JP2017057186A - First agent composition for aerosol type foamy oxidation hair dye - Google Patents

Abstract

PROBLEM TO BE SOLVED: To improve the effervescence of a first agent composition for aerosol type foamy oxidation hair dye in low temperature, and to provide aerosol type foamy oxidation hair dye compositions having improved finger-combing smoothness at the time of rinsing after application to the hair and an improved feel after drying, by comprising the first composition for aerosol type foamy oxidation hair dyes in their constitutions.SOLUTION: A first agent composition for aerosol type foamy oxidation hair dyes comprises (A) 2.0 to 10.0 mass% of an alkanol amide nonionic surfactant, (B) a nonionic surfactant with an HLB of 10.0 or more (except component (A)) and (C) alkanolamine in the undiluted composition of the first agent composition for aerosol type foamy oxidation hair dyes.SELECTED DRAWING: None

Description

The present invention relates to an aerosol-type foamy oxidative hair dye composition. More specifically, the improvement of foamability of the aerosol-type foam oxidation hair dye first agent composition under low temperature conditions and the inclusion of the aerosol-type foam oxidation hair dye first agent composition in the hair The present invention relates to an aerosol-type foamy oxidative hair dye composition that has improved finger touch during rinsing after application to the skin and improved feel after drying.

Conventionally, hair nail polish using an acid dye, color treatment using a basic dye, oxidative hair dye using an oxidation dye, and the like are known as hair dyes. Among them, the oxidation hair dye is most excellent in terms of high hair dyeing power and fastness, and the hair dye often refers to the oxidation hair dye.

As the form of the oxidative hair dye, a cream form or an emulsion form is the most common, but since a tool such as a brush is used for application, a certain level of skill is required from the user. Therefore, in addition to being more stretchable and easier to spread than creamy or milky dosage forms and being familiar with details, it can also be applied by hand without using tools such as brushes, so it can be applied to the entire hair. A foam-like dosage form that is easy to apply uniformly is used.

Examples of the foamed dosage form include a dosage form for foaming using a foaming agent, a dosage form for foaming by shaking in a container, and a dosage form for foaming by a pump former. Among them, the aerosol type dosage form can be used immediately by ejecting bubbles just by pressing the button on the aerosol container, and it is convenient because there is no need for foaming, and the amount of use can be adjusted freely. Since it can be used separately, it can be said that it is a preferable dosage form.

Since an oxidative hair dye performs hair dyeing using the reaction between an alkaline agent and an oxidant, the alkaline agent and the oxidant are preferably contained in separate agents. Therefore, in the case of an aerosol type, it is common to use a multi-agent type in which two or more agents are discharged and used at the same time. The agent containing an alkaline agent is the first agent, and the agent containing the oxidizing agent is the first agent. Often called two agents. In addition, each agent generally has a form in which the stock solution composition of each agent is separately contained in an aerosol container together with a propellant such as LPG.

The above-described aerosol-type foamy oxidative hair dye is a mechanism that foams by being vaporized when a propellant such as LPG is discharged. Since the propellant is less likely to vaporize under low temperature conditions, there is a problem that foaming is difficult to occur, and studies such as the following Patent Document 1 have been made.

JP 2010-280580 A

Oxidative hair dyes may stain the surroundings when used, and are often used in bathrooms. Therefore, it may be stored on a bathroom shelf or bathroom sink. It is not uncommon for bathrooms in winter to be around 5 ° C. Even if heating is used, the temperature of the contents does not rise immediately due to the structure of the aerosol, so there is still room for further study on the foamability under low temperature conditions.

In addition, ammonia is most often used as the first alkali agent. However, not only does the irritating odor cause discomfort to the user, but also irritating odor is generated in the surrounding area, which limits the use place and time of use. Therefore, an alkanolamine having almost no irritating odor is preferably used.

However, as described in Patent Document 1, the defoaming action of alkanolamine has been pointed out. Due to the defoaming action, the foamability under low temperature conditions may be deteriorated. For this reason, in the aerosol type foamy hair dye, the foamability under low temperature conditions of the first agent containing alkanolamine is a particular point to be examined.

Furthermore, as described in Patent Document 1, when hair is treated with a composition containing an alkanolamine, squeaking may occur and the feel may be reduced. For this reason, it was necessary to examine the touch after treatment of the aerosol-type foamy hair dye composition containing the first agent containing alkanolamine.

In addition, various surfactants are used for foaming, but it is also a problem that the fingering at the time of rinsing after application to hair deteriorates due to the influence of the surfactant.

Therefore, the present invention includes the aerosol-type foamy oxidation hair dye first agent composition in the composition together with the improvement of foamability under the low temperature conditions of the aerosol-type foam oxidation hair dye first agent composition. It is an object of the present invention to provide an aerosol-type foamy oxidative hair dye composition which has improved finger touch during rinsing after application to hair and improved feel after drying.

As a result of intensive studies to solve the above problems, the present inventor has found that (A) an alkanolamide type nonionic surfactant is added to the stock solution composition of the aerosol type foamy hair dye first composition. Aerosol type foamy oxidative hair containing 0% by mass to 10.0% by mass, (B) nonionic surfactant (excluding component (A)) with HLB of 10.0 or more, and (C) alkanolamine It discovered that the agent 1st agent composition can solve the said subject, and came to complete this invention.

The present invention improves the foaming property of the aerosol-type foamy oxidation hair dye first agent composition under low temperature conditions and includes the aerosol-type foamy oxidation hair dye first agent composition in the composition, so that the hair It is possible to provide an aerosol-type foamy oxidative hair dye composition having improved finger-handling during rinsing after application and improved feeling after drying.

Hereinafter, the present invention will be described in detail.

First, terms will be explained. In the present invention, the aerosol-type foamy oxidative hair dye composition is a multiple-agent type. For example, in the case of a two-agent type, it is composed of two agents, an aerosol-type foam oxidation hair dye first agent composition and an aerosol-type foam oxidation hair dye second agent composition. Although it may be composed of three or more agents, it is preferably a two-agent system.

In the present invention, the undiluted solution composition is a composition used to be housed in an aerosol container together with a propellant and discharged in the form of foam.

In the present invention, the aerosol-type foamy oxidative hair dye first agent composition is a state in which a stock solution composition containing an alkaline agent is housed in an aerosol container together with a propellant and can be discharged in the form of foam ( Hereinafter, this is simply referred to as “first agent”). The aerosol type foamy hair dye second agent composition is a state in which a stock solution composition containing an oxidizing agent is housed in an aerosol container together with a propellant and can be discharged in a foamy state (hereinafter referred to as “foam”). Simply referred to as "second agent").

In the present invention, the mixture refers to a mixture of a plurality of agents constituting the aerosol type foamy hair dye composition. The aerosol-type foamy oxidative hair dye composition disclosed in the present invention is often applied to the hair although a plurality of agents are discharged from the aerosol container at the time of use. It may also refer to a later broken foam mixture.

As for the method of applying each discharged agent or mixture to the hair, it is preferable that the agent or the mixture is once applied to the hair, applied to the hair, applied to the hair, or applied directly to the hair. When using hands here, it is preferable to wear gloves. The range to which the foam is applied may be the entire hair or only a specific part.

In the present invention, the nonionic surfactant HLB is an index indicating a hydrophilic-lipophilic balance, and there are various methods. Here, it is calculated using either “Griffin method” or “Handbook—Cosmetic / Formulation raw material—Revised edition, Nikko Chemicals Co., Ltd., 1977, pp. 854-855”. Is preferred. The “HLB value is 10.0 or more” means a surfactant having an HLB of 10.0 or more in either of the “Griffin method” and the “method based on measured values”.

Prior to the description of the present invention, the first agent, the second agent, the propellant, the aerosol container, and the mixing ratio of the first agent and the second agent will be described.

The dosage form of the stock solution composition of the first agent is not particularly limited as long as it can be discharged from an aerosol container in the form of foam, and examples thereof include a solubilized product, an emulsion, and a multi-layer separation type. In the case of an emulsion, it is easy to cause creaming due to the influence of the propellant, so it is easy to cause clogging and ejection failure, and in the case of a multi-layer separation type, it is likely to be uneven when stored with the propellant in an aerosol container. Solutes are preferred.

The first agent contains an alkaline agent in the stock solution composition.

The alkali agent in the stock solution composition of the first agent is not particularly limited, but ammonia, ammonium salt, alkanolamine, organic amines (2-amino-2-methyl-1,3-propanediol, guanidine, etc.), inorganic alkali (Sodium hydroxide, potassium hydroxide, etc.), carbonates (sodium carbonate, potassium carbonate, ammonium carbonate, ammonium hydrogen carbonate, etc.), basic amino acids (arginine, lysine, etc.) and their salts, etc. Or in combination of two or more kinds.

The pH of the first agent is preferably 8.0 to 12.0.

The first agent contains an oxidation dye in the stock composition.

The content of the oxidation dye in the stock solution composition of the first agent is preferably 0.01% by mass to 7.0% by mass.

The oxidation dye in the stock solution composition of the first agent is not particularly limited, but paraphenylenediamine, toluene-2,5-diamine, 5-aminoorthocresol, paraaminophenol, metaaminophenol, orthoaminophenol, 4-diaminophenoxyethanol. , 2-nitro-p-phenylenediamine, picramic acid, 2-amino-5-nitrophenol, resorcin, α-naphthol, paramethylaminophenol, 5- (2-hydroxyethylamino) -2-methylphenol and their A salt etc. are mentioned, It can contain individually by 1 type or in combination of 2 or more types as appropriate.

The first agent may further contain an acid dye, a basic dye, a natural dye, a disperse dye, etc. in addition to the oxidation dye in the stock solution composition, and may be used alone or in combination of two or more. be able to.

The acid dye in the stock solution composition of the first agent is not particularly limited, but Red No. 2, Red No. 3, Red No. 102, Red No. 104 (1), Red No. 105 (1), Red No. 106, Red No. 227, Red No. 230 (1), Yellow No. 4, Yellow No. 5, Yellow No. 202 (1), Yellow No. 202 (2), No. 203 Yellow, No. 205, No. 207 No. Color No. 402, Green No. 3, Green No. 204, Green No. 401, Purple No. 401, Blue No. 1, Blue No. 2, Blue No. 202, Brown No. 201, Black No. 401, etc. Two or more kinds can be contained in appropriate combination.

The basic dye in the stock solution composition of the first agent is not particularly limited, but Basic Blue 3, Basic Blue 6, Basic Blue 7, Basic Blue 9, Basic Blue 26, Basic Blue 41, Basic Blue 47, Basic Blue 99, Basic Brown 4, Basic Brown 16, Basic Brown 17, Basic Green 1, Basic Green 4, Basic Orange 1, Basic Orange 2, Basic Orange 31, Basic Red 1, Basic Red 2, Basic Red 22, Basic Red 46, Basic Red 51, Basic Red 76, Basic Red 118, Basic Violet 1, Basic Violet 3, Basic Violet 4, Basic Violet 10, Basic Violet 11: 1, Basic Violet 14, Basic Violet 16, Basic Yellow 11, Basic Yellow 28, Basic Yellow 57, Basic Yellow 87, and the like, and may be contained singly or in appropriate combination of two or more.

Natural dyes in the stock solution composition of the first agent are not particularly limited, but include cutinous pigments, turmeric pigments, anato pigments, copper chlorophyllin sodium, paprika pigments, lac pigments, etc., one kind alone or two or more kinds as appropriate It can contain in combination.

The disperse dye in the stock solution composition of the first agent is not particularly limited, but Disperse Black 9, Disperse Blue 1, Disperse Blue 3, Disperse Blue 7, Disperse Brown 4, Disperse Orange 3, Disperse Red 11, Disperse Red 15, Disperse Red 17, Disperse Violet 1, Disperse Violet 4, Disperse Violet 15, and the like. These can be used alone or in appropriate combination of two or more.

The dosage form of the stock solution composition of the second agent is not particularly limited as long as it can be discharged from the aerosol container in the form of foam, and examples thereof include a solubilized product, an emulsion, and a multilayer separation type.

The second agent contains an oxidizing agent in the stock solution composition.

The oxidizing agent in the stock solution composition of the second agent is not particularly limited, but hydrogen peroxide, urea peroxide, melamine peroxide, sodium percarbonate, potassium percarbonate, sodium perborate, potassium perborate, sodium peroxide , Potassium peroxide, magnesium peroxide, barium peroxide, calcium peroxide, strontium peroxide, sulfate hydrogen peroxide adduct, phosphate hydrogen peroxide adduct, pyrophosphate hydrogen peroxide adduct, etc. Can be used alone or in combination of two or more.

The content of the oxidizing agent in the stock solution composition of the second agent is preferably 0.1 to 15.0% by mass.

The pH of the second agent is preferably 1.0 to 5.0.

A well-known propellant can be used for a propellant. Examples thereof include liquefied gas such as LPG and dimethyl ether, and compressed gas such as carbon dioxide gas and nitrogen gas. Among these, liquefied gas is preferable. These 1 type (s) or 2 or more types can be used.

The mass ratio of the stock solution composition and the propellant contained in the aerosol container is preferably stock solution composition: propellant = 90: 10 to 98: 2. When the ratio of the propellant is higher than 90:10, the ejection momentum may be strongly scattered. When the ratio of the undiluted solution composition is higher than 98: 2, foaming is difficult regardless of normal temperature or low temperature conditions.

As the aerosol container, a well-known aerosol container can be used. Since it is necessary to mix the first agent and the second agent immediately before use, each stock solution composition is usually contained in a separate aerosol container. When discharged by the force of the propellant, bubbles are formed by the propellant vaporizing and expanding.

Moreover, the aerosol container which accommodates two inner bags and a connection member in one can, and discharges a mixture in foam form can also be used. In an aerosol container having an inner bag, an aerosol container containing the stock solution composition of each agent and a propellant in the inner bag can also be used.

The material and internal pressure of the aerosol container can be appropriately selected according to the type of alkali agent, oxidizing agent, propellant, and method for storing the stock solution composition.

The mixing ratio of the plurality of agents including the first agent and the second agent is not particularly limited, but the first agent: second agent = 1: 5 to 5: 1 is preferable. In cases other than the first agent: second agent = 1: 5 to 5: 1, the hair dyeing effect may not be obtained.

The pH of the mixture of the first agent and the second agent is preferably 7.0 to 12.0.

The first agent of the present invention contains (A) an alkanolamide type nonionic surfactant in its stock solution composition. This is because when an aerosol container is filled with both the stock solution composition and LPG, LPG is dissolved in the stock solution composition, thereby improving the foaming property under low temperature conditions and improving the fingering during rinsing after application. There is an effect and the effect which improves the touch after drying.

2.0 mass%-10.0 mass% are preferable, and, as for content in the stock solution composition of the said (A) component of this invention, 3.5 mass%-8.0 mass% are more preferable. When the amount is less than 2.0% by mass, the foamability under low temperature conditions may be deteriorated, and even if the content exceeds 10.0% by mass, the effect is not changed.

Although the said (A) component of this invention is not specifically limited, A diethanolamide type, a monoethanolamide type, a monoisopropanolamide type etc. are mentioned, It can contain individually by 1 type or in combination of 2 or more types. Among these, it is preferable to contain a diethanolamide type in terms of good fingering during rinsing.

The diethanolamide type of the component (A) of the present invention is not particularly limited, but palm oil fatty acid diethanolamide, palm kernel fatty acid diethanolamide, lauric acid diethanolamide, myristic acid diethanolamide, stearic acid diethanolamide, oleic acid diethanolamide Etc., and may be contained singly or in appropriate combination of two or more. Among these, it is preferable to contain coconut oil fatty acid diethanolamide in terms of good feel after drying.

The 1st agent of this invention contains the nonionic surfactant (except (A) component) whose (B) HLB is 10.0 or more in the stock solution composition. This has the effect of dissolving the component (A) in the stock composition.

The HLB of the component (B) of the present invention is preferably 10.0 or more, more preferably 12.0 or more, and most preferably 15.5 or more. When the HLB is less than 10.0, the component (A) may not be sufficiently dissolved and may be separated.

1.0 mass%-7.0 mass% are preferable, as for content in the stock solution composition of the said (B) component of this invention, 2.0 mass%-6.0 mass% are more preferable, 2.5 A mass% to 5.0 mass% is most preferred. When the amount is less than 1.0% by mass, the component (A) may not be sufficiently dissolved and may be separated. When the amount exceeds 7.0% by mass, the fingering during rinsing may be poor.

The component (B) of the present invention is not particularly limited, but polyoxyalkylene alkyl ether, propylene glycol fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, Polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbit fatty acid ester, polyoxyethylene lanolin, polyoxyethylene lanolin alcohol, polyoxyethylene sorbit beeswax, polyoxyethylene hydrogenated castor oil, polyoxyethylene sterol, polyoxyethylene hydrogenated sterol, Hydrophilic among polyethylene glycol fatty acid ester, alkyl glucoside, polyoxyalkylene alkyl glucoside, etc. May be mentioned those can contain singly or in combination of two or more as appropriate. Among these, it is preferable to contain polyoxyalkylene alkyl ether in terms of good stability in alkalinity.

The polyoxyalkylene alkyl ether of the component (B) of the present invention is not particularly limited, and examples thereof include polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, etc., alone or in combination of two or more. Can be contained. Among the above, polyoxyethylene alkyl ether is preferable from the viewpoint of good solubility of the component (A).

The first agent of the present invention contains (C) an alkanolamine in its stock solution composition. This has the effect of promoting the oxidative polymerization of the oxidative dye by reacting with the oxidizing agent, the effect of swelling the hair to increase the permeability, and the effect of dissolving the component (A) in the stock solution composition.

It is preferable that content in the undiluted | stock solution composition of the said (C) component of this invention is 0.5 mass%-10.0 mass%. When the amount is less than 0.5% by mass, the component (A) may not be sufficiently dissolved and may be separated. If it exceeds 10.0% by mass, the hair may be damaged.

The component (C) of the present invention is not particularly limited, but monoethanolamine, diethanolamine, triethanolamine, monopropanolamine, isopropanolamine, dipropanolamine, tripropanolamine, 2-amino-2-methyl-1,3 -Propanediol, 2-amino-2-methyl-1-propanol, 2-amino-2-hydroxymethyl-1,3-propanediol, and the like are included, alone or in combination of two or more. be able to. Among these, it is preferable to contain monoethanolamine in terms of high hair dyeing power.

The 1st agent of this invention may use together alkali agents other than the said (C) component in the stock solution composition in order to assist hair dyeing power and decoloring power. Alkaline agents other than the component (C) are not particularly limited, but ammonia, ammonium salts, organic amines (2-amino-2-methyl-1,3-propanediol, guanidine, etc.), inorganic alkalis (sodium hydroxide, Potassium hydroxide, etc.), carbonates (sodium carbonate, potassium carbonate, ammonium carbonate, ammonium hydrogen carbonate, etc.), basic amino acids (arginine, lysine, etc.) and their salts, etc., one kind alone or two or more kinds Can be contained in appropriate combinations. Among these, it is preferable to contain ammonia in terms of high hair dyeing power.

The first agent of the present invention may contain any component as a component that is usually used in hair dyes in addition to the above components, as long as the effects of the present invention are not impaired. For example, water, a water-soluble polymer containing hydroxyethyl cellulose, a higher alcohol, a solvent containing 1,3-butylene glycol, glycerin, propylene glycol, a nonionic surfactant other than the component (A) and the component (B), Anionic surfactants, cationic surfactants, amphoteric surfactants, fatty acids, thickeners, proteins, amino acids, fats and oils, waxes, silicones, hydrocarbons including liquid paraffin, sorbitol, maltose, etc. Saccharides, hydrolyzed proteins, protein derivatives such as silylated proteins, parabens, antiseptic ingredients such as sodium benzoate, EDTA-2Na, diethylenetriaminepentaacetic acid, chelating ingredients such as hydroxyethanediphosphonic acid, phenacetin, 8-hydroxyquinoline, Acetanilide, phenoxyethanol 1 selected from stable components such as sodium pyrophosphate, barbituric acid, uric acid and tannic acid, pH adjusting components, antioxidant components such as sodium sulfite, plant or herbal extracts, vitamins containing ascorbic acids, flavorings, etc. You may contain the above. For example, you may contain 1 or more types chosen from what is listed in "Quasi-drug raw material specification 2006 integrated version" (Pharmaceutical daily report company).

EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited only to these examples.

In the evaluation test shown in the present invention, various experimental results carried out while variously changing the components contained in the stock solution composition and the contents thereof are shown below. In addition, the unit which shows content of each component in a stock solution composition is all the mass%, the content of each component is the numerical value converted into a pure part, the ratio shows mass ratio, and this was prepared by the usual method.

In the evaluation test shown in the present invention, the displayed HLB value is calculated by the “method using actual measurement values”.

The stock solution composition of each example was filled into an aerosol container equipped with a simultaneous discharge mechanism, and each was filled with a propellant (LPG) at a mass ratio shown in the table to prepare a first agent of each example.

In the evaluation test shown in the present invention, “foaming under low temperature conditions”, “passing through fingers during rinsing”, and “feel after drying” were evaluated.

In the evaluation test shown in the present invention, “foaming under a low temperature condition” means that the first agent is stored overnight in a thermostatic bath set at 5 ° C., taken out from the thermostatic bath, shaken up and down 20 times, and then foamed. The appearance was evaluated according to the following evaluation criteria.

Evaluation criteria for “foaming under low-temperature conditions” ◎: Completely foamed ○: Almost foamed but slightly liquid is observed Δ: Liquid and foam are mixed x: Evaluation is liquid: Excellent or better I reckon

In the evaluation test shown in the present invention, a “stock solution at the time of rinsing” and “feel after drying” were separately prepared as a stock solution composition of the second agent for evaluation. The stock solution composition is shown in Table 1. The prepared stock solution composition was filled into an aerosol container equipped with a simultaneous discharge mechanism, and a propellant (LPG) was filled at a mass ratio shown in the table to prepare a second agent.

In the evaluation test shown in the present invention, the mixing ratio of the first agent and the second agent was set to 1: 1.

“Finger rinsing” and “feel after drying” were actually used by 10 professional panelists, and the rinsing fingers and feeling after drying were evaluated according to the following evaluation criteria. Was rounded off to the first decimal place. In addition, the method of use in this case is that after the first agent and the second agent are separately ejected from an aerosol container equipped with a simultaneous ejection mechanism, they are mixed before being applied to the hair or when being applied to the hair. It was left for 5 minutes after application and rinsed with water at 40 ° C., and the fingering at that time was evaluated as “fingering during rinsing”. After rinsing, the hair was dried with a drier, and the finger passage when the hot air disappeared was evaluated as “feel after drying”. The coating amount was 40 g for the first agent and the second agent, respectively, for a total of 80 g.

Evaluation criteria 5 for “Fingering during rinsing”: Fingering is particularly good 4: Fingering is good 3: Fingering is no problem 2: Fingering is a little bad 1: Fingering is bad Evaluation: Good 3 or better Consider

Evaluation criteria 5 for “feel after drying” 5: fingering is particularly good 4: fingering is good 3: fingering is not problematic 2: fingering is slightly bad 1: fingering is bad Evaluation: 3 or more is good I reckon

In the evaluation test shown in the present invention, it is judged that the present invention was able to be carried out only with good items in all items of “foaming under low temperature conditions”, “passing through fingers during rinsing”, and “feel after drying”.

<First evaluation test>
In the 1st evaluation test, it evaluated about the 1st agent which changed variously the kind and content of said (A) component. Table 2 shows the components and contents of the stock solution composition, the ratio of the stock solution composition: propellant, and the evaluation results.

<Second evaluation test>
In the 2nd evaluation test, it evaluated about the 1st agent which changed variously the kind and content of said (B) component. Table 3 shows the components and contents of the stock solution composition, the ratio of the stock solution composition: propellant, and the evaluation results.

<Third evaluation test>
In the 3rd evaluation test, it evaluated about the 1st agent which changed variously the kind and content of said (C) component. Table 4 shows the components and contents of the stock solution composition, the ratio of the stock solution composition: propellant, and the evaluation results.

<Fourth evaluation test>
In the 4th evaluation test, the fingering at the time of the rinse of the component composition difference of the stock solution composition of the 2nd agent was evaluated. The first agent for evaluation is shown in Example 27 of Table 5, and the second agent for evaluation used is that shown in Table 1 and that shown in Table 6. The evaluation results are shown in Table 7.

As shown in Table 7, it can be seen that even when the component composition of the stock solution composition of the second agent is changed, the touch after rinsing and the feel after drying are good, and the first agent of the present invention is included in the composition. It can be seen that the finger touch at the time and the feeling after drying can be improved.

The present invention improves the foaming property of the aerosol-type foamy oxidation hair dye first agent composition under low temperature conditions and includes the aerosol-type foamy oxidation hair dye first agent composition in the composition, so that the hair It is possible to provide an aerosol-type foamy oxidative hair dye first-agent composition having improved feeling after fingering and rinsing after application.

Claims (6)

(A) 2.0 mass% to 10.0 mass% of (A) alkanolamide type nonionic surfactant in the stock solution composition of the aerosol type foamy hair dye 1st composition, (B) HLB is 10 Aerosol-type foamy oxidation hair dye 1st agent composition containing 0.0 or more nonionic surfactant (except for component (A)) and (C) alkanolamine. The first component composition of an aerosol-type foamy oxidative hair dye according to claim 1, wherein the component (A) is a diethanolamide type. The aerosol-type foamy oxidative hair dye 1 of Claim 1 or 2 whose content in the undiluted | stock solution composition of the said (B) component is 1.0 mass%-7.0 mass%. Agent composition. The said foam (B) component is a polyoxyethylene alkyl ether, The aerosol type foamy oxidation hair dye 1st agent composition as described in any one of Claim 1 to 3 characterized by the above-mentioned. The aerosol-type foam oxidation according to any one of claims 1 to 4, wherein the content of the component (C) in the stock solution composition is 0.5 mass% to 10.0 mass%. Hair dye first agent composition. 6. The aerosol-type foamy oxidative hair dye first composition according to any one of claims 1 to 5, wherein the component (C) is monoethanolamine.