JP2016171783A - Sugar-coating liquid and preparation method therefor - Google Patents
Sugar-coating liquid and preparation method therefor Download PDFInfo
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本発明は、糖衣液の調製方法と、それにより得られる糖衣液、その糖衣液を用いて得られる糖衣製品に関するものである。 The present invention relates to a method for preparing a sugar coating liquid, a sugar coating liquid obtained thereby, and a sugar coating product obtained using the sugar coating liquid.
糖衣掛けは錠剤などの医薬品やチューインガムなどの菓子類で古くから広く用いられている技術である。その一般的な方法は、例えば回転釜を用い、芯となる物質に糖衣液を掛けては乾燥する工程を繰り返し、芯物質にコーティングを施す技術である。 Sugar coating is a technique that has been widely used for a long time in pharmaceuticals such as tablets and confectionery such as chewing gum. The general method is a technique in which, for example, a rotary pot is used, and a process of applying a sugar coating liquid to a core material and drying is repeated to coat the core material.
糖衣製品を口に入れるとまず最外層が口腔内で溶解するため、そこに香料を添加するとインパクトのある製品が得られる。しかし糖衣層は薄く作るため、糖衣液に香料を均一に分散させないと香味の発現が不均一なものとなってしまう。 When the sugar-coated product is put in the mouth, the outermost layer is first dissolved in the oral cavity, so adding a fragrance to it gives an impact product. However, since the sugar-coating layer is made thin, unless the fragrance is uniformly dispersed in the sugar-coating liquid, the expression of the flavor becomes non-uniform.
糖衣に香料を使用する場合、一般的な糖衣液は水溶液のため、水溶性香料であれば糖衣液に直接混合しても十分に溶解して均一に分散するが、油溶性香料を用いる際には予め乳化香料とし、その後に糖衣液に分散させる必要があった（特許文献１）。 When a fragrance is used in a sugar coating, a general sugar coating liquid is an aqueous solution, so if it is a water-soluble fragrance, even if it is mixed directly with the sugar coating liquid, it will dissolve and disperse evenly. Had to be preliminarily emulsified and then dispersed in a sugar coating liquid (Patent Document 1).
また、メントールを乳化剤のみで乳化した乳剤は、乳化状態が数時間しか安定ではなく次第に乳剤の表面にメントールが析出してきてしまうため、さらに脂肪酸や脂肪酸エステルを添加する必要があった（特許文献２）。 In addition, an emulsion obtained by emulsifying menthol only with an emulsifier is stable only for several hours, and menthol is gradually deposited on the surface of the emulsion. Therefore, it is necessary to further add a fatty acid or a fatty acid ester (Patent Document 2). ).
油溶性香料を予め乳化させることなく、乳化が安定した糖衣液を調製できる糖衣液の調製方法、及び香り立ちのよい糖衣液、糖衣製品を提供することを課題とした。 It was an object of the present invention to provide a sugar-coating liquid preparation method capable of preparing a sugar-coating liquid with stable emulsification without pre-emulsifying an oil-soluble fragrance, and a sugar-coating liquid and a sugar-coating product having a good aroma.
上記課題を解決するため、発明者らは鋭意検討の結果、油溶性香料を予め乳化させることなく、糖質とアラビアガムを含有する水溶液に、油溶性香料と乳化剤とを直接添加混合しても、特定の乳化剤を用いることによって、乳化が安定した糖衣液を調製できることを見出した。 In order to solve the above-mentioned problems, the inventors have intensively studied to add and dissolve oil-soluble fragrance and emulsifier directly into an aqueous solution containing sugar and gum arabic without emulsifying the oil-soluble fragrance in advance. It has been found that a sugar coating liquid with stable emulsification can be prepared by using a specific emulsifier.
また上記製法により香り立ちのよい糖衣液、糖衣製品の提供が可能となることを見出した。 It has also been found that the above-mentioned production method makes it possible to provide a sugar-coating liquid and a sugar-coating product with a good fragrance.
本発明は以下の構成からなる。
（１）糖質とアラビアガムを含有する水溶液に、油溶性香料とソルビタン脂肪酸エステルを添加し撹拌することを特徴とする、糖衣液の調製方法。
（２）糖質がマルチトールである、（１）に記載の糖衣液の調製方法。
（３）油溶性香料の油滴が平均粒径１μｍ以下になるまで撹拌することを特徴とする、（１）または（２）に記載の糖衣液の調製方法。
（４）ソルビタン脂肪酸エステルがソルビタンモノラウレートである、（１）乃至（３）のいずれかに記載の糖衣液の調製方法。
（５）油溶性香料がメントールである、（１）乃至（４）のいずれかに記載の糖衣液の調製方法。
（６）ソルビタン脂肪酸エステルの添加量が油溶性香料に対して５〜２００重量％である、（１）乃至（５）のいずれかに記載の糖衣液の調製方法。
（７）（１）乃至（６）のいずれかに記載の方法で得られる糖衣液。
（８）油溶性香料の油滴が平均粒径１μｍ以下であることを特徴とする、（７）に記載の糖衣液。
（９）（７）または（８）に記載の糖衣液を用いて得られる糖衣製品。
（１０）糖衣製品がチューインガムである、（９）に記載の糖衣製品。
The present invention has the following configuration.
(1) A method for preparing a sugar coating liquid, comprising adding an oil-soluble fragrance and a sorbitan fatty acid ester to an aqueous solution containing a saccharide and gum arabic and stirring.
(2) The method for preparing a sugar coating liquid according to (1), wherein the sugar is maltitol.
(3) The method for preparing a sugar coating liquid according to (1) or (2), wherein stirring is performed until oil droplets of the oil-soluble fragrance have an average particle diameter of 1 μm or less.
(4) The method for preparing a sugar coating liquid according to any one of (1) to (3), wherein the sorbitan fatty acid ester is sorbitan monolaurate.
(5) The method for preparing a sugar-coating liquid according to any one of (1) to (4), wherein the oil-soluble fragrance is menthol.
(6) The preparation method of the sugar-coating liquid in any one of (1) thru | or (5) whose addition amount of sorbitan fatty acid ester is 5-200 weight% with respect to oil-soluble fragrance | flavor.
(7) A sugar coating liquid obtained by the method according to any one of (1) to (6).
(8) The sugar-coating liquid according to (7), wherein oil droplets of the oil-soluble fragrance have an average particle diameter of 1 μm or less.
(9) A sugar-coating product obtained using the sugar-coating liquid according to (7) or (8).
(10) The sugar-coated product according to (9), wherein the sugar-coated product is chewing gum.
本発明の方法により、予め油溶性香料を乳化させておく工程を省略でき、乳化が安定した糖衣液の効率的な調製が可能となる。また撹拌時に高圧をかけるなどの特別な装置も必要としない。さらに本発明の方法により、香り立ちの良い糖衣液、糖衣製品を得ることができる。 By the method of the present invention, the step of emulsifying the oil-soluble fragrance in advance can be omitted, and an efficient preparation of a sugar-coating liquid with stable emulsification is possible. Also, no special equipment such as applying high pressure during stirring is required. Furthermore, by the method of the present invention, a sugar-coating liquid and a sugar-coating product having a good fragrance can be obtained.
本発明に用いられる油溶性香料は油溶性であれば特に限定されることはないが、メントールなど、揮発性の芳香物質を含むものが望ましい。 The oil-soluble fragrance used in the present invention is not particularly limited as long as it is oil-soluble, but preferably contains a volatile fragrance such as menthol.
ソルビタン脂肪酸エステルはソルビタンと脂肪酸のエステルで、食品用乳化剤や化粧品・工業用界面活性剤として、単独または他の界面活性剤と併用して、古くから添加物として用いられている。種類としてはソルビタンモノラウレート、ソルビタンモノパルミテート、ソルビタンモノステアレート、ソルビタンモノオレエートなどが知られており、本発明に用いられるソルビタン脂肪酸エステルは、ソルビタンとラウリン酸のエステルであるソルビタンモノラウレートが特に望ましい。 Sorbitan fatty acid ester is an ester of sorbitan and fatty acid, and has been used as an additive for a long time as a food emulsifier or cosmetic / industrial surfactant alone or in combination with other surfactants. As types, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan monooleate and the like are known, and the sorbitan fatty acid ester used in the present invention is sorbitan monolaurate which is an ester of sorbitan and lauric acid. A rate is particularly desirable.
ソルビタンモノラウレートの例としては、エマゾールＬ−１０Ｖ（花王株式会社）、リケマールＬ−２５０Ａ（理研ビタミン株式会社）などが挙げられる。 Examples of sorbitan monolaurate include Emazole L-10V (Kao Corporation), Riquemar L-250A (RIKEN Vitamin Co., Ltd.) and the like.
ソルビタン脂肪酸エステルの添加量は使用する油溶性香料の種類にもよるが、凡その目安として油溶性香料に対し、５〜２００重量％であることが望ましい。添加量が少な過ぎると乳化状態の安定化が十分ではなく、過剰量の場合には乳化の安定という目的は達せられるものの、乳化剤による好ましくない風味が感じられてしまう。 The amount of sorbitan fatty acid ester added depends on the type of oil-soluble fragrance used, but as a rough guide, it is preferably 5 to 200% by weight based on the oil-soluble fragrance. If the addition amount is too small, stabilization of the emulsified state is not sufficient, and if it is excessive, the object of stabilizing the emulsification can be achieved, but an unfavorable flavor due to the emulsifier is felt.
本発明に用いられる糖質は、ショ糖、糖アルコールなどが挙げられるが、齲蝕予防、カロリーの過剰摂取防止の観点から糖アルコールが望ましい。糖アルコールは、一般的に糖衣に用いられるものであれば特に限定されないが、マルチトール、キシリトール、ソルビトール、エリスリトール、イソマルツロース、還元イソマルツロースなどが挙げられ、特にマルチトールが好ましい。 Examples of the saccharide used in the present invention include sucrose and sugar alcohol, and sugar alcohol is preferable from the viewpoint of preventing caries and excessive intake of calories. The sugar alcohol is not particularly limited as long as it is generally used for sugar coating, and examples include maltitol, xylitol, sorbitol, erythritol, isomaltulose, and reduced isomaltulose, and maltitol is particularly preferable.
本発明における糖衣液とは、錠剤やチューインガムなどのセンターの表面に糖衣層を形成するために調製された、糖質やガム質などからなる水溶液のことを指す。そして糖衣製品とは、例えば回転釜で錠剤やチューインガムなどのセンターを回転させながら糖衣液の噴霧と乾燥を繰り返し、糖衣層を設けたものが例示できるが、表面に糖衣層を有する経口組成物であれば特に限定されない。 The sugar-coating liquid in the present invention refers to an aqueous solution composed of a saccharide, a gum or the like prepared to form a sugar-coating layer on the surface of a center such as a tablet or chewing gum. Examples of the sugar-coating product include those in which a sugar-coating liquid is repeatedly sprayed and dried while rotating a center such as a tablet or chewing gum in a rotary kettle, and a sugar-coating layer is provided. If there is no particular limitation.
糖衣液を調製するための混合は、撹拌装置を用いて行われる。撹拌装置の例としては、家庭用ジューサーミキサー、縦型ミキサー、ホモジナイザー、ハンドミキサー、泡立て器などが挙げられる。撹拌の回転数、撹拌時間などは用いる糖質の種類や各成分の配合割合により適宜調節する必要があるが、油溶性香料の油滴の平均粒径が約１μｍ以下になるまで撹拌することが、製品の香り立ちの点で望ましい。 Mixing for preparing the sugar coating liquid is performed using a stirring device. Examples of the stirring device include a home juicer mixer, a vertical mixer, a homogenizer, a hand mixer, and a whisk. The number of rotations of stirring, stirring time, etc. need to be adjusted as appropriate depending on the type of sugar used and the blending ratio of each component, but stirring may be performed until the average particle diameter of oil-soluble fragrance oil droplets is about 1 μm or less This is desirable in terms of product fragrance.
なお本願において油滴の平均粒径は、リガク社製Ｘ線回折装置を用いて測定、算出した。 In the present application, the average particle diameter of the oil droplets was measured and calculated using a Rigaku X-ray diffractometer.
以下、実施例を挙げてさらに詳しく説明するが、本発明はこれらに限定されるものではない。 EXAMPLES Hereinafter, although an Example is given and it demonstrates in more detail, this invention is not limited to these.
実施例１
水３２０ｇ、マルチトール６４０ｇ、アラビアガム４０ｇを混合、溶解した液に、エマゾールＬ−１０Ｖ（花王株式会社製、ＨＬＢ８．６）５ｇ、メントール１０ｇを投入し、縦型ホモジナイザー（株式会社マイクロテック・ニチオン製ＮＳ−５６Ｓ）を用いて２３５００ｒｐｍで３分間撹拌混合し、糖衣液を得た。得られた糖衣液中のメントールの粒径を測定したところ、その平均値は０．６μｍであった。そして得られた乳化液は乳化が安定し、メントールの香りが十分に感じられる、香り立ちのいいものであった。
Example 1
To a solution obtained by mixing and dissolving 320 g of water, 640 g of maltitol, and 40 g of gum arabic, 5 g of Emazole L-10V (manufactured by Kao Corporation, HLB 8.6) and 10 g of menthol were added, and a vertical homogenizer (Microtech Nichion Co., Ltd.). Using NS-56S), the mixture was stirred and mixed at 23500 rpm for 3 minutes to obtain a sugar coating liquid. When the particle size of menthol in the obtained sugar coating liquid was measured, the average value was 0.6 μm. The obtained emulsified liquid was stable in emulsification and had a good scent with a sufficient scent of menthol.
実施例２
水３２０ｇ、マルチトール６４０ｇ、アラビアガム４０ｇを混合、溶解した液に、エマゾールＬ−１０Ｖ（花王株式会社製、ＨＬＢ８．６）５ｇ、メントール１０ｇを投入し、家庭用ジューサーミキサー（テスコム社製ＴＭ８３６）を用いて、１００００ｒｐｍで１分間撹拌混合し、糖衣液を得た。得られた糖衣液中のメントールの粒径を測定したところ、その平均値は０．５μｍであった。そして得られた乳化液は乳化が安定し、メントールの香りが十分に感じられる、香り立ちのいいものであった。
Example 2
To a solution obtained by mixing and dissolving 320 g of water, 640 g of maltitol, and 40 g of gum arabic, 5 g of Emazole L-10V (manufactured by Kao Corporation, HLB8.6) and 10 g of menthol were added, and a home juicer mixer (TM836 manufactured by Tescom). Was mixed with stirring at 10,000 rpm for 1 minute to obtain a sugar coating liquid. When the particle size of menthol in the obtained sugar coating liquid was measured, the average value was 0.5 μm. The obtained emulsified liquid was stable in emulsification and had a good scent with a sufficient scent of menthol.
実施例３
水３２０ｇ、キシリトール３００ｇ、マルチトール３００ｇ、アラビアガム４０ｇを混合、溶解した液に、エマゾールＬ−１０Ｖ（花王株式会社製、ＨＬＢ８．６）０．７５ｇ、オレンジオイル１５ｇを投入し、縦型ホモジナイザー（株式会社マイクロテック・ニチオン製ＮＳ−５６Ｓ）を用いて２３５００ｒｐｍで２分間撹拌混合し、糖衣液を得た。得られた糖衣液中のオレンジオイルの粒径を測定したところ、その平均値は０．５μｍであった。そして得られた乳化液は乳化が安定し、オレンジの香りが十分に感じられる、香り立ちのいいものであった。
Example 3
To a solution obtained by mixing and dissolving 320 g of water, 300 g of xylitol, 300 g of maltitol, and 40 g of gum arabic, 0.75 g of Emazole L-10V (manufactured by Kao Corporation, HLB8.6) and 15 g of orange oil were added, and a vertical homogenizer ( The mixture was stirred and mixed at 23500 rpm for 2 minutes using NS-56S manufactured by Microtech Nichion Co., Ltd. to obtain a sugar coating solution. When the particle size of the orange oil in the obtained sugar coating liquid was measured, the average value was 0.5 μm. The obtained emulsified liquid was stable in emulsification and had a good scent with a sufficient orange scent.
実施例４
水３２０ｇ、マルチトール６４０ｇ、アラビアガム４０ｇを混合、溶解した液に、リケマールＬ−２５０Ａ（理研ビタミン株式会社製、ＨＬＢ７．４）５ｇ、メントール１０ｇを投入し、家庭用ジューサーミキサー（テスコム社製ＴＭ８３６）を用いて、１００００ｒｐｍで１分間撹拌混合し、糖衣液を得た。得られた糖衣液中のメントールの粒径を測定したところ、その平均値は０．７μｍであった。そして得られた乳化液は乳化が安定し、メントールの香りが十分に感じられる、香り立ちのいいものであった。
Example 4
To a solution obtained by mixing and dissolving 320 g of water, 640 g of maltitol, and 40 g of gum arabic, 5 g of Riquemar L-250A (manufactured by Riken Vitamin Co., Ltd., HLB7.4) and 10 g of menthol are added, and a household juicer mixer (TM836 manufactured by Tescom) is added. ) And stirred and mixed at 10,000 rpm for 1 minute to obtain a sugar coating liquid. When the particle size of menthol in the obtained sugar coating liquid was measured, the average value was 0.7 μm. The obtained emulsified liquid was stable in emulsification and had a good scent with a sufficient scent of menthol.
実施例５
水３２０ｇ、マルチトール６４０ｇ、アラビアガム４０ｇを混合、溶解した液に、エマゾールＬ−１０Ｖ（花王株式会社製、ＨＬＢ８．６）２０ｇ、メントール１０ｇを投入し、ヒスコトロン（株式会社マイクロテック・ニチオン製ホモジナイザー）を用いて３分間撹拌混合し、糖衣液を得た。得られた糖衣液中のメントールの粒径を測定したところ、その平均値は１．５μｍであった。そして得られた乳化液は乳化が安定し、メントールの香りが感じられる、香り立ちのいいものであった。
Example 5
To a solution obtained by mixing and dissolving 320 g of water, 640 g of maltitol, and 40 g of gum arabic, 20 g of Emazole L-10V (manufactured by Kao Corporation, HLB8.6) and 10 g of menthol were added. ) For 3 minutes with stirring to obtain a sugar coating solution. When the particle size of menthol in the obtained sugar coating liquid was measured, the average value was 1.5 μm. And the obtained emulsified liquid was stable in emulsification and had a good scent with a menthol scent.
実施例６
水３２０ｇ、マルチトール６４０ｇ、アラビアガム４０ｇを混合、溶解した液に、エマゾールＬ−１０Ｖ（花王株式会社製、ＨＬＢ８．６）２０ｇ、メントール１０ｇを投入し、泡立て器を用いて手作業で３分間撹拌混合し、糖衣液を得た。得られた糖衣液中のメントールの粒径を測定したところ、その平均値は６０μｍであった。そして得られた乳化液はほぼ均質に乳化しており、メントールの香りも感じられるものであった。
Example 6
Into a solution obtained by mixing and dissolving 320 g of water, 640 g of maltitol, and 40 g of gum arabic, 20 g of Emazole L-10V (manufactured by Kao Corporation, HLB8.6) and 10 g of menthol are added, and manually for 3 minutes using a whisk. The mixture was stirred and mixed to obtain a sugar coating liquid. When the particle size of menthol in the obtained sugar coating liquid was measured, the average value was 60 μm. And the obtained emulsion was emulsified almost uniformly, and the scent of menthol was also felt.
比較例１
水３２０ｇ、マルチトール６４０ｇ、アラビアガム４０ｇを混合、溶解した液に、リョートーシュガーエステルＳ−９７０（三菱化学フーズ株式会社製 ショ糖ステアリン酸エステル、ＨＬＢ９）５ｇ、メントール１０ｇを投入し、家庭用ジューサーミキサー（テスコム社製ＴＭ８３６）を用いて、１００００ｒｐｍで１分間撹拌混合し、糖衣液を得た。得られた糖衣液はすぐに乳化が崩れ始め、メントールが表面に浮いてしまい、乳化が安定した糖衣液を得ることはできなかった。
Comparative Example 1
To a solution obtained by mixing and dissolving 320 g of water, 640 g of maltitol, and 40 g of gum arabic, 5 g of Ryoto Sugar Ester S-970 (Mitsubishi Chemical Foods Co., Ltd., sucrose stearate ester, HLB9) and 10 g of menthol are introduced. Using a juicer mixer (TM836 manufactured by Tescom), the mixture was stirred and mixed at 10,000 rpm for 1 minute to obtain a sugar coating solution. The obtained sugar coating liquid immediately started to lose its emulsification, menthol floated on the surface, and a sugar coating liquid with stable emulsification could not be obtained.
比較例２
水３２０ｇ、マルチトール６４０ｇ、アラビアガム４０ｇを混合、溶解した液に、サンソフトＮｏ．６８１（太陽化学社製 コハク酸モノステアリン酸グリセリン、ＨＬＢ８．５）５ｇ、メントール１０ｇを投入し、家庭用ジューサーミキサー（テスコム社製ＴＭ８３６）を用いて、１００００ｒｐｍで１分間撹拌混合し、糖衣液を得た。得られた糖衣液はすぐに乳化が崩れ始め、メントールが表面に浮いてしまい、乳化が安定した糖衣液を得ることはできなかった。
Comparative Example 2
In a solution obtained by mixing and dissolving 320 g of water, 640 g of maltitol and 40 g of gum arabic, 681 (glycerin succinate monostearate manufactured by Taiyo Kagaku Co., Ltd., HLB8.5) and 10 g of menthol were added, and the mixture was stirred and mixed at 10,000 rpm for 1 minute using a household juicer mixer (TM836 manufactured by Tescom). Obtained. The obtained sugar coating liquid immediately started to lose its emulsification, menthol floated on the surface, and a sugar coating liquid with stable emulsification could not be obtained.
比較例３
水３２０ｇ、マルチトール６４０ｇ、アラビアガム４０ｇを混合、溶解した液に、サンレシチンＡ−１（太陽化学社製 酵素分解レシチン）５ｇ、メントール１０ｇを投入し、家庭用ジューサーミキサー（テスコム社製ＴＭ８３６）を用いて、１００００ｒｐｍで１分間撹拌混合し、糖衣液を得た。得られた糖衣液はすぐに乳化が崩れ始め、メントールが表面に浮いてしまい、乳化が安定した糖衣液を得ることはできなかった。
Comparative Example 3
To a solution obtained by mixing and dissolving 320 g of water, 640 g of maltitol, and 40 g of gum arabic, 5 g of sun lecithin A-1 (enzymatically decomposed lecithin manufactured by Taiyo Chemical Co., Ltd.) and 10 g of menthol were added, and a home juicer mixer (TM836 manufactured by Tescom). Was mixed with stirring at 10,000 rpm for 1 minute to obtain a sugar coating liquid. The obtained sugar coating liquid immediately started to lose its emulsification, menthol floated on the surface, and a sugar coating liquid with stable emulsification could not be obtained.
実施例７
水３２０ｇ、マルチトール６４０ｇ、アラビアガム４０ｇを混合、溶解した液に、エマゾールＬ−１０Ｖ（花王株式会社製、ＨＬＢ８．６）０．３ｇ、メントール１０ｇを投入し、家庭用ジューサーミキサー（テスコム社製ＴＭ８３６）を用いて、１００００ｒｐｍで１分間撹拌混合し、糖衣液を得た。得られた糖衣液中のメントールの粒径を測定したところ、その平均値は０．８μｍであった。そして得られた乳化液はほぼ均質に乳化しており、メントールの香りも感じられるものであった。
Example 7
To a solution obtained by mixing and dissolving 320 g of water, 640 g of maltitol, and 40 g of gum arabic, 0.3 g of Emazole L-10V (manufactured by Kao Corporation, HLB8.6) and 10 g of menthol were added, and a home juicer mixer (manufactured by Tescom) Using TM836), the mixture was stirred and mixed at 10,000 rpm for 1 minute to obtain a sugar coating liquid. When the particle size of menthol in the obtained sugar coating liquid was measured, the average value was 0.8 μm. And the obtained emulsion was emulsified almost uniformly, and the scent of menthol was also felt.
比較例４
水３２０ｇ、マルチトール６４０ｇ、アラビアガム４０ｇを混合、溶解した液に、メントール１０ｇを投入し、家庭用ジューサーミキサー（テスコム社製ＴＭ８３６）を用いて、１００００ｒｐｍで撹拌混合を続けたが、メントールは乳化することなく、糖衣液を得ることはできなかった。
Comparative Example 4
10 g of menthol was added to a solution in which 320 g of water, 640 g of maltitol and 40 g of gum arabic were mixed and dissolved, and stirring and mixing were continued at 10,000 rpm using a household juicer mixer (TM836 manufactured by Tescom). The sugar coating liquid could not be obtained without this.
実施例８
直径９００ｍｍの回転釜に芯物質となるチューインガムセンター１ｋｇを投入し、２５ｒｐｍで回転させながら実施例１で得られた糖衣液０．５ｋｇを数回に分けて噴霧し、２時間回転を続け本発明の糖衣チューインガムを得た。得られたチューインガムは口に入れた瞬間からメントールの香りが十分に感じられるものであった。
Example 8
1 kg of chewing gum center as a core substance is put into a rotary kettle with a diameter of 900 mm, and 0.5 kg of the sugar coating liquid obtained in Example 1 is sprayed in several portions while rotating at 25 rpm, and the rotation is continued for 2 hours. Of sugar-coated chewing gum. The obtained chewing gum had a sufficient menthol scent from the moment it was put in the mouth.
実施例９
実施例６で得られた糖衣液を用いて、実施例８と同様の方法で本発明の糖衣チューインガムを得た。得られたチューインガムは、実施例８で得られたものと比べるとメントールの香り立ちが少し弱かったものの、すべてのチューインガムに香料を均一に分散させることができた。
Example 9
The sugar-coating chewing gum of the present invention was obtained in the same manner as in Example 8, using the sugar-coating liquid obtained in Example 6. Although the obtained chewing gum had a slightly weak menthol fragrance compared with that obtained in Example 8, the fragrance could be uniformly dispersed in all chewing gums.
実施例１０
水３２０ｇ、マルチトール６４０ｇ、アラビアガム４０ｇを混合、溶解した液に、エマゾールＬ−１０Ｖ（花王株式会社製、ＨＬＢ８．６）２５ｇ、メントール１０ｇを投入し、家庭用ジューサーミキサー（テスコム社製ＴＭ８３６）を用いて、１００００ｒｐｍで１分間撹拌混合し、糖衣液を得た。得られた糖衣液中のメントールの粒径を測定したところ、その平均値は０．５μｍであった。そして得られた乳化物は乳化が安定し、メントールの香りが十分に感じられる、香り立ちのいいものであった。
得られた糖衣液を用いて実施例８と同様の方法で糖衣チューインガムを得た。得られたチューインガムは、口に入れた瞬間はメントールの香りが十分に感じられたものの、噛み始めるとともに乳化剤特有の苦みも感じられ、あまり好ましいものではなかった。
Example 10
To a solution obtained by mixing and dissolving 320 g of water, 640 g of maltitol, and 40 g of gum arabic, 25 g of Emazole L-10V (manufactured by Kao Corporation, HLB8.6) and 10 g of menthol were added, and a home juicer mixer (TM836 manufactured by Tescom). Was mixed with stirring at 10,000 rpm for 1 minute to obtain a sugar coating liquid. When the particle size of menthol in the obtained sugar coating liquid was measured, the average value was 0.5 μm. The obtained emulsion was stable and emulsified, and the scent of menthol was sufficiently felt, giving it a good scent.
Sugar coating chewing gum was obtained in the same manner as in Example 8 using the obtained sugar coating liquid. The obtained chewing gum was not very preferable because it had a sufficient menthol scent when it was put into the mouth, but also began to chew and felt bitterness peculiar to emulsifiers.
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