JP2015525145A5 - - Google Patents
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- JP2015525145A5 JP2015525145A5 JP2015513130A JP2015513130A JP2015525145A5 JP 2015525145 A5 JP2015525145 A5 JP 2015525145A5 JP 2015513130 A JP2015513130 A JP 2015513130A JP 2015513130 A JP2015513130 A JP 2015513130A JP 2015525145 A5 JP2015525145 A5 JP 2015525145A5
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- curable film
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- 239000000758 substrate Substances 0.000 claims description 26
- 229920001577 copolymer Polymers 0.000 claims description 23
- 229920001651 Cyanoacrylate Polymers 0.000 claims description 16
- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl 2-cyanoacrylate Chemical compound COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 claims description 16
- 239000000178 monomer Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 9
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 239000000969 carrier Substances 0.000 claims description 8
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 7
- 239000004744 fabric Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N benzohydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 239000007779 soft material Substances 0.000 claims description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N Butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 3
- 240000008528 Hevea brasiliensis Species 0.000 claims description 3
- 239000005062 Polybutadiene Substances 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- 239000002174 Styrene-butadiene Substances 0.000 claims description 3
- 229920002725 Thermoplastic elastomer Polymers 0.000 claims description 3
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 239000011888 foil Substances 0.000 claims description 3
- 125000001072 heteroaryl group Chemical group 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 229920001194 natural rubber Polymers 0.000 claims description 3
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 3
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 3
- 229920002857 polybutadiene Polymers 0.000 claims description 3
- 229920001195 polyisoprene Polymers 0.000 claims description 3
- 229920000193 polymethacrylate Polymers 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 claims description 3
- 229920001289 polyvinyl ether Polymers 0.000 claims description 3
- 239000011115 styrene butadiene Substances 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 3
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 claims description 2
- LTYWEEUBKYARKZ-UHFFFAOYSA-N 2-phenylethyl 2-cyanoprop-2-enoate Chemical group N#CC(=C)C(=O)OCCC1=CC=CC=C1 LTYWEEUBKYARKZ-UHFFFAOYSA-N 0.000 claims description 2
- MIOPJNTWMNEORI-UHFFFAOYSA-N Camphorsulfonic acid Chemical compound C1CC2(CS(O)(=O)=O)C(=O)CC1C2(C)C MIOPJNTWMNEORI-UHFFFAOYSA-N 0.000 claims description 2
- 239000002313 adhesive film Substances 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 230000005693 optoelectronics Effects 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
- 239000004753 textile Substances 0.000 claims description 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 239000010408 film Substances 0.000 claims 20
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims 1
- 230000001070 adhesive Effects 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N acetic acid ethyl ester Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N Coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 206010073306 Exposure to radiation Diseases 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 238000000113 differential scanning calorimetry Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000003190 viscoelastic substance Substances 0.000 description 2
- 0 **OC(C(C#N)=C)=O Chemical compound **OC(C(C#N)=C)=O 0.000 description 1
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 1
- OLQIKGSZDTXODA-UHFFFAOYSA-N 4-[3-(4-hydroxy-2-methylphenyl)-1,1-dioxo-2,1$l^{6}-benzoxathiol-3-yl]-3-methylphenol Chemical compound CC1=CC(O)=CC=C1C1(C=2C(=CC(O)=CC=2)C)C2=CC=CC=C2S(=O)(=O)O1 OLQIKGSZDTXODA-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- JMXROTHPANUTOJ-UHFFFAOYSA-H Naphthol Green B Chemical compound [Na+].[Na+].[Na+].[Fe+3].C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21 JMXROTHPANUTOJ-UHFFFAOYSA-H 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000000111 anti-oxidant Effects 0.000 description 1
- 230000003078 antioxidant Effects 0.000 description 1
- 150000001746 carotenes Chemical class 0.000 description 1
- 235000005473 carotenes Nutrition 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- VOLSCWDWGMWXGO-UHFFFAOYSA-N cyclobuten-1-yl acetate Chemical compound CC(=O)OC1=CCC1 VOLSCWDWGMWXGO-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 230000003014 reinforcing Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
本発明は、粘着テープ、転写テープ、ラベル、ラミネートなどのような接着性物品を提供する。 The present invention provides an adhesive tape, transfer tape, labels, the adhesive article such as a laminate.
第１の態様において、本発明は、剥離基材および／または担体基材上の硬化性フィルムを含む物品であって、該フィルムは、
（ａ）式（Ｉ）：
で示される化合物から選択される少なくとも１種のシアノアクリレートモノマー；および
（ｂ）少なくとも１種のフィルム形成性（コ）ポリマー
を含む物品を提供する。
In a first aspect, the present invention is an article comprising a curable film on a release substrate and / or a carrier substrate, the film comprising:
(A) Formula (I):
An article comprising at least one cyanoacrylate monomer selected from the compounds represented by: and (b) at least one film-forming (co) polymer is provided.
本発明の物品に関し、該フィルムは、フィルムの総重量に基づいて：
（ａ）１５〜８０重量％の式（Ｉ）で示される化合物から選択される１種以上のシアノアクリレートモノマー；
（ｂ）２０〜８５重量％の１種以上のフィルム形成性（コ）ポリマー；および
（ｃ）０〜６５重量％の１種以上の添加剤
を含み得る。
With respect to the article of the invention, the film is based on the total weight of the film:
(A) 15 to 80% by weight of one or more cyanoacrylate monomers selected from compounds of formula (I);
(B) 20 to 85 wt% of one or more film-forming (co) polymer over; may include, and (c) one or more additives of 0 to 65 wt%.
有利に、本発明の接着性物品は無駄を回避し、最少量の反応性材料のみが使用され、ダイカッティングなどの予備切断のために、テープの長さから必要な形状を切り出すことができる。酢酸エチルで洗浄することにより、テープの残りを壁およびタイルから容易に除去することができる。これらの特徴のために、本発明の製品は多目的に使用可能であり、望ましい。 Advantageously, the adhesive article of the present invention avoids waste, uses only a minimum amount of reactive material, and can cut out the required shape from the length of the tape for pre-cutting such as die cutting. By washing with ethyl acetate, the remainder of the tape can be easily removed from the walls and tiles. Because of these features, the products of the present invention are versatile and desirable.
２つのフィルム層間の担体基材は、紙、ポリマー性フィルム、金属箔、発泡体、布、粘弾性材料およびそれらの組合せから選択され得る。粘弾性材料の例は、ポリ（メタ）アクリレート、ポリビニルエーテル、天然ゴム、ポリイソプレン、ポリブタジエン、ポリイソブチレン、ポリクロロプレン、ブタジエンアクリロニトリルポリマー、熱可塑性エラストマー、スチレン-イソプレン、スチレン-イソプレン-スチレンブロックコポリマー、エチレン-プロピレン-ジエンポリマー、スチレン-ブタジエンポリマー、ポリ-α-オレフィン、シリコーン、エチレン含有コポリマー、エチレンビニルアセテートおよび／またはそれらの組合せであり得る。担体基材は、粘着剤、可塑剤、強化剤、酸化防止剤、安定剤、吸水剤および／またはそれらの組合せを含み得る。担体基材はこれらの材料を発泡させた形態であってもよい。 The carrier substrate between the two film layers may be selected from paper, polymeric film, metal foil, foam, fabric, viscoelastic material and combinations thereof. Examples of viscoelastic materials are poly (meth) acrylate, polyvinyl ether, natural rubber, polyisoprene, polybutadiene, polyisobutylene, polychloroprene, butadiene acrylonitrile polymer, thermoplastic elastomer, styrene-isoprene, styrene-isoprene-styrene block copolymer, It can be an ethylene-propylene-diene polymer, styrene-butadiene polymer, poly-α-olefin, silicone, ethylene-containing copolymer, ethylene vinyl acetate and / or combinations thereof. The carrier substrate can include an adhesive , a plasticizer, a toughener, an antioxidant, a stabilizer, a water absorbing agent, and / or combinations thereof. The carrier substrate may be in the form of foaming these materials.
別の態様に関して明確性のために記載される本発明の特定の特徴は、１つの態様における組合せをも提供し得ることが望ましい。逆に言えば、１つの態様に関して簡潔さのために記載される本発明の種々の特徴は、別々に、または任意の適当な部分的組合せにおいても供され得る。
本明細書の当初の開示は、少なくとも下記の態様を包含する。
〔１〕剥離基材および／または担体基材上の硬化性フィルムを含む物品であって、該硬化性フィルムは：
（ａ）式（Ｉ）：
で示される化合物から選択される少なくとも１種のシアノアクリレートモノマー；および
（ｂ）少なくとも１種のフィルム形成性（コ）ポリマー
を含む、物品。
〔２〕前記シアノアクリレートモノマーは、式（ＩＩ）：
で示される化合物から選択される、前記〔１〕に記載の物品。
〔３〕前記シアノアクリレートモノマーは１０１３.２５ｍｂａｒで２５℃より高い融点を有する、前記〔１〕または〔２〕に記載の物品。
〔４〕前記シアノアクリレートモノマーは（２-フェニルエチル）２-シアノアクリレートである、前記〔１〕〜〔３〕のいずれかに記載の物品。
〔５〕前記シアノアクリレートモノマーは、硬化性フィルムの総重量に基づいて少なくとも約１５重量％の量で存在する、前記〔１〕〜〔４〕のいずれかに記載の物品。
〔６〕前記シアノアクリレートモノマーは、硬化性フィルムの総重量に基づいて約２０重量％〜約８０重量％の量で存在する、前記〔１〕〜〔５〕のいずれかに記載の物品。
〔７〕前記フィルム形成性（コ）ポリマーは、ポリ（メタ）アクリレート（コ）ポリマー、ポリビニルエーテル、天然ゴム、ポリイソプレン、ポリブタジエン、ポリイソブチレン、ポリクロロプレン；ブタジエン-アクリロニトリルポリマー、熱可塑性エラストマー、スチレン-イソプレンコポリマー、スチレン-イソプレン-スチレンブロックコポリマー、エチレン-プロピレン-ジエンポリマー、スチレン-ブタジエンポリマー、ポリ-α-オレフィン、シリコーン、エチレンビニルアセテートコポリマーおよび／またはそれらの組合せから選択される、前記〔１〕〜〔６〕のいずれかに記載の物品。
〔８〕前記フィルム形成性（コ）ポリマーは、示差走査熱量測定（ＤＳＣ）で測定して３０℃より低いガラス転移温度（Ｔ ｇ ）を有する、前記〔１〕〜〔７〕のいずれかに記載の物品。
〔９〕前記フィルム形成性（コ）ポリマーは２３℃で感圧接着性を有する（コ）ポリマーである、前記〔１〕〜〔８〕のいずれかに記載の物品。
〔１０〕前記フィルム形成性（コ）ポリマーは、（メタ）アクリル酸、（メタ）アクリル酸エステルおよび場合により他のコモノマーのコポリマーである、前記〔１〕〜〔９〕のいずれかに記載の物品。
〔１１〕前記フィルム形成性（コ）ポリマーは約０〜約３０の酸価を有する、前記〔１〕〜〔１０〕のいずれかに記載の物品。
〔１２〕前記フィルム形成性（コ）ポリマーはエチレンビニルアセテートコポリマーである、前記〔１〕〜〔８〕のいずれかに記載の物品。
〔１３〕前記エチレンビニルアセテートコポリマーは、エチレンビニルアセテートコポリマーの総重量に基づいて５０重量％〜９８重量％のビニルアセテート含量を有する、前記〔１２〕に記載の物品。
〔１４〕前記フィルム形成性（コ）ポリマーは、硬化性フィルムの総重量に基づいて約２０重量％〜約８５重量％の量で存在する、前記〔１〕〜〔１３〕のいずれかに記載の物品。
〔１５〕硬化性フィルム中、シアノアクリレートモノマーの総量：フィルム形成性（コ）ポリマーの総量の重量比は、１：８〜８：１である、前記〔１〕〜〔１４〕のいずれかに記載の物品。
〔１６〕前記硬化性フィルムは、シアノアクリレートポリマー、粘着剤、可塑剤、強化剤、酸化防止剤、安定剤、吸水剤および／またはそれらの組合せから選択される１種以上の添加剤をさらに含む、前記〔１〕〜〔１５〕のいずれかに記載の物品。
〔１７〕前記硬化性フィルムは、硬化性フィルムの総重量に基づいて１重量％以下の量で存在する安定剤をさらに含む、前記〔１〕〜〔１６〕のいずれかに記載の物品。
〔１８〕前記安定剤は、場合によりヒドロキノン、スルホン酸、ＢＦ ３ またはＳＯ ２ 、ホウ酸、亜鉛塩、リン酸、カルボン酸またはそれらの組合せの１種である、前記〔１７〕に記載の物品。
〔１９〕前記硬化性フィルムはカンファースルホン酸などの酸をさらに含む、前記〔１〕〜〔１８〕のいずれかに記載の物品。
〔２０〕酸は硬化性フィルムの総重量に基づいて１重量％以下の量で存在する、前記〔１〕〜〔１９〕のいずれかに記載の物品。
〔２１〕前記硬化性フィルムは染料をさらに含む前記〔１〕〜〔２０〕のいずれかに記載の物品であって、該染料は、ナフトールグリーン、クマリン、カロテン、ｍ-クレゾールパープル、Ｃｕ（ＩＩ）フタロシアニンからなる群から任意に選択される、物品。
〔２２〕前記染料は硬化性フィルムの総重量に基づいて約０重量％〜約１０重量％の量で存在する、前記〔２１〕に記載の物品。
〔２３〕前記硬化性フィルムは、動的機械分析（ＤＭＡ）により１Ｈｚおよび２３℃で測定して、約３.３×１０５Ｐａ以下の貯蔵弾性率Ｇ`を有する、前記〔１〕〜〔２２〕のいずれかに記載の物品。
〔２４〕前記硬化性フィルムは、ＤＩＮ ＥＮ １７１９により測定される標準ループタック試験において、少なくとも約３Ｎのタック値を有する、前記〔１〕〜〔２３〕のいずれかに記載の物品。
〔２５〕前記硬化性フィルムは、ＤＩＮ ＥＮ １９３９により、スチール基材上、２３℃で測定して１０分後に、約３Ｎ／２５ｍｍ〜約５０Ｎ／２５ｍｍの１８０°剥離強度を有する、前記〔１〕〜〔２４〕のいずれかに記載の物品。
〔２６〕前記硬化性フィルムは、示差走査熱量測定（ＤＳＣ）により測定して１０℃より低いガラス転移温度（Ｔ ｇ ）を有する、前記〔１〕〜〔２５〕のいずれかに記載の物品。
〔２７〕前記担体基材は、ポリマーフィルム、発泡体、金属箔、布およびそれらの組合せから選択される、前記〔１〕〜〔２６〕のいずれかに記載の物品。
〔２８〕前記剥離基材は、場合により剥離剤で被覆された紙またはプラスチック系材料である、前記〔１〕〜〔２７〕のいずれかに記載の物品。
〔２９〕前記物品は、ラベル、片面テープ、転写テープまたは両面テープである、前記〔１〕〜〔２８〕のいずれかに記載の物品。
〔３０〕硬化性フィルムの硬化物は約１.４５〜約１.６の範囲（好ましくは約１.４７〜約１.５５の範囲）の屈折率を有する、前記〔１〕〜〔２９〕のいずれかに記載の物品。
〔３１〕硬化性フィルムの硬化物は半透明、例えば透明である、前記〔１〕〜〔３０〕のいずれかに記載の物品。
〔３２〕前記〔１〕〜〔３１〕のいずれかに記載の硬化性フィルムの硬化物。
〔３３〕前記硬化性フィルムは、以下の条件：熱暴露、湿分暴露または放射暴露の任意の１つにより硬化可能である、前記〔１〕〜〔３１〕のいずれかに記載の物品。
〔３４〕前記硬化性フィルムは、約０〜２００℃の範囲の温度に２〜３６０秒間暴露することにより硬化可能である、前記〔１〕〜〔３３〕のいずれかに記載の物品。
〔３５〕前記硬化性フィルムは、約１０〜１００％の範囲の湿度に１〜２４時間暴露することにより硬化可能である、前記〔１〕〜〔３３〕のいずれかに記載の物品。
〔３６〕前記硬化性フィルムは、放射、例えばＵＶ放射に暴露することにより硬化可能である、前記〔１〕〜〔３３〕のいずれかに記載の物品。
〔３７〕次のステップ：
（ａ）前記〔１〕〜〔３１〕のいずれかに記載の物品を提供すること；
（ｂ）該物品の硬化性フィルムを少なくとも１つの表面に付着させて組立品を形成すること；
（ｃ）該物品の硬化性フィルムを硬化するのに十分な条件に該組立品を暴露することを含み、ここで、該物品の剥離基材は、存在する場合、ステップ（ｂ）の前および／または後で取り除かれる、硬化性表面へのフィルムの付着方法。
〔３８〕光電子デバイスの製造における前記〔１〕〜〔３１〕のいずれかに記載の物品の使用。
〔３９〕第１基材の第２基材への接着方法であって、該方法は以下：
（ｉ）前記〔１〕〜〔３１〕のいずれかに記載の物品を提供すること；
（ｉｉ）該物品の硬化性フィルムを少なくとも１つの基材に付着させること；
（ｉｉｉ）該基材を合わせること；および
（ｉｉｉ）互いに接着するように該部品間の粘着性フィルムを硬化させること
を含み、ここで、該物品の剥離基材は、存在する場合、ステップ（ｉｉ）の前および／または後で取り除かれる、方法。
〔４０〕少なくとも１つの基材は軟質材料を含む、前記〔３９〕に記載の方法。
〔４１〕前記軟質材料は少なくとも１つの編織物、繊維製品、布、シート材料、プラスチックおよびそれらの組合せである、前記〔４０〕に記載の方法。
It will be appreciated that certain features of the invention described for clarity with respect to another aspect may also provide a combination in one aspect. Conversely, the various features of the invention described for brevity with respect to one aspect may be provided separately or in any suitable subcombination.
The initial disclosure herein includes at least the following embodiments.
[1] An article comprising a curable film on a release substrate and / or carrier substrate, the curable film comprising:
(A) Formula (I):
At least one cyanoacrylate monomer selected from the compounds represented by:
(B) at least one film-forming (co) polymer
Including an article.
[2] The cyanoacrylate monomer has the formula (II):
The article according to [1], which is selected from the compounds represented by:
[3] The article according to [1] or [2], wherein the cyanoacrylate monomer has a melting point higher than 25 ° C. at 1013.25 mbar.
[4] The article according to any one of [1] to [3], wherein the cyanoacrylate monomer is (2-phenylethyl) 2-cyanoacrylate.
[5] The article of any one of [1] to [4], wherein the cyanoacrylate monomer is present in an amount of at least about 15% by weight based on the total weight of the curable film.
[6] The article according to any one of [1] to [5], wherein the cyanoacrylate monomer is present in an amount of about 20 wt% to about 80 wt% based on the total weight of the curable film.
[7] The film-forming (co) polymer is poly (meth) acrylate (co) polymer, polyvinyl ether, natural rubber, polyisoprene, polybutadiene, polyisobutylene, polychloroprene; butadiene-acrylonitrile polymer, thermoplastic elastomer, styrene [1] selected from -isoprene copolymers, styrene-isoprene-styrene block copolymers, ethylene-propylene-diene polymers, styrene-butadiene polymers, poly-α-olefins, silicones, ethylene vinyl acetate copolymers and / or combinations thereof. ] The article according to any one of [6].
[8] The film-forming (co) polymer has a glass transition temperature (T g ) lower than 30 ° C. as measured by differential scanning calorimetry (DSC), according to any one of the above [1] to [7] The article described.
[9] The article according to any one of [1] to [8], wherein the film-forming (co) polymer is a (co) polymer having a pressure-sensitive adhesive property at 23 ° C.
[10] The film-forming (co) polymer according to any one of the above [1] to [9], which is a copolymer of (meth) acrylic acid, (meth) acrylic acid ester and optionally another comonomer. Goods.
[11] The article according to any one of [1] to [10], wherein the film-forming (co) polymer has an acid value of about 0 to about 30.
[12] The article according to any one of [1] to [8], wherein the film-forming (co) polymer is an ethylene vinyl acetate copolymer.
[13] The article according to [12], wherein the ethylene vinyl acetate copolymer has a vinyl acetate content of 50 wt% to 98 wt% based on the total weight of the ethylene vinyl acetate copolymer.
[14] The film-forming (co) polymer is present in any of [1] to [13], wherein the film-forming (co) polymer is present in an amount of about 20 wt% to about 85 wt% based on the total weight of the curable film. Goods.
[15] The weight ratio of the total amount of cyanoacrylate monomer to the total amount of film-forming (co) polymer in the curable film is 1: 8 to 8: 1, any one of [1] to [14] The article described.
[16] The curable film further includes one or more additives selected from cyanoacrylate polymers, pressure-sensitive adhesives, plasticizers, reinforcing agents, antioxidants, stabilizers, water-absorbing agents, and / or combinations thereof. The article according to any one of [1] to [15].
[17] The article according to any one of [1] to [16], wherein the curable film further includes a stabilizer present in an amount of 1% by weight or less based on the total weight of the curable film.
[18] The article according to [17], wherein the stabilizer is optionally one of hydroquinone, sulfonic acid, BF 3 or SO 2 , boric acid, zinc salt, phosphoric acid, carboxylic acid, or a combination thereof. .
[19] The article according to any one of [1] to [18], wherein the curable film further contains an acid such as camphorsulfonic acid.
[20] The article according to any one of [1] to [19], wherein the acid is present in an amount of 1% by weight or less based on the total weight of the curable film.
[21] The article according to any one of [1] to [20], wherein the curable film further contains a dye, and the dye includes naphthol green, coumarin, carotene, m-cresol purple, Cu (II ) Articles arbitrarily selected from the group consisting of phthalocyanines.
[22] The article of [21], wherein the dye is present in an amount of about 0% to about 10% by weight based on the total weight of the curable film.
[23] The [1] to [22], wherein the curable film has a storage elastic modulus G ′ of about 3.3 × 10 5 Pa or less as measured by dynamic mechanical analysis (DMA) at 1 Hz and 23 ° C. The article according to any one of the above.
[24] The article according to any one of [1] to [23], wherein the curable film has a tack value of at least about 3N in a standard loop tack test measured according to DIN EN 1719.
[25] The curable film has a 180 ° peel strength of about 3 N / 25 mm to about 50 N / 25 mm after 10 minutes as measured at 23 ° C. on a steel substrate according to DIN EN 1939, [1] To [24].
[26] The curable film has a differential scanning calorimetry (DSC) by measurement to 10 ° C. lower than the glass transition temperature (T g), article according to any one of [1] to [25].
[27] The article according to any one of [1] to [26], wherein the carrier substrate is selected from a polymer film, a foam, a metal foil, a cloth, and a combination thereof.
[28] The article according to any one of [1] to [27], wherein the release substrate is paper or a plastic material optionally coated with a release agent.
[29] The article according to any one of [1] to [28], wherein the article is a label, a single-sided tape, a transfer tape, or a double-sided tape.
[30] The cured product of the curable film has a refractive index in the range of about 1.45 to about 1.6 (preferably in the range of about 1.47 to about 1.55). The article according to any one of the above.
[31] The article according to any one of [1] to [30], wherein the cured product of the curable film is translucent, for example, transparent.
[32] A cured product of the curable film according to any one of [1] to [31].
[33] The article according to any one of [1] to [31], wherein the curable film can be cured by any one of the following conditions: heat exposure, moisture exposure, or radiation exposure.
[34] The article according to any one of [1] to [33], wherein the curable film is curable by exposure to a temperature in a range of about 0 to 200 ° C for 2 to 360 seconds.
[35] The article according to any one of [1] to [33], wherein the curable film is curable by exposure to humidity in a range of about 10 to 100% for 1 to 24 hours.
[36] The article according to any one of [1] to [33], wherein the curable film is curable by exposure to radiation, for example, UV radiation.
[37] Next steps:
(A) providing the article according to any one of [1] to [31];
(B) attaching the curable film of the article to at least one surface to form an assembly;
(C) exposing the assembly to conditions sufficient to cure the curable film of the article, wherein the release substrate of the article, if present, before step (b) and A method of attaching a film to a curable surface, which is removed later.
[38] Use of the article according to any one of [1] to [31] in the manufacture of an optoelectronic device.
[39] A method of adhering the first base material to the second base material, the method being as follows:
(I) providing the article according to any one of [1] to [31];
(Ii) attaching the curable film of the article to at least one substrate;
(Iii) combining the substrates; and
(Iii) curing the adhesive film between the parts to adhere to each other
Wherein the release substrate of the article, if present, is removed before and / or after step (ii).
[40] The method according to [39], wherein the at least one substrate includes a soft material.
[41] The method according to [40], wherein the soft material is at least one knitted fabric, textile, fabric, sheet material, plastic, and combinations thereof.
Claims (23)
（ａ）式（Ｉ）：
で示される化合物から選択される少なくとも１種のシアノアクリレートモノマー；および
（ｂ）少なくとも１種のフィルム形成性（コ）ポリマー
を含む、物品。 An article comprising a curable film on a release substrate and / or carrier substrate, wherein the curable film is:
(A) Formula (I):
An article comprising at least one cyanoacrylate monomer selected from the compounds represented by: and (b) at least one film-forming (co) polymer.
で示される化合物から選択される、請求項１に記載の物品。 The cyanoacrylate monomer has the formula (II):
The article of claim 1, wherein the article is selected from the compounds represented by:
（ａ）請求項１〜１５のいずれかに記載の物品を提供すること；
（ｂ）該物品の硬化性フィルムを少なくとも１つの表面に付着させて組立品を形成すること；
（ｃ）該物品の硬化性フィルムを硬化するのに十分な条件に該組立品を暴露することを含み、ここで、該物品の剥離基材は、存在する場合、ステップ（ｂ）の前および／または後で取り除かれる、硬化性表面へのフィルムの付着方法。 Next steps:
(A) providing the article according to any one of claims 1 to 15 ;
(B) attaching the curable film of the article to at least one surface to form an assembly;
(C) exposing the assembly to conditions sufficient to cure the curable film of the article, wherein the release substrate of the article, if present, before step (b) and A method of attaching a film to a curable surface, which is removed later.
（ｉ）請求項１〜１５のいずれかに記載の物品を提供すること；
（ｉｉ）該物品の硬化性フィルムを少なくとも１つの基材に付着させること；
（ｉｉｉ）該基材を合わせること；および
（ｉｉｉ）互いに接着するように該部品間の粘着性フィルムを硬化させること
を含み、ここで、該物品の剥離基材は、存在する場合、ステップ（ｉｉ）の前および／または後で取り除かれる、方法。 A method for adhering a first substrate to a second substrate, the method comprising:
(I) providing an article according to any one of claims 1 to 15 ;
(Ii) attaching the curable film of the article to at least one substrate;
(Iii) combining the substrates; and (iii) curing the adhesive film between the parts to adhere to each other, wherein the release substrate of the article, if present, includes the step ( a method which is removed before and / or after ii).
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2012/059630 WO2013174430A1 (en) | 2012-05-23 | 2012-05-23 | An article comprising a film on a carrier or release substrate |
| EPPCT/EP2012/059630 | 2012-05-23 | ||
| PCT/EP2013/060340 WO2013174776A1 (en) | 2012-05-23 | 2013-05-20 | An article comprising a film on a carrier or release substrate |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015525145A JP2015525145A (en) | 2015-09-03 |
| JP2015525145A5 true JP2015525145A5 (en) | 2016-07-07 |
| JP6204461B2 JP6204461B2 (en) | 2017-09-27 |
Family
ID=48468316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015513130A Active JP6204461B2 (en) | 2012-05-23 | 2013-05-20 | Article comprising a film on a support or release substrate |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JP6204461B2 (en) |
| KR (1) | KR102116588B1 (en) |
| CN (1) | CN104540912B8 (en) |
| BR (1) | BR112014028792A2 (en) |
| ES (1) | ES2640050T3 (en) |
| TW (1) | TWI582194B (en) |
| WO (2) | WO2013174430A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8877868B2 (en) * | 2013-02-26 | 2014-11-04 | Henkel IP & Holding GmbH | Hot melt adhesive comprising cyanoacrylate curing compounds |
| DE102015115717B4 (en) | 2015-09-17 | 2022-12-08 | Lohmann Gmbh & Co. Kg | Asymmetric adhesive film with a force decoupling function and use |
| CN105368330B (en) * | 2015-11-23 | 2018-11-27 | 绍兴市上虞舜东橡塑制品有限公司 | A kind of a-cyanoacrylate heat-conducting glue and preparation method thereof |
| JP2017177315A (en) * | 2016-03-31 | 2017-10-05 | デクセリアルズ株式会社 | Method for cutting adhesive film, adhesive film, and wound body |
| DE102016207075A1 (en) | 2016-04-26 | 2017-10-26 | Tesa Se | Repositionable moisture-curing adhesive tape |
| DE102016007914A1 (en) | 2016-06-30 | 2018-01-04 | Lohmann Gmbh & Co. Kg | Thermally activatable latently reactive adhesive film |
| CN110573985A (en) * | 2017-04-14 | 2019-12-13 | 惠普发展公司，有限责任合伙企业 | Substrate encapsulated by energy absorbing material |
| CN108452369B (en) * | 2018-06-21 | 2021-02-09 | 浙江派菲特新材料科技有限公司 | Preparation method of medical adhesive with high antibacterial performance |
| CN110964458B (en) * | 2019-12-23 | 2020-12-15 | 苏州世华新材料科技股份有限公司 | Preparation method of bio-based acrylate anti-warping adhesive tape |
| BR112022022901A2 (en) * | 2020-06-23 | 2023-01-03 | Akzo Nobel Coatings Int Bv | RADIATION CURABLE COATING COMPOSITION, METHOD OF COATING A SUBSTRATE AND COATED SUBSTRATE |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3728375A (en) * | 1971-05-12 | 1973-04-17 | Eastman Kodak Co | Cyanoacrylate adhesive compositions |
| US4440910A (en) * | 1982-01-18 | 1984-04-03 | Loctite Corporation | Toughened cyanoacrylates containing elastomeric rubbers |
| JPS59145271A (en) * | 1983-02-05 | 1984-08-20 | Taoka Chem Co Ltd | Adhesive composition |
| JPH0491069A (en) | 1990-08-07 | 1992-03-24 | Three Bond Co Ltd | New alpha-cyanoacrylate and adhesive composition |
| JPH06192202A (en) | 1992-10-13 | 1994-07-12 | Toagosei Chem Ind Co Ltd | 2-cyanoacrylate |
| US5677376A (en) * | 1994-01-14 | 1997-10-14 | Minnesota Mining And Manufacturing Company | Acrylate-containing polymer blends |
| US5902443A (en) * | 1997-01-28 | 1999-05-11 | Toagosei America, Inc. | Method for bonding with cyanoacrylate adhesive |
| IES990974A2 (en) * | 1998-11-23 | 2000-05-31 | Loctite R & D Ltd | Cyanoacrylate Compositions |
| US6475331B1 (en) * | 2001-06-26 | 2002-11-05 | Henkel Loctite Corporation | Cyanoacrylate compositions |
| EP2121777B1 (en) * | 2007-03-09 | 2011-04-20 | Henkel Corporation | Cyanoacrylate compositions incorporating graphite platelets |
| JP2010059405A (en) * | 2008-08-07 | 2010-03-18 | Three Bond Co Ltd | Cyanoacrylate-based adhesive composition |
| GB2463065B (en) * | 2008-09-01 | 2012-11-07 | Loctite R & D Ltd | Transferable curable non-liquid film on a release substrate |
| KR101573966B1 (en) * | 2008-09-26 | 2015-12-02 | 헨켈 아이피 앤드 홀딩 게엠베하 | Cyanoacrylate compositions in non-flowable forms |
| DE102008056980A1 (en) | 2008-11-12 | 2010-05-20 | Tesa Se | Radiation crosslinkable, foamed self-adhesive based on vinylaromatic block copolymers |
| DE102008062368A1 (en) | 2008-12-17 | 2010-06-24 | Tesa Se | Pressure-sensitive adhesives based on natural rubber and polyacrylates |
| CN101928541B (en) * | 2010-05-19 | 2012-07-04 | 江苏和成化学材料有限公司 | UV curable adhesive |
| JP5528285B2 (en) | 2010-10-01 | 2014-06-25 | 日東電工株式会社 | Adhesive sheet |
| JP5658976B2 (en) | 2010-11-05 | 2015-01-28 | 日東電工株式会社 | Double-sided adhesive tape and polishing member |
-
2012
- 2012-05-23 WO PCT/EP2012/059630 patent/WO2013174430A1/en active Application Filing
-
2013
- 2013-05-20 TW TW102117706A patent/TWI582194B/en active
- 2013-05-20 ES ES13723791.3T patent/ES2640050T3/en active Active
- 2013-05-20 KR KR1020147032689A patent/KR102116588B1/en active IP Right Grant
- 2013-05-20 CN CN201380026458.8A patent/CN104540912B8/en active Active
- 2013-05-20 JP JP2015513130A patent/JP6204461B2/en active Active
- 2013-05-20 BR BR112014028792A patent/BR112014028792A2/en not_active Application Discontinuation
- 2013-05-20 WO PCT/EP2013/060340 patent/WO2013174776A1/en active Application Filing
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