the test piece with the sacrificial anode material exposed by masking, the SWAAT test (ASTM
G85) to evaluate the corrosion resistance. If no through-holes were generated after 1000 hours, the pass (○) was evaluated, and if no through-holes were generated even after 1500 hours, it was evaluated as excellent (◎). Those that produced through-holes in less than 1000 hours were evaluated as rejected (x).

  As seen in Table 3, none of the test materials 1 to 31 according to the present invention produced through holes in the SWAAT test. In particular, the test materials 14 to 31 on which the endothelial material was arranged did not generate through holes for a longer time. Further, these aluminum alloy clad materials are formed into a tube so that the endothelial material is on the refrigerant passage side and the sacrificial anode material is on the atmosphere side (outer surface side), and an aluminum fin is assembled to the tube at a temperature of 600 ° C. When a heat exchanger was manufactured by brazing and heating for 3 minutes and joining both, it was confirmed that improved corrosion resistance of the outer surface (atmosphere side) was obtained.

  On the other hand, as shown in Table 4, the test materials 101 and 109 have a large amount of Si in the sacrificial anode material, the test material 102 has a large amount of Fe in the sacrificial anode material, and the test material 105 has a sacrificial anode material. Because of the large amount of Mn, the amount of self-corrosion of the sacrificial anode material increased, and through holes were generated in the SWAAT test. Since the test material 103 had a small amount of Cu in the sacrificial anode material, the amount of self-corrosion of the sacrificial anode material increased, and a through hole was generated in the SWAAT test. Since the test material 104 has a large amount of Cu in the sacrificial anode material, the test material 106 has a small amount of Zn in the sacrificial anode material, so that the sacrificial anode effect is not sufficient, and a through hole was generated in the SWAAT test. Since the test material 107 had a large amount of Zn in the sacrificial anode material, the amount of self-corrosion of the sacrificial anode material increased, and a through hole was generated in the SWAAT test. Since the test material 108 had a small amount of Cu in the core material, the sacrificial anode effect was not sufficient, and a through hole was generated in the SWAAT test.

  Since the test material 110 has a large amount of Si in the core material, the core material melted during brazing heating. Since the test material 111 had a large amount of Fe in the core material, the self-corrosion amount of the core material increased, and a through hole was generated in the SWAAT test. Since the test material 112 had a small amount of Mn in the core material, the tensile strength was low.

  Since the test material 113 had a large amount of Cu in the endothelial material, the endothelial material melted during brazing heating. Since the test material 114 had a large amount of Mn in the endothelial material, cracking occurred during cold rolling, and a sound clad material could not be obtained.

1 Tube material 2 Aluminum alloy clad material 3 Inner fin 4 Seam 5 Paste brazing

Aluminum alloy clad sheet according to claim 4, before Symbol sacrificial anode material further Si: 1.5% or less, Fe: 0.7% or less, Mn: it contains one or more than 1.5% of It is characterized by doing.

A heat exchanger according to claim 5 is formed by forming the aluminum alloy clad material according to any one of claims 1 to 4 into a tube so that the endothelial material is on the refrigerant passage side and the sacrificial anode material is on the atmosphere side. It is characterized by being assembled by brazing aluminum fins.

Claims (10)

  An aluminum alloy clad material in which a sacrificial anode material is clad on one surface of a core material, and the core material is Mn: 0.6 to 2.0% (mass%, the same applies hereinafter), Cu: 0.03 to 1.0 Al—Mn—Cu alloy containing the balance aluminum and unavoidable impurities, and the sacrificial anode material contains Zn: 0.5 to 6.0%, Cu: 0.03 to 0.3% And the Al-Zn-Cu alloy composed of the balance aluminum and inevitable impurities, and the Cu content of the core material and the sacrificial anode material is (Cu content% of the sacrificial anode material) ≦ (Cu content% of the core material) An aluminum alloy clad material characterized by   The aluminum alloy clad material according to claim 1, wherein the core material further contains one or two of Si: 1.5% or less and Fe: 0.7% or less.   The aluminum alloy clad material according to claim 1 or 2, wherein the core material further contains Ti: 0.01 to 0.3%.   An aluminum alloy clad material in which a core material is clad with an endothelial material on one surface and a sacrificial anode material is clad on the other surface, and the core material has Mn: 0.6-2.0%, Cu: 0.03- Al-Mn-Cu alloy containing 1.0% balance aluminum and inevitable impurities, endothelial material is Mn: 0.6-2.0%, Cu: 0.2-1.5% Al-Mn-Cu alloy containing the balance aluminum and inevitable impurities, and the sacrificial anode material contains Zn: 0.5-6.0%, Cu: 0.03-0.3% Al-Zn-Cu alloy consisting of the balance aluminum and inevitable impurities, and the Cu content of the core material, the endothelial material and the sacrificial anode material is (Cu content% of the sacrificial anode material) ≦ (Cu content% of the core material) ≤ (Cu content% of endothelial material%) Aluminum alloy clad material to.   The aluminum alloy clad material according to claim 4, wherein the core material further contains one or two of Si: 1.5% or less and Fe: 0.7% or less.   The aluminum alloy clad material according to claim 4 or 5, wherein the core material further contains Ti: 0.01 to 0.3%.   7. The aluminum alloy clad material according to claim 4, wherein the endothelial material further contains one or two of Si: 1.5% or less and Fe: 0.7% or less. .   8. The aluminum alloy clad material according to claim 4, wherein the endothelial material further contains Ti: 0.01 to 0.3%.   The sacrificial anode material further contains one or more of Si: 1.5% or less, Fe: 0.7% or less, and Mn: 1.5% or less. The aluminum alloy clad material according to any one of the above.   The aluminum alloy cladding material according to any one of claims 1 to 9 is formed into a tube so that the endothelial material is on the refrigerant passage side and the sacrificial anode material is on the atmosphere side, and aluminum fins are assembled and brazed to the tube. A heat exchanger characterized by comprising

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