JP2015172110A - Cushioning tape - Google Patents

Cushioning tape Download PDF

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JP2015172110A
JP2015172110A JP2014047596A JP2014047596A JP2015172110A JP 2015172110 A JP2015172110 A JP 2015172110A JP 2014047596 A JP2014047596 A JP 2014047596A JP 2014047596 A JP2014047596 A JP 2014047596A JP 2015172110 A JP2015172110 A JP 2015172110A
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buffer tape
base material
pressure
sensitive adhesive
adhesive layer
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JP6339386B2 (en
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和央 津田
Kazuhisa Tsuda
和央 津田
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Lintec Corp
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Lintec Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a cushioning tape that can, without providing notches, suppress the occurrence of detachment or wrinkle when is attached to a curved surface or corner part, as a cushioning tape to be attached to the edge part or its periphery of a resin member to be incorporated.SOLUTION: Provided is a cushioning tape 1 that is to be attached to the edge part and its periphery of a resin member to be incorporated, during the incorporation and after the incorporation into a vehicle, formed by laminating an adhesive layer 12 onto one surface 11b of a foamed substrate 11.

Description

本発明は、車両への組み込み時及び組み込み後の、組み込み対象の樹脂部材のエッジ部とその周辺に貼付される緩衝テープに関する。   The present invention relates to a shock-absorbing tape that is affixed to and around an edge portion of a resin member to be incorporated during and after incorporation into a vehicle.

自動車等の各車両は、樹脂部材を組み合わせて構成した各種の内装部品を有し、このような内装部品で代表的なものとしてはフロントパネルが挙げられる。
一方、車両製造時において、これら樹脂部材を所定の箇所に組み込む際には、組み込む樹脂部材に緩衝テープを貼付することで、緩衝テープと組み込まれる他の樹脂部材との接触部分における滑りをよくして、組み込みを容易とすることがある。また、完成した車両は、走行時の振動等によって、組み込み後の樹脂部材の組み込み部においてきしみ音が発生することがあり、このきしみ音を低減するために、組み込む樹脂部材のエッジ部とその周辺に緩衝テープが貼付されることがある。通常、このような緩衝テープは、車両の製造時に樹脂部材の必要とされる箇所に貼付され、車両の完成後も貼付されたままとなる。
Each vehicle such as an automobile has various interior parts formed by combining resin members, and a typical example of such interior parts is a front panel.
On the other hand, when these resin members are assembled at predetermined locations during vehicle manufacture, a buffer tape is affixed to the resin member to be incorporated, so that sliding at the contact portion between the buffer tape and another resin member to be incorporated is improved. May be easy to incorporate. In addition, the completed vehicle may generate a squeaking noise at the mounting portion of the resin member after mounting due to vibration during driving, etc. In order to reduce this squeaking noise, the edge portion of the mounting resin member and its surroundings A buffer tape may be attached to Usually, such a buffer tape is affixed to a place where a resin member is required at the time of manufacture of the vehicle, and remains affixed even after the vehicle is completed.

このような緩衝テープとしては、緩衝作用を有する基材である不織布上に粘着剤層(接着層)が積層された構成のものが開示されている(例えば、特許文献1参照)。   As such a buffer tape, the thing of the structure by which the adhesive layer (adhesion layer) was laminated | stacked on the nonwoven fabric which is a base material which has a buffering effect | action is disclosed (for example, refer patent document 1).

特開2000−104023号公報JP 2000-104023 A

しかし、特許文献1に記載の緩衝テープは、基材が不織布であるために延伸性が乏しく、曲面部や角部に対する追従性が低く、これらの部位に対して不織布が凸状となるように緩衝テープを貼付した場合には剥がれ易く、樹脂部材の組み込みや樹脂部材の組み込み後のきしみ音の低減が困難になるという問題点があった。また、この緩衝テープは、曲面部や角部に対して不織布が凹状となるように貼付した場合には、不織布にしわが発生し易く、樹脂部材の組み込みが困難になるという問題点があった。そして、これらの問題点を解決するためには、基材が不織布である緩衝テープの該当部位に切り込みを入れる必要があるが、その場合、車両製造時の作業が煩雑になってしまうという問題点があった。   However, the buffer tape described in Patent Document 1 has poor stretchability because the base material is a non-woven fabric, has low followability with respect to curved surfaces and corners, and the non-woven fabric becomes convex with respect to these parts. When a buffer tape is affixed, it is easy to peel off, and there is a problem that it becomes difficult to reduce the squeak noise after the resin member is incorporated or after the resin member is incorporated. In addition, this buffer tape has a problem that when the non-woven fabric is affixed to the curved surface portion and the corner portion, wrinkles are likely to occur in the non-woven fabric and it becomes difficult to incorporate the resin member. And in order to solve these problems, it is necessary to cut into the corresponding part of the buffer tape whose base material is a nonwoven fabric, but in that case, the work at the time of vehicle manufacture becomes complicated was there.

本発明は、上記事情に鑑みてなされたものであり、組み込む樹脂部材のエッジ部とその周辺に貼付される緩衝テープとして、切り込みを入れなくても、曲面部又は角部へ貼付した場合の剥がれやしわの発生が抑制される緩衝テープを提供することを課題とする。   The present invention has been made in view of the above circumstances, and as a buffer tape to be applied to the edge portion of the resin member to be incorporated and the periphery thereof, peeling off when applied to a curved surface portion or a corner portion without being cut. It is an object of the present invention to provide a buffer tape in which the generation of wrinkles is suppressed.

上記課題を解決するため、本発明は、車両への組み込み時及び組み込み後の、組み込み対象の樹脂部材のエッジ部とその周辺に貼付される緩衝テープであって、発泡基材の一方の面上に粘着剤層が積層されたことを特徴とする緩衝テープを提供する。
本発明の緩衝テープは、前記発泡基材において、前記粘着剤層の非積層面から積層面へと向かう方向に延びる細孔部が、前記非積層面又は積層面に対して垂直な断面に分布していることが好ましい。
本発明の緩衝テープは、前記細孔部が、前記発泡基材の前記粘着剤層の非積層面から積層面へと貫通していることが好ましい。
In order to solve the above-described problems, the present invention provides a buffer tape that is attached to and around an edge portion of a resin member to be incorporated at the time of assembling into a vehicle and after assembling, on one surface of a foamed substrate. A buffer tape, characterized in that a pressure-sensitive adhesive layer is laminated thereon.
In the cushioning tape of the present invention, in the foamed base material, pores extending in a direction from the non-laminated surface of the pressure-sensitive adhesive layer to the laminated surface are distributed in a cross section perpendicular to the non-laminated surface or the laminated surface. It is preferable.
In the buffer tape of the present invention, it is preferable that the pores penetrate from the non-laminated surface of the pressure-sensitive adhesive layer of the foamed base material to the laminated surface.

本発明によれば、組み込む樹脂部材のエッジ部とその周辺に貼付される緩衝テープとして、切り込みを入れなくても、曲面部又は角部へ貼付した場合の剥がれやしわの発生が抑制される緩衝テープが提供される。   According to the present invention, as a buffer tape to be applied to the edge portion of the resin member to be incorporated and its periphery, a buffer that suppresses the occurrence of peeling and wrinkles when applied to a curved surface portion or a corner portion without being cut. Tape is provided.

本発明に係る第1実施形態の緩衝テープを模式的に例示する断面図である。It is sectional drawing which illustrates typically the buffer tape of 1st Embodiment which concerns on this invention. 本発明に係る第2実施形態の緩衝テープを模式的に例示する図である。It is a figure which illustrates typically the buffer tape of a 2nd embodiment concerning the present invention.

本発明に係る緩衝テープは、車両への組み込み時及び組み込み後の、組み込み対象の樹脂部材のエッジ部とその周辺に貼付される緩衝テープであって、発泡基材の一方の面上に粘着剤層が積層されたことを特徴とする。
前記緩衝テープは、自動車等の車両製造時において、これら車両に組み込む樹脂部材のエッジ部とその周辺表面に貼付されて、使用されるものである。
The shock-absorbing tape according to the present invention is a shock-absorbing tape that is affixed to the edge portion of the resin member to be incorporated and its periphery at the time of assembling into the vehicle and after the assembling, and is an adhesive on one surface of the foamed substrate. The layer is laminated.
When the vehicle such as an automobile is manufactured, the buffer tape is used by being attached to an edge portion of a resin member incorporated in the vehicle and a peripheral surface thereof.

前記緩衝テープは、前記発泡基材が滑り性を有することにより、緩衝テープと組み込まれる他の樹脂部材との接触部分における滑りをよくして、組み込みを容易にする。また、前記緩衝テープは、前記発泡基材が空孔(発泡)部を有することにより、緩衝性を有するので、車両製造後(組み込み後)もそのまま貼付されたままとすることで、樹脂部材の組み込み部において走行時の振動等によって発生するきしみ音を低減する。
このように前記緩衝テープは、樹脂部材の組み込み部での擦れ、傷付き、きしみ音の発生等の不具合を低減するものである。
When the foamed base material is slippery, the buffer tape improves the slip at the contact portion between the buffer tape and another resin member to be incorporated, and facilitates the incorporation. Moreover, since the said foaming base material has a buffering property because the said foaming base material has a void | hole (foaming) part, after the vehicle manufacture (after integration), it is affixed as it is, and the resin member of Reduces squeak noise caused by vibration during running in the built-in part.
As described above, the buffer tape reduces problems such as rubbing, scratching, and generation of squeaking noises at the resin member assembly.

また、前記緩衝テープは、前記発泡基材が空孔(発泡)部を有することにより、延伸性を有する。したがって、前記緩衝テープは、前記延伸性に基づいて、凸状の曲面部及び角部への追従性に優れ、切り込みを入れなくても、これらの部位に貼付した場合の剥がれが抑制される。また、前記緩衝テープは、前記発泡基材の延伸性及び緩衝性に基づいて、凹状の曲面部及び角部へ貼付した場合でも、変形が吸収され、切り込みを入れなくても、しわの発生が抑制される。   Moreover, the said buffer tape has a drawability because the said foaming base material has a void | hole (foaming) part. Therefore, the buffer tape is excellent in followability to convex curved surface portions and corner portions on the basis of the stretchability, and even when not cut, peeling when applied to these portions is suppressed. Moreover, even when the buffer tape is applied to the concave curved surface portion and the corner portion based on the stretchability and the buffer property of the foamed base material, the deformation is absorbed, and wrinkles are generated without making a cut. It is suppressed.

前記緩衝テープの貼付対象である樹脂部材の材質は特に限定されず、目的に応じて任意に選択でき、好ましいものとしては、ポリプロピレン、ポリカーボネート/ABS樹脂アロイ等の合成樹脂や、メラミン樹脂塗料(アルキド・メラミン樹脂塗料)等の樹脂塗料で塗装された部材が例示できる。
前記樹脂部材としては、車両の内装部材が好適である。
以下、図面を参照しながら、本発明について詳細に説明する。
The material of the resin member to which the buffer tape is applied is not particularly limited and can be arbitrarily selected according to the purpose. Preferred examples include synthetic resins such as polypropylene and polycarbonate / ABS resin alloy, and melamine resin paint (alkyd resin). -The member painted with resin paints, such as a melamine resin paint), can be illustrated.
As the resin member, an interior member of a vehicle is suitable.
Hereinafter, the present invention will be described in detail with reference to the drawings.

<第1実施形態>
図1は、本発明に係る第1実施形態の緩衝テープを模式的に例示する断面図である。
ここに示す緩衝テープ1は、発泡基材11の一方の面11b上に粘着剤層12及び剥離材13がこの順に積層されてなるものである。
発泡基材11は、主面として、前記一方の面、すなわち粘着剤層12の積層面(裏面)11bと、他方の面、すなわち粘着剤層12の非積層面(表面)11aとを有するが、前記非積層面11aが、組み込まれる側の部材との接触面となる。
<First Embodiment>
FIG. 1 is a cross-sectional view schematically illustrating the buffer tape according to the first embodiment of the invention.
The buffer tape 1 shown here is formed by laminating an adhesive layer 12 and a release material 13 in this order on one surface 11 b of a foam substrate 11.
The foamed substrate 11 has, as main surfaces, the one surface, that is, the laminated surface (back surface) 11b of the pressure-sensitive adhesive layer 12, and the other surface, that is, the non-laminated surface (front surface) 11a of the pressure-sensitive adhesive layer 12. The non-laminated surface 11a serves as a contact surface with a member to be incorporated.

発泡基材11は、多数の気泡(空孔部、図示略)を内部に有する樹脂基材であり、また、表面が凹凸面である。そして、表面(特に、前記非積層面11a)が凹凸面であることにより、発泡基材11は、他の部材との摩擦力が小さく、滑り性が高い。
発泡基材11は、公知のものでよく、例えば、気泡が互いに独立して存在する独立気泡発泡基材でもよいし、気泡が互いに融合して存在する連続気泡発泡基材でもよく、互いに独立した気泡と互いに融合した気泡とが混在する発泡基材であってもよい。
The foamed base material 11 is a resin base material having a large number of bubbles (hole portions, not shown) inside, and the surface is an uneven surface. And since the surface (especially the said non-lamination surface 11a) is an uneven surface, the foaming base material 11 has a small frictional force with another member, and its slipperiness is high.
The foamed base material 11 may be a known one, and may be, for example, a closed-cell foamed base material in which bubbles are present independently of each other, or an open-cell foamed base material in which bubbles are fused with each other. It may be a foamed base material in which bubbles and bubbles fused with each other are mixed.

発泡基材11を構成する前記樹脂としては、ポリエチレン、ポリスチレン、エチレン−酢酸ビニル共重合体(EVA)、エチレン−プロピレン共重合体等の合成樹脂が例示できる。   Examples of the resin constituting the foam base 11 include synthetic resins such as polyethylene, polystyrene, ethylene-vinyl acetate copolymer (EVA), and ethylene-propylene copolymer.

発泡基材11は、発泡倍率が2〜50倍であることが好ましく、5〜20倍であることがより好ましい。前記発泡倍率が前記下限値以上であることで、曲面部又は角部に貼付された緩衝テープ1の剥がれとしわの発生を抑制する効果がより高くなる。また、前記発泡倍率が前記上限値以下であることで、発泡基材11の強度がより向上する。
なお、本明細書において「発泡倍率」とは、同じ質量の発泡材(例えば、発泡基材11)と非発泡材について、非発泡材の体積に対する発泡材の体積の倍率([非発泡材と同じ質量の発泡材の体積]/[非発泡材の体積])を意味する。
The foaming base material 11 preferably has a foaming ratio of 2 to 50 times, and more preferably 5 to 20 times. When the expansion ratio is equal to or higher than the lower limit value, the effect of suppressing peeling and wrinkle generation of the buffer tape 1 attached to the curved surface portion or the corner portion is further increased. Moreover, the intensity | strength of the foaming base material 11 improves more because the said expansion ratio is below the said upper limit.
In the present specification, the “foaming ratio” means the ratio of the volume of the foam material to the volume of the non-foam material ([non-foam material and Volume of foamed material of the same mass] / [volume of non-foamed material]).

発泡基材11の厚さは、100〜5000μmであることが好ましく、200〜2000μmであることがより好ましい。   The thickness of the foamed substrate 11 is preferably 100 to 5000 μm, and more preferably 200 to 2000 μm.

粘着剤層12は、公知のものでよく、例えば、粘着テープの分野で通常使用されるものでよい。粘着剤層12を構成する粘着剤として、具体的には、アクリル系粘着剤、ゴム系粘着剤、シリコーン系粘着剤、ポリウレタン系粘着剤、ポリエステル系粘着剤が例示できる。これら粘着剤は、エマルション型、溶剤型及び無溶剤型のいずれでもよい。   The pressure-sensitive adhesive layer 12 may be a known one, for example, one that is usually used in the field of pressure-sensitive adhesive tapes. Specific examples of the pressure-sensitive adhesive constituting the pressure-sensitive adhesive layer 12 include acrylic pressure-sensitive adhesives, rubber-based pressure-sensitive adhesives, silicone-based pressure-sensitive adhesives, polyurethane-based pressure-sensitive adhesives, and polyester-based pressure-sensitive adhesives. These pressure-sensitive adhesives may be any of emulsion type, solvent type and solventless type.

前記粘着剤は、耐候性等の点から、アクリル系粘着剤であることが好ましい。
前記アクリル系粘着剤を用いて形成した粘着剤層12は、重量平均分子量が好ましくは30万〜200万、より好ましくは50万〜150万のアクリル系樹脂を含み、かつ架橋処理されたアクリル系粘着剤からなる層であることが好適である。重量平均分子量がこのような範囲であることで、粘着力及び保持力のバランスに優れた緩衝テープ1が得られる。
なお、ここで「重量平均分子量」とは、ゲルパーミエーションクロマトグラフィー(GPC)法により測定したポリスチレン換算の値である。
The pressure-sensitive adhesive is preferably an acrylic pressure-sensitive adhesive from the viewpoint of weather resistance and the like.
The pressure-sensitive adhesive layer 12 formed using the acrylic pressure-sensitive adhesive preferably contains an acrylic resin having a weight average molecular weight of 300,000 to 2,000,000, more preferably 500,000 to 1,500,000, and is crosslinked. A layer made of an adhesive is suitable. When the weight average molecular weight is in such a range, the buffer tape 1 having an excellent balance between adhesive force and holding force can be obtained.
Here, the “weight average molecular weight” is a value in terms of polystyrene measured by a gel permeation chromatography (GPC) method.

粘着剤層12が含む前記アクリル系樹脂としては、(メタ)アクリル酸エステル系共重合体が例示できる。また、この(メタ)アクリル酸エステル系共重合体で好ましいものとしては、アルキル基の炭素数が1〜20の(メタ)アクリル酸アルキルエステルと、活性水素を有する官能基を含む単量体と、任意で用いられる他の単量体と、の共重合体が例示できる。なお、本明細書において、「(メタ)アクリル酸」とは、「アクリル酸」及び「メタクリル酸」の両方を含む概念とする。   As said acrylic resin which the adhesive layer 12 contains, a (meth) acrylic acid ester-type copolymer can be illustrated. Moreover, as a preferable thing in this (meth) acrylic acid ester-type copolymer, the C1-C20 (meth) acrylic-acid alkylester with the alkyl group, the monomer containing the functional group which has active hydrogen, A copolymer with other monomers that are optionally used can be exemplified. In this specification, “(meth) acrylic acid” is a concept including both “acrylic acid” and “methacrylic acid”.

アルキル基の炭素数が1〜20の前記(メタ)アクリル酸アルキルエステルとしては、(メタ)アクリル酸メチル、(メタ)アクリル酸エチル、(メタ)アクリル酸プロピル、(メタ)アクリル酸ブチル、(メタ)アクリル酸ペンチル、(メタ)アクリル酸ヘキシル、(メタ)アクリル酸シクロヘキシル、(メタ)アクリル酸2−エチルヘキシル、(メタ)アクリル酸イソオクチル、(メタ)アクリル酸デシル、(メタ)アクリル酸ドデシル、(メタ)アクリル酸ミリスチル、(メタ)アクリル酸パルミチル、(メタ)アクリル酸ステアリル等が例示できる。
前記(メタ)アクリル酸エステル系共重合体における、アルキル基の炭素数が1〜20の前記(メタ)アクリル酸アルキルエステルは、一種のみでもよいし、二種以上でもよい。
Examples of the alkyl group having 1 to 20 carbon atoms in the alkyl group include methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, butyl (meth) acrylate, ( Pentyl (meth) acrylate, hexyl (meth) acrylate, cyclohexyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, isooctyl (meth) acrylate, decyl (meth) acrylate, dodecyl (meth) acrylate, Examples thereof include myristyl (meth) acrylate, palmityl (meth) acrylate, and stearyl (meth) acrylate.
In the (meth) acrylic acid ester-based copolymer, the alkyl group having 1 to 20 carbon atoms in the alkyl group may be one kind or two or more kinds.

活性水素を有する官能基を含む前記単量体としては、(メタ)アクリル酸2−ヒドロキシエチル、(メタ)アクリル酸2−ヒドロキシプロピル、(メタ)アクリル酸3−ヒドロキシプロピル、(メタ)アクリル酸2−ヒドロキシブチル、(メタ)アクリル酸3−ヒドロキシブチル、(メタ)アクリル酸4−ヒドロキシブチル等の(メタ)アクリル酸ヒドロキシアルキルエステル等のヒドロキシル基含有モノマー;アクリルアミド、メタクリルアミド、N−メチルアクリルアミド、N−メチルメタクリルアミド、N−メチロールアクリルアミド、N−メチロールメタクリルアミド等のアミド基含有モノマー;(メタ)アクリル酸モノメチルアミノエチル、(メタ)アクリル酸モノエチルアミノエチル、(メタ)アクリル酸モノメチルアミノプロピル、(メタ)アクリル酸モノエチルアミノプロピル等の(メタ)アクリル酸モノアルキルアミノアルキル;アクリル酸、メタクリル酸、クロトン酸、マレイン酸、イタコン酸、シトラコン酸等のエチレン性不飽和結合を有するカルボン酸等が例示できる。
前記(メタ)アクリル酸エステル系共重合体における、活性水素を有する官能基を含む前記単量体は、一種のみでもよいし、二種以上でもよい。
Examples of the monomer containing a functional group having active hydrogen include 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, and (meth) acrylic acid. Hydroxyl group-containing monomers such as 2-hydroxybutyl, (meth) acrylic acid 3-hydroxybutyl and (meth) acrylic acid hydroxyalkyl esters such as 4-hydroxybutyl; acrylamide, methacrylamide, N-methylacrylamide Amide group-containing monomers such as N-methylmethacrylamide, N-methylolacrylamide, N-methylolmethacrylamide; monomethylaminoethyl (meth) acrylate, monoethylaminoethyl (meth) acrylate, monomethylamino (meth) acrylate Professional , Monoalkylaminoalkyl (meth) acrylates such as monoethylaminopropyl (meth) acrylate; carboxyls having ethylenically unsaturated bonds such as acrylic acid, methacrylic acid, crotonic acid, maleic acid, itaconic acid, citraconic acid An acid etc. can be illustrated.
The said monomer containing the functional group which has active hydrogen in the said (meth) acrylic-ester type copolymer may be only 1 type, and 2 or more types may be sufficient as it.

任意で用いられる前記他の単量体としては、酢酸ビニル、プロピオン酸ビニル等のビニルエステル;エチレン、プロピレン、イソブチレン等のオレフィン;塩化ビニル、ビニリデンクロリド等のハロゲン化オレフィン;スチレン、α−メチルスチレン等のスチレン系単量体;ブタジエン、イソプレン、クロロプレン等のジエン系単量体;アクリロニトリル、メタクリロニトリル等のニトリル系単量体;N,N−ジメチルアクリルアミド、N,N−ジメチルメタクリルアミド等のN,N−ジアルキル置換アクリルアミド等が例示できる。
前記(メタ)アクリル酸エステル系共重合体における、任意で用いられる前記他の単量体は、一種のみでもよいし、二種以上でもよい。
Examples of the other monomer used optionally include vinyl esters such as vinyl acetate and vinyl propionate; olefins such as ethylene, propylene and isobutylene; halogenated olefins such as vinyl chloride and vinylidene chloride; styrene and α-methylstyrene. Styrene monomer such as butadiene monomer, diene monomer such as isoprene and chloroprene, nitrile monomer such as acrylonitrile and methacrylonitrile, N, N-dimethylacrylamide, N, N-dimethylmethacrylamide, etc. Examples thereof include N, N-dialkyl-substituted acrylamide.
The other monomer used optionally in the (meth) acrylic acid ester copolymer may be one kind or two or more kinds.

前記(メタ)アクリル酸エステル系共重合体の共重合形態は、特に限定されず、ランダム共重合体、ブロック共重合体及びグラフト共重合体のいずれでもよい。   The copolymerization form of the (meth) acrylic acid ester copolymer is not particularly limited, and any of a random copolymer, a block copolymer, and a graft copolymer may be used.

粘着剤層12が含む前記(メタ)アクリル酸エステル系共重合体等のアクリル系樹脂は、一種のみでもよいし、二種以上でもよい。   The acrylic resin such as the (meth) acrylic acid ester copolymer contained in the pressure-sensitive adhesive layer 12 may be one kind or two or more kinds.

前記アクリル系粘着剤は、架橋処理されたものが好ましく、この架橋処理に用いられる架橋剤は特に限定されず、公知のものでもよい。
前記架橋剤としては、ポリイソシアネート化合物、エポキシ化合物、メラミン樹脂、尿素樹脂、ジアルデヒド類、メチロールポリマー、金属キレート化合物、金属アルコキシド、金属塩等が例示でき、ポリイソシアネート化合物、エポキシ化合物が好ましい。
前記架橋剤は一種を単独で用いてもよいし、二種以上を併用してもよい。
前記架橋剤の使用量は、その種類にもよるが、前記(メタ)アクリル酸エステル系共重合体100質量部に対して、好ましくは0.01〜20質量部、より好ましくは0.1〜10質量部の範囲で選定される。
The acrylic pressure-sensitive adhesive is preferably subjected to a crosslinking treatment, and the crosslinking agent used for the crosslinking treatment is not particularly limited and may be a known one.
Examples of the crosslinking agent include polyisocyanate compounds, epoxy compounds, melamine resins, urea resins, dialdehydes, methylol polymers, metal chelate compounds, metal alkoxides, metal salts and the like, and polyisocyanate compounds and epoxy compounds are preferred.
The cross-linking agents may be used alone or in combination of two or more.
Although the usage-amount of the said crosslinking agent is based also on the kind, Preferably it is 0.01-20 mass parts with respect to 100 mass parts of said (meth) acrylic acid ester-type copolymers, More preferably, it is 0.1-0.1. It is selected in the range of 10 parts by mass.

前記アクリル系粘着剤には、必要に応じて粘着付与剤、酸化防止剤、紫外線吸収剤、光安定剤、軟化剤、シランカップリング剤、充填剤等のその他の成分が配合されていてもよく、配合されている前記その他の成分は、一種のみでもよいし、二種以上でもよい。   The acrylic pressure-sensitive adhesive may contain other components such as a tackifier, an antioxidant, an ultraviolet absorber, a light stabilizer, a softener, a silane coupling agent, and a filler as necessary. These other components may be used alone or in combination of two or more.

粘着剤層12の厚さは、10〜100μmであることが好ましく、20〜50μmであることがより好ましい。   The thickness of the pressure-sensitive adhesive layer 12 is preferably 10 to 100 μm, and more preferably 20 to 50 μm.

剥離材13は、公知のものでよく、例えば、粘着テープの分野で通常使用されるものでよい。好ましい剥離材13としては、紙基材又はフィルム基材の表面に剥離層が設けられたものが例示できる。   The release material 13 may be a known material, for example, one that is usually used in the field of adhesive tape. Examples of preferable release material 13 include those in which a release layer is provided on the surface of a paper substrate or a film substrate.

前記紙基材としては、ポリエチレンラミネート紙、ポリプロピレンラミネート紙、クレーコート紙、樹脂コート紙、グラシン紙、上質紙等の各種紙材が例示できる。
前記フィルム基材としては、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリエチレン、ポリプロピレン、ポリアクリレート等の各種樹脂フィルムが例示できる。
また、剥離材13としては、前記紙基材又はフィルム基材に填料等の充填剤を含有させた合成紙又はフィルムも例示でき、必要に応じて、これら合成紙又はフィルムの表面に剥離層が設けられていてもよい。
前記剥離層としては、シリコーン系樹脂、長鎖アルキル系樹脂、フッ素系樹脂等の剥離剤を含有するものが例示できる。
Examples of the paper substrate include various paper materials such as polyethylene laminated paper, polypropylene laminated paper, clay coated paper, resin coated paper, glassine paper, and high quality paper.
Examples of the film substrate include various resin films such as polyethylene terephthalate, polybutylene terephthalate, polyethylene, polypropylene, and polyacrylate.
Examples of the release material 13 include a synthetic paper or film in which a filler such as a filler is contained in the paper base or film base. If necessary, a release layer is formed on the surface of the synthetic paper or film. It may be provided.
Examples of the release layer include those containing release agents such as silicone resins, long-chain alkyl resins, and fluorine resins.

剥離材13の厚さは特に限定されず、適宜調節すればよい。   The thickness of the release material 13 is not particularly limited, and may be adjusted as appropriate.

緩衝テープ1は、上述の延伸性及び緩衝性を有するのに加え、基材が不織布ではないので、繊維くずが発生せず、さらに気密性が高いことで水蒸気等も透過させにくく、貼付部位内部の部材の腐食が抑制される。
また、緩衝テープ1は、ロール形態とすることが可能で、任意の幅及び長さで貼付装置を使用して貼付可能であり、切り込みを入れる等の余分な操作も不要なので、作業性にも優れる。
In addition to having the above-described stretchability and buffering property, the buffer tape 1 does not generate fiber waste because it is not a non-woven fabric, and it is difficult to permeate water vapor and the like due to its high airtightness. Corrosion of the member is suppressed.
In addition, the buffer tape 1 can be formed in a roll form, and can be pasted by using a sticking device with an arbitrary width and length, and an extra operation such as making a cut is unnecessary, so that workability is also improved. Excellent.

緩衝テープ1は、発泡基材11の前記積層面11b上に粘着剤層12及び剥離材13をこの順となるように積層することで製造できる。
粘着剤層12は、発泡基材11の前記積層面11bに粘着剤層形成用組成物を塗布し、乾燥させることで形成できる。また、剥離材の剥離層表面に前記粘着剤層形成用組成物を塗布し、乾燥させることで形成した粘着剤層を、発泡基材11の表面に貼り合わせることでも粘着剤層12を形成できる。この場合、剥離材として上述の剥離材13を用いた場合には、この剥離材13は取り除く必要はなく、直ちに緩衝テープ1が得られるが、剥離材13以外の剥離材を用いた場合には、この剥離材は取り除く。
粘着剤層形成用組成物の乾燥条件は、特に限定されないが、温度は70〜130℃であることが好ましく、時間は1〜5分であることが好ましい。
The buffer tape 1 can be manufactured by laminating the pressure-sensitive adhesive layer 12 and the release material 13 on the laminated surface 11b of the foamed base material 11 in this order.
The pressure-sensitive adhesive layer 12 can be formed by applying a composition for forming a pressure-sensitive adhesive layer to the laminated surface 11 b of the foamed substrate 11 and drying it. Alternatively, the pressure-sensitive adhesive layer 12 can also be formed by applying the pressure-sensitive adhesive layer-forming composition to the surface of the release layer of the release material and drying the pressure-sensitive adhesive layer formed on the surface of the foam substrate 11. . In this case, when the above-described release material 13 is used as the release material, it is not necessary to remove the release material 13 and the buffer tape 1 is obtained immediately. However, when a release material other than the release material 13 is used, Remove this release material.
The drying conditions of the pressure-sensitive adhesive layer forming composition are not particularly limited, but the temperature is preferably 70 to 130 ° C., and the time is preferably 1 to 5 minutes.

前記粘着剤層形成用組成物としては、粘着剤層12を構成する前記粘着剤及び溶媒が配合されてなるものが例示できる。
前記溶媒としては、酢酸エチル、酢酸ブチル等のエステル;メチルイソブチルケトン、メチルエチルケトン、シクロヘキサノン等のケトン;トルエン、キシレン等の芳香族炭化水素等が例示できる。
Examples of the pressure-sensitive adhesive layer forming composition include those in which the pressure-sensitive adhesive and the solvent constituting the pressure-sensitive adhesive layer 12 are blended.
Examples of the solvent include esters such as ethyl acetate and butyl acetate; ketones such as methyl isobutyl ketone, methyl ethyl ketone and cyclohexanone; aromatic hydrocarbons such as toluene and xylene.

粘着剤層形成用組成物の発泡基材11又は剥離材への塗布は、公知の方法で行えばよく、エアーナイフコーター、ブレードコーター、バーコーター、グラビアコーター、ロールコーター、ロールナイフコーター、カーテンコーター、ダイコーター、ナイフコーター、スクリーンコーター、マイヤーバーコーター、キスコーター等の各種コーターを用いる方法が例示できる。   Application of the pressure-sensitive adhesive layer forming composition to the foamed substrate 11 or the release material may be performed by a known method, such as an air knife coater, blade coater, bar coater, gravure coater, roll coater, roll knife coater, curtain coater. Examples thereof include methods using various coaters such as a die coater, a knife coater, a screen coater, a Meyer bar coater, and a kiss coater.

粘着剤層形成用組成物の発泡基材11又は剥離材への塗布量は、適宜調節すればよいが、粘着剤の塗布量が20〜50g/mとなる塗布量であることが好ましい。 The application amount of the pressure-sensitive adhesive layer forming composition to the foamed base material 11 or the release material may be adjusted as appropriate, but the application amount of the pressure-sensitive adhesive is preferably 20 to 50 g / m 2 .

粘着剤層12の形成後は、剥離材13が設けられていない場合には、これを粘着剤層12上に貼り合わせればよく、例えば、剥離材13が紙基材又はフィルム基材の表面に剥離層が設けられたものである場合には、剥離層を粘着剤層12に接触させるようにして、剥離材13を粘着剤層12に貼り合わせればよい。これにより緩衝テープ1が得られる。   After the pressure-sensitive adhesive layer 12 is formed, if the release material 13 is not provided, it may be bonded onto the pressure-sensitive adhesive layer 12. For example, the release material 13 is applied to the surface of a paper substrate or a film substrate. When the release layer is provided, the release material 13 may be bonded to the pressure-sensitive adhesive layer 12 so that the release layer is brought into contact with the pressure-sensitive adhesive layer 12. Thereby, the buffer tape 1 is obtained.

なお、上記の各工程においては、発泡基材11や、発泡基材11上に粘着剤層12等が形成されたものを、ロール状に巻き取った状態から繰り出して、さらにいずれかの層を形成した後、さらにロール状に巻き取るようにする、所謂ロールトゥロール方式で、緩衝テープ1を製造することもできる。   In each of the above steps, the foamed base material 11 or the foamed base material 11 on which the pressure-sensitive adhesive layer 12 or the like is formed is rolled out from the rolled state, and any layer is further formed. After the formation, the buffer tape 1 can be manufactured by a so-called roll-to-roll method in which the film is further wound into a roll.

<第2実施形態>
図2は、本発明に係る第2実施形態の緩衝テープを模式的に例示する図であり、(a)は断面図、(b)は発泡基材側から見た正面図である。なお、図2に示す構成要素のうち、図1に示すものと同じものには、図1の場合と同じ符号を付し、その詳細な説明は省略する。
Second Embodiment
FIG. 2 is a diagram schematically illustrating a buffer tape according to a second embodiment of the present invention, in which (a) is a cross-sectional view and (b) is a front view as seen from the foamed substrate side. 2 that are the same as those shown in FIG. 1 are assigned the same reference numerals as in FIG. 1, and detailed descriptions thereof are omitted.

ここに示す緩衝テープ2は、発泡基材11に代えて、細孔部24を有する発泡基材21を備えている点以外は、図1に示す緩衝テープ1と同様のものである。
緩衝テープ2は、細孔部24が設けられていることにより、緩衝テープ1よりもさらに曲面部及び角部への追従性に優れる。
また、緩衝テープ2は、発泡基材21の粘着剤層12の非積層面21aにおいて細孔部24が開口しているものである場合、前記非積層面21aは、発泡基材11の表面よりもさらに凹凸の程度が大きいので、他の部材との摩擦力がより小さく、より滑り性が高い。
The shock-absorbing tape 2 shown here is the same as the shock-absorbing tape 1 shown in FIG. 1 except that it has a foamed base material 21 having pores 24 instead of the foamed base material 11.
Since the buffer tape 2 is provided with the pores 24, the buffer tape 2 is more excellent in followability to curved surfaces and corners than the buffer tape 1.
Further, when the buffer tape 2 is one in which the pores 24 are opened in the non-laminate surface 21 a of the pressure-sensitive adhesive layer 12 of the foam base material 21, the non-laminate surface 21 a is more than the surface of the foam base material 11. Furthermore, since the degree of unevenness is large, the frictional force with other members is smaller and the slipperiness is higher.

発泡基材21は、細孔部24が多数設けられた点以外は、緩衝テープ1における発泡基材11と同様のものである。
細孔部24は、発泡基材21の粘着剤層12の非積層面(表面)21aから、発泡基材21の粘着剤層12の積層面(裏面)21bへかけて、発泡基材21を貫通して設けられており、細孔部24は、発泡基材21において、前記非積層面21a又は積層面21bに対して垂直な断面に分布している。
The foam base 21 is the same as the foam base 11 in the buffer tape 1 except that a large number of pores 24 are provided.
The pore 24 extends from the non-laminated surface (front surface) 21a of the pressure-sensitive adhesive layer 12 of the foamed base material 21 to the laminated surface (back surface) 21b of the pressure-sensitive adhesive layer 12 of the foamed base material 21. The fine pores 24 are distributed in a cross section perpendicular to the non-laminated surface 21 a or the laminated surface 21 b in the foamed base material 21.

また、細孔部24は、発泡基材21において、前記非積層面21a若しくは積層面21b、又はこれらの面に対して平行な断面に分布しており、これらの面における細孔部24の数は、特に限定されないが、1〜100個/cmであることが好ましく、2〜50個/cmであることがより好ましい。細孔部24の数が前記下限値以上であることで、細孔部24を設けたことによる効果がより顕著に得られ、細孔部24の数が前記上限値以下であることで、発泡基材21の強度がより向上する。 In addition, the pores 24 are distributed in the non-laminated surface 21a or the laminated surface 21b or a cross section parallel to these surfaces in the foam substrate 21, and the number of pores 24 on these surfaces is not particularly limited, but is preferably 1 to 100 / cm 2, more preferably 2 to 50 / cm 2. When the number of the pores 24 is equal to or greater than the lower limit, the effect of providing the pores 24 is more remarkably obtained. When the number of the pores 24 is equal to or less than the upper limit, foaming is performed. The strength of the base material 21 is further improved.

細孔部24の、その延伸方向(前記非積層面21aから前記積層面21bへと向かう方向)に対して直交する方向の断面の形状は、円形であるが、本発明において前記断面形状はこれに限定されず、その他の形状でもよい。   The shape of the cross section of the pore 24 in the direction orthogonal to the extending direction (the direction from the non-laminated surface 21a to the laminated surface 21b) is a circle. However, other shapes may be used.

細孔部24の前記断面形状における最大径(図2では円の直径)Dは、特に限定されず、適宜調節すればよいが、発泡基材21の厚さHに対して1〜40%であることが好ましく、5〜20%であることがより好ましい。なお、ここで「最大径」とは、前記断面形状において、細孔部24の壁面上の二点間を結ぶ線分で最長のものを意味する。 The maximum diameter (diameter of the circle in FIG. 2) D 1 of the cross-sectional shape of the pore 24 is not particularly limited and may be adjusted as appropriate, but may be 1 to 40 with respect to the thickness H 1 of the foam base 21. % Is preferable, and 5 to 20% is more preferable. Here, the “maximum diameter” means the longest line segment connecting two points on the wall surface of the pore 24 in the cross-sectional shape.

前記非積層面21a若しくは積層面21b、又はこれらの面に対して平行な断面において、隣り合う細孔部24同士の距離Lは、発泡基材21の厚さHの0.1〜20倍であることが好ましく、1〜5倍であることがより好ましい。なお、ここで「隣り合う細孔部24同士の距離」とは、隣り合う一方の細孔部24の壁面上の点と、他方の細孔部24の壁面上の点と、を結ぶ線分で最短のものを意味する。
また、前記面において、距離Lは細孔部24同士間ですべて同じあってもよいし、すべて異なっていてもよく、一部のみ同じであってもよい。
The non-laminated surface 21a or laminated surface 21b, or in a cross section parallel to these surfaces, the distance L 1 between the pore portions 24 adjacent 0.1-20 thickness H 1 of the foaming base material 21 It is preferable that it is double, and it is more preferable that it is 1 to 5 times. Here, the “distance between adjacent pores 24” is a line segment connecting a point on the wall surface of one adjacent pore 24 and a point on the wall surface of the other pore 24. Means the shortest.
Further, in the surface, the distance L 1 is may be a same all across the pore portions 24 to each other, may be different all, may be the same part only.

ここでは、細孔部24として、発泡基材21の粘着剤層12の非積層面21aから、粘着剤層12の積層面21bへかけて、発泡基材21を貫通しているものを示しているが、本発明においては、細孔部24が発泡基材21を貫通していなくてもよく、例えば、前記非積層面21a又は積層面21bにおいて細孔部24が開口していなくてもよい。   Here, the pores 24 are shown as penetrating through the foamed base material 21 from the non-laminated surface 21a of the pressure-sensitive adhesive layer 12 of the foamed base material 21 to the laminated surface 21b of the pressure-sensitive adhesive layer 12. However, in the present invention, the pores 24 do not have to penetrate the foamed base material 21, and for example, the pores 24 do not have to be opened in the non-laminated surface 21a or the laminated surface 21b. .

緩衝テープ2において、細孔部24はすべて同じでなくてもよく、例えば、前記断面形状、前記断面形状における最大径、長さ等のいずれかが互いに異なるものが混在していてもよい。   In the buffer tape 2, all the pores 24 may not be the same, and, for example, the cross-sectional shape, the maximum diameter in the cross-sectional shape, the length, and the like may be mixed.

緩衝テープ2は、発泡基材11に代えて発泡基材21を用いる点以外は、緩衝テープ1と同様の方法で製造できる。また、発泡基材21の粘着剤層12の非積層面21aにおいて細孔部24が開口している緩衝テープ2は、先に述べた方法で緩衝テープ1を得た後、その発泡基材11に細孔部24を形成して発泡基材21とすることでも製造できる。   The buffer tape 2 can be manufactured by the same method as the buffer tape 1 except that the foam substrate 21 is used instead of the foam substrate 11. The buffer tape 2 having the pores 24 opened on the non-laminated surface 21a of the pressure-sensitive adhesive layer 12 of the foam substrate 21 is obtained by obtaining the buffer tape 1 by the method described above, and then the foam substrate 11 It can also be manufactured by forming the pores 24 in the foamed base material 21.

発泡基材21は、例えば、発泡基材11等の細孔部24を有しない発泡基材に対して、細孔部24を形成することで得られる。
細孔部24は、例えば、その形成対象である発泡基材に対して、加熱した針状の構造物を差し込む方法、レーザを照射する方法、高圧の水を吹き付ける方法等で形成できるが、簡便かつ効率的に形成できる点から、加熱した針状の構造物を差し込む方法が好ましい。
The foam base 21 is obtained by forming the pores 24 with respect to the foam base having no pores 24 such as the foam base 11.
The pore 24 can be formed by, for example, a method of inserting a heated needle-like structure, a method of irradiating a laser, a method of spraying high-pressure water, or the like on a foam base material to be formed. In view of efficient formation, a method of inserting a heated needle-like structure is preferable.

本発明に係る緩衝テープは、図1及び2に示すものに限定されず、本発明の効果を損なわない範囲内において、一部構成が適宜変更、省略又は追加されたものであってもよい。   The buffer tape according to the present invention is not limited to the one shown in FIGS. 1 and 2, and a part of the configuration may be appropriately changed, omitted, or added within a range not impairing the effects of the present invention.

本発明に係る緩衝テープは、上述のように発泡基材での滑り性が高く、例えば、「JIS B0601:2013 4.2.1」に準拠した発泡基材の表面粗さ(算術平均粗さRa)は0.05μm以上であることが好ましく、0.07μm以上であることがより好ましい。一方、発泡基材の前記表面粗さの上限値は、本発明の効果を損なわない限り特に限定されない。また、「JIS K7125:1999」に準拠した発泡基材の樹脂部材に対する動摩擦力は18N以下であることが好ましく、14N以下であることがより好ましい。   The shock-absorbing tape according to the present invention is highly slippery on the foamed base as described above. For example, the surface roughness (arithmetic average roughness) of the foamed base conforming to “JIS B0601: 2013 4.2.1”. Ra) is preferably 0.05 μm or more, and more preferably 0.07 μm or more. On the other hand, the upper limit of the surface roughness of the foamed substrate is not particularly limited as long as the effect of the present invention is not impaired. In addition, the dynamic friction force of the foamed base material to the resin member in accordance with “JIS K7125: 1999” is preferably 18 N or less, and more preferably 14 N or less.

また、本発明に係る緩衝テープは、上述のように延伸性を有し、例えば、幅15mmの緩衝テープを流れ方向(MD方向)に延伸し、破断したときの破断強度が好ましくは5N/15mm以上、より好ましくは10N/15mm以上、破断伸度が好ましくは40%以上、より好ましくは60%以上のものとすることができる。
そして、本発明に係る緩衝テープは、例えば、幅15mmの緩衝テープを流れ方向(MD方向)に20%延伸してから1分後の残留応力が、10N/15mm以下であることが好ましく、8N/15mm以下であることがより好ましい。
これら延伸時の物性は、緩衝テープを凸状の曲面部及び角部へ貼付した場合の剥がれの抑制効果と、凹状の曲面部及び角部へ貼付した場合のしわの発生抑制効果の尺度となるものである。
The buffer tape according to the present invention has stretchability as described above. For example, the buffer tape having a width of 15 mm is stretched in the flow direction (MD direction) and preferably has a breaking strength of 5 N / 15 mm. As described above, more preferably, it is 10 N / 15 mm or more, and the elongation at break is preferably 40% or more, more preferably 60% or more.
The buffer tape according to the present invention preferably has a residual stress of 10 N / 15 mm or less after 1 minute after stretching a buffer tape having a width of 15 mm by 20% in the flow direction (MD direction), for example, 8N / 15 mm or less is more preferable.
These physical properties at the time of stretching are a measure of the effect of suppressing peeling when the buffer tape is applied to convex curved surface portions and corner portions, and the effect of suppressing the occurrence of wrinkles when applied to concave curved surface portions and corner portions. Is.

また、本発明に係る緩衝テープは、「JIS K7181」に準拠した、発泡基材の25%圧縮時の圧縮応力が、0.1MPa以下であることが好ましい。このような圧縮応力であることにより、樹脂部材の組み込み部での擦れ、傷付き、きしみ音の発生等の不具合をより低減できる。   Moreover, it is preferable that the compression stress at the time of 25% compression of the foaming base material of the buffer tape concerning this invention based on "JISK7181" is 0.1 MPa or less. With such a compressive stress, it is possible to further reduce problems such as rubbing, scratching, and generation of squeaking noise at the resin member assembly portion.

以下、具体的実施例により、本発明についてより詳細に説明する。ただし、本発明は、以下に示す実施例に、何ら限定されるものではない。
なお、実施例及び比較例における緩衝テープの各特性は、以下の方法で測定、評価した。
Hereinafter, the present invention will be described in more detail with reference to specific examples. However, the present invention is not limited to the following examples.
In addition, each characteristic of the buffer tape in an Example and a comparative example was measured and evaluated with the following method.

(表面粗さ)
緩衝層(発泡基材、不織布)の表面粗さ(算術平均粗さRa、μm)を、「JIS B0601:2013 4.2.1」に準拠して測定した。
(動摩擦力)
緩衝層(発泡基材、不織布)のポリプロピレン板(PP(コウベポリシート)型番PP−N−BN)に対する動摩擦力(N)を、「JIS K7125:1999」に準拠し、面荷重1kgf(9.80665N)、テストスピード10mm/分として測定した。
(残留応力)
幅15mmの緩衝テープを流れ方向(MD方向)に20%延伸したときの残留応力(N/15mm)を、延伸直後、並びに延伸後1分、5分及び10分の段階で測定し、応力緩和を評価した。
(引張物性)
幅15mmの緩衝テープを流れ方向(MD方向)に延伸し、引張物性として、緩衝テープが破断したときの強度(破断強度、N/15mm)と、緩衝テープの伸度(破断伸度、%)とを、それぞれ測定した。
(圧縮応力)
緩衝層(発泡基材、不織布)の圧縮応力を、「JIS K7181」に準拠して測定した。
(Surface roughness)
The surface roughness (arithmetic mean roughness Ra, μm) of the buffer layer (foamed substrate, nonwoven fabric) was measured in accordance with “JIS B0601: 2013 4.2.1”.
(Dynamic frictional force)
The dynamic friction force (N) of the buffer layer (foamed substrate, non-woven fabric) against the polypropylene plate (PP (Kobe Poly Sheet) model number PP-N-BN) is based on “JIS K7125: 1999” and the surface load is 1 kgf (9. 80665N), and the test speed was 10 mm / min.
(Residual stress)
Residual stress (N / 15mm) when buffer tape with a width of 15mm is stretched 20% in the flow direction (MD direction) is measured immediately after stretching and at 1 minute, 5 minutes and 10 minutes after stretching to relieve stress. Evaluated.
(Tensile properties)
Stretching a buffer tape with a width of 15 mm in the flow direction (MD direction), as tensile properties, the strength when the buffer tape breaks (breaking strength, N / 15 mm) and the elongation of the buffer tape (breaking elongation,%) And were measured respectively.
(Compressive stress)
The compressive stress of the buffer layer (foamed substrate, non-woven fabric) was measured in accordance with “JIS K7181”.

[実施例1]
図1に示す構成の緩衝テープを製造した。
発泡基材としては、ポリエチレンを主成分とし、厚さが1.0mm、発泡倍率が15倍の黒色のもの(積水化学工業社製「ボラーラXL−S#1501」)を用いた。粘着剤層としては、アクリル系粘着剤で構成され、厚さが40μmであるものを形成し、粘着剤の塗布量を39g/mとした。剥離材としては剥離紙「SP−7LKシロ」(リンテック社製)を用いた。
得られた緩衝テープの評価結果を表1に示す。
[Example 1]
A buffer tape having the structure shown in FIG. 1 was produced.
As the foam base material, a black base material (“Bora La XL-S # 1501” manufactured by Sekisui Chemical Co., Ltd.) having polyethylene as a main component, a thickness of 1.0 mm, and a foaming ratio of 15 times was used. The pressure-sensitive adhesive layer was made of an acrylic pressure-sensitive adhesive and had a thickness of 40 μm, and the amount of pressure-sensitive adhesive applied was 39 g / m 2 . As the release material, release paper “SP-7LK Shiro” (manufactured by Lintec Corporation) was used.
The evaluation results of the obtained buffer tape are shown in Table 1.

[実施例2]
図2に示す構成の緩衝テープを製造した。
すなわち、実施例1で用いた発泡基材に代えて、実施例1で用いた発泡基材に、以下のような厚さ方向に貫通する細孔部を設けたものを用いた点以外は、実施例1と同じ方法で、緩衝テープを製造した。細孔部は、発泡基材に所定のサイズ及び間隔を有する熱針ロールを押し当てることで形成した。
細孔部の数:25個/cm
細孔部の断面形状における最大径D:100μm
隣り合う細孔部同士の距離L:2mm
得られた緩衝テープの評価結果を表1に示す。
[Example 2]
A buffer tape having the structure shown in FIG. 2 was produced.
That is, in place of the foamed base material used in Example 1 instead of the foamed base material used in Example 1, the one provided with a pore portion penetrating in the thickness direction as described below was used. A buffer tape was manufactured in the same manner as in Example 1. The pores were formed by pressing a hot needle roll having a predetermined size and spacing against the foamed substrate.
Number of pores: 25 / cm 2
Maximum diameter D 1 in the cross-sectional shape of the pores: 100 μm
Distance L 1 between adjacent pores: 2 mm
The evaluation results of the obtained buffer tape are shown in Table 1.

[実施例3]
発泡基材として、厚さが0.5mm、発泡倍率が7倍であるものを用いた点以外は、実施例1と同じ方法で、図1に示す構成の緩衝テープを製造した。
得られた緩衝テープの評価結果を表1に示す。
[Example 3]
A buffer tape having the configuration shown in FIG. 1 was produced in the same manner as in Example 1 except that a foamed substrate having a thickness of 0.5 mm and a foaming ratio of 7 was used.
The evaluation results of the obtained buffer tape are shown in Table 1.

[比較例1]
発泡基材に代えて、ポリエチレン製で、厚さが1.0mmの不織布基材を用い、剥離材を積層しなかった点以外は、実施例1と同じ方法で、緩衝テープを製造した。
得られた緩衝テープの評価結果を表1に示す。
[Comparative Example 1]
A buffer tape was manufactured in the same manner as in Example 1 except that a nonwoven fabric substrate made of polyethylene and having a thickness of 1.0 mm was used instead of the foamed substrate, and the release material was not laminated.
The evaluation results of the obtained buffer tape are shown in Table 1.

Figure 2015172110
Figure 2015172110

表1に示すように、実施例1〜3の緩衝テープは、動摩擦力が小さく、滑り性が高かった。また、20%延伸時の残留応力は、各段階でいずれも低く、特に実施例3で低かった。実施例2の緩衝テープは、基材に細孔部が設けられていることで、実施例1の緩衝テープよりもさらに残留応力が低かった。また、引張物性は、破断強度及び破断伸度のいずれもが、実施例1〜3の緩衝テープで十分な大きさであり、特に実施例3で大きかった。このように、実施例1〜3の緩衝テープは、車両への組み込み時及び組み込み後の、組み込み対象の樹脂部材のエッジ部とその周辺に貼付されるものとして、滑り性が高く、また、20%延伸時の残留応力や引張物性の評価結果から明らかなように、切り込みを入れなくても、曲面部又は角部へ貼付した場合の剥がれやしわの発生が抑制される程度の十分な性能を有しており、特に実施例3の緩衝テープが優れていた。さらに、実施例1〜3の緩衝テープは、基材が不織布ではないため、裁断時や使用時に繊維くず等の塵の発生が抑制されていた。そして、実施例1〜3の緩衝テープは、圧縮応力が低いため、車両への組み込み後、3次曲面を有する樹脂部材同士の接合部に柔軟に適合でき、樹脂部材の干渉低減に有効なものであった。
これに対して、比較例1の緩衝テープは、延伸性が乏しく、20%延伸時の残留応力は測定できず、取り扱い難いものであった。また、比較例1の緩衝テープは、基材が不織布であるため、裁断時や使用時に繊維くずが発生した。
As shown in Table 1, the buffer tapes of Examples 1 to 3 had small kinetic frictional force and high slipperiness. Moreover, the residual stress at the time of 20% stretching was low in each stage, and particularly low in Example 3. The buffer tape of Example 2 had a lower residual stress than the buffer tape of Example 1 because the pores were provided in the base material. In addition, the tensile properties were sufficiently large for the buffer tapes of Examples 1 to 3 in both breaking strength and breaking elongation, particularly in Example 3. As described above, the buffer tapes of Examples 1 to 3 are highly slippery when attached to the edge portion of the resin member to be incorporated and its periphery at the time of assembling into the vehicle and after the assembling. As is clear from the evaluation results of residual stress and tensile properties at% stretching, it has sufficient performance to suppress the occurrence of peeling and wrinkles when applied to curved surfaces or corners, even if not cut. In particular, the buffer tape of Example 3 was excellent. Furthermore, since the base material of the buffer tapes of Examples 1 to 3 was not a nonwoven fabric, generation of dust such as fiber scraps was suppressed during cutting and use. And since the buffer tape of Examples 1-3 has a low compressive stress, it can adapt flexibly to the joint part of the resin members which have a tertiary curved surface after incorporation in a vehicle, and is effective in reducing the interference of the resin members Met.
On the other hand, the buffer tape of Comparative Example 1 was poor in stretchability, and the residual stress at 20% stretching could not be measured and was difficult to handle. Moreover, since the base material was a nonwoven fabric, the buffer tape of the comparative example 1 generate | occur | produced the fiber waste at the time of cutting and use.

本発明は、車両製造時に樹脂部材に貼付する緩衝テープとして利用可能である。   The present invention can be used as a buffer tape to be affixed to a resin member when a vehicle is manufactured.

1,2・・・緩衝テープ、11,21・・・発泡基材、11a・・・発泡基材の表面(粘着剤層の非積層面)、11b・・・発泡基材の裏面(粘着剤層の積層面)、21a・・・発泡基材の表面(粘着剤層の非積層面)、21b・・・発泡基材の裏面(粘着剤層の積層面)、12・・・粘着剤層、13・・・剥離材、24・・・細孔部、D・・・細孔部の断面形状における最大径、H・・・発泡基材の厚さ、L・・・隣り合う細孔部同士の距離 DESCRIPTION OF SYMBOLS 1, 2 ... Buffer tape, 11, 21 ... Foaming base material, 11a ... The surface of a foaming base material (non-lamination surface of an adhesive layer), 11b ... The back surface of a foaming base material (adhesive) Layer laminated surface), 21a... Surface of foamed substrate (non-laminated surface of adhesive layer), 21b .. back surface of foamed substrate (laminated surface of adhesive layer), 12... , 13 ... release material, 24 ... pore part, D 1 ... maximum diameter in the cross-sectional shape of the pore part, H 1 ... thickness of the foamed substrate, L 1 ... adjacent to each other Distance between pores

Claims (3)

車両への組み込み時及び組み込み後の、組み込み対象の樹脂部材のエッジ部とその周辺に貼付される緩衝テープであって、
発泡基材の一方の面上に粘着剤層が積層されたことを特徴とする緩衝テープ。
A buffer tape that is attached to and around the edge portion of the resin member to be incorporated at the time of incorporation into the vehicle and after incorporation,
A buffer tape comprising an adhesive layer laminated on one surface of a foam substrate.
前記発泡基材において、前記粘着剤層の非積層面から積層面へと向かう方向に延びる細孔部が、前記非積層面又は積層面に対して垂直な断面に分布していることを特徴とする請求項1に記載の緩衝テープ。   In the foamed base material, the pores extending in the direction from the non-laminated surface to the laminated surface of the pressure-sensitive adhesive layer are distributed in a cross section perpendicular to the non-laminated surface or the laminated surface. The buffer tape according to claim 1. 前記細孔部が、前記発泡基材の前記粘着剤層の非積層面から積層面へと貫通していることを特徴とする請求項2に記載の緩衝テープ。   The buffer tape according to claim 2, wherein the pores penetrate from the non-laminated surface of the pressure-sensitive adhesive layer of the foamed base material to the laminated surface.
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KR20200036929A (en) * 2017-08-30 2020-04-07 가부시키가이샤 데라오카 세이사쿠쇼 Adhesive tape

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