JP2016509248A - ラベル - Google Patents
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- JP2016509248A JP2016509248A JP2015548761A JP2015548761A JP2016509248A JP 2016509248 A JP2016509248 A JP 2016509248A JP 2015548761 A JP2015548761 A JP 2015548761A JP 2015548761 A JP2015548761 A JP 2015548761A JP 2016509248 A JP2016509248 A JP 2016509248A
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- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
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- G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
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- B41M5/28—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using thermochromic compounds or layers containing liquid crystals, microcapsules, bleachable dyes or heat- decomposable compounds, e.g. gas- liberating
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- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
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- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
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- B41M5/46—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by the light-to-heat converting means; characterised by the heat or radiation filtering or absorbing means or layers
- B41M5/465—Infrared radiation-absorbing materials, e.g. dyes, metals, silicates, C black
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- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
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- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/28—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using thermochromic compounds or layers containing liquid crystals, microcapsules, bleachable dyes or heat- decomposable compounds, e.g. gas- liberating
- B41M5/282—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using thermochromic compounds or layers containing liquid crystals, microcapsules, bleachable dyes or heat- decomposable compounds, e.g. gas- liberating using thermochromic compounds
- B41M5/284—Organic thermochromic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
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- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
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- G09F3/02—Forms or constructions
- G09F2003/0257—Multilayer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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Abstract
Description
中心複合計画を用いて、特定の応答(光沢、ヘーズ、鮮明度、透過率、静摩擦係数、動的摩擦係数およびLab値)に対する3つの変数(レーザー書込み可能な顔料の粒径、レーザー書込み可能な顔料の濃度、およびコーティングの厚さ)の効果を示した。中心複合計画は、色域および光学的特性に関する変数を最適化するためにも使用した。
y=b0+b1 *x1+...+bk *xk+b12 *x1 *x2+b13 *x1 *x3+...+bk-1,k *xk-1 *xk+b11 *x1 2+...+bkk *xk 2
に従った応答表面の推定(当てはめ)に属し、上記式により、
(1)因子x1、...、xkの主要な効果、
(2)これらの因子の相互作用(x1 *x2、x1 *x3、...、xk-1 *xk)、および
(3)これらの因子の二次成分(x1 **2、...、xk **2)
を含む従属変数yの観測値にモデルを当てはめる。
コーティングの基礎配合物を3つのステップで作製した。
1. プリミックスまたは粒状物を作製した後、40ミクロンのD95になるまで粉砕した。
2. 次いで、D50が実験設計用に所望のサイズになるようにプリミックスを再び粉砕した。
3. 実験設計に従って、レットダウン段階により、コーティング中の顔料の濃度を制御した。
応答最適化を実施して、実験のデータを基準にして最適な粒径、濃度および厚さを判定した。
サイズ =95.9430
濃度 =58.1313
厚さ =2.59001
予測応答
光沢 =88.0482 望ましさ=0.473421
ヘーズ =3.0247 望ましさ=0.775029
青ref l =22.1718 望ましさ=0.778282
赤refl l=26.2476 望ましさ=0.737524
赤ref a =13.8736 望ましさ=0.043041
青ref b =−12.5885 望ましさ=0.028761
上述したコーティング組成物および手順を用いて、被覆された製品を作製した
下記の手順に従って、摩擦係数を測定した。
1. 導入
1.1 フィルムの摩擦(滑り)係数は、印刷機および包装機械の性能に顕著に影響を与え得る、非常に重要な特性である。
1.2 試験方法は、ASTM D1894に基づいている。
2. 装置
2.1 Instron Tensiometer Model 1011。
2.2 低摩擦型滑車組立体が取り付けられた滑り用台座。
2.3 ソリ(6.5cm×6.5cm×0.5cm、重量は約200グラム)。
2.4 ソリ用のヒモ(長さ70cm、伸長性はなし)。
2.5 (ソリ用フィルム試料の)切断処理テンプレート20cm×6.5cm。
3. 試薬
なし。
4. 試験方法
4.1 機器設定
4.1.1 Instronのスイッチを入れる。
4.1.2 下記の設定が正しいかを点検する:
単位=メートル
荷重範囲=500グラム
トランデューサー=5000グラム
クロスヘッド速度=125mm/min
チャート式記録装置速度=200mm/min(20mm×10)
測定範囲における変位=500グラム
摩擦(滑り)係数の測定
4.1.3 金属台座の表面が清潔であることを保証する。
4.1.4 台座の各端部の幅いっぱいに両面テープを貼ってフィルム試料を平坦に保ち、ヒダがないようにする。
4.2 手順
フィルム/金属
4.2.1 テンプレートを用いて、フィルムの試料を(MDに)に切断し、(両面テープを用いて)ソリに取り付ける。フィルムがヒダまたはシワを含まないことを保証する。
4.2.2 金属台座の最上面が清潔であることを保証する。
4.2.3 ヒモを低摩擦型滑車に巻いて、ソリに取り付ける。
4.2.4 ソリを台座上に置き、わずかな程度のたるみがヒモにあることを確かめる。ソリは、台座上に置いてからすぐに動かすべきでない。
4.2.5 チャート式記録装置を始動し、「Instron」クロスヘッドの「up」ボタンを押す。
4.2.6 試験が完了したら、チャートを停止させ、クロスヘッドを元々の位置に戻す。
4.2.7 フィルム試料を廃棄する。試料は、2回以上使用すべきでない。
フィルム/フィルム
4.2.8 テンプレートを用いて、フィルムの試料を(MDに)切断し、(両面テープを用いて)ソリに取り付ける。
4.2.9 試料を約15cm(TD)および35cm(MD)切断し、両面テープを用いて金属台座に取り付ける。フィルムがヒダまたはシワを含まないことを保証する。
4.2.10 ここからは、ステップ4.2.3.から4.2.7.に従う
5. 計算
5.1 チャートの初期最大表示値は、静摩擦係数(u s)である。
u s=記録された初期最大値(グラム)/ソリ重量(グラム)
5.2 2つの表面が互いに一様に滑っている間に得られた平均表示値が、動摩擦係数(u d)である。
u d=記録された平均値(グラム)/ソリ重量(グラム)
Claims (34)
- レーザーマーキング可能なライナーレス型ラベルストック。
- レーザーマーキング前に
a) 透明であり、かつ/または
b) 無色である、
請求項1に記載のラベルストック。 - レーザー放射への曝露時に、少なくとも1つの観測可能または測定可能な特徴において、熱分解によらない化学的または分子的で識別可能な変化を受ける、請求項1または請求項2に記載のラベルストック。
- 第1のレーザー放射への曝露時に、少なくとも1つの観測可能または測定可能な特徴において、第1の熱分解によらない化学的または分子的で識別可能な変化を受け、第2のレーザー放射への曝露時に、少なくとも1つの観測可能または測定可能な特徴において、第2の熱分解によらない化学的または分子的で識別可能な変化を受ける、請求項3に記載のラベルストック。
- 観測可能または測定可能な特徴が、フィルムの色を含む、請求項3または請求項4に記載のラベルストック。
- レーザーマーキング可能な層および粘着層および任意選択によりさらに層を含む、請求項1から5のいずれか一項に記載のラベルストック。
- ポリマーフィルムまたはバイオポリマーフィルムを含む、請求項1から6のいずれか一項に記載のラベルストック。
- UV遮断成分を含む、全面的UV保護を有する請求項1から7のいずれかに記載のラベルストック。
- UV遮断成分が、UV−A放射およびUV−B放射を選択的に遮断する、請求項8に記載のラベルストック。
- UV遮断成分が、UV−C放射を選択的には遮断せず、任意選択によりnIR放射を選択的には遮断しない、請求項8または請求項9に記載のラベルストック。
- 1つの層またはコーティング中のレーザーマーキング可能な成分、および異なる層またはコーティング中のUV遮断成分を含む、請求項8から10のいずれかに記載のラベルストック。
- レーザーマーキング可能な成分が、レーザー書込み可能な顔料を含み、レーザー書込み可能な顔料粒子の少なくとも50%が、約1ミクロン未満の粒径を有する、請求項1から11のいずれかに記載のラベルストック。
- レーザーマーキング可能な成分が、レーザー書込み可能な顔料を含み、レーザー書込み可能な顔料粒子の平均粒径が、約100nm以下である、請求項1から12のいずれかに記載のラベルストック。
- レーザーマーキング可能な成分が、ラベルストック基材の中または上のコーティングまたは層中に存在する、請求項1から13のいずれかに記載のラベルストック。
- レーザーマーキング可能な成分が、レーザー書込み可能なコーティングまたは層中に存在し、層またはコーティングの厚さが、約10ミクロン以下である、請求項1から14のいずれかに記載のラベルストック。
- 厚さが、約2ミクロンから約4ミクロンまでである、請求項15に記載のラベルストック。
- 70超の光沢度の光沢(45°)を有する、請求項1から16のいずれかに記載のラベルストック。
- 85超の光沢度の光沢(45°)を有する、請求項1から17のいずれかに記載のラベルストック。
- レーザー照射後の製品が、約0.4から約0.9の間の摩擦係数を有する、請求項1から18のいずれかに記載のラベルストック。
- レーザー書込み可能であり、かつインク印刷可能でもある、請求項1から19のいずれかに記載のラベルストック。
- 有機レーザー書込み可能な顔料を含む、請求項1から20のいずれかに記載のラベルストック。
- レーザー書込み可能な不飽和有機顔料を含む、請求項21に記載のラベルストック。
- レーザー書込み可能な有機顔料が、少なくとも1つのspまたはsp2混成した炭素原子を有する、請求項22に記載のラベルストック。
- レーザー書込み可能な有機顔料が、エチレン性不飽和および/またはアセチレン性不飽和を含む、請求項23に記載のラベルストック。
- ジアセチレン部分を含むレーザー書込み可能な顔料を含む、請求項24に記載のラベルストック。
- インジウムスズ酸化物をさらに含む、請求項1から25のいずれかに記載のラベルストック。
- Pergascript Black 1Cを含む、請求項1から26のいずれかに記載のラベルストック。
- SABoTBAをさらに含む、請求項1から27のいずれかに記載のラベルストック。
- 請求項1から28に記載のラベルストックからのラベル。
- 請求項1から29のいずれかに記載のラベルまたはラベルストックを含む、包装。
- 請求項1から30のいずれかに記載のラベルによってラベリングされた、製品。
- フィルムの一方の側に剥離コーティングまたは剥離層を設け、フィルムの他方の側に接着剤を設けること、および請求項1から31のいずれかに記載のレーザー書込み可能な顔料をラベルストックの内部に、任意選択により剥離コーティングまたは剥離層の内部に組み込むことを含む、請求項1から31のいずれかに記載のライナーレス型ラベルストックを製造する方法。
- 品物上に画像、情報またはその他の視覚的特性をもたらすための、請求項1から32のいずれかに記載のレーザー書込み可能なライナーレス型ラベルストックまたはラベルの使用。
- 請求項1から33のいずれかに記載のライナーレス型ラベルストックを調製または加工するための、装置。
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PCT/GB2013/053368 WO2014096837A2 (en) | 2012-12-19 | 2013-12-19 | Label |
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JP2015548761A Pending JP2016509248A (ja) | 2012-12-19 | 2013-12-19 | ラベル |
JP2017195575A Withdrawn JP2018028679A (ja) | 2012-12-19 | 2017-10-06 | ラベル |
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EP (1) | EP2934900A2 (ja) |
JP (2) | JP2016509248A (ja) |
GB (1) | GB201222961D0 (ja) |
WO (1) | WO2014096837A2 (ja) |
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DE102016113656A1 (de) * | 2016-07-25 | 2018-01-25 | Infineon Technologies Ag | Elektronisches identifikationsdokument |
EP3541884A1 (en) * | 2016-11-17 | 2019-09-25 | UPM Raflatac Oy | A linerless thermal label web and labels produced thereof |
US10580329B2 (en) * | 2016-11-23 | 2020-03-03 | Precision Dynamics Corporation | Stabilizing a detachable item on a printable substrate |
FI128112B (en) * | 2017-12-08 | 2019-10-15 | Upm Raflatac Oy | Package closure |
US11441047B2 (en) * | 2018-12-19 | 2022-09-13 | Xerox Corporation | Color changing ink jet ink with tunable transition stimuli |
US20220281254A1 (en) * | 2019-08-08 | 2022-09-08 | Agfa-Gevaert Nv | Laser Markable Label and Tag |
KR20220086602A (ko) * | 2019-10-25 | 2022-06-23 | 도요보 가부시키가이샤 | 레이저 인자 가능한 필름 및 그것을 사용한 포장체 |
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Also Published As
Publication number | Publication date |
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JP2018028679A (ja) | 2018-02-22 |
US9916777B2 (en) | 2018-03-13 |
US20150294602A1 (en) | 2015-10-15 |
GB201222961D0 (en) | 2013-01-30 |
EP2934900A2 (en) | 2015-10-28 |
WO2014096837A3 (en) | 2014-08-14 |
WO2014096837A2 (en) | 2014-06-26 |
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