JP2016055396A - Wire electric discharge machining method and device thereof - Google Patents

Wire electric discharge machining method and device thereof Download PDF

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JP2016055396A
JP2016055396A JP2014185163A JP2014185163A JP2016055396A JP 2016055396 A JP2016055396 A JP 2016055396A JP 2014185163 A JP2014185163 A JP 2014185163A JP 2014185163 A JP2014185163 A JP 2014185163A JP 2016055396 A JP2016055396 A JP 2016055396A
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electric discharge
discharge machining
heavy metal
wire
wire electric
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利雄 橋野
Toshio Hashino
利雄 橋野
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Fiebri Chem Kk
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Abstract

PROBLEM TO BE SOLVED: To provide a wire electric discharge machining method enabling a long time stable wire electric discharge machining, a device to perform the method, and a means to prevent formation of verdigris, which may cause process trouble.SOLUTION: A wire electric discharge machining method uses water purified using an ion exchange resin (11) and further made free from any heavy metal ion, particularly a copper ion using an ion exchange resin (15), as a dielectric substance for the wire electric discharge machining. The wire electric discharge machining method enables a long time stable wire electric discharge machining, suppressing formation of verdigris.SELECTED DRAWING: Figure 2

Description

本発明は、ワイアー放電加工方法およびその装置に関し、さらに詳しくは、長時間の安定した運転を可能にするワイアー放電加工方法およびその装置に関する。   The present invention relates to a wire electric discharge machining method and an apparatus thereof, and more particularly to a wire electric discharge machining method and an apparatus thereof that enable stable operation for a long time.

放電加工は、電極と被加工物との間に短い周期で繰り返されるアーク放電によって被加工物表面の一部を除去する機械加工の方法である。ワイアー放電加工はこの放電加工の一種で、金属の細いワイアーを電極として、これを繰り出しながら、被加工物との間のアーク放電により被加工物を所望の形状に切り出す。金型などの精密加工に好ましく用いられる加工方法である。被加工物とワイアーとの間には、誘電体として水または油が置かれる。水を利用する場合には、被加工物とワイアーとの間に水を吹き掛ける方式と、水を満たす浸漬方式が一般的には知られている。   Electric discharge machining is a machining method in which a part of the surface of a workpiece is removed by arc discharge repeated at short intervals between an electrode and the workpiece. Wire electric discharge machining is a type of electric discharge machining, in which a thin metal wire is used as an electrode, and the workpiece is cut into a desired shape by arc discharge between the workpiece and the workpiece. This is a processing method preferably used for precision processing of dies and the like. Water or oil is placed as a dielectric between the work piece and the wire. In the case of using water, a method of spraying water between a workpiece and a wire and a dipping method for filling water are generally known.

誘電体として水を使用する場合、水の抵抗率(電気伝導度)は、イオン交換により純水化して一定の範囲にあるよう制御されるのが通常である。さらに、水のその他の特性・性質を改善することもなされている。例えば、特開2002−301624号公報(特許文献1)は、被加工物の腐食を防止するために、腐食性イオンである硫酸イオンと塩化物イオン濃度を低下させ、他方で水の電気伝導度を上昇させない方法が提案されている。この方法では、亜硝酸イオンとともに炭酸イオン、炭酸水素イオンおよび水酸化物イオンのうちの1種以上を固定した陰イオン交換樹脂と水とを接触させ循環させる。   When water is used as a dielectric, the resistivity (electric conductivity) of water is usually controlled to be in a certain range after being purified by ion exchange. In addition, other properties and properties of water have been improved. For example, Japanese Patent Laid-Open No. 2002-301624 (Patent Document 1) reduces the concentration of sulfate ions and chloride ions, which are corrosive ions, in order to prevent corrosion of a workpiece, while the electrical conductivity of water. A method has been proposed that does not raise the value. In this method, water is brought into contact with an anion exchange resin in which at least one of carbonate ion, hydrogen carbonate ion and hydroxide ion is fixed together with nitrite ion and water.

しかしながら、本発明者の知る限りでは、ワイアー加工放電の誘電体としての水に対して重金属のイオン濃度の制御を行うとの提案は、これまでなされていない。   However, as far as the present inventor knows, no proposal has been made so far to control the ion concentration of heavy metal with respect to water as a dielectric for wire processing discharge.

特開2002−301624号公報JP 2002-301624 A

本発明者は、今般、ワイアー放電加工の誘電体としての水の重金属イオン濃度を制御することで、長時間の安定したワイアー放電加工が可能になるとの知見を得た。本発明は、この知見に基づくものである。   The present inventor has recently obtained the knowledge that by controlling the heavy metal ion concentration of water as a dielectric for wire electric discharge machining, stable wire electric discharge machining for a long time becomes possible. The present invention is based on this finding.

従って、本発明は、長時間の安定したワイアー放電加工を可能にするワイアー放電加工方法およびその方法を実施するための装置の提供をその目的としている。   Therefore, an object of the present invention is to provide a wire electric discharge machining method that enables stable wire electric discharge machining for a long time and an apparatus for carrying out the method.

そして、本発明によるワイアー放電加工方法は、ワイアーと被加工物との間で放電を生じさせて、これにより被加工物の一部を除去して成形が行なわれる方法であって、重金属イオンが除かれた水を、誘電体として前記ワイアーと前記被加工物との間に置くことを特徴とするものである。   The wire electric discharge machining method according to the present invention is a method in which a discharge is generated between the wire and the workpiece, thereby removing a part of the workpiece and molding is performed. The removed water is placed between the wire and the workpiece as a dielectric.

また、本発明の一つの態様によれば、前記水を、前記ワイアーと前記被加工物との間に誘電体として置いた後、重金属イオンを除き、再び前記ワイアーと前記被加工物との間に置くよう循環させる。   Further, according to one aspect of the present invention, after the water is placed as a dielectric between the wire and the workpiece, heavy metal ions are removed, and the wire and the workpiece are again disposed. Cycle to put on.

また、さらに好ましい態様によれば、重金属イオンは水をイオン交換樹脂と接触させることにより除かれ、より好ましい態様によれば、イオン交換樹脂は重金属イオンを捕捉可能なキレート構造を有するものである。   According to a further preferred embodiment, heavy metal ions are removed by bringing water into contact with the ion exchange resin. According to a more preferred embodiment, the ion exchange resin has a chelate structure capable of capturing heavy metal ions.

また、本発明によるワイアー放電加工装置は、上記の本発明によるワイアー放電加工方法を実施するための装置であって、ワイアーと被加工物との間で放電を生じさせて、これにより被加工物の一部を除去して被加工物の成形を行うワイアー放電加工手段と、誘電体として水を、前記ワイアーと前記被加工物との間に置く手段と、前記水から重金属イオンを除去する重金属イオン除去手段とを少なくとも備えてなることを特徴とする。   Further, a wire electric discharge machining apparatus according to the present invention is an apparatus for carrying out the above-described wire electric discharge machining method according to the present invention, and generates an electric discharge between the wire and the workpiece, whereby the workpiece is processed. Wire electric discharge machining means for forming a workpiece by removing a part of the wire, means for placing water as a dielectric between the wire and the workpiece, and heavy metal for removing heavy metal ions from the water And an ion removing means.

本発明の一つの態様によれば、本発明によるワイアー放電加工装置は、前記ワイアーと前記被加工物との間に誘電体として置かれた水を、前記重金属イオン除去手段に導入して重金属イオンを除き、その後再び前記ワイアーと前記被加工物との間に置くよう循環させる手段を備えてなる。   According to one aspect of the present invention, a wire electric discharge machining apparatus according to the present invention introduces water placed as a dielectric between the wire and the workpiece into the heavy metal ion removing means to remove heavy metal ions. , And thereafter, means for circulating so as to be placed again between the wire and the workpiece.

また、さらに好ましい態様によれば、重金属イオン除去手段がイオン交換樹脂であり、より好ましい態様によれば、イオン交換樹脂は重金属イオンを捕捉可能なキレート構造を有するものである。   According to a further preferred embodiment, the heavy metal ion removing means is an ion exchange resin, and according to a more preferred embodiment, the ion exchange resin has a chelate structure capable of capturing heavy metal ions.

ワイアー放電加工装置において、誘電体としての水が循環される系を説明する図である。It is a figure explaining the system by which water as a dielectric material is circulated in a wire electric discharge machining apparatus. 図1の装置において、純水化のためのイオン交換樹脂を備える純水化手段11と、重金属イオン除去手段15を、水の循環経路に対して直列に設けた構成を示す図である。In the apparatus of FIG. 1, it is a figure which shows the structure which provided the pure water purification means 11 provided with the ion exchange resin for pure water, and the heavy metal ion removal means 15 in series with respect to the circulation path of water. 図1の装置において、純水化のためのイオン交換樹脂を備える純水化手段11と、重金属イオン除去手段15を、水の循環経路に対して並列に設けた構成を示す図である。In the apparatus of FIG. 1, it is a figure which shows the structure which provided the pure water means 11 provided with the ion exchange resin for pure water, and the heavy metal ion removal means 15 in parallel with respect to the circulation path of water.

重金属イオンの制御
本発明によれば、重金属イオンの除去により、長時間の安定したワイアー放電加工が可能になる。放電加工装置の運転をある時間続けると、装置の水の循環経路においてノズルを始めとした細孔の詰まりが観察された。本発明に従い、重金属イオンの存在を制御した結果、このような不具合の発生が大きく抑制された。本発明に従い、重金属イオンの存在を制御することで、系内、とりわけ水と接触する箇所あるいは水が留まる槽などにおいて水と接触する箇所での変色の発生が認められなくなった。本発明者の観察によれば、この変色は銅を主生物とする酸化物であり、いわゆる緑青を主たる成分とする物質であって、この発生を抑制できたことが上記不具合を改善できた要因であると推察された。つまり、この変色が進み、最悪の場合、析出物として水に流れ出すことがある。本発明にあっては、この原因物質と思われる重金属のイオンの除くことで、このような不具合の発生を効率よく抑制できたものと考えられる。なお、この重金属は、ワイアーおよび被加工物に含まれる重金属であると思われ、加工中に微量ながら水中に溶出してしまうものと思われる。
Control of Heavy Metal Ions According to the present invention, long-term stable wire electric discharge machining can be performed by removing heavy metal ions. When the operation of the electric discharge machining apparatus was continued for a certain period of time, clogging of pores such as nozzles was observed in the water circulation path of the apparatus. As a result of controlling the presence of heavy metal ions in accordance with the present invention, the occurrence of such problems was greatly suppressed. By controlling the presence of heavy metal ions in accordance with the present invention, the occurrence of discoloration in the system, particularly in the place where it comes into contact with water or in the place where the water stays, etc., is no longer observed. According to the observation of the present inventor, this discoloration is an oxide mainly composed of copper, and is a substance mainly composed of so-called patina, and the fact that this generation can be suppressed is a factor that has improved the above problem It was guessed that. That is, this discoloration proceeds, and in the worst case, it may flow into water as a precipitate. In the present invention, it is considered that the occurrence of such inconveniences can be efficiently suppressed by removing heavy metal ions which are considered to be causative substances. This heavy metal is considered to be a heavy metal contained in the wire and the workpiece, and is likely to elute in water during processing.

本発明において制御の対象となる重金属イオンは、好ましくは、銅、亜鉛、および鉄からなる群から選ばれるものである。とりわけ銅イオン濃度を制御することで良好な結果が得られる。具体的には、重金属イオン濃度を0.05ppm以下とする。好ましくは、少なくとも銅イオンの濃度を0.05ppm以下とする。   The heavy metal ion to be controlled in the present invention is preferably selected from the group consisting of copper, zinc, and iron. In particular, good results can be obtained by controlling the copper ion concentration. Specifically, the heavy metal ion concentration is set to 0.05 ppm or less. Preferably, at least the copper ion concentration is 0.05 ppm or less.

本発明の好ましい態様によれば、重金属イオン濃度の制御をイオン交換樹脂により行う。より好ましい態様によれば、キレート構造を有する樹脂により重金属イオンを捕捉する。水の電気伝導度を上げるイオン種を放出しない態様で重金属イオンを捕捉するものであるため好ましい。とりわけ二価の重金属イオンを選択的に捕捉するキレート構造を有する樹脂が好ましい。このようなキレート構造を有する樹脂は公知であり、また市販されており、それらを利用することができ、その具体例としては、イミジノ酢酸をキレート構造として有するポリマー、イミノプロピオン酸基やアミノリン酸基をキレート構造として有するポリマー等があげられる。   According to a preferred embodiment of the present invention, the heavy metal ion concentration is controlled by an ion exchange resin. According to a more preferred embodiment, heavy metal ions are captured by a resin having a chelate structure. It is preferable because it captures heavy metal ions in a manner that does not release ionic species that increase the electrical conductivity of water. In particular, a resin having a chelate structure that selectively captures divalent heavy metal ions is preferable. Resins having such a chelate structure are known and commercially available, and they can be used. Specific examples thereof include a polymer having imidinoacetic acid as a chelate structure, an iminopropionic acid group and an aminophosphate group. And the like having a chelate structure.

ワイアー放電加工装置および水循環系
本発明による方法および装置にあって、重金属イオン濃度を制御するとの構成を除き、ワイアー放電加工方法および装置は、公知のまたはこれから知られる方法および装置であってよい。
Wire electric discharge machining apparatus and water circulation system In the method and apparatus according to the present invention, the wire electric discharge machining method and apparatus may be a known or known method and apparatus, except that the heavy metal ion concentration is controlled.

本発明による方法および装置における、誘電体としての水が循環される系を、図面を参照しながら説明する。図1において、加工槽1は、ワイアーと被加工物との間に放電を生じさせ、被加工物を加工する操作が行われる箇所であり、この加工槽1中に水が満たされ、その中で被加工物への化合を行う加工装置2が浸漬される。なお、本発明は、このような被加工物が水に浸漬される態様のみならず、ワイアーと被加工物の間に水を吹きかける方式に対しても適用可能である。   A system in which water as a dielectric is circulated in the method and apparatus according to the present invention will be described with reference to the drawings. In FIG. 1, a processing tank 1 is a place where an electric discharge is generated between a wire and a workpiece and an operation for processing the workpiece is performed, and the processing tank 1 is filled with water, Then, the processing device 2 for compounding the workpiece is immersed. In addition, this invention is applicable not only to the aspect in which such a to-be-processed object is immersed in water but to the system which sprays water between a wire and a to-be-processed object.

この加工槽1に満たされる水は、清水槽3から清水経路4を通じて、ポンプ5により導かれる。加工槽1の水はワイアーと被加工物の間に誘電体として置かれた後、汚水経路6通じて、汚水槽7に一旦溜められる。この汚水槽7の水は汚水経路8を通じてポンプ9により清水槽3に戻される。その際、フィルター10を通し、析出物などを除去するのが一般的である。   The water filled in the processing tank 1 is guided by the pump 5 from the fresh water tank 3 through the fresh water path 4. The water in the processing tank 1 is placed as a dielectric between the wire and the workpiece, and then temporarily stored in the sewage tank 7 through the sewage path 6. The water in the sewage tank 7 is returned to the fresh water tank 3 by the pump 9 through the sewage path 8. At that time, it is common to remove precipitates through the filter 10.

清水槽3の水は、ワイアー放電加工の開始前に、イオン交換樹脂を備える純水化手段11に導かれ、イオン交換樹脂と接触させることにより誘電体として十分な程度まで純水とされる。図1にあっては、水は、経路12を通じてポンプ13により純水化手段11に導かれ、経路14を介して清水槽3に戻る。放電加工中、このイオン交換樹脂による純水化のプロセスは連続的に行われてもよく、また清水槽3中の水の電気伝導度をモニターしながら、一定の値を超えたならば純水化プロセスを行うように構成されてもよい。一般に、純水度は約20μs/cm(50万Ω)以上とされ、通常は5〜20μS/cm程度の範囲に維持される。   The water in the fresh water tank 3 is led to a pure water purification means 11 having an ion exchange resin before the start of wire electric discharge machining, and is brought into pure water to a sufficient degree as a dielectric by contacting with the ion exchange resin. In FIG. 1, the water is guided to the pure water purification means 11 by the pump 13 through the path 12 and returns to the fresh water tank 3 through the path 14. During the electrical discharge machining, the process of pure water with the ion exchange resin may be continuously performed. If the electrical conductivity of the water in the fresh water tank 3 is monitored and a certain value is exceeded, pure water is used. It may be configured to perform a digitization process. In general, the purity is about 20 μs / cm (500,000 Ω) or more, and is usually maintained in the range of about 5 to 20 μS / cm.

本発明にあっては、この水の循環経路のいずれかの箇所において、重金属イオンを除く手段を設ける。例えば、図1中のAまたはBの箇所に設けることができる。その具体的な構成を、図2および図3を参照しながら説明する。   In the present invention, means for removing heavy metal ions is provided at any point in the water circulation path. For example, it can be provided at A or B in FIG. The specific configuration will be described with reference to FIGS.

図2は、純水化手段11と、重金属イオン除去手段15を、水の循環経路に対して直列に備えてなる構成を示すものである。なお、図1に示される加工槽と繋がる構成は、図2においては省略されている。図中、重金属イオン除去手段15内には、キレート構造を有し、重金属イオンを捕捉可能な樹脂が充填される。清水槽3にある水は、ポンプ13により経路12aを通じて、まず重金属イオン除去手段15に導かれ、重金属イオンが除かれ、次に経路12bを通じて純水化手段11に導かれ、経路14を通じて清水槽3に戻る。本発明において、純水化手段11と重金属イオン除去手段15は逆の順序とされてもよい。   FIG. 2 shows a configuration in which the pure water purification means 11 and the heavy metal ion removal means 15 are provided in series with the water circulation path. In addition, the structure connected with the processing tank shown by FIG. 1 is abbreviate | omitted in FIG. In the figure, the heavy metal ion removing means 15 is filled with a resin having a chelate structure and capable of capturing heavy metal ions. The water in the fresh water tank 3 is first led to the heavy metal ion removing means 15 by the pump 13 through the path 12a, the heavy metal ions are removed, and then led to the pure water purification means 11 through the path 12b. Return to 3. In the present invention, the pure water purification means 11 and the heavy metal ion removal means 15 may be reversed.

図3は、純水化手段11と、重金属イオン除去手段15を、水の循環経路に対して並列に備えてなる構成を示すものである。なお、図1に示される加工槽と繋がる構成は、図3においても省略されている。図中、清水槽3にある水は、経路12cを通じてポンプ13aにより重金属イオン除去手段15に導かれ、重金属イオンが除かれ、経路14aを通じて清水槽3に戻る。清水槽3にある水は、他方で、ポンプ13bにより経路12cを通じて、純水化手段11に導かれ純水化され、経路14aを通じて清水槽3に戻る。勿論ポンプ13aの1台で配管の分岐により行うこともできる。また、図2および図3のいずれの態様にあっても、イオン交換手段11および重金属イオン除去手段15は筒またはタンクの形状とされて、これら筒またはタンクだけ取り外して取り替えることができるようにすることができる。これによりイオン交換樹脂の再生あるいは交換を取り外して容易に行うことができる。   FIG. 3 shows a configuration in which the pure water purification means 11 and the heavy metal ion removal means 15 are provided in parallel with the water circulation path. In addition, the structure connected with the processing tank shown by FIG. 1 is abbreviate | omitted also in FIG. In the figure, the water in the fresh water tank 3 is guided to the heavy metal ion removing means 15 by the pump 13a through the path 12c, the heavy metal ions are removed, and returns to the fresh water tank 3 through the path 14a. On the other hand, the water in the fresh water tank 3 is led to the pure water purification means 11 through the path 12c by the pump 13b and purified, and returns to the fresh water tank 3 through the path 14a. Of course, it can also be performed by branching of the pipe with one pump 13a. 2 and 3, the ion exchange means 11 and the heavy metal ion removal means 15 are in the shape of a cylinder or tank so that only these cylinders or tanks can be removed and replaced. be able to. Thereby, the regeneration or replacement of the ion exchange resin can be easily performed by removing it.

本発明を以下の実施例によりさらに説明するが、本発明はこれら実施例に限定されるものではない。   The present invention is further illustrated by the following examples, but the present invention is not limited to these examples.

実施例1
図1に示される基本構造を有するワイアー放電加工機(FANUC社製:180iS−WB)において、イミノジ酢酸官能基を有するポリスチレン樹脂を充填したイオン交換樹脂筒と、純水化のためのイオン交換樹脂筒とを並列に設置した。3ケ月間運転した後、加工槽、清水槽、その他水流路を観察したところ、緑青と思われる変色の発生は認められなかった。3か月の運転後の加工槽および清水槽における水中の銅イオン濃度を測定したところ、加工槽では0.07ppm、清水槽では検出限度(0.05ppm)以下であった。
Example 1
In a wire electric discharge machine (manufactured by FANUC: 180iS-WB) having the basic structure shown in FIG. 1, an ion exchange resin cylinder filled with a polystyrene resin having an iminodiacetic acid functional group, and an ion exchange resin for pure water purification The cylinder was installed in parallel. After operating for 3 months, the processing tank, fresh water tank, and other water flow paths were observed, and no discoloration considered to be patina was observed. When the copper ion concentration in the water in the processing tank and the fresh water tank after the operation for 3 months was measured, it was 0.07 ppm in the processing tank and below the detection limit (0.05 ppm) in the fresh water tank.

実施例2
図1に示される基本構造を有するワイアー放電加工機(FANUC社製:310iS−WA)において、イミノジ酢酸官能基を有するポリスチレン樹脂を充填したイオン交換樹脂筒と、純水化のためのイオン交換樹脂筒とを直列に設置した。6か月間運転した後、加工槽、清水槽、その他水流路を観察したところ、緑青と思われる変色の発生は認められなかった。6か月の運転後の清水槽における水中の銅イオン濃度を測定したところ、検出限度(0.05ppm)以下であった。なお、イミノジ酢酸官能基を有するポリスチレン樹脂を充填したイオン交換樹脂筒を設置せずに6か月間運転したときの清水槽における銅イオン濃度は0.11ppmであり、水と接触する箇所において緑青と思われる変色が観察された。
Example 2
In a wire electric discharge machine (manufactured by FANUC: 310iS-WA) having the basic structure shown in FIG. 1, an ion exchange resin cylinder filled with a polystyrene resin having an iminodiacetic acid functional group, and an ion exchange resin for pure water purification The cylinder was installed in series. After 6 months of operation, the processing tank, fresh water tank, and other water channels were observed, and no discoloration that seemed patina was observed. When the copper ion concentration in the water in the fresh water tank after 6 months of operation was measured, it was below the detection limit (0.05 ppm). In addition, the copper ion concentration in a fresh water tank when it operates for six months without installing the ion exchange resin cylinder filled with the polystyrene resin having an iminodiacetic acid functional group is 0.11 ppm. A possible discoloration was observed.

比較例
ワイアー放電加工機(FANUC社製:16−W)において、重金属イオンを捕捉するイオン交換樹脂筒を設けず、純水化のためのイオン交換樹脂筒を設置した状態で6ケ月間運転した。その後、加工槽、清水槽、その他水流路を観察したところ、緑青と思われる変色の発生が認められた。加工槽および清水槽における水中の銅イオン濃度を測定したところ、加工槽では0.26ppm、清水槽では0.07ppmであった。

In the comparative example wire electric discharge machine (manufactured by FANUC: 16-W), the ion exchange resin cylinder for capturing heavy metal ions was not provided, but the ion exchange resin cylinder for pure water was installed and operated for 6 months. . Thereafter, when the processing tank, fresh water tank, and other water flow paths were observed, the occurrence of discoloration considered to be patina was observed. When the copper ion concentration in the water in the processing tank and fresh water tank was measured, it was 0.26 ppm in the processing tank and 0.07 ppm in the fresh water tank.

Claims (10)

ワイアーと被加工物との間で放電を生じさせて、これにより被加工物の一部を除去して成形が行なわれるワイアー放電加工方法であって、
重金属イオンが除かれた水を、誘電体として前記ワイアーと前記被加工物との間に置くことを特徴とする、ワイアー放電加工方法。
A wire electric discharge machining method in which a discharge is generated between a wire and a workpiece, thereby removing a part of the workpiece and molding is performed.
A wire electric discharge machining method, wherein water from which heavy metal ions are removed is placed between the wire and the workpiece as a dielectric.
前記水を、前記ワイアーと前記被加工物との間に誘電体として置いた後、重金属イオンを除き、再び前記ワイアーと前記被加工物との間に置くよう循環させる、請求項1に記載のワイアー放電加工方法。   The water according to claim 1, wherein the water is placed as a dielectric between the wire and the workpiece and then circulated so as to remove heavy metal ions and again between the wire and the workpiece. Wire electric discharge machining method. 前記水をイオン交換樹脂と接触させることにより重金属イオンを除く、請求項1または2に記載のワイアー放電加工方法。   The wire electric discharge machining method according to claim 1 or 2, wherein heavy metal ions are removed by bringing the water into contact with an ion exchange resin. 前記イオン交換樹脂が、重金属イオンを捕捉可能なキレート構造を有するものである、請求項3に記載のワイアー放電加工方法。   The wire electric discharge machining method according to claim 3, wherein the ion exchange resin has a chelate structure capable of capturing heavy metal ions. 前記重金属イオンが、前記ワイアーまたは前記被加工物に含まれる重金属由来のイオンである、請求項1〜4のいずれか一項に記載のワイアー放電加工方法。   The wire electric discharge machining method according to any one of claims 1 to 4, wherein the heavy metal ions are ions derived from heavy metals contained in the wire or the workpiece. 前記重金属イオンが、銅、亜鉛、および鉄からなる群から選ばれるものである、請求項1〜5のいずれか一項に記載のワイアー放電加工方法。   The wire electric discharge machining method according to any one of claims 1 to 5, wherein the heavy metal ion is selected from the group consisting of copper, zinc, and iron. 請求項1〜6のいずれか一項に記載のワイアー放電加工方法を実施するための装置であって、
ワイアーと被加工物との間で放電を生じさせて、これにより被加工物の一部を除去して被加工物の成形を行うワイアー放電加工手段と、
誘電体として水を、前記ワイアーと前記被加工物との間に置く手段と、
前記水から重金属イオンを除去する重金属イオン除去手段と
を少なくとも備えてなることを特徴とする、ワイアー放電加工装置。
An apparatus for carrying out the wire electric discharge machining method according to any one of claims 1 to 6,
A wire electric discharge machining means for generating a discharge between the wire and the workpiece, thereby removing a part of the workpiece and forming the workpiece;
Means for placing water as a dielectric between the wire and the workpiece;
A wire electric discharge machining apparatus comprising at least heavy metal ion removing means for removing heavy metal ions from the water.
前記ワイアーと前記被加工物との間に誘電体として置かれた水を、前記重金属イオン除去手段に導入して重金属イオンを除き、その後再び前記ワイアーと前記被加工物との間に置くよう循環させる手段を備えてなる、請求項7に記載のワイアー放電加工装置。   Water placed as a dielectric between the wire and the workpiece is introduced into the heavy metal ion removing means to remove heavy metal ions, and then circulated again to be placed between the wire and the workpiece. The wire electric discharge machining apparatus according to claim 7, further comprising means for causing the wire to discharge. 前記重金属イオン除去手段がイオン交換樹脂である、請求項7または8に記載のワイアー放電加工装置。   The wire electric discharge machining apparatus according to claim 7 or 8, wherein the heavy metal ion removing means is an ion exchange resin. 前記イオン交換樹脂が、重金属イオンを捕捉可能なキレート構造を有するものである、請求項7〜9のいずれか一項に記載のワイアー放電加工装置。

The wire electric discharge machining apparatus according to any one of claims 7 to 9, wherein the ion exchange resin has a chelate structure capable of capturing heavy metal ions.

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JPH02292128A (en) * 1981-07-30 1990-12-03 Corning Glass Works Electric discharging process by wire
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JP2004000874A (en) * 2002-04-05 2004-01-08 Toyobo Co Ltd Filter apparatus for metal ions in solution
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JP2013099847A (en) * 2007-01-29 2013-05-23 Thermocompact Electrode wire for spark erosion

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4303704A (en) * 1980-05-19 1981-12-01 Courduvelis Constantine I Selective removal of copper or nickel from complexing agents in aqueous solution
JPH02292128A (en) * 1981-07-30 1990-12-03 Corning Glass Works Electric discharging process by wire
JPH07328621A (en) * 1994-06-08 1995-12-19 Matsushita Electric Ind Co Ltd Water purifier
JPH0889845A (en) * 1994-09-28 1996-04-09 Nec Corp Filter
JPH09196518A (en) * 1996-01-16 1997-07-31 Matsushita Electric Ind Co Ltd Refrigerating cycle
JP2002346838A (en) * 2001-05-21 2002-12-04 Gyoseisha:Kk Method and apparatus for maintaining purity of processing pure water in wire electric discharge machining, method and apparatus for wire electric discharge machining, method and apparatus for maintaining pure water, and method and electrode for electrolysis
JP2004000874A (en) * 2002-04-05 2004-01-08 Toyobo Co Ltd Filter apparatus for metal ions in solution
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US20100103764A1 (en) * 2008-10-27 2010-04-29 Industrial Technology Research Institute Working trough and method for maintaining uniform temperature of working fluid

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