JP5536381B2 - Green tea-containing tea beverage - Google Patents

Green tea-containing tea beverage Download PDF

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JP5536381B2
JP5536381B2 JP2009160287A JP2009160287A JP5536381B2 JP 5536381 B2 JP5536381 B2 JP 5536381B2 JP 2009160287 A JP2009160287 A JP 2009160287A JP 2009160287 A JP2009160287 A JP 2009160287A JP 5536381 B2 JP5536381 B2 JP 5536381B2
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tea
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JP2011010640A (en
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真一 小林
智 早川
秀樹 牧
芳明 横尾
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Suntory Beverage and Food Ltd
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本発明は、碾茶の冷水抽出液を含有する容器詰茶飲料に関し、より詳細には、旨味、コク、喉越しに優れ、苦渋味が低減された容器詰緑茶飲料とその製造方法に関する。   The present invention relates to a packaged tea beverage containing a cold water extract of strawberry tea, and more particularly to a packaged green tea beverage that is excellent in umami, richness and throat, and has a reduced bitter taste.

近年、缶やペットボトル等の容器に充填された容器詰茶飲料が多く開発、市販されており、茶飲料のなかでも、特に緑茶飲料の市場が拡大している。このような茶飲料に対する消費者の嗜好は高まっており、最近は、旨味やコク味が強く、かつ、渋味の抑えられたスッキリ感の高い緑茶飲料が好まれる傾向にある。そこで、渋味の多いカテキン類を抽出せずに旨味の成分だけを取り出す方法の開発が望まれている。   In recent years, many container-packed tea beverages filled in containers such as cans and plastic bottles have been developed and marketed, and among tea beverages, the market for green tea beverages in particular is expanding. Consumers' preference for such tea beverages is increasing, and recently, green tea beverages with strong umami and richness and a refreshing feeling with reduced astringency tend to be preferred. Therefore, development of a method for extracting only umami components without extracting astringent catechins is desired.

このような方法として、いくつかの方法が提案されている。例えば、特許文献1には、茶葉を0〜30℃の低温水で抽出した抽出液に、ポリビニルポリピロリドン(PVPP)を接触処理してカテキンを除去することを特徴とする緑茶抽出液の製造方法が開示されている。また、特許文献2には、溶存酸素が除去され且つ0〜36℃に保持されてなる静水中に茶葉を浸漬して抽出することで旨味を有するとともに渋みが少ない茶抽出液が得られることも開示されている。さらに、特許文献3には、20℃以上60℃未満(好ましくは50℃以下)で、溶存酸素濃度1ppm以下の脱気水を用い、総カテキン類濃度及び没食子酸エステル型カテキン類濃度を特定範囲になるように抽出を行うことで、常温以下に冷却された状態で販売され飲用される場合の渋味や収歛味を抑えた茶飲料が製造できることが開示されている。   Several methods have been proposed as such methods. For example, Patent Document 1 discloses a method for producing a green tea extract characterized by removing catechins by contacting polyvinylpolypyrrolidone (PVPP) with an extract obtained by extracting tea leaves with low-temperature water at 0 to 30 ° C. Is disclosed. Patent Document 2 also discloses that a tea extract having umami and less astringency can be obtained by immersing and extracting tea leaves in still water from which dissolved oxygen is removed and maintained at 0 to 36 ° C. It is disclosed. Furthermore, in Patent Document 3, degassed water having a dissolved oxygen concentration of 1 ppm or less at 20 ° C. or more and less than 60 ° C. (preferably 50 ° C. or less) is used, and the total catechin concentration and gallic acid ester type catechin concentration are specified ranges. It is disclosed that a tea beverage with reduced astringency and astringency when sold and drunk in a state cooled to room temperature or lower can be produced by performing extraction so that

特開2003−204754号公報JP 2003-204754 A 特開2000−50799号公報JP 2000-50799 A 特開平6−343389号公報JP-A-6-343389

上記のとおり、渋味の多いカテキン類を除去または浸出させないことで、渋味を抑えた緑茶飲料を製造する方法は種々提案されているが、旨味やコク味という面で必ずしも満足できるものではなく、製造が煩雑であるという問題もあった。また、カテキン類が少ない緑茶飲料においては、レトルト殺菌等の加熱処理を行うことによって発生する不快な加熱臭が顕著で、茶類本来の良質な香気香味を阻害することがあった。   As described above, various methods for producing green tea beverages with reduced astringency by not removing or leaching astringent catechins have been proposed, but are not necessarily satisfactory in terms of umami and richness. There was also a problem that the production was complicated. Moreover, in the green tea drink with few catechins, the unpleasant heating odor which generate | occur | produces by performing heat processing, such as a retort sterilization, is remarkable, and tea's original high quality aroma flavor may be inhibited.

本発明の課題は、加熱殺菌及び長期保存を伴う容器詰茶飲料において、旨味やコク味が強く、かつ、渋味、雑味の抑えられた緑茶飲料を提供することにある。   An object of the present invention is to provide a green tea beverage that has strong umami and richness, and has reduced astringency and miscellaneous taste, in a packaged tea beverage with heat sterilization and long-term storage.

本発明者らは上記課題を解決するために鋭意検討を行った結果、茶葉として碾茶を用い45℃以下の冷水で抽出を行うと、雑味が抑制された茶抽出液が得られることを見出した。そして、この雑味の少ない碾茶の冷水抽出液は、渋味成分であるカテキン類が低濃度で、かつ旨味成分であるアミノ酸を高濃度に含有することを確認した。   As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that a tea extract with reduced miscellaneous taste can be obtained by using strawberry tea as a tea leaf and extracting with cold water at 45 ° C. or lower. It was. And it was confirmed that the cold water extract of strawberry tea with less miscellaneous taste contains a low concentration of catechins which are astringent components and a high concentration of amino acids which are umami components.

本発明者らは、また、碾茶の冷水抽出液の加熱殺菌処理に伴い発生する不快な加熱臭が、煎茶またはかぶせ茶の抽出液が配合された場合に抑制され、碾茶の冷水抽出液の持つ雑味の少ない優れた香気香味が加熱殺菌しても維持できることを見出し、本発明を完成するに至った。   Further, the present inventors have suppressed the unpleasant heating odor generated by the heat sterilization treatment of the cold water extract of strawberry tea when the extract of sencha or kabusecha is blended, and the cold water extract of strawberry tea has. The present inventors have found that an excellent aroma and flavor with less miscellaneous taste can be maintained even by heat sterilization, and have completed the present invention.

すなわち、これに限定されるものではないが、本発明は以下を包含する。
(1) 碾茶を45℃以下の水で抽出して碾茶抽出液を得る工程と、前記抽出液に加熱殺菌処理を行う工程とを含む、容器詰茶飲料の製造方法。
(2) 碾茶の抽出が、20〜45℃の水で行われる、(1)に記載の方法。
(3) 碾茶の抽出液の割合が、茶飲料全体に対して10〜90重量%である、(1)又は(2)に記載の方法。
(4) 抹茶の抽出液を混合する工程をさらに含む、(1)〜(3)のいずれかに記載の方法。
(5) 碾茶を45℃以下の水で抽出して得られる碾茶抽出液を含有し、20ppm以上のアミノ酸と120〜380ppmのカテキン類とを含有する、容器詰茶飲料。
(6) 碾茶抽出液の割合が、茶飲料全体に対して10〜90重量%である、(5)に記載の容器詰茶飲料。
(7) 碾茶を45℃以下の水で抽出して得られる碾茶抽出液を含有する容器詰茶飲料に、煎茶及び/又はかぶせ茶の抽出液を含有させることを特徴とする、加熱臭の抑制方法。
That is, although not limited to this, this invention includes the following.
(1) A method for producing a packaged tea beverage, comprising a step of extracting strawberry tea with water of 45 ° C. or less to obtain a strawberry tea extract, and a step of subjecting the extract to a heat sterilization treatment.
(2) The method according to (1), wherein the extraction of strawberry tea is performed with water at 20 to 45 ° C.
(3) The method according to (1) or (2), wherein the ratio of the tea tea extract is 10 to 90% by weight relative to the whole tea beverage.
(4) The method according to any one of (1) to (3), further comprising a step of mixing a green tea extract.
(5) A packaged tea beverage containing a tea tea extract obtained by extracting tea tea with water of 45 ° C. or less, and containing 20 ppm or more of amino acids and 120 to 380 ppm of catechins.
(6) The container-packed tea beverage according to (5), wherein the ratio of the tea tea extract is 10 to 90% by weight relative to the whole tea beverage.
(7) Inhibition of heated odor, characterized by containing a sencha and / or kabusecha extract in a packaged tea beverage containing a strawberry tea extract obtained by extracting strawberry tea with water at 45 ° C. or lower. Method.

本発明によれば、比較的簡便な方法で、渋味、雑味が抑えられ、旨味・コク味が強化された容器詰緑茶飲料を提供できる。本発明の渋味、雑味成分が抑制された緑茶飲料は、清涼感のある水色を有し、一度にゴクゴク飲めると高いドリンカビリティを有するため、暑い季節等において喉の渇きを癒す飲料として好適である。   According to the present invention, it is possible to provide a packaged green tea beverage in which astringency and miscellaneous taste are suppressed and umami and richness are enhanced by a relatively simple method. The green tea beverage with suppressed astringency and miscellaneous taste component of the present invention has a refreshing light blue color and has high drinkability when it can be drunk at once, so that it is a beverage that heals thirst in hot seasons etc. Is preferred.

本発明においては、碾茶を45℃以下の水で抽出して碾茶抽出液を得る工程と、前記抽出液に加熱殺菌処理を行う工程とによって、容器詰茶飲料を製造する。
(碾茶の冷水抽出工程)
煎茶は、通常、収穫された生茶葉を少なくとも蒸す工程(蒸熱工程)、揉む工程(粗揉工程、精揉工程)及び乾燥工程を順次経て蒸製緑茶として製茶される。本明細書の碾茶とは、収穫された生茶葉を蒸し、前記煎茶のような茶葉を揉む工程を経ないで乾燥して製造された茶葉をいう。また、本明細書中のかぶせ茶とは、茶葉を摘採する前に一定期間遮光する被覆栽培によって収穫された生茶葉を、煎茶と同様の製造工程を経て得られた茶葉をいう。
In the present invention, a packaged tea beverage is produced by a process of extracting strawberry tea with water at 45 ° C. or less to obtain a strawberry tea extract and a process of subjecting the extract to a heat sterilization treatment.
(Cold tea cold water extraction process)
Sencha is usually made as steamed green tea through at least a steaming process (steaming process), a kneading process (coarse koji process, a brewing process) and a drying process in order. As used herein, “boiled tea” refers to a tea leaf produced by steaming harvested fresh tea leaves and drying them without going through the process of brewing tea leaves such as the above-mentioned sencha. In addition, kabuse tea in the present specification refers to tea leaves obtained by subjecting fresh tea leaves harvested by covering cultivation that is shielded from light for a certain period of time before plucking tea leaves to the same manufacturing process as sencha.

本発明では、茶葉を揉む工程を経ないで製造された碾茶を原料に用いることにより、旨味・コク味が増強され、渋味、雑味が抑制された香気香味に優れた茶飲料が得られる。碾茶の抽出液が香気香味に優れる理由は明らかでないが、茶葉を揉む工程を経た煎茶は、茶葉の細胞壁に含まれる雑味成分の浸出が高められ、この雑味成分が渋味を増強したり、加熱臭を発生させたりすることがある一方、茶葉を揉む工程を経ていない碾茶は、細胞壁があまり破壊されておらず、雑味成分の浸出が少ないため、渋味がなく加熱臭も抑制されるものと推察される。   In the present invention, a tea beverage excellent in aroma and flavor with enhanced umami and richness and reduced astringency and miscellaneous taste is obtained by using, as a raw material, strawberry tea produced without going through the process of brewing tea leaves. . The reason why the extract of strawberry tea is excellent in aroma and flavor is not clear, but in sencha that has undergone the process of brewing tea leaves, the leaching of miscellaneous components contained in the cell walls of tea leaves is enhanced, and this miscellaneous component enhances astringency In addition, the tea leaves that have not undergone the process of brewing the tea leaves are not destroyed so much and the leaching of miscellaneous components is less, so the aroma is not astringent and the heat smell is suppressed. Inferred.

本発明において碾茶の抽出は、45℃以下、好ましくは40℃以下の水を用いて行う。45℃を超える温度で抽出を行うと、雑味成分の浸出を高めることになり、抽出液の香味が悪くなり、かつ、加熱殺菌時に加熱臭の発生が顕著となる。また、抽出温度が低すぎると、雑味成分は浸出されないが、加熱殺菌時に不快な加熱臭を発生させることがあることから、抽出温度の下限は、20℃以上、好ましくは25℃以上、より好ましくは30℃以上とするのがよい。なお、本明細書では、この温度帯で抽出された碾茶の抽出液を、碾茶の冷水抽出液ということもある。   In the present invention, the extraction of strawberry tea is performed using water of 45 ° C. or lower, preferably 40 ° C. or lower. When extraction is performed at a temperature exceeding 45 ° C., the leaching of miscellaneous components is increased, the flavor of the extract is deteriorated, and the generation of a heated odor becomes remarkable during heat sterilization. Further, if the extraction temperature is too low, miscellaneous components are not leached, but an unpleasant heated odor may be generated during heat sterilization, so the lower limit of the extraction temperature is 20 ° C. or higher, preferably 25 ° C. or higher. Preferably it is 30 degreeC or more. In addition, in this specification, the extract of strawberry tea extracted in this temperature range may be called cold water extract of strawberry tea.

本発明においては、上記碾茶の冷水抽出液を茶飲料全体に対して10〜90重量%程度含有させるようにするとよい。碾茶の冷水抽出液の割合が90重量%以上を超えると、加熱臭が発生する場合があり、碾茶が10重量%を下回ると、渋味、雑味が少なく豊かな旨味、コク味を有するという本発明の特徴が感じられにくい。   In this invention, it is good to make it contain about 10 to 90 weight% of the cold water extract of the said tea tea with respect to the whole tea drink. If the ratio of the cold water extract of strawberry tea exceeds 90% by weight, a heated odor may be generated, and if strawberry tea is less than 10% by weight, it has a rich aroma and rich taste with little astringency and miscellaneous taste. It is difficult to feel the features of the present invention.

碾茶の冷水抽出液を茶飲料全体に対して10〜90重量%程度含有させるには、原料茶葉全体に対し10〜90重量%の碾茶を配合して抽出を行う、又は碾茶の冷水抽出液と碾茶以外の茶葉の抽出液を別々に調製し、碾茶の冷水抽出液の割合が10〜90重量%となるように混合する、等の方法で行うことができる。   In order to contain about 10 to 90% by weight of the tea tea cold water extract with respect to the whole tea beverage, extraction is performed by blending 10 to 90% by weight of tea tea with respect to the whole raw tea leaves, or Extracts of tea leaves other than bud tea can be prepared separately and mixed so that the ratio of the chilled tea cold water extract is 10 to 90% by weight.

碾茶以外の茶葉としては、これに限定されるものではないが、例えば、煎茶、深蒸煎茶、玉露、かぶせ茶、番茶、玉緑茶、芽茶、茎茶、棒茶などの中の1種類を単独で用いてもよいし、また、2種類以上の茶葉を組み合わせて用いてもよい。さらに、緑茶などの不発酵茶に加えて、半発酵茶(例えば烏龍茶)、発酵茶(例えば紅茶)等をブレンドすることも可能である。特に、煎茶、かぶせ茶を用いると、碾茶の冷水抽出液の加熱に伴う加熱臭を効果的に抑制することができる。   Examples of tea leaves other than bud tea include, but are not limited to, for example, sencha, deep steamed sencha, gyokuro, kabusecha, bancha, tamago green tea, bud tea, stem tea, and stick tea. Or two or more types of tea leaves may be used in combination. Furthermore, in addition to non-fermented tea such as green tea, semi-fermented tea (for example, oolong tea), fermented tea (for example, black tea) and the like can be blended. In particular, when sencha or kabusecha is used, it is possible to effectively suppress the heating odor accompanying the heating of the cold water extract of strawberry tea.

本発明においては、複数の原料茶葉を混合してから抽出液を得ることもでき、また、複数の原料茶葉から複数の抽出液を得てから、その抽出液を混合して茶飲料とすることもできる。   In the present invention, it is also possible to obtain an extract after mixing a plurality of raw tea leaves, and after obtaining a plurality of extracts from a plurality of raw tea leaves, mixing the extracts to obtain a tea beverage You can also.

(加熱殺菌工程)
本発明においては、保存性に優れた容器詰茶飲料を製造するため、茶抽出液に加熱殺菌処理を行う。加熱殺菌の方法としては、公知の方法を採用することができ、例えば、レトルト殺菌法、高温短時間殺菌法(HTST法)、超高温殺菌法(UHT法)などを好適に行うことができる。容器詰飲料の容器に応じて加熱殺菌法を適宜選択することもでき、例えば、PETボトルを飲料容器として用いる場合などはUHT殺菌が好適である。また、加熱装置や加熱方式にも特に制限はなく、例えば、直接水蒸気を吹き込むスチームインジェクション式や飲料を水蒸気中に噴射して加熱するスチームインフュージョン式などの直接加熱方式、プレートやチューブなど表面熱交換器を用いる間接加熱方式など公知の方法で行うことができる。加熱殺菌の温度は目的を達することができれば特に制限されないが、90℃以上であることが好ましい。本発明の碾茶の冷水抽出液は、加熱殺菌をしても不快臭の発生が抑制されており、容器詰め飲料として特に優れている。
(Heat sterilization process)
In the present invention, the tea extract is subjected to a heat sterilization treatment in order to produce a container-packed tea beverage with excellent storage stability. As a heat sterilization method, a known method can be employed. For example, a retort sterilization method, a high temperature short time sterilization method (HTST method), an ultra high temperature sterilization method (UHT method), or the like can be suitably performed. A heat sterilization method can be appropriately selected according to the container of the packaged beverage. For example, when a PET bottle is used as a beverage container, UHT sterilization is preferable. Also, there is no particular limitation on the heating device and heating method, for example, a direct injection method such as a steam injection method in which water vapor is directly blown or a steam infusion method in which a beverage is injected into water vapor, a surface heat such as a plate or a tube. It can be performed by a known method such as an indirect heating method using an exchanger. The temperature of the heat sterilization is not particularly limited as long as the purpose can be achieved, but it is preferably 90 ° C. or higher. The cold tea extract of strawberry tea according to the present invention is particularly excellent as a container-packed beverage because the generation of an unpleasant odor is suppressed even after heat sterilization.

(容器詰緑茶飲料)
本発明の容器詰緑茶飲料では、上記の碾茶の冷水抽出液を含有させることを特徴とする。以下に、好ましい製造方法の一例を示す。
(Packed green tea beverage)
The container-packed green tea beverage of the present invention is characterized in that it contains the cold water extract of the above tea. Below, an example of a preferable manufacturing method is shown.

まず、本発明における原料茶葉中の碾茶の割合は、10〜100重量%、好ましくは10〜90重量%、好ましくは15〜60重量%、より好ましくは20〜40重量%程度である。碾茶の割合が少ないと、旨味成分が少ない、カテキン類が多い、問題が発生する場合があり、碾茶の割合が多いと加熱殺菌時に加熱臭が発生する場合がある。茶葉の混合は公知の方法で行うことができる。   First, the ratio of strawberry tea in the raw tea leaves in the present invention is about 10 to 100% by weight, preferably about 10 to 90% by weight, preferably about 15 to 60% by weight, and more preferably about 20 to 40% by weight. If the ratio of strawberry tea is small, there may be a problem that there are few umami components, there are many catechins, and if the ratio of strawberry tea is large, a heated odor may be generated during heat sterilization. The mixing of tea leaves can be performed by a known method.

本発明においては、碾茶から水を用いて抽出液を得る。抽出液である水の温度は、45℃以下、好ましくは40℃以下である。碾茶を含む茶葉を45℃を超える温度で抽出すると雑味成分が多く浸出し、香気香味が低下するためである。抽出溶媒(冷水)の割合は、通常、原料茶葉の乾燥重量を基準として、5〜500重量部、好ましくは5〜100重量部である。抽出方法は、回分式(ニーダー抽など出)、カラム式(ドリップ抽出など)等を用いることができ、抽出時間は、3〜60分、好ましくは5〜30分程度である。   In the present invention, an extract is obtained from strawberry tea using water. The temperature of water as the extract is 45 ° C. or lower, preferably 40 ° C. or lower. This is because extracting miscellaneous tea containing tea leaves at a temperature exceeding 45 ° C. leaches a lot of miscellaneous components and lowers the aroma and flavor. The ratio of the extraction solvent (cold water) is usually 5 to 500 parts by weight, preferably 5 to 100 parts by weight, based on the dry weight of the raw tea leaves. The extraction method may be a batch method (kneader extraction or the like), a column method (drip extraction or the like), and the extraction time is 3 to 60 minutes, preferably about 5 to 30 minutes.

このように得た抽出液は、公知の固液分離手段、例えばメッシュ分離、濾別や遠心分離を用いて茶葉が分離され、緑茶抽出液を得る。25℃以上の温度で抽出した場合、抽出液は、直ちに25℃以下、好ましくは5〜25℃、より好ましくは15〜25℃程度となるように冷却することが微生物制御の観点から好ましい。抽出液の温度又は冷却後の抽出液の温度が20〜25℃の場合には7.5分間以内に、抽出液の温度又は冷却後の抽出液の温度が15〜20℃の場合には13.5分間以内に加熱殺菌処理に供すことが微生物制御の観点から重要である。なお、抽出の際、または抽出後には、アスコルビン酸や重曹などのpH調整剤等の抽出助剤を添加してもよい。   From the extract thus obtained, tea leaves are separated using a known solid-liquid separation means such as mesh separation, filtration or centrifugation, and a green tea extract is obtained. When extracted at a temperature of 25 ° C. or higher, it is preferable from the viewpoint of microorganism control that the extract is immediately cooled to 25 ° C. or less, preferably 5 to 25 ° C., more preferably about 15 to 25 ° C. When the temperature of the extract or the temperature of the extract after cooling is 20 to 25 ° C., it is within 7.5 minutes, and when the temperature of the extract or the temperature of the extract after cooling is 15 to 20 ° C., 13 It is important from the viewpoint of microbial control that it is subjected to heat sterilization within 5 minutes. Note that an extraction aid such as a pH adjuster such as ascorbic acid or sodium bicarbonate may be added during or after extraction.

加熱殺菌条件は、容器の種類や保存条件等に合わせて、UHT殺菌、レトルト殺菌等を適宜選択すればよい。具体的には、缶や瓶の容器のように容器に充填後、加熱殺菌できる場合には食品衛生法に定められた殺菌条件でレトルト殺菌が採用され、ペットボトル、紙容器のようにレトルト殺菌できないものについては、あらかじめ上記と同等の殺菌条件、例えばプレート式熱交換器で高温短時間殺菌後、一定の温度まで冷却して、ホットパック充填又は無菌下での充填などの方法により容器に充填する等の方法が採用される。   The heat sterilization conditions may be appropriately selected from UHT sterilization, retort sterilization, and the like according to the type of container, storage conditions, and the like. Specifically, if the container can be heated and sterilized after filling into a container such as a can or bottle, retort sterilization is adopted under the sterilization conditions stipulated in the Food Sanitation Law, and retort sterilization is performed like a plastic bottle or paper container. For those that cannot, pre-sterilize the same conditions as above, for example, sterilize at high temperature and short time in a plate heat exchanger, cool to a certain temperature, and fill the container by hot pack filling or aseptic filling. Such a method is adopted.

本発明の容器詰飲料は、上述の製造方法、即ち碾茶を他の茶葉と混合して冷水抽出液を得て茶飲料として製造されるものに限定されず、例えば碾茶の冷水抽出液と他の茶葉の抽出液とを混合して得られる茶飲料も含まれる。いずれの場合においても、碾茶の冷水抽出液の香気香味を活かすには、茶飲料全体に対し、カテキン類が380ppm以下、好ましくは350ppm以下、より好ましくは300ppm以下となるように調整するのがよい。カテキン類が380ppmを超えると、カテキン類由来の渋味が顕著に感じられ、碾茶由来の旨味・コク味を阻害することになる。カテキン類の下限値は、120ppm程度である。カテキン類が120ppmを下回ると、茶本来の香味(適度な渋味)が得られず、水っぽい味わいとなる。また、茶飲料全体に対し、アミノ酸が20ppm以上存在すると、碾茶由来の旨味・コク味を顕著に感じられ、香気香味に優れた飲料となる。   The container-packed beverage of the present invention is not limited to the above-described production method, that is, not limited to a method in which strawberry tea is mixed with other tea leaves to obtain a cold water extract and manufactured as a tea beverage. A tea beverage obtained by mixing with tea leaf extract is also included. In any case, in order to make use of the aroma and flavor of the cold water extract of strawberry tea, the catechins should be adjusted to 380 ppm or less, preferably 350 ppm or less, more preferably 300 ppm or less with respect to the whole tea beverage. . If the catechins exceed 380 ppm, the astringent taste derived from the catechins is noticeably felt, and the umami and rich taste derived from strawberry tea are inhibited. The lower limit of catechins is about 120 ppm. When catechins are less than 120 ppm, the original flavor of tea (appropriate astringency) cannot be obtained, and the taste becomes watery. Moreover, when 20 ppm or more of amino acid exists with respect to the whole tea drink, the umami | savory taste and rich taste derived from strawberry tea will be felt notably, and it will become a drink excellent in aroma flavor.

すなわち、碾茶の冷水抽出液を含有し、アミノ酸が20ppm以上、カテキン類が120〜380ppmとなるように調整された茶飲料が、本発明の茶飲料の好ましい態様の一つとして例示される。ここで、本明細書でいうカテキンとは、カテキン、ガロカテキン、カテキンガレート、ガロカテキンガレート、エピカテキン、エピガロカテキン、エピカテキンガレート、エピガロカテキンガレートの8種類の総称をいう。本発明では、これらカテキンのうち、1種以上を上記範囲となるように含有させればよい。   That is, a tea beverage containing a cold water extract of strawberry tea and adjusted to have an amino acid content of 20 ppm or more and a catechin content of 120 to 380 ppm is exemplified as one preferred embodiment of the tea beverage of the present invention. Here, the term “catechin” as used herein refers to eight general names of catechin, gallocatechin, catechin gallate, gallocatechin gallate, epicatechin, epigallocatechin, epicatechin gallate, and epigallocatechin gallate. In this invention, what is necessary is just to contain 1 or more types among these catechins so that it may become the said range.

さらに、本発明の茶飲料には、抹茶の抽出液を配合することが好ましい。抹茶とは、碾茶を石臼で挽く等により微細化したものである。抹茶の抽出液を配合することにより、碾茶の冷水抽出液にはほとんど含まれないグリセロ糖脂質を、茶飲料中に含有させることができる。本発明者らの検討によると、グリセロ糖脂質は、茶飲料、特に緑茶飲料のコク味を増強させるのに有効な成分である。本発明の茶飲料のような、カテキン類の少ない茶飲料においては、グリセロ糖脂質の存在が、飲料にボディ感を付与するのに効果的である。   Furthermore, it is preferable to mix a green tea extract with the tea beverage of the present invention. Matcha tea is refined by grinding tea with a stone mill. By blending the matcha tea extract, glyceroglycolipids that are hardly contained in the cold water extract of strawberry tea can be contained in the tea beverage. According to the study by the present inventors, glyceroglycolipid is an effective component for enhancing the body taste of tea beverages, particularly green tea beverages. In tea beverages with few catechins, such as the tea beverage of the present invention, the presence of glyceroglycolipid is effective for imparting a body feeling to the beverage.

なお、抹茶の抽出は、冷水を用いた抽出とするのが好ましい。抹茶の冷水抽出液は、碾茶の場合と同様に、旨味・コク味が強く、渋味が抑制されている。冷水の具体的温度は、碾茶の抽出温度と同等、またはそれ以下の温度が好ましく、45℃以下、好ましくは40℃以下、より好ましくは35℃以下をいう。抹茶は碾茶よりも細胞壁成分、すなわち雑味成分が浸出しやすいため、より低温で抽出するのが好ましいのである。   In addition, it is preferable that extraction of matcha is performed using cold water. The cold water extract of matcha has a strong umami and rich taste and astringency is suppressed, as in the case of strawberry tea. The specific temperature of the cold water is preferably equal to or lower than the extraction temperature of strawberry tea, and is 45 ° C. or lower, preferably 40 ° C. or lower, more preferably 35 ° C. or lower. Matcha tea is preferably extracted at a lower temperature because cell wall components, i.e., miscellaneous components, tend to leach out from tea.

抹茶の冷水抽出液は、抹茶を冷水に懸濁することにより調製されるが、必要に応じて、前記抹茶の冷水懸濁液に高圧ホモジナイザー処理を行って、グリセロ糖脂質の浸出を高めてもよい。高圧ホモジナイザーの圧力は、5〜30MPa、好ましくは10〜20MPa程度である。   The green tea cold water extract is prepared by suspending green tea in cold water, but if necessary, the cold water suspension of the green tea may be subjected to a high-pressure homogenizer treatment to enhance leaching of glyceroglycolipid. Good. The pressure of the high-pressure homogenizer is about 5 to 30 MPa, preferably about 10 to 20 MPa.

抹茶の冷水懸濁液(高圧ホモジナイザー処理をしたものも含む)は、遠心分離等の清澄化処理を行うのが好ましい。抹茶由来の不溶性固形分が喉越しに影響を与える他、不溶性固形分中の細胞壁成分の雑味が、茶飲料の香気香味、特に加熱殺菌処理における香気香味に影響を及ぼすためである。   It is preferable that a chilled water suspension of matcha (including those subjected to a high-pressure homogenizer treatment) is subjected to a clarification treatment such as centrifugation. This is because the insoluble solid content derived from Matcha affects the throat, and the miscellaneous taste of cell wall components in the insoluble solid affects the aroma flavor of the tea beverage, particularly the aroma flavor in the heat sterilization treatment.

このようにして得られる抹茶の抽出液は、グリセロ糖脂質が茶飲料全体に対して0.2μg/ml以上、好ましくは0.4μg/ml以上の割合となるように配合するとよい。   The green tea extract thus obtained may be blended so that the glyceroglycolipid is 0.2 μg / ml or more, preferably 0.4 μg / ml or more based on the whole tea beverage.

以下の実施例により、本発明をより具体的に説明するが、本発明はこれらに限定されるものではない。なお、本明細書において、配合割合などは重量基準であり、数値範囲はその端点を含むものとして記載される。   The present invention will be described more specifically with reference to the following examples, but the present invention is not limited thereto. In the present specification, the blending ratio and the like are based on weight, and the numerical range is described as including the end points.

実験1:抽出温度の影響
碾茶(福寿園)の乾燥重量に対して30重量部の水を抽出溶媒として用いた。抽出溶媒の温度を30℃(実施例1)、40℃(実施例2)、45℃(実施例3)及び50℃(比較例1)とし、8分間抽出した後、茶葉を分離し、さらに遠心分離処理(6000rpm、10分)により粗大な粉砕茶組織や茶粒子などの固形分を除去して、碾茶の冷水抽出液を得た。これに重曹及びアスコルビン酸を混合しpHを6〜7に調整した後、缶容器に充填し、加熱殺菌(130℃、2分)して容器詰茶飲料を得た。
Experiment 1: Influence of extraction temperature 30 parts by weight of water was used as an extraction solvent with respect to the dry weight of 碾 茶 (Fukujuen). The temperature of the extraction solvent was 30 ° C. (Example 1), 40 ° C. (Example 2), 45 ° C. (Example 3), and 50 ° C. (Comparative Example 1). After extraction for 8 minutes, the tea leaves were separated, Centrifugation (6000 rpm, 10 minutes) removed solids such as coarse crushed tea tissue and tea particles to obtain a cold water extract of strawberry tea. Sodium bicarbonate and ascorbic acid were mixed with this to adjust the pH to 6 to 7, and then filled into a can container and sterilized by heating (130 ° C., 2 minutes) to obtain a packaged tea beverage.

この茶飲料について、専門パネラー8名で官能評価した。評価は、コク味、旨味、後味のスッキリ感、雑味、ボディ感(飲み応え)、好ましい香気(青々しい香り)について、5段階で行い、平均値を求めた。評価基準は以下のとおりである。5点:強く感じる、4点:感じる、3点:少し感じる、2点:ほとんど感じない、1点:感じない。   About this tea drink, sensory evaluation was carried out by eight expert panelists. Evaluation was carried out in five stages for the refreshing taste, umami, aftertaste, miscellaneous taste, body feeling (drinking response), and preferred aroma (bluish fragrance), and the average value was obtained. The evaluation criteria are as follows. 5 points: feel strong 4 points: feel 3 points: feel a little 2 points: hardly feel 1 point: feel no

結果を表1に示す。表1から明らかなように、抽出温度が低くなると雑味が少なくなる傾向があった。碾茶を50℃で抽出して得た茶飲料(比較例1)ではスッキリ感がなく、雑味があるのに対し、45℃以下の冷水で抽出して得た茶飲料(実施例1〜3)では、コク味や旨味、飲み応え、青々しい香りは保持しながらも、雑味がなく、すっきり飲めるという評価であった。   The results are shown in Table 1. As is clear from Table 1, there was a tendency for the miscellaneous taste to decrease as the extraction temperature decreased. The tea beverage obtained by extracting strawberry tea at 50 ° C. (Comparative Example 1) does not have a refreshing feeling and has a miscellaneous taste, whereas the tea beverage obtained by extraction with cold water of 45 ° C. or less (Examples 1 to 3) ) Was evaluated as having a rich taste, umami, drinking response, and a lush fragrance, but without any miscellaneous taste.

Figure 0005536381
Figure 0005536381

実験2:アミノ酸およびカテキン類の影響
実施例1と同様にして、碾茶を40℃以下の各温度帯で抽出し、表2に示すカテキン類及びアミノ酸含量となるように適宜水を配合して、pH調整、加熱殺菌を行い、容器詰茶飲料を製造した。
Experiment 2: Influence of amino acids and catechins In the same manner as in Example 1, strawberry tea was extracted at each temperature zone of 40 ° C. or less, and water was appropriately added so that the catechins and amino acid contents shown in Table 2 were obtained. pH adjustment and heat sterilization were performed to produce a packaged tea beverage.

この茶飲料について、実験1と同様に官能評価を行った。カテキン類及びアミノ酸の測定方法は以下のとおりである。
<カテキン類の測定>
カテキン類は、試料となる茶飲料をメンブレンフィルター(孔径0.45μm、十慈フィールド株式会社 水系未滅菌13A)で固形分を除去した後、HPLC分析に供して測定した。
(HPLC分析条件)
・分析装置:東ソー株式会社、TOSOH HPLCシステム LC8020 model II
[マルチステーション:LC−8020、ポンプ:CCMC−II、オートサンプラ:AS−8021、検出器:UV−8020、カラムオーブン:CO−8020、オンラインデガッサ:SD−8023]
・分析条件:[カラム:TSKgel ODS−80Ts QA(TOSOH社、内径4.6mm×長さ150mm)、溶離液A:[10%アセトニトリル/水]+0.05%TFA(トリフルオロ酢酸)、溶離液B:[80%アセトニトリル/水]+0.05%TFA、流速:1.0ml/min、温度40℃、検出:UV275nm]
・グラジエント条件:
The tea beverage was subjected to sensory evaluation in the same manner as in Experiment 1. The methods for measuring catechins and amino acids are as follows.
<Measurement of catechins>
The catechins were measured by subjecting the tea beverage to be a sample to HPLC analysis after removing the solid content with a membrane filter (pore size: 0.45 μm, Toji Field Corporation, water-based non-sterile 13A).
(HPLC analysis conditions)
・ Analyzer: Tosoh Corporation, TOSOH HPLC system LC8020 model II
[Multi-station: LC-8020, pump: CCMC-II, autosampler: AS-8021, detector: UV-8020, column oven: CO-8020, online degasser: SD-8023]
Analysis conditions: [Column: TSKgel ODS-80Ts QA (TOSOH, inner diameter 4.6 mm × length 150 mm), eluent A: [10% acetonitrile / water] + 0.05% TFA (trifluoroacetic acid), eluent B : [80% acetonitrile / water] + 0.05% TFA, flow rate: 1.0 ml / min, temperature 40 ° C., detection: UV 275 nm]
・ Gradient condition:

Figure 0005536381
Figure 0005536381

<アミノ酸の測定>
アミノ酸は、飲料中のアミノ態窒素を測定した。アミノ態窒素は、TNBS法(trinitro benzen sulfanic acid法)で測定した。まず、試料となる茶飲料に、リン酸緩衝溶液及び0.1% 2,4,6-Trinitro Benzenesulfanic acid Na塩水溶液を混合し、45℃で90分間反応させた後、蛍光強度(OD340nm)を測定した。グリシン標準液から検量線を作成し、資料中のアミノ態窒素の含有量をグリシン相当として算出した。
<Measurement of amino acids>
For amino acids, amino nitrogen in the beverage was measured. Amino nitrogen was measured by the TNBS method (trinitro benzen sulfanic acid method). First, a phosphate buffer solution and a 0.1% 2,4,6-Trinitro Benzenesulfanic acid Na salt aqueous solution are mixed in a tea beverage as a sample, reacted at 45 ° C. for 90 minutes, and then the fluorescence intensity (OD 340 nm) is measured. It was measured. A calibration curve was prepared from the glycine standard solution, and the amino nitrogen content in the data was calculated as glycine equivalent.

表3に、結果を示す。アミノ態窒素が20ppm以上、カテキン類が120ppm〜380ppmである(実施例4〜7)と、コク味や旨味、飲み応え、青々しい香りは保持しながらも、雑味がなく、すっきり飲めるという評価であった。   Table 3 shows the results. Evaluation that amino nitrogen is 20 ppm or more, and catechins are 120 ppm to 380 ppm (Examples 4 to 7), the rich taste, umami, drinking response, and lush aroma are retained, but there is no miscellaneous taste and refreshing Met.

Figure 0005536381
Figure 0005536381

実験3:碾茶以外の冷水抽出液とのブレンド
煎茶(福寿園)またはかぶせ茶(福寿園)を用いて40℃の水を用いて茶抽出液を調製した。この煎茶抽出液・かぶせ茶抽出液を、実験1と同様の方法で抽出した碾茶抽出液(抽出温度:40℃、5℃)と混合し、表4に示すカテキン類及びアミノ酸含量となるように適宜水を配合して、pH調整、加熱殺菌して、茶飲料を製造した。
Experiment 3: A tea extract was prepared using 40 ° C water using blended sencha (Fukujuen) or kabusecha (Fukujuen) with a cold water extract other than tea. This sencha extract / kabuse tea extract was mixed with the strawberry tea extract (extraction temperature: 40 ° C., 5 ° C.) extracted in the same manner as in Experiment 1, so that the catechins and amino acid contents shown in Table 4 were obtained. Water was appropriately mixed, pH was adjusted, and heat sterilization was performed to produce a tea beverage.

カテキン類及びアミノ態窒素の測定と官能評価の結果を表4に示す。碾茶の冷水抽出液に、煎茶やかぶせ茶の冷水抽出液を混合した場合も、好ましい茶飲料を得ることができた。特に、茶飲料に含まれるアミノ態窒素が20ppm以上、カテキン類が120ppm〜380ppmである(実施例11〜14)と、コク味や旨味、飲み応え、青々しい香りは保持しながらも、雑味がなく、すっきり飲めるという評価であった。   Table 4 shows the results of measurement and sensory evaluation of catechins and amino nitrogen. Even when the cold water extract of strawberry tea was mixed with the cold water extract of sencha or kabusecha, a preferred tea beverage could be obtained. In particular, the amino nitrogen contained in the tea beverage is 20 ppm or more, and the catechins are 120 ppm to 380 ppm (Examples 11 to 14). There was no evaluation, and it was an evaluation that it could be refreshed.

Figure 0005536381
Figure 0005536381

実験4:加熱臭の評価
40℃で抽出した碾茶の抽出液(実施例4)、40℃で抽出した碾茶の抽出液75%と40℃で抽出した煎茶の抽出液25%の混合液(実施例11)、20℃抽出した碾茶の抽出液75%と20℃で抽出した煎茶25%の抽出液25%の混合液(実施例17)、5℃抽出した碾茶の抽出液75%と5℃で抽出した煎茶25%の抽出液混合液(実施例18)を、それぞれ実験1と同様にして、pH調整、加熱殺菌して容器詰茶飲料を得、それぞれ官能評価を行った。
Experiment 4: Evaluation of heating odor A mixture of strawberry tea extract extracted at 40 ° C (Example 4), 75% strawberry tea extract extracted at 40 ° C and 25% sencha extract extracted at 40 ° C (implementation) Example 11), a mixture of 75% of a tea extract extracted at 20 ° C. and 25% of an extract of 25% sencha extracted at 20 ° C. (Example 17) 75% of a tea extract extracted at 5 ° C. and 5 ° C. In the same manner as in Experiment 1, the mixed liquid of 25% sencha extracted in the above (Example 18) was subjected to pH adjustment and heat sterilization to obtain a packaged tea beverage, and each was subjected to sensory evaluation.

いずれもコク味、旨味、スッキリ感、飲み応えがあり、雑味は少なかったが、加熱臭は、碾茶のみで製造した茶飲料(実施例4)と比べ、碾茶に煎茶の抽出を混合して製造した茶飲料(実施例11)の方が少なかった。また、抽出温度を比較すると、5℃抽出して製造した茶飲料(実施例18)に比べ、20℃(実施例17)または40℃抽出して製造した茶飲料(実施例の方が少なかった。これより、碾茶の抽出温度は20〜40℃程度が加熱臭の抑制に適当であること、碾茶に煎茶等を組み合わせると加熱臭が抑制されることが示唆された。   All had richness, umami, refreshing feeling, drinking response, and less miscellaneous taste, but the heated odor was mixed with sencha extract extracted from strawberry tea compared to tea drink made only with strawberry tea (Example 4). There were fewer tea beverages produced (Example 11). Moreover, when comparing the extraction temperature, the tea beverage produced by extracting at 20 ° C. (Example 17) or 40 ° C. (Example was less) than the tea beverage produced by extracting at 5 ° C. (Example 18). From this, it was suggested that the extraction temperature of strawberry tea is about 20 to 40 ° C. is suitable for suppressing heated odor, and that odor is suppressed when sencha is combined with strawberry tea.

実験5:粉砕碾茶の冷水抽出液
碾茶を石臼挽きした抹茶(福寿園、粒度:10,000±2,000cm2/g)を、80倍倍量の30℃の水に懸濁し、この懸濁液を高圧ホモジナイザーにより15MPaの圧力で処理し、遠心分離処理(6000rpm、2分)して粗大な粉砕茶組織や茶粒子などの固形分を除去して、抹茶の冷水抽出液を調製した。
Experiment 5: Cold water extract of ground tea tea Matcha tea (Fukujuen, grain size: 10,000 ± 2,000cm 2 / g) made from ground tea is suspended in 80 times the amount of 30 ° C water, and this suspension is used as a high-pressure homogenizer. Was processed at a pressure of 15 MPa and centrifuged (6000 rpm, 2 minutes) to remove solid components such as coarse crushed tea tissue and tea particles, thereby preparing a green tea cold water extract.

この抹茶の冷水抽出液を、実験1と同様に調製した碾茶の冷水抽出液(抽出温度:40℃)に、種々の割合で混合した後、容器に充填して加熱殺菌し、容器詰飲料とした。碾茶抽出液と抹茶抽出液とは、茶飲料中のグリセロ糖脂質が0μg/ml,0.1μg/ml,0.2μg/ml,0.4μg/ml,0.8μg/mlとなるように混合した。得られた茶飲料について、抹茶の冷水抽出液を混合していない本発明品4を基準(対照)に、6段階(5点:対照より著しく強く感じる、4点:対照より十分感じる、3点:対照より感じる、2点:対照より少し感じる、1点:対照よりわずかに感じる、0点:対照と同等)で評価した。   This green tea cold water extract was mixed in various proportions with the tea tea cold water extract (extraction temperature: 40 ° C.) prepared in the same manner as in Experiment 1, and then filled in a container and sterilized by heating. did. The tea tea extract and matcha tea extract are mixed so that the glyceroglycolipid in the tea beverage is 0 μg / ml, 0.1 μg / ml, 0.2 μg / ml, 0.4 μg / ml, and 0.8 μg / ml. did. About the obtained tea beverage, 6 points (5 points: feel significantly stronger than the control, 4 points: feel more sufficiently than the control, 3 points, based on the product 4 of the present invention which is not mixed with the green tea cold water extract) : Feeling from control, 2 points: Feeling slightly from control, 1 point: Feeling slightly from control, 0 point: Equivalent to control.

グリセロ糖脂質の測定方法は以下のとおり。
<グリセロ糖脂質の測定方法>
グリセロ糖脂質の定量分析条件は以下の通りである。
・逆相カラム:TSKgel ODS−80Ts QA (TOSOH社、内径4.6mm×長さ150mm)
・サンプル注入量:10μl
・流量:1.0ml/min.
・RI検出器:SHIMADZU社 RIA-10A
・溶離液:95%メタノール
・温度:40℃
定量分析の標品としては、Lipid Products社のMGDG、DGDGを使用した。MGDGの標品を分析すると大きく二つのピークに分かれ、茶飲料中にみられるピークが保持時間が後ろのピークだったので、標品のピーク面積の比率に基づいて濃度を比例配分し、分析濃度とした。なお、本明細書におけるグリセロ糖脂質の濃度は、特に示した場合を除き、MGDG、DGDGの合計値として表した。
The measurement method of glyceroglycolipid is as follows.
<Method for measuring glyceroglycolipid>
The conditions for quantitative analysis of glyceroglycolipid are as follows.
-Reversed phase column: TSKgel ODS-80Ts QA (TOSOH, inner diameter 4.6 mm x length 150 mm)
Sample injection volume: 10 μl
-Flow rate: 1.0 ml / min.
・ RI detector: SHIMADZU RIA-10A
-Eluent: 95% methanol-Temperature: 40 ° C
As a standard for quantitative analysis, MGDG and DGDG manufactured by Lipid Products were used. Analyzing the MGDG sample, it was roughly divided into two peaks, and the peak found in the tea beverage was the peak after the retention time, so the concentration was proportionally distributed based on the ratio of the peak area of the sample, and the analysis concentration It was. The concentration of glyceroglycolipid in the present specification was expressed as the total value of MGDG and DGDG unless otherwise specified.

結果を表5に示す。グリセロ糖脂質を0.2μg/ml以上含有させることで、スッキリ感、雑味を変えずに、コク味・旨味・飲み応えをより一層増強できることがわかった。   The results are shown in Table 5. It was found that the inclusion of 0.2 μg / ml or more of glyceroglycolipid can further enhance the richness, umami, and drinking response without changing the refreshing feeling and miscellaneous taste.

Figure 0005536381
Figure 0005536381

Claims (6)

碾茶を45℃以下の水で抽出して碾茶抽出液を得る工程と、
煎茶抽出液と碾茶抽出液とを、碾茶抽出液の割合が10〜90重量%となるように混合する工程と、
混合した液に加熱殺菌処理を行う工程と、
を含む、20ppm以上のアミノ酸と120〜380ppmのカテキン類を含有する容器詰緑茶飲料の製造方法。
Extracting the tea with water at 45 ° C. or less to obtain a tea tea extract;
Mixing the sencha extract and the tea extract so that the ratio of the tea extract is 10 to 90% by weight;
A step of heat sterilizing the mixed liquid;
The manufacturing method of the container-packed green tea drink containing 20 ppm or more of amino acids and 120-380 ppm catechins .
碾茶の抽出が、20〜40℃の水で行われる、請求項1に記載の方法。   The method according to claim 1, wherein the extraction of bud tea is performed with water at 20 to 40 ° C. 抹茶の抽出液を混合する工程をさらに含む、請求項1又は2に記載の方法。   The method according to claim 1, further comprising a step of mixing the matcha tea extract. 碾茶を45℃以下の水で抽出して得られる碾茶抽出液と煎茶抽出液を含有し、20ppm以上のアミノ酸と120〜380ppmのカテキン類とを含有する、容器詰緑茶飲料。 A packaged green tea beverage containing a tea tea extract and a sencha extract obtained by extracting tea with water at 45 ° C. or less, and containing 20 ppm or more of amino acids and 120 to 380 ppm of catechins. 碾茶抽出液の割合が、緑茶飲料全体に対して10〜90重量%である、請求項に記載の容器詰緑茶飲料。 The container-packed green tea beverage according to claim 4 , wherein the ratio of the tea tea extract is 10 to 90% by weight relative to the whole green tea beverage. 抹茶の抽出液をさらに含む、請求項4又は5に記載の緑茶飲料。 The green tea beverage according to claim 4 or 5 , further comprising a matcha tea extract.
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