JP2016015488A - 感光性のポルフィリン系染料、及び色素増感太陽電池 - Google Patents
感光性のポルフィリン系染料、及び色素増感太陽電池 Download PDFInfo
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- JP2016015488A JP2016015488A JP2015130977A JP2015130977A JP2016015488A JP 2016015488 A JP2016015488 A JP 2016015488A JP 2015130977 A JP2015130977 A JP 2015130977A JP 2015130977 A JP2015130977 A JP 2015130977A JP 2016015488 A JP2016015488 A JP 2016015488A
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- 150000004032 porphyrins Chemical class 0.000 title abstract description 14
- 238000006243 chemical reaction Methods 0.000 abstract description 10
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 1
- 230000000903 blocking effect Effects 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 18
- 239000003792 electrolyte Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000004065 semiconductor Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000003574 free electron Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229930002875 chlorophyll Natural products 0.000 description 2
- 235000019804 chlorophyll Nutrition 0.000 description 2
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000011712 cell development Effects 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000001443 photoexcitation Effects 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/008—Dyes containing a substituent, which contains a silicium atom
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
- H10K85/371—Metal complexes comprising a group IB metal element, e.g. comprising copper, gold or silver
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Inorganic Chemistry (AREA)
- Hybrid Cells (AREA)
- Photovoltaic Devices (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
Abstract
【課題】色素増感太陽電池のような光電変換装置に用いられるために適応される、感光性のポルフィリン系染料の提供。【解決手段】ポルフィリン中心、少なくとも１の電子供与体ユニット、少なくとも１の電子授与体ユニット、及び少なくとも１の遮断ユニットを有し、ここで各ユニットは直接ポルフィリン中心に接続され、又はエチニルブリッジを介してポルフィリン中心に接続される、感光性のポルフィリン系染料。【選択図】なし
Description
本願発明は、感光性のポルフィリン系染料に関し、特に、光電変換装置のための感光性のポルフィリン系染料に関する。本願発明は、また、色素増感太陽電池に関する。
近年、環境保護の意識が増加し、再生可能エネルギーの要求が増えている。様々な再生可能エネルギー源から、太陽エネルギーは化石燃料にとって代わる新たなエネルギー源として期待されており、というもの、枯渇のないクリーンエネルギーを供給するからである。太陽エネルギーは、汚染を生ずることなしに電気エネルギーに変換される。言い換えると、太陽エネルギーは最も有望な再生可能エネルギー源である。
一般に、太陽電池は、太陽エネルギーを電気エネルギーに変換するために使用される。従来の太陽電池は半導体材料より成る。特に、シリコンを用いる太陽電池は、市場の主流である。太陽電池の光電変換効率や対費用効果は徐々に改善される。しかしながら、従来の太陽電池の光電変換効率や対費用効果は未だ充分とは言えない。結果として、多くの学術施設及び製造業者が多くの努力を元の太陽電池の外形を改善することにつぎ込み、また、パフォーマンスを高め製造原価を減らすために新たな太陽電池の外形を探すことにつぎ込んでいる。例えば、色素増感太陽電池（ＤＳＳＣ）は、候補の太陽電池の一つであり、というのも、色素増感太陽電池の製造原価は、従来のシリコンを用いる太陽電池の製造原価の１／１０から１／５と低いためである。さらに、色素増感太陽電池を高圧の真空環境で製造する必要がないため、色素増感太陽電池の製造環境は従来の色素増感太陽電池より厳しくない。
色素増感太陽電池は、化学反応から生じる光電流を生成するための染料を用いた光増感剤の光励起を使うフォト電気化学システムである。一般的に、色素増感太陽電池は、基板、透明導電性フィルム、半導体フィルム、染料、電解質及び対電極を備える。動作原理は以下である。最初に、二酸化チタン又は酸化亜鉛の半導体フィルムが特別な光吸収染料を用いて塗布される。染料が日光に照らされるとき、染料の電子が基底状態から励起状態に励起される。励起電子は、自由電子となるために半導体フィルムの伝導体に挿入される。これらの自由電子は、半導体フィルムに接続された導電ガラス又は導電プラスティック（導電ポリマー）を通して流れ出る。その結果、電流が生成される。電解質は、染料とは別側に配置される。電子を失った染料の分子は、その元の状態に復帰するため、電解質から電子を受ける。それから、染料から流れ出る電子が経路を通り、電解質に接触する白金電極に至る。その結果、電解質はこれらの自由電子を受け取り、完全なループが形成される。色素増感太陽電池では、感光性の染料の塗布方法や構造が、光電変換効率及び色素増感太陽電池の安定性に影響するだろう。さらに、感光性の染料の選択は、色素増感太陽電池のコストに大いに関連し、太陽電池の発展の潜在性にも関連する。
有機の感光性の染料は、その高い吸収率、安易な修正、調節可能な光物理特性によって太陽電池の発展に貢献している。発明者は、ＵＳ出願の2010/0125136 A1において、感光性のポルフィリン系染料を記述した。ポルフィリンは、人工葉緑素と見なされる。葉緑素は、植物で見つけられる緑色素であり、例えば、二酸化炭素と水から酸素と炭水化物を生成する光合成を開始するために植物が光を吸収できるようにする。ポルフィリンは色素増感太陽電池の中で同じような役割を果たし、例えば、可視光や近赤外光のエネルギーを電気エネルギーに変換する。色素増感太陽電池の中でポルフィリン分子を使う利点は、二酸化チタンの利用、日光の幅広い吸収帯域、及び励起電子のより長い寿命に、励起電子の適切なエネルギーレベルを含む。しかしながら、ポルフィリンを使う従来の太陽電池は、充分な利点を得ていない。ポルフィリン分子は容易に集約され光電変換効率に影響することが分かっている。
従って、本願発明に示す貴重な感光性のポルフィリン系染料は、色素増感太陽電池のような光電変換装置のための感光性染料の特性を改善するために発展される。光電変換効率、太陽電池の安定性、合成の簡易性、コスト効果の間のバランスは色素増感太陽電池の商業的競争力を強化する。
色素増感太陽電池のような光電変換装置のための感光性のポルフィリン系染料が供される。感光性のポルフィリン系染料は以下の構造式を有する。
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW103122733A TWI474536B (zh) | 2014-07-01 | 2014-07-01 | 紫質光敏染料化合物以及染料敏化太陽能電池 |
| TW103122733 | 2014-07-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2016015488A true JP2016015488A (ja) | 2016-01-28 |
| JP6106217B2 JP6106217B2 (ja) | 2017-08-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015130977A Active JP6106217B2 (ja) | 2014-07-01 | 2015-06-30 | 感光性のポルフィリン系染料、及び色素増感太陽電池 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US9691555B2 (ja) |
| EP (1) | EP2977412A3 (ja) |
| JP (1) | JP6106217B2 (ja) |
| KR (1) | KR20160003566A (ja) |
| TW (1) | TWI474536B (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020007278A (ja) * | 2018-07-11 | 2020-01-16 | 地方独立行政法人東京都立産業技術研究センター | 新規なポルフィリン誘導体、ポルフィリン誘導体の製造方法、ドナー材料、光電変換装置、および光電変換装置の製造方法 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI565700B (zh) * | 2015-08-24 | 2017-01-11 | 臺灣塑膠工業股份有限公司 | 具有苝酸酐骨架的光敏染料、包含其的光敏染料混合物及染料敏化太陽能電池 |
| TWI589578B (zh) | 2016-04-13 | 2017-07-01 | Nat Chi Nan Univ | A compound with a bacterial chlorophyll backbone, with bacterial chlorophyll bones Frame of organic dyes |
| CN111187271B (zh) * | 2020-01-08 | 2021-05-14 | 华南理工大学 | 一种卟啉有机小分子受体材料及其制备方法和在有机太阳电池中的应用 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100125136A1 (en) * | 2008-11-17 | 2010-05-20 | Dc Solar Corp. A Taiwan Corporation | Porphyrin-based photosensitizer dyes for dye-sensitized solar cells |
| US20130090469A1 (en) * | 2011-10-05 | 2013-04-11 | National Chung Hsing University | Green zinc porphyrin sensitizers and their applications |
| CN103044952A (zh) * | 2013-01-04 | 2013-04-17 | 北京科技大学 | 一类不对称卟啉太阳能电池染料及其制备方法 |
| JP2013239312A (ja) * | 2012-05-14 | 2013-11-28 | Toyota Central R&D Labs Inc | 色素増感型太陽電池及び色素増感型太陽電池モジュール |
| JP2014165064A (ja) * | 2013-02-26 | 2014-09-08 | Rohm Co Ltd | 色素増感太陽電池およびその製造方法、および電子機器 |
| JP2014237743A (ja) * | 2013-06-06 | 2014-12-18 | 国立大学法人京都大学 | ポルフィリン錯体及び色素増感太陽電池 |
| WO2015005869A1 (en) * | 2013-07-08 | 2015-01-15 | Agency For Science, Technology And Research | Perylene functionalized porphyrin dyes for dye-sensitized solar cells |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5648485A (en) | 1994-10-26 | 1997-07-15 | University Of British Columbia | β, β-dihydroxy meso-substituted chlorins, isobacteriochlorins, and bacteriochlorins |
| US6943054B2 (en) | 2003-07-25 | 2005-09-13 | The Regents Of The University Of California | Attachment of organic molecules to group III, IV or V substrates |
| US7223628B2 (en) | 2003-07-25 | 2007-05-29 | The Regents Of The University Of California | High temperature attachment of organic molecules to substrates |
| US7582751B2 (en) | 2005-07-29 | 2009-09-01 | North Carolina State University | Methods and intermediates for the synthesis of porphyrins |
| US8907081B2 (en) | 2011-05-27 | 2014-12-09 | Sharp Laboratories Of America, Inc. | Long wavelength absorbing porphyrin photosensitizers for dye-sensitized solar cells |
-
2014
- 2014-07-01 TW TW103122733A patent/TWI474536B/zh not_active IP Right Cessation
- 2014-11-24 US US14/551,867 patent/US9691555B2/en active Active
-
2015
- 2015-06-24 EP EP15173501.6A patent/EP2977412A3/en not_active Withdrawn
- 2015-06-29 KR KR1020150092060A patent/KR20160003566A/ko not_active Application Discontinuation
- 2015-06-30 JP JP2015130977A patent/JP6106217B2/ja active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100125136A1 (en) * | 2008-11-17 | 2010-05-20 | Dc Solar Corp. A Taiwan Corporation | Porphyrin-based photosensitizer dyes for dye-sensitized solar cells |
| US20130090469A1 (en) * | 2011-10-05 | 2013-04-11 | National Chung Hsing University | Green zinc porphyrin sensitizers and their applications |
| JP2013239312A (ja) * | 2012-05-14 | 2013-11-28 | Toyota Central R&D Labs Inc | 色素増感型太陽電池及び色素増感型太陽電池モジュール |
| CN103044952A (zh) * | 2013-01-04 | 2013-04-17 | 北京科技大学 | 一类不对称卟啉太阳能电池染料及其制备方法 |
| JP2014165064A (ja) * | 2013-02-26 | 2014-09-08 | Rohm Co Ltd | 色素増感太陽電池およびその製造方法、および電子機器 |
| JP2014237743A (ja) * | 2013-06-06 | 2014-12-18 | 国立大学法人京都大学 | ポルフィリン錯体及び色素増感太陽電池 |
| WO2015005869A1 (en) * | 2013-07-08 | 2015-01-15 | Agency For Science, Technology And Research | Perylene functionalized porphyrin dyes for dye-sensitized solar cells |
Non-Patent Citations (6)
| Title |
|---|
| CHENG-HUA WU,ET AL.: "Porphyrins for efficient dye-sensitized solar cells covering the near-IR region", JOURNAL OF MATERIALS CHEMISTRY A, vol. 2, no. 4, JPN6016021159, 28 January 2014 (2014-01-28), pages 991 - 999, XP055228836, ISSN: 0003333178, DOI: 10.1039/C3TA14208F * |
| CHOU-POU HSIEH,ET AL.: "Synthesis and characterization of porphyrin sensitizers with various electron-donating substituents", JOURNAL OF MATERIALS CHEMISTRY, vol. 20, JPN6016021162, 2010, pages 1127 - 1134, XP002724947, ISSN: 0003333181, DOI: 10.1039/b919645e * |
| JIANFENG LU,ET AL.: "A cyclopenta[1,2-b:5,4-b']dithiophene-porphyrin conjugate for mesoscopic solar cells: a D-π-D-A app", PHYSICAL CHEMISTRY CHEMICAL PHYSICS, vol. 16, no. 45, JPN6016021164, 7 December 2014 (2014-12-07), pages 24755 - 24762, XP055228871, ISSN: 0003491333, DOI: 10.1039/C4CP03425B * |
| JIE LUO,ET AL.: "N-Annulated Perylene as An Efficient Electron Donor for Porphyrin-Based Dyes: Enhanced Light-Harvest", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 136, JPN6016021161, 28 January 2014 (2014-01-28), pages 265 - 272, XP055228860, ISSN: 0003333180, DOI: 10.1021/ja409291g * |
| TAKERU BESSHO,ET AL.: "Highly Efficient Mesoscopic Dye-Sensitized Solar Cells Based on Donor-Acceptor-Substituted Porphyri", ANGEW. CHEM. INT. ED., vol. 49, JPN6016021160, 2010, pages 6646 - 6649, ISSN: 0003333179 * |
| TERESA RIPOLLES-SANCHIS,ET AL.: "Design and characterization of alkoxy-wrapped push-pull porphyrins for dye-sensitized solar cells", CHEMICAL COMMUNICATION, vol. 48, JPN6016021163, 2012, pages 4368 - 4370, ISSN: 0003333182 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020007278A (ja) * | 2018-07-11 | 2020-01-16 | 地方独立行政法人東京都立産業技術研究センター | 新規なポルフィリン誘導体、ポルフィリン誘導体の製造方法、ドナー材料、光電変換装置、および光電変換装置の製造方法 |
| JP7062284B2 (ja) | 2018-07-11 | 2022-05-06 | 地方独立行政法人東京都立産業技術研究センター | 新規なポルフィリン誘導体、ポルフィリン誘導体の製造方法、ドナー材料、光電変換装置、および光電変換装置の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US9691555B2 (en) | 2017-06-27 |
| EP2977412A3 (en) | 2016-05-11 |
| US20160005546A1 (en) | 2016-01-07 |
| EP2977412A2 (en) | 2016-01-27 |
| TW201440288A (zh) | 2014-10-16 |
| JP6106217B2 (ja) | 2017-08-09 |
| KR20160003566A (ko) | 2016-01-11 |
| TWI474536B (zh) | 2015-02-21 |
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