JP2016154500A - Production method of container-packed tea beverage retaining excellent flavor and umami taste - Google Patents

Production method of container-packed tea beverage retaining excellent flavor and umami taste Download PDF

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JP2016154500A
JP2016154500A JP2015035714A JP2015035714A JP2016154500A JP 2016154500 A JP2016154500 A JP 2016154500A JP 2015035714 A JP2015035714 A JP 2015035714A JP 2015035714 A JP2015035714 A JP 2015035714A JP 2016154500 A JP2016154500 A JP 2016154500A
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tea
tea beverage
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umami
sterilization
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貴史 塩野
Takashi Shiono
貴史 塩野
祐子 四元
Yuko Yotsumoto
祐子 四元
広幸 長沼
Hiroyuki Naganuma
広幸 長沼
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Kirin Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a production method of container-packed tea beverage that can complement and enhance the flavor and umami of a tea beverage deteriorated during heat sterilization treatment and, in addition, can retain its excellent flavor and umami for a long period of time after production.SOLUTION: In a production method of a container-packed tea beverage a container-packed tea beverage, which can retain its excellent flavor and umami for a long period of time while suppressing an increase in deterioration odor, is provided by (1) containing a methyl methionine sulfonium salt in an amount of 0.001-0.15 pts.wt. with respect to 1 pts.wt. of the total polyphenols derived from tea and performing heat sterilization of the tea beverage by UHT sterilization under a condition having an F value is 10-20, or (2) containing a methyl methionine sulfonium salt in an amount of 0.001-0.15 pts.wt. with respect to 1 pts.wt. of the total polyphenols derived from tea, adding 0.001-0.1v/v% ethanol or 0.001-0.1v/v% propylene glycol to the tea beverage, and performing heat sterilization of the tea beverage by UHT sterilization under a condition having an F value is 1-20.SELECTED DRAWING: None

Description

本発明は、容器詰茶飲料の製造時の加熱殺菌処理において低下する茶飲料の香味及び旨味を補完、増強した上で、その優れた香味及び旨味を、劣化臭の増加を抑えつつ、製造後も長期間持続できる容器詰茶飲料を製造する方法、及び該方法によって製造された優れた香味と旨味が持続する容器詰茶飲料に関する。   The present invention complements and enhances the flavor and umami of tea beverages that are reduced in the heat sterilization treatment during the manufacture of packaged tea beverages, and after the manufacture, while suppressing the increase in deteriorated odors, with excellent flavor and umami. The present invention also relates to a method for producing a containerized tea beverage that can be sustained for a long period of time, and a containerized tea beverage that is produced by the method and has excellent flavor and umami.

茶飲料の中でも手軽に飲用できる容器詰茶飲料は近年の主流となっており、多くの商品が市場に流通、販売されている。消費者の嗜好の多様化に伴い、茶飲料の香味の差別化ならびに高付加価値化が望まれており、容器詰茶飲料が製造後一定期間の間に消費されるという点を鑑みると、当該香味品質の持続、ということに関しても関心が高い。   Container-packed tea beverages that can be easily consumed among tea beverages have become the mainstream in recent years, and many products are distributed and sold in the market. With the diversification of consumer tastes, it is desired to differentiate the flavor of tea beverages and increase the added value, and in view of the fact that packaged tea beverages are consumed for a certain period after production, There is also a great deal of interest in maintaining flavor quality.

上記ニーズに伴い、容器詰茶飲料の製造に際して、茶飲料の香味や呈味を増強する試みは以前より行われている。茶原料の中には高級玉露のように、もともと旨味の強い茶もあるが、これらの茶葉を用いても加熱殺菌による風味低下は十分に抑制できない一方、生産量や価格の面でも容器詰茶飲料用の原料として工業的に使用することは難しい。   In connection with the above needs, attempts have been made to enhance the flavor and taste of tea beverages in the manufacture of packaged tea beverages. Some tea ingredients, such as high-quality gyokuro, originally have a strong flavor, but even with these tea leaves, the deterioration of flavor due to heat sterilization cannot be sufficiently suppressed, but in terms of production volume and price, it is also packaged tea. It is difficult to use industrially as a raw material for beverages.

従来より、茶系飲料の旨味や香味を増強する手段として、茶葉抽出に際して酵素剤を添加して抽出する方法や、グルタミン酸、核酸等の香味成分を添加する方法等が知られている。酵素剤を添加して抽出する方法としては、例えば、特公昭46−17958号公報には、プロトペクチナーゼとセルラーゼを併用して茶葉を抽出する方法が、特公昭52−42877号公報には、紅茶葉をタンナーゼで処理する方法が、特公平1−47979号公報には、α−アミラーゼ、β−アミラーゼ、セルラーゼ、及びプロテアーゼから選択した酵素の混合物により処理して抽出する方法が開示されている。   Conventionally, as means for enhancing the umami and flavor of tea-based beverages, a method of extracting by adding an enzyme agent during tea leaf extraction, a method of adding flavor components such as glutamic acid and nucleic acid, and the like are known. As a method for extracting by adding an enzyme agent, for example, Japanese Patent Publication No. 46-17958 discloses a method of extracting tea leaves by using protopectinase and cellulase in combination, and Japanese Patent Publication No. 52-42877 discloses black tea. Japanese Patent Publication No. 1-447979 discloses a method of treating leaves with tannase, and a method of treating and extracting leaves with a mixture of enzymes selected from α-amylase, β-amylase, cellulase, and protease is disclosed.

特開2003−144049号公報には、茶葉原料を、プロテアーゼ及びタンナーゼの存在下で処理する方法が、特開2008−67631号公報には、緑茶葉をプロテアーゼ存在下で抽出処理し、得られた抽出液に更にプロテアーゼを作用させて茶エキスを得る方法が、特開2009−95333号公報には、茶葉からカテキン類の少なくとも一部を除去し、この茶葉をプロテアーゼ、セルラーゼ、ペクチナーゼから選択される1種以上の酵素を用いて酵素抽出する方法が開示されている。   Japanese Patent Laid-Open No. 2003-144049 discloses a method of treating tea leaf raw materials in the presence of protease and tannase, and Japanese Patent Laid-Open No. 2008-67631 obtained green tea leaves in the presence of protease. JP-A-2009-95333 discloses a method for removing a catechin from tea leaves, and the tea leaves are selected from protease, cellulase, and pectinase. A method of enzyme extraction using one or more enzymes is disclosed.

また、香味成分を添加する方法としては、例えば、特開2007−110988号公報には、テアニンや3−ガロイルキナ酸、コハク酸を添加することによる茶の風味増強方法が開示されている。しかし、これらの方法でも加熱殺菌処理後の風味低下は十分には抑えられず、加熱殺菌処理後の香味品質としては十分満足いくものではなかった。他には、加熱殺菌処理後の風味低下を考慮して、上記物質を大量に配合することが考えられるが、風味そのものが人工的になり、自然な茶の風味とはかけ離れるといった点が課題であった。   In addition, as a method for adding a flavor component, for example, JP 2007-110988 discloses a method for enhancing the flavor of tea by adding theanine, 3-galloylquinic acid, and succinic acid. However, even with these methods, the flavor reduction after the heat sterilization treatment cannot be sufficiently suppressed, and the flavor quality after the heat sterilization treatment is not sufficiently satisfactory. In addition, it is conceivable to add a large amount of the above substances in consideration of flavor reduction after heat sterilization treatment, but the flavor itself becomes artificial, and it is a problem that it is far from the natural tea flavor Met.

容器詰茶飲料において、加熱殺菌処理工程などの加熱工程で、茶飲料が有している香味が消失又は変質してしまうという課題を解決するための方法も各種提案されている。例えば、特開2005−160416号公報には、茶の生の葉或いは酵素を失活した葉を摘採後凍結処理し、該凍結した茶葉を水蒸気蒸留して得られる留出液を配合してフレッシュで耐熱性のある香気・香味が付与された密閉容器入り緑茶飲料が、特開平05−317013号公報には、フィチン酸を添加することによって、加熱殺菌条件を軽減し、原料の新鮮な風味をより多く保持した茶飲料等の製造方法が、特開2009−89641号公報には、茶葉を熱水で抽出して、花香成分であるホトリエノール(3,7−ジメチルオクタ−1,5,7−トリエン−3−オール)を含む抽出液を得、該抽出液にアスコルビン酸類を添加して調合液を得て、該調合液を加熱殺菌したものを、容器に充填する茶飲料の製造方法が開示されている。   Various methods for solving the problem that the flavor of tea beverages disappears or deteriorates in a heating step such as a heat sterilization treatment step in packaged tea beverages have been proposed. For example, Japanese Patent Application Laid-Open No. 2005-160416 discloses a fresh tea by blending a distillate obtained by plucking fresh leaves of tea or leaves inactivated enzymes and then subjecting the frozen tea leaves to steam distillation. A green tea beverage in a sealed container with a heat-resistant fragrance and flavor is disclosed in Japanese Patent Application Laid-Open No. 05-317013. By adding phytic acid, the heat sterilization conditions are reduced, and the fresh flavor of the raw material is improved. Japanese Patent Application Laid-Open No. 2009-89641 discloses a method for producing a more retained tea beverage or the like, in which tea leaves are extracted with hot water, and florenol (3,7-dimethylocta-1,5,7- Disclosed is a method for producing a tea beverage in which an extract containing trien-3-ol) is obtained, a preparation is obtained by adding ascorbic acids to the extract, and the preparation is heated and sterilized. Has been.

しかしながら、これらの方法も、その工程が複雑であったり、また、加熱殺菌処理後の茶飲料が、茶飲料の自然な茶の風味及び呈味を保持するという点では十分なものではなかったりしていた。したがって、容器詰茶飲料の製造方法において、製造時の加熱殺菌処理において低下する茶飲料の香味及び旨味を補完し、茶飲料が自然な茶の風味を保持し、香味及び旨味が増強された容器詰茶飲料を提供する観点からは満足のいくものではなかった。また、その香味及び旨味を持続するという観点では具体的な技術の提案はなされていない状況であった。   However, these methods are also complicated in the process, and are not sufficient in that the tea beverage after the heat sterilization treatment retains the natural tea flavor and taste of the tea beverage. It was. Therefore, in the method for producing a container-packed tea beverage, a container in which the flavor and umami of the tea beverage, which decreases during the heat sterilization treatment at the time of production, is complemented, and the tea beverage retains the natural tea flavor and the flavor and umami are enhanced. From the perspective of providing stuffed tea beverages, it was not satisfactory. In addition, no specific technology has been proposed from the viewpoint of maintaining the flavor and umami.

他方で、メチルメチオニンスルホニウム関連物質ならびにそれを含む植物体を用いて、緑茶の香味改善等を行う方法が開示されている。例えば、特開昭50−40796号公報には、緑茶の香味改良法として、メチルメチオニンスルホニウムと、有機酸、酸性アミノ酸及び5’−ヌクレオタイドから選択された化合物との塩を調製し、該成分を緑茶に噴霧したり、或いは、緑茶製造工程における茶葉の揉捻時に添加したりすることにより、緑茶の飲用に際して60〜80℃の湯を加えた時に香味を発生せしめる、緑茶の香味改良方法が開示されている。しかし、この方法は、緑茶葉の処理による香味改善方法であって、容器詰等の茶飲料の製造における香味改善技術に関するものではない。また、茶飲料の製造に際して、キャベツや、ケール等を添加する方法も開示されている。例えば、特開平11−332530号公報には、ケールの微粉末と、不発酵茶、半発酵茶微粉末を含有させ、栄養成分を補給した、ケール含有飲料について、特開2005−151856号公報には、大麦、ハト麦とタマネギを含有する茶飲料に、キャベツやアスパラガスを含有させた茶飲料が開示されている。これらの飲料は、茶飲料等に、ケールや、キャベツ等の野菜の栄養成分を補給させているだけのものであり、メチルメチオニンスルホニウムのような特定成分を含有せしめて、容器詰茶飲料の製造における香味の改善を図る技術に関するものではない。   On the other hand, a method for improving the flavor of green tea using a methylmethionine sulfonium-related substance and a plant containing the same is disclosed. For example, in JP-A-50-40796, as a method for improving the flavor of green tea, a salt of methylmethioninesulfonium and a compound selected from an organic acid, an acidic amino acid and 5′-nucleotide is prepared, Disclosed is a method for improving the flavor of green tea by causing the flavor to be generated when hot water at 60 to 80 ° C. is added when drinking green tea by spraying the green tea on the green tea or by adding it when twisting the tea leaves in the green tea production process Has been. However, this method is a flavor improvement method by processing green tea leaves, and is not related to a flavor improvement technique in the production of tea beverages such as containers. In addition, a method of adding cabbage, kale or the like when manufacturing a tea beverage is also disclosed. For example, JP-A-11-332530 discloses a kale-containing beverage that contains a fine powder of kale, a non-fermented tea, and a semi-fermented tea fine powder and supplements with nutrients, as disclosed in JP-A-2005-151856. Discloses a tea beverage containing cabbage or asparagus in a tea beverage containing barley, pigeon and onion. These beverages are made only by supplementing tea beverages with nutritional components of vegetables such as kale and cabbage, and contain a specific component such as methylmethionine sulfonium to produce a packaged tea beverage. It is not related to the technology to improve the flavor in

また、本発明者らは、先に、容器詰茶飲料の製造方法において、メチルメチオニンスルホニウム塩を茶抽出液に含有させ、加熱殺菌することで、加熱殺菌処理において低下する茶飲料の香味及び旨味を補完し、香味及び旨味を増強した容器詰茶飲料を製造する方法を開発し、開示した(特開2012−130314号公報)。該方法により、容器詰茶飲料の製造時の加熱殺菌処理による香味の劣化や、旨味の低下に対する香味及び旨味の補完や、改善についての成果は得られたものの、該製造方法により得られた容器詰茶飲料を長期間保存した場合に、増強した香味及び旨味が著しく減少するという新たな課題を見出した。   In addition, the present inventors previously described that in the method for producing a packaged tea beverage, the flavor and umami of the tea beverage, which is reduced in the heat sterilization treatment, by adding methyl methionine sulfonium salt to the tea extract and sterilizing by heat. Has been developed and disclosed (Japanese Patent Laid-Open No. 2012-130314) for producing a packaged tea beverage with enhanced flavor and umami. Although the results of the deterioration of the flavor due to the heat sterilization treatment during the production of the container-packed tea beverage and the complementation and improvement of the flavor and umami for the decrease in umami were obtained by the method, the container obtained by the production method The present inventors have found a new problem that the enhanced flavor and umami significantly decrease when the stuffed tea beverage is stored for a long period of time.

特公昭46−17958号公報。Japanese Patent Publication No. 46-17958. 特公昭52−42877号公報。Japanese Patent Publication No. 52-42877. 特公平1−47979号公報。Japanese Patent Publication No. 1-47979. 特開昭50−40796号公報。Japanese Patent Application Laid-Open No. 50-40796. 特開平05−317013号公報。Japanese Patent Laid-Open No. 05-317013. 特開平11−332530号公報。Japanese Patent Application Laid-Open No. 11-332530. 特開2003−144049号公報。JP2003-144049A. 特開2005−151856号公報。Japanese Patent Application Laid-Open No. 2005-151856. 特開2005−160416号公報。JP-A-2005-160416. 特開2007−110988号公報。JP2007-110988A. 特開2008−67631号公報。JP 2008-67631 A. 特開2009−89641号公報。JP 2009-89641 A. 特開2009−95333号公報。JP 2009-95333 A. 特開2012−130314号公報。Unexamined-Japanese-Patent No. 2012-130314.

本発明の課題は、容器詰茶飲料の製造時の加熱殺菌処理において低下する茶飲料の香味及び旨味を補完、増強した上で、その優れた香味及び旨味を、劣化臭の増加を抑えつつ、長期間持続できる容器詰茶飲料、及び、該容器詰茶飲料を製造する方法を提供することにある。   The problem of the present invention is to supplement and enhance the flavor and umami of a tea beverage that is reduced in the heat sterilization treatment at the time of producing a packaged tea beverage, while suppressing the increase in the deterioration odor, while improving the excellent flavor and umami. The object is to provide a packaged tea beverage that can last for a long period of time, and a method for producing the packaged tea beverage.

本発明者らは、先に、容器詰茶飲料の製造方法において、メチルメチオニンスルホニウム塩を茶抽出液に含有させ、加熱殺菌することで、加熱殺菌処理において低下する茶飲料の香味及び旨味を補完し、香味及び旨味を増強した容器詰茶飲料を製造する方法を見出し、開示した(特開2012−130314号公報)。しかし、該製造方法により得られた容器詰茶飲料を長期間保存した場合に、増強した香味及び旨味が著しく減少するという新たな課題を見出した。そこで、本発明者らは、該開示の方法を、更に発展させ、茶飲料の製造時の加熱殺菌処理において低下する茶飲料の香味及び旨味を補完、増強し、その香味及び旨味を、劣化臭の増加を抑えつつ、長期間維持できる効果的方法について鋭意検討する中で、メチルメチオニンスルホニウム塩を特定量含有させた茶抽出液を、特定の加熱殺菌手段により、特定の条件下で加熱殺菌処理をするか、或いは、該メチルメチオニンスルホニウム塩の含有の下に、更に、特定の成分を添加し、特定の加熱殺菌手段により、特定の条件下で加熱殺菌処理をすることにより、加熱殺菌処理で低下する茶飲料の香味及び旨味の補完、増強を効果的に行うことが可能であり、そして、保存時の劣化臭の増加が抑えられた、優れた香味及び旨味を長期間持続できる容器詰茶飲料を製造することが可能であることを見出し、本発明を完成するに至った。   The inventors of the present invention previously supplemented the flavor and umami of a tea beverage, which is reduced in a heat sterilization treatment, by containing methyl methionine sulfonium salt in the tea extract and heat sterilizing in the method for producing a packaged tea beverage. And a method for producing a packaged tea beverage with enhanced flavor and umami was found and disclosed (Japanese Patent Laid-Open No. 2012-130314). However, the present inventors have found a new problem that the enhanced flavor and umami significantly decrease when the packaged tea beverage obtained by the production method is stored for a long period of time. Accordingly, the present inventors have further developed the disclosed method to complement and enhance the flavor and umami of tea beverages that are reduced in the heat sterilization treatment during the production of tea beverages, In an eager study of an effective method that can be maintained for a long time while suppressing the increase in the amount of tea, the tea extract containing a specific amount of methylmethionine sulfonium salt is heat-sterilized under specific conditions by specific heat-sterilizing means. Or by adding a specific component under the presence of the methylmethionine sulfonium salt and subjecting it to heat sterilization under specific conditions by a specific heat sterilization means. It is possible to effectively supplement and enhance the reduced flavor and umami of tea beverages, and to suppress the increase in deterioration odor during storage and to maintain excellent flavor and umami for a long time. It found that it is possible to manufacture the packaged tea drinks, which resulted in the completion of the present invention.

すなわち本発明は、容器詰茶飲料の製造方法において、(1)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、該茶飲料を、UHT殺菌により、F値10〜20の条件で、加熱殺菌を行うか、或いは、(2)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、更に、茶飲料に対して、0.001〜0.1v/v%のエタノール、又は、0.001〜0.1v/v%のプロピレングリコールを添加して、該茶飲料を、UHT殺菌により、F値1〜20の条件で、加熱殺菌を行うことにより、保存時の劣化臭の増加が抑えられた、優れた香味と旨味を長期間持続できる容器詰茶飲料を製造する方法からなる。   That is, the present invention relates to a method for producing a container-packed tea beverage, wherein (1) 0.001 to 0.15 parts by weight of methylmethionine sulfonium salt is contained with respect to 1 part by weight of tea-derived total polyphenol, Or heat sterilization under conditions of F value of 10 to 20 by UHT sterilization, or (2) 0.001 to 0.15 parts by weight of methylmethionine with respect to 1 part by weight of total polyphenol derived from tea A sulfonium salt is contained, and 0.001 to 0.1 v / v% ethanol or 0.001 to 0.1 v / v% propylene glycol is added to the tea beverage, and the tea beverage is added. By sterilizing by heating under the condition of F value of 1 to 20 by UHT sterilization, manufacture of packaged tea beverages that can maintain excellent flavor and umami for a long period of time, with suppressed increase in deterioration odor during storage how to Ranaru.

本発明の容器詰茶飲料の製造方法において、茶飲料に含有させるメチルメチオニンスルホニウム塩、特にメチルメチオニンスルホニウムクロライドは、ケール、キャベツ、又は、ブロッコリー由来の抽出物として調製することができる。本発明の容器詰茶飲料の製造方法において、UHT殺菌による加熱温度は、適宜の温度範囲で設定することができるが、通常、110℃〜145℃の範囲で設定することができる。   In the method for producing a packaged tea beverage of the present invention, the methylmethionine sulfonium salt, particularly methylmethionine sulfonium chloride, contained in the tea beverage can be prepared as an extract derived from kale, cabbage, or broccoli. In the method for producing a packaged tea beverage of the present invention, the heating temperature by UHT sterilization can be set in an appropriate temperature range, but can usually be set in the range of 110 ° C to 145 ° C.

本発明の容器詰茶飲料の製造方法において、UHT殺菌の条件として用いられるF値とは、基準温度(121.1℃)で一定数の微生物を死滅させるのに要する加熱時間(分)であって、121.1℃における加熱時間として定義される。例えば、F=1と同等の殺菌条件とは、111.1℃では10分、121.1℃では1分、F=20と同等の殺菌条件とは、121.1℃では20分、137.2℃では30秒のように設定できる。   In the method for producing a packaged tea beverage of the present invention, the F value used as the condition for UHT sterilization is the heating time (minutes) required to kill a certain number of microorganisms at the reference temperature (121.1 ° C.). And defined as the heating time at 121.1 ° C. For example, sterilization conditions equivalent to F = 1 are 10 minutes at 111.1 ° C., 1 minute at 121.1 ° C., and sterilization conditions equivalent to F = 20 are 20 minutes at 121.1 ° C. It can be set to 30 seconds at 2 ° C.

容器詰茶飲料の製造方法は、不発酵茶、半発酵茶、発酵茶、後発酵茶等の各種茶飲料の製造に対して適用できるが、特に望ましい茶飲料としては、緑茶飲料を挙げることができる。   The method for producing a containerized tea beverage can be applied to the production of various tea beverages such as non-fermented tea, semi-fermented tea, fermented tea, post-fermented tea, and particularly desirable tea beverages include green tea beverages. it can.

本発明は、本発明の容器詰茶飲料の製造方法によって製造された、優れた香味及び旨味を、劣化臭の増加を抑えつつ、長期間持続できる容器詰茶飲料の発明を包含する。   The present invention includes the invention of a packaged tea beverage that can be maintained for a long period of time while suppressing an increase in a deteriorated odor, with excellent flavor and umami produced by the method for producing a packaged tea beverage of the present invention.

また、本発明は、容器詰茶飲料の製造において、(1)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、該茶飲料を、UHT殺菌により、F値10〜20の条件で、加熱殺菌を行うか、或いは、(2)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、更に、茶飲料に対して、0.001〜0.1v/v%のエタノール、又は、0.001〜0.1v/v%のプロピレングリコールを添加して、該茶飲料を、UHT殺菌により、F値1〜20の条件で、加熱殺菌を行うことにより、保存時の劣化臭の増加を抑えつつ、優れた香味及び旨味を長期間持続させることを特徴とする容器詰茶飲料における飲料の香味及び旨味の増強方法の発明を包含する。   Further, the present invention provides (1) 0.001 to 0.15 parts by weight of methylmethionine sulfonium salt with respect to 1 part by weight of total polyphenol derived from tea, Or heat sterilization under conditions of F value of 10 to 20 by UHT sterilization, or (2) 0.001 to 0.15 parts by weight of methylmethionine with respect to 1 part by weight of total polyphenol derived from tea A sulfonium salt is contained, and 0.001 to 0.1 v / v% ethanol or 0.001 to 0.1 v / v% propylene glycol is added to the tea beverage, and the tea beverage is added. The container is characterized by maintaining excellent flavor and umami for a long period of time while suppressing an increase in deterioration odor during storage by performing heat sterilization under conditions of F value of 1 to 20 by UHT sterilization. For tea beverage Including the invention of a method enhancement of the flavor and taste of the drink that.

すなわち具体的には本発明は、[1]容器詰茶飲料の製造方法において、(1)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、該茶飲料を、UHT殺菌により、F値10〜20の条件で、加熱殺菌を行うか、或いは、(2)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、更に、茶飲料に対して、0.001〜0.1v/v%のエタノール、又は、0.001〜0.1v/v%のプロピレングリコールを添加して、該茶飲料を、UHT殺菌により、F値1〜20の殺菌条件で、加熱殺菌を行うことを特徴とする容器詰茶飲料の製造方法や、[2]メチルメチオニンスルホニウム塩が、メチルメチオニンスルホニウムクロライドであることを特徴とする上記[1]に記載の容器詰茶飲料の製造方法や、[3]メチルメチオニンスルホニウムクロライドが、ケール、キャベツ、又は、ブロッコリー由来の抽出物であることを特徴とする上記[1]又は[2]に記載の容器詰茶飲料の製造方法や、[4]UHT殺菌による加熱温度が、110℃〜145℃の範囲で設定されることを特徴とする上記[1]〜[3]のいずれかに記載の容器詰茶飲料の製造方法や、[5]茶飲料が緑茶飲料であることを特徴とする上記[1]〜[4]のいずれかに記載の容器詰茶飲料の製造方法からなる。   Specifically, the present invention provides [1] a method for producing a container-packed tea beverage, wherein (1) 0.001 to 0.15 parts by weight of methylmethionine sulfonium salt is 1 part by weight of total polyphenol derived from tea. And the tea beverage is heat sterilized by UHT sterilization under the condition of F value of 10 to 20, or (2) 0.001 to 0 parts by weight of the total polyphenol derived from tea .15 parts by weight of methylmethionine sulfonium salt, and 0.001 to 0.1 v / v% ethanol or 0.001 to 0.1 v / v% propylene glycol with respect to the tea beverage In addition, the tea beverage is subjected to heat sterilization under UHT sterilization under sterilization conditions of F value of 1 to 20, and [2] methylmethionine sulfonium salt, Mechi It is methionine sulfonium chloride, The manufacturing method of the container-packed tea drink as described in said [1] characterized by [3] methylmethionine sulfonium chloride being an extract derived from kale, cabbage, or broccoli The method for producing a packaged tea beverage according to the above [1] or [2], or the heating temperature by [4] UHT sterilization is set in a range of 110 ° C. to 145 ° C. [1] to [4] The method for producing a containerized tea beverage according to any one of [1] to [3], or [5] The tea beverage is a green tea beverage, A method for producing a container-packed tea beverage.

また、本発明は、[6]上記[1]〜[5]のいずれかに記載の製造方法で製造された、優れた香味及び旨味を製造後も長期間持続できる容器詰茶飲料や、[7]容器詰茶飲料の製造において、(1)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、該茶飲料を、UHT殺菌により、F値10〜20の条件で、加熱殺菌を行うか、或いは、(2)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、更に、茶飲料に対して、0.001〜0.1v/v%のエタノール、又は、0.001〜0.1v/v%のプロピレングリコールを添加して、該茶飲料を、UHT殺菌により、F値1〜20の条件で、加熱殺菌を行うことにより、保存時の劣化臭の増加を抑えつつ、優れた香味と旨味を持続させることを特徴とする容器詰茶飲料における飲料の香味及び旨味の増強方法からなる。   The present invention also provides [6] a packaged tea beverage produced by the production method according to any one of [1] to [5] above, which can maintain excellent flavor and umami for a long period of time after production, 7] In the production of a container-packed tea beverage, (1) 0.001 to 0.15 parts by weight of methylmethionine sulfonium salt is added to 1 part by weight of the total polyphenol derived from tea, and the tea drink is subjected to UHT sterilization. By heat sterilization under the condition of F value of 10 to 20, or (2) 0.001 to 0.15 parts by weight of methylmethionine sulfonium salt with respect to 1 part by weight of total polyphenol derived from tea Furthermore, 0.001 to 0.1 v / v% ethanol or 0.001 to 0.1 v / v% propylene glycol is added to the tea beverage, and the tea beverage is subjected to UHT sterilization. By the condition of F value 1-20 , By performing the heat sterilization, while suppressing an increase in deterioration smell during storage, consisting of excellent way enhanced flavor and taste of the beverage in the packaged tea beverage, wherein to prolong the flavor and taste.

本発明により、容器詰茶飲料のような茶飲料の製造時の加熱殺菌処理により低下する茶飲料の香味及び旨味を補完、増強し、かつ、その優れた香味及び旨味を、劣化臭の増加を抑えつつ、長期間持続できる容器詰茶飲料を製造することができ、優れた香味と旨味を持続できる容器詰茶飲料、及びその製造方法を提供することができる。   The present invention complements and enhances the flavor and umami of tea beverages that are reduced by heat sterilization treatment during the manufacture of tea beverages such as packaged tea beverages, and increases the superior odor and umami to increase the deterioration odor. It is possible to produce a containerized tea beverage that can be sustained for a long time while suppressing it, and to provide a containerized tea beverage that can maintain an excellent flavor and umami, and a method for producing the same.

本発明は、容器詰茶飲料の製造方法において、(1)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、該茶飲料を、UHT殺菌により、F値10〜20の条件で、加熱殺菌を行うか、或いは、(2)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、更に、茶飲料に対して、0.001〜0.1v/v%のエタノール、又は、0.001〜0.1v/v%のプロピレングリコールを添加して、該茶飲料を、UHT殺菌により、F値1〜20の条件で、加熱殺菌を行うことにより、加熱殺菌処理で低下する茶飲料の香味及び旨味を補完、増強し、かつ、その優れた香味及び旨味を、劣化臭の増加を抑えつつ、長期間持続できる容器詰茶飲料を製造し、提供することからなる。   The present invention relates to a method for producing a packaged tea beverage, wherein (1) 0.001 to 0.15 parts by weight of methylmethionine sulfonium salt is contained per 1 part by weight of tea-derived total polyphenol, , Heat sterilization under conditions of F value of 10 to 20 by UHT sterilization, or (2) 0.001 to 0.15 parts by weight of methylmethioninesulfonium with respect to 1 part by weight of total polyphenol derived from tea Salt is added, and 0.001 to 0.1 v / v% ethanol or 0.001 to 0.1 v / v% propylene glycol is added to the tea beverage, By performing heat sterilization under conditions of F value of 1 to 20 by UHT sterilization, the flavor and umami of tea beverages that are reduced by heat sterilization are complemented and enhanced, and the excellent flavor and umami are degraded. Increased odor While suppressing, to produce a packaged tea beverage that can be long lasting, it consists of providing.

<茶飲料>
本発明で、茶飲料の製造に用いる原料溶液は、通常の方法に従い茶葉から抽出した茶抽出液を用いて調製することができる。原料となる茶葉は特に限定されないが、Camellia sinensisに属する茶葉等を用いることができ、緑茶葉のような不発酵茶に限らず烏龍茶のような半発酵茶や紅茶のような発酵茶、プーアル茶のような後発酵茶なども用いることができる。本発明の効果がより発揮できるという点で緑茶葉が好ましい。なお茶抽出液の代わりに市販の茶エキスやパウダーを用いてもよく、茶抽出液とエキスやパウダーを混合して用いてもよい。茶飲料に含有される茶由来の総ポリフェノール量は任意に決めることができるが、好ましくは20〜150mg/100mL、より好ましくは40〜100mg/100mLのとき、加熱殺菌処理後の容器詰茶飲料において、より旨味が強く、緑茶らしい自然な風味を得ることができる。そのほか、通常の茶飲料を製造する際に使用する食品添加物などは適宜使用することができる。
<Tea drink>
In this invention, the raw material solution used for manufacture of a tea drink can be prepared using the tea extract extracted from the tea leaf in accordance with the normal method. The tea leaves used as the raw material are not particularly limited, but tea leaves belonging to Camellia sinensis can be used. Not only non-fermented teas such as green tea leaves, but also semi-fermented teas such as oolong teas, fermented teas such as black tea, and puer teas Post-fermented tea such as can also be used. Green tea leaves are preferred in that the effects of the present invention can be more exerted. Note that a commercially available tea extract or powder may be used instead of the tea extract, or a mixture of the tea extract and the extract or powder may be used. The total amount of tea-derived polyphenols contained in the tea beverage can be arbitrarily determined, but preferably 20 to 150 mg / 100 mL, more preferably 40 to 100 mg / 100 mL, in a packaged tea beverage after heat sterilization treatment It has a stronger flavor and a natural flavor like green tea. In addition, food additives and the like used when producing ordinary tea beverages can be used as appropriate.

<メチルメチオニンスルホニウム塩>
本発明の茶飲料で、該茶飲料に含有させるメチルメチオニンスルホニウム塩は、キャベツジュース中の潰瘍抑制効果を研究する中でその有効成分の一つとして見出された化合物群であり、キャベツなどのアブラナ科植物に含有される。メチルメチオニンスルホニウム塩は、メチルメチオニンスルホニウムと、無機酸、有機酸、酸性アミノ酸、および5’−ヌクレオタイドから選択された化合物との塩であることが好ましい。無機酸としては、塩酸、硫酸、硝酸などが挙げられる。また、有機酸としては、クエン酸、リンゴ酸、コハク酸などが挙げられる。さらに、酸性アミノ酸としては、グルタミン酸、アスパラギン酸などが挙げられる。加えて、5’−ヌクレオタイドとしては、5’−イノシン酸、5’−アデニル酸、5’−グアニル酸、などが挙げられる。メチルメチオニンスルホニウム塩の添加量は、茶飲料中に含まれる茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部、好ましくは0.007〜0.06重量部、より好ましくは、0.01〜0.06重量部添加するのがよい。
<Methylmethionine sulfonium salt>
In the tea beverage of the present invention, the methylmethionine sulfonium salt contained in the tea beverage is a group of compounds found as one of its active ingredients in studying the ulcer suppressing effect in cabbage juice, such as cabbage Contained in cruciferous plants. The methyl methionine sulfonium salt is preferably a salt of methyl methionine sulfonium and a compound selected from an inorganic acid, an organic acid, an acidic amino acid, and 5′-nucleotide. Examples of the inorganic acid include hydrochloric acid, sulfuric acid, nitric acid and the like. Examples of the organic acid include citric acid, malic acid, succinic acid and the like. Furthermore, examples of acidic amino acids include glutamic acid and aspartic acid. In addition, 5′-nucleotide includes 5′-inosinic acid, 5′-adenylic acid, 5′-guanylic acid, and the like. The amount of methylmethionine sulfonium salt added is 0.001 to 0.15 parts by weight, preferably 0.007 to 0.06 parts by weight, based on 1 part by weight of the total polyphenol derived from tea contained in the tea beverage. Preferably, 0.01 to 0.06 part by weight is added.

<メチルメチオニンスルホニウムクロライド(MMS)>
メチルメチオニンスルホニウム塩は、飲料に用いることができる化合物であれば特に限定されないが、好ましくは、メチルメチオニンスルホニウムと無機酸との塩であり、さらに好ましくは、メチルメチオニンスルホニウムクロライドである。メチルメチオニンスルホニウムクロライドは、ケールやキャベツ、及びブロッコリー等に含まれるアミノ酸の一種であり、それらの植物体の抽出物若しくはその抽出物から分画濃縮したものを使用することができる。メチルメチオニンスルホニウムクロライドは食品添加物として市販されており、本発明では該市販のメチルメチオニンスルホニウムクロライドを使用することができる。該市販のメチルメチオニンスルホニウムクロライドを使用することで、香味の調整やコストの面で有利となることがある。メチルメチオニンスルホニウムクロライドの添加量は、茶飲料中に含まれる茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部、好ましくは0.007〜0.06重量部、より好ましくは、0.01〜0.06重量部添加するのがよい。
<Methylmethionine sulfonium chloride (MMS)>
The methyl methionine sulfonium salt is not particularly limited as long as it is a compound that can be used in beverages, but is preferably a salt of methyl methionine sulfonium and an inorganic acid, and more preferably methyl methionine sulfonium chloride. Methyl methionine sulfonium chloride is a kind of amino acid contained in kale, cabbage, broccoli, and the like, and extracts of these plants or fractions and concentrates thereof can be used. Methyl methionine sulfonium chloride is commercially available as a food additive. In the present invention, the commercially available methyl methionine sulfonium chloride can be used. Use of the commercially available methylmethionine sulfonium chloride may be advantageous in terms of flavor adjustment and cost. The amount of methylmethionine sulfonium chloride added is 0.001 to 0.15 parts by weight, preferably 0.007 to 0.06 parts by weight, based on 1 part by weight of the total polyphenol derived from tea contained in the tea beverage. Preferably, 0.01 to 0.06 part by weight is added.

<総ポリフェノール>
ここで茶由来の総ポリフェノールとは、茶由来成分のうち、以下に示す酒石酸鉄法で定量されたものを指す。茶由来ポリフェノールには、カテキン、エピカテキン、ガロカテキン、エピガロカテキン、カテキンガレート、エピカテキンガレート、ガロカテキンガレート、エピガロカテキンガレート等や、カテキン類の酸化2量体であるテアフラビン類、さらにはカテキン類やテアフラビン類を構成単位とする多量体のタンニン類などが含まれる。茶由来の総ポリフェノール量は、日本食品分析センター編、「五訂 日本食品標準成分分析マニュアルの解説」、中央法規、2001年7月、p.252に記載の公定法(酒石酸鉄試薬法)にしたがって測定する。
<Total polyphenol>
Here, the tea-derived total polyphenol refers to a tea-derived component quantified by the iron tartrate method shown below. Tea-derived polyphenols include catechin, epicatechin, gallocatechin, epigallocatechin, catechin gallate, epicatechin gallate, gallocatechin gallate, epigallocatechin gallate, etc., theaflavins that are catechin oxidized dimers, and further catechin And multimeric tannins containing theaflavins as structural units. The total amount of polyphenols derived from tea can be found in the Japanese Food Analysis Center, “Explanation of the 5th edition Japanese Food Standards Component Analysis Manual”, Central Law, July 2001, p. Measured according to the official method described in 252 (iron tartrate reagent method).

<エタノール・プロピレングリコール>
本発明の容器詰茶飲料の製造方法においては、メチルメチオニンスルホニウム塩の含有に加えて、特定量のエタノール、若しくは、プロピレングリコールを含有させることにより、殺菌条件の適正範囲を広げることができる。具体的には、エタノール又はプロピレングリコールを0.001〜0.1v/v%の範囲で含有させる。該エタノール及びプロピレングリコールは、茶飲料調合の際に抽出液に対して添加すればよく、メチルメチオニンスルホニウム塩と同時に添加してもよい。なお、これらエタノール及びプロピレングリコールの両者を併用して添加することもできる。
<Ethanol / propylene glycol>
In the method for producing a packaged tea beverage of the present invention, the appropriate range of sterilization conditions can be expanded by containing a specific amount of ethanol or propylene glycol in addition to the inclusion of methylmethionine sulfonium salt. Specifically, ethanol or propylene glycol is contained in the range of 0.001 to 0.1 v / v%. The ethanol and propylene glycol may be added to the extract during tea beverage preparation, and may be added simultaneously with the methylmethionine sulfonium salt. In addition, both ethanol and propylene glycol can be used in combination.

<UHT殺菌>
本発明では、容器詰茶飲料の製造において用いられる加熱殺菌手段として、UHT殺菌が用いられる。UHT殺菌は、超高温短時間で殺菌する方法であり、PETボトル詰清涼飲料製造の際などの殺菌方法として広く用いられている。本発明の容器詰茶飲料の製造方法においては、このUHT殺菌をおこなう際に、特定のF値範囲で加熱殺菌することが必要となる。F値とは、基準温度で一定数の微生物を死滅させるのに要する加熱時間(分)であって、通常121.1℃における加熱時間をいう。たとえば、F=1と同等の殺菌条件とは、111.1℃では10分、121.1℃では1分、F=20と同等の殺菌条件とは、121.1℃では20分、137.2℃では30秒のように設定できる。なお本発明でUHT殺菌をおこなう際には、加熱温度は110℃〜145℃程度に設定することが好ましく、124℃〜145℃程度に設定することがより好ましい。UHT殺菌機を用いて上記条件で殺菌を行う場合は、上記条件を実際に担保できる温度と時間を設定する。
<UHT sterilization>
In the present invention, UHT sterilization is used as a heat sterilization means used in the manufacture of a packaged tea beverage. UHT sterilization is a method of sterilization at a very high temperature in a short time, and is widely used as a sterilization method in the production of PET bottled soft drinks. In the manufacturing method of the container-packed tea beverage of the present invention, it is necessary to sterilize by heating in a specific F value range when performing this UHT sterilization. The F value is the heating time (minutes) required to kill a certain number of microorganisms at the reference temperature, and usually refers to the heating time at 121.1 ° C. For example, sterilization conditions equivalent to F = 1 are 10 minutes at 111.1 ° C., 1 minute at 121.1 ° C., and sterilization conditions equivalent to F = 20 are 20 minutes at 121.1 ° C. It can be set to 30 seconds at 2 ° C. In addition, when performing UHT sterilization by this invention, it is preferable to set a heating temperature to about 110 to 145 degreeC, and it is more preferable to set to about 124 to 145 degreeC. When performing sterilization under the above conditions using a UHT sterilizer, the temperature and time at which the above conditions can be actually secured are set.

<UHT殺菌条件>
本発明の容器詰茶飲料の製造においては、以下のUHT殺菌条件において、加熱殺菌が行われる。
(1)メチルメチオニンスルホニウム塩添加(エタノール、プロピレングリコール無添加):F値10〜20の条件で、加熱殺菌。
上記加熱殺菌の範囲以外では、保存するに従い、旨味が漸減するほか、同時に劣化臭が増加するので、製造後、長期間に渡って流通、販売される容器詰茶飲料としては相応しくない。
(2)メチルメチオニンスルホニウム塩添加+エタノール(0.001〜0.1v/v%)添加:F値1〜20の条件で、加熱殺菌。
上記加熱殺菌の範囲以外では、保存するに従い、旨味が漸減するほか、同時に劣化臭が増加するので、製造後、長期間に渡って流通、販売される容器詰茶飲料としては相応しくない。
(3)メチルメチオニンスルホニウム塩添加+プロピレングリコール(0.001〜0.1v/v%)添加:F値1〜20の条件で、加熱殺菌。
上記加熱殺菌の範囲以外では、保存するに従い、旨味が漸減するほか、同時に劣化臭が増加するので、製造後、長期間に渡って流通、販売される容器詰茶飲料としては相応しくない。
<UHT sterilization conditions>
In the manufacture of the packaged tea beverage of the present invention, heat sterilization is performed under the following UHT sterilization conditions.
(1) Addition of methylmethionine sulfonium salt (no addition of ethanol or propylene glycol): heat sterilization under conditions of F value of 10-20.
Outside the range of heat sterilization, the umami gradually decreases as the product is stored, and at the same time the deteriorated odor increases. Therefore, it is not suitable as a packaged tea beverage that is distributed and sold for a long time after production.
(2) Addition of methylmethionine sulfonium salt + addition of ethanol (0.001 to 0.1 v / v%): Heat sterilization under conditions of F value of 1 to 20.
Outside the range of heat sterilization, the umami gradually decreases as the product is stored, and at the same time the deteriorated odor increases. Therefore, it is not suitable as a packaged tea beverage that is distributed and sold for a long time after production.
(3) Addition of methylmethionine sulfonium salt + addition of propylene glycol (0.001 to 0.1 v / v%): Sterilization by heating under conditions of F value of 1 to 20.
Outside the range of heat sterilization, the umami gradually decreases as the product is stored, and at the same time the deteriorated odor increases. Therefore, it is not suitable as a packaged tea beverage that is distributed and sold for a long time after production.

<容器詰茶飲料>
UHT殺菌した茶飲料を、常法に従って、PETボトル、紙容器、ビン容器、缶容器などの容器に充填することで、容器詰茶飲料を製造することができる。本発明方法で製造した茶飲料は、長期間保存しても、劣化臭が増加しにくく、香味、旨味に優れている。なお、UHT殺菌の特性を生かす面からPETボトルに充填することが最も好ましい。
<Packed tea beverage>
A container-packed tea beverage can be produced by filling a UHT-sterilized tea beverage in a container such as a PET bottle, a paper container, a bottle container, or a can container according to a conventional method. The tea beverage produced by the method of the present invention hardly deteriorates even when stored for a long period of time, and is excellent in flavor and umami. In addition, it is most preferable to fill the PET bottle from the aspect of utilizing the characteristics of UHT sterilization.

以下、実施例により本発明をより具体的に説明するが、本発明の技術的範囲はこれらの例示に限定されるものではない。   EXAMPLES Hereinafter, although an Example demonstrates this invention more concretely, the technical scope of this invention is not limited to these illustrations.

[実施例1〜2、比較例1〜5]   [Examples 1 and 2, Comparative Examples 1 to 5]

<調製例(1)>茶飲料調合液の調製
緑茶葉200gに対して70℃の熱水8000gを添加し、適宜攪拌しながら6分間抽出した。固液分離し、10℃まで冷却した後に遠心分離処理を行った後、イオン交換水で8000gに調整して緑茶抽出液を得た。さらに、この得られた緑茶抽出液1000gに対して、L−アスコルビン酸を40mg/茶飲料100mLとなるように添加してから、炭酸水素ナトリウムでpHを6.5に調整後、最終的に2500gとなるようにイオン交換水を添加して、茶飲料調合液(対照)を調製した。一方、使用する緑茶抽出液を6000gにする点、メチルメチオニンスルホニウムクロライド(MMS)(浜理薬品工業株式会社製)を0.001w/w%となるように添加する点、最終液量を15000gとする点以外は全く同様にして茶飲料調合液(試験区)を調製した。これら茶飲料調合液の総ポリフェノール量は70mg/100mlであり、メチルメチオニンスルホニウムクロライドの添加量は茶飲料中に含まれる茶由来の総ポリフェノール1重量部に対して、0.0143重量部に相当する。
<Preparation Example (1)> Preparation of Tea Beverage Preparation Liquid 8000 g of hot water at 70 ° C. was added to 200 g of green tea leaves, and extracted for 6 minutes with appropriate stirring. After solid-liquid separation and cooling to 10 ° C., centrifugal separation was performed, and the green tea extract was obtained by adjusting to 8000 g with ion-exchanged water. Furthermore, L-ascorbic acid was added to 1000 g of the obtained green tea extract so as to be 40 mg / 100 mL of tea beverage, and the pH was adjusted to 6.5 with sodium hydrogen carbonate. Ion exchange water was added so as to prepare a tea beverage preparation (control). On the other hand, the point which makes the green tea extract used 6000g, the point which adds methylmethionine sulfonium chloride (MMS) (made by Hamari Pharmaceutical Co., Ltd.) so that it may become 0.001 w / w%, and the final liquid amount are 15000g. Except for this point, a tea beverage preparation (test group) was prepared in exactly the same manner. The total amount of polyphenols in these tea beverage preparations is 70 mg / 100 ml, and the amount of methylmethionine sulfonium chloride added corresponds to 0.0143 parts by weight with respect to 1 part by weight of the total polyphenol derived from tea contained in the tea beverage. .

<UHT殺菌条件>   <UHT sterilization conditions>

(実施例1〜2、比較例1〜4)
得られたそれぞれの茶飲料調合液を用いて、表1に示す条件でUHT殺菌をおこなった。UHT殺菌機の条件は、表1の殺菌条件を実際に担保できるように温度と時間を設定した。UHT殺菌はF値が1〜40の範囲で行い、殺菌後は、PETボトルに充填して容器詰茶飲料とした。
(Examples 1-2, Comparative Examples 1-4)
UHT sterilization was performed under the conditions shown in Table 1 using the obtained tea beverage preparations. The conditions of the UHT sterilizer were set with temperature and time so that the sterilization conditions shown in Table 1 could be actually secured. UHT sterilization was performed in the range of F value of 1 to 40, and after sterilization, it was filled into a PET bottle to obtain a container-packed tea beverage.

Figure 2016154500
Figure 2016154500

(比較例5)
得られた茶飲料調合液(試験区)をレトルト缶に充填した後、表2に示す条件でレトルト殺菌をおこなった。レトルト殺菌機の条件は、表2の殺菌条件を実際に担保できるように温度と時間を設定した。
(Comparative Example 5)
After filling the obtained tea beverage preparation (test section) into a retort can, retort sterilization was performed under the conditions shown in Table 2. The conditions of the retort sterilizer were set with temperature and time so that the sterilization conditions shown in Table 2 could be actually secured.

Figure 2016154500
Figure 2016154500

<官能評価(1)>
製造した容器詰緑茶飲料を訓練されたパネリスト5名により官能評価を行った。また、45℃保存庫に保存して、製造2週間後、4週間後にも同様に官能評価をおこなった。香味評価(旨味)は、比較例1の製造後保存0週間を対照(5点満点中の1点)として、緑茶飲料の香味を構成する旨味の強度を評価した。すなわち、評価素点は次の通りである:1点は「旨味が対照と同等である」、2点は「旨味が対照より若干強い程度」、3点は「旨味が対照より強いまたは優れている」、4点は「旨味が対照より明らかに強いまたは優れている」、5点は「旨味が対照より著しく強いまたは優れている」とした。これらの評価素点はさらに、下記の評価基準でレベル分けした。香味の評価基準は次の通りである:◎が最も緑茶飲料としての旨味が優れており、○、△、及び×の順に従って、旨味の強度が弱くなり、△及び×は、緑茶飲料として旨味増強効果が不十分なものである。また、香味評価(劣化臭)は、比較例1の製造後保存0週間を対照(5点満点中の1点)として、保存期間中に生成される緑茶飲料の劣化臭の強度を評価した。
<Sensory evaluation (1)>
Sensory evaluation was conducted by five panelists who were trained on the packaged green tea beverages produced. Moreover, it preserve | saved in a 45 degreeC storage warehouse, and sensory evaluation was similarly performed 2 weeks after manufacture and 4 weeks after. For flavor evaluation (umami), the strength of umami constituting the flavor of the green tea beverage was evaluated using 0 weeks after storage of Comparative Example 1 as a control (1 point out of 5 points). That is, the evaluation score is as follows: 1 point is “the taste is equivalent to the control”, 2 points is “a degree of umami is slightly stronger than the control”, 3 points is “the taste is stronger or better than the control” 4 points were “the taste is clearly stronger or better than the control” and 5 points were “the taste was significantly stronger or better than the control”. These evaluation raw points were further divided into levels according to the following evaluation criteria. The evaluation criteria of the flavor are as follows: ◎ is the best green tea beverage, and the umami strength decreases in the order of ○, △, and ×, and △ and × are umami as green tea beverages. The enhancement effect is insufficient. Moreover, flavor evaluation (deterioration odor) evaluated the intensity | strength of the deterioration odor of the green tea drink produced | generated in the preservation | save period by making 0 weeks of preservation | save after manufacture of the comparative example 1 into a control | contrast (1 point out of 5 points).

すなわち、評価素点は次の通りである:1点は「対照と同等である」、2点は「対照より微妙な劣化臭を感じるが許容できる」、3点は「対照より強い劣化臭を感じる」、4点は「対照より明らかに強い劣化臭を感じる」、5点は「対照より著しく強い劣化臭を感じる」とした。これらの評価素点はさらに、下記の評価基準でレベル分けした。香味の評価基準は次の通りである:◎が最も対照の香味に近く、○、△、及び×の順に従って、対照からの香味の変化が大きくなるものであり、△及び×は、緑茶飲料として劣化臭が許容しがたいものである。   In other words, the evaluation score is as follows: 1 point is “equivalent to the control”, 2 points “feels a subtle deterioration odor than the control but is acceptable”, 3 points “a stronger deterioration odor than the control” 4 points were “feeling a clearly deteriorating odor than the control”, and 5 points were “feeling a significantly deteriorating odor than the control”. These evaluation raw points were further divided into levels according to the following evaluation criteria. The evaluation criteria of the flavor are as follows: ◎ is the closest to the flavor of the control, and the change in flavor from the control increases in the order of ○, △, and ×, where △ and × are green tea beverages As a result, the deterioration odor is unacceptable.

<評価基準(旨味)>
◎:(5段階評価で3.5点以上)
○:(5段階評価で3点以上3.5点未満)
△:(5段階評価で2.5点以上3点未満)
×:(5段階評価で2.5点未満)
<Evaluation criteria (umami)>
A: (3.5 points or more in a five-step evaluation)
○: (3 points or more and less than 3.5 points in a 5-level evaluation)
Δ: (2.5 points or more and less than 3 points in a five-step evaluation)
X: (less than 2.5 points in a 5-step evaluation)

<評価基準(劣化臭)>
◎:(5段階評価で2.5点未満)
○:(5段階評価で2.5点以上3.0点未満)
△:(5段階評価で3.0点以上3.5点未満)
×:(5段階評価で3.5点以上)
<Evaluation criteria (degraded odor)>
A: (less than 2.5 points in a five-step evaluation)
○: (2.5 points or more and less than 3.0 points in 5 grades)
△: (3.0 points or more and less than 3.5 points in a 5-step evaluation)
×: (3.5 points or more in a 5-step evaluation)

香味評価の結果を表3に示す。メチルメチオニンスルホニウムクロライドを添加した茶飲料において、比較例4及び5は、製造直後はいずれも旨味が増強されていたが、保存するに従って旨味の強度が著しく低下してしまった。また同時に劣化臭が増加していた。比較例2及び3は、製造直後の旨味の増強が十分ではなかった。一方、実施例の容器詰茶飲料においては、製造直後だけでなく、一定期間保存後も旨味の増強が維持されており、劣化臭の増加も抑えられていた。   The results of flavor evaluation are shown in Table 3. In tea beverages to which methylmethionine sulfonium chloride was added, Comparative Examples 4 and 5 had enhanced umami immediately after production, but the intensity of umami significantly decreased with storage. At the same time, the deterioration odor increased. In Comparative Examples 2 and 3, the enhancement of umami immediately after production was not sufficient. On the other hand, in the packaged tea beverages of the examples, the enhancement of umami was maintained not only immediately after production but also after storage for a certain period of time, and the increase in deteriorated odor was suppressed.

Figure 2016154500
Figure 2016154500

[実施例3〜14、比較例6〜8]   [Examples 3-14, Comparative Examples 6-8]

<調製例(2)(エタノール添加茶飲料調合液の調製[1])>
エタノールを最終液量に対して0.001v/v%となるように添加した以外は、調製例(1)の茶飲料調合液(試験区;MMS0.001w/w%添加)と同様に調合液を調製した。
<Preparation example (2) (Preparation of ethanol-added tea beverage preparation [1])>
Except that ethanol was added so as to be 0.001 v / v% with respect to the final liquid volume, the liquid preparation was the same as the tea beverage preparation liquid of the preparation example (1) (test section; MMS 0.001 w / w% addition). Was prepared.

<調製例(3)(エタノール添加茶飲料調合液の調製[2])>
エタノールを最終液量に対して0.01v/v%となるように添加した以外は、調製例(1)の茶飲料調合液(試験区;MMS0.001w/w%添加)と同様に調合液を調製した。
<Preparation example (3) (Preparation of ethanol-added tea beverage preparation [2])>
Except that ethanol was added so as to be 0.01 v / v% with respect to the final liquid volume, the preparation liquid was the same as the tea drink preparation liquid of the preparation example (1) (test section; MMS 0.001 w / w% addition). Was prepared.

<調製例(4)(エタノール添加茶飲料調合液の調製[3]>
エタノールを最終液量に対して0.1v/v%となるように添加した以外は、調製例(1)の茶飲料調合液(試験区;MMS0.001w/w%添加)と同様に調合液を調製した。
<Preparation Example (4) (Preparation of ethanol-added tea beverage preparation [3]>
Except that ethanol was added so as to be 0.1 v / v% with respect to the final liquid amount, the preparation liquid was the same as the tea drink preparation liquid of the preparation example (1) (test section; MMS 0.001 w / w% addition). Was prepared.

<UHT殺菌条件>
得られた茶調合液について、表4の条件でUHT殺菌を行ってPETボトルに充填して容器詰茶飲料を製造した。UHT殺菌機の条件は、表4の殺菌条件を実際に担保できるように温度と時間を設定した。
<UHT sterilization conditions>
About the obtained tea preparation liquid, UHT sterilization was performed on the conditions of Table 4, and it filled with the PET bottle, and manufactured the container-packed tea drink. The conditions of the UHT sterilizer were set with temperature and time so that the sterilization conditions shown in Table 4 could be actually secured.

Figure 2016154500
Figure 2016154500

<官能評価(2)>
実施例3〜14および比較例6〜8の容器詰茶飲料について官能評価(1)と同様に官能評価をおこなった。結果を表5に示す。エタノールを0.001v/v%、0.01v/v%若しくは0.1v/v%添加すると、F値が1〜10であっても、エタノールを添加しない場合のF値10〜20と同様に、メチルメチオニンスルホニウムクロライド添加により増強された優れた香味、旨味が製造直後だけでなく、一定期間保存後も持続していた。また劣化臭の増加も抑えられていた。
<Sensory evaluation (2)>
The sensory evaluation was performed similarly to sensory evaluation (1) about the container-packed tea beverages of Examples 3 to 14 and Comparative Examples 6 to 8. The results are shown in Table 5. When ethanol is added at 0.001 v / v%, 0.01 v / v%, or 0.1 v / v%, even if F value is 1 to 10, it is the same as F value 10 to 20 when ethanol is not added The excellent flavor and umami enhanced by the addition of methylmethionine sulfonium chloride persisted not only immediately after production but also after storage for a certain period of time. Moreover, the increase in the deterioration odor was also suppressed.

Figure 2016154500
Figure 2016154500

[実施例15〜18、比較例9]   [Examples 15 to 18, Comparative Example 9]

<調製例(5)(プロピレングリコール添加茶飲料調合液の調製)>
プロピレングリコール(PG)を最終液量に対して0.1v/v%となるように添加した以外は、調製例(1)の茶飲料調合液(試験区;MMS0.001w/w%添加)と同様に調合液を調製した。
<Preparation Example (5) (Preparation of propylene glycol-added tea beverage preparation)>
Except that propylene glycol (PG) was added to 0.1 v / v% with respect to the final liquid amount, the tea beverage preparation liquid of the preparation example (1) (test group; MMS 0.001 w / w% addition) and Similarly, a preparation liquid was prepared.

<UHT殺菌条件>
得られた茶調合液について、表6の条件でUHT殺菌を行ってPETボトルに充填して容器詰茶飲料を製造した。UHT殺菌機の条件は、表6の殺菌条件を実際に担保できるように温度と時間を設定した。
<UHT sterilization conditions>
About the obtained tea liquid mixture, UHT sterilization was performed on the conditions of Table 6, it filled with the PET bottle, and the container-packed tea drink was manufactured. The conditions of the UHT sterilizer were set with temperature and time so that the sterilization conditions shown in Table 6 could be actually secured.

Figure 2016154500
Figure 2016154500

<官能評価(3)>
実施例15〜18及び比較例9の容器詰茶飲料について官能評価(1)及び(2)と同様に官能評価を行った。結果を表7に示す。プロピレングリコールを添加すると、F値が1〜10であっても、プロピレングリコールを添加しない場合のF値10〜20と同様に、メチルメチオニンスルホニウムクロライド添加による増強された優れた香味および旨味が製造直後だけでなく、一定期間保存後も持続していた。また、劣化臭の増加も抑えられていた。
<Sensory evaluation (3)>
The sensory evaluation was performed in the same manner as in the sensory evaluations (1) and (2) for the packaged tea beverages of Examples 15 to 18 and Comparative Example 9. The results are shown in Table 7. When propylene glycol is added, even if the F value is 1 to 10, the enhanced excellent flavor and umami due to the addition of methylmethionine sulfonium chloride is immediately after production, as in the F value of 10 to 20 when no propylene glycol is added. In addition, it persisted after storage for a certain period. Moreover, the increase in the deterioration odor was also suppressed.

Figure 2016154500
Figure 2016154500

本発明は、容器詰茶飲料の製造時の加熱殺菌処理により低下する茶飲料の香味及び旨味を補完、増強し、かつ、その優れた香味及び旨味を、劣化臭の増加を抑えつつ、製造後も長期間持続できる、容器詰茶飲容器詰茶飲料を提供する。
The present invention supplements and enhances the flavor and umami of tea beverages that are reduced by heat sterilization during the production of packaged tea beverages, and improves the excellent flavor and umami while suppressing the increase in deteriorated odors. To provide a packaged tea beverage that can last for a long time.

Claims (7)

容器詰茶飲料の製造方法において、(1)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、該茶飲料を、UHT殺菌により、F値10〜20の条件で、加熱殺菌を行うか、或いは、(2)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、更に、茶飲料に対して、0.001〜0.1v/v%のエタノール、又は、0.001〜0.1v/v%のプロピレングリコールを添加して、該茶飲料を、UHT殺菌により、F値1〜20の殺菌条件で、加熱殺菌を行うことを特徴とする容器詰茶飲料の製造方法。   In the method for producing a containerized tea beverage, (1) 0.001 to 0.15 part by weight of methylmethionine sulfonium salt is contained per 1 part by weight of the total polyphenol derived from tea, and the tea beverage is subjected to UHT sterilization. , Sterilization by heating under the condition of F value of 10 to 20, or (2) 0.001 to 0.15 part by weight of methylmethionine sulfonium salt is added to 1 part by weight of total polyphenol derived from tea Furthermore, 0.001 to 0.1 v / v% ethanol or 0.001 to 0.1 v / v% propylene glycol is added to the tea beverage, and the tea beverage is subjected to UHT sterilization. A method for producing a packaged tea beverage characterized by performing heat sterilization under sterilization conditions having an F value of 1 to 20. メチルメチオニンスルホニウム塩が、メチルメチオニンスルホニウムクロライドであることを特徴とする請求項1に記載の容器詰茶飲料の製造方法。   The method for producing a packaged tea beverage according to claim 1, wherein the methylmethioninesulfonium salt is methylmethioninesulfonium chloride. メチルメチオニンスルホニウムクロライドが、ケール、キャベツ、又は、ブロッコリー由来の抽出物であることを特徴とする請求項1又は2に記載の容器詰茶飲料の製造方法。   The method for producing a packaged tea beverage according to claim 1 or 2, wherein the methylmethionine sulfonium chloride is an extract derived from kale, cabbage, or broccoli. UHT殺菌による加熱温度が、110℃〜145℃の範囲で設定されることを特徴とする請求項1〜3のいずれかに記載の容器詰茶飲料の製造方法。   The heating temperature by UHT sterilization is set in the range of 110 to 145 degreeC, The manufacturing method of the packaged tea drink in any one of Claims 1-3 characterized by the above-mentioned. 茶飲料が緑茶飲料であることを特徴とする請求項1〜4のいずれかに記載の容器詰茶飲料の製造方法。   The method for producing a containerized tea beverage according to any one of claims 1 to 4, wherein the tea beverage is a green tea beverage. 請求項1〜5のいずれかに記載の製造方法で製造された、優れた香味及び旨味を製造後も長期間持続できる容器詰茶飲料。   A packaged tea beverage produced by the production method according to any one of claims 1 to 5 and capable of maintaining an excellent flavor and umami for a long time after production. 容器詰茶飲料の製造において、(1)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、該茶飲料を、UHT殺菌により、F値10〜20の条件で、加熱殺菌を行うか、或いは、(2)茶由来の総ポリフェノール1重量部に対して、0.001〜0.15重量部のメチルメチオニンスルホニウム塩を含有させ、更に、茶飲料に対して、0.001〜0.1v/v%のエタノール、又は、0.001〜0.1v/v%のプロピレングリコールを添加して、該茶飲料を、UHT殺菌により、F値1〜20の条件で、加熱殺菌を行うことにより、保存時の劣化臭の増加を抑えつつ、優れた香味と旨味を持続させることを特徴とする容器詰茶飲料における飲料の香味及び旨味の増強方法。   In the production of containerized tea beverages, (1) 0.001 to 0.15 parts by weight of methylmethionine sulfonium salt is contained with respect to 1 part by weight of total polyphenol derived from tea, and the tea beverage is subjected to UHT sterilization. F2 is sterilized under conditions of 10 to 20, or (2) 0.001 to 0.15 parts by weight of methylmethionine sulfonium salt is included with respect to 1 part by weight of polyphenol derived from tea, Furthermore, 0.001 to 0.1 v / v% ethanol or 0.001 to 0.1 v / v% propylene glycol is added to the tea beverage, and the tea beverage is subjected to UHT sterilization. Beverage flavor and umami in a containerized tea beverage characterized by maintaining an excellent flavor and umami while suppressing an increase in deterioration odor during storage by performing heat sterilization under conditions of F value of 1 to 20 of Strong way.
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