JP2016056331A - Multiple agent type article for oxidative composition - Google Patents
Multiple agent type article for oxidative composition Download PDFInfo
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- JP2016056331A JP2016056331A JP2014186406A JP2014186406A JP2016056331A JP 2016056331 A JP2016056331 A JP 2016056331A JP 2014186406 A JP2014186406 A JP 2014186406A JP 2014186406 A JP2014186406 A JP 2014186406A JP 2016056331 A JP2016056331 A JP 2016056331A
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- 239000000203 mixture Substances 0.000 title claims abstract description 268
- 230000001590 oxidative effect Effects 0.000 title claims abstract description 101
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 114
- 238000004061 bleaching Methods 0.000 claims abstract description 106
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 69
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 54
- 150000001875 compounds Chemical class 0.000 claims abstract description 44
- 150000004967 organic peroxy acids Chemical class 0.000 claims abstract description 20
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- 239000002243 precursor Substances 0.000 claims abstract description 12
- 150000002978 peroxides Chemical class 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims description 95
- 239000003814 drug Substances 0.000 claims description 54
- 229940079593 drug Drugs 0.000 claims description 54
- 125000004432 carbon atom Chemical group C* 0.000 claims description 36
- -1 organic peracids Compound Chemical class 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 11
- 238000004140 cleaning Methods 0.000 claims description 8
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 5
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 4
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 3
- 125000004429 atom Chemical group 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 229940126534 drug product Drugs 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 239000000825 pharmaceutical preparation Substances 0.000 claims description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 2
- 239000003599 detergent Substances 0.000 abstract description 41
- 239000003513 alkali Substances 0.000 abstract description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 5
- 239000001301 oxygen Substances 0.000 abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 abstract description 5
- 238000005406 washing Methods 0.000 abstract description 4
- 239000007844 bleaching agent Substances 0.000 description 49
- 239000007921 spray Substances 0.000 description 38
- 239000002738 chelating agent Substances 0.000 description 11
- 230000002708 enhancing effect Effects 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- NGSWKAQJJWESNS-UHFFFAOYSA-N 4-coumaric acid Chemical group OC(=O)C=CC1=CC=C(O)C=C1 NGSWKAQJJWESNS-UHFFFAOYSA-N 0.000 description 8
- 239000002736 nonionic surfactant Substances 0.000 description 8
- 238000005507 spraying Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 150000002430 hydrocarbons Chemical group 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- NGSWKAQJJWESNS-ZZXKWVIFSA-M 4-Hydroxycinnamate Natural products OC1=CC=C(\C=C\C([O-])=O)C=C1 NGSWKAQJJWESNS-ZZXKWVIFSA-M 0.000 description 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 4
- DFYRUELUNQRZTB-UHFFFAOYSA-N Acetovanillone Natural products COC1=CC(C(C)=O)=CC=C1O DFYRUELUNQRZTB-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000002252 acyl group Chemical group 0.000 description 4
- 239000002280 amphoteric surfactant Substances 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000002552 dosage form Substances 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 241000222290 Cladosporium Species 0.000 description 2
- 101150020891 PRKCA gene Proteins 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000005708 Sodium hypochlorite Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004042 decolorization Methods 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 238000009991 scouring Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 229940045872 sodium percarbonate Drugs 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N COC(c(cc1)ccc1O)=O Chemical compound COC(c(cc1)ccc1O)=O LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 239000004343 Calcium peroxide Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- JGFDZZLUDWMUQH-UHFFFAOYSA-N Didecyldimethylammonium Chemical class CCCCCCCCCC[N+](C)(C)CCCCCCCCCC JGFDZZLUDWMUQH-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000004450 alkenylene group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000001449 anionic compounds Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-O bis(2-hydroxyethyl)azanium Chemical compound OCC[NH2+]CCO ZBCBWPMODOFKDW-UHFFFAOYSA-O 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 description 1
- 235000019402 calcium peroxide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- RLGQACBPNDBWTB-UHFFFAOYSA-N cetyltrimethylammonium ion Chemical class CCCCCCCCCCCCCCCC[N+](C)(C)C RLGQACBPNDBWTB-UHFFFAOYSA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- QQJDHWMADUVRDL-UHFFFAOYSA-N didodecyl(dimethyl)azanium Chemical class CCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCC QQJDHWMADUVRDL-UHFFFAOYSA-N 0.000 description 1
- MELGLHXCBHKVJG-UHFFFAOYSA-N dimethyl(dioctyl)azanium Chemical class CCCCCCCC[N+](C)(C)CCCCCCCC MELGLHXCBHKVJG-UHFFFAOYSA-N 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 150000002016 disaccharides Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- VICYBMUVWHJEFT-UHFFFAOYSA-N dodecyltrimethylammonium ion Chemical class CCCCCCCCCCCC[N+](C)(C)C VICYBMUVWHJEFT-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- DELLBLKQOILBPT-UHFFFAOYSA-N ethyl-dimethyl-tetradecylazanium Chemical class CCCCCCCCCCCCCC[N+](C)(C)CC DELLBLKQOILBPT-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 229960002163 hydrogen peroxide Drugs 0.000 description 1
- GTTBQSNGUYHPNK-UHFFFAOYSA-N hydroxymethylphosphonic acid Chemical compound OCP(O)(O)=O GTTBQSNGUYHPNK-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 150000002891 organic anions Chemical class 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000004076 pulp bleaching Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- PCMORTLOPMLEFB-ONEGZZNKSA-N sinapic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC(OC)=C1O PCMORTLOPMLEFB-ONEGZZNKSA-N 0.000 description 1
- PCMORTLOPMLEFB-UHFFFAOYSA-N sinapinic acid Natural products COC1=CC(C=CC(O)=O)=CC(OC)=C1O PCMORTLOPMLEFB-UHFFFAOYSA-N 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical class O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- GLFDLEXFOHUASB-UHFFFAOYSA-N trimethyl(tetradecyl)azanium Chemical class CCCCCCCCCCCCCC[N+](C)(C)C GLFDLEXFOHUASB-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
Abstract
Description
本発明は、酸化性組成物用多剤型物品に関する。詳しくは、住環境設備等に使用する漂白剤組成物や漂白洗浄剤組成物として好適な酸化性組成物を調製するための酸化性組成物用多剤型物品に関する。 The present invention relates to a multi-drug article for an oxidizing composition. More specifically, the present invention relates to a multi-drug article for an oxidizing composition for preparing an oxidizing composition suitable as a bleaching composition or a bleaching detergent composition used for living environment facilities.
酸化性組成物は、他の物質に対して酸化作用を有する化合物を含む組成物である。この酸化作用は、有色物質に対しては、脱色、漂白、変色などの現象として認識され得るものである。酸化性組成物は、風呂・トイレ・台所等の硬質表面の漂白、カビ取り、衣類の漂白、汚れ・匂い原因物質の分解、除菌、パルプの漂白、繊維の精練などの様々な用途に用いられている。すなわち、硬質表面への適用として、硬質表面の脱色、漂白などの色素の変質に酸化性組成物を用いることが知られている。 An oxidizing composition is a composition containing a compound having an oxidizing action on other substances. This oxidation action can be recognized as a phenomenon such as decolorization, bleaching, and discoloration for colored substances. Oxidizing compositions are used for various purposes such as bleaching hard surfaces such as baths, toilets and kitchens, removing mold, bleaching clothes, decomposing dirt and odor-causing substances, disinfecting, pulp bleaching, and fiber scouring. It has been. That is, as an application to a hard surface, it is known to use an oxidizing composition for alteration of a pigment such as decolorization or bleaching of a hard surface.
生活環境において発生する様々な汚れに対し、外観上の美観維持、衛生などの目的から、洗浄、漂白、除菌などの対処が行なわれている。なかでも、トイレ、浴室、風呂釜、配水管などの洗浄し難い場所の汚れは、界面活性剤などを主成分とした洗浄剤のみでは除去困難であり、しばしば漂白剤が使用されている。一例を挙げると、浴室の浴槽、タイル目地、ドア枠、窓枠、コントローラや、台所の三角コーナーなどの黒ずみ汚れはＣｌａｄｏｓｐｏｒｉｕｍ属細菌等のカビが生産する色素が原因であり、クレンザーや界面活性剤だけでは除去し難いので、次亜塩素酸ナトリウム水溶液の漂白作用により除去する方法が一般に行われている。 For various stains generated in the living environment, countermeasures such as washing, bleaching, and sterilization are performed for the purpose of maintaining the appearance and hygiene. In particular, dirt in places that are difficult to clean, such as toilets, bathrooms, bath tubs, and water pipes, is difficult to remove only with a cleaning agent mainly composed of a surfactant or the like, and a bleaching agent is often used. For example, dark stains such as bath tubs, tile joints, door frames, window frames, controllers, and triangular corners of kitchens are caused by pigments produced by molds such as Cladosporium bacteria, cleansers and surfactants. Since it is difficult to remove it by itself, a method of removing it by bleaching action of a sodium hypochlorite aqueous solution is generally performed.
しかしながら、次亜塩素酸ナトリウムを使用したカビ取り剤は、漂白及び洗浄性能は優れているが目や皮膚に対する刺激が強く、特有の塩素系の臭いを有し狭い浴室などで使用する場合には注意が必要であり、また、誤って酸性の洗浄剤と混合すると有毒ガスを発生するという問題がある。 However, mold remover using sodium hypochlorite has excellent bleaching and cleaning performance, but it is highly irritating to eyes and skin, and has a specific chlorine-based odor. Attention is required, and there is a problem that a toxic gas is generated when mixed with an acidic cleaning agent by mistake.
このため、このような課題の発生しない酸化性組成物として、酸素系漂白剤を使用したカビ取り剤の提案がされている。例えば、特許文献１には、過酸化水素、アルカリ剤及び漂白活性化剤を併用した硬表面用漂白剤組成物が開示されている。 For this reason, a mold removing agent using an oxygen bleach has been proposed as an oxidizing composition that does not cause such problems. For example, Patent Document 1 discloses a bleaching composition for hard surfaces using hydrogen peroxide, an alkali agent and a bleach activator in combination.
また、特許文献２には、水に溶解して過酸化水素を発生する過酸化物、キレート剤、銅化合物及びバインダー化合物とからなる高い殺菌・除菌効果を発揮する組成物が開示されている。 Patent Document 2 discloses a composition that exhibits a high bactericidal / sterilizing effect, which comprises a peroxide that dissolves in water to generate hydrogen peroxide, a chelating agent, a copper compound, and a binder compound. .
また、特許文献３には過酸化水素を含有し特定の緩衝能を有するＡ剤、並びに、アルカリ剤を含有するＢ剤からなる２剤型漂白剤が開示されている。 Patent Document 3 discloses a two-component bleaching agent comprising an A agent containing hydrogen peroxide and having a specific buffer capacity, and a B agent containing an alkali agent.
しかしながら、カビ汚れは除去困難な強固な汚れであり、従来提案されている酸素系漂白剤を使用したカビ取り剤等は、更なる性能向上が望まれる。本発明は、カビ汚れなどの除去困難な汚れに対する漂白性能や漂白洗浄性能を向上させた酸素系漂白剤組成物ないし酸素系漂白洗浄剤組成物として好適な酸化性組成物用の多剤型物品を提供するものである。 However, mold stains are hard stains that are difficult to remove, and a conventionally proposed mold remover using an oxygen-based bleaching agent is desired to further improve performance. The present invention relates to an oxygen-based bleach composition or an oxygen-based bleach-cleaner composition having improved bleaching performance and bleach-cleaning performance against difficult-to-remove stains such as mold stains, and a multi-drug article for an oxidizing composition. Is to provide.
本発明は、次の（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水から選択される成分を含む剤の組み合わせからなり、（Ａ）成分と（Ｃ）成分が別の剤に配合されている、酸化性組成物用多剤型物品に関する。
（Ａ）成分：下記一般式（Ａ１）で表される化合物及びその塩から選択される１以上の化合物
（Ｂ）成分：有機過酸前駆体及び有機過酸からなる群から選択される１以上の化合物
（Ｃ）成分：過酸化水素及び水中で過酸化水素を生成する過酸化物からなる群から選択される１以上の化合物
（Ｄ）成分：アルカリ金属の水酸化物、アルカリ金属の炭酸塩、アルカリ土類金属の水酸化物、アルカリ土類金属の炭酸塩、モノエタノールアミン、ジエタノールアミン及びトリエタノールアミンからなる群から選択される１以上のアルカリ剤
The present invention comprises a combination of agents comprising the following components (A), (B), (C), (D), and a component selected from water: (A) and (C) Relates to a multi-dose article for an oxidizable composition, in which is formulated in another agent.
Component (A): One or more compounds selected from the compound represented by the following general formula (A1) and salts thereof (B) Component: One or more selected from the group consisting of organic peracid precursors and organic peracids Compound (C) component: One or more compounds (D) selected from the group consisting of hydrogen peroxide and a peroxide that generates hydrogen peroxide in water: Alkali metal hydroxide, alkali metal carbonate One or more alkaline agents selected from the group consisting of alkaline earth metal hydroxides, alkaline earth metal carbonates, monoethanolamine, diethanolamine and triethanolamine
［式（Ａ１）中、Ｒ１〜Ｒ５は、それぞれ独立に、水素原子、水酸基、炭素数１以上、３以下のアルコキシ基、及び−（Ｒ６）ｘＣＯＯＲ７からなる群から選択される原子又は基を示す。Ｒ６は、２重結合を有していてもよい炭素数１以上、６以下の炭化水素基を示し、Ｒ７は、水素原子、又は炭素数１以上、３以下の炭化水素基を示し、ｘは、０又は１の数を示す。Ｒ１〜Ｒ５のうち少なくとも１つは、−（Ｒ６）ｘＣＯＯＲ７である。］ [In Formula (A1), R 1 to R 5 are each independently selected from the group consisting of a hydrogen atom, a hydroxyl group, an alkoxy group having 1 to 3 carbon atoms, and — (R 6 ) x COOR 7. Indicates an atom or group. R 6 represents a hydrocarbon group having 1 to 6 carbon atoms which may have a double bond, R 7 represents a hydrogen atom or a hydrocarbon group having 1 to 3 carbon atoms, x represents a number of 0 or 1. At least one of R 1 to R 5 is — (R 6 ) x COOR 7 . ]
本発明によれば、カビ汚れなどの除去困難な対象汚れに対して、優れた漂白性能を発現する、漂白剤組成物や漂白洗浄剤組成物として好適な酸化性組成物を調製できる酸化性組成物用多剤型物品が提供される。 INDUSTRIAL APPLICABILITY According to the present invention, an oxidizing composition capable of preparing an oxidizing composition suitable for a bleaching composition or a bleaching detergent composition that exhibits excellent bleaching performance against difficult-to-remove target dirt such as mold dirt. A multi-drug article for physical use is provided.
＜（Ａ）成分＞
（Ａ）成分は、前記一般式（Ａ１）で表される化合物及びその塩から選択される１以上の化合物である。
一般式（Ａ１）で表される化合物は、−（Ｒ６）ｘＣＯＯＲ７を少なくとも１つ有する。
Ｒ６は、２重結合を有していてもよい炭素数１以上、６以下の炭化水素基であり、アルキレン基、又はアルケニレン基が挙げられる。Ｒ６は炭素数２以上、４以下が好ましく、２以上、３以下がより好ましく、２が更に好ましい。
Ｒ７は、水素原子、又は炭素数１以上、３以下の炭化水素基を示し、水素原子又は炭素数１以上、２以下の炭化水素基が好ましく、水素原子又はメチル基がより好ましく、水素原子が更に好ましい。
式（Ａ１）中、−（Ｒ６）ｘＣＯＯＲ７以外のＲ１〜Ｒ５は、水素原子及び炭素数１以上、３以下のアルコキシ基から選ばれる原子又は基が好ましく、水素原子及びメトキシ基から選ばれる原子又は基がより好ましく、全て水素原子であることがより好ましい。Ｒ１〜Ｒ５の炭素数１以上、３以下のアルコキシ基は、炭素数１のメトキシ基が好ましい。
（Ａ）成分は、前記一般式（Ａ１）で表される化合物の塩として含有することができる。（Ａ）成分の塩は、アルカリ金属塩が好ましく、ナトリウム塩がより好ましい。
<(A) component>
The component (A) is one or more compounds selected from the compound represented by the general formula (A1) and a salt thereof.
The compound represented by the general formula (A1) has at least one of — (R 6 ) x COOR 7 .
R 6 is a hydrocarbon group having 1 to 6 carbon atoms which may have a double bond, and examples thereof include an alkylene group and an alkenylene group. R 6 preferably has 2 or more and 4 or less carbon atoms, more preferably 2 or more and 3 or less, and still more preferably 2.
R 7 represents a hydrogen atom or a hydrocarbon group having 1 to 3 carbon atoms, preferably a hydrogen atom or a hydrocarbon group having 1 to 2 carbon atoms, more preferably a hydrogen atom or a methyl group, and a hydrogen atom. Is more preferable.
In formula (A1), R 1 to R 5 other than — (R 6 ) x COOR 7 are preferably a hydrogen atom or an atom or group selected from an alkoxy group having 1 to 3 carbon atoms, and a hydrogen atom and a methoxy group Are more preferable, and it is more preferable that all are hydrogen atoms. The alkoxy group having 1 to 3 carbon atoms of R 1 to R 5 is preferably a methoxy group having 1 carbon atom.
The component (A) can be contained as a salt of the compound represented by the general formula (A1). The salt of the component (A) is preferably an alkali metal salt, more preferably a sodium salt.
（Ａ）成分の好ましい化合物を以下に示す。化合物１〜６は、後述の実施例で用いた化合物の番号と一致する。 (A) The preferable compound of a component is shown below. Compounds 1 to 6 correspond to the compound numbers used in Examples described later.
（Ａ）成分は、漂白性能向上の観点からは、Ｒ１〜Ｒ５のうち、好ましくは１つ以上、そして、好ましくは３つ以下、より好ましくは２以下が−（Ｒ６）ｘＣＯＯＲ７であり、更に好ましくは１つが−（Ｒ６）ｘＣＯＯＲ７である。
Ｒ１〜Ｒ５のうち、１つが−（Ｒ６）ｘＣＯＯＲ７である場合、−（Ｒ６）ｘＣＯＯＲ７は水酸基に対してパラ位又はオルト位であることが好ましく、パラ位であることがより好ましい。
From the viewpoint of improving the bleaching performance, the component (A) is preferably at least one of R 1 to R 5 , and preferably at most 3, and more preferably at most 2-(R 6 ) x COOR 7 And more preferably one is — (R 6 ) x COOR 7 .
When one of R 1 to R 5 is-(R 6 ) x COOR 7 ,-(R 6 ) x COOR 7 is preferably in the para position or ortho position with respect to the hydroxyl group, and is in the para position. It is more preferable.
（Ａ）成分は、漂白性能向上の観点からは、ｐ−クマル酸、ｐ−３−（４−ヒドロキシフェニル）プロピオン酸、シナピン酸、ｐ−ヒドロキシ安息香酸、サリチル酸、パラオキシ安息香酸メチル、及びそれらの塩から選ばれる１種又は２種以上が好ましい。
また、（Ａ）成分は、漂白性能向上の観点からは、ｐ−クマル酸、ｐ−３−（４−ヒドロキシフェニル）プロピオン酸、及びそれらの塩から選ばれる１種又は２種以上が好ましく、ｐ−クマル酸、又はその塩がより好ましく、ｐ−クマル酸の塩がより好ましい。
(A) Component is p-coumaric acid, p-3- (4-hydroxyphenyl) propionic acid, sinapinic acid, p-hydroxybenzoic acid, salicylic acid, methyl paraoxybenzoate, and those from the viewpoint of improving bleaching performance 1 type or 2 types or more chosen from these salts are preferable.
The component (A) is preferably one or more selected from p-coumaric acid, p-3- (4-hydroxyphenyl) propionic acid, and salts thereof from the viewpoint of improving the bleaching performance. p-coumaric acid or a salt thereof is more preferable, and a salt of p-coumaric acid is more preferable.
＜（Ｂ）成分＞
（Ｂ）成分は、有機過酸前駆体及び有機過酸からなる群から選択される１以上の化合物である。
<(B) component>
The component (B) is one or more compounds selected from the group consisting of organic peracid precursors and organic peracids.
漂白性能を高める観点と、組成物中での安定性が高い観点から、（Ｂ）成分としては、下記一般式（Ｂ１）で表される有機過酸前駆体である化合物が好ましい。 From the viewpoint of enhancing the bleaching performance and the viewpoint of high stability in the composition, the component (B) is preferably a compound that is an organic peracid precursor represented by the following general formula (B1).
［式中、Ｒ11bは炭素数５以上、１９以下のアルキル基又はアルケニル基、Ｚは、ＳＯ3Ｍ又はＣＯＯＭ、Ｍは陽イオンを示す。］ [Wherein, R 11b represents an alkyl group or alkenyl group having 5 to 19 carbon atoms, Z represents SO 3 M or COOM, and M represents a cation. ]
また、組成物中での安定性を更に高める観点から、一般式（Ｂ１）におけるＲ11bは、好ましくは炭素数８以上であり、更には９以上、更には１０以上、更には１１以上である。また、過酸化水素と有効に反応し、効率よく有機過酸を生成するために、一般式（Ｂ１）におけるＲ11bは、炭素数１９以下であり、好ましくは１５以下であり、更には１３以下、更には１１以下である。 Further, from the viewpoint of further improving the stability in the composition, R 11b in the general formula (B1) preferably has 8 or more carbon atoms, more preferably 9 or more, further 10 or more, and further 11 or more. . In addition, in order to efficiently react with hydrogen peroxide and efficiently generate an organic peracid, R 11b in the general formula (B1) has 19 or less carbon atoms, preferably 15 or less, and further 13 or less. And 11 or less.
組成物中での安定性を更に高め、また、過酸化水素と有効に反応し、効率よく有機過酸を生成するために、一般式（Ｂ１）におけるＲ11bは、炭素数１１であることがより好ま
しい。また、一般式（Ｂ１）におけるＲ11bは、アルキル基が好ましい。
R 11b in the general formula (B1) must have 11 carbon atoms in order to further enhance the stability in the composition, and to effectively react with hydrogen peroxide and efficiently generate an organic peracid. More preferred. In addition, R 11b in the general formula (B1) is preferably an alkyl group.
一般式（Ｂ１）におけるＭの陽イオンとしては、Ｎａ、Ｋ等のアルカリ金属イオン、アンモニウムイオン、炭素数３以上、１５以下、更に炭素数７以上、１５以下のアルキルアンモニウムイオン、モノエタノールアンモニウムイオン、ジエタノールアンモニウムイオン、トリエタノールアンモニウムイオン等が挙げられ、アルカリ金属イオンが好ましい。 Examples of the cation of M in the general formula (B1) include alkali metal ions such as Na and K, ammonium ions, alkyl ammonium ions having 3 to 15 carbon atoms, and further having 7 to 15 carbon atoms and monoethanol ammonium ions. , Diethanolammonium ion, triethanolammonium ion and the like, and alkali metal ions are preferable.
本発明の（Ｂ）成分としては、アルカノイル基の炭素数が６以上、２０以下のアルカノイルオキシベンゼンスルホン酸塩及びアルカノイル基の炭素数が６以上、２０以下のアルカノイルオキシベンゼンカルボン酸塩からなる群から選択される１以上の化合物が好ましく、アルカノイル基の炭素数が６以上、２０以下のアルカノイルオキシベンゼンスルホン酸塩がより好ましい。これらのアルカノイル基の炭素数は、１６以下であり、更には１４以下、更には１２以下が好ましい。 As the component (B) of the present invention, a group consisting of an alkanoyloxybenzenesulfonate having an alkanoyl group having 6 to 20 carbon atoms and an alkanoyloxybenzenecarboxylate having an alkanoyl group having 6 to 20 carbon atoms One or more compounds selected from are preferable, and alkanoyloxybenzene sulfonates having an alkanoyl group having 6 to 20 carbon atoms are more preferable. These alkanoyl groups have 16 or less carbon atoms, more preferably 14 or less, and even more preferably 12 or less.
＜（Ｃ）成分＞
（Ｃ）成分は、過酸化水素及び水中で過酸化水素を生成する過酸化物からなる群から選択される１以上の化合物である。
<(C) component>
Component (C) is one or more compounds selected from the group consisting of hydrogen peroxide and peroxides that generate hydrogen peroxide in water.
水中で過酸化水素を生成する過酸化物としては、無機過酸化物、過酸化水素付加物が挙げられ、好ましくは、過炭酸塩、トリポリリン酸塩・過酸化水素付加物、ピロリン酸塩・過酸化水素付加物、尿素・過酸化水素付加物、硫酸塩・過酸化水素付加物、過ホウ酸塩、過ケイ酸塩、過酸化塩であり、より好ましくは、過炭酸ナトリウム、トリポリリン酸ナトリウム・過酸化水素付加物、ピロリン酸ナトリウム・過酸化水素付加物、尿素・過酸化水素付加物、又は４Ｎａ2ＳＯ4・２Ｈ2Ｏ2、過ホウ酸ナトリウム一水和物、過ホウ酸ナトリウム四水化物、過ケイ酸ナトリウム、過酸化ナトリウム、過酸化カルシウム等である。 Examples of peroxides that generate hydrogen peroxide in water include inorganic peroxides and hydrogen peroxide adducts, preferably percarbonates, tripolyphosphate / hydrogen peroxide adducts, pyrophosphates / peroxides. Hydrogen oxide adduct, urea / hydrogen peroxide adduct, sulfate / hydrogen peroxide adduct, perborate, persilicate, peroxide, more preferably sodium percarbonate, sodium tripolyphosphate Hydrogen peroxide adduct, sodium pyrophosphate / hydrogen peroxide adduct, urea / hydrogen peroxide adduct, or 4Na 2 SO 4 .2H 2 O 2 , sodium perborate monohydrate, sodium perborate tetrahydrate Compounds, sodium persilicate, sodium peroxide, calcium peroxide and the like.
（Ｃ）成分は、過酸化水素、過炭酸ナトリウム及び過ホウ酸ナトリウムからなる群から選択される１以上の化合物が好ましく、過酸化水素がより好ましい。 The component (C) is preferably one or more compounds selected from the group consisting of hydrogen peroxide, sodium percarbonate and sodium perborate, more preferably hydrogen peroxide.
＜（Ｄ）成分＞
（Ｄ）成分は、アルカリ金属の水酸化物、アルカリ金属の炭酸塩、アルカリ土類金属の水酸化物、アルカリ土類金属の炭酸塩、モノエタノールアミン、ジエタノールアミン及びトリエタノールアミンからなる群から選択される１以上のアルカリ剤である。
<(D) component>
The component (D) is selected from the group consisting of alkali metal hydroxides, alkali metal carbonates, alkaline earth metal hydroxides, alkaline earth metal carbonates, monoethanolamine, diethanolamine and triethanolamine. One or more alkaline agents.
漂白性能を高める観点から、（Ｄ）成分は、アルカリ金属の水酸化物及びアルカリ金属の炭酸塩からなる群から選択される１以上のアルカリ剤が好ましく、アルカリ金属の水酸化物から選択される１以上のアルカリ剤が好ましい。（Ｄ）成分は、水酸化ナトリウム、水酸化カリウム、炭酸ナトリウム及び炭酸カリウムからなる群から選択される１以上のアルカリ剤がより好ましく、水酸化ナトリウム及び水酸化カリウムからなる群から選択される１以上のアルカリ剤が更に好ましい。 From the viewpoint of enhancing the bleaching performance, the component (D) is preferably one or more alkali agents selected from the group consisting of alkali metal hydroxides and alkali metal carbonates, and is selected from alkali metal hydroxides. One or more alkaline agents are preferred. The component (D) is more preferably one or more alkaline agents selected from the group consisting of sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate, and 1 selected from the group consisting of sodium hydroxide and potassium hydroxide. The above alkali agents are more preferable.
＜酸化性組成物＞
本発明の酸化性組成物用多剤型物品は、（Ａ）〜（Ｄ）成分を複数の剤に分配して組み合わせた物品であり、当該複数の剤が混合されて酸化性組成物（以下、本発明の酸化性組物という）が調製される。本発明の多剤型物品は、（Ａ）成分と（Ｃ）成分は別の剤に配合されているため、少なくとも２つの剤を含む。
<Oxidizing composition>
The multi-drug article for an oxidizing composition of the present invention is an article in which the components (A) to (D) are distributed and combined into a plurality of agents, and the plurality of agents are mixed to form an oxidizing composition (hereinafter referred to as “oxidizing composition”). , Referred to as the oxidizing composition of the present invention). The multi-drug type article of the present invention contains at least two agents because the component (A) and the component (C) are blended in different agents.
以下、本発明の酸化性組成物における各成分の含有量、ｐＨ、含有させることのできる成分等を示す。含有量やｐＨは、本発明の酸化性組成物使用時における各成分の含有量及びｐＨとして位置付けることができる。すなわち、特に記載のない場合は、酸化性組成物全体に対する含有割合、ｐＨを表している。本発明の酸化性組成物用多剤型物品は、下記の好ましい態様を１つ以上満たす酸化性組成物の調製用であることが好ましい。 Hereinafter, the content of each component in the oxidizing composition of the present invention, pH, components that can be contained, and the like are shown. Content and pH can be positioned as content and pH of each component at the time of use of the oxidizing composition of the present invention. That is, unless otherwise specified, the content ratio and pH with respect to the entire oxidizing composition are indicated. The multi-drug article for an oxidizing composition of the present invention is preferably for the preparation of an oxidizing composition that satisfies one or more of the following preferred embodiments.
本発明の酸化性組成物は、漂白性能を高める観点から、（Ａ）成分を、酸型化合物に換算した量で、０．００１質量％以上、更に０．０１質量％以上、更に０．１質量％以上、更に０．５質量％以上、更に０．７質量％以上、０．８質量％以上含有することが好ましく、そして、経済的な観点から、１０質量％以下、更に５質量％以下、更に２質量％以下含有することが好ましい。以下、（Ａ）成分の量は、特記しない限り、酸型化合物に換算した量をいう。 From the viewpoint of improving the bleaching performance, the oxidizing composition of the present invention is 0.001% by mass or more, further 0.01% by mass or more, and further 0.1% in terms of the amount of the component (A) converted to an acid type compound. It is preferably contained in an amount of not less than 0.5% by mass, more preferably not less than 0.5% by mass, further not less than 0.7% by mass, and not less than 0.8% by mass. Further, it is preferable to contain 2% by mass or less. Hereinafter, the amount of the component (A) means an amount converted to an acid type compound unless otherwise specified.
本発明の酸化性組成物は、漂白性能を高める観点から、（Ｂ）成分を、０．０１質量％以上、更に０．１質量％以上、更に１質量％以上、更に２質量％以上含有することが好ましく、そして、保存安定性の観点から３０質量％以下、更に２０質量％以下、更に１０質量％以下、更に５質量％以下、更に３質量％以下含有することが好ましい。 The oxidizing composition of the present invention contains the component (B) in an amount of 0.01% by mass or more, further 0.1% by mass or more, further 1% by mass or more, and further 2% by mass or more from the viewpoint of enhancing the bleaching performance. In view of storage stability, it is preferably 30% by mass or less, more preferably 20% by mass or less, further 10% by mass or less, further 5% by mass or less, and further preferably 3% by mass or less.
本発明の酸化性組成物は、漂白性能を高める観点から、（Ｃ）成分を、過酸化水素として、０．０１質量％以上、更に０．１質量％以上、更に０．５質量％以上、更に１質量％以上、更に１.４質量％以上含有することが好ましく、そして、保存安定性の観点から、５０質量％以下、更に３０質量％以下、更に２０質量％以下、更に１０質量％以下、更に５質量％以下、更に２質量％以下、更に１．６質量％以下含有することが好ましい。以下、（Ｃ）成分の量は、特記しない限り、過酸化水素としての量をいう。 From the viewpoint of enhancing the bleaching performance, the oxidizing composition of the present invention, as the component (C), is hydrogen peroxide, 0.01 mass% or more, further 0.1 mass% or more, further 0.5 mass% or more, Further, it is preferably contained in an amount of 1% by mass or more, more preferably 1.4% by mass or more, and from the viewpoint of storage stability, 50% by mass or less, further 30% by mass or less, further 20% by mass or less, and further 10% by mass or less. Further, it is preferable to contain 5% by mass or less, further 2% by mass or less, and further 1.6% by mass or less. Hereinafter, the amount of the component (C) refers to the amount as hydrogen peroxide unless otherwise specified.
（Ａ）成分の含有量に対する（Ｂ）成分の含有量の質量比［（Ｂ）／（Ａ）］は、漂白性能を高める観点から、０．１以上、更に０．２以上、更に０．５以上、更に１以上、更に１．５以上が好ましく、そして、５０以下、更に３０以下、更に２０以下、更に１５以下、更に１０以下、更に５以下、更に３以下が好ましい。 The mass ratio [(B) / (A)] of the content of the component (B) to the content of the component (A) is 0.1 or more, more preferably 0.2 or more, and further preferably 0.00 from the viewpoint of enhancing the bleaching performance. 5 or more, further 1 or more, and further 1.5 or more are preferable, and 50 or less, further 30 or less, further 20 or less, further 15 or less, further 10 or less, further 5 or less, and further 3 or less are preferable.
（Ａ）成分の含有量に対する（Ｃ）成分の含有量の質量比［（Ｃ）／（Ａ）］は、漂白性能を高める観点から、０．１以上、更に０．２以上、更に０．５以上、更に１以上、が好ましく、そして、５０以下、更に３０以下、更に２０以下、更に１５以下、更に１０以下、更に８以下が好ましい。 The mass ratio [(C) / (A)] of the content of the component (C) to the content of the component (A) is 0.1 or more, more preferably 0.2 or more, and further preferably 0.00 from the viewpoint of enhancing the bleaching performance. 5 or more, further 1 or more are preferable, and 50 or less, further 30 or less, further 20 or less, further 15 or less, further 10 or less, and further 8 or less are preferable.
（Ｂ）成分の含有量に対する（Ｃ）成分の含有量の質量比［（Ｃ）／（Ｂ）］は、漂白性能を高める観点から、０．０１以上、更に０．０５以上、更に０．１以上、更に０．３以上、更に０．５以上、更に１以上、更に１．２以上が好ましく、そして、５０以下、更に３０以下、更に２０以下、更に１０以下、更に５以下、更に３以下が好ましい。 The mass ratio [(C) / (B)] of the content of the component (C) to the content of the component (B) is 0.01 or more, more preferably 0.05 or more, and further preferably 0.00 from the viewpoint of enhancing the bleaching performance. 1 or more, further 0.3 or more, further 0.5 or more, further 1 or more, further 1.2 or more are preferable, and 50 or less, further 30 or less, further 20 or less, further 10 or less, further 5 or less, further 3 The following is preferred.
（Ｂ）成分の含有量と（Ｃ）成分の含有量の合計に対する（Ａ）成分の含有量の質量比、（Ａ）／［（Ｂ）＋（Ｃ）］は、漂白性能を高める観点から、０．０１以上、更に０．０５以上、更に０．１以上、更に０．１５以上、が好ましく、そして、２０以下、更に１０以下、更に５以下、更に３以下、更に１以下、更に０．５以下、更に０．２５以下が好ましい。 The mass ratio of the content of the component (A) to the total content of the component (B) and the content of the component (C), (A) / [(B) + (C)] is from the viewpoint of enhancing the bleaching performance. 0.01 or more, further 0.05 or more, further 0.1 or more, further 0.15 or more, and preferably 20 or less, further 10 or less, further 5 or less, further 3 or less, further 1 or less, further 0 .5 or less, more preferably 0.25 or less.
本発明の酸化性組成物において、（Ｄ）成分は、使用時のｐＨが、２０℃で１０以上、１２．５以下となる量を含有することが好ましい。
本発明の酸化性組成物は、漂白性能を高める観点から、（Ｄ）成分を、０．０１質量％以上、更に０．１質量％以上、更に１質量％以上、更に１．３質量％以上含有することが好ましく、そして、漂白性能を高める観点から、５０質量％以下、更に３０質量％以下、更に２０質量％以下、更に１０質量％以下、更に５質量％以下、更に２質量％以下含有することが好ましい。
In the oxidizing composition of the present invention, the component (D) preferably contains an amount such that the pH during use is 10 or more and 12.5 or less at 20 ° C.
From the viewpoint of enhancing the bleaching performance, the oxidizing composition of the present invention comprises the component (D) at 0.01% by mass or more, further 0.1% by mass or more, further 1% by mass or more, and further 1.3% by mass or more. It is preferably contained, and from the viewpoint of enhancing the bleaching performance, 50% by mass or less, further 30% by mass or less, further 20% by mass or less, further 10% by mass or less, further 5% by mass or less, and further 2% by mass or less It is preferable to do.
＜（Ｅ）成分＞
本発明の酸化性組成物は、（Ｅ）成分として、界面活性剤を含有することが好ましい。
<(E) component>
The oxidizing composition of the present invention preferably contains a surfactant as the component (E).
（Ｅ）成分としては、ノニオン界面活性剤、カチオン界面活性剤、両性界面活性剤及びアニオン界面活性剤からなる群から選択される１以上の界面活性剤が挙げられる。
（Ｅ）成分は、ノニオン界面活性剤、両性界面活性剤及びアニオン界面活性剤からなる群から選択される１以上の界面活性剤が好ましく、ノニオン界面活性剤、及び両性界面活性剤から選択される１以上の界面活性剤がより好ましく、ノニオン界面活性剤から選択される１以上の界面活性剤が更に好ましい。
The component (E) includes one or more surfactants selected from the group consisting of nonionic surfactants, cationic surfactants, amphoteric surfactants and anionic surfactants.
The component (E) is preferably one or more surfactants selected from the group consisting of nonionic surfactants, amphoteric surfactants and anionic surfactants, and is selected from nonionic surfactants and amphoteric surfactants. One or more surfactants are more preferred, and one or more surfactants selected from nonionic surfactants are even more preferred.
ノニオン界面活性剤としては、一般式（Ｅ１−１）で表される化合物及び一般式（Ｅ１−２）で表される化合物から選ばれる化合物が好ましく、一般式（Ｅ１−１）で表される化合物がより好ましい。
Ｒ11e−Ｘ−（ＡＯ）m−Ｙ （Ｅ１−１）
〔式中、Ｒ11eは、直鎖又は分岐鎖の炭素数６以上、２２以下のアルキル基又はアルケニル基及び直鎖又は分岐鎖の炭素数１以上、１８以下のアルキル基で置換されていてもよいアリール基からなる群から選択される基を示す。Ｘは−Ｏ−又は−ＣＯＯ−を示す。Ａは直鎖又は分岐鎖の炭素数２以上、３以下のアルキレン基を示し、ｍ個のＡは同一でも異なっていてもよい。ＹはＨ又は炭素数１以上、３以下のアルキル基を示す。ｍは、ＡＯの平均付加モル数であり、３以上、５０以下の数を示す。〕
Ｒ11e'−(ＯＲ12e')xＧy （Ｅ１−２）
〔式中、Ｒ11e'は炭素数８以上、１８以下の分岐鎖又は直鎖である１価の脂肪族炭化水素基、Ｒ12e'は炭素数２以上、４以下のアルキレン基、Ｇは還元糖に由来する残基、ｘは平均値で０以上、６以下の数、ｙは平均値で１以上、１０以下の数を示す。〕
As the nonionic surfactant, a compound selected from a compound represented by the general formula (E1-1) and a compound represented by the general formula (E1-2) is preferable, and the nonionic surfactant is represented by the general formula (E1-1). Compounds are more preferred.
R 11e -X- (AO) m -Y (E1-1)
[In the formula, R 11e may be substituted with a linear or branched alkyl group or alkenyl group having 6 to 22 carbon atoms and a linear or branched alkyl group having 1 to 18 carbon atoms. Indicates a group selected from the group consisting of good aryl groups. X represents —O— or —COO—. A represents a linear or branched alkylene group having 2 to 3 carbon atoms, and m A may be the same or different. Y represents H or an alkyl group having 1 to 3 carbon atoms. m is the average added mole number of AO and represents a number of 3 or more and 50 or less. ]
R 11e ′ − (OR 12e ′ ) x G y (E1-2)
[Wherein R 11e ′ is a branched or straight-chain monovalent aliphatic hydrocarbon group having 8 to 18 carbon atoms, R 12e ′ is an alkylene group having 2 to 4 carbon atoms, and G is a reduced group. Residues derived from sugar, x is an average value of 0 or more and 6 or less, and y is an average value of 1 or more and 10 or less. ]
一般式（Ｅ１−１）においてＡ基はエチレン基又はプロピレン基（好ましくはエチレン基）を示すことが好ましいが、これらはブロック型に重合してもよく、ランダム型に重合してもよい。Ｒ11eは、直鎖又は分岐鎖の炭素数６以上、１８以下のアルキル基であることが好ましく、Ｘは−Ｏ−が好ましく、ＹはＨであることが好ましい。ｍは、３以上、１５以下であることが好ましい。 In general formula (E1-1), the A group preferably represents an ethylene group or a propylene group (preferably an ethylene group), but these may be polymerized in a block type or a random type. R 11e is preferably a linear or branched alkyl group having 6 to 18 carbon atoms, X is preferably —O—, and Y is preferably H. m is preferably 3 or more and 15 or less.
一般式（Ｅ１−２）において、好ましいｘの値は０以上、２以下であり、より好ましくは０である。また、ｙの平均値は好ましくは１以上、５以下、より好ましくは１以上、１．５以下、より更に好ましくは１．１以上、１．４以下である。尚、ｙの測定値はプロトンＮＭＲ法によるものである。好ましい原料は、それらの入手容易性及びコストの点から、単糖類ではグルコース及びフルクトースであり、２糖類以上ではマルトース及びスクロースである。Ｒ11e'は、直鎖又は分岐鎖の総炭素数８以上、１６以下のアルキル基が好ましい。 In the general formula (E1-2), a preferable value of x is 0 or more and 2 or less, more preferably 0. The average value of y is preferably 1 or more and 5 or less, more preferably 1 or more and 1.5 or less, and still more preferably 1.1 or more and 1.4 or less. In addition, the measured value of y is based on the proton NMR method. Preferred raw materials are glucose and fructose for monosaccharides, and maltose and sucrose for disaccharides and higher in view of their availability and cost. R 11e ′ is preferably a linear or branched alkyl group having 8 to 16 carbon atoms in total.
カチオン界面活性剤としては、一般式（Ｅ２）で表される第４級アンモニウム塩が好ましく用いられる。 As the cationic surfactant, a quaternary ammonium salt represented by the general formula (E2) is preferably used.
〔式中、Ｒ12e、Ｒ13e、Ｒ14e、Ｒ15eは、少なくとも１つが直鎖又は分岐鎖の炭素数６以上、２０以下、好ましくは８以上、１８以下のアルキル基又はアルケニル基を示し、残りが炭素数１以上、３以下アルキル基又はヒドロキシアルキル基を示す。また、Ｌ-は有機又は無機の陰イオン基を示す。〕 [Wherein, R 12e , R 13e , R 14e , R 15e represents a linear or branched alkyl group or alkenyl group having 6 to 20 carbon atoms, preferably 8 to 18 carbon atoms, The remainder represents an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms. L - represents an organic or inorganic anionic group. ]
これら第４級アンモニウム塩の具体例としては、以下の化合物が挙げられる。 Specific examples of these quaternary ammonium salts include the following compounds.
〔式中、ｈは６以上、２０以下、好ましくは８以上、１８以下の数、ｇ及びｄは同一又は異なって、それぞれ独立に、６以上、２０以下、好ましくは８以上、１８以下の数を示し、Ｒ16eは炭素数１以上、３以下のアルキル基又はヒドロキシアルキル基を示し、Ｑ-は、有機又は無機の陰イオン基、好ましくは、Ｃｌ-、Ｂｒ-等のハロゲンイオン、ＣＨ3ＳＯ4 -、ＣＨ3ＣＨ2ＳＯ4 -等のアルキルサルフェートイオン、又はＣ11Ｈ23ＣＯＯ-、ＣＨ3ＣＯＯ-等の脂肪酸イオンを示す。〕 [Wherein, h is a number of 6 or more and 20 or less, preferably 8 or more and 18 or less, and g and d are the same or different and are each independently a number of 6 or more and 20 or less, preferably 8 or more and 18 or less. R 16e represents an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, Q − represents an organic or inorganic anion group, preferably a halogen ion such as Cl − or Br − , CH 3 An alkyl sulfate ion such as SO 4 − and CH 3 CH 2 SO 4 — or a fatty acid ion such as C 11 H 23 COO − and CH 3 COO − is shown. ]
これらの中でも、ジオクチルジメチルアンモニウム塩、ジデシルジメチルアンモニウム塩、ジドデシルジメチルアンモニウム塩、ドデシルトリメチルアンモニウム塩、テトラデシルトリメチルアンモニウム塩、テトラデシルジメチルエチルアンモニウム塩及びヘキサデシルトリメチルアンモニウム塩からなる群から選択されるカチオン界面活性剤が好ましい。 Among these, it is selected from the group consisting of dioctyldimethylammonium salt, didecyldimethylammonium salt, didodecyldimethylammonium salt, dodecyltrimethylammonium salt, tetradecyltrimethylammonium salt, tetradecyldimethylethylammonium salt and hexadecyltrimethylammonium salt. Cationic surfactants are preferred.
両性界面活性剤としては、カルボベタイン、スルホベタイン、ヒドロキシスルホベタインなどが挙げられる。 Examples of amphoteric surfactants include carbobetaine, sulfobetaine, and hydroxysulfobetaine.
アニオン界面活性剤としては、アルキル硫酸エステル塩、アルキルエーテル硫酸エステル塩、アルキルベンゼンスルホン酸又はその塩、アルカンスルホン酸又はその塩、飽和又は不飽和脂肪酸塩、アルキル又はアルケニルエーテルカルボン酸塩、α−スルホ脂肪酸塩、α−スルホ脂肪酸エステルなどが挙げられる。これらの中でもアルキルベンゼンスルホン酸又はその塩が好ましい。 Examples of the anionic surfactant include alkyl sulfate ester salt, alkyl ether sulfate ester salt, alkylbenzene sulfonic acid or its salt, alkane sulfonic acid or its salt, saturated or unsaturated fatty acid salt, alkyl or alkenyl ether carboxylate, α-sulfo Examples include fatty acid salts and α-sulfo fatty acid esters. Among these, alkylbenzenesulfonic acid or a salt thereof is preferable.
（Ｅ）成分としては、（Ｂ）成分の保存安定性の観点から、ノニオン界面活性剤が好ましい。また、（Ｅ）成分中、ノニオン界面活性剤の割合が５０質量％以上、更に６０質量％以上、更に７０質量％以上、更に８０質量％以上、そして、９５質量％以下、更に９０質量％以下、更に８５質量％以下であることが好ましい。 As the component (E), a nonionic surfactant is preferable from the viewpoint of the storage stability of the component (B). Further, in the component (E), the proportion of the nonionic surfactant is 50% by mass or more, further 60% by mass or more, further 70% by mass or more, further 80% by mass or more, and 95% by mass or less, further 90% by mass or less. Furthermore, it is preferable that it is 85 mass% or less.
本発明の酸化性組成物は、漂白性能及び保存安定性を高める観点から、（Ｅ）成分を、０．１質量％以上、更に１質量％以上、更に４質量％以上、そして、液の粘度を低くして取り扱いを良好にするために、５０質量％以下、更に３０質量％以下、更に１５質量％以下含有することが好ましい。 In the oxidizing composition of the present invention, from the viewpoint of enhancing bleaching performance and storage stability, the component (E) is 0.1% by mass or more, further 1% by mass or more, further 4% by mass or more, and the viscosity of the liquid. In order to improve the handling by reducing the content, it is preferable to contain 50% by mass or less, further 30% by mass or less, and further 15% by mass or less.
＜（Ｆ）成分＞
本発明の酸化性組成物は、（Ｆ）成分として、キレート剤を含有することが好ましい。
<(F) component>
The oxidizing composition of the present invention preferably contains a chelating agent as the component (F).
（Ｆ）成分は、カルシウムキレート定数（ｐＫＣａ）が４以上、更に４．５以上、更に５以上のキレート剤であることが、組成物の保存安定性の観点から好ましい。ここでｐＫＣａとは、カルシウムイオン電極を用い、キレート剤０．１質量％溶液、ｐＨ１０、２５℃、０．１Ｍ ＮＨ4Ｃｌ−ＮＨ4ＯＨ緩衝液を用いて測定した値である。 The component (F) is preferably a chelating agent having a calcium chelate constant (pKCa) of 4 or more, further 4.5 or more, and further 5 or more from the viewpoint of the storage stability of the composition. Here, pKCa is a value measured using a calcium ion electrode and using a 0.1 mass% chelating agent solution, pH 10, 25 ° C., and 0.1 M NH 4 Cl—NH 4 OH buffer.
本発明の（Ｆ）成分として用いられるキレート剤の具体例としては、エチレンジアミン４酢酸、ニトリロトリ酢酸、ヒドロキシエチルイミノジ酢酸等のアミノ酸系キレート剤、１−ヒドロキシエチリデン−１，１−ジホスホン酸、エタンヒドロキシ−１，１，２−トリホスホン酸、エタン−１，２−ジカルボキシ−１，２−ジホスホン酸、メタンヒドロキシホスホン酸等のホスホン酸系キレート剤、アクリル酸／マレイン酸コポリマー等のカルボン酸系ポリマー、トリポリリン酸等のポリリン酸系キレート剤を挙げることができる。これらの中でも、ホスホン酸系キレート剤及びカルボン酸系キレート剤からなる群から選択される１以上のキレート剤が好ましい。 Specific examples of the chelating agent used as the component (F) of the present invention include amino acid chelating agents such as ethylenediaminetetraacetic acid, nitrilotriacetic acid, hydroxyethyliminodiacetic acid, 1-hydroxyethylidene-1,1-diphosphonic acid, and ethane. Phosphonic acid chelating agents such as hydroxy-1,1,2-triphosphonic acid, ethane-1,2-dicarboxy-1,2-diphosphonic acid and methanehydroxyphosphonic acid, and carboxylic acid systems such as acrylic acid / maleic acid copolymer Polyphosphoric acid-type chelating agents, such as a polymer and tripolyphosphoric acid, can be mentioned. Among these, one or more chelating agents selected from the group consisting of phosphonic acid chelating agents and carboxylic acid chelating agents are preferred.
本発明の酸化性組成物は、組成物の安定性の観点から、（Ｆ）成分を、好ましくは０．０１質量％以上、更には０．１質量％以上、更には０．２質量％以上、含有する。また、本発明の酸化性組成物は、混合後のｐＨ値をアルカリ性とするために、（Ｆ）成分を、好ましくは３０質量％以下、更には２０質量％以下、更には１０質量％以下、更には５質量％以下、更には３質量％以下、更には１質量％以下、更には０．５質量％以下含有する。 In the oxidizing composition of the present invention, the component (F) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and further 0.2% by mass or more, from the viewpoint of the stability of the composition. ,contains. Further, the oxidizing composition of the present invention is preferably 30% by mass or less, more preferably 20% by mass or less, and even more preferably 10% by mass or less in order to make the pH value after mixing alkaline. Further, it is contained in an amount of 5% by mass or less, further 3% by mass or less, further 1% by mass or less, and further 0.5% by mass or less.
＜（Ｇ）成分＞
（Ｇ）成分として、水を含有することが好ましい。水は、組成物の残部の量（組成物全体を１００質量％とする量）で用いられるのが好ましい。水の含有量は、５０質量％以上であることが好ましく、更に６０質量％以上、更に７０質量％以上、更に８０質量％以上、更に９０質量％以上であることが好ましい。
<(G) component>
(G) It is preferable to contain water as a component. Water is preferably used in an amount of the remainder of the composition (an amount that makes the entire composition 100% by mass). The water content is preferably 50% by mass or more, more preferably 60% by mass or more, further 70% by mass or more, further 80% by mass or more, and further preferably 90% by mass or more.
＜その他の成分＞
本発明の酸化性組成物は、その他の成分として、香料、ｐＨ調整剤、可溶化剤、浸透剤、懸濁化剤、研磨剤、顔料等の任意成分を含有すること出来る。
<Other ingredients>
The oxidizing composition of the present invention can contain optional components such as a fragrance, a pH adjuster, a solubilizer, a penetrating agent, a suspending agent, an abrasive, and a pigment as other components.
本発明の酸化性組成物は、風呂・トイレ・台所等の硬質表面の漂白、カビ取り、衣類の漂白、汚れ・匂い原因物質の分解、除菌、パルプの漂白、など、ある対象物に対して酸化作用が有用な効果をもたらす様々な用途に用いることができる。なかでも、本発明の酸化性組成物は、漂白用又は漂白洗浄用であることが好ましい。更に、硬質表面の漂白用又は漂白洗浄用であることが好ましい。 The oxidizing composition of the present invention is suitable for certain objects such as bleaching hard surfaces such as baths, toilets and kitchens, removing mold, bleaching clothes, decomposing dirt and odor-causing substances, disinfecting, and bleaching pulp. Thus, it can be used for various applications in which the oxidizing action has a useful effect. Especially, it is preferable that the oxidizing composition of the present invention is for bleaching or bleaching washing. Furthermore, it is preferable for bleaching or bleaching of hard surfaces.
本発明の酸化性組成物は、硬質表面用の漂白剤又は硬質表面用の漂白洗浄剤として用いることが好ましい。また、衣料用洗浄剤として用いることも出来、消臭剤、除菌剤、殺菌剤として使用することも好ましい。カビ取り剤として用いることが好ましく、浴室用のカビ取り剤として用いることも好ましい。カビが発生する硬質表面は一般に耐酸化性が高いこと、及び本発明の酸化性組成物が従来技術では除去困難であったカビ汚れに対して顕著な漂白効果を示すことから、本発明の酸化性組成物は、カビ取り剤として用いることがより好ましい。 The oxidizing composition of the present invention is preferably used as a hard surface bleach or a hard surface bleach cleaner. Moreover, it can also be used as a washing | cleaning agent for clothes, and it is also preferable to use it as a deodorizer, a disinfectant, and a disinfectant. It is preferable to use it as a mold removing agent, and it is also preferable to use it as a mold removing agent for bathrooms. The hard surface on which mold is generated generally has high oxidation resistance, and the oxidizing composition of the present invention exhibits a remarkable bleaching effect against mold stains that were difficult to remove by the prior art. The composition is more preferably used as a mold removing agent.
本発明の酸化性組成物は、水を含有する液体形態である。本発明の酸化性組成物は、２０℃のｐＨが９以上、更に１０以上、更１１以上、そして、１３以下、更に１２．８以下、更に１２．５以下であることが好ましい。 The oxidizing composition of the present invention is in a liquid form containing water. The oxidizing composition of the present invention preferably has a pH at 20 ° C. of 9 or more, further 10 or more, 11 or more, 13 or less, further 12.8 or less, and further 12.5 or less.
本発明により、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水を含有する液体漂白剤組成物又は液体漂白洗浄剤組成物が提供される。
また、本発明により、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水を含有する、硬質表面用液体漂白剤組成物又は硬質表面用液体漂白洗浄剤組成物が提供される。
また、本発明により、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水を含有する、硬質表面用カビ取り剤組成物、更に浴室用カビ取り剤組成物が提供される。
According to the present invention, a liquid bleaching composition or a liquid bleaching detergent composition containing (A) component, (B) component, (C) component, (D) component, and water is provided.
Moreover, according to this invention, the liquid bleaching composition for hard surfaces or the liquid bleaching detergent composition for hard surfaces containing (A) component, (B) component, (C) component, (D) component, and water. Is provided.
Further, according to the present invention, there is provided a mold removing agent composition for hard surface, further comprising a mold removing agent composition for bathroom, comprising (A) component, (B) component, (C) component, (D) component, and water. Provided.
一例として、本発明の酸化性組成物が衣料用液体漂白洗浄剤組成物である場合の好ましい含有量を以下に示す。
衣料用液体漂白洗浄剤組成物中の（Ａ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に０．１５質量％以上、そして、１０質量％以下、更に５質量％以下、更に３質量％以下、更に１質量％以下、更に０．５質量％以下が好ましい。また、衣料用液体漂白洗浄剤組成物中の（Ｂ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に１質量％以上、そして、３０質量％以下、更に１０質量％以下、更に５質量％以下、更に３質量％以下が好ましい。また、衣料用液体漂白洗浄剤組成物中の（Ｃ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に１質量％以上、更に１．４質量％以上、そして、５０質量％以下、更に３０質量％以下、更に１０質量％以下、更に５質量％以下、更に２質量％以下が好ましい。また、衣料用液体漂白洗浄剤組成物中の（Ｄ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に１質量％以上、そして、５０質量％以下、更に３０質量％以下、更に１０質量％以下、更に５質量％以下、更に２質量％以下が好ましい。また、（Ｅ）成分を用いる場合、衣料用液体漂白洗浄剤組成物中の（Ｅ）成分の含有量は、０．１質量％以上、更に１質量％以上、更に４質量％以上、そして、５０質量％以下、更に３０質量％以下、更に１５質量％以下が好ましい。また、（Ｆ）成分を用いる場合、衣料用液体漂白洗浄剤組成物中の（Ｆ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に０．１５質量％以上、そして、３０質量％以下、更に２０質量％以下、更に１０質量％以下、更に５質量％以下、更に１質量％以下、更に０．５質量％以下が好ましい。これらの含有量は、本発明の酸化性組成物が、衣料用液体漂白剤組成物である場合にも同様に適用できる。
As an example, the preferable content in the case where the oxidizing composition of the present invention is a liquid bleach detergent composition for clothing is shown below.
The content of the component (A) in the liquid bleach detergent composition for clothing is 0.01% by weight or more, further 0.1% by weight or more, further 0.15% by weight or more, and 10% by weight or less. 5 mass% or less, Furthermore 3 mass% or less, Furthermore 1 mass% or less, Furthermore 0.5 mass% or less is preferable. In addition, the content of the component (B) in the liquid bleach detergent composition for clothing is 0.01% by mass or more, further 0.1% by mass or more, further 1% by mass or more, and 30% by mass or less. 10 mass% or less, Furthermore 5 mass% or less, Furthermore 3 mass% or less are preferable. In addition, the content of the component (C) in the liquid bleach detergent composition for clothing is 0.01% by mass or more, further 0.1% by mass or more, further 1% by mass or more, further 1.4% by mass or more, And 50 mass% or less, Furthermore, 30 mass% or less, Furthermore, 10 mass% or less, Furthermore, 5 mass% or less, Furthermore, 2 mass% or less is preferable. The content of the component (D) in the liquid bleach detergent composition for clothing is 0.01% by mass or more, further 0.1% by mass or more, further 1% by mass or more, and 50% by mass or less. 30% by mass or less, more preferably 10% by mass or less, further 5% by mass or less, and further preferably 2% by mass or less. In addition, when the component (E) is used, the content of the component (E) in the liquid bleach detergent composition for clothing is 0.1% by mass or more, further 1% by mass or more, further 4% by mass or more, and 50 mass% or less, Furthermore, 30 mass% or less, Furthermore, 15 mass% or less is preferable. When the component (F) is used, the content of the component (F) in the liquid bleach detergent composition for clothing is 0.01% by mass or more, further 0.1% by mass or more, and further 0.15% by mass. In addition, 30% by mass or less, further 20% by mass or less, further 10% by mass or less, further 5% by mass or less, further 1% by mass or less, and further 0.5% by mass or less are preferable. These contents can be similarly applied when the oxidizing composition of the present invention is a liquid bleach composition for clothing.
一例として、本発明の酸化性組成物が、硬質表面用漂白洗浄剤組成物である場合の好ましい含有量を以下に示す。
硬質表面用漂白洗浄剤組成物中の（Ａ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に０．１５質量％以上、そして、２０質量％以下、更に１０質量％以下、更に５質量％以下、更に３質量％以下、更に１質量％以下、更に０．９質量％以下が好ましい。また、硬質表面用漂白洗浄剤組成物中の（Ｂ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に１質量％以上、更に１．５質量％以上、そして、５０質量％以下、更に３０質量％以下、更に１０質量％以下、更に５質量％以下、更に３質量％以下が好ましい。また、硬質表面用漂白洗浄剤組成物中の（Ｃ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に１質量％以上、更に１．４質量％以上、そして、５０質量％以下、更に３０質量％以下、更に１０質量％以下、更に５質量％以下、更に２質量％以下、更に１．５質量％以下が好ましい。また、硬質表面用漂白洗浄剤組成物中の（Ｄ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に１質量％以上、そして、５０質量％以下、更に３０質量％以下、更に１０質量％以下、更に５質量％以下、更に２質量％以下が好ましい。また、（Ｅ）成分を用いる場合、硬質表面用漂白洗浄剤組成物中の（Ｅ）成分の含有量は、０．１質量％以上、更に１質量％以上、更に４質量％以上、そして、５０質量％以下、更に３０質量％以下、更に１５質量％以下が好ましい。また、（Ｆ）成分を用いる場合、硬質表面用漂白洗浄剤組成物中の（Ｆ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に０．１５質量％以上、そして、３０質量％以下、更に２０質量％以下、更に１０質量％以下、更に５質量％以下、更に１質量％以下、更に０．５質量％以下が好ましい。これらの含有量は、本発明の酸化性組成物が、硬質表面用漂白剤組成物、カビ取り剤組成物又は浴室用カビ取り剤組成物である場合にも同様に適用できる。
As an example, the preferable content when the oxidizing composition of the present invention is a bleaching detergent composition for hard surfaces is shown below.
The content of the component (A) in the bleaching detergent composition for hard surface is 0.01% by mass or more, further 0.1% by mass or more, further 0.15% by mass or more, and 20% by mass or less. It is preferably 10% by mass or less, more preferably 5% by mass or less, further 3% by mass or less, further 1% by mass or less, and further preferably 0.9% by mass or less. In addition, the content of the component (B) in the hard surface bleach detergent composition is 0.01% by mass or more, further 0.1% by mass or more, further 1% by mass or more, further 1.5% by mass or more, And 50 mass% or less, Furthermore, 30 mass% or less, Furthermore, 10 mass% or less, Furthermore, 5 mass% or less, Furthermore, 3 mass% or less is preferable. The content of the component (C) in the hard surface bleaching detergent composition is 0.01% by mass or more, further 0.1% by mass or more, further 1% by mass or more, and further 1.4% by mass or more. And 50 mass% or less, Furthermore, 30 mass% or less, Furthermore, 10 mass% or less, Furthermore, 5 mass% or less, Furthermore, 2 mass% or less, Furthermore, 1.5 mass% or less is preferable. The content of the component (D) in the hard surface bleach detergent composition is 0.01% by mass or more, further 0.1% by mass or more, further 1% by mass or more, and 50% by mass or less, It is preferably 30% by mass or less, more preferably 10% by mass or less, further 5% by mass or less, and further preferably 2% by mass or less. Further, when the component (E) is used, the content of the component (E) in the bleaching detergent composition for hard surfaces is 0.1% by mass or more, further 1% by mass or more, further 4% by mass or more, and 50 mass% or less, Furthermore, 30 mass% or less, Furthermore, 15 mass% or less is preferable. Further, when the component (F) is used, the content of the component (F) in the bleaching detergent composition for hard surfaces is 0.01% by mass or more, further 0.1% by mass or more, and further 0.15% by mass. In addition, 30% by mass or less, further 20% by mass or less, further 10% by mass or less, further 5% by mass or less, further 1% by mass or less, and further 0.5% by mass or less are preferable. These contents can be similarly applied when the oxidizing composition of the present invention is a hard surface bleaching composition, a mold removing composition, or a bathroom mold removing composition.
本発明は、有機過酸前駆体及び有機過酸からなる群から選択される１以上の化合物〔（Ｂ）成分〕と、過酸化水素及び水中で過酸化水素を生成する過酸化物からなる群から選択される１以上の化合物〔（Ｃ）成分〕とアルカリ剤〔（Ｄ）成分〕とを用いて得た酸化性組成物の酸化力が、前記一般式（Ａ１）で表される化合物から選択される１以上の化合物〔（Ａ）成分〕により、飛躍的に向上すること、すなわち、（Ｂ）成分と（Ｃ）成分の併用系において（Ａ）成分の効果が著しいことを見いだしたものである。本発明により、有機過酸前駆体及び有機過酸からなる群から選択される１以上の化合物〔（Ｂ）成分〕と、過酸化水素及び水中で過酸化水素を生成する過酸化物からなる群から選択される１以上の化合物〔（Ｃ）成分〕とアルカリ剤〔（Ｄ）成分〕とを用いて得た酸化性組成物に、前記一般式（Ａ１）で表される化合物から選択される１以上の化合物〔（Ａ）成分〕を適用して前記酸化性組成物の酸化力を向上させる、酸化性組成物の酸化力向上方法が提供される。 The present invention comprises one or more compounds selected from the group consisting of an organic peracid precursor and an organic peracid [component (B)], a group consisting of hydrogen peroxide and a peroxide that generates hydrogen peroxide in water. From the compound represented by the general formula (A1), the oxidizing power of the oxidizing composition obtained by using one or more compounds [component (C)] and an alkali agent (component (D)) selected from One or more selected compounds [component (A)] have been found to be dramatically improved, that is, the effect of component (A) is remarkable in the combined system of component (B) and component (C). It is. According to the present invention, one or more compounds selected from the group consisting of an organic peracid precursor and an organic peracid [component (B)], a group consisting of hydrogen peroxide and a peroxide that generates hydrogen peroxide in water An oxidizing composition obtained by using one or more compounds selected from (component (C)) and an alkali agent (component (D)) is selected from the compounds represented by formula (A1). There is provided a method for improving the oxidizing power of an oxidizing composition, wherein one or more compounds [component (A)] are applied to improve the oxidizing power of the oxidizing composition.
一般に、色素（色素化合物）に対して、過酸化水素〔（Ｃ）成分〕は酸化剤として作用するが、過酸化水素と有機過酸前駆体〔（Ｂ）成分〕とを併用することで、より酸化力の高い有機過酸が生じるため、漂白分野では、しばしば過酸化水素と有機過酸前駆体とを併用することが行われる。そのため、有機過酸前駆体は漂白活性化剤としても知られていたが、その効果は公知技術の範疇に留まっており、更に抜本的に漂白力を向上させる技術が望まれていた。本発明では、（Ｂ）成分と（Ｃ）成分とを併用した系において、（Ａ）成分を存在させることで、漂白力を大幅に向上させることが可能となった。これは、（Ａ）成分が過酸化水素と反応して（Ａ）成分の活性種が生成し、これが色素化合物に作用することで、色素化合物が有機過酸の酸化力を受けやすい状態になるためであると推察される。本発明によれば、特定構造の（Ａ）成分を選定して用いることにより、従来技術では漂白することが困難であった対象物の漂白が可能となり、更には酸化剤の各種対象物に有用な効果を示すことが可能となる。 In general, hydrogen peroxide [(C) component] acts as an oxidizing agent for the dye (dye compound), but by using hydrogen peroxide and an organic peracid precursor [(B) component] together, In the bleaching field, hydrogen peroxide and an organic peracid precursor are often used in combination because an organic peracid having a higher oxidizing power is generated. For this reason, organic peracid precursors have been known as bleach activators, but their effects remain within the scope of known techniques, and a technique that drastically improves bleaching power has been desired. In the present invention, in the system in which the component (B) and the component (C) are used in combination, the bleaching power can be greatly improved by the presence of the component (A). This is because the component (A) reacts with hydrogen peroxide to generate the active species of the component (A), which acts on the dye compound, so that the dye compound is easily subjected to the oxidizing power of organic peracid. This is presumed to be due to this. According to the present invention, by selecting and using the component (A) having a specific structure, it is possible to bleach an object that has been difficult to bleach with the prior art, and further useful for various objects of oxidizing agents. It becomes possible to show an advantageous effect.
＜酸化性組成物用多剤型物品＞
本発明の酸化性組成物用多剤型物品は、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水から選択される成分を含む剤の組み合わせからなり、（Ａ）成分と（Ｃ）成分が別の剤に配合されている。剤の数は２つ以上であり、好ましくは２つである。剤は、液体組成物、粉末組成物、ゲル状組成物など、いずれの形態であってもよい。形態が液体であることが好ましい。また、剤は、これらの組成物とその容器又は包装部材との結合物であってもよい。
<Multi-drug article for oxidizing composition>
The multi-dose article for an oxidizing composition of the present invention comprises a combination of agents comprising a component selected from (A) component, (B) component, (C) component, (D) component, and water, ( A component and (C) component are mix | blended with another agent. The number of agents is two or more, preferably two. The agent may be in any form such as a liquid composition, a powder composition, or a gel composition. The form is preferably a liquid. The agent may be a combination of these compositions and their container or packaging member.
本発明の酸化性組成物用多剤型物品は、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分を使用直前に混合して本発明の組成物を調製するのに好適である。（Ｃ）成分の安定性の観点で、（Ａ）成分と（Ｃ）成分とを分離した状態で保持しておき、使用直前に（Ａ）成分、（Ｂ）成分、（Ｃ）成分を混合することが好ましい。このような使用形態を考慮した場合、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水から選択される成分を含む剤の組み合わせからなり、（Ａ）成分と（Ｃ）成分が別の剤に配合されている、本発明の酸化性組成物用多剤型物品は好適である。本発明の酸化性組成物用多剤型物品は、複数の剤を混合して得られる酸化性組成物が、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分を、前記本発明の酸化性組物における含有量の範囲で含有することが好ましい。 The multi-drug article for an oxidizing composition of the present invention is prepared by mixing the component (A), the component (B), the component (C) and the component (D) immediately before use to prepare the composition of the present invention. Is preferred. From the viewpoint of component (C) stability, keep component (A) and component (C) separated, and mix component (A), component (B), and component (C) immediately before use. It is preferable to do. In consideration of such usage, it comprises a combination of an agent containing a component selected from (A), (B), (C), (D), and water, and (A) The multi-drug type article for an oxidizing composition of the present invention in which the component (C) is blended with another agent is suitable. In the multi-drug article for an oxidizing composition of the present invention, the oxidizing composition obtained by mixing a plurality of agents comprises (A) component, (B) component, (C) component, (D) component, It is preferable to contain in the range of content in the oxidizing composition of the present invention.
本発明の酸化性組成物用多剤型物品は、（Ａ）成分を含有する剤と、これとは異なる（Ｃ）成分を含有する剤とを含む。
（Ａ）成分を含有する剤は、水を含有する液体組成物であることが好ましく、その場合、当該組成物のｐＨは、２０℃で、１１以上、更に１２以上、更に１３以上、そして、１３．８以下、更に１３．６以下であることが好ましい。
また、（Ｄ）成分を含有する剤は、水を含有する液体組成物であることが好ましく、その場合、当該組成物のｐＨは、２０℃で、１以上、更に２以上、更２．５以上、そして、５以下、更に４以下、更に３．５以下であることが好ましい。
The multi-drug article for an oxidizing composition of the present invention includes an agent containing the component (A) and an agent containing the component (C) different from the agent.
The agent containing the component (A) is preferably a liquid composition containing water. In that case, the pH of the composition is 20 ° C., 11 or more, 12 or more, 13 or more, and It is preferably 13.8 or less, more preferably 13.6 or less.
The agent containing the component (D) is preferably a liquid composition containing water. In that case, the pH of the composition is 1 ° C. or more, 2 or more, and 2.5 or more at 20 ° C. It is preferable that it is 5 or less, 4 or less, and 3.5 or less.
本発明の酸化性組成物用多剤型物品として、（Ａ）成分、（Ｄ）成分、及び水を含有する第１の液体組成物からなる第１の剤と、（Ｂ）成分、（Ｃ）成分、及び水を含有する第２の液体組成物からなる第２の剤との組み合わせを含む酸化性組成物用多剤型物品であって、前記第１の剤と第２の剤とを分離した状態で保持し、第１の剤と第２の剤が混合されて、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水を含有する酸化性組成物が調製される、酸化性組成物用多剤型物品が挙げられる。 As the multi-drug article for an oxidizing composition of the present invention, the first agent comprising the first liquid composition containing the component (A), the component (D), and water, the component (B), (C ) A multi-drug article for an oxidizing composition comprising a combination of a component and a second agent comprising a second liquid composition containing water, wherein the first agent and the second agent are Oxidizing composition which is held in a separated state, and the first agent and the second agent are mixed to contain (A) component, (B) component, (C) component, (D) component, and water Are prepared as multi-dose articles for oxidizing compositions.
本発明の酸化性組成物用多剤型物品として、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水から選択される成分を含む剤の組み合わせからなり、（Ａ）成分と（Ｃ）成分が別の剤に配合されている、漂白剤組成物用多剤型物品が挙げられる。
また、本発明の酸化性組成物用多剤型物品として、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水から選択される成分を含む剤の組み合わせからなり、（Ａ）成分と（Ｃ）成分が別の剤に配合されている、漂白洗浄剤組成物用多剤型物品が挙げられる。
なお、多剤型物品は、１つ１つの剤が独立した物品となっている形態（例えばキットなど）や１つ１つの剤を１つの物品にまとめた形態（例えば２剤型スプレー式物品など）など、種々の形態であってよい。
これら酸化性組成物用多剤型物品は、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水を混合して本発明の酸化性組成物、更に本発明の漂白剤組成物、本発明の漂白洗浄剤組成物を調製するために好適である。
The multi-dose article for an oxidizing composition of the present invention comprises a combination of agents including a component selected from (A) component, (B) component, (C) component, (D) component, and water, ( A multi-component article for a bleaching composition in which the component (A) and the component (C) are blended in separate agents.
In addition, the multi-dose article for the oxidizing composition of the present invention comprises a combination of agents including (A) component, (B) component, (C) component, (D) component, and a component selected from water. (A) component and (C) component are mix | blended with another agent, The multi-drug type article for bleaching detergent compositions is mentioned.
In addition, the multi-drug type article is a form in which each agent is an independent article (for example, a kit) or a form in which each agent is combined into a single article (for example, a two-part spray type article) ) And the like.
These multi-drug-type articles for the oxidizing composition are prepared by mixing the component (A), the component (B), the component (C), the component (D), and water, and the oxidizing composition of the present invention. It is suitable for preparing a bleaching composition, the bleaching detergent composition of the present invention.
本発明の酸化性組成物用多剤型物品、更に漂白剤組成物用多剤型物品又は漂白洗浄剤組成物用多剤型物品では、少なくとも（Ａ）成分と（Ｃ）成分を分離した状態で保持し、使用時に（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水を混合して用いることが好ましい。また、本発明の漂白剤組成物用多剤型物品又は漂白洗浄剤組成物用多剤型物品では、（Ａ）成分及び（Ｄ）成分を含有する剤と、（Ｂ）成分及び（Ｃ）成分を含有する剤とを含むことが好ましい。 In the multi-drug article for the oxidizing composition of the present invention, the multi-drug type article for the bleaching composition or the multi-drug type article for the bleaching detergent composition, at least the component (A) and the component (C) are separated. The component (A), the component (B), the component (C), the component (D), and water are preferably mixed and used at the time of use. Further, in the multi-drug article for a bleaching composition or the multi-drug type article for a bleaching detergent composition of the present invention, an agent containing the component (A) and the component (D), the component (B) and the component (C) It is preferable to contain the agent containing a component.
また、本発明の酸化性組成物用多剤型物品、更に漂白剤組成物用多剤型物品又は漂白洗浄剤組成物用多剤型物品では、内容物の安定性を高めるために、（Ａ）成分及び（Ｄ）成分を含有する剤と、（Ｂ）成分及び（Ｃ）成分を含有する剤との２剤に分けて保持し、使用時に混合して用いることがより好ましい。 In order to increase the stability of the contents of the multi-drug article for the oxidizing composition of the present invention, and further for the multi-drug article for the bleach composition or the multi-drug article for the bleach cleaning composition, (A It is more preferable to use two components, ie, an agent containing the component (A) and the component (D), and an agent containing the component (B) and the component (C).
本発明の漂白剤組成物用多剤型物品の一例として、（Ａ）成分、（Ｄ）成分、及び水を含有する第１の液体組成物からなる第１の剤と、（Ｂ）成分、（Ｃ）成分、及び水を含有する第２の液体組成物からなる第２の剤との組み合わせを含む漂白剤組成物用多剤型物品であって、前記第１の剤と第２の剤とを分離した状態で保持し、第１の剤と第２の剤が混合されて、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分及び水を含有する漂白剤組成物が調製される、漂白剤組成物用多剤型物品（以下、漂白剤組成物用多剤型物品１という）が挙げられる。 As an example of a multi-drug article for a bleaching composition of the present invention, a first agent comprising a first liquid composition containing (A) component, (D) component, and water, and (B) component, (C) A multi-drug article for a bleaching composition comprising a combination of a component and a second agent comprising a second liquid composition containing water, wherein the first agent and the second agent And the first agent and the second agent are mixed, and a bleaching composition containing (A) component, (B) component, (C) component, (D) component and water Multi-drug type articles for bleaching compositions (hereinafter referred to as multi-drug type articles 1 for bleaching composition) in which products are prepared.
この漂白剤組成物用多剤型物品１では、第１の剤中の（Ａ）成分の含有量は、０．０２質量％以上、更に０．２質量％以上、更に０．３質量％以上が好ましく、そして、４０質量％以下、更に２０質量％以下、更に５質量％以下、更に２質量％以下が好ましい。漂白剤組成物用多剤型物品１では、（Ｄ）成分を用いて第１の液体組成物のｐＨを調整することが好ましい。第１の剤中の（Ｄ）成分の含有量は、０．０２質量％以上、更に０．２質量％以上、更に２質量％以上が好ましく、そして、５０質量％以下、更に２０質量％以下、更に１０質量％、更に５質量％以下が好ましい。水は残部となる量で用いられる。第１の剤は、（Ｃ）成分を含有しないことが好ましい。第１の液体組成物のｐＨは、２０℃で、１１以上、更に１２以上、更に１３以上、そして、１３．８以下、更に１３．６以下であることが好ましい。 In this multi-drug type article 1 for bleach composition, the content of the component (A) in the first agent is 0.02% by mass or more, further 0.2% by mass or more, and further 0.3% by mass or more. It is preferably 40% by mass or less, more preferably 20% by mass or less, further 5% by mass or less, and further preferably 2% by mass or less. In the multi-component article 1 for bleach composition, it is preferable to adjust the pH of the first liquid composition using the component (D). The content of the component (D) in the first agent is 0.02% by mass or more, more preferably 0.2% by mass or more, and further preferably 2% by mass or more, and 50% by mass or less, and further 20% by mass or less. Further, 10% by mass, and further 5% by mass or less are preferable. Water is used in the remaining amount. It is preferable that a 1st agent does not contain (C) component. The pH of the first liquid composition is preferably 11 or more, further 12 or more, further 13 or more, and 13.8 or less, and further 13.6 or less at 20 ° C.
また、この漂白剤組成物用多剤型物品１では、第２の剤中の（Ｂ）成分の含有量は、０．０２質量％以上、更に０．２質量％以上、更に２質量％以上、更に３質量％以上が好ましく、そして、５０質量％以下、更に３０質量％以下、更に１０質量％以下、更に５質量％以下が好ましい。また、この漂白剤組成物用多剤型物品１では、第２の剤中の（Ｃ）成分の含有量は、０．０２質量％以上、更に０．２質量％以上、更に２質量％以上が好ましく、そして、５０質量％以下、更に３０質量％以下、更に１０質量％以下、更に５質量％以下、更に３質量％以下が好ましい。水は残部となる量で用いられる。第２の液体組成物のｐＨは、２０℃で、１以上、更に２以上、更２．５以上、そして、５以下、更に４以下、更に３．５以下であることが好ましい。 Moreover, in this multi-drug type article 1 for bleach composition, the content of the component (B) in the second agent is 0.02% by mass or more, further 0.2% by mass or more, and further 2% by mass or more. Further, 3% by mass or more is preferable, and 50% by mass or less, further 30% by mass or less, further 10% by mass or less, and further 5% by mass or less are preferable. Moreover, in this multi-drug type article 1 for bleach composition, the content of the component (C) in the second agent is 0.02% by mass or more, further 0.2% by mass or more, and further 2% by mass or more. It is preferably 50% by mass or less, more preferably 30% by mass or less, further 10% by mass or less, further 5% by mass or less, and further preferably 3% by mass or less. Water is used in the remaining amount. The pH of the second liquid composition is preferably 1 or more, further 2 or more, further 2.5 or more, and 5 or less, further 4 or less, and further 3.5 or less at 20 ° C.
本発明の漂白洗浄剤組成物用多剤型物品の一例として、（Ａ）成分、（Ｄ）成分、及び水を含有する第１の液体組成物からなる第１の剤と、（Ｂ）成分、（Ｃ）成分、及び水を含有する第２の液体組成物からなる第２の剤との組み合わせを含む漂白洗浄剤組成物用多剤型物品であって、前記第１の剤と第２の剤とを分離した状態で保持し、第１の剤と第２の剤が混合されて、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水を含有する漂白洗浄剤組成物が調製される、漂白洗浄剤組成物用多剤型物品（以下、漂白洗浄剤組成物用多剤型物品１という）が挙げられる。この漂白洗浄剤組成物用多剤型物品１においても、第１の剤中の（Ａ）成分の含有量、（Ｄ）成分の含有量、第２の剤中の（Ｂ）成分の含有量、第２の剤中の（Ｃ）成分の含有量、第１の剤のｐＨ、第２の剤のｐＨは、それぞれ、前記漂白剤組成物用多剤型物品１で述べた範囲が適用できる。また、何れの剤においても、水は残部となる量で用いられる。また、第１の剤は、（Ｃ）成分を含有しないことが好ましい。 As an example of a multi-drug article for a bleaching detergent composition of the present invention, a first agent comprising a first liquid composition containing component (A), component (D), and water, and component (B) , (C) component, and a multi-component article for a bleaching detergent composition comprising a combination of a second agent comprising a second liquid composition containing water, wherein the first agent and the second agent The first agent and the second agent are mixed and contain (A) component, (B) component, (C) component, (D) component, and water. A multi-drug article for a bleach detergent composition (hereinafter referred to as multi-drug article 1 for a bleach detergent composition) in which a bleach detergent composition is prepared may be mentioned. Also in this multi-drug article 1 for bleaching detergent composition, the content of component (A) in the first agent, the content of component (D), the content of component (B) in the second agent The content of the component (C) in the second agent, the pH of the first agent, and the pH of the second agent can each be within the ranges described in the multi-drug type article 1 for bleach composition. . In any agent, water is used in an amount that makes up the balance. Moreover, it is preferable that a 1st agent does not contain (C) component.
本発明の酸化性組成物用多剤型物品、更に前記漂白剤組成物用多剤型物品１又は漂白洗浄剤組成物用多剤型物品１では、第１の剤及び第２の剤の少なくとも一方が（Ｅ）成分を含有することが好ましい。第１の剤及び第２の剤の両方が（Ｅ）成分を含有することがより好ましい。第１の剤が（Ｅ）成分を含有する場合、第１の剤中の（Ｅ）成分の含有量は０．０１質量％以上、更に０．１質量％以上、更に０．４質量％以上が好ましく、そして、５質量％以下、更に３質量％以下、更に１．０質量％以下、更に０．６質量％以下が好ましい。また、第２の剤が（Ｅ）成分を含有する場合、第２の剤中の（Ｅ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に０．５質量％以上、更に３質量％以上、更に５質量％以上が好ましく、そして、５０質量％以下、更に３０質量％以下、更に１０質量％以下が好ましい。 In the multi-component article for the oxidizing composition of the present invention, and further in the multi-component article 1 for the bleach composition or the multi-component article 1 for the bleach detergent composition, at least one of the first agent and the second agent. One side preferably contains the component (E). It is more preferable that both the first agent and the second agent contain the component (E). When the first agent contains the component (E), the content of the component (E) in the first agent is 0.01% by mass or more, further 0.1% by mass or more, and further 0.4% by mass or more. And 5% by mass or less, further 3% by mass or less, further 1.0% by mass or less, and further 0.6% by mass or less are preferable. Further, when the second agent contains the component (E), the content of the component (E) in the second agent is 0.01% by mass or more, further 0.1% by mass or more, and further 0.5%. It is preferably not less than 3% by mass, more preferably not less than 3% by mass, and further not less than 5% by mass, and is preferably not more than 50% by mass, more preferably not more than 30% by mass, and further preferably not more than 10% by mass.
また、本発明の酸化性組成物用多剤型物品、更に前記漂白剤組成物用多剤型物品１又は漂白洗浄剤組成物用多剤型物品１では、第２の剤が（Ｆ）成分を含有することが好ましい。その場合、第２の剤中の（Ｆ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に０．３質量％以上が好ましく、そして、２．０質量％以下、更に１．０質量％以下、更に０．５質量％以下が好ましい。 Further, in the multi-component article for the oxidizing composition of the present invention, and further in the multi-component article 1 for the bleach composition or the multi-component article 1 for the bleach cleaning composition, the second agent is the component (F). It is preferable to contain. In that case, the content of the component (F) in the second agent is 0.01% by mass or more, more preferably 0.1% by mass or more, further preferably 0.3% by mass or more, and 2.0% by mass. Hereinafter, 1.0 mass% or less is further preferable, and 0.5 mass% or less is further preferable.
漂白剤組成物用多剤型物品１又は漂白洗浄剤組成物用多剤型物品１のような本発明の多剤型物品では、（Ｅ）成分、（Ｆ）成分は、第１、第２の液体組成物の何れに配合してもよいが、それぞれが、少なくとも第２の液体組成物に配合されていることが好ましい。 In the multi-drug article of the present invention such as the multi-drug type article 1 for the bleaching composition or the multi-drug type article 1 for the bleaching detergent composition, the (E) component and the (F) component are the first and second components. Although it may mix | blend with any of these liquid compositions, it is preferable that each is mix | blended with the 2nd liquid composition at least.
本発明の酸化性組成物用多剤型物品、更に漂白剤組成物用多剤型物品又は漂白洗浄剤組成物用多剤型物品が、前記のような２剤型である場合には、第１の剤と第２の剤を分離して収容する収容部と各収容部から内容物を噴霧する２つのスプレー手段とを備えた容器を用いた２剤型スプレー式酸化剤物品、更に２剤型スプレー式漂白剤物品又は２剤型スプレー式漂白洗浄剤物品であることが好ましい。この形態のスプレー物品では、それぞれの収容部から排出される第１の液体組成物と第２の液体組成物が噴出直後に合一されて混合した状態で対象物に噴射されることが好ましい。従って、それぞれのスプレー口から噴射された内容物が混合されて対象物に付着するよう、スプレー口の開口方向の角度を調整することが好ましい。２剤型スプレー式漂白剤物品又は２剤型スプレー式漂白洗浄剤物品である場合には、スプレーから噴出する前に液が接しないように、２個のスプレー口を有する容器が好ましい。また、噴出した液が先端部分で固化することを防止するために、２個のスプレー口の間隔は０．０１ｍｍ以上、好ましくは０．１ｍｍ以上、より好ましくは１ｍｍ以上、更に好ましくは３ｍｍ以上であることが好ましく、噴出した液が混合しやすくするために、１０ｍｍ以下、更には８ｍｍ以下、更には５ｍｍ以下であることが好ましい。 When the multi-drug article for the oxidizing composition of the present invention, the multi-drug article for the bleaching composition or the multi-drug article for the bleaching detergent composition is the two-drug type as described above, Two-part spray-type oxidant article using a container provided with a container that separates and stores one agent and a second agent, and two spraying means for spraying contents from each container, and further two agents It is preferably a type spray bleach article or a two-part spray bleach detergent article. In the spray article of this form, it is preferable that the first liquid composition and the second liquid composition discharged from the respective storage units are jetted onto the object in a state of being combined and mixed immediately after jetting. Therefore, it is preferable to adjust the angle in the opening direction of the spray ports so that the contents ejected from the respective spray ports are mixed and adhere to the object. In the case of a two-part spray-type bleaching article or a two-part-type spray-type bleaching detergent article, a container having two spray ports is preferable so that the liquid does not come into contact before being ejected from the spray. Further, in order to prevent the ejected liquid from solidifying at the tip portion, the distance between the two spray ports is 0.01 mm or more, preferably 0.1 mm or more, more preferably 1 mm or more, and further preferably 3 mm or more. In order to facilitate mixing of the ejected liquid, it is preferably 10 mm or less, more preferably 8 mm or less, and further preferably 5 mm or less.
本発明は、
（Ａ）成分、（Ｄ）成分及び水を含有する第１の液体組成物からなる第１の剤が収容された第１の収容部と、
（Ｂ）成分、（Ｃ）成分及び水を含有する第２の液体組成物からなる第２の剤が収容された第２の収容部と、
スプレー口を有し、前記第１の収容部から前記第１の液体組成物を噴霧する第１のスプレー手段と、
スプレー口を有し、前記第２の収容部から前記第２の液体組成物を噴霧する第２のスプレー手段と、
を備え、
前記第１の収容部と前記第２の収容部により、前記第１の液体組成物と前記第２の液体組成物が分離されており、
前記第１のスプレー手段のスプレー口と前記第２のスプレー手段のスプレー口が、前記第１の液体組成物と前記第２の液体組成物が噴射後に混合されるよう、設けられている、２剤型スプレー式漂白剤物品を提供する。この２剤型スプレー式漂白剤物品においても、第１の液体組成物中の（Ａ）成分の含有量、第１の液体組成物中の（Ｄ）成分の含有量、第２の液体組成物中の（Ｂ）成分の含有量、第２の液体組成物中の（Ｃ）成分の含有量、第１の液体組成物のｐＨ、第２の液体組成物のｐＨは、それぞれ、前記漂白剤組成物用多剤型物品１で述べた範囲が適用できる。また、何れの液体組成物においても、水は残部となる量で用いられる。また、第１の剤は、（Ｃ）成分を含有しないことが好ましい。
The present invention
A first container containing a first agent comprising a first liquid composition containing the component (A), the component (D) and water;
A second container containing a second agent comprising a second liquid composition containing the component (B), the component (C) and water;
A first spray means having a spray port and spraying the first liquid composition from the first container;
A second spray means having a spray port and spraying the second liquid composition from the second container;
With
The first liquid composition and the second liquid composition are separated by the first container and the second container,
The spray port of the first spray means and the spray port of the second spray means are provided so that the first liquid composition and the second liquid composition are mixed after jetting. A dosage form spray bleach article is provided. In this two-part spray bleaching article, the content of the component (A) in the first liquid composition, the content of the component (D) in the first liquid composition, the second liquid composition The content of the component (B), the content of the component (C) in the second liquid composition, the pH of the first liquid composition, and the pH of the second liquid composition are the bleaching agent, respectively. The range described in the multi-drug article 1 for composition can be applied. In any liquid composition, water is used in the remaining amount. Moreover, it is preferable that a 1st agent does not contain (C) component.
また、本発明は、
（Ａ）成分、（Ｄ）成分及び水を含有する第１の液体組成物からなる第１の剤が収容された第１の収容部と、
（Ｂ）成分、（Ｃ）成分及び水を含有する第２の液体組成物からなる第２の剤が収容された第２の収容部と、
スプレー口を有し、前記第１の収容部から前記第１の液体組成物を噴霧する第１のスプレー手段と、
スプレー口を有し、前記第２の収容部から前記第２の液体組成物を噴霧する第２のスプレー手段と、
を備え、
前記第１の収容部と前記第２の収容部により、前記第１の液体組成物と前記第２の液体組成物が分離されており、
前記第１のスプレー手段のスプレー口と前記第２のスプレー手段のスプレー口が、前記第１の液体組成物と前記第２の液体組成物が噴射後に混合されるよう、設けられている、２剤型スプレー式漂白洗浄剤物品を提供する。この２剤型スプレー式漂白洗浄剤物品においても、第１の液体組成物中の（Ａ）成分の含有量、第１の液体組成物中の（Ｄ）成分の含有量、第２の液体組成物中の（Ｂ）成分の含有量、第２の液体組成物中の（Ｃ）成分の含有量、第１の液体組成物のｐＨ、第２の液体組成物のｐＨは、それぞれ、前記漂白洗浄剤組成物用多剤型物品１で述べた範囲が適用できる。また、何れの液体組成物においても、水は残部となる量で用いられる。また、第１の剤は、（Ｃ）成分を含有しないことが好ましい。
The present invention also provides:
A first container containing a first agent comprising a first liquid composition containing the component (A), the component (D) and water;
A second container containing a second agent comprising a second liquid composition containing the component (B), the component (C) and water;
A first spray means having a spray port and spraying the first liquid composition from the first container;
A second spray means having a spray port and spraying the second liquid composition from the second container;
With
The first liquid composition and the second liquid composition are separated by the first container and the second container,
The spray port of the first spray means and the spray port of the second spray means are provided so that the first liquid composition and the second liquid composition are mixed after jetting. A dosage form spray bleach detergent article is provided. Also in this two-part spray bleach detergent product, the content of the component (A) in the first liquid composition, the content of the component (D) in the first liquid composition, the second liquid composition The content of the component (B) in the product, the content of the component (C) in the second liquid composition, the pH of the first liquid composition, and the pH of the second liquid composition are the bleaching, respectively. The range described in the multi-drug article 1 for the detergent composition can be applied. In any liquid composition, water is used in the remaining amount. Moreover, it is preferable that a 1st agent does not contain (C) component.
また、本発明の漂白剤組成物用多剤型物品又は漂白洗浄剤組成物用多剤型物品が、前記のような２剤型である場合には、第１の剤と第２の剤を分離して収容する収容部と、各収容部から内容物を搬送し合流させる経路と、合流した剤を噴霧する１つのスプレー手段とを備えた容器を用いた２剤型スプレー式漂白剤物品又は２剤型スプレー式漂白洗浄剤物品であってもよい。この形態のスプレー物品では、それぞれの収容部から排出される第１の液体組成物と第２の液体組成物が噴出直後に合一されて混合した状態に搬送されスプレー口から対象物に噴射されることが好ましい。 Moreover, when the multi-drug type article for bleach composition or the multi-drug type article for bleach cleaning composition of the present invention is the two-drug type as described above, the first agent and the second agent are added. A two-part spray bleaching article using a container having a container that is separately housed, a path through which the contents are conveyed and merged from each container, and one spraying means for spraying the merged agent, or It may be a two-part spray bleach detergent article. In the spray article of this form, the first liquid composition and the second liquid composition discharged from the respective accommodating portions are united and mixed immediately after the jetting, and are transported and injected from the spray port onto the object. It is preferable.
なお、漂白剤組成物用多剤型物品、漂白洗浄剤組成物用多剤型物品、２剤型スプレー式漂白剤物品、２剤型スプレー式漂白洗浄剤物品で述べた事項は、他の酸化剤組成物を用いた物品（例えばカビ取り剤）に適用できる。従って、例えば、前記の漂白剤組成物用多剤型物品や漂白洗浄剤組成物用多剤型物品を、カビ取り剤用多剤型物品として、また、２剤型スプレー式漂白剤物品や２剤型スプレー式漂白洗浄剤物品を、２剤型スプレー式カビ取り剤物品として用いることができる。 In addition, the matters described in the multi-drug product for bleach composition, multi-drug product for bleach detergent composition, 2-drug spray bleach product, 2d spray bleach product are other oxidation items. The present invention can be applied to articles (for example, mold removers) using the agent composition. Therefore, for example, the above-mentioned multi-drug article for bleaching composition or multi-drug type article for bleaching detergent composition is used as a multi-drug type article for mold remover, or as a two-drug spray bleaching article or 2 The dosage form spray bleach detergent article can be used as a two-part spray mold remover article.
＜漂白方法＞
本発明の酸化性組成物を漂白目的で使用する場合、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水を含有する漂白用液体組成物を漂白対象物に接触させることが好ましい。漂白用液体組成物は、本発明の酸化性組成物用多剤型物品から調製された本発明の酸化性組成物又は本発明の酸化性組成物を濃度調整したものが用いられる。なお、この漂白用液体組成物もまた酸化性組成物である。
<Bleaching method>
When the oxidizing composition of the present invention is used for bleaching purposes, a bleaching liquid composition containing (A) component, (B) component, (C) component, (D) component, and water is to be bleached. It is preferable to make it contact. As the bleaching liquid composition, the oxidizing composition of the present invention prepared from the multi-dose article for the oxidizing composition of the present invention or the concentration-adjusted composition of the oxidizing composition of the present invention is used. This bleaching liquid composition is also an oxidizing composition.
漂白対象物が硬質表面である場合、漂白用液体組成物中の（Ａ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に０．１５質量％以上、そして、２０質量％以下、更に１０質量％以下、更に５質量％以下、更に３質量％以下、更に１質量％以下、更に０．９質量％以下が好ましい。また、漂白用液体組成物中の（Ｂ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に１質量％以上、更に２質量％以上、そして、５０質量％以下、更に３０質量％以下、更に１０質量％以下、更に５質量％以下が好ましい。また、漂白用液体組成物中の（Ｃ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に１質量％以上、更に１．４質量％以上、そして、５０質量％以下、更に３０質量％以下、更に１０質量％以下、更に５質量％以下、更に２質量％以下が好ましい。また、漂白用液体組成物中の（Ｄ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に１質量％以上、そして、５０質量％以下、更に３０質量％以下、更に１０質量％以下、更に５質量％以下、更に２質量％以下が好ましい。また、（Ｅ）成分を用いる場合、漂白用液体組成物中の（Ｅ）成分の含有量は、０．１質量％以上、更に１質量％以上、更に４質量％以上、そして、５０質量％以下、更に３０質量％以下、更に１５質量％以下が好ましい。また、（Ｆ）成分を用いる場合、漂白用液体組成物中の（Ｆ）成分の含有量は、０．０１質量％以上、更に０．１質量％以上、更に０．１５質量％以上、そして、３０質量％以下、更に２０質量％以下、更に１０質量％以下、更に５質量％以下、更に１質量％以下、更に０．５質量％以下が好ましい。 When the bleaching object is a hard surface, the content of the component (A) in the bleaching liquid composition is 0.01% by mass or more, further 0.1% by mass or more, further 0.15% by mass or more, and 20% by mass or less, further 10% by mass or less, further 5% by mass or less, further 3% by mass or less, further 1% by mass or less, and further preferably 0.9% by mass or less. The content of the component (B) in the bleaching liquid composition is 0.01% by mass or more, further 0.1% by mass or more, further 1% by mass or more, further 2% by mass or more, and 50% by mass. Hereinafter, it is preferably 30% by mass or less, further 10% by mass or less, and further preferably 5% by mass or less. The content of the component (C) in the bleaching liquid composition is 0.01% by mass or more, further 0.1% by mass or more, further 1% by mass or more, further 1.4% by mass or more, and 50%. It is preferably not more than mass%, more preferably not more than 30 mass%, further not more than 10 mass%, further not more than 5 mass%, and further not more than 2 mass%. The content of component (D) in the bleaching liquid composition is 0.01% by mass or more, further 0.1% by mass or more, further 1% by mass or more, and 50% by mass or less, and further 30% by mass. Hereinafter, it is preferably 10% by mass or less, further 5% by mass or less, and further preferably 2% by mass or less. When the component (E) is used, the content of the component (E) in the bleaching liquid composition is 0.1% by mass or more, further 1% by mass or more, further 4% by mass or more, and 50% by mass. Hereinafter, it is further preferably 30% by mass or less, and more preferably 15% by mass or less. When the component (F) is used, the content of the component (F) in the bleaching liquid composition is 0.01% by mass or more, further 0.1% by mass or more, further 0.15% by mass or more, and 30% by mass or less, further 20% by mass or less, further 10% by mass or less, further 5% by mass or less, further 1% by mass or less, and further preferably 0.5% by mass or less.
また、漂白用液体組成物のｐＨは、２０℃で、１０以上、更に１１以上、更に１２以上、そして、１３以下、更に１２．５以下であることが好ましい。 The pH of the bleaching liquid composition is preferably 10 or more, further 11 or more, further 12 or more, 13 or less, and further 12.5 or less at 20 ° C.
漂白用液体組成物における各成分の含有量とｐＨは、本発明の酸化性組成物の使用時の各成分の含有量及びｐＨとして位置付けることができる。 The content and pH of each component in the bleaching liquid composition can be positioned as the content and pH of each component when the oxidizing composition of the present invention is used.
本発明は、
（Ａ）成分、（Ｂ）成分、（Ｃ）成分、（Ｄ）成分、及び水を混合して酸化性組成物を調製する第１のステップ、
第１のステップで調製された酸化性組成物を漂白対象物に接触させる第２のステップ、を含む漂白方法を提供する。第１のステップで、（Ｅ）成分、（Ｆ）成分から選ばれる成分を混合することができる。
The present invention
A first step of preparing an oxidizing composition by mixing (A) component, (B) component, (C) component, (D) component, and water;
There is provided a bleaching method comprising a second step of contacting the oxidizing composition prepared in the first step with an object to be bleached. In the first step, a component selected from the component (E) and the component (F) can be mixed.
また、本発明は、
（Ａ）成分、及び水を含有する第１の液体組成物と、（Ｂ）成分、（Ｃ）成分及び水を含有する第２の液体組成物とを混合して、（Ａ）成分、（Ｂ）成分、（Ｃ）成分、及び水を含有する酸化性組成物を調製する第１のステップ、
第１のステップで調製された酸化性組成物を漂白対象物に接触させる第２のステップ、を含む漂白方法を提供する。第１のステップで用いる第１の液体組成物と第２の液体組成物には、それぞれ、（Ｄ）成分、（Ｅ）成分、（Ｆ）成分から選ばれる成分を適宜混合することができる。
The present invention also provides:
The first liquid composition containing the component (A) and water is mixed with the second liquid composition containing the component (B), the component (C) and water, and the component (A), ( A first step of preparing an oxidizing composition comprising B) component, (C) component, and water;
There is provided a bleaching method comprising a second step of contacting the oxidizing composition prepared in the first step with an object to be bleached. In the first liquid composition and the second liquid composition used in the first step, components selected from the component (D), the component (E), and the component (F) can be appropriately mixed.
これらの漂白方法では、酸化性組成物は前記した漂白用液体組成物であってよく、（Ａ）成分〜（Ｃ）成分の好ましい態様、酸化性組成物の好ましい態様、漂白用液体組成物の好ましい態様、第１の液体組成物、第２の液体組成物などは、何れも前述のものが適用できる。また、漂白方法は、カビ取り方法であってよい。 In these bleaching methods, the oxidizing composition may be the above-described bleaching liquid composition, the preferred embodiment of the components (A) to (C), the preferred embodiment of the oxidizing composition, and the bleaching liquid composition. The preferred embodiments, the first liquid composition, the second liquid composition, and the like can be applied to any of the above. The bleaching method may be a mold removing method.
本発明の酸化性組成物は、カビ取り剤組成物としての用途の他に、風呂・トイレ・台所等の硬質表面の漂白、衣類の漂白、汚れ・匂い原因物質の分解、除菌、パルプの漂白、繊維の精練などにも使用することが出来る。 The oxidizing composition of the present invention, in addition to its use as a fungicide composition, bleaches hard surfaces such as baths, toilets and kitchens, bleaches clothes, decomposes dirt and odor-causing substances, disinfects, and removes pulp. It can also be used for bleaching and fiber scouring.
表１に示す組成のＡ液及びＢ液を調製し、両者を等量（体積比１：１）混合し、酸化性組成物であるカビ取り剤組成物を得た〔（Ｃ）成分の含有量は過酸化水素としての量である。〕。Ａ液とＢ液は、硫酸及び／又は水酸化ナトリウムを用いてｐＨを調整した。この組成物を使用し、下記のカビ汚れ洗浄試験を実施した。その結果を下記表１に示す。なお、Ａ液とＢ液を等量混合した組成物のｐＨ（２０℃）は、何れも１２．０であった。また、Ａ液とＢ液を等量混合した直後の組成物中の各成分の含有量は、表１中の数値（質量％）の１／２となった。なお、各実施例の（Ａ）成分の含有量が同モル濃度となるように、（Ａ）成分の質量濃度を調整した。 Liquid A and liquid B having the composition shown in Table 1 were prepared, and both were mixed in an equal amount (volume ratio 1: 1) to obtain a fungicide removing composition which was an oxidizing composition [Containment of component (C) The amount is the amount as hydrogen peroxide. ]. A liquid and B liquid adjusted pH using a sulfuric acid and / or sodium hydroxide. Using this composition, the following mold stain cleaning test was conducted. The results are shown in Table 1 below. In addition, pH (20 degreeC) of the composition which mixed A liquid and B liquid equally was all 12.0. In addition, the content of each component in the composition immediately after mixing equal amounts of liquid A and liquid B was ½ of the numerical value (% by mass) in Table 1. In addition, the mass concentration of (A) component was adjusted so that content of (A) component of each Example might become the same molar concentration.
＜カビ汚れ洗浄試験＞
クラドスポリウム（Cladosporium）属細菌を素焼きタイルに接種し、温度３０℃、湿度１００％ＲＨで６０日間培養したものをカビ発生タイルとし、漂白性能を比較した。
<Must stain cleaning test>
Bleaching performance was compared by inoculating unglazed tiles with bacteria of the genus Cladosporium and culturing for 60 days at a temperature of 30 ° C. and a humidity of 100% RH as mold generating tiles.
カビ発生タイルに上記カビ取り剤組成物を２０μｌ滴下し、直径約１ｃｍとし、２５℃で２０分放置後、水洗、風乾した後、色差計（日本電色工業製ＳＥ６０００）を用いて明度（Ｌ）値を測定し、次式により漂白率を算出した。 20 μl of the above mold removing composition was dropped onto the mold generating tile, the diameter was about 1 cm, left at 25 ° C. for 20 minutes, washed with water, air-dried, and lightness (L) using a color difference meter (SE6000 manufactured by Nippon Denshoku Industries Co., Ltd.). ) Value was measured, and the bleaching rate was calculated by the following formula.
表中の比較化合物１〜３は以下の化合物である。 Comparative compounds 1 to 3 in the table are the following compounds.
表１中、（Ｂ）成分の有機過酸前駆体と（Ｃ）成分の過酸化水素の併用系である比較品１に比べ、更に（Ａ）成分を配合した本発明品１〜６では、漂白率がより大きくなっていた。本発明品１〜６から、（Ｂ）成分と（Ｃ）成分の併用系に（Ａ）成分を用いることで、漂白率が大幅に向上することがわかった。 In Table 1, in comparison with Comparative Product 1 which is a combined system of an organic peracid precursor of component (B) and hydrogen peroxide of component (C), the present invention products 1 to 6 further blended with component (A) The bleaching rate was larger. From the inventive products 1 to 6, it was found that the bleaching rate was greatly improved by using the component (A) in the combined system of the component (B) and the component (C).
Claims (6)
（Ａ）成分：下記一般式（Ａ１）で表される化合物及びその塩から選択される１以上の化合物
（Ｂ）成分：有機過酸前駆体及び有機過酸からなる群から選択される１以上の化合物
（Ｃ）成分：過酸化水素及び水中で過酸化水素を生成する過酸化物からなる群から選択される１以上の化合物
（Ｄ）成分：アルカリ金属の水酸化物、アルカリ金属の炭酸塩、アルカリ土類金属の水酸化物、アルカリ土類金属の炭酸塩、モノエタノールアミン、ジエタノールアミン及びトリエタノールアミンからなる群から選択される１以上のアルカリ剤
［式（Ａ１）中、Ｒ１〜Ｒ５は、それぞれ独立に、水素原子、水酸基、炭素数１以上、３以下のアルコキシ基、及び−（Ｒ６）ｘＣＯＯＲ７からなる群から選択される原子又は基を示す。Ｒ６は、２重結合を有していてもよい炭素数１以上、６以下の炭化水素基を示し、Ｒ７は、水素原子、又は炭素数１以上、３以下の炭化水素基を示し、ｘは、０又は１の数を示す。Ｒ１〜Ｒ５のうち少なくとも１つは、−（Ｒ６）ｘＣＯＯＲ７である。］ It consists of the combination of the agent containing the following (A) component, (B) component, (C) component, (D) component, and the component selected from water, (A) component and (C) component are another agents A multi-dose article for an oxidizing composition, which is blended in
Component (A): One or more compounds selected from the compound represented by the following general formula (A1) and salts thereof (B) Component: One or more selected from the group consisting of organic peracid precursors and organic peracids Compound (C) component: One or more compounds (D) selected from the group consisting of hydrogen peroxide and a peroxide that generates hydrogen peroxide in water: Alkali metal hydroxide, alkali metal carbonate One or more alkaline agents selected from the group consisting of alkaline earth metal hydroxides, alkaline earth metal carbonates, monoethanolamine, diethanolamine and triethanolamine
[In Formula (A1), R 1 to R 5 are each independently selected from the group consisting of a hydrogen atom, a hydroxyl group, an alkoxy group having 1 to 3 carbon atoms, and — (R 6 ) x COOR 7. Indicates an atom or group. R 6 represents a hydrocarbon group having 1 to 6 carbon atoms which may have a double bond, R 7 represents a hydrogen atom or a hydrocarbon group having 1 to 3 carbon atoms, x represents a number of 0 or 1. At least one of R 1 to R 5 is — (R 6 ) x COOR 7 . ]
［式中、Ｒ11bは炭素数５以上、１９以下のアルキル基又はアルケニル基、Ｚは、ＳＯ3Ｍ又はＣＯＯＭ、Ｍは陽イオンを示す。］ The multi-drug type article for oxidizing compositions according to claim 1 or 2, wherein the component (B) is an organic peracid precursor represented by the following general formula (B1).
[Wherein, R 11b represents an alkyl group or alkenyl group having 5 to 19 carbon atoms, Z represents SO 3 M or COOM, and M represents a cation. ]
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