JP2015227260A - 爆轟法による炭素粒子の製造方法 - Google Patents
爆轟法による炭素粒子の製造方法 Download PDFInfo
- Publication number
- JP2015227260A JP2015227260A JP2014113057A JP2014113057A JP2015227260A JP 2015227260 A JP2015227260 A JP 2015227260A JP 2014113057 A JP2014113057 A JP 2014113057A JP 2014113057 A JP2014113057 A JP 2014113057A JP 2015227260 A JP2015227260 A JP 2015227260A
- Authority
- JP
- Japan
- Prior art keywords
- explosive
- substance
- detonation
- raw material
- carbon particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 92
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 92
- 239000002245 particle Substances 0.000 title claims abstract description 65
- 238000000034 method Methods 0.000 title claims abstract description 32
- 239000002994 raw material Substances 0.000 claims abstract description 48
- 239000007788 liquid Substances 0.000 claims abstract description 30
- 150000001491 aromatic compounds Chemical class 0.000 claims abstract description 17
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims abstract description 15
- 239000002360 explosive Substances 0.000 claims description 107
- 239000000126 substance Substances 0.000 claims description 53
- 238000005474 detonation Methods 0.000 claims description 50
- 238000004519 manufacturing process Methods 0.000 claims description 36
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 32
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 claims description 27
- 239000000015 trinitrotoluene Substances 0.000 claims description 26
- 239000002826 coolant Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 14
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims description 11
- UZGLIIJVICEWHF-UHFFFAOYSA-N octogen Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 UZGLIIJVICEWHF-UHFFFAOYSA-N 0.000 claims description 10
- 239000012298 atmosphere Substances 0.000 claims description 6
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 claims description 6
- RAESLDWEUUSRLO-UHFFFAOYSA-O aminoazanium;nitrate Chemical compound [NH3+]N.[O-][N+]([O-])=O RAESLDWEUUSRLO-UHFFFAOYSA-O 0.000 claims description 5
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 4
- AGUIVNYEYSCPNI-UHFFFAOYSA-N N-methyl-N-picrylnitramine Chemical compound [O-][N+](=O)N(C)C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O AGUIVNYEYSCPNI-UHFFFAOYSA-N 0.000 claims description 4
- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Tetranitrate Chemical compound [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 claims description 4
- 229910001882 dioxygen Inorganic materials 0.000 claims description 4
- 239000007800 oxidant agent Substances 0.000 claims description 4
- 239000000026 Pentaerythritol tetranitrate Substances 0.000 claims description 3
- 229960004321 pentaerithrityl tetranitrate Drugs 0.000 claims description 3
- 239000010432 diamond Substances 0.000 abstract description 49
- 229910003460 diamond Inorganic materials 0.000 abstract description 48
- 239000000463 material Substances 0.000 abstract description 25
- 238000004880 explosion Methods 0.000 description 37
- 238000001816 cooling Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000002441 X-ray diffraction Methods 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000002113 nanodiamond Substances 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 239000010703 silicon Substances 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- -1 Composition B Chemical compound 0.000 description 6
- 239000000028 HMX Substances 0.000 description 6
- 238000011088 calibration curve Methods 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000004925 Acrylic resin Substances 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000004445 quantitative analysis Methods 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical class 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000013558 reference substance Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- UPSVYNDQEVZTMB-UHFFFAOYSA-N 2-methyl-1,3,5-trinitrobenzene;1,3,5,7-tetranitro-1,3,5,7-tetrazocane Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O.[O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 UPSVYNDQEVZTMB-UHFFFAOYSA-N 0.000 description 1
- ZCSHACFHMFHFKK-UHFFFAOYSA-N 2-methyl-1,3,5-trinitrobenzene;2,4,6-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)C1NC([N+]([O-])=O)NC([N+]([O-])=O)N1.CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O ZCSHACFHMFHFKK-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 235000002905 Rumex vesicarius Nutrition 0.000 description 1
- 244000207667 Rumex vesicarius Species 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004200 deflagration Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000012377 drug delivery Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/25—Diamond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/06—Processes using ultra-high pressure, e.g. for the formation of diamonds; Apparatus therefor, e.g. moulds or dies
- B01J3/062—Processes using ultra-high pressure, e.g. for the formation of diamonds; Apparatus therefor, e.g. moulds or dies characterised by the composition of the materials to be processed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/06—Processes using ultra-high pressure, e.g. for the formation of diamonds; Apparatus therefor, e.g. moulds or dies
- B01J3/08—Application of shock waves for chemical reactions or for modifying the crystal structure of substances
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/25—Diamond
- C01B32/26—Preparation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Description
X線回折(XRD)の測定結果から、2θ=75°付近に現れるダイヤモンドの(220)面での回折ピークについて、面積強度を求め、予め作成した検量線を用いて、ダイヤモンドの含有割合を求めた。
X線回折の測定条件を以下に示す。
・X線回折装置の装置名:リガク製水平型X線回折装置SmartLab
・測定方法:θ−2θ
・X線源:Cu−Kα線
・励起電圧−電流:45kV−200mA
・発散スリット:2/3°
・散乱スリット:2/3°
・受光スリット:0.6mm
透過型電子顕微鏡を用いた測定の結果から、本発明の製造方法で得られた炭素粒子は、ダイヤモンドとグラファイト質の炭素とから形成されていることを確認した。そのため、これらの炭素成分の格子像が観察できるCCDカメラと撮影倍率を有する透過型電子顕微鏡を用いた。透過型電子顕微鏡の測定条件を以下に示す。
・TEMの装置名:日本電子製透過型電子顕微鏡JEM−ARM200F
・測定方法:懸濁法、分散溶媒:メタノール
・加速電圧:200kV
・CCDカメラ:Gatan製UltraScan
・撮影倍率:30万倍、80万倍
・写真倍率:220万倍、A4サイズに印刷時は590万倍
本実験例では、原料物質としてTNTを用いて、かつ、爆発性物質としてヒドラジン系液体爆薬を用いて、爆轟法により炭素粒子を製造した。
本実験例では、原料物質として、質量2.52kg、密度1.60g/cm3のTNT成型体を質量3.82kg、密度1.61g/cm3のTNT成型体(中国化薬製TNTの円柱形溶填物、直径10cm×長さ30cm)に変更したこと、爆発性物質であるヒドラジン系液体爆薬の使用量を0.93kgから1.29kgに変更したこと以外は、実験例1と同様にして、16μm篩通過分192.1g、32μm篩通過分356.5gおよび100μm篩通過分222.2gの炭素粒子を得た。炭素粒子の合計回収量は、770.8gであった。本実験例における実験内容、炭素粒子の回収量および収率、ならびに、上記XRD定量法により求めたダイヤモンドの合計回収量および収率を下記表1に示す。
本実験例では、原料物質として、質量2.52kg、密度1.60g/cm3のTNT成型体を質量6.30kg、密度1.59g/cm3のTNT成型体(中国化薬製TNTの円柱形溶填物、直径10cm×長さ50cm)に変更したこと、爆発性物質であるヒドラジン系液体爆薬の使用量を0.93kgから2.17kgに変更したこと、冷却材である蒸留水の使用量を200Lから220Lに変更したこと以外は、実験例1と同様にして、16μm篩通過分257.4g、32μm篩通過分531.8gおよび100μm篩通過分336.4gの炭素粒子を得た。炭素粒子の合計回収量は、1125.6gであった。本実験例における実験内容、炭素粒子の合計回収量および収率、ならびに、上記XRD定量法により求めたダイヤモンドの合計回収量および収率を下記表1に示す。
12 爆発性物質
20 爆発容器
22 伝爆薬
24 雷管や導爆線
30 冷却容器
32 冷却材
34 架台
36 穴あき円板
Claims (8)
- 爆轟法により炭素粒子を製造する方法であって、3個以上のニトロ基を有する芳香族化合物を含む原料物質の周囲に常温・常圧で液体である爆発性物質を配置する工程と、前記爆発性物質を爆轟させる工程とを含むことを特徴とする製造方法。
- 前記原料物質が、トリニトロトルエン、シクロトリメチレントリニトラミン、シクロテトラメチレンテトラニトラミン、四硝酸ペンタエリスリトールおよびトリニトロフェニルメチルニトラミンよりなる群から選択される少なくとも1種を含む請求項1に記載の製造方法。
- 前記爆発性物質が、ヒドラジンと硝酸ヒドラジンとの混合物、ヒドラジンと硝酸アンモニウムとの混合物、ニトロメタン、およびヒドラジンとニトロメタンとの混合物よりなる群から選択される少なくとも1種を含む請求項1または2に記載の製造方法。
- 前記原料物質と前記爆発性物質をチャンバー内に装填した状態で前記爆轟を行う請求項1〜3のいずれか1項に記載の製造方法。
- 前記チャンバー内の雰囲気が実質的に酸素ガスを含まない請求項4に記載の製造方法。
- 前記チャンバー内で前記原料物質と前記爆発性物質との周囲に冷却材を配置する請求項4または5に記載の製造方法。
- 前記冷却材が実質的に酸化性物質を発生しない物質である請求項6に記載の製造方法。
- 前記爆轟工程で得られた残渣から炭素粒子を回収する工程をさらに含む請求項1〜7のいずれか1項に記載の製造方法。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014113057A JP6114717B2 (ja) | 2014-05-30 | 2014-05-30 | 爆轟法による炭素粒子の製造方法 |
PCT/JP2015/065220 WO2015182648A1 (ja) | 2014-05-30 | 2015-05-27 | 爆轟法による炭素粒子の製造方法 |
US15/313,789 US10201791B2 (en) | 2014-05-30 | 2015-05-27 | Method for producing carbon particles by detonation |
EP15799381.7A EP3150552A4 (en) | 2014-05-30 | 2015-05-27 | Method for producing carbon particles by detonation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014113057A JP6114717B2 (ja) | 2014-05-30 | 2014-05-30 | 爆轟法による炭素粒子の製造方法 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2015227260A true JP2015227260A (ja) | 2015-12-17 |
JP2015227260A5 JP2015227260A5 (ja) | 2016-07-21 |
JP6114717B2 JP6114717B2 (ja) | 2017-04-12 |
Family
ID=54698972
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014113057A Active JP6114717B2 (ja) | 2014-05-30 | 2014-05-30 | 爆轟法による炭素粒子の製造方法 |
Country Status (4)
Country | Link |
---|---|
US (1) | US10201791B2 (ja) |
EP (1) | EP3150552A4 (ja) |
JP (1) | JP6114717B2 (ja) |
WO (1) | WO2015182648A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017002823A1 (ja) * | 2015-07-01 | 2017-01-05 | 株式会社神戸製鋼所 | グラファイト群、該グラファイト群を含む炭素粒子 |
WO2017159253A1 (ja) * | 2016-03-18 | 2017-09-21 | 株式会社ダイセル | 硬化性樹脂組成物および光学部材 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101705943B1 (ko) * | 2014-04-08 | 2017-02-22 | 성균관대학교산학협력단 | 전기 폭발법을 이용한 다중층 그래핀이 코팅된 복합체 분말의 제조방법 |
RU2712551C1 (ru) * | 2019-03-11 | 2020-01-29 | Валерий Юрьевич Долматов | Способ получения детонационных наноалмазов |
RU2711599C1 (ru) * | 2019-03-11 | 2020-01-17 | Валерий Юрьевич Долматов | Способ получения детонационных наноалмазов |
KR102540730B1 (ko) * | 2020-07-30 | 2023-06-12 | (주)서한에프앤씨 | 진공 팩을 이용한 고체에어로졸 소화기의 점화장치 및 이를 이용한 고체에어로졸 소화기 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03271109A (ja) * | 1990-03-22 | 1991-12-03 | Agency Of Ind Science & Technol | ダイヤモンドの合成方法 |
JP2005289677A (ja) * | 2004-03-31 | 2005-10-20 | Nof Corp | ダイヤモンド合成用爆薬組成物およびダイヤモンドの合成方法 |
JP2006102656A (ja) * | 2004-10-06 | 2006-04-20 | Asahi Kasei Chemicals Corp | ダイヤモンドの製造方法 |
WO2006075763A1 (ja) * | 2005-01-11 | 2006-07-20 | Hiroshi Ishizuka | 単結晶質ダイヤモンド微粉及びその製造方法 |
JP2007269576A (ja) * | 2006-03-31 | 2007-10-18 | Nof Corp | クラスターダイヤモンドの合成方法、及び合成装置 |
JP2012135718A (ja) * | 2010-12-27 | 2012-07-19 | Vision Development Co Ltd | ダイヤモンドの製造方法 |
JP2012170913A (ja) * | 2011-02-23 | 2012-09-10 | Nippon Kayaku Co Ltd | 単結晶ナノダイヤモンド造粒粉体の製造方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3050564A1 (en) | 1980-07-31 | 1982-09-23 | G Adaurov | Method of obtaining diamond and/or diamond-like modifications of boron nitride |
BG49267A3 (en) * | 1990-11-09 | 1991-09-16 | Stavri Ja Stavrev | Method for preparing ultradispersional diamond |
RU2051092C1 (ru) * | 1991-12-25 | 1995-12-27 | Научно-производственное объединение "Алтай" | Алмазсодержащее вещество и способ его получения |
WO2007001031A1 (ja) * | 2005-06-29 | 2007-01-04 | Nippon Kayaku Kabushiki Kaisha | 微細ダイヤモンドの製造方法及び微細ダイヤモンド |
WO2007078210A1 (fr) | 2005-12-30 | 2007-07-12 | Gosudarstvennoe Uchrezhdenie 'federalnoe Agentstvo Po Pravovoi Zaschite Rezultatov Intellektualnoi Deyatelnosti Voennogo, Spetsialnogo I Dvoinogo Naznachenia' Pri Ministerstve Yustitsii Rossiyskoy Fed | Nanodiamant et procede de fabrication correspondant |
CN101977878B (zh) * | 2007-12-21 | 2016-03-23 | 达里安·诺曼德·斯旺森 | 采用具有正至中性氧平衡的爆炸配方通过爆炸生成金刚石的方法 |
-
2014
- 2014-05-30 JP JP2014113057A patent/JP6114717B2/ja active Active
-
2015
- 2015-05-27 US US15/313,789 patent/US10201791B2/en not_active Expired - Fee Related
- 2015-05-27 WO PCT/JP2015/065220 patent/WO2015182648A1/ja active Application Filing
- 2015-05-27 EP EP15799381.7A patent/EP3150552A4/en not_active Withdrawn
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03271109A (ja) * | 1990-03-22 | 1991-12-03 | Agency Of Ind Science & Technol | ダイヤモンドの合成方法 |
JP2005289677A (ja) * | 2004-03-31 | 2005-10-20 | Nof Corp | ダイヤモンド合成用爆薬組成物およびダイヤモンドの合成方法 |
JP2006102656A (ja) * | 2004-10-06 | 2006-04-20 | Asahi Kasei Chemicals Corp | ダイヤモンドの製造方法 |
WO2006075763A1 (ja) * | 2005-01-11 | 2006-07-20 | Hiroshi Ishizuka | 単結晶質ダイヤモンド微粉及びその製造方法 |
JP2007269576A (ja) * | 2006-03-31 | 2007-10-18 | Nof Corp | クラスターダイヤモンドの合成方法、及び合成装置 |
JP2012135718A (ja) * | 2010-12-27 | 2012-07-19 | Vision Development Co Ltd | ダイヤモンドの製造方法 |
JP2012170913A (ja) * | 2011-02-23 | 2012-09-10 | Nippon Kayaku Co Ltd | 単結晶ナノダイヤモンド造粒粉体の製造方法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017002823A1 (ja) * | 2015-07-01 | 2017-01-05 | 株式会社神戸製鋼所 | グラファイト群、該グラファイト群を含む炭素粒子 |
JP2017014071A (ja) * | 2015-07-01 | 2017-01-19 | 株式会社神戸製鋼所 | グラファイト群、該グラファイト群を含む炭素粒子 |
US10195575B2 (en) | 2015-07-01 | 2019-02-05 | Kobe Steel, Ltd. | Graphite group, carbon particles containing said graphite group |
WO2017159253A1 (ja) * | 2016-03-18 | 2017-09-21 | 株式会社ダイセル | 硬化性樹脂組成物および光学部材 |
CN108884176A (zh) * | 2016-03-18 | 2018-11-23 | 株式会社大赛璐 | 固化性树脂组合物及光学部件 |
JPWO2017159253A1 (ja) * | 2016-03-18 | 2019-01-24 | 株式会社ダイセル | 硬化性樹脂組成物および光学部材 |
CN108884176B (zh) * | 2016-03-18 | 2021-03-02 | 株式会社大赛璐 | 固化性树脂组合物及光学部件 |
US10988607B2 (en) | 2016-03-18 | 2021-04-27 | Daicel Corporation | Curable resin composition and optical member |
Also Published As
Publication number | Publication date |
---|---|
US20170183234A1 (en) | 2017-06-29 |
US10201791B2 (en) | 2019-02-12 |
WO2015182648A1 (ja) | 2015-12-03 |
EP3150552A4 (en) | 2017-12-06 |
JP6114717B2 (ja) | 2017-04-12 |
EP3150552A1 (en) | 2017-04-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6114717B2 (ja) | 爆轟法による炭素粒子の製造方法 | |
JP5973987B2 (ja) | 爆轟法による炭素粒子の製造方法 | |
Gao et al. | Facile, continuous and large-scale synthesis of CL-20/HMX nano co-crystals with high-performance by ultrasonic spray-assisted electrostatic adsorption method | |
KR102046772B1 (ko) | 그래파이트군, 해당 그래파이트군을 포함하는 탄소 입자 | |
WO2017094788A1 (ja) | 被覆粒子 | |
JP2018188689A (ja) | 複合粒子、コールドスプレー用材料、被覆材料及びその製造方法 | |
JP6220769B2 (ja) | 爆轟法による炭素粒子の製造方法 | |
JP2007269576A (ja) | クラスターダイヤモンドの合成方法、及び合成装置 | |
US10906016B2 (en) | Method for manufacturing nanoparticles by detonation | |
Langenderfer et al. | Detonation synthesis of nanoscale silicon carbide from elemental silicon | |
WO2017002665A1 (ja) | 被覆粒子 | |
RU2491987C2 (ru) | Способ получения сверхтвердого композиционного материала | |
JPH0659398B2 (ja) | ダイヤモンド合成用爆薬組成物 | |
Dolmatov | On the possibility of obtaining nitrogen-free detonation nanodiamonds: effect of covalently bound nitrogen in explosive molecules on the yield of nanodiamonds | |
Shang et al. | Analysis crystal characteristics of diamond synthesized by different dynamic loading methods | |
AU2021241164A1 (en) | Explosive composition for diamond synthesis | |
JP2018108904A (ja) | フッ素化グラファイト微粒子集合体およびその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160602 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20160727 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20161227 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170207 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20170221 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20170317 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6114717 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |