JP2016219447A - Voltage holding ratio specification device of electric double layer capacitor and voltage holding ratio specification method of electric double layer capacitor - Google Patents

Voltage holding ratio specification device of electric double layer capacitor and voltage holding ratio specification method of electric double layer capacitor Download PDF

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JP2016219447A
JP2016219447A JP2015098765A JP2015098765A JP2016219447A JP 2016219447 A JP2016219447 A JP 2016219447A JP 2015098765 A JP2015098765 A JP 2015098765A JP 2015098765 A JP2015098765 A JP 2015098765A JP 2016219447 A JP2016219447 A JP 2016219447A
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holding ratio
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electric double
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JP6625345B2 (en
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小林 健二
Kenji Kobayashi
健二 小林
池田 正和
Masakazu Ikeda
正和 池田
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Hioki EE Corp
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Abstract

PROBLEM TO BE SOLVED: To shorten the time required for specifying the voltage holding ratio of an electric double layer capacitor.SOLUTION: A voltage holding ratio specification device of an electric double layer capacitor includes a charging section 2 performing constant-voltage charging for an inspection object capacitor 11 charged to a rated voltage with a rated voltage, a current detector 3 for detecting a charging current Ich flowing through the capacitor 11 in a constant-voltage charged state with the rated voltage, and outputting while converting into a voltage signal Vi, and a processing section 5 executing the specification processing for acquiring the features of a transient current waveform in a transient period T1 of the charging current Ich, which makes a transition to a steady period where the current value becomes substantially constant, after passing the transient period where the current value decreases gradually in the constant-voltage charged state, based on the voltage signal Vi, and specifying the voltage holding ratio of the capacitor 11 based on the features thus acquired.SELECTED DRAWING: Figure 1

Description

本発明は、電気二重層キャパシタの電圧保持率を特定する電圧保持率特定装置および電圧保持率特定方法に関するものである。   The present invention relates to a voltage holding ratio specifying device and a voltage holding ratio specifying method for specifying a voltage holding ratio of an electric double layer capacitor.

この種の電圧保持率特定装置の一例として、下記の特許文献1に開示された漏れ電流の検査システムが知られている。なお、後述するように、漏れ電流は電気二重層キャパシタの充電電圧の減少比率にほぼ比例し、したがって、漏れ電流は電気二重層キャパシタの充電電圧の保持率(電圧保持率)にほぼ反比例することから、この漏れ電流の検査システムは、電圧保持率を特定する電圧保持率特定装置でもある。   As an example of this type of voltage holding ratio specifying device, a leakage current inspection system disclosed in Patent Document 1 below is known. As will be described later, the leakage current is almost proportional to the reduction rate of the charging voltage of the electric double layer capacitor, and therefore the leakage current is almost inversely proportional to the charging voltage holding rate (voltage holding rate) of the electric double layer capacitor. Therefore, this leakage current inspection system is also a voltage holding ratio specifying device for specifying a voltage holding ratio.

この漏れ電流の検査システム(電圧保持率特定装置)は、電気二重層キャパシタ(以下、単にキャパシタともいう)を充放電する充放電装置と、充放電装置にデータ通信回線を通じて接続し充放電装置を制御する制御装置とを備えたキャパシタの漏れ電流の検査システムである。この検査システムでは、充放電装置は、設定時間の間、設定電圧を保ちながらキャパシタを充電しつつキャパシタに流れる電流(緩和充電時に流れる電流)を測定し、制御装置は、充放電装置から電流のデータを取得して、上記の設定時間の間にキャパシタに流れる定常電流を演算する。   This leakage current inspection system (voltage holding ratio specifying device) includes a charge / discharge device for charging / discharging an electric double layer capacitor (hereinafter also simply referred to as a capacitor), and a charge / discharge device connected to the charge / discharge device through a data communication line. A capacitor leakage current inspection system including a control device for controlling. In this inspection system, the charging / discharging device measures the current flowing through the capacitor while charging the capacitor while maintaining the set voltage for a set time (current flowing during relaxed charging). Data is acquired and the steady current flowing in the capacitor during the set time is calculated.

この場合、この緩和充電時に流れる定常電流は、漏れ電流と密接な関係を持ち、従来の放置試験(キャパシタを一定電圧まで充電し、そのまま一定時間(JIS D1401では、72時間(3日間))放置した後の電圧を充電完了直後の電圧と比較して漏れ電流の程度を間接的に把握する試験)において漏れ電流の評価に用いられてきた自己放電時のキャパシタの充電電圧の減少比率にほぼ比例することが確認されている。したがって、この検査システムでは、緩和充電時に流れている定常電流を測定することで、漏れ電流を評価することが可能となっている。なお、この検査システムでは、この評価に際して、算出した定常電流を、従来の放置試験において漏れ電流の評価に用いられてきた充電電圧の減少比率に換算することも可能となっている。   In this case, the steady-state current that flows during this relaxed charge has a close relationship with the leakage current, and the conventional neglect test (capacitor is charged to a certain voltage and left as it is for a certain time (72 hours (3 days in JIS D1401)). Compared with the voltage immediately after the charging is completed, the leakage current is evaluated in an indirect manner), which is almost proportional to the decrease rate of the capacitor charging voltage during self-discharge, which has been used to evaluate the leakage current. It has been confirmed that Therefore, in this inspection system, it is possible to evaluate the leakage current by measuring the steady current flowing during relaxation charging. In this inspection system, it is possible to convert the calculated steady-state current into the reduction rate of the charging voltage that has been used for the leakage current evaluation in the conventional standing test in this evaluation.

この漏れ電流の検査システムは、上記のようにして漏れ電流を評価するものであり、従来のように電気二重層キャパシタの充電電圧の低下の度合いから漏れ電流を間接的に測定するものではなく、緩和充電時の定常電流に基づいて判断するものであることから、この漏れ電流の検査システムによれば、キャパシタの漏れ電流(つまり、充電電圧の減少比率)、ひいては充電電圧の保持率を検査する際の試験時間を短縮することが可能となっている。   This leakage current inspection system evaluates the leakage current as described above, and does not indirectly measure the leakage current from the degree of decrease in the charging voltage of the electric double layer capacitor as in the past. Since the determination is based on the steady-state current at the time of relaxation charging, according to this leakage current inspection system, the leakage current of the capacitor (that is, the reduction ratio of the charging voltage), and thus the charging voltage holding ratio, is inspected. It is possible to shorten the test time.

特開2003−133189号公報(第2−4頁、第1−2図)JP 2003-133189 A (page 2-4, FIG. 1-2)

ところが、上記した漏れ電流の検査システム(電圧保持率特定装置)には、以下のような解決すべき課題が存在している。すなわち、近年では、キャパシタの漏れ電流についての検査(減少比率についての検査)に要する時間、つまり、等価的にはキャパシタの電圧保持率についての検査に要する時間の更なる短縮が望まれている。しかしながら、この電圧保持率特定装置では、定常電流を測定しなければならないために、緩和充電時に流れる電流が定常状態となるまで常に待つ必要があることに起因して、電圧保持率の特定に要する時間の更なる短縮が難しいという解決すべき課題が存在している。   However, the above leakage current inspection system (voltage holding ratio specifying device) has the following problems to be solved. That is, in recent years, it has been desired to further shorten the time required for the inspection of the leakage current of the capacitor (inspection for the reduction ratio), that is, equivalently, the time required for the inspection of the voltage holding ratio of the capacitor. However, in this voltage holding ratio specifying device, since it is necessary to measure a steady current, it is necessary to always wait until the current flowing at the time of relaxation charging reaches a steady state, so that it is necessary to specify the voltage holding ratio. There is a problem to be solved that it is difficult to further reduce the time.

本発明は、かかる課題を解決するためになされたものであり、電気二重層キャパシタの電圧保持率の特定に要する時間をさらに短縮し得る電気二重層キャパシタの電圧保持率特定装置および電気二重層キャパシタの電圧保持率特定方法を提供することを主目的とする。   The present invention has been made to solve such a problem, and a voltage holding ratio specifying device for an electric double layer capacitor and an electric double layer capacitor capable of further shortening the time required for specifying the voltage holding ratio of the electric double layer capacitor The main purpose is to provide a method for specifying the voltage holding ratio.

上記目的を達成すべく請求項1記載の電気二重層キャパシタの電圧保持率特定装置は、定格電圧に充電されている検査対象の電気二重層キャパシタに対して当該定格電圧で定電圧充電する充電部と、前記定格電圧での定電圧充電状態において前記電気二重層キャパシタに流れる電流を検出すると共に電圧信号に変換して出力する電流検出部と、前記定電圧充電状態において電流値が徐々に減少する過渡期間を経た後に前記電流値がほぼ一定となる定常期間に移行する前記電流の当該過渡期間での過渡電流波形の特徴を前記電圧信号に基づいて取得すると共に、当該取得した特徴に基づいて前記電気二重層キャパシタの電圧保持率を特定する特定処理を実行する処理部とを備えている。   In order to achieve the above object, a voltage holding ratio specifying device for an electric double layer capacitor according to claim 1 is a charging unit that charges the electric double layer capacitor to be inspected at a rated voltage at a constant voltage with the rated voltage. A current detection unit that detects a current flowing through the electric double layer capacitor in the constant voltage charging state at the rated voltage, converts the current into a voltage signal, and outputs the voltage signal; and a current value gradually decreases in the constant voltage charging state. Based on the voltage signal, the characteristics of the transient current waveform in the transient period of the current that transitions to a steady period in which the current value becomes substantially constant after passing through the transient period, and based on the acquired characteristics And a processing unit that executes specific processing for specifying the voltage holding ratio of the electric double layer capacitor.

請求項2記載の電気二重層キャパシタの電圧保持率特定装置は、請求項1記載の電気二重層キャパシタの電圧保持率特定装置において、前記検査対象と同じ仕様の複数の電気二重層キャパシタを前記特徴の類似するもの同士にグループ化して生成した複数のグループと、当該複数のグループのそれぞれについてのグループ化した前記電気二重層キャパシタの前記電圧保持率が含まれる保持率範囲とを関連付ける関連付け情報が記憶された記憶部を有し、前記処理部は、前記特定処理において、前記関連付け情報を参照することにより、前記取得した特徴に関連付けされた前記保持率範囲内に前記検査対象の電気二重層キャパシタの前記電圧保持率が含まれると特定する。   The voltage holding ratio specifying device for an electric double layer capacitor according to claim 2 is the voltage holding ratio specifying device for an electric double layer capacitor according to claim 1, wherein a plurality of electric double layer capacitors having the same specifications as the inspection object are the characteristics. Is stored associating information for associating a plurality of groups generated by grouping together similar ones and a holding ratio range including the voltage holding ratio of the electric double layer capacitor grouped for each of the plurality of groups The processing unit refers to the association information in the specific process, so that the electrical double layer capacitor to be inspected is within the retention rate range associated with the acquired feature. It is specified that the voltage holding ratio is included.

請求項3記載の電気二重層キャパシタの電圧保持率特定装置は、請求項1または2記載の電気二重層キャパシタの電圧保持率特定装置において、前記処理部は、前記過渡電流波形の形状を前記特徴として取得する。   The voltage holding ratio specifying device for an electric double layer capacitor according to claim 3 is the voltage holding ratio specifying device for the electric double layer capacitor according to claim 1 or 2, wherein the processing unit has a shape of the transient current waveform as the characteristic. Get as.

請求項4記載の電気二重層キャパシタの電圧保持率特定装置は、請求項1または2記載の電気二重層キャパシタの電圧保持率特定装置において、前記処理部は、前記過渡期間の始期から所定時間を経過した時点での前記過渡電流波形の電流値を前記特徴として取得する。   The voltage holding ratio specifying device for an electric double layer capacitor according to claim 4 is the voltage holding ratio specifying device for the electric double layer capacitor according to claim 1 or 2, wherein the processing unit takes a predetermined time from the beginning of the transient period. The current value of the transient current waveform at the time when it has elapsed is acquired as the feature.

請求項5記載の電気二重層キャパシタの電圧保持率特定方法は、定格電圧に充電されている電気二重層キャパシタに対して当該定格電圧で定電圧充電する処理と、前記定格電圧での定電圧充電状態において前記電気二重層キャパシタに流れる電流を検出すると共に電圧信号に変換して出力する処理と、前記定電圧充電状態において前記電流値が徐々に減少する過渡期間を経た後に前記電流値がほぼ一定となる定常期間に移行する前記電流の当該過渡期間での過渡電流波形の特徴を前記電圧信号に基づいて取得すると共に、当該取得した特徴に基づいて前記電気二重層キャパシタの電圧保持率を特定する特定処理とを実行する。   The method for specifying the voltage holding ratio of the electric double layer capacitor according to claim 5 includes: a process of performing constant voltage charging at the rated voltage on the electric double layer capacitor charged at the rated voltage; and constant voltage charging at the rated voltage. In the state, the current flowing through the electric double layer capacitor is detected, converted into a voltage signal and output, and the current value is substantially constant after a transient period in which the current value gradually decreases in the constant voltage charging state. Based on the voltage signal, acquire the characteristics of the transient current waveform in the transient period of the current that transitions to the steady period, and specify the voltage holding ratio of the electric double layer capacitor based on the acquired characteristics Execute specific processing.

請求項1記載の電気二重層キャパシタの電圧保持率特定装置および請求項4記載の電気二重層キャパシタの電圧保持率特定方法では、検査対象の電気二重層キャパシタの電圧保持率の特定に際しては、定常期間に移行する前の過渡期間での過渡電流波形の特徴を取得し、この特徴に基づいて、検査対象の電圧保持率を特定する。具体的には、請求項2記載の電気二重層キャパシタの電圧保持率特定装置のように、取得しておいた関連付け情報を参照することにより、取得した過渡電流波形についての特徴に関連付けられている保持率範囲を検査対象の電圧保持率が含まれる保持率範囲であると特定する。   According to the voltage holding ratio specifying device for the electric double layer capacitor according to claim 1 and the voltage holding ratio specifying method for the electric double layer capacitor according to claim 4, the voltage holding ratio of the electric double layer capacitor to be inspected is normally determined. The characteristics of the transient current waveform in the transition period before the transition to the period are acquired, and the voltage holding ratio to be inspected is specified based on the characteristics. Specifically, as in the voltage holding ratio specifying device for the electric double layer capacitor according to claim 2, it is associated with the characteristics of the acquired transient current waveform by referring to the acquired association information. The holding ratio range is specified as a holding ratio range including the voltage holding ratio to be inspected.

したがって、この電気二重層キャパシタの電圧保持率特定装置およびこの電気二重層キャパシタの電圧保持率特定方法によれば、背景技術で説明した漏れ電流の検査システム(電圧保持率特定装置)とは異なり、電気二重層キャパシタに流れる電流が定常状態となるまで待つ必要が無いため、検査対象の電圧保持率の特定に要する時間を十分に短縮することができる。   Therefore, according to the voltage holding ratio specifying device of the electric double layer capacitor and the voltage holding ratio specifying method of the electric double layer capacitor, unlike the leakage current inspection system (voltage holding ratio specifying device) described in the background art, Since it is not necessary to wait until the current flowing through the electric double layer capacitor reaches a steady state, the time required for specifying the voltage holding ratio to be inspected can be sufficiently shortened.

請求項3記載の電気二重層キャパシタの電圧保持率特定装置によれば、電気二重層キャパシタに流れる電流についての過渡電流波形の形状に現れる特徴(形状についての特徴)を取得する構成のため、所定の時間における電流値だけではなく、この電流値の減少の度合いなどを考慮してより正確にグループ化することが可能となる結果、このような正確なグループ化によって生成されたグループと、このグループに関連付けされた保持率範囲とに基づいて、検査対象の電圧保持率をより正確に特定することができる。   According to the apparatus for specifying a voltage holding ratio of an electric double layer capacitor according to claim 3, since the characteristic (characteristic about the shape) appearing in the shape of the transient current waveform for the current flowing through the electric double layer capacitor is acquired, the predetermined As a result, it is possible to perform grouping more accurately in consideration of not only the current value at the time of the current time but also the degree of decrease in the current value. It is possible to more accurately specify the voltage holding ratio to be inspected based on the holding ratio range associated with.

請求項4記載の電気二重層キャパシタの電圧保持率特定装置によれば、所定時間での過渡電流波形の電流値だけを測定するだけで済むため、過渡電流波形についての波形を測定する構成と比較して、装置構成を簡略化でき、その結果として装置コストの低減を図ることができる。   According to the voltage holding ratio specifying device for the electric double layer capacitor according to claim 4, since only the current value of the transient current waveform at a predetermined time needs to be measured, it is compared with the configuration for measuring the waveform of the transient current waveform. Thus, the apparatus configuration can be simplified, and as a result, the apparatus cost can be reduced.

電圧保持率特定装置1の構成図である。1 is a configuration diagram of a voltage holding ratio specifying device 1. FIG. 電圧保持率特定装置1が電気二重層キャパシタ11を充電する際の充電電流Ichの波形図である。4 is a waveform diagram of a charging current Ich when the voltage holding ratio specifying device 1 charges an electric double layer capacitor 11. FIG. 複数のサンプルについての図2における期間T1aでの過渡電流波形図である。It is a transient current waveform figure in period T1a in Drawing 2 about a plurality of samples. 図3の部分拡大図である。FIG. 4 is a partially enlarged view of FIG. 3.

以下、電気二重層キャパシタの電圧保持率特定装置および電圧保持率特定方法の実施の形態について、添付図面を参照して説明する。   Hereinafter, embodiments of a voltage holding ratio specifying device and a voltage holding ratio specifying method for an electric double layer capacitor will be described with reference to the accompanying drawings.

最初に、電気二重層キャパシタの電圧保持率特定装置の構成について、図面を参照して説明する。   First, the configuration of the voltage holding ratio specifying device for the electric double layer capacitor will be described with reference to the drawings.

図1に示す電気二重層キャパシタの電圧保持率特定装置としての電圧保持率特定装置1は、充電部2、電流検出部3、記憶部4および処理部5を備え、検査対象の電気二重層キャパシタ(以下、キャパシタともいう)11の電圧保持率Aを特定する。   A voltage holding ratio specifying device 1 as a voltage holding ratio specifying device for an electric double layer capacitor shown in FIG. 1 includes a charging unit 2, a current detecting unit 3, a storage unit 4, and a processing unit 5, and an electric double layer capacitor to be inspected. A voltage holding ratio A of 11 (hereinafter also referred to as a capacitor) is specified.

充電部2は、処理部5によって制御されることにより、電圧保持率特定装置1の検出端子P1,P2間にプローブPL1,PL2を介して接続されたキャパシタ11に対して、定電流充電する動作(定電流充電動作)と、定電圧充電する動作(定電圧充電動作)とを切り替えて実行可能に構成されている。   The charging unit 2 is controlled by the processing unit 5 so that the capacitor 11 connected between the detection terminals P1 and P2 of the voltage holding ratio specifying device 1 via the probes PL1 and PL2 is charged with a constant current. (Constant current charging operation) and constant voltage charging operation (constant voltage charging operation) can be switched and executed.

電流検出部3は、充電部2によるキャパシタ11に対する充電動作の際に流れる電流(充電電流)Ichの電流ループ内に配設されて、この充電電流Ichを連続的に時系列に検出すると共に、電圧信号Vi(例えば、充電電流Ichの電流値に比例して電圧値が変化する信号)に変換して出力する。   The current detection unit 3 is disposed in a current loop of a current (charging current) Ich that flows when the charging unit 2 charges the capacitor 11, and continuously detects the charging current Ich in time series. The voltage signal Vi (for example, a signal whose voltage value changes in proportion to the current value of the charging current Ich) is converted and output.

記憶部4は、ハードディスク装置や半導体メモリなどで構成されている。この記憶部4には、検査対象のキャパシタ11を定電圧充電した際に測定(取得)される後述の過渡電流波形の特徴に基づいて、このキャパシタ11の電圧保持率Aを特定するための情報Dreが予め記憶されている。具体的には、この情報Dreは、関連付け情報として機能して、検査対象のキャパシタ11と同じ仕様の複数の電気二重層キャパシタ(良品)がグループ化されて生成される複数(n個:nは2以上の整数)のグループGP1,GP2,・・・,GPn(電気二重層キャパシタの過渡電流波形に現れる特徴の類似する(特徴が共通する)もの同士をグループ化することで生成されるグループ:以下、区別しないときには「グループGP」ともいう)と、この複数のグループGP1,GP2,・・・,GPnのそれぞれについてのグループ化された電気二重層キャパシタの電圧保持率Bが含まれる保持率範囲Rb1,Rb2,・・・,Rbn(以下、区別しないときには「保持率範囲Rb」ともいう)とを関連付ける。   The storage unit 4 is configured by a hard disk device, a semiconductor memory, or the like. Information for specifying the voltage holding ratio A of the capacitor 11 is stored in the storage unit 4 based on the characteristics of a transient current waveform (described later) measured (acquired) when the capacitor 11 to be inspected is charged at a constant voltage. Dre is stored in advance. Specifically, this information Dre functions as association information, and a plurality (n: n is a number) generated by grouping a plurality of electric double layer capacitors (non-defective products) having the same specifications as the capacitor 11 to be inspected. , GPn (an integer greater than or equal to 2) groups GP1, GP2,..., GPn (groups generated by grouping similar features (common features) appearing in the transient current waveform of the electric double layer capacitor): Hereinafter, when not distinguished, it is also referred to as “group GP”), and a holding ratio range including the voltage holding ratio B of the grouped electric double layer capacitors for each of the plurality of groups GP1, GP2,. Rb1, Rb2,..., Rbn (hereinafter also referred to as “retention rate range Rb” when not distinguished).

この関連付け情報Dreの取得手順について説明する。まず、検査対象のキャパシタ11と同じ仕様の電気二重層キャパシタをランダムに複数個選択し、選択した各電気二重層キャパシタに対して、JIS D1401に規定されている下記の試験手順(第1〜第3ステップ)に従って第1試験を実施して、電圧保持率Bを測定(取得)する。
第1ステップ:放電状態の電気二重層キャパシタを、充電電圧が定格電圧になるまで定電流充電する。ここで、「定格電圧」とは、電気二重層キャパシタが安全に使用し得る充電電圧の限度の電圧であり、電気二重層キャパシタのカタログや仕様書に記載されている定格電圧を意味する。
第2ステップ:定格電圧に充電されている電気二重層キャパシタを、上記の規格に規定されている時間(300秒間)だけ、さらに定格電圧と同じ電圧で定電圧充電する。
第3ステップ:定電圧充電が完了した電気二重層キャパシタの端子間を開放状態に設定して、上記の規格に規定されている時間(72時間)放置後の端子間電圧(充電電圧)を測定し、定格電圧に対するこの測定された端子間電圧の比率を電圧保持率Bとして算出する。
A procedure for acquiring the association information Dre will be described. First, a plurality of electric double layer capacitors having the same specifications as the capacitor 11 to be inspected are selected at random, and for each selected electric double layer capacitor, the following test procedures defined in JIS D1401 (the first to first tests) The first test is performed according to 3 steps), and the voltage holding ratio B is measured (acquired).
First step: The electric double layer capacitor in a discharged state is charged with a constant current until the charging voltage reaches the rated voltage. Here, the “rated voltage” is a voltage at the limit of the charging voltage that can be safely used by the electric double layer capacitor, and means a rated voltage described in catalogs and specifications of the electric double layer capacitor.
Second step: The electric double layer capacitor charged to the rated voltage is charged at a constant voltage at the same voltage as the rated voltage for the time (300 seconds) specified in the above standard.
Third step: Set the open state between the terminals of the electric double layer capacitor for which constant voltage charging is completed, and measure the inter-terminal voltage (charge voltage) after being left for the time specified in the above standard (72 hours) Then, the ratio of the measured inter-terminal voltage to the rated voltage is calculated as the voltage holding ratio B.

次いで、電圧保持率Bを算出した各電気二重層キャパシタに対して、以下の試験手順(第aおよび第bステップ)に従って第2試験を実施して、後述の過渡電流波形の特徴を測定(取得)する。
第aステップ:放電状態の電気二重層キャパシタをその充電電圧が定格電圧になるまで、図2に示すように、一定の電流値の充電電流Ichで定電流充電する。
第bステップ:定格電圧に充電された電気二重層キャパシタをさらに定格電圧と同じ電圧で定電圧充電しつつ、この定電圧充電状態での充電電流Ichの波形を測定(取得)する。具体的には、定電圧充電状態での充電電流Ichは、図2に示すように、電流値が徐々に減少する過渡期間T1を経た後に、電流値が一定となる定常期間T2に最終的に移行するが、この第bステップでは、この定常期間T2に移行する前の過渡期間T1(特に、電流値の変化の度合いが大きな過渡期間T1の前半の期間T1a)での充電電流Ichの波形(過渡電流波形)を測定する。なお、電気二重層キャパシタによっては、上記の期間T1a中に、電流値の変化の度合いが小さくなることもあるが、この場合でも、他の電気二重層キャパシタと同じ期間T1aの波形を測定する。
Next, a second test is performed on each electric double layer capacitor whose voltage holding ratio B has been calculated according to the following test procedure (steps a and b) to measure (obtain the characteristics of a transient current waveform, which will be described later. )
Step a: The electric double layer capacitor in a discharged state is charged with a constant current with a constant charging current Ich as shown in FIG. 2 until the charging voltage reaches the rated voltage.
Step b: Measure (acquire) the waveform of the charging current Ich in this constant voltage charged state while further charging the electric double layer capacitor charged to the rated voltage with a constant voltage at the same voltage as the rated voltage. Specifically, as shown in FIG. 2, the charging current Ich in the constant voltage charging state finally passes through a transient period T1 in which the current value gradually decreases and then finally enters a steady period T2 in which the current value becomes constant. In this b-th step, the waveform of the charging current Ich in the transition period T1 before transitioning to the steady period T2 (particularly, the first half period T1a of the transition period T1 where the degree of change in the current value is large) ( Measure the transient current waveform. Depending on the electric double layer capacitor, the degree of change in the current value may be reduced during the period T1a. Even in this case, the waveform of the same period T1a as the other electric double layer capacitors is measured.

続いて、特徴を取得した各電気二重層キャパシタに対して、特徴が類似(共通)するもの同士をグループ化する。次いで、グループ化によって生成された複数のグループGPのそれぞれについて、グループGPに含まれる各電気二重層キャパシタの電圧保持率Bの範囲を保持率範囲Rbとして求める。最後に、複数のグループGPのそれぞれについて求めた保持率範囲Rbを、対応するグループGPに関連付けて、関連付け情報Dreとして記憶部4に記憶させる。これにより、関連付け情報Dreの取得が完了する。   Subsequently, the similar (common) features are grouped for each electric double layer capacitor from which the features have been acquired. Next, for each of the plurality of groups GP generated by the grouping, the range of the voltage holding ratio B of each electric double layer capacitor included in the group GP is obtained as the holding ratio range Rb. Finally, the retention rate range Rb obtained for each of the plurality of groups GP is stored in the storage unit 4 as association information Dre in association with the corresponding group GP. Thereby, acquisition of the association information Dre is completed.

このように、電気二重層キャパシタには、上記の定電圧充電中の充電電流Ichについての過渡期間での過渡電流波形に現れる特徴と、電圧保持率が含まれる保持率範囲との間に相関関係があることについて、1000Fの電気二重層キャパシタを例に挙げて説明する。   Thus, in the electric double layer capacitor, there is a correlation between the characteristics appearing in the transient current waveform in the transient period for the charging current Ich during the constant voltage charging and the holding ratio range including the voltage holding ratio. The fact that there is an electric double layer capacitor of 1000F will be described as an example.

まず、この電気二重層キャパシタの複数のサンプルに対して第1試験を実施して、各サンプルの電圧保持率Bを測定(取得)した。この結果、これらのサンプルでは、昇順で、68.0%,88.0%,89.7%,90.3%,91.0%,94.3%,94.4%,95.7%、95.7%という電圧保持率Bが取得された。   First, the first test was performed on a plurality of samples of the electric double layer capacitor, and the voltage holding ratio B of each sample was measured (acquired). As a result, in these samples, 68.0%, 88.0%, 89.7%, 90.3%, 91.0%, 94.3%, 94.4%, 95.7% in ascending order. A voltage holding ratio B of 95.7% was obtained.

次いで、第2試験を実施して、各サンプルの過渡期間T1の前半の期間T1aでの充電電流Ichの波形(過渡電流波形)を測定(取得)した。この結果を図3に示す。   Next, a second test was performed, and the waveform (transient current waveform) of the charging current Ich in the first half period T1a of the transient period T1 of each sample was measured (acquired). The result is shown in FIG.

この図3の各波形に基づくと、取得した充電電流Ichの波形は、以下のような互いに異なる特徴に着目して、3つのグループGP(第1グループGP1,第2グループGP2,第3グループGP3)に分類された。   Based on the waveforms of FIG. 3, the acquired waveform of the charging current Ich pays attention to the following different features and is divided into three groups GP (first group GP1, second group GP2, third group GP3). ).

まず、第1グループGP1としてグループ化された電気二重層キャパシタについての充電電流Ichの過渡電流波形の特徴(波形の形状についての特徴)は、電流値が、定電圧充電の開始(図3中の0時間)から比較的早い時間ta(同図では約5時間後)にある程度小さい値(同図ではIa(約0.003A)未満の値)に達し、かつその後も減少の度合いが徐々に少なくなりながら定常状態での値(定常値。例えば、0.0003A)に向けて低下するという第1の特徴である。   First, the characteristics of the transient current waveform of the charging current Ich (characteristics regarding the shape of the waveform) for the electric double layer capacitors grouped as the first group GP1 is that the current value is the start of constant voltage charging (in FIG. 3). It reaches a relatively small value (a value less than Ia (about 0.003 A in the figure)) from a relatively early time ta (after about 5 hours in the figure) to the relatively early time ta, and the degree of decrease gradually decreases thereafter. The first feature is that the value decreases toward a value in a steady state (steady value, for example, 0.0003 A).

また、第2グループGP2としてグループ化された電気二重層キャパシタについての充電電流Ichの過渡電流波形の特徴(波形の形状についての特徴)は、電流値が、定電圧充電の開始から上記の時間taが経過した時点では上記の値Iaには達してはいないものの、その後も減少の度合いは徐々に少なくなりながらも減少し続けて、図3には記載されていないが、最終的には(例えば、40時間程度経過した時点においては)、上記した第1グループGP1の電気二重層キャパシタについての定常値とほぼ同程度の小さい値に達するという第2の特徴である。   The characteristics of the transient current waveform of the charging current Ich (characteristics regarding the waveform shape) for the electric double layer capacitors grouped as the second group GP2 is that the current value is equal to the time ta described above from the start of constant voltage charging. Although the value Ia has not been reached at the time when elapses, the degree of decrease continues to decrease while gradually decreasing, and although not shown in FIG. The second feature is that, when about 40 hours have passed), it reaches a small value almost equal to the steady value for the electric double layer capacitors of the first group GP1 described above.

また、第3グループGP3としてグループ化された電気二重層キャパシタについての充電電流Ichの過渡電流波形の特徴(波形の形状についての特徴)は、電流値が、定電圧充電の開始から上記の時間taに上記の値Ia未満の値に達するものの、その後は急激に減少の度合いが低下することで、比較的短時間に上記した他のグループGP1,GP2の電気二重層キャパシタについての定常値よりも極めて高い値(例えば、0.001Aのように一桁以上高い値)で定常状態に達するという第3の特徴である。   The characteristics of the transient current waveform of the charging current Ich for the electric double layer capacitors grouped as the third group GP3 (characteristics regarding the shape of the waveform) are as follows. However, since the degree of decrease suddenly decreases after that, the value of the electric double layer capacitors of the other groups GP1 and GP2 described above is much higher than the steady values for the other groups GP1 and GP2. The third feature is that the steady state is reached at a high value (for example, a value higher by one digit or more like 0.001A).

続いて、各グループGP1,GP2,GP3のそれぞれについて、グループGPに含まれるサンプルの電圧保持率Bの範囲を保持率範囲Rbとして求めた。この例では、第1グループGP1に含まれるサンプルの電圧保持率Bは、94.3%,94.4%,95.7%、95.7%であり、第2グループGP2に含まれるサンプルの電圧保持率Bは、89.7%,90.3%,91.0%であり、第3グループGP3に含まれるサンプルの電圧保持率Bは、68.0%,88.0%であった。   Subsequently, for each of the groups GP1, GP2, GP3, the range of the voltage holding ratio B of the samples included in the group GP was obtained as the holding ratio range Rb. In this example, the voltage holding ratio B of the samples included in the first group GP1 is 94.3%, 94.4%, 95.7%, 95.7%, and the samples included in the second group GP2 The voltage holding ratio B was 89.7%, 90.3%, 91.0%, and the voltage holding ratio B of the samples included in the third group GP3 was 68.0%, 88.0%. .

したがって、第1グループGP1に含まれる各サンプルの電圧保持率Bについての保持率範囲Rb1を93%以上と規定し、第2グループGP2に含まれる各サンプルの電圧保持率Bについての保持率範囲Rb2を89%以上93%未満と規定し、第3グループGP3に含まれる各サンプルの電圧保持率Bについての保持率範囲Rb3を89%未満と規定することで、保持率範囲Rb1と第1グループGP1とを、また保持率範囲Rb2と第2グループGP2とを、また保持率範囲Rb3と第3グループGP3とをそれぞれ関連付けできることが確認された。つまり、電気二重層キャパシタには、上記の定電圧充電中の充電電流Ichについての過渡期間での過渡電流波形に現れる特徴と、電圧保持率が含まれる保持率範囲との間に相関関係があることが確認された。   Therefore, the holding ratio range Rb1 for the voltage holding ratio B of each sample included in the first group GP1 is defined as 93% or more, and the holding ratio range Rb2 for the voltage holding ratio B of each sample included in the second group GP2. Is defined as 89% or more and less than 93%, and the retention rate range Rb3 for the voltage retention rate B of each sample included in the third group GP3 is defined as less than 89%, whereby the retention rate range Rb1 and the first group GP1 It is confirmed that the retention rate range Rb2 and the second group GP2 can be associated with each other, and the retention rate range Rb3 and the third group GP3 can be associated with each other. In other words, in the electric double layer capacitor, there is a correlation between the characteristics appearing in the transient current waveform in the transient period for the charging current Ich during constant voltage charging and the retention ratio range including the voltage retention ratio. It was confirmed.

処理部5は、例えば、A/D変換器、メモリおよびCPUなどを備えて、充電部2に対する制御処理(具体的には、定電流充電時の充電電流Ichの電流値を設定する処理、および定電圧充電時の電圧値を設定する処理)と、電流検出部3から出力される電圧信号Viに基づいて充電電流Ichの過渡電流波形を測定する波形測定処理と、測定した過渡電流波形の特徴を取得する特徴取得処理と、この取得した特徴に基づいて検査対象となっているキャパシタ11の電圧保持率Aを特定する特定処理とを実行する。また、処理部5は、特定した電圧保持率Aを出力する出力処理についても実行可能に構成されている。この出力処理では、電圧保持率特定装置1にディスプレイ装置などの出力装置を設けて、この出力装置に電圧保持率Aを出力したり、電圧保持率特定装置1の外部に設けられた他の装置に対して電圧保持率Aを出力したりすることができる。   The processing unit 5 includes, for example, an A / D converter, a memory, a CPU, and the like, and performs control processing for the charging unit 2 (specifically, processing for setting a current value of the charging current Ich during constant current charging, and Processing for setting a voltage value during constant voltage charging), waveform measurement processing for measuring a transient current waveform of the charging current Ich based on the voltage signal Vi output from the current detection unit 3, and characteristics of the measured transient current waveform And a specific process for specifying the voltage holding ratio A of the capacitor 11 to be inspected based on the acquired characteristic. The processing unit 5 is also configured to be able to execute an output process for outputting the specified voltage holding ratio A. In this output processing, an output device such as a display device is provided in the voltage holding ratio specifying device 1, and the voltage holding rate A is output to this output device, or another device provided outside the voltage holding ratio specifying device 1. Or the voltage holding ratio A can be output.

次に、電圧保持率特定装置1の動作を、電圧保持率特定方法と併せて図面を参照して説明する。なお、本例では一例として、上記したサンプルと同一仕様のキャパシタ11を検査対象とし、記憶部4には、このサンプルについての上記した関連付け情報Dre(図3に記載されている情報)が予め記憶されているものとする。   Next, the operation of the voltage holding ratio specifying device 1 will be described with reference to the drawings together with the voltage holding ratio specifying method. In this example, as an example, the capacitor 11 having the same specification as that of the above-described sample is to be inspected, and the storage unit 4 stores in advance the above-described association information Dre (information described in FIG. 3) regarding this sample. It is assumed that

電圧保持率特定装置1では、検査対象とするキャパシタ11がプローブPL1,PL2を介して検出端子P1,P2間に接続されている状態において、処理部5が、キャパシタ11の電圧保持率Aを特定するための処理を実行する。   In the voltage holding ratio specifying device 1, the processing unit 5 specifies the voltage holding ratio A of the capacitor 11 in a state where the capacitor 11 to be inspected is connected between the detection terminals P1 and P2 via the probes PL1 and PL2. To execute the process.

この処理では、処理部5は、まず、充電部2に対する制御処理を実行して、定電流充電時での充電電流Ichの電流値と、定電圧充電時での充電電圧の電圧値(本例では、定電流充電時にキャパシタ11を定格電圧まで充電するため、定格電圧値)とを充電部2に設定すると共に、充電部2に対して充電動作を開始させる。   In this process, the processing unit 5 first executes a control process for the charging unit 2, and the current value of the charging current Ich at the time of constant current charging and the voltage value of the charging voltage at the time of constant voltage charging (this example) Then, in order to charge the capacitor 11 to the rated voltage during constant current charging, the charging unit 2 is set to the rated voltage value) and the charging unit 2 is started to perform a charging operation.

これにより、充電部2は、まず、設定された電流値の充電電流Ichでの定電流充電をキャパシタ11に対して実行し、その後、キャパシタ11の充電電圧値が定格電圧値に達した時点で、定電流充電から定電圧充電に切り替えてキャパシタ11への充電を継続する。なお、他の充電装置などによって既に定格電圧に充電されているキャパシタ11を検査対象とするときには、電圧保持率特定装置1は、定電流充電動作を省いて、定電圧充電動作から開始する。   As a result, the charging unit 2 first performs constant current charging with the charging current Ich of the set current value on the capacitor 11, and then when the charging voltage value of the capacitor 11 reaches the rated voltage value. Then, switching from constant current charging to constant voltage charging continues to charge the capacitor 11. When the capacitor 11 that has already been charged to the rated voltage by another charging device or the like is to be inspected, the voltage holding ratio specifying device 1 omits the constant current charging operation and starts from the constant voltage charging operation.

電流検出部3は、充電部2がキャパシタ11を充電している際にキャパシタ11に流れる充電電流Ichを連続的に時系列に検出すると共に電圧信号Viに変換して処理部5に出力する。   The current detection unit 3 continuously detects the charging current Ich flowing through the capacitor 11 in time series while the charging unit 2 is charging the capacitor 11, converts the current into a voltage signal Vi, and outputs the voltage signal Vi to the processing unit 5.

次いで、処理部5は、波形測定処理を実行する。この波形測定処理では、処理部5は、図2に示す期間T1aにおいて電流検出部3から出力される電圧信号Viに基づいて、この期間T1aでの充電電流Ichの波形(過渡電流波形)を測定(取得)する。   Next, the processing unit 5 executes a waveform measurement process. In this waveform measurement process, the processing unit 5 measures the waveform (transient current waveform) of the charging current Ich in this period T1a based on the voltage signal Vi output from the current detection unit 3 in the period T1a shown in FIG. (get.

続いて、処理部5は、特徴取得処理を実行する。この特徴取得処理では、処理部5は、取得した過渡電流波形に現れている特徴が、関連付け情報Dreに含まれている各グループGPにグループ化する際の各特徴(この例では、第1の特徴、第2の特徴および第3の特徴)のうちのいずれに該当するかを判別することで、充電電流Ichの過渡電流波形の特徴を取得する。   Subsequently, the processing unit 5 executes feature acquisition processing. In this feature acquisition process, the processing unit 5 uses each feature (in this example, the first feature) when the features appearing in the acquired transient current waveform are grouped into each group GP included in the association information Dre. The characteristic of the transient current waveform of the charging current Ich is acquired by determining which of the characteristic, the second characteristic, and the third characteristic).

次いで、処理部5は、特定処理を実行する。この特定処理では、処理部5は、記憶部4に記憶されている関連付け情報Dreを参照することにより、取得した充電電流Ichの過渡電流波形についての特徴に関連付けられている保持率範囲Rbを特定する(本例では、保持率範囲Rb1〜Rb3のいずれか1つを特定する)。これにより、特定処理が完了する。最後に、処理部5は、出力処理を実行して、検査対象のキャパシタ11の電圧保持率Aが、このようにして特定した保持率範囲Rbに含まれる値であることを出力する。これにより、キャパシタ11の電圧保持率Aを特定するための処理が完了する。   Next, the processing unit 5 executes a specific process. In this specifying process, the processing unit 5 specifies the retention rate range Rb associated with the characteristics of the acquired transient current waveform of the charging current Ich by referring to the association information Dre stored in the storage unit 4. (In this example, any one of the retention ranges Rb1 to Rb3 is specified). Thereby, the specific process is completed. Finally, the processing unit 5 performs an output process and outputs that the voltage holding ratio A of the capacitor 11 to be inspected is a value included in the holding ratio range Rb specified in this way. Thereby, the process for specifying the voltage holding ratio A of the capacitor 11 is completed.

このように、このキャパシタ(電気二重層キャパシタ)の電圧保持率特定装置1およびその電圧保持率特定方法では、定電圧充電されている状態において測定される充電電流Ichの電流値が一定となる定常期間T2に移行する前の過渡期間T1(具体的には、期間T1a)での充電電流Ichについての過渡電流波形の特徴に基づいて、キャパシタ11の電圧保持率Aを特定する。具体的には、検査対象と同じ仕様の複数の電気二重層キャパシタを上記の特徴の類似(共通)するもの同士にグループ化して生成した複数のグループGPと、複数のグループGPのそれぞれについてのグループ化した電気二重層キャパシタの電圧保持率Bが含まれる保持率範囲Rbとを関連付ける関連付け情報Dreを予め取得しておき、検査対象のキャパシタ11の電圧保持率Aの特定に際しては、上記した充電電流Ichについての過渡電流波形の特徴を測定(取得)し、取得しておいた関連付け情報Dreを参照することにより、取得した充電電流Ichの過渡電流波形についての特徴に関連付けられている保持率範囲Rbを検査対象の電気二重層キャパシタの電圧保持率Aが含まれる保持率範囲であると特定する。   As described above, in the voltage holding ratio specifying device 1 and the voltage holding ratio specifying method for this capacitor (electric double layer capacitor), the current value of the charging current Ich measured in the state of constant voltage charging is constant. Based on the characteristics of the transient current waveform for the charging current Ich in the transition period T1 (specifically, the period T1a) before the transition to the period T2, the voltage holding ratio A of the capacitor 11 is specified. Specifically, a plurality of group GPs generated by grouping a plurality of electric double layer capacitors having the same specifications as the inspection object into those having similar (common) characteristics as described above, and a group for each of the plurality of group GPs The association information Dre for associating with the holding ratio range Rb including the voltage holding ratio B of the converted electric double layer capacitor is acquired in advance, and when specifying the voltage holding ratio A of the capacitor 11 to be inspected, the charging current described above is used. By measuring (acquiring) the characteristics of the transient current waveform for Ich and referring to the acquired association information Dre, the retention ratio range Rb associated with the characteristics of the acquired transient current waveform of the charging current Ich Is specified as a holding ratio range including the voltage holding ratio A of the electric double layer capacitor to be inspected.

したがって、このキャパシタ(電気二重層キャパシタ)の電圧保持率特定装置1およびその電圧保持率特定方法によれば、背景技術で説明した漏れ電流の検査システム(電圧保持率特定装置)とは異なり、充電電流Ichが定常状態となるまで待つ必要が無いため、キャパシタ11の電圧保持率Aの特定に要する時間を十分に短縮することができる。   Therefore, according to the voltage holding ratio specifying device 1 and the voltage holding ratio specifying method of this capacitor (electric double layer capacitor), unlike the leakage current inspection system (voltage holding ratio specifying device) described in the background art, charging is performed. Since there is no need to wait until the current Ich reaches a steady state, the time required for specifying the voltage holding ratio A of the capacitor 11 can be sufficiently shortened.

また、このキャパシタの電圧保持率特定装置1およびその電圧保持率特定方法によれば、充電電流Ichについての過渡電流波形の形状に現れる特徴(形状についての特徴)を取得(測定)する構成のため、所定の時間における電流値だけではなく、この電流値の減少の度合いなどを考慮してより正確にグループ化することが可能となる結果、このような正確なグループ化によって生成されたグループGPと、このグループGPに関連付けされた保持率範囲Rbとに基づいて、キャパシタ11の電圧保持率Aをより正確に特定することができる。   Further, according to the capacitor voltage holding ratio specifying device 1 and the voltage holding ratio specifying method, the feature (feature concerning the shape) appearing in the shape of the transient current waveform for the charging current Ich is obtained (measured). In addition to the current value at a predetermined time, it is possible to perform grouping more accurately in consideration of the degree of decrease in the current value, and the like. Based on the holding ratio range Rb associated with the group GP, the voltage holding ratio A of the capacitor 11 can be specified more accurately.

なお、充電電流Ichの過渡電流波形をグループ化する際に使用されるこの過渡電流波形の特徴については、上記した例のように、過渡電流波形の形状についての特徴に限定されず、例えば、図4に示すように、過渡期間T1の始期(0時間のとき)から所定時間tb(この例では13時間)を経過した時点での過渡電流波形の電流値(同図中において○印での電流値)を、過渡電流波形の特徴として取得する構成を採用することもできる。この場合、同図に示すように、過渡電流波形の所定時間tbでの電流値が、電流閾値Ith1以下となる過渡電流波形についての特徴を有するキャパシタを第1グループとしてグループ化し、電流閾値Ith1を超え電流閾値Ith2以下となる過渡電流波形についての特徴を有するキャパシタを第2グループとしてグループ化し、電流閾値Ith2を超えるという過渡電流波形についての特徴を有するキャパシタを第3グループとしてグループ化する。   Note that the characteristics of the transient current waveform used when grouping the transient current waveforms of the charging current Ich are not limited to the characteristics of the shape of the transient current waveform as in the above-described example. As shown in FIG. 4, the current value of the transient current waveform when the predetermined time tb (13 hours in this example) has elapsed from the beginning of the transient period T1 (at 0 hour) (the current at the circle in the figure) It is also possible to adopt a configuration in which (value) is acquired as a characteristic of the transient current waveform. In this case, as shown in the figure, capacitors having characteristics with respect to the transient current waveform in which the current value at the predetermined time tb of the transient current waveform is equal to or less than the current threshold value Ith1 are grouped as a first group, and the current threshold value Ith1 is set. Capacitors having a characteristic regarding the transient current waveform that is less than or equal to the overcurrent threshold Ith2 are grouped as a second group, and capacitors having a characteristic about the transient current waveform that exceeds the current threshold Ith2 are grouped as a third group.

この構成によれば、所定時間tbでの過渡電流波形の電流値だけを測定するだけで済むため、過渡電流波形についての波形を測定する構成と比較して、装置構成を簡略化でき、その結果として装置コストの低減を図ることができる。   According to this configuration, since it is only necessary to measure the current value of the transient current waveform at the predetermined time tb, the apparatus configuration can be simplified as compared with the configuration for measuring the waveform of the transient current waveform. As a result, the device cost can be reduced.

1 電圧保持率特定装置
2 充電部
3 電流検出部
5 処理部
11 キャパシタ
Dre 関連付け情報
Ich 充電電流
DESCRIPTION OF SYMBOLS 1 Voltage holding ratio specific device 2 Charging part 3 Current detection part 5 Processing part 11 Capacitor Dre Association information Ich charging current

Claims (5)

定格電圧に充電されている検査対象の電気二重層キャパシタに対して当該定格電圧で定電圧充電する充電部と、
前記定格電圧での定電圧充電状態において前記電気二重層キャパシタに流れる電流を検出すると共に電圧信号に変換して出力する電流検出部と、
前記定電圧充電状態において電流値が徐々に減少する過渡期間を経た後に前記電流値がほぼ一定となる定常期間に移行する前記電流の当該過渡期間での過渡電流波形の特徴を前記電圧信号に基づいて取得すると共に、当該取得した特徴に基づいて前記電気二重層キャパシタの電圧保持率を特定する特定処理を実行する処理部とを備えている電気二重層キャパシタの電圧保持率特定装置。
A charging unit that performs constant voltage charging at the rated voltage for the electric double layer capacitor to be inspected that is charged at the rated voltage;
A current detection unit that detects a current flowing in the electric double layer capacitor in a constant voltage charged state at the rated voltage and converts the current into a voltage signal and outputs the current signal;
Based on the voltage signal, the characteristics of the transient current waveform in the transient period of the current that transitions to a steady period in which the current value becomes substantially constant after a transient period in which the current value gradually decreases in the constant voltage charging state. And a processing unit that executes a specifying process for specifying the voltage holding ratio of the electric double layer capacitor based on the acquired characteristics.
前記検査対象と同じ仕様の複数の電気二重層キャパシタを前記特徴の類似するもの同士にグループ化して生成した複数のグループと、当該複数のグループのそれぞれについてのグループ化した前記電気二重層キャパシタの前記電圧保持率が含まれる保持率範囲とを関連付ける関連付け情報が記憶された記憶部を有し、
前記処理部は、前記特定処理において、前記関連付け情報を参照することにより、前記取得した特徴に関連付けされた前記保持率範囲内に前記検査対象の電気二重層キャパシタの前記電圧保持率が含まれると特定する請求項1記載の電気二重層キャパシタの電圧保持率特定装置。
A plurality of groups generated by grouping a plurality of electric double layer capacitors having the same specifications as the inspection object into those having similar characteristics, and the group of the electric double layer capacitors grouped for each of the plurality of groups A storage unit storing association information for associating with a holding ratio range including the voltage holding ratio;
When the processing unit refers to the association information in the specific process, the voltage holding ratio of the electric double layer capacitor to be inspected is included in the holding ratio range associated with the acquired feature. 2. The voltage holding ratio specifying device for an electric double layer capacitor according to claim 1.
前記処理部は、前記過渡電流波形の形状を前記特徴として取得する請求項1または2記載の電気二重層キャパシタの電圧保持率特定装置。   The voltage holding ratio specifying device for an electric double layer capacitor according to claim 1, wherein the processing unit acquires the shape of the transient current waveform as the characteristic. 前記処理部は、前記過渡期間の始期から所定時間を経過した時点での前記過渡電流波形の電流値を前記特徴として取得する請求項1または2記載の電気二重層キャパシタの電圧保持率特定装置。   3. The voltage holding ratio specifying device for an electric double layer capacitor according to claim 1, wherein the processing unit acquires, as the characteristic, a current value of the transient current waveform when a predetermined time has elapsed from the beginning of the transient period. 定格電圧に充電されている電気二重層キャパシタに対して当該定格電圧で定電圧充電する処理と、
前記定格電圧での定電圧充電状態において前記電気二重層キャパシタに流れる電流を検出すると共に電圧信号に変換して出力する処理と、
前記定電圧充電状態において前記電流値が徐々に減少する過渡期間を経た後に前記電流値がほぼ一定となる定常期間に移行する前記電流の当該過渡期間での過渡電流波形の特徴を前記電圧信号に基づいて取得すると共に、当該取得した特徴に基づいて前記電気二重層キャパシタの電圧保持率を特定する特定処理とを実行する電気二重層キャパシタの電圧保持率特定方法。
A process of charging the electric double layer capacitor charged to the rated voltage at a constant voltage at the rated voltage;
A process of detecting a current flowing in the electric double layer capacitor in a constant voltage charging state at the rated voltage and converting it to a voltage signal and outputting the detected current;
The voltage signal is characterized by a transient current waveform in the transient period of the current that transitions to a steady period in which the current value becomes substantially constant after a transient period in which the current value gradually decreases in the constant voltage charging state. And a specifying process for specifying the voltage holding ratio of the electric double layer capacitor based on the acquired characteristics.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018088260A1 (en) 2016-11-10 2018-05-17 Necエナジーデバイス株式会社 Control device, control method, and program

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001257008A (en) * 2000-03-13 2001-09-21 Nippon Telegr & Teleph Corp <Ntt> Estimation method of lithium-ion battery capacity and lithium-ion battery pack
JP2001289924A (en) * 2000-04-03 2001-10-19 Nippon Telegr & Teleph Corp <Ntt> Capacity estimating method of lithium ion battery, degradation judging method and degradation judging device for the lithium ion battery, and lithium ion battery pack
JP2002162451A (en) * 2000-11-28 2002-06-07 Nippon Telegr & Teleph Corp <Ntt> Capacity estimating method, deterioration determination method and deterioration determination device of lithium ion battery and lithium ion battery pack having deterioration determining function
JP2003133189A (en) * 2001-10-22 2003-05-09 Nissan Diesel Motor Co Ltd Method of inspecting leakage current and inspection system
JP2003153454A (en) * 1998-01-19 2003-05-23 Matsushita Electric Ind Co Ltd Method of detecting deterioration of secondary battery and battery charger provided with function of detecting deterioration
JP2004101188A (en) * 2002-09-04 2004-04-02 Sanyo Electric Co Ltd Method for detecting full-charge capacity of battery
WO2013128635A1 (en) * 2012-03-02 2013-09-06 株式会社 日立製作所 Storage battery analysis system, storage battery analysis method, and storage battery analysis program
JP2016143580A (en) * 2015-02-03 2016-08-08 株式会社ジェイ・イー・ティ Manufacturing method for power storage device, and inspection device for structure
JP2016539320A (en) * 2013-10-01 2016-12-15 サントル ナシオナル ドゥ ラ ルシェルシェ シアンティフィクCentre National De La Recherche Scientifique Method and apparatus for evaluating deterioration state of lithium battery

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003153454A (en) * 1998-01-19 2003-05-23 Matsushita Electric Ind Co Ltd Method of detecting deterioration of secondary battery and battery charger provided with function of detecting deterioration
JP2001257008A (en) * 2000-03-13 2001-09-21 Nippon Telegr & Teleph Corp <Ntt> Estimation method of lithium-ion battery capacity and lithium-ion battery pack
JP2001289924A (en) * 2000-04-03 2001-10-19 Nippon Telegr & Teleph Corp <Ntt> Capacity estimating method of lithium ion battery, degradation judging method and degradation judging device for the lithium ion battery, and lithium ion battery pack
JP2002162451A (en) * 2000-11-28 2002-06-07 Nippon Telegr & Teleph Corp <Ntt> Capacity estimating method, deterioration determination method and deterioration determination device of lithium ion battery and lithium ion battery pack having deterioration determining function
JP2003133189A (en) * 2001-10-22 2003-05-09 Nissan Diesel Motor Co Ltd Method of inspecting leakage current and inspection system
JP2004101188A (en) * 2002-09-04 2004-04-02 Sanyo Electric Co Ltd Method for detecting full-charge capacity of battery
WO2013128635A1 (en) * 2012-03-02 2013-09-06 株式会社 日立製作所 Storage battery analysis system, storage battery analysis method, and storage battery analysis program
JP2016539320A (en) * 2013-10-01 2016-12-15 サントル ナシオナル ドゥ ラ ルシェルシェ シアンティフィクCentre National De La Recherche Scientifique Method and apparatus for evaluating deterioration state of lithium battery
JP2016143580A (en) * 2015-02-03 2016-08-08 株式会社ジェイ・イー・ティ Manufacturing method for power storage device, and inspection device for structure

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018088260A1 (en) 2016-11-10 2018-05-17 Necエナジーデバイス株式会社 Control device, control method, and program

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